know: definitions of photon and planck’s constant. energy/mass relationship equation

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Know: Definitions of photon and Planck’s Constant. Energy/mass relationship equation. Only certain energy levels are permitted in atoms. Definitions of: hadron; baryon; meson; lepton; and quark. Understand The manner in which the Photoelectric Effect demonstrates the particle nature of light. The connection between energy and mass and the fact that energy and mass can be converted into one another. An atom may be ionized (lose an electron) if it absorbs a photon with great enough energy. An electron may jump to a higher energy level if it is hit with a photon with the correct energy to make the transition – this causes atoms to ABSORB photons with very specific energies. An electron in an excited state will naturally decay to a lower energy state, releasing a photon with energy equal to the difference in energy between the levels – this causes atoms to EMIT photons with very specific energies. All particles have corresponding anti-particles with equal mass and opposite charge. A baryon is a collection of three quarks. A meson is a pairing of a quark and an anti-quark. Leptons are indivisible and have a charge of -1 or 0. Strong nuclear force holds the nuclei of atoms together and is carried by gluons. Weak nuclear force is involved in beta decay and is carried by bosons. Electromagnetic force governs interactions between atoms; forms molecules; gives matter its shape; and is carried by photons. Gravitational force is not explained by the Standard Model. Be able to Determine the energy of a photon based on its frequency and/or wavelength. Determine a photon’s ‘type’ using the EM Spectrum chart. Use/interpret a graph of photon energy vs. frequency and/or frequency vs. wavelength. Determine the energy contained in a given amount of mass. Convert universal mass units MeV. Use/interpret a graph of energy vs. mass. Determine the energy needed to liberate an electron from an atom. Determine the photon energy needed to make an electron jump to a higher energy level. Determine the photon energy released when an electron drops to a lower energy level. Determine if it is possible for a particular photon to be emitted by a specific energy transition. Determine the number of possible photon energies emitted during a specific set of transitions to a lower energy state. Explain why a hot gas will have a ‘bright line’ emission spectrum. Explain why a cold gas will have a ‘dark line’ absorption spectrum. Determine the charge on a baryon; meson; or lepton. Build a baryon or meson with a specific charge. Explain the relationship between matter and anti-matter. Explain the phenomenon of beta decay.

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Know: Definitions of photon and Planck’s Constant. Energy/mass relationship equation. Only certain energy levels are permitted in atoms. Definitions of: hadron; baryon; meson; lepton; and quark. Understand - PowerPoint PPT Presentation

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Page 1: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Know: • Definitions of photon and Planck’s Constant.• Energy/mass relationship equation. • Only certain energy levels are permitted in atoms. • Definitions of: hadron; baryon; meson; lepton; and quark. Understand • The manner in which the Photoelectric Effect demonstrates the particle nature of light. • The connection between energy and mass and the fact that energy and mass can be converted into one another. • An atom may be ionized (lose an electron) if it absorbs a photon with great enough energy. • An electron may jump to a higher energy level if it is hit with a photon with the correct energy to make the transition – this causes atoms

to ABSORB photons with very specific energies. • An electron in an excited state will naturally decay to a lower energy state, releasing a photon with energy equal to the difference in

energy • between the levels – this causes atoms to EMIT photons with very specific energies. • All particles have corresponding anti-particles with equal mass and opposite charge. • A baryon is a collection of three quarks. • A meson is a pairing of a quark and an anti-quark. • Leptons are indivisible and have a charge of -1 or 0. • Strong nuclear force holds the nuclei of atoms together and is carried by gluons. • Weak nuclear force is involved in beta decay and is carried by bosons. • Electromagnetic force governs interactions between atoms; forms molecules; gives matter its shape; and is carried by photons. • Gravitational force is not explained by the Standard Model.

Be able to • Determine the energy of a photon based on its frequency and/or wavelength. • Determine a photon’s ‘type’ using the EM Spectrum chart. • Use/interpret a graph of photon energy vs. frequency and/or frequency vs. wavelength. • Determine the energy contained in a given amount of mass. • Convert universal mass units MeV. • Use/interpret a graph of energy vs. mass. • Determine the energy needed to liberate an electron from an atom. • Determine the photon energy needed to make an electron jump to a higher energy level. • Determine the photon energy released when an electron drops to a lower energy level. • Determine if it is possible for a particular photon to be emitted by a specific energy transition. • Determine the number of possible photon energies emitted during a specific set of transitions to a lower energy state. • Explain why a hot gas will have a ‘bright line’ emission spectrum. • Explain why a cold gas will have a ‘dark line’ absorption spectrum. • Determine the charge on a baryon; meson; or lepton. • Build a baryon or meson with a specific charge. • Explain the relationship between matter and anti-matter. • Explain the phenomenon of beta decay.

Page 2: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Light as a wave• Light is an electromagnetic wave produced by an oscillating

_______________________. The vibrating charges produce alternating _________________________________which are perpendicular to the direction of the wave’s motion. This waves can travel through vacuum in vast space.

