Title Cover & Contents

Author(s)

Citation Bulletin of the Institute for Chemical Research, KyotoUniversity (1981), 58(5-6)

Issue Date 1981-01-31

URL http://hdl.handle.net/2433/76918

Right

Type Others

Textversion publisher

Kyoto University

ISSN 0023-6071

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 58, Nos. 5-6

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY

KYOTO, JAPAN

November, 1980

(Bull. Inst. Chem. Res., Kyoto Univ.)

INSTITUTE F●R CHEMICAL RESEARCH

KYOTO UNIVERSITY

Director

TOSI710 TAKADA

iVlemhers o£'Cowncil

Yoshichika Barrno. `E�hi FuJrTs Hiroshi INAGt1KI

YﾜZO INOi」YE Keri-IC111 KATAYAMA R�OZO KITAYIARU

Naokazu KorzuMi …iVﾜchio'KURATA - Shinzaburo Oxa

Masaya OKANO Tatsu�� Toshio Taxana

Mitsuru TAKANAMI Hidekuni TAKEKosHI「 TOhrU TAKENAKA

Yoshimasa TAKEzAKI Megumi TAsHIRo Natsu UYEDA

Takuj i YaNasu :

Publication Cornrnittee

M�.S�.ﾎ�ill ARAKAWA R�OZO KITAMARi」 M�.S�.iC�.ZU MATSUI

Kenj i SoDA Hidekuni TAKEKosHI TOIIT'U TAKENAKA

Business Staff

Tetsuo FuJIMoTo Seiji IJIRI Shoichi MATsuMuRA

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Term I Vol. I Title I Published

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N 19・654No.・・蒲蕪 雛 攣慮黙 陰罪tめn曲 一

CONTENTS

Toshio Ibuki and Yoshimasa Takezaki: Unimolecular Decomposition of Chemically Activated Propylene.........................................................511

Mutsuo Matsumoto, Anilkumar G. Gaonkar, and Tohru Takenaka: The Es- timation of Hamaker Constants of Alcohols and Interfacial Tensions at Alcohol-Mercury Interfaces...............................................................523

Tetsuya Hanai, Yasuo Kita, and Naokazu Koizumi: Dielectric Relaxation Profiles in a Theory of Interfacial Polarization Developed for Concentrated

Disperse Systems of Spherical Particles ................................................534

Junzo Umemura and Henry H. Mantsch: The Molecular Association of Tetracaine with Ethylpalmitate: an Infrared Spectroscopic Study ............ 548

Notes

Morimasa Miyazaki: EPR Study of Vanadium Oxide Bis(8-quinolinolate) Doped in Zinc Bis(8-quinolinolate) Dihydrate .......................................555

Noriyuki Kimura, Soichi Hayashi, and Tohru Takenaka: Infrared Studies on Molecular Orientation in Nematic Films of MBBA with Two Free Surfaces... 559

Review

Kazuo Yonaha and Seizen Toyama : w-Amino Acid : Pyruvate Aminotrans-ferase ..........................................................................................564

The Papers Published by the Staff Members of the Institute from July 1979 to

June 1980 ....................................................................................587

ISSN 0023-6071

BULLETIN OF THE INSTITUTE

FOR CHEMICAL RESEARCH

KYOTO UNIVERSITY

Vol. 58

Published bi-monthly by

THE INSTITUTE FOR CHEMICAL RESEARCH KYOTO UNIVERSITY

KYOTO, JAPAN

1980

(Bull. Inst. Chem. Res., Kyoto Univ.)

Contents of Volume 58, 1980

Toshiyasu Higo and Yoshihisa Iwashita: Cross Assembler/Editor Program. of HP2100 to Use INTEL 8085 ............................................................1

Hidekuni Takekoshi and Toshihiro Miyanaga: Model Experiments for rf Structure of Kyoto University Superconducting Cyclotron....................... 5

Takao Igaki, Tetsuya Hanai, Takehiro Nishidai, Mitsuyuki Abe, and Hidekuni Takekoshi: PIXE Analysis Using Kyoto University Cyclotron ...............11

Yoshihisa Iwashita: Field Stability Improvement of the Kyoto University Cyclotron ....................................................................................25

Toshiro Takabatake, Hiromasa Mazaki, and Teruya Shinjo: Localized Spin Fluctuations in 4d and 5d Transition Metals with Iron Impurities ............29

