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    KS4 Chemistry

    Atomic Structure

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    Atomic Structure

    Electron configuration

    Summary activities

    Isotopes

    Introducing atoms

    Atomic number and mass number

    Contents

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    Discovery of atomic structure

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    Atoms the building blocks

    All substances are made from very tiny particles called atoms.

    John Dalton had ideas about theexistence of atoms about 200 years

    ago but only relatively recently have

    special microscopes (called

    electron microscopes) beeninvented that can see atoms.

    The yellow blobs in this image are

    individual gold atoms, as seenthrough an electron microscope.

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    Elements different types of atom

    Elements are the simplest substances. There are about

    100 different elements.

    Each element is made up of just one particular type of atom,

    which is different to the atoms in any other element.

    Copperis anelement made up ofcopper atoms only.

    Carbon is anelement made up ofcarbon atoms only.

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    How small is an atom?

    Atoms are extremely small they are about 0.00000001cm

    wide.

    N X3,000,000,000

    If a football was enlarged

    by the same amount itwould stretch from the

    UK to the USA.

    To make an atom the size of a football it would have to be

    enlarged by about 3,000,000,000 times.

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    The Amazing Atomic Zoom

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    Inside an atom

    Where are the electrons and nucleus found in an atom?

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    Atomic Structure

    Electron configuration

    Summary activities

    Isotopes

    Introducing atoms

    Atomic number and mass number

    Contents

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    How heavy is an atom?

    A single grain of sand contains millions of atoms of silicon

    and oxygen.

    Each atom must therefore have an extremely small mass.

    millions of these atoms

    join to form each tiny

    grain of sand

    Si

    O

    O

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    Relative atomic mass

    Atoms are so small that their mass is not measured in grams

    but in atomic mass units.

    Relative atomic mass = 12C

    The element carbon is the atom that the mass of all otheratoms is compared to. Carbon has a RAM of 12.

    The atoms of each type of element have a relative atomic

    mass (RAM).

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    Relative atomic mass examples

    The lightest atom is hydrogen. It has 112 the mass of carbon

    and so has a RAM of 1.

    Mg

    Magnesium is twice as heavy as carbon. It has a RAM of 24.

    HH H

    HHH

    HH

    HH HH

    HH H

    HHH

    HH

    HH HH C

    12 atoms x 1 = 1 atom x 12

    CCMg

    1 atom x 24 = 2 atoms x 12

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    Even smaller particles

    For some time people thought that atoms were the smallest

    particles and could not be broken into anything smaller.

    proton

    neutron

    electron

    Scientists now know that atoms are actually made from even

    smallersubatomic particles. There are three types:

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    Where are subatomic particles found?

    Protons, neutrons and electrons are NOT evenly distributed in

    an atom.

    The electrons are

    spread out around the

    edge of the atom. Theyorbit the nucleus in

    layers called shells.

    The protons and neutrons

    exist in a dense core at the

    centre of the atom. This is

    called the nucleus.

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    The atom: check it out!

    Draw a labelled diagram of the atom showing the nucleus

    and labelling protons, neutrons and electrons.

    nucleus

    neutron proton

    electron

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    Particle Mass Chargeproton 1 +1

    neutron 1 0

    electron almost 0 -1

    Properties of subatomic particles

    There are two properties of subatomic particles that are

    especially important:

    1. Mass

    2. Electrical charge

    The atoms of an element contain equal numbers of

    protons and electrons and so have no overall charge.

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    How many protons?

    The atoms of any particular element always contain the same

    number of protons. For example:

    The number of protons in an atom

    is known as its atomic number

    orproton number.

    It is the smaller of the two numbers

    shown in most periodic tables.

    hydrogen atoms always contain 1 proton;

    carbon atoms always contain 6 protons;

    magnesium atoms always contain 12 protons,

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    Whats the atomic number?

    What are the atomic numbers of these elements?

    11

    sodium

    26

    iron

    50

    tin

    9

    fluorine

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    More about atomic number

    Each element has a definite and fixed number of protons.