• Light is a wave because

1. Light have wave characteristics such as _________________________________________________

2. Light exhibit wave behavior such as _________________________________________________

• However, the wave model of light can not explain interactions of light with matter

electric charges electric and magnetic fields

amplitude, wavelength, frequency, and velocity.

diffraction, interference, and the Doppler effect.

Page 3: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

An unusual phenomenon was discovered in the early 1900's. If a beam of light is pointed at the negative end of a pair of charged plates, a current flow is measured. A current is simply a flow of electrons in a metal, such as a wire. Thus, the beam of light must be liberating electrons from one metal plate, which are attracted to the other plate by electrostatic forces. This results in a current flow.

An unusual phenomenon was discovered in the early 1900's. Photoelectric_EffectIf a beam of light is pointed at the negative end of a pair of charged plates, a current flow is measured which means the beam of light must be liberating electrons from one metal plate, which are attracted to the other plate by electrostatic forces. However, the observed phenomenon was that the current flow varied strongly with the frequency of light such that there was a sharp cutoff and no current flow for smaller frequencies. Only when the frequency is above a certain point (threshold frequency), the current flow increases with light strength.

Photoelectric Effect

Waves have a particle nature

Page 4: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

exampleWhich graph best represents the relationship between the intensity of light that falls on a photo-emissive surface and the number of photoelectrons that the surface emits? 

1 2 3 4

Page 5: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• When the source of a dim orange light shines on a photosensitive metal, no photoelectrons are ejected from its surface.  What could be done to increase the likelihood of producing photoelectrons?

1. Replace the orange light source with a red light source.

2. Replace the orange light source with a higher frequency light source.

3. Increase the brightness of the orange light source.

4. Increase the angle at which the photons of orange light strike the metal.

example

Page 6: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

A beam of monochromatic light incident on a metal surface causes the emission of photoelectrons.  The length of time that the surface is illuminated by this beam is varied, but the intensity of the beam is kept constant.  Which graph below best represents the relationship between the total number of photoelectrons emitted and the length of time of illumination?

1

2

3

4

example

Page 7: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Einstein explains photoelectric effect• ..\..\RealPlayer Downloads\Photoelectric Effect and Photoelectr

ic Cell.flv

• Einstein successful explained the photoelectric effect within the context of the new physics of the time, quantum physics developed by Max Planck.

• Quantum theory assumes that electromagnetic energy is emitted from and absorbed by matter in discrete amounts of packets. Each packet carries a quantum of energy.

• The quantum, or basic unit, of electromagnetic energy is called a photon. A photon is a mass-less particle of light, it carries a quantum of energy.

Energy: E = h∙f

Page 8: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• since f = c/λ E = h∙f = h∙c/λ • The amount of energy E of each photon is directly proportional to

the frequency f of the electromagnetic radiation, and inversely proportional to the wavelength λ.– E is energy of a photon, in Joules, or eV, – 1 eV = 1.60x10-19 J– h is Planck’s constant, 6.63 x 10-34 J∙s– f is frequency of the photon, in hertz– c is the speed of light in vacuum, c = 3.00x108 m/s– λ is wavelength, in meters

E

f

E

λ

Energy: E = h∙f

Page 9: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• Which characteristic of electromagnetic radiation is directly proportional to the energy of a photon?

1. wavelength

2. period

3. frequency

4. path

Page 10: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Example• The energy of a photon is 2.11 electronvolts

1. Determine the energy of the photon in Joules

2. Determine the frequency of the photon

3. Determine the color of light associated with the photon.

Page 11: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• The slope of a graph of photon energy versus photon frequency represents

1. Planck’s constant

2. the mass of a photon

3. the speed of light

4. the speed of light squared

Page 12: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

The Compton effect: photon-particle collision

• In 1922 Arthur Compton was able to bounce an X-ray photon off an electron.  The result was an electron with more kinetic energy than it started with, and an X-ray with less energy than it started with.  A photon can actually interact with a particle!  A photon has momentum!!  - another proof that photon is a particle.

• During the collision, both energy and momentum are conserved.

Page 13: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

The momentum of a photon• A photon, although mass-less, it has momentum as well as

energy. All photons travel at the speed of light, c. The momentum of photon is

p = h/λ = h∙f/c

Where p is momentum,

h is plank’s constant,

λ is the wavelength

• Momentum p is directly proportional to the frequency light, and inversely proportional to the wavelength.

p = h/λ = h∙f/c E = hc/λ = h∙f

Page 14: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• A photon of light carries

1. energy, but not momentum

2. momentum, but not energy

3. both energy and momentum

4. neither energy nor momentum

Page 15: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• All photons in a vacuum have the same

1. speed

2. wavelength

3. energy

4. frequency

example

Page 16: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• The threshold frequency of a photo emissive surface is 7.1 x 1014 hertz.  Which electromagnetic radiation, incident upon the surface, will produce the greatest amount of current?