Masahiko Kurakado, Hiromasa Mazaki, and Shinji Tachi: Excess Quasi- particles in Sn—SnO2—Sn Tunnel Junction by Charged Particles ...............45

Takeshi Mukoyama and Rintaro Katano: Gravitational Effect on Internal Conversion....................................................................................56

Takeshi Mukoyama and Laszlo Sarkadi: A Computer .Code for K- and L- Shell Ionization Cross Sections in the Plane-Wave Born Approximation...... 60

Takeshi Mukoyama: - Electronic Wave Functions for Helium-Like Atoms.........67 Takeshi Mukoyama: Effect of Electronic Correlation on Atomic Excitation

Probability Accompanying g Decay ...................................................71 Yoshihisa Iwashita, Toshiyasu. Higo, and Kenro Kuroki: Magnetic Field.

Trimming Effect of Saturated Ferromagnetic Rods.................................78 Yasuyuki Nakayama, Tatsumi Mizogawa, and Tatsumi Kawaratani: Study

of the Emission of Low-Energy Positrons from MgO ..............................88 Takeshi Mukoyama and Laszlo Sarkadi: Plane-Wave Born-Approximation

Calculations of K- and L-Shall Ionization by Heavy Charged Particles ...... 95 Hidekazu Doe, Masakazu Matsui, and Tsunenobu Shigematsu: Nonaqueous

Extraction of Zinc from Ethylene Glycol Solution of Lithium Perchlorate and/or Chloride..............................................................................133

Matsujiro Sakurada: EPR Studies of Axial Ligation of Low-Spin Cobalt(II) Schiff Base Complexes with Lewis Bases and CO ..................................140

Hidekazu Doe, Masakazu Matsui, and Tsunenobu Shigematsu: The Influence of Solvents on the Stability Constants of Some Divalent Cation Com-

pounds. Zinc Chlorides in Methanol-Nitromethane, Methanol-Water and Ethylene Glycol .......................................................................154

Takeshi Mukoyama, Hiromasa. Mazaki, Shunji Kakiuchi, and Masakazu Matsui: Estimation of Chemical Effect on the Decay Rate of 99mTc ......... 164

Yuzuru Kusaka, Haruo Tsuji, Yuzo Fujimoto, Keiko Ishida; Tetsuo Mamuro, Tadao Matsunami, Akira Mizohata, and Shoji Hirai: Multielement

Neutron Activation Analysis of Underground _ Water Sample ...................171 Yoshihiro Sasaki: Electronic Spectra of Octahedral Nickel(II). and Cobalt(II)

Complexes with 2-(2-Pyridyl):imidazole and 2-(2-Pyridyl)benzimidazole ...... 187 Masao Kiyama and Toshio Takada: Transformation Products of Iron(III)

Hydroxide by Hydrolysis at Elevated Temperatures between 50 and 90°C ... 193

U

Taitiro Fujinaga, Tooru Kuwamoto, and Kenji Sugiura: Gas Chroma- tography of Metal Chelates Using the LVGC Method. Nickel(II)

Trifluoroacetylacetonate •..................................................................201 Teruo Hinoue, Satoshi Okazaki, and Taitiro Fujinaga: A Rapid Scan Internal

Reflection Spectroscopic System.........................................................211 Jun-ichi Hayami, Masaki Asahi, Rui Tamura, and Noboru Ono: Nucleo-

fugicity in the Aromatic Nucleophilic Substitution Reaction of Picryl Derivatives with Nitrite Ion in Acetonitrile .......................................... 222

Keizo Hiraki, Yuzo Tamari, Yasuharu Nishikawa, and Tsunenobu Shigematsu: Homogeneities of Trace Amounts of Selenium in Powdered Samples and

the Variation of Oxidation-State of the Element during Storage ............... 228 Mutsuo Koyama and Rokuji Matsushita: Use of Neutron Spectrum Sensitive

Monitors for Instrumental Neutron Activation Analysis ..........................235 Yoshihiro Sasaki: Characterization of Iron(II) Octahedral Complexes with

a-Dioximes and Possibility of Application of a-Furyldioxime to Chemical Analysis of Iron(II) ........................................................................244

Toshihiko Akiyama, Yoshichika Bando, and Toshio Takada: Cation Distri- bution and Some Properties of Brownmillerite Phase Ca2Fe2_irMn,,M,,Os (M=Mg, Ni, Zn) ...........................................................................252

