laser based sensor for detection of trace gases in the environment
DESCRIPTION
LASER BASED SENSOR FOR DETECTION OF TRACE GASES IN THE ENVIRONMENT. M. A. Gondal, I. A. Bakhtiari and Z. H. Yamani Laser Research Laboratory & Physics Department King Fahd University of Petroleum & Minerals. Gondal. Me!!. Bakhtiari. Plan. Intro.: What is photoacoustic spectroscopy - PowerPoint PPT PresentationTRANSCRIPT
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LASER BASED SENSOR FOR DETECTION OF TRACE GASES IN THE ENVIRONMENTM. A. Gondal, I. A. Bakhtiari and Z. H. YamaniLaser Research Laboratory & Physics DepartmentKing Fahd University of Petroleum & Minerals GondalBakhtiariMe!!
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PlanIntro.: What is photoacoustic spectroscopyModifying the PA set upResults for EthyleneFuture workConclusion
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Conventional SpectroscopyPrincipal: Energy absorbed is determined by the difference (Io - I) / Io.DetectorSampleLight SourceIoIIntroduction:What is photoacoustic spectroscopy
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Principal: Energy absorbed by the sample produces sound waves which are detected by sensitive microphone. The name PA is due to Light Generated Sound
Advantages:Sample may be gaseous, liquid, solid opaque, powdered.Highly sensitive.Light SourceChopperSampleMicrophone
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LASER RADIATIONEXCITATIONHEAT(VIBRATIONAL)(ELECTRONIC)EMISSIONCHEM. REACTIONRADIATIONEXPANSIONPHASE TRANSITIONSOUND WAVES
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ventPhotoacoustic spectroscopy system using chopper for modulation
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Modifying the PA set up
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Resonant Photoacoustic Cell developed at KFUPM R = 8 mmL = 160 mmIt turns out that: n0,0,1 ~ 3400 HzDont worry about higher resonance frequencies, because they are beyond microphone response limit
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Noise level in PA cell, filled with pure nitrogen
Full signal
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0.001732
0.002194
0.002819
0.002047
0.001547
0.00186
0.005302
0.024404
0.024584
0.006024
0.003456
0.001671
0.001537
0.001733
0.001185
0.001218
0.001454
0.003623
0.005518
0.035726
0.055897
0.021637
0.00228
0.001821
0.001072
0.001689
0.00241
0.002436
0.001314
0.01024
0.029584
0.02054
0.002072
0.001328
0.002227
0.001916
0.001662
0.001768
0.001423
0.001269
0.003343
0.003672
0.005893
0.006452
0.001743
0.001639
0.000932
0.002255
0.00282
0.001466
0.001267
0.001799
0.001559
0.001967
0.002728
0.004437
0.002475
0.00206
0.001895
0.000867
0.001345
0.002919
0.002594
0.003307
0.002436
0.001374
0.001822
0.00255
0.001384
0.00091
0.001661
0.001832
0.002102
0.001996
0.002726
0.003933
0.003503
0.003216
0.002507
0.001193
0.002058
0.001625
0.001372
0.001532
0.001432
0.002633
0.003199
0.003747
0.003012
0.002682
0.002816
0.001775
0.001522
0.001542
0.001474
0.001603
0.001847
0.001368
0.001905
0.012807
0.019589
0.00745
0.002799
0.001369
0.001456
0.000976
0.001269
0.001429
0.001643
0.004028
0.011717
0.009409
0.007826
0.004361
0.001922
0.001709
0.002997
0.002586
0.003148
0.002444
0.003033
0.019338
0.087143
0.082643
0.014963
0.003131
0.002977
0.003311
0.002163
0.001682
0.002028
0.002492
0.00284
0.003318
0.008956
0.0129
0.004684
0.002107
0.003893
0.003061
0.002619
0.001963
0.002826
0.001838
0.003914
0.008789
0.004992
0.003934