1. low-intensity infrared radiation 2. high-intensity infrared radiation 3. low-intensity ultraviolet radiation 4. high-intensity ultraviolet radiation

example

Page 17: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• In conclusion, light has both wave and particle nature.• Wave nature:

– Exhibit wave characteristics: _______________________________________________________

– Exhibit wave behavior:– _______________________________________________

• Particle nature:– ________________________________________

– _________________________________– _________________________________

Page 18: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Particles have wave nature• Just as radiation has both wave and particle characteristics,

matter in motion has wave as well as particle characteristics.

• The wavelengths of the waves associated with the motion of ordinary object is too small to be detected.

• The waves associated with the motion of particles of atomic or subatomic size, such as electrons, can produce diffraction and interference patterns that can be observed.

Page 19: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

All Matters have wave nature• All matters have wave nature. • Louis de Broglie (French physicist and a Nobel laureate

) assumed that any particle--an electron, an atom, a bowling ball, whatever--had a "wavelength" that was equal to Planck's constant divided by its momentum...

λ = h / p

Page 20: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

In summary

• Waves has particle nature, it has momentum just like a particle:

• Particle has wave nature, it has a wavelength just like a wave:

p = h / λ

λ = h / p

Page 21: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

models of an atom1. Describe Thompson’s model

2. Explain the strengths and weaknesses of Rutherford’s model of the atom

3. Describe Bohr model of an atom

4. Describe cloud model

Page 22: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• About 440BC, a Greek scientist named Democritus came up with the idea that eventually, all objects could be reduces to a single particle that could not be reduced any further.He called this particle an atom, from the Greek word atomos which meant “not able to be divided.”From this, the idea of the atom – the basic building block of all matter – was born.

• Around 1700, scientists understanding of molecular composition of matter had grown considerably. They had figured out that elements combine together in specific ratios to form compounds. In 1803, British chemist John Dalton came up with a theory about atoms:– All substances are made of small particles that can’t be created,

divided, or destroyed called atoms. – Atoms of the same element are exactly alike, and atoms of

different elements are different from each other. (So, atoms of gold are exactly like gold atoms, but different than aluminum atoms).

– Atoms join with other atoms to make new substances.

Page 23: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• In 1897, a British scientist named JJ Thomson discovered that electrons are relatively low-mass, negatively charged particles present in atoms.

• Because atoms are neutral, he proposed a model - the "atom" was made of negatively-charged particles (electrons) dispersed among positively-charged particles (protons) like raisins in "plums in a pudding".

• In 1909, British scientist Ernest Rutherford decided to test the Thomson theory, and designed an experiment to examine the parts of an atom.

Page 24: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Rutherford’s model• In his experiment, He fired alpha particles (2 positive charges) beam

at extremely thin gold foil.• He expected alpha particles travel in straight line unaffected because

the net electric force on the alpha particle would be relatively small. • However, he found a small number of particles were scattered at large

angles.• Rutherford explained this phenomenon by assuming the following:

– Most particles were not affected due to the vast empty space inside the atom

– Only a few particles were scattered due to the repulsive force between the concentrated positive charge inside the atom and the particle.

• Rutherford’s model of the atom – most of the mass was concentrated into a compact nucleus

(holding all of the positive charge), with electrons occupying the bulk of the atom's space and orbiting the nucleus at a distance.

Page 25: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• In Rutherford’s model of the atom, electrons orbit the nucleus in a manner similar to planets orbiting the sun.

Page 26: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example• The diagram represents alpha particle A

approaching a gold nucleus.  D is the distance between the path of the alpha particle and the path for a head-on collision. If D is decreased, the angle of deflection θ of the alpha particle would

1. decrease

2. increase

3. remain the same

Page 27: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• Which diagram shows a possible path of an alpha particle as it passes very near the nucleus of a gold atom?

A. 1

B. 2

C. 3

D. 4

example

Page 28: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• In Rutherford's model of the atom, the positive charge

1. is distributed throughout the atom's volume

2. revolves about the nucleus in specific orbits

3. is concentrated at the center of the atom

4. occupies most of the space of the atom

example

Page 29: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Limitation of Rutherford model• According to Rutherford, electrons

accelerate due to centripetal force, and the accelerating charges radiate electromagnetic waves, losing energy. So the radius of electron’s orbit would steadily decrease.

• This model would lead a rapid collapse of the atom as the electron plunged into the nucleus.

Page 30: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

The Bohr Model of the hydrogen atom• Danish physicist Niels Bohr attempted to explain the problems in Rutherford’s

model. He proposed in 1913 that electrons move around the nucleus of an atom in specific paths, on different levels of energy.

1. All forms of energy are quantized.2. The electron in an atom can occupy only

certain specific orbits and no other.3. Electrons can jump from one orbit to another

by emitting or absorbing a quantum of energy in the form of photon.

4. Each allowed orbit in the atom corresponds to a specific energy level. The orbit nearest the nucleus represents the smallest amount of energy that the electron can have. The electron can remain in this orbit with out losing energy even though it is being accelerated.

