@land MATERIAL SAFETY· DATA SHEET S-LAND BM - Black

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY IDENTIFICATION .............. S-LAND CO,.LTD Rm305,Seeun Bldg,909 Hwajung-Dong,

Dukyang-Ku,Koyang-City,Kyunggi-do,Korea PRODUCT NAME ................... --·8-LAND BM Black PRODUCT USE ..................... '~·PERMANENT MARKER PEN INDUSTRY. MATERIAL USE ....................... PIGMENT.

SECTION 2 COMPOSIT)ON I CHEMICAL CHARATERIZATION

PRODUCT IDENTIFICATION Ethyl Alcohol CAS Number: 64-17-5 PM :107-98-2 IPA :71-23-8 Maleic Acid Resin :26009-09-2 C. I Solvent Black 7 :8005-02-5

SECTION 3 HAZARDS IDENTIFICATION

May be irritating to respiratory tract, skin and eyes . This product is not rapidly ignitable . Use only with adequate ventilation . Wash throughly after handing.

SECTION 4 FIRST AID MEASURES

INHALATION : If inhaled, move to fresh air . Perform artifical respiration if necessary . Get medical attention immediately .

EYES: Flush eye with flowing water until no evidence ol chemical remains (at last 15 minutes J . If irritation develops consult an oculist .

SKIN : Remove contaminated clothing and shoes immediately . Wash affected skin with soap and water . Get medical attention immediately .

INGESTION : If swallowed, dilute with water and induce vomiting . Get medical attention immediately _ Never give anything by mouth to unconscious person .

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SECTION 5 FIRE FIGHTING MEASURES

Fire and explosion hazard : Fire hazard when exposed to heat or flame. Vapour- air mixtures may lignite or explode .

Suitable extinguishing media : Dry chemical, Water Spray, Foam, C02 Gases of C02 , CO, No, and other hazardous oxides could be generated. Self-contained breathing apparatus for fighters. Move container from fire if you can do it without risk. Do not scaiter spilled material with highpressure water steams.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precaution Environmental precautions

Clean up with appropriate personal equipment (see Section 8) . Scoop or sweep & transfer into a closed container. Keep waste out of sewers.

Method for cleaning up Scoop or sweep into a container lor reuse or disposaL" Keep unnecessary person away.

SECTION 7 HANDLING AND STORAGE

Stored in cool dry place, keep container tightly closed . Do not inhale the substance and avoid contact with the skin or eyes . Wear protective clothing when handling open container : avoid environmental pollution by handling the product carefully . Wash throughly after handling . Use only with adequate ventilation .

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

Respiratory Protection : Local exhaust ventilation

Hand Protection Eye Protection Skin Protection

Air purifying respirator Rubber gloves Safety goggles Impervious clothing

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Uniform liquid ODOUR : Odour like alcohol PH : 6.0-8.5 VISCOSITY : no data available BOILING POINT : 11 0 "C MELTING POINT : no data available FLASH POINT : 27"C SOLUBILITY IN WATER : insoluble in water OXIDISING PROPERTIES : None

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SECTION 10 STABILITY AND REACTIVITY

STABILITY AND REACTIVITY : Stable under normal condition of storage and use HAZARDOUS REACTIONS : None HAZARDOUS DECOMPOSITION: None

SECTION 11 TOXICOLOGICAL INFORMATION

TOLERANCE LIMIT : 50(50]ppm, 205(200)ppm ACTUAL ORAL TOXICITY : LD50(rat) : 5410mg/kg SKIN IRRITATION I RABBIT I DRMZE TEST :no data available IRRITATION OF MUCOUS/ RABBIT EYES/ DRAIZE TEST : no data available

SECTION 12 ECOLOGICAL INFORMATION

BIODEGADATION : no data available FISH TOXICITY: no data available

SECTION 13 DISPOSAL CONSIDERATIONS

Ensure that disposal is in compliance with local, national regulations

SECTION 14 TRANSPORT INFORMATION

GGV IMDG CODE : None ICAO/ lATA - DGR : Not restricted UN No. : Not restricted RID/ ADR : None

SECTION 15 REGULATORY INFORMATION

no data available

SECTION 16 OTHER INFORMATION

NOTE: .............. , .............................. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY. EXPRESSED OR IMPLIED, EXCEPT THAT IT IS ACCURATE TO THE BEST KNOWLEDGE

S-LAND. THE DATA ON HfiS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. S-LAND. ASSUMES NO LEGAL RESPONSIBILITY FOR USE ORRELIANCE UPON THESE DATA.