0.002888
0.001138
0.001053
0.001256
0.001664
0.002085
0.002011
0.001474
0.002081
0.003464
0.003053
0.001915
0.001584
0.001409
0.001921
0.002646
0.00173
0.001692
0.002042
0.001293
0.001558
0.003544
0.004046
0.002271
0.001643
0.001293
0.001783
0.001992
0.002105
0.001303
0.001558
0.003214
0.00383
0.002041
0.001811
0.001919
0.001715
0.001671
0.001586
0.001472
0.00119
0.002023
0.002728
0.004707
0.008866
0.004737
0.002425
0.001947
0.001131
0.001268
0.001334
0.001913
0.001997
0.001673
0.005284
0.005988
0.005694
0.003983
0.00192
0.001888
0.001649
0.001455
0.001337
0.001763
0.002288
0.006311
0.058096
0.079864
0.026573
0.002419
0.001195
0.001137
0.00114
0.002102
0.002137
0.002898
0.003992
0.007799
0.007548
0.012219
0.007468
0.00244
0.001621
0.001832
0.002848
0.002062
0.001272
0.001322
0.002555
0.007702
0.006834
0.002542
0.001915
0.002379
0.001392
0.001395
0.001826
0.002414
0.00195
0.002052
0.002514
0.004709
Percent Full Scale: Left
nosie level with Mod
0.001261
0.001376
0.001239
0.001261
0.001134
0.001696
0.001407
0.001139
0.001585
0.001252
0.001213
0.000808
0.001273
0.001306
0.001004
0.001311
0.001687
0.001424
0.001139
0.001818
0.002343
0.001244
0.001009
0.001608
0.001871
0.001143
0.000831
0.000844
0.001121
0.001171
0.000632
0.000556
0.000844
0.001178
0.001337
0.000829
0.000956
0.001573
0.00117
0.00053
0.000534
0.000784
0.0007
0.00086
0.001119
0.000964
0.00066
0.000694
0.000686
0.001034
0.000747
0.000869
0.001137
0.001439
0.000829
0.000612
0.000493
0.000915
0.001588
0.000925
0.000518
0.000783
0.001003
0.001113
0.000625
0.000681
0.000698
0.000499
0.000583
0.000864
0.000883
0.000835
0.000758
0.000859
0.001118
0.001412
0.001189
0.001118
0.001453
0.001033
0.00063
0.001003
0.001306
0.000941
0.001002
0.000832
0.000959
0.000656
0.000574
0.000814
0.000872
0.000662
0.000984
0.001029
0.001009
0.000974
0.001034
0.001317
0.001139
0.001125
0.000898
0.000865
0.000877
0.000819
0.001344
0.001472
0.001143
0.001103
0.000859
0.001244
0.000995
0.000633
0.000772
0.001038
0.001129
0.00149
0.001319
0.000859
0.001055
0.000956
0.001411
0.001599
0.001539
0.000977
0.000712
0.001237
0.002994
0.002469
0.000624
0.000586
0.001226
0.0012
0.001107
0.002163
0.00232
0.001657
0.001479
0.001577
0.001359
0.001268
0.001551
0.001811
0.001659
0.001459
0.0016
0.00121
0.001871
0.002222
0.001405
0.001053
0.001482
0.001337
0.000958
0.001676
0.002442
0.001176
0.0009
0.001355
0.001268
0.001444
0.001386
0.001573
0.001721
0.001162
0.001164
0.002357
0.004061
0.002924
0.001712
0.000972
0.00226
0.00372
0.00175
0.001279
0.002017
0.002372
0.001891
0.001037
0.001651
0.001673
0.001507
0.001154
0.000978
0.00157
0.001372
0.004345
0.005401
0.002159
0.00144
0.00077
0.00082
0.001172
0.001523
0.001511
0.00153
0.001948
0.00139
0.000961
0.000896
0.0008
0.00149
0.002403
0.001979
0.001624
0.001496
0.00379
0.003298
0.001108
0.001102
0.0009
0.001495
0.002138
0.001893
0.001976
0.001346
0.001941
0.002373
0.001345
0.001204
0.001938
0.001493
0.000878
0.000954
0.001612
0.002227
0.001586
0.00177
0.001915
0.001246
0.000808
0.001392
0.001608
0.00201
0.001809
0.001742
0.001711
0.001388
0.001488
0.001162
0.001118
0.001567
0.001207
0.001389
0.001387
0.001659
0.001846
0.002253
0.001766
0.00152
0.001801
0.001651
0.001205
0.001642
0.001598
0.001255
0.001702
0.002292
0.002145
0.002478
0.002927
0.003557
0.00243
0.00153
0.001228
0.001528
0.001228
0.001788
0.002
0.002482
0.002275
0.002573
0.002667
0.002376
0.002905
0.001769
0.001703
0.002064
0.002785
0.001708
0.001577
0.001721
0.002497
0.003307
0.003015
0.003044
0.003392
0.003364