Page 31: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• When electron is in any particular orbit, it is said to be in a stationary state. Each stationary state represents an energy level. The successive energy levels of an atom are assigned integral numbers, denoted by n=1, 2, 3…

• When the electron is in the lowest level (n=1), it is said to be in the ground state.

• For a hydrogen atom, an electron in any level above the ground state is said to be in an excited state.

Page 32: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• When electron goes up from lower to higher level, the atom absorbs a quantum of energy in the form of a photon.

• When electron goes down from higher to lower level, the atom emits a quantum of energy in the form of a photon.

Page 33: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• If the energy of the photon of light is just right, it will cause the electron to jump to a higher level. 

• When the electron jumps back down, a photon is emitted for each jump down. 

• A photon without the right amount of energy (the pink one) passes through the atom with no effect.

• Photons with too much energy will cause the electron to be ejected which ionizes the atom

Page 34: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Energy levels

• excitation: any process that raises the energy level of electrons in an atom.

• Excitation can be the result of absorbing the energy of colliding particles of matter, such as electrons, or of photons of electromagnetic radiation.

• A photon’s energy is absorbed by an electron in an atom only if the photon’s energy corresponds exactly to an energy-level difference possible for the electron.

• Excitation energies are different for different atoms.

Page 35: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• Atoms rapidly lose the energy of their various excited states as their electrons return to the ground state. This lost energy is in the form of photons of specific frequencies, which appear as the spectrum lines in the characteristic spectrum of each element.

• A spectrum line is a particular frequency of absorbed or emitted energy characteristic of an atom.

Absorption Spectrum

Emission Spectrum

Page 36: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example• White light is passed through a cloud of

cool hydrogen gas and then examined with a spectroscope. What is the cause of dark lines observed on a bright background?

Page 37: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Ionization potential• An atom can absorb sufficient energy to

raise an electron to an energy level such that the electron is removed from the atom’s bound and an ion is formed.

• The energy required to remove an electron from an atom to form an ion is called the atom’s ionization potential.

• An atom in an excited state requires a smaller amount of energy to become an ion than does an atom in the ground state.

Page 38: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Energy level diagram• The energy level of an

electron that has been completely removed from the atom is defined to be 0.00 eV. All other energy levels have negative values.

• The electron in the ground state has the lowest energy, with largest negative value.Ground state

ionization

Page 39: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Ephoton = Einitial - Efinal

• This formula can be used to determine the energy of the photon emitted (+) or absorbed(-).

Ephoton = hf

where h = 6.63 x 10-34 Js

• This formula can be used to determine the energy of a photon if you know the frequency of it.  Planck's constant, h, can be used in terms of Joule(s) or eV(s). (note: the Regents reference table only gives it in terms of  Js)

Page 40: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Energy level is explained by Louis de Broglie’s particle-wave theory

• According to de Broglie, particles have wave nature:

λ = h / p• If we begin to think of electrons as waves, we'll have to change

our whole concept of what an "orbit" is. Instead of having a little particle whizzing around the nucleus in a circular path, we'd have a wave sort of strung out around the whole circle. Now, the only way such a wave could exist is if a whole number of its wavelengths fit exactly around the circle.

• If the circumference is exactly as long as two wavelengths, say, or three or four or five, that's great, but two and a half won't cut it.

Page 41: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

..\..\RealPlayer Downloads\Quantum Mechanics- The Structure Of Atoms.flv

Page 42: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Limitations of Bohr’s model

• It can not predict or explain the electron orbits of elements having many electrons

Page 43: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

The cloud model (Schrödinger model)• In this model, electrons are not confined to specific orbits,

instead, they are spread out in space in a form called an electron cloud.

• The electron cloud is densest in regions where the probability of finding the electron is highest.

The cloud model represents a sort of history of where the electron has probably been and where it is likely to be going. 

Page 44: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example• The term "electron cloud" refers to the

1. electron plasma surrounding a hot wire

2. cathode rays in a gas discharge tube

3. high-probability region for an electron in an atom

4. negatively charged cloud that can produce a lightning strike

Page 45: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Atomic spectra

1. Explain atomic spectra using Bohr’s model of the atom.

2. Recognize that each element has a unique emission and absorption spectrum.

Page 46: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• According to Bohr’s model, electrons in atoms can be found in only certain discrete energy states.

Atomic spectra

Page 47: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Atomic spectra• When electrons jump from the lower to the higher number

orbits, they absorb a particular amount of energy and we can observe the absorption spectrum.

•When they fall back again they release the same amount of energy and we can observe the emission (bright-line) spectrum. The amount of energy absorbed or released in this way can be directly related to the wavelength at which we see the absorption and emission lines on the spectrum.

Page 48: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation
Page 49: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• Each element has a characteristic spectrum that differs from that of every other element.

• The emission spectrum can be used to identify the element, even when the element is mixed with other elements.

Hydrogen spectrum Helium spectrum

Page 50: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Emission (bright-line, atomic) spectra

• When an electron in an atom in an excited state falls to a lower energy level, the energy of the emitted photon is equal to the difference between the energies of the initial and final states.