Yasunori Ikeda, Yoshichika Bando, and Toshio Takada: Crystal Orientation of Spinel Type Ferrite during Solid-Solid Reaction.................................260

Tetsu Kumagai, Masakazu Matsui, and Tsunenobu Shigematsu: Forced-Flow Chromatography of Alkaline Earths Using Spectrofluorometric Detector ... 269

Shigeo Tanimoto, Tatsuo Oida, Toshio Kokubo, Toyonari Sugimoto, and Masaya Okano: Diels-Alder Addition of N, N-Diethyl-1, 3-butadienyl-

amine to Dehydroaromatic Intermediates Generated from Some Halo-aromatics ....................................................................................289

Nobuharu Ando, Satoshi Ohi, Yukio Yamamoto, Jun'ichi Oda, and Yuzo Inouye: Synthesis and Complexation Stereochemis try of Crown Ethers .....293

Ken Nishikawa, Motohisa Oobatake, and Tatsuo Ooi: Method for Energy Computation of Protein Structures. A Set of Amino Acid Geometries

and Energy Parameters ......................................................................308 Haruo Misono, Yoshiyasu Kawabata, Mitsuyoshi Toyosato, Tatsuo Yama-

moto, and Kenji Soda: Purification and Properties of L-Methionine Decarboxylase of Streptomyces sp. .........................................................323

Shinpei Yamamoto, Yoshikazu Yuki, and Susumu Nagasaki: Purification and Properties of a Yeast Cell Lytic Enzyme from Pellicularia sasaki ............ 334

Shinpei Yamamoto, Yoshikazu Yuki, and Susumu Nagasaki: Action Pattern of a Yeast Cell Lytic Enzyme from Pellicularia sasaki ..............................343

Susumu Nagasaki, Yoshikazu Yuki, and Shinpei Yamamoto: Some Properties of a Yeast Cell Lytic Enzyme from Pellicularia sasaki, Especially Refering to

Thermal Denaturation.....................................................................351 Makoto Fushimi, Naomichi Baba, Jun'ichi Oda, and Yuzo Inouye: Asym-

metric Reduction of a-Keto-esters and Trifluoroacetophenone with N-anionized Hantzsch ester ..............................................................357

Masaaki Yasuda, Seizen Toyama, Kazuo Yonaha, and Kenji Soda: Purifica- tion and Crystallization of L-Ornithine: a-Ketoglutarate a-Amino

transferase from Corynebacterium Sepedonicum ........................ ................ 366

Eiichi Takenouchi, Donka K. Nikolova, Hidehiko Tanaka, Tatsuo Yamamoto, and Kenji Soda: Mechanism of Lysine Overproduction by a Yeast

Mutant Resistant to a Lysine Sulfur Analog .........................................371 Naomichi Baba, . Taketoshi Makino, Jun'ichi Oda, and Yuzo Inouye: 1-D-

Glucopyranosyl-1, 4-dihydronicotinaznides . as Chiral NADH: Model And Their Asymmetric Reactions with Prochiral Substrates . ........................... 386

Terumitsu Kotani, Toshio Hayashi, and Akio Nakajima: Molecular Charac- terization of Tri-block Copolymer Containing Polyamino Acid as One

Component ...................................................................................449 Suong-Hyu Hyon and Ryozo Kitamaru:, Structure and Properties of Lightly

Cross-linked Isotactic Polypropylene, Crystallized from the Melt under Uniaxial Compression .....................................................................457

Akiyoshi Kawaguchi, Ryo Matsui, and Ken-ichi Katayama: Lattice Distor- tion of Polyethylene at Low Temperatures ..........................................470

Toshio Ibuki and Yoshimasa Takezaki: Unimolecular Decomposition of Chemically Activated Propylene ........................................................511

Mutsuo Matsumoto, Anilkumar G. Gaonkar, and Tohru Takenaka: The Es- timation of Hamaker Constants of Alcohols and Interfacial Tensions

at Alcohol-Mercury Interfaces ...........................................................523 Tetsuya Hanai, Yasuo Kita, and Naokazu Koizumi: Dielectric Relaxation

Profiles in a Theory of Interfacial Polarization Developed for Concentrated Disperse Systems of Spherical Particles ................................................534