0.002809
0.003115
0.002618
0.003241
0.002371
0.002949
0.003796
0.003386
0.003156
0.003254
0.002183
0.002254
0.003251
0.003326
0.003203
0.002659
0.002884
0.004762
0.00401
0.001877
0.002169
0.001868
0.003016
0.002992
0.003147
0.002503
0.002533
0.004029
0.00378
0.003765
0.003932
0.004392
0.003332
0.002259
0.003019
0.004859
0.003125
0.003052
0.002628
0.003
0.00274
0.003859
0.00284
0.001736
0.001821
0.002596
0.003268
0.002754
0.002638
0.003402
0.002366
0.002079
0.003071
0.003429
0.002316
0.004343
0.005705
0.004307
0.002974
0.003512
0.004848
0.003117
0.003411
0.002675
0.001403
0.002263
0.003619
0.002991
0.003411
0.001916
0.001883
0.002434
0.001837
0.001982
0.002469
0.003599
0.003585
0.002178
0.001586
0.002465
0.00276
0.002484
0.001472
0.001457
0.002185
0.002596
0.002424
0.001894
0.00176
0.002024
0.002648
0.001869
0.001959
0.002686
0.002036
0.002157
0.002224
0.001952
0.002435
0.002613
0.001878
0.003062
0.004318
0.002798
0.002394
0.002776
0.003225
0.003397
0.002727
0.001628
0.001543
0.002489
0.002887
0.004257
0.004374
0.002874
0.002785
0.003675
0.004131
0.003302
0.003587
0.002593
0.003952
0.002766
0.001745
0.00196
0.002743
0.003962
0.005544
0.004976
0.003614
0.002821
0.003326
0.003858
0.003681
0.003763
0.006593
0.005181
0.004866
0.005498
0.005129
0.003753
0.004208
0.004307
0.003944
0.002329
0.003156
0.003247
0.004656
0.002977
0.003466
0.004986
0.005467
0.003999
0.004448
0.004767
0.003905
0.004511
0.00597
0.003663
0.003319
0.003218
0.004163
0.004037
0.002665
0.003168
0.003979
0.003136
0.003822
0.005647
0.003623
0.003136
0.003756
0.005138
0.003462
0.004473
0.004396
0.004213
0.003387
0.003377
0.004233
0.007464
0.005664
0.003961
0.004313
0.005778
0.005751
0.007506
0.004731
0.003143
0.00428
0.007692
0.007286
0.005096
0.006181
0.007167
0.007414
0.004659
0.005274
0.003492
0.00366
0.004476
0.004965
0.004587
0.003381
0.004773
0.004861
0.004705
0.003824
0.003649
0.01207
0.0112
0.01095
0.002602
0.004169
0.004064
0.003563
0.005805
0.008098
0.007386
0.00619
0.003576
0.004818
0.004638
0.003748
0.003342
0.002498
0.00427
0.005554
0.003525
0.006231
0.008771
0.00669
0.005395
0.0035
0.00413
0.004535
0.003441
0.004836
0.005873
0.003764
0.003849
0.003477
0.004859
0.005868
0.005326
0.005446
0.009069
0.011195
0.007358
0.005684
0.008072
0.00695
0.006023
0.006893
0.006212
0.006038
0.005457
0.004973
0.00747
0.007263
0.006818
0.007204
0.006157
0.006914
0.005406
0.004692
0.004078
0.004852
0.004599
0.007528
0.008666
0.004879
0.003557
0.007862
0.009606
0.006761
0.008636
0.006751
0.004424
0.00791
0.00775
0.007431
0.006997
0.00499
0.008425
0.010095
0.006844
0.008237
0.008848
0.006323
0.004711
0.005632
0.005869
0.005835
0.004815
0.00533
0.005436
0.007137
0.009483
0.00987
0.007833
0.006924
0.009723
0.00973
0.012558
0.009769
0.008582
0.009357
0.007542
0.005648
0.008845
0.007165
0.006574
0.010358
0.010104
0.007647
0.005526
0.009876
0.007838
0.005207
0.005512
0.00684
0.006998
0.007135
0.006085
0.006415
0.0074
0.008251
0.007075
0.005461
0.004723
0.005154
0.004648
0.002789
0.004374
0.006757
0.004998
0.004658
0.004678
0.008461
0.007723
0.00358
0.004985
0.007561
0.006012
0.004114
0.004725
0.004997
0.006303
0.004882
0.005758
0.006208
0.006284
0.007704
0.006954
0.003537
0.005882
0.005328
0.002699
0.002962
0.005083
0.005397
0.003855
0.00229
0.00138
0.002361
0.003957
0.005068
0.005303
0.004141
0.00304
0.004936
0.005308
0.003598
0.004174
0.003411
0.004583
0.004038
0.004496
0.005331
0.004088
0.003211
0.002619
0.003762
0.003089
0.00344
0.003656
0.002971
0.004493
0.003327
0.003386
0.004212