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@land MATERIAL SAFETY. DATA SHEET S-LAND BM - Red

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY IDENTIFICATION .............. S-LANO CO,.LTD Rm305,Seeun 8ldg,909 Hwajung-Oong,

Dukyang-Ku.Koyang-City,Kyunggi-do,Korea PRODUCT NAME ..................... ·S-LAND BM Red PRODUCT USE ...................... :·PERMANENT MARKER PEN INDUSTRY. MATERIAL USE ....................... PIGMENT.

SECTION 2 COMPOSITION I CHEMICAL CHAF!ATERIZATION

PRODUCT iDENTIFICATION EthYl Alcohol CAS Number : 64-17-5 PM :107-98-2 1-Propanol :71-23-8 Benzyl Alcohol :100-51-6 Maleic Actd Resin :26009-09-2 Dye Complex :65138-66-1

SECTION 3 HAZARDS IDENTIFICATION

May be irritating to respiratory tract. skin and eyes . This product is not rapidly ignitable . Use only with adequate ventilation . Wash throughly after handing.

SECTION 4 FIRST AID MEASURES

INHALATION: If inhaled. move {O fresh air . Perform artifical respiration if necessary . Gel medical anent ion immediately .

EYES : Flush eye with flowing water un!if no evidence of chemical remains ( at last 15 minutes J . If irritation develops consult an oculist ,

SKIN :Remove contaminated clothing and shoes immediately. Wash affected skin with soap and water . Get medical attention immediately.

INGESTION : If swallowed, dilute with water and induce vomiting . Get medical al!ention immediately . Never give anything by mouth to unconscious person .

SECTION 5 FIRE FIGHTING MEASURES

Fire and explosion hazard : Fire hazard when exposed to heat or flame. Vapour - air mixtures may lignite or explode .

Suitable extinguishing media : Dry chemical, Water Spray, Foam, CO~

Gases of CO;;, CO, Nox and other hazardous oxides could be generated. Sell-contained breathing apparatl,ls lor lighters. Move container from fire if you can do it without risk. Do not scaiter spilled material with high pressure water steams.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precaution Environmental precautions

Clean up with appropriate personal equipment (see Section 8) . Scoop or sweep & transfer into a closed container. Keep waste out of sewers.

Method for cleaning up Scoop or sweep into a container for reuse or disposal. Keep unnecessary person away.

SECTION 7 HANDLING AND STORAGE

Stored in cool dry place, keep container tightly closed , Do not inhale the substance and avoid contact with the skin or eyes . Wear protective clothing when handling open container ; avoid environmental pollution by handling the product carefully . Wash throughly after handling . Use only with adequate ventilation .

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

Respiratory Protection : Local exhaust ventilation

Hand Protection . Eye Protection Skin Protection

Air purHying respirator Rubber gloves Safety goggles Impervious clothing

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Uniform liquid ODOUR : Odour like alcohol PH : 6.0-8.5 VISCOSITY : no data available BOILING POINT : 103'C MELTING POINT : no data available FLASH POINT : 26'C SOLUBILITY IN WATER : insoluble in water OXIDISING PROPERTIES : None

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SECTION 10 STABILITY AND REACTIVITY

STABILITY AND REACTIVITY : Stable under normal condition of storage and use HAZARDOUS REACTIONS : Nonf? HAZARDOUS DECOMPOSITION: None

SECTION 11 TOXICOLOGICAL INFORMATION

TOLERANCE LIMIT : 50(50)ppm, 205(200)ppm ACTUAL ORAL TOXICITY : LD50(rat) : 5410mg/kg SKIN IRRITATION I RABBIT I ORAIZE TEST :no data available IRRiTATION OF MUCOUS{ RABBIT EYES/ DRAIZE TEST : no data available

SECTION 12 ECOLOGICAL INFORMATION

BIODEGADATION : no data available FISH TOXICITY: no data available

SECTION 13 DISPOSAL CONSIDERATIONS

Ensure that disposal is in compliance with local, national regulations

SECTION 14 TRANSPORT INFORMATION

GGV IMDG CODE : None ICAO/ lATA - OGR : Not restricted UN No. : Not restricted RID/ ADR : None

SECTION 15 REGULATORY INFORMATION

no data available

SECTION 16 OTHER INFORMATION

NOTE: .............................................. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED. EXCEPT THAT IT IS ACCURATE TO THE BEST KNOWLEDGE

S-LAND. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. S-LAND. ASSUMES NO LEGAL RESPONSIBILITY FOR USE ORRELIANCE UPON THESE DATA.