Junzo Umemura and Henry H. Mantsch: The Molecular Association of Tetracaine with Ethylpalmitate: an Infrared Spectroscopic Study ............ 548

Notes

Yoshihiro Sasaki: Characterization of Iron(II) Complexes with 1-Diketones and Monothio-ji-diketone .................................................................275

Mitsuko Suzuki, Masakazu Matsui, Tsunenobu Shigematsu, Yasuzo Matsuo, and Toyoshi Nagai: On the Sensitivity in Fluorometry of Europium as

Naphthoyltrifluoroacetonate ............................................................279 Takejiro Takamatsu, Munetsugu Kawashima, and Mutsuo Koyama: Analysis

of Rock and Sediment Standard Prepared in Japan by Neutron Activation and X-ray Fluorescence Methods ......................................................285

Naomichi Baba, Taketoshi Makino, Jun'ichi Oda, and Yuzo Inouye: A Note on the Difference in Reactivity of Dihydronicotinamide 1S-D-glucopyranoside

and Its Acetylated Form ..................................................................382 Morimasa Miyazaki: EPR Study of Vanadium Oxide Bis(8-quinolinolate)

Doped in Zinc Bis(8-quinolinolate) Dihydrate .......................................555 Noriyuki Kimura, Soichi Hayashi, and Tohru Takenaka: Infrared Studies on

Molecular Orientation in Nematic Films of MBBA with Two Free Surfaces... 559

Communication

Naomichi Baba, Jun'ichi Oda, and Yuzo Inouye: NADH Model Studies: 1, 4-Dihydronicotinamide Covalently Bonded to a Cyclic Peptide, Bacitracin ....................................................................................379

iv

Reviews

Norio Kurihara and Minoru Nakajima: Biodegradation of Lindane (7-BHC) and its Isomers in Mammals and Insects .............................................390

Takamitsu Yorifuji: Bacteria Aminohydrolases and Their Plausible Evolu- tionary Relationships .....................................................................418

Yoshikazu Izumi, Yoshiki Tani, and Hideaki Yamada: Biotin Biosynthesis Microorganisms..............................................................................434

Eiichi Fujita, Kaoru Fuji, Yoshimitsu Nagao, and Masahito Ochiai: The Chemistry on Diterpenoids in 1979. Part—I ........................................484

Kazuo Yonaha and Seizen Toyama: w-Amino Acid : Pyruvate Amino- transferase ....................................................................................564

V

Author Index to Volume 58, 1980

Abe, Mitsuyuki ....................................................................................11 Akiyama, Toshihiko ..............................................................................252

Ando, Nobuharu .................................................................................293 Asahi, Masaki ....................................................................................222 Baba, Naomichi ...............................................................357, 379, 382, 386

Bando, Yoshichika ........................................................................252, 260 Doe, Hidekazu ..............................................................................133, 154 Fuji, Kaoru .......................................................................................484

Fujimoto, Yuzo ....................................................................................171 Fujinaga, Taitiro ...........................................................................201, 211

Fujita, Eiichi .......................................................................................484 Fushimi, Makoto .................................................................................357

Gaonkar, Anilkumar G. ........................................................................523 Hanai, Tetsuya ................................................................................11, 534

Hayami, Jun-ichi .................................................................................222 Hayashi, Soichi ....................................................................................559 Hayashi, Toshio ...................................................................................449 Higo, Toshiyasu .................................................................................1, 78

Hinoue, Teruo ....................................................................................211 Hirai, Shoji ........................................................................................171

Hiraki, Keizo ......................................................................................228 Hyon, Suong-Hyu.................................................................................457

Ibuki, Toshio ......................................................................................511 Igaki, Takao .......................................................................................11 Ikeda, Yasunori ...................................................................................260 Inouye, Yuzo ............................................................293, 357, 379, 382, 386

Ishida, Keiko ......................................................................................171 Iwashita, Yoshihisa ........................................................................1, 25, 78

Izumi, Yoshikazu .................................................................................434 Kakiuchi, Shunji .................................................................................164

Katano, Rintaro .................................................................................56 Katayama, Ken-ichi .............................................................................470

Kawabata, Yoshiyasu ...........................................................................323 Kawaguchi, Akiyoshi ...........................................................................470 Kawaratani, Tatsumi ...........................................................................88 Kawashima, Munetsugu ........................................................................285 Kimura, Noriyuki ................................................................................559