0.006065
0.005999
0.006032
0.003562
0.004376
0.004303
0.002372
0.002557
0.003829
0.003731
0.003119
0.002379
0.002516
0.004378
0.003646
0.003346
0.003691
0.00277
0.002878
0.003986
0.005761
0.006527
0.004453
0.004945
0.006355
0.004794
0.003642
0.004224
0.005341
0.003704
0.002407
0.004388
0.005101
0.004039
0.004966
0.006068
0.004439
0.002963
0.003465
0.003324
0.004502
0.006144
0.005852
0.004474
0.004627
0.004901
0.005795
0.005197
0.004254
0.003589
0.005749
0.005119
0.0038
0.005719
0.004297
0.005529
0.004693
0.007616
0.008912
0.004999
0.0046
0.006212
0.006749
0.005996
0.003655
0.004052
0.005635
0.006048
0.005423
0.003597
0.00529
0.005065
0.005274
0.005315
0.006155
0.004394
0.00429
0.006378
0.007085
0.004194
0.002929
0.004808
0.007568
0.005318
0.004389
0.007394
0.006112
0.005928
0.004713
0.004413
0.003169
0.003812
0.004863
0.004639
0.005205
0.003831
0.006472
0.007401
0.006113
0.00667
0.005269
0.004659
0.005161
0.006558
0.004983
0.005186
0.007191
0.006492
0.003966
0.003711
0.006779
0.007923
0.006111
0.005035
0.007996
0.009571
0.006453
0.005215
0.005474
0.003366
0.002891
0.004032
0.007242
0.009896
0.009412
0.006047
0.003916
0.004011
0.003348
0.002776
0.002881
0.002572
0.002556
0.004121
0.005605
0.00403
0.002404
0.002691
0.003616
0.00561
0.00638
0.004974
0.003782
0.002793
0.002912
0.003519
0.004947
0.004482
0.003915
0.004625
0.003767
0.00248
0.004466
0.003312
0.004141
0.004327
0.003441
0.004452
0.004178
0.004504
0.004744
0.004732
0.004732
0.004993
0.00584
0.006472
0.003628
0.002652
0.003069
0.004818
0.004315
0.003643
0.00309
0.004795
0.005166
0.0053
0.005307
0.003702
0.002663
0.002537
0.004493
0.005251
0.005837
0.004029
0.002933
0.005345
0.006223
0.00336
0.003171
0.00333
0.002761
0.003473
0.003409
0.003841
0.003476
0.00454
0.003172
0.003197
0.003798
0.003077
0.002326
0.002023
0.003862
0.004251
0.003377
0.003994
0.005087
0.004546
0.0046
0.003233
0.002195
0.001896
0.002883
0.002436
0.002346
0.002388
0.002844
0.00243
0.003118
0.004192
0.003397
0.002249
0.002494
0.00265
0.002236
0.003627
0.00423
0.003985
0.003924
0.004089
0.003192
0.003301
0.002552
0.002483
0.005178
0.005649
0.004187
0.00411
0.003961
0.003395
0.002896
0.004346
0.00543
0.004274
0.002559
0.002746
0.002666
0.003288
0.002685
0.002844
0.003132
0.003492
0.004538
0.0066
0.005573
0.002592
0.003839
0.004508
0.004131
0.003796
0.002169
0.003047
0.005331
0.006025
0.004173
0.002889
0.002995
0.003734
0.002527
0.004268
0.005573
0.004758
0.003991
0.006027
0.007674
0.005774
0.002839
0.004219
0.004455
0.004953
0.00406
0.00324
0.005626
0.006199
0.004483
0.003487
0.003681
0.006038
0.004731
0.002473
0.002687
0.004596
0.005593
0.004167
0.005177
0.004265
0.003289
0.003768
0.004793
0.004369
0.004342
0.005567
0.005007
0.003769
0.005448
0.005926
0.005264
0.00338
0.001388
0.002136
0.002858
0.002303
0.002117
0.00224
0.002183
0.003066
0.005029
0.005239
0.002752
0.002865
0.004138
0.003878
0.002492
0.002946
0.004475
0.003869
0.002626
0.004881
0.006892
0.004867
0.003459
0.004317
0.003709
0.003308
0.003186
0.003384
0.003708
0.00588
0.004808
0.0029
0.004163
0.004684
0.004933
0.003552
0.00291
0.004143
0.00397
0.003696
0.004248
0.004198
0.004681
0.004828
0.00495
0.003873
0.003806
0.002564
0.002587
0.003426
0.003844
0.003539
0.002916
0.005162
0.00656
0.005537
0.002007
0.001961
0.002639
0.004302
0.003284
0.004191
0.005944
0.004267
0.003301
0.002781
0.002308
0.002894
0.002541
0.003006
0.004735
0.004464
0.003821
0.00442
0.002924
0.004186
0.00552
0.006063
0.004018
0.003393
0.003407
0.002893
0.004534
0.005179
0.003376
0.0047