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rc?·land MATERIAL SAFETY· DATA SHEET S-LAND BM - Blue

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY IDENTIFICATION.c ............ S-LAND CO,.LTO Rm305,Seeun Bldg,909 Hwajung-Dong,

Dukyang-Ku, Koyang-City, Kyunggi-do, Korea PRODUCT NAME ..................... ·S-LAND BM Blue PRODUCT USE ...................... :·PERMANENT MARKER PEN INDUSTRY. MATERIAL USE ....................... PIGMENT.

SECTION 2 COMPOSITION I CHEMICAL CHARATERIZATION

PRODUCT IDENTIFICATION Ethyl Alcohol CAS Number : 64-17-5 PM :107-98-2 1-Propanol :71-23-8 Benzyl Alcohol :100-51-6 Maleic Acid Resin :26009-09-2 C.l Solvent Blue 5 :1328-86-6

SECTION 3 HAZARDS IDENTIFICATION

May be irritating to respiratory tract, skin and eyes . This product is not rapidly ignitable . Use only with adequate ventilation . Wash throughly after handing.

SECTION 4 FIRST AID MEASURES

INHALATION : If inhaled, move .to fresh air . Perform artifical respiration if necessary . Get medical attention immediately .

EYES : Flush eye with flowing water until no evidence of chemical remains ( at last 15 minutes ) . If irritation develops consult an oculist .

SKIN : Remove contaminated clothing and shoes immediately . Wash affected skin with soap and water . Get medical attention immediately .

INGESTION : If swallowed, dilute with water and induce vomiting . Get medical attention immediately . Never give anything by mouth to unconscious person .

SECTION 5 FIRE FIGHTING MEASURES

Fire and explosion hazard : Fire hazard when exposed to heat or flame. Vapour- air mixtures may lionite or explod&.

Suitabl& extinguishing media : Dry chemical, Waler Spray. Foam, C02 Gases of C02 , CO, No, and other hazardous oxides could be generated. Self-contained breathing apparatus for fighters. Move container from fire if you can do it without risk. Do not scaiter spilled material with high pressure water steams.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precaution Environmental precautions

Clean up with appropriate personal equipment (see Section 8) . Scoop or sweep & transfer into a closed container. Keep waste out of sewers.

Method for cleaning up Scoop or sweep into a container for reuse or disposaL· Keep unnecessary person away.

SECTION 7 HANDLING AND STORAGE

Stored in cool dry place, keep container tightly closed , Do not inhale the substance and avoid contact with the skin or ey&s . Wear protective clothing when handling open container ; avoid environmental pollution by handling the product carefully . Wash throughly after handling . Use only with adeQuate ventilation .

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

Respiratory Protection : local exhaust ventilation

Hand Protection Eye Protection Skin Protection

Air purifying respirator Rubber gloves Safety goggles lmp&rvious clothing

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Uniform liquid ODOUR ; Odour like alcohol PH : 6.0-8.5 VISCOSITY : no data available BOILING POINT : 110'C MELTING POINT : no data available FLASH POINT ; 27'C SOLUBILITY IN WATER : insoluble in water OXIDISING PROPERTIES : Non&

2

SECTION 10 STABILITY AND REACTIVITY

STABILITY AND REACTIVITY : Stable under normal condition of storage and use HAZARDOUS REACTIONS : None HAZARDOUS DECOMPOSITION: None

SECTION 11 TOXICOLOGICAL INFORMATION

TOLERANCE LIMIT : 50(50)ppm, 205(200)ppm ACTUAL ORAL TOXICITY : LDSO(rat) : 5430mglkg SKIN IRRITATION I RABBIT I DRAIZE TEST : no data available IRRITATION OF MUCOUS/ RABBIT EYES/ DRAIZE TEST : no data available

SECTION 12 ECOLOGICAL INFORMATION

BIODEGADATION : no data available FISH TOXICITY: no data available

SECTION 13 DISPOSAL,CONSIDERATIONS

Ensure that disposal is in compliance with local, national regulations

SECTION 14 TRANSPORT INFORMATION

GGV IMDG CODE : None ICAO/ lATA- DGR : Not reslricted UN No. : Not restricted RID/ ADR : None

SECTION 15 REGULATORY INFORMATION

no data available

SECTION 16 OTHER INFORMATION

NOTE: .............................................. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY. EXPRESSED OR IMPLIED. EXCEPT THAT ~T IS ACCURATE TO THE BEST KNOWLEDGE

S-LAND. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HEREIN. S-LAND. ASSUMES NO LEGAL RESPONSIBILITY FOR USE ORRELIANCE · UPON THESE DATA.

3

@land MATERIAL SAFETY DATA SHEET S-LAND BM - Green

SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

COMPANY JDENTIFICATION .............. S-LAND CO,.l TD Rm305,Seeun Bldg,909 Hwajung-Oong,

Dukyang-Ku, Koyang-City ,Kyunggi-do,Korea PRODUCT NAME .................... ···S-LANO BM Green PRODUCT USE ..................... --·PERMANENT MARKER PEN INDUSTRY. MATERIAL USE.. ..................... PIGMENT.

