know that an iron catalyst is used during the haber process explain the choice of temperature and...

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Conditions of the Haber Process.. • Know that an Iron Catalyst is used during the Haber Process • Explain the choice of temperature and pressure used • Explain the importance of recycling the Nitrogen and Hydrogen

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Conditions of the Haber Process..

• Know that an Iron Catalyst is used during the Haber Process

• Explain the choice of temperature and pressure used

• Explain the importance of recycling the Nitrogen and Hydrogen

N2 + H2 NH3

1. Balance the Equation 2. Name the catalyst missing from the

equation3. Explain how the catalyst affects the

reaction

............

A catalyst will lower the activation energy - hence increases the reaction rate, while

remaining chemically unchanged at the end

of the reaction.

Catalyst No Catalyst

Am

ount

Add

ed

Nitrogen + Hydrogen = Ammonia

Activation Energy with a:

Show instructionsHide instructions

Click on the words to show how they will be

represented on the graph

- Press CONTROL and click on the hole to enlarge it- Press CONTROL + ALT and click on the hole to make it smaller

Read the instructions in the magnifying glass to see how to use the next slide!

The forward reaction is exothermic so if we carry out the reaction at a lower temperature we will get a higher yield of ammonia.

When the temperature is low the reaction is slow, in industry time is money !

A compromise is made with the temperature. To ensure a reasonable yield is collected at a reasonable rate, a reasonably high temperature is used.

The higher the pressure the higher the yield. However, high pressures are expensive and dangerous.

A compromise is made with the pressure. The company will weigh up the cost of the high pressure with the yield produced. This usually means the pressure is between 200 and 350 atm.

On each pass through the process only about 15% conversion occurs, but any unreacted gases are recycled, so that eventually an overall conversion of 98% can be achieved. This is why recycling the gases is so important.

What temperature gives the highest yield

What pressure gives the highest yield

Why use a catalyst?

What does a low

temperature produce

Explain the reasons for using a reasonably high temperature in industry

Explain the reasons for using a pressure between 200 – 350 atm in industry

Why recycle the Nitrogen and Hydrogen?

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Think – Pair share and peer marking could be

used for pupils to obtain their answer

Design an APP for the new PEAR tablet...

FACTORY FANTASIE’S

Manage your own Haber Processing Factory

Choose your upgrades

Get a Porsche for your Bonus

You set the Temperature, Pressure, Workers Pay!

Aim: You choose!

PEAR Show instructionsHide instructions

Click on the green button at the bottom

of the screen

FACTORY FANTASIE’S

Stage One.....

Choose your site...

FACTORY FANTASIE’S

Stage Two.....

Choose your manager... and set the Pay! (be careful, each

manager has their own advantages and disadvantages).

Show instructionsHide instructions

Click Activity Suggestion to gain an

insight into the activity

Click on the left green oval

Click on the right green oval

Activity SuggestionActivity Suggestion

Pupils create a game based on running a factory that allows the gamer to control everything i.e. increase pressure to a very high point allowing them to maximise the yield, however this will be very costly. The bosses can have different methods if they use the example to start them off (for example, one boss could be a risk taker, another very focused on cost, another very focused on the yield and not worried about money). It will be up to the teacher to decide the limitations . There are numerous ways to make the activity varied. After this the pupils can switch their game designs with each other. This is just a suggestion, an example to give the pupils an idea

FACTORY FANTASIE’S

Stage Three.....

Set the Temperature...

FACTORY FANTASIE’S

Stage Four.....

Set the Pressure...

Show instructionsHide instructions

Click lesson idea to gain an insight into the

activity

Click on the left green oval

Click on the right green oval

FACTORY FANTASIE’S

Final Stage...Produce a Report..

How much Ammonia will you make?

How Quickly will you produce the ammonia?

Have you remembered to use a catalyst?

Will your plant be able to run for years to come?

Have you made it too expensive?

What conditions did you choose?

To Summarize

An Iron

catalyst is

used in the

Haber Process

A compromise

is made for the

conditions of

the reaction.

450 and 200 –

350atm.

For an efficient conversion It is very important that the unused Nitrogen

and Hydrogen is recycled back into

the reaction

I can’t wait to get on my Pear Pad when I get home... I will get

the best yield this time?