0.004946
0.002494
0.002736
0.002332
0.003876
0.004344
0.002939
0.003125
0.003457
0.00317
0.00403
0.004474
0.002801
0.002087
0.002105
0.002403
0.002047
0.002368
0.002561
0.002824
0.002249
0.001852
0.001879
0.002302
0.002255
0.002387
0.00255
0.003065
0.002543
0.002601
0.002419
0.003063
0.002358
0.001854
0.002616
0.0029
0.002567
0.001611
0.002261
0.002857
0.003072
0.002123
0.002318
0.002832
0.003478
0.003088
0.004422
0.003758
0.002401
0.003321
0.0034
0.003698
0.003249
0.00237
0.002936
0.003356
0.003018
0.003492
0.005315
0.004311
0.002267
0.002011
0.002779
0.003004
0.003064
0.002965
0.00259
0.003638
0.002959
0.003554
0.002943
0.00187
0.002709
0.002775
0.00312
0.005092
0.003872
0.002768
0.002539
0.00382
0.00361
0.004567
0.003776
0.003648
0.003015
0.002142
0.003793
0.004846
0.003396
0.004333
0.006354
0.007343
0.004368
0.00498
0.004174
0.004467
0.003985
0.00393
0.003094
0.00385
0.004655
0.003113
0.003674
0.00568
0.005683
0.005008
0.004403
0.002967
0.004537
0.006307
0.006138
0.003307
0.002833
0.004742
0.005513
0.002357
0.002885
0.002713
0.003421
0.00466
0.004247
0.00304
0.003446
0.004227
0.003991
0.004515
0.005074
0.004303
0.00276
0.003021
0.003702
0.003029
0.003109
0.005057
0.004058
0.002805
0.002506
0.004148
0.004531
0.004432
0.002385
0.003352
0.003553
0.004465
0.004391
0.003207
0.003196
0.003435
0.004087
0.003799
0.002876
0.003101
0.004562
0.006204
0.00362
0.002455
0.001656
0.003179
0.002746
0.001973
0.002307
0.002627
0.002347
0.003221
0.003656
0.002671
0.002021
0.002472
0.001496
0.001863
0.00216
0.001772
0.002118
0.001571
0.002018
0.002547
0.003477
0.002844
0.001908
0.002022
0.002618
0.00195
0.002284
0.003533
0.003408
0.002048
0.001364
0.001985
0.001864
0.001997
0.002098
0.001302
0.001455
0.002475
0.002473
0.001147
0.001249
0.001276
0.001941
0.001911
0.001335
0.001316
0.001733
0.001259
0.001116
0.002339
0.002261
0.001563
0.001267
0.001353
0.001925
0.001749
0.001647
0.001339
0.001179
0.00156
0.001684
0.001311
0.001467
0.001647
0.002165
0.001704
0.001609
0.001686
0.002285
0.002276
0.001436
0.001537
0.001928
0.001293
0.001694
0.002654
0.001748
0.002016
0.002634
0.001841
0.001331
0.001935
0.002351
0.002543
0.001691
0.001051
0.001341
0.001279
0.0014
0.002015
0.001754
0.001296
0.001201
0.002527
0.003149
0.002396
0.00158
0.001343
0.002007
0.002071
0.001428
0.001149
0.002075
0.002343
0.00219
0.001993
0.001723
0.002324
0.002456
0.002008
0.001997
0.00215
0.002366
0.002903
0.001656
0.001726
0.001541
0.002109
0.001347
0.001687
0.00261
0.003555
0.002348
0.002725
0.003025
0.002261
0.002475
0.003448
0.001996
0.001605
0.002256
0.002979
0.002794
0.002497
0.002734
0.003654
0.003444
0.002748
0.001546
0.00135
0.001492
0.001712
0.002756
0.003075
0.002294
0.002367
0.001891
0.002402
0.002758
0.002045
0.001594
0.002275
0.002567
0.002249
0.001363
0.001311
0.00161
0.001458
0.001724
0.002464
0.002401
0.002156
0.001792
0.002352
0.00141
0.00104
0.001663
0.001624
0.00125
0.001108
0.001387
0.001093
0.001784
0.001611
0.001462
0.001842
0.002235
0.002583
0.002496
0.00225
0.00311
0.003593
0.0016
0.001512
0.002139
0.002174
0.001551
0.001417
0.001818
0.002233
0.001962
0.001379
0.00173
0.002263
0.001528
0.001476
0.002149
0.002466
0.002996
0.002983
0.002655
0.002404
0.0026
0.002547
0.002391
0.002662
0.001993
0.001645
0.001343
0.001658
0.001618
0.001643
0.001736
0.002147
0.002219
0.001753
0.001884
0.00191
0.001531
0.001134
0.000936
0.002532
0.003047
0.001703
0.001717
0.001651
0.001341
0.001588
0.002433
0.001924
0.001563
0.001612
0.00178
0.001246
0.001629
0.001604
0.000981
0.001232