Ephoton = Ei – Ef = hf

• Ei is the initial energy of the electron in its excited state and Ef is the final energy of the electron in the lower energy level.

Page 51: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• Each energy difference between two energy levels corresponds to a photon having a specific frequency.

• For example: An electron in a hydrogen atom drops from the n = 3 energy level to the n = 2 energy level. The energy of the emitted photon is

Page 52: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

A specific series of frequencies, characteristic of the element, is produced when the electrons of its atoms in excited states fall back to lower states or to the ground state. When these emitted frequencies appear as a series of bright lines against a dark background, they are called a bright-line spectrum or an emission spectrum.

Page 53: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example• An electron in a hydrogen atom drops from the

n = 4 energy level to the n = 2 energy level. The energy of the emitted photon is

Page 54: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• Excited hydrogen atoms are all in the n = 3 state. How many different photon energies could possibly be emitted as these atoms return to the ground state?

A. 1

B. 2

C. 3

D. 4

example

Page 55: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• What is the minimum amount of energy needed to ionize a mercury electron in the c energy level?

Page 56: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

question

• Which electron transition in the hydrogen atom results in the emission of a photon of greatest energy?

1.   n = 2 to n = 1

2.   n = 3 to n = 2

3.   n = 4 to n = 2

4.   n = 5 to n = 3

Page 57: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• An atom can absorb only photons having energies equal to specific differences in its energy levels.

• The frequencies and wavelengths of these absorbed photons are exactly the same as those of the photons emitted when electrons lose energy and fall between the same energy levels.

Absorption spectra

Page 58: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• If the atoms of an element are subjected to white light, which consists of all the visible frequencies, the atoms will selectively absorb the same frequencies that they emit when excited. The absorbed frequencies appear as dark lines in the otherwise continuous white-light spectrum. The series of dark lines is called an absorption spectrum.

absorption Spectrum

Page 59: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

The four-line Balmer series spectrum shown in the diagram is emitted by a hydrogen gas sample in a laboratory.  A star moving away from Earth also emits a hydrogen spectrum.  Which spectrum might be observed on Earth for this star?                                                            

A

B

C

D

Page 60: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• An electron in a mercury atom that is changing from the a to the g level absorbs a photon with an energy of

1. 12.86 eV

2. 10.38 eV

3. 7.90 eV

4. 2.48 eV

Page 61: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• When an electron changes from a higher energy level to a lower energy level within an atom, a quantum of energy is

1. fission

2. fused

3. emitted

4. absorbed

Page 62: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

nucleus

1. Define nuclear force

2. Describe universal mass unit

3. Use mass-energy relationship in calculations

Page 63: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Nuclear force• ..\..\RealPlayer Downloads\Physical Science 7.4c - The Atomic

Nucleus.flv

• The nucleus is the core of an atom made up of one or more protons (except for one of the isotopes of hydrogen) and one or more neutron. The positively charged protons in any nucleus containing more than one proton are separated by a distance of 10-15 m.

• In the nucleus, there are two major forces:

– A large repulsive electric (Coulomb) force between protons

– A very strong attractive nuclear force to keep the protons together.

• It is this nuclear force inside a nucleus that overcomes the repulsive electric force between protons and hold the nucleus together.

Page 64: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Nuclear force has rather unusual properties. 1. It is charge independent. This means that in all pairs

neutron & neutron, proton & proton, and neutron & proton, nuclear forces are the same.

2. at distances 10-13 cm, the nuclear force is attractive and very strong, 100 times stronger than the electromagnetic repulsion. Strongest forces known to exist, nuclear force is also called strong force.

3. the nuclear force very short range force. At distances greater than a few nucleon diameters, the nuclear attraction practically disappears. As the nucleus gets bigger, the attractive nuclear force between the nucleons gets smaller, the nucleus becomes very unstable and starts to break apart, causing radioactive decay.

Page 65: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• Which type of force overcomes the repulsive electrostatic force between protons in the nucleus of an atom?

1. magnetic

2. nuclear

3. gravitational

4. centrifugal

Page 66: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

• The force that holds protons and neutrons together is known as the

1. gravitational force

2. strong force

3. magnetic force

4. electrostatic force

example

Page 67: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• Compared to the gravitational force between two nucleons in an atom of helium, the nuclear force between the nucleons is

1. weaker and has a shorter range

2. weaker and has a longer range

3. stronger and has a shorter range

4. stronger and has a longer range

Page 68: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

Universal mass unit• The universal mass unit, or atomic mass unit, is defined as

1/12 the mass of an atom of carbon-12, which is a carbon atom having 6 protons, 6 neutrons, and 6 electrons.

• In universal mass unit, – the mass of the proton is 1.0073 u, – the mass of the neutron is 1.0087 u, – the mass of an electron is 0.0005 u.

• In SI units, a mass of one universal mass unit,1 u = 1.66 x 10-27 kg.

Page 69: Know:  Definitions of photon and Planck’s Constant. Energy/mass relationship equation

example

• An atomic mass unit is defined as 1/12 the mass of an atom of

1.