    If the number of protons changes, then the atom becomes

    a different element.

    Changes in the number of particles in the nucleus

    (protons or neutrons) is very rare. It only takes place in

    nuclear processes such as:

    radioactive decay;

    nuclear bombs;

    nuclear reactors.

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    Atom Protons Neutrons Mass number

    hydrogen 1 0 1

    lithium 3 4 7

    aluminium 13 14 27

    Mass number

    Electrons have a mass of almost zero, which means that the

    mass of each atom results almost entirely from the number of

    protons and neutrons in the nucleus.

    The sum of the protons and neutrons in

    an atoms nucleus is the mass number.

    It is the larger of the two numbers shownin most periodic tables.

    Wh h b ?

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    127

    Whats the mass number?

    What is the mass number of these atoms?

    73

    59

    64

    4

    Mass number = number of protons + number of neutrons

    Atom Protons Neutrons Mass numberhelium 2 2

    copper 29 35

    cobalt 27 32

    iodine 53 74

    germanium 32 41

    H t ?

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    How many neutrons?

    How many neutrons are there in these atoms?

    Atom Massnumber

    Atomicnumber

    Number ofneutrons

    helium 4 2

    fluorine 19 9

    strontium 88 38

    zirconium 91 40

    uranium 238 92

    51

    146

    50

    10

    2

    Number of neutrons = mass number - number of protons

    = mass number - atomic number

    B ildi l

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    Building a nucleus

    C t t

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    Atomic Structure

    Electron configuration

    Summary activities

    Isotopes

    Introducing atoms

    Atomic number and mass number

    Contents

    H l t ?

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    Atom Protons Neutrons Electrons

    helium 2 2 2

    copper 29 35 29

    iodine 53 74 53

    How many electrons?

    Atoms have no overall electrical charge and are neutral.

    This means atoms must have an equal number of

    protons and electrons.

    The number of electrons is therefore the same as

    the atomic number.

    Atomic number is defined as the number of protons rather

    than the number of electrons because atoms can lose or

    gain electrons but do not normally lose or gain protons.

    C l l ti th b f l t

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    Atom Protons Neutrons Electrons Atomic

    number

    Mass

    number

    boron 5 6

    potassium 19 20

    chromium 24 28

    mercury 80 121

    argon 18 22

    Calculating the number of electrons

    5

    19

    18

    24

    80

    5

    19

    18

    24

    80

    11

    39

    40

    52

    201

    What are the missing numbers?

    H l t d?

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    How are electrons arranged?

    Electrons are not evenly spread but exist in layers

    called shells.

    3rd shell

    2nd shell

    1st

    shell

    The arrangement of electrons in these shells is often called

    the electron configuration.

    Ho man electrons per shell?

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    How many electrons per shell?

    Each shell has a maximum number of electrons that it can

    hold. Electrons will fill the shells nearest the nucleus first.

    3rd shell holds

    a maximum of

    8 electrons

    2nd shell holds

    a maximum of

    8 electrons

    1st shell holdsa maximum of

    2 electrons

    Calculating electron configurations

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    Calculating electron configurations

    Properties of the nucleus and electrons

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    Properties of the nucleus and electrons

    Summary: the atom so far

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    Thinly spread around the outside

    of the atom.

    Very small and light.

    Negatively charged.

    Found orbiting the nucleus in layers called shells.

    Able to be lost or gained in chemical reactions.

    Summary: the atom so far

    The nucleus is:

    Electrons are:

    Dense it contains nearly all the mass

    of the atom in a tiny space. Made up of protons and neutrons.

    Positively charged because of the

    protons.

    Contents

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    Atomic Structure

    Electron configuration

    Summary activities

    Isotopes

    Introducing atoms

    Atomic number and mass number

    Contents

    What is an isotope?

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    What is an isotope?

    Elements consist of one type of atom, but sometimes these

    atoms can be slightly different.

    mass number

    is different

    atomic number

    is the same

    Atoms that differ in this way are called isotopes.