0.001611
0.002161
0.002198
0.001993
0.002311
0.001564
0.001481
0.00165
0.002112
0.001772
0.001719
0.001402
0.001639
0.001772
0.001082
0.001754
0.002096
0.002312
0.001691
Percent Full Scale: Left
Frequency (Hz)
PA Signal (arb. Units)
Noise Level with electronic Modulation
Sheet1
;Freq(Hz)Percent Full Scale: Left
1999.89620.001261
2002.58790.001376
2005.27950.001239
2007.97120.001261
2010.66280.001134
2013.35450.001696
2016.04610.001407
2018.73780.001139
2021.42940.001585
2024.12110.001252
2026.81270.001213
2029.50440.000808
2032.1960.001273
2034.88770.001306
2037.57930.001004
2040.2710.001311
2042.96260.001687
2045.65430.001424
2048.34590.001139
2051.03760.001818
2053.72920.002343
2056.42090.001244
2059.11250.001009
2061.80420.001608
2064.49580.001871
2067.18750.001143
2069.87920.000831
2072.57080.000844
2075.26250.001121
2077.95410.001171
2080.64580.000632
2083.33740.000556
2086.02910.000844
2088.72070.001178
2091.41240.001337
2094.1040.000829
2096.79570.000956
2099.48730.001573
2102.1790.00117
2104.87060.00053
2107.56230.000534
2110.25390.000784
2112.94560.0007
2115.63720.00086
2118.32890.001119
2121.02050.000964
2123.71220.00066
2126.40380.000694
2129.09550.000686
2131.78710.001034
2134.47880.000747
2137.17040.000869
2139.86210.001137
2142.55370.001439
2145.24540.000829
2147.9370.000612
2150.62870.000493
2153.32030.000915
2156.0120.001588
2158.70360.000925
2161.39530.000518
2164.08690.000783
2166.77860.001003
2169.47020.001113
2172.16190.000625
2174.85350.000681
2177.54520.000698
2180.23680.000499
2182.92850.000583
2185.62010.000864
2188.31180.000883
2191.00340.000835
2193.69510.000758
2196.38670.000859
2199.07840.001118
2201.770.001412
2204.46170.001189
2207.15330.001118
2209.8450.001453
2212.53660.001033
2215.22830.00063
2217.91990.001003
2220.61160.001306
2223.30320.000941
2225.99490.001002
2228.68650.000832
2231.37820.000959
2234.06980.000656
2236.76150.000574
2239.45310.000814
2242.14480.000872
2244.83640.000662
2247.52810.000984
2250.21970.001029
2252.91140.001009
2255.6030.000974
2258.29470.001034
2260.98630.001317
2263.6780.001139
2266.36960.001125
2269.06130.000898
2271.75290.000865
2274.44460.000877
2277.13620.000819
2279.82790.001344
2282.51950.001472
2285.21120.001143
2287.90280.001103
2290.59450.000859
2293.28610.001244
2295.97780.000995
2298.66940.000633
2301.36110.000772
2304.05270.001038
2306.74440.001129
2309.4360.00149
2312.12770.001319
2314.81930.000859
2317.5110.001055
2320.20260.000956
2322.89430.001411
2325.58590.001599
2328.27760.001539
2330.96920.000977
2333.66090.000712
2336.35250.001237
2339.04420.002994
2341.73580.002469
2344.42750.000624
2347.11910.000586
2349.81080.001226
2352.50240.0012
2355.19410.001107
2357.88570.002163
2360.57740.00232
2363.2690.001657
2365.96070.001479
2368.65230.001577
2371.3440.001359
2374.03560.001268
2376.72730.001551
2379.41890.001811
2382.11060.001659
2384.80220.001459
2387.49390.0016
2390.18550.00121
2392.87720.001871
2395.56880.002222
2398.26050.001405
2400.95210.001053
2403.64380.001482
2406.33540.001337
2409.02710.000958
2411.71880.001676
2414.41040.002442
2417.10210.001176
2419.79370.0009
2422.48540.001355
2425.1770.001268
2427.86870.001444
2430.56030.001386
2433.2520.001573
2435.94360.001721
2438.63530.001162
2441.32690.001164
2444.01860.002357
2446.71020.004061
2449.40190.002924
2452.09350.001712
2454.78520.000972
2457.47680.00226
2460.16850.00372
2462.86010.00175
2465.55180.001279
2468.24340.002017
2470.93510.002372
2473.62670.001891
2476.31840.001037
2479.010.001651