2.

3.

4.

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Mass-energy relationship

• Einstein showed that mass and energy are different forms of the same thing and are equivalent.

E = mc2

• E is energy in joules,

• m is mass in kg,

• c is the speed of light in vacuum 3.00x108 m/s

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example• What is the amount of energy in one kilogram of mass?

• Kilogram is very big unit of mass in the reference of mass-energy conversion.

• Universal mass unit (u) is used:

1 u = 9.31 x 102 MeV

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• According to the chart, the energy equivalent of the rest mass of a proton is approximately

1. 9.4 x 102 MeV

2. 1.9 x 103 MeV

3. 9.0 x 1016 MeV

4. 6.4 x 1018 MeV

example

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• Approximately how much energy would be generated if the mass in a nucleus of an atom of were converted to energy? 

• [The mass of is 2.0 atomic mass units.]

1.   3.2 x 10-10 J

2.   1.5 x 10-10 J

3.   9.3 x 102 MeV

4.   1.9 x 103 MeV

example

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question

• Which particle would generate the greatest amount of energy if its entire mass were converted into energy?

1. electron

2. proton

3. alpha particle

4. neutron

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example• How much energy would be generated if a 1.0

x10-3-kilogram mass were completely converted to energy?

1.   9.3 x 10-1  MeV

2.   9.3 x 102  MeV

3.   9.0 x 1013  J

4.   9.0 x 1016  J

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• The graph represents the relationship between mass and its energy equivalent.  The slope of the graph represents

1. the electrostatic constant

2. gravitational field strength

3. the speed of light squared

4. Planck's constant

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example• If a deuterium nucleus has a mass of

1.53 × 10-3 universal mass units less than its components, this mass represents an energy of

1. 1.38 MeV

2. 1.42 MeV

3. 1.53 MeV

4. 3.16 MeV

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example• The light of the "alpha line" in the Balmer

series of the hydrogen spectrum has a wavelength of 6.58 × 10-7 meter. The energy of an "alpha line" photon is approximately

1. 6.63 × 10-34 J

2. 3.0 × 108 J

3. 3.02 × 10-19 J

4. 4.54 × 1013 J

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example• The alpha line in the Balmer series of the hydrogen

spectrum consists of light having a wavelength of 6.56 x 10-7 meter.

1. Calculate the frequency of this light.

2. Determine the energy in joules of a photon of this light.

3. Determine the energy in electronvolts of a photon of this light.

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example• The energy equivalent of the rest mass

of an electron is approximately

1. 5.1 × 105 J

2. 8.2 × 10-14 J

3. 2.7 × 10-22 J

4. 8.5 × 10-28 J

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Nuclear mass and energy• According to Einstein’s mass-energy equation,

any change in energy results in an equivalent change in mass. Mass-energy is conserved at all levels from cosmic to subatomic.

• In chemical reactions, if energy is released, then the total mass must be decreased. If energy is absorbed, then the total mass must be increased. However, the change of mass is too small to be measured.

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• In nuclear reaction, the changes in energy relative to the masses involved are much larger, the corresponding change in mass can be measured.

Example:

• total mass of two protons and two neutrons is 2(1.0073 u + 1.0087 u) = 4.0320 u

• The mass of a helium-4 is 4.0016 u

• The mass of the nucleus is less than its components. This is true for every nucleus, with the exception for hydrogen-1, which has only one nucleon.

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• Nuclear fission is a nuclear reaction in which the nucleus of an atom splits into smaller parts (lighter nuclei). Fission of heavy elements is an exothermic reaction which can release large amounts of energy both as electromagnetic radiation and as kinetic energy of the fragments (heating the bulk material where fission takes place).

• Nuclear fusion is the process by which two or more atomic nuclei join together, or "fuse", to form a single heavier nucleus. This is usually accompanied by the release or absorption of large quantities of energy. The fusion of two nuclei with lower masses than iron (which, along with nickel, has the largest binding energy per nucleon) generally releases energy while the fusion of nuclei heavier than iron absorbs energy

• ..\..\RealPlayer Downloads\Fission And Fusion.flv

Nuclear fission and fusion

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example• If a deuterium nucleus has a mass of 1.53

× 10-3 universal mass units less than its components, this mass represents an energy of _______________ MeV.

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• A tritium nucleus consists of one proton and two neutrons and has a total mass of 3.0170 atomic mass units.  What is the mass defect of the tritium nucleus?

1. 0.0014 u

2. 0.0077 u

3. 1.0010 u

4. 2.0160 u

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Studying atomic nuclei• The structure of the atomic nucleus and the nature of matter

have been investigated using particle accelerators.

• Particle accelerators use electric and magnetic fields to increase the kinetic energies of charged particles, such as electrons and protons, and project them at speeds near the speed of light.

• Collisions between the high speed particles and atomic nuclei may disrupt the nuclei and release new particles.

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The standard model of particle physics - objectives

1. State the standard model of particle physics

2. Describe the fundamental forces in nature

3. Classify subatomic particles

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• The Standard Model of particle physics (formulated in the 1970s) describes the universe in terms of Matter (fermions - 24) and Force (bosons - 4).