    Although atoms of the same element always have the same

    number of protons, they may have different numbers of

    neutrons.

    Properties of isotopes

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    Properties of isotopes

    The isotopes of an element are virtually identical in their

    chemical reactions.

    The uncharged neutrons make no difference to chemical

    properties but do affect physical properties such as meltingpoint and density.

    Natural samples of elements areoften a mixture of isotopes.

    This is because they have the same number of protons and

    the same number of electrons.

    Isotopes of carbon

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    Isotopes of carbon

    Most naturally-occurring carbon exists as carbon-12, about1% is carbon-13 and a much smaller amount is carbon-14.

    6 protons

    6 neutrons

    7 electrons

    6 protons

    6 neutrons

    8 electrons

    6 protons

    6 neutrons

    6 electrons

    Isotopes of hydrogen

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    Isotopes of hydrogen

    Hydrogen-1 makes up the vast majority of the naturally-

    occurring element but two other isotopes exist.

    hydrogen deuterium tritium

    1 proton

    0 neutrons1 electron

    1 proton

    1 neutron1 electron

    1 proton

    2 neutrons1 electron

    Isotopes of chlorine

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    Isotopes of chlorine

    About 75% of naturally-occurring chlorine is chlorine-35 and

    25% is chlorine-37.

    17 protons

    18 neutrons

    17 electrons

    17 protons

    20 neutrons

    17 electrons

    Isotopes of oxygen

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    What are the

    particle

    numbers ineach isotope?

    10

    8

    8

    8

    8

    8

    oxygen-16 oxygen-18

    protons

    neutrons

    electrons

    Isotopes of oxygen

    Almost all of naturally-occurring oxygen is oxygen-16 but

    about 0.2% is oxygen-18.

    Isotopes and RAM

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    Isotopes and RAM

    Many elements are a mixture of isotopes. The RAM given in

    the periodic table takes account of this.

    For example, chlorine exists as two isotopes:

    chlorine-35 (75%) and chlorine-37 (25%).

    To calculate the RAM of a mixture of isotopes,

    multiply the percentage of each isotope by its

    atomic mass and add them together.

    = (0.75 x 35) + (0.25 x 37)

    = 26.25 + 9.25

    = 35.5

    RAM of chlorine= (75% x 35) + (25% x 37)

    Calculating RAM

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    Calculating RAM

    Bromine contains 50.5% bromine-79 and 49.5% bromine-81.

    = (0.505 x 79) + (0.495 x 81)

    = 39.895 + 40.095= 79.99

    = 80 (the RAM is usually rounded

    to the nearest whole number)

    RAM of bromine= (50.5% x 79) + (49.5% x 81)

    What is the RAM of naturally-occurring bromine?

    Summarizing atomic structure

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    Summarizing atomic structure

    Atomic structure word check

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    Atomic structure word check

    Contents

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    Atomic Structure

    Electron configuration

    Summary activities

    Isotopes

    Introducing atoms

    Atomic number and mass number

    Contents

    Glossary (part 1)

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    Glossary (part 1)

    atomThe smallest particle that can exist on its own.

    atomic numberThe number of protons in the nucleusof an element, also known as the proton number.

    electronNegative particle that orbits the nucleus of anatom.

    elementSubstance made up of only one type of atom.

    isotopesDifferent atoms of the same element. They havethe same number of protons and electrons, but a differentnumber of neutrons.

    Glossary (part 2)

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    Glossary (part 2)

    nucleusThe dense positive centre of an atom, made upof protons and neutrons.

    neutronA neutral particle, with a mass of 1. It is found inthe nucleus of an atom.

    mass numberThe number of protons and neutrons inan atom.

    protonA positive particle, with a mass of 1. It is found inthe nucleus of an atom.

    relative atomic mass (RAM)The mass of anelement compared to the mass of112 of the mass of

    carbon-12.

    Anagrams

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    Anagrams

    Atomic structure word search

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    Atomic structure word search

    Properties of subatomic particles

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    Properties of subatomic particles

    Multiple-choice quiz

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    Multiple choice quiz