Kita, Yasuo .......................................................................................534 Kitamaru, Ryozo .................................................................................457

Kiyama, Masao ...................................................................................193 Koizumi, Naokazu ..............................................................................534 Kokubo, Toshio ...................................................................................289 Kotani, Terumitsu ................................................................................449

vl

Koyama, Mutsuo ...........................................................................235, 285 Kumagai, Tetsu ...................................................................................269 Kurakado, Masahiko ........................................................................... 45 Kurihara, Norio ...................................................................................390 Kuroki, Kenro ....................................................................................78 Kusaka, Yuzuru ...................................................................................171 Kuwamoto, Tooru ................................................................................201 Makino, Taketoshi ........................................................................382, 386 Mamuro, Tetsuo .................................................................................171 Mantsch, Henry H. ..............................................................................548 Matsui, Masakazu ......................................................133, 154, 164, 269, 279 Matsui, Ryo .......................................................................................470 Matsumoto, Mutsuo ...............................................................................523 Matsunami, Tadao ..............................................................................171 Mutsuo, Yasuzo ...................................................................................279 Matsushita, Rokuji ..............................................................................235 Mazaki, Hiromasa .....................................................................29, 45, 164 Misono, Haruo ....................................................................................323 Miyanaga, Toshihiro .............................................................................5 Miyazaki, Morimasa .............................................................................555 Mizogawa, Tatsumi ..............................................................................88 Mizohata, Akira .................................................................................171 Mukoyama, Takeshi .....................................................56, 60, 67, 71, 95, 164 Nagai, Toyoshi ....................................................................................279 Nagao, Yoshimitsu ..............................................................................484 Nagasaki, Susumu .....................................................................334, 343, 351 Nakajima, Akio ...................................................................................449 Nakajima, Minoru................................................................................390 Nakayama, Yasuyuki ...........................................................................88 Nikolova, Donka K. .............................................................................371 Nishidai, Takehiro ................................................................................11 Nishikawa, Ken ...................................................................................308 Nishikawa, Yasuharu ...........................................................................228 Ochiai, Masahito .................................................................................484 Oda, Jun'ichi ..............................................................293, 357, 379, 382, 386 Ohi, Satoshi .......................................................................................293 Oida, Tatsuo.......................................................................................289 Okano, Masaya ...................................................................................289 Okazaki, Satoshi .................................................................................211 Ono, Noboru ......................................................................................222 Oobatake, Motohisa .............................................................................308 Ooi, Tatsuo .......................................................................................308 Sakurada, Matsujiro .............................................................................140 Sarkadi, Laszlo .................................................................................60, 95 Sasaki, Yoshihiro .....................................................................187,244,275 Shigematsu, Tsunenobu ................................................133, 154, 228, 269, 279 Shinjo, Teruya ....................................................................................29 Soda, Kenji ...........................................................................323, 366, 371

VII

Sugimoto, Toyonari ..............................................................................289 Sugiura, Kenji ....................................................................................201 Suzuki, Mitsuko ...................................................................................279 Tachi, Shinji .......................................................................................45 Takabatake, Toshiro .............................................................................29 Takada, Toshio .......................................................................193, 252, 260 Takamatsu, Takejiro .............................................................................285 Takekoshi, Hidekuni ...........................................................................5, 11 Takenaka, Tohru ...........................................................................523, 559 Takenouchi, Eiichi ..............................................................................371 Takezaki, Yoshimasa .............................................................................511 Tamari, Yuzo ......................................................................................228 Tamaru, Rui .......................................................................................222 Tanaka, Hidehiko ................................................................................371 Tani, Yoshiki ......................................................................................434 Tanimoto, Shigeo .................................................................................289 Toyama, Seizen .............................................................................366, 564 Toyosato, Mitsuyoshi ...........................................................................323 Tsuji, Haruo .......................................................................................171 Umemura, Junzo .................................................................................548 Yamada, Hideaki .................................................................................434 Yamamoto, Shinpei .................................................................334, 343, 351 Yamamoto, Tatsuo ........................................................................323, 371 Yamamoto, Yukio ................................................................................293 Yasuda, Masaaki .................................................................................366 Yonaha, Kazuo .............................................................................366, 564 Yorifuji, Takamitsu ..............................................................................418 Yuki, Yoshikazu .....................................................................334, 343, 351