• Unlike the force-carrying particles, the matter particles have associated antimatter particles, such as the antielectron (also called positron) and antiquarks. So there are together 24 fermions.

Standard model of particle physics..\..\RealPlayer Downloads\CERN- The Standard Model Of Particle Physics.flv

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The fundamental forces in nature • There are four known forces. Two of these forces are only seen in

atomic nuclei or other subatomic particles. Aside from gravity, all the macroscopically observable forces — such as friction & pressure as well as electrical & magnetic interaction — are due to electromagnetic force.

– Gravitational

– Electromagnetic

– strong nuclear

– Weak nuclear

• ..\..\RealPlayer Downloads\The Weak and Strong Nuclear Forces (9 of 15).flv

• The weak nuclear force is another very short-range nuclear force that causes transformation of protons to neutrons and vice-versa, along with other radioactive (gives off photons and other particles) phenomena.

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force Relative strength

range Force carrier

mass charge

Strongnuclear

1038 ~10-15 m gluon 0 0

Electro-

Magnetic

1036 ~1/r2 photon 0 0

Weak nuclear

1025 10-18 m W boson

W boson

Z boson

80.6 GeV

80.6 GeV

91.2 GeV

+e-e0

gravitational 1 ~1/r2 graviton 0 0

• The Standard Model describe the force between two particles in terms of the exchange of virtual force carrier particles between them.

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GRAVITYGravitation is a force of attraction that acts between each and every particle in the Universe. It is the weakest of the four fundamental forces. It is always attractive, never repulsive. It pulls matter together, causes you to have a weight, apples to fall from trees, keeps the Moon in its orbit around the Earth, the planets confined in their orbits around the Sun, and binds together galaxies in clusters.

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THE ELECTROMAGNETIC FORCE

• The electromagnetic force determines the ways in which electrically charged particles interact with each other and also with magnetic fields. This force can be attractive or repulsive.

• This force holds the atoms together.• This force also governs the emission and

absorption of light and other forms of electromagnetic radiation.

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THE STRONG NUCLEAR FORCE

• The strong nuclear force binds together the protons and neutrons that comprise an atomic nucleus and prevents the mutual repulsion between positively charged protons from causing them to fly apart.

• The strong nuclear force interaction is the underlying source of the vast quantities of energy that are liberated by the nuclear reactions that power the stars.

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THE WEAK NUCLEAR FORCE

• The weak nuclear force causes the radioactive decay of certain particular atomic nuclei. In particular, this force governs the process called beta decay whereby a neutron breaks up spontaneously into a proton, and electron and an antineutrino.

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LONG-RANGE and SHORT-RANGE FORCES

• The strong and weak nuclear interactions are effective only over extremely short distances. The range of strong force is about 10-15 meters and that of the weak force is 10-18 meters.

• In contrast, the electromagnetic and gravitational interactions are long-range forces, their strengths being inversely proportional to the square of distance.

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Force carriers• According to modern quantum theories, the

various fundamental forces are conveyed between real particles by means of virtual particles. The force-carrying particles (which are known as gauge bosons) for each of the forces are as follows: – electromagnetic force - photons; – weak nuclear interaction - very massive 'W' and

'Z' bosons; – strong nuclear interaction - gluons. – gravitation - graviton.

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The fundamental forces

force Relative strength

Range of force

Force carrier mass charge

Strong (nuclear) 1 ~ 10-15m gluon 0 0

electromagnetic 10-2 ~ 1/r2 photon 0 0

weak 10-13 < 10-18m W bosonW bosonZ boson

80.6 GeV 80.6 GeV 91.2 GeV

+e-e0

gravitational 10-38 ~ 1/r2 graviton 0 0

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example

1. Which force is responsible for a neutron decaying into a proton?

2. Which force bonds quarks together into particles like protons and neutrons?

3. Which force governs the motion of an apple falling from a tree?

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4. What are you made of? What forces hold you together?

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Sub-Atomic Particles• Although the Proton, Neutron and Electron

have been considered the fundamental particles of an atom, recent discoveries from experiments in atomic accelerators have shown that there are actually 12 fundamental particles (with 12 antiparticles). Protons and neutrons are no longer considered fundamental particles in this sub-atomic classification.

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Matter

Hadrons (held together by strong

force)

Leptons (no strong Force)

Baryons(3 quarks)Protons and neutrons

Mesons(quark & anitquark)

The fundamental particles are classified into two classes: quarks and leptons

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Hadrons and lepton

• Particles can be classified according to the types of interactions they have with other particles.

• A particle that interacts through the strong nuclear force, as well as the electromagnetic, weak and gravitational forces is called a hadron.

• A particle that interacts through the electromagnetic, weak and gravitational forces, but not the strong nuclear force, is called a lepton.