SECTION 2 COMPOSITION I CHEMICAL CHARATERIZAT!ON

PRODUCT IOENTIFICA TION Ethyt Alcohol CAS Number : 64-1 7-5 PM :107-98-2 lPA :71-23-8 Maleic Acid R;>sin :26009-09-2 C. I Solvent Dye(mixture) :84215-37-2

SECTION 3 HAZARDS IDENTfFlCATION

May be irritating to respirat01y tract, skin and eyes . This product is nol rapidty ignitable . Use only with adequate ventilation . Wash throughly alter handing.

SECTION 4 FIRST AID MEASURES

INHALATION: It inhaled, move to fresh air. · Perform artifical respiration if necessary .

Get medical atteniiOn immediately . EYES : Flush eye with !lowing water until no evidence ol chemical remains

{ at last 15 rn inutes ) . If irritation develops consult an oculist .

SKIN : Remove contaminated clothing and shoes immediately . Wash affected skin with soap and water . Get medical attention immediately .

INGESTION : If swallowed. dilute with water and induce vomiting . Get medical attention immEldiately. Never give anything bY mouth 19 unconscious person .

1

SECTION 5 FIRE FIGHTING MEASURES

Fire and explosion hazard : Fire t1azard when exposed to heal or flame. Vapour - air mixtures may lignite or explode .

Suitable extinguishing media :

Dry chemical, Water Spray, Foam, C02 Gases of C02 , CO, No, and other hazardous oxides could be generated. Sell-contained breathing apparatus for fighters. Move container from fire if you can do it without risk. Do not scaiter spilled material with high pressure water steams.

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precaution Environmental precautions

Clean up with appropriate personal equipment (see Section 8) . Scoop or sweep & transfer into a closed container. Keep waste out of sewers.

Melhod tor cleaning up Scoop or sweep into a container for reuse or disposal. Keep unnecessary person away.

SECT!ON 7 HANDUNG AND STORAGE

Stored in coof dry place, keep container tightly closed . Do flO! inhale the substance and avoid contact with the skin or eyes . Wear protective clothing when handling open container : avoid environmental pollution by handling the product carefully . Wash through!y after handling . Use only with adequate ven!ilation _

SECTION 8 EXPOSURE CONTROLS, PERSONAL PROTECTION

Respiratory Protection : Local exhaust ventilation

Hand Protection Air purifying respirator

Rubber gloves Eye Protection Skin Protection

Safety goggles Impervious clothing

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE : Uniform liquid ODOUR : Odour like alcohol PH : 6.0-8.5 VISCOSITY : no data available BOILING POINT : 103"C MELTING POINT : no data available FLASH POINT : 26"C SOLUBILITY IN WATER : insoluble in water OXIDISING PROPERTIES : None

2

SECTION 10 STABILITY AND REACTIVITY

STABILITY AND REACTIVITY : Stable under normal condition of st01age and usa HAZARDOUS REACTIONS :None HAZARDOUS DECOMPOSITION: None

SECTION 11 TOXICOLOGICAL INFORMATION

TOLERANCE LIMIT : 50(50)ppm, 205(200)ppm ACTUAL ORAL TOXICITY : L050(rat) : 5430mg/kg SKIN IRRITATION I RABBIT I DRA!ZE TEST : no data available IRRITATION OF MUCOUS/ RABBIT EYES/ DRAIZE TEST : no data available

SECTION 12 ECOLOGICAL INFORMATION

BIODEGADATION : no data avaiiab!e FISH TOXICITY: no data available

SECTION 13 DISPOSAL.CONSIDERATIONS

Ensure that disposal is in compliance wiit1 local, national regulations

SECTION 14 TRANSPORT INFORMATION

GGV IMOG CODE : None ICAO/ lATA - DGR : No! restricted UN No. : Not restricted RIO/ AOR : None

SECTION 15 REGULATORY INFORMATION

no data available

SECTION 16 OTHER INFORMATION

NOTE: .............................................. THIS INFORMATION IS FURNISHED WITHOUT WARRANTY, EXPRESSED OR IMPLIED, EXCEPT THAT fi IS ACCURATE TO THE BEST KNOWLEDGE

S-LANO. THE DATA ON THIS SHEET RELATES ONLY TO THE SPECIFIC MATERIAL DESIGNATED HER!OIN. S-LAND. ASSUMES NO LEGAL RESPONSIBILITY FOR USE ORRELJANCE UPON THESE DATA.

3