2481.70170.001673
2484.39330.001507
2487.0850.001154
2489.77660.000978
2492.46830.00157
2495.15990.001372
2497.85160.004345
2500.54320.005401
2503.23490.002159
2505.92650.00144
2508.61820.00077
2511.30980.00082
2514.00150.001172
2516.69310.001523
2519.38480.001511
2522.07640.00153
2524.76810.001948
2527.45970.00139
2530.15140.000961
2532.8430.000896
2535.53470.0008
2538.22630.00149
2540.9180.002403
2543.60960.001979
2546.30130.001624
2548.99290.001496
2551.68460.00379
2554.37620.003298
2557.06790.001108
2559.75950.001102
2562.45120.0009
2565.14280.001495
2567.83450.002138
2570.52610.001893
2573.21780.001976
2575.90940.001346
2578.60110.001941
2581.29270.002373
2583.98440.001345
2586.6760.001204
2589.36770.001938
2592.05930.001493
2594.7510.000878
2597.44260.000954
2600.13430.001612
2602.82590.002227
2605.51760.001586
2608.20920.00177
2610.90090.001915
2613.59250.001246
2616.28420.000808
2618.97580.001392
2621.66750.001608
2624.35910.00201
2627.05080.001809
2629.74240.001742
2632.43410.001711
2635.12570.001388
2637.81740.001488
2640.5090.001162
2643.20070.001118
2645.89230.001567
2648.5840.001207
2651.27560.001389
2653.96730.001387
2656.65890.001659
2659.35060.001846
2662.04220.002253
2664.73390.001766
2667.42550.00152
2670.11720.001801
2672.80880.001651
2675.50050.001205
2678.19210.001642
2680.88380.001598
2683.57540.001255
2686.26710.001702
2688.95870.002292
2691.65040.002145
2694.3420.002478
2697.03370.002927
2699.72530.003557
2702.4170.00243
2705.10860.00153
2707.80030.001228
2710.49190.001528
2713.18360.001228
2715.87520.001788
2718.56690.002
2721.25850.002482
2723.95020.002275
2726.64180.002573
2729.33350.002667
2732.02510.002376
2734.71680.002905
2737.40840.001769
2740.10010.001703
2742.79170.002064
2745.48340.002785
2748.1750.001708
2750.86670.001577
2753.55830.001721
2756.250.002497
2758.94170.003307
2761.63330.003015
2764.3250.003044
2767.01660.003392
2769.70830.003364
2772.39990.002809
2775.09160.003115
2777.78320.002618
2780.47490.003241
2783.16650.002371
2785.85820.002949
2788.54980.003796
2791.24150.003386
2793.93310.003156
2796.62480.003254
2799.31640.002183
2802.00810.002254
2804.69970.003251
2807.39140.003326
2810.0830.003203
2812.77470.002659
2815.46630.002884
2818.1580.004762
2820.84960.00401
2823.54130.001877
2826.23290.002169
2828.92460.001868
2831.61620.003016
2834.30790.002992
2836.99950.003147
2839.69120.002503
2842.38280.002533
2845.07450.004029
2847.76610.00378
2850.45780.003765
2853.14940.003932
2855.84110.004392
2858.53270.003332
2861.22440.002259
2863.9160.003019
2866.60770.004859
2869.29930.003125
2871.9910.003052
2874.68260.002628
2877.37430.003
2880.06590.00274
2882.75760.003859
2885.44920.00284
2888.14090.001736
2890.83250.001821
2893.52420.002596
2896.21580.003268
2898.90750.002754
2901.59910.002638
2904.29080.003402
2906.98240.002366
2909.67410.002079
2912.36570.003071
2915.05740.003429
2917.7490.002316
2920.44070.004343
2923.13230.005705
2925.8240.004307
2928.51560.002974
2931.20730.003512
2933.89890.004848
2936.59060.003117
2939.28220.003411
2941.97390.002675
2944.66550.001403
2947.35720.002263
2950.04880.003619
2952.74050.002991
2955.43210.003411
2958.12380.001916
2960.81540.001883
2963.50710.002434
2966.19870.001837
2968.89040.001982
2971.5820.002469
2974.27370.003599
2976.96530.003585
2979.6570.002178
2982.34860.001586
2985.04030.002465
2987.73190.00276
2990.42360.002484
2993.11520.001472
2995.80690.001457
2998.49850.002185
3001.19020.002596
3003.88180.002424
3006.57350.001894
3009.26510.00176
3011.95680.002024
3014.64840.002648
3017.34010.001869
3020.03170.001959
3022.72340.002686
3025.4150.002036
3028.10670.002157
3030.79830.002224
3033.490.001952
3036.18160.002435
3038.87330.002613
3041.56490.001878
3044.25660.003062
3046.94820.004318
3049.63990.002798
3052.33150.002394
3055.02320.002776
3057.71480.003225
3060.40650.003397
3063.09810.002727
3065.78980.001628
3068.48140.001543
3071.17310.002489
3073.86470.002887
3076.55640.004257
3079.2480.004374
3081.93970.002874
3084.63130.002785
3087.3230.003675
3090.01460.004131
3092.70630.003302
3095.39790.003587
3098.08960.002593
3100.78120.003952
3103.47290.002766
3106.16460.001745
3108.85620.00196
3111.54790.002743
3114.23950.003962
3116.93120.005544
3119.62280.004976
3122.31450.003614
3125.00610.002821
3127.69780.003326
3130.38940.003858
3133.08110.003681
3135.77270.003763
3138.46440.006593
3141.1560.005181
3143.84770.004866
3146.53930.005498
3149.2310.005129
3151.92260.003753
3154.61430.004208
3157.30590.004307
3159.99760.003944
3162.68920.002329
3165.38090.003156
3168.07250.003247
3170.76420.004656
3173.45580.002977
3176.14750.003466
3178.83910.004986
3181.53080.005467
3184.22240.003999
3186.91410.004448
3189.60570.004767
3192.29740.003905
3194.9890.004511
3197.68070.00597
3200.37230.003663
3203.0640.003319
3205.75560.003218
3208.44730.004163
3211.13890.004037
3213.83060.002665
3216.52220.003168
3219.21390.003979
3221.90550.003136
3224.59720.003822
3227.28880.005647
3229.98050.003623
3232.67210.003136
3235.36380.003756
3238.05540.005138
3240.74710.003462
3243.43870.004473
3246.13040.004396
3248.8220.004213
3251.51370.003387
3254.20530.003377
3256.8970.004233
3259.58860.007464
3262.28030.005664
3264.97190.003961
3267.66360.004313
3270.35520.005778
3273.04690.005751
3275.73850.007506
3278.43020.004731
3281.12180.003143
3283.81350.00428
3286.50510.007692
3289.19680.007286
3291.88840.005096
3294.58010.006181
3297.27170.007167
3299.96340.007414
3302.6550.004659
3305.34670.005274
3308.03830.003492
3310.730.00366
3313.42160.004476
3316.11330.004965
3318.80490.004587
3321.49660.003381
3324.18820.004773
3326.87990.004861
3329.57150.004705
3332.26320.003824
3334.95480.003649
3337.64650.01207
3340.33810.0112
3343.02980.01095
3345.72140.002602
3348.41310.004169
3351.10470.004064
3353.79640.003563
3356.4880.005805
3359.17970.008098
3361.87130.007386
3364.5630.00619
3367.25460.003576
3369.94630.004818
3372.63790.004638
3375.32960.003748
3378.02120.003342
3380.71290.002498
3383.40450.00427
3386.09620.005554
3388.78780.003525
3391.47950.006231
3394.17110.008771
3396.86280.00669
3399.55440.005395
3402.24610.0035
3404.93770.00413
3407.62940.004535
3410.3210.003441
3413.01270.004836
3415.70430.005873
3418.3960.003764
3421.08760.003849
3423.77930.003477
3426.47090.004859
3429.16260.005868
3431.85420.005326
3434.54590.005446
3437.23750.009069
3439.92920.011195
3442.62080.007358
3445.31250.005684
3448.00420.008072
3450.69580.00695
3453.38750.006023
3456.07910.006893
3458.77080.006212
3461.46240.006038
3464.15410.005457
3466.84570.004973
3469.53740.00747
3472.2290.007263
3474.92070.006818
3477.61230.007204
3480.3040.006157
3482.99560.006914
3485.68730.005406
3488.37890.004692
3491.07060.004078
3493.76220.004852
3496.45390.004599
3499.14550.007528
3501.83720.008666
3504.52880.004879
3507.22050.003557
3509.91210.007862
3512.60380.009606
3515.29540.006761
3517.98710.008636
3520.67870.006751
3523.37040.004424
3526.0620.00791
3528.75370.00775
3531.44530.007431
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