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• Hadrons group can be subdivided into baryons and mesons.– Baryons are made of three quarks, the

charges on a baryon can be 0, +1, or -1– examples of baryons are neutrons, protons.– The term "baryon" is derived from the Greek

βαρύς (barys), meaning "heavy.“• Mesons are made a quark-antiquark pair,

mesons is a particle of intermediate mass.

Hadrons – baryons & mesons

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• All hadrons are constructed of quarks.

A baryon is made up of 3 quarks, for example:

A proton consists of up, up, down quarks

A neutron consists of up, down, down quarks

When quarks combine to form baryons, their charges add algebraically to a total of 0, +1, -1.

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example

• Baryons may have charges of

1. +1e and + 4/3 e

2. +2e and +3e

3. -1e and +1e

4. -2e and - e

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question

• Protons and neutrons are examples of

1. positrons

2. baryons

3. mesons

4. quarks

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What are the Leptons?• A lepton has a mass much less than that of a

proton, the lepton classification of sub-atomic particles consists of 6 fundamental particles:– Electron – Muon – Tau – Electron Neutrino – Muon Neutrino – Tau Neutrino

• The reference tables give the names, symbols and charges of the six members of the lepton family.

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Electron, Muon and Tau Leptons• The Electron remains a fundamental particle, as

if was in the Atomic Theory. It has an electrical charge of (-1) and plays an active role in chemical reactions.

• The Muon is primarily a result of a high-energy collision in an atomic accelerator. The Muon is similar to an Electron, only heavier.

• The Tau particle is similar to a Muon, only heavier yet.

• Muon and Tau particles are unstable and exist in nature for a very short time.

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Neutrinos• Neutrinos are small and have no electrical

charge. This makes them extremely difficult to detect. They can possess a large amount of energy and the very rare times they do collide with another particle, that energy can be released.

• There are 3 types of neutrinos:– Electron Neutrino, which has no charge and

is extremely difficult to detect – Muon Neutrino, which is created when some

atomic particles decay – Tau Neutrino, which is heavier than the Muon

Neutrino.

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Quarks• Another group of sub-atomic particles are the

Quarks. Just like their name, they exhibit unusual characteristics. There are 6 fundamental particles among the Quarks are:

• Up and Down Quarks • Charm, Strange, Top and Bottom Quarks • Other particles are made up of combination of

Quarks.• The reference table gives the names, symbols,

and charges of the six quarks.

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Up and Down Quarks

• The Up Quark has an electrical charge of (+2/3). The Down Quark has an electrical charge of (-1/3).

• The Proton is made up of  two Up Quarks and one Down Quark. The electrical charge of the proton is then: (+2/3) + (+2/3) + (-1/3) = (+1).

• The Neutron is made up of one Up Quark and two Down Quarks. The resulting electrical charge of the Neutron is: (+2/3) + (-1/3) + (-1/3) = (0).

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Charm, Strange, Top and Bottom Quarks

• The Charm Quark has the same electrical charge as the Up Quark but is heavier. The Top Quark is then heavier than the Charm.

• The Strange Quark has the same electrical charge as the Down Quark but is heavier. The Bottom Quark is heavier than the Strange.

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Particles inmatter

hadrons leptons

baryons mesons

3 quarksquark and antiquark

6 types

6 types of quarks

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antiparticle• An antiparticle is associated with each particle. • An antiparticle is a particle having mass, lifetime,

and spin identical to the associated particle, but with charge of opposite sign (if charged) and magnetic moment reversed in sign. An antiparticle is denoted by a bar over the symbol of the particle.

• Example: p, stands for antiproton, which can be described as a stable baryon carrying a unit negative charge, but having the same mass as a proton.

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• A positron (+e) is a particle whose mass is equal to the mass of the electron and whose positive electric charge is equal in magnitude to the negative charge of the electron.

• Positron is the antiparticle of electron (e). • The antineutron (n) has the same mass as the

neutron and is also electrically neutral. However the magnetic moment and spin of the antineutron are in the same direction, whereas, the magnetic moment and spin of the neutron are in opposite directions.

• Antiparticle for a neutrino is identical to the neutrino except for their direction of spin.

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Fundamentalparticles

Fundamentalparticles

6 6 6 6

quarks antiquarks leptons antileptons

There are total of 24 basic particles

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antimatter

• Antimatter is material consisting of atoms that are composed of antiprotons, antineutrons, and positrons.

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example

• The subatomic particles that make up both protons and neutrons are known as

1. electrons

2. nuclides

3. positrons

4. quarks

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example

• According to the Standard Model, a proton is constructed of two up quarks and one down quark (uud), and a neutron is constructed of one up quark and two down quarks (udd). During beta decay, a neutron decays into a proton, an electron, and an electron antineutrino. During this process there is a conversion of a

1. u quark to a d quark 2. d quark to a meson 3. baryon to another baryon 4. lepton to another lepton

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example

• A lithium atom consists of 3 protons, 4 neutrons, and 3 electrons. This atom contains a total of

1. 9 quarks and 7 leptons

2. 12 quarks and 6 leptons

3. 14 quarks and 3 leptons

4. 21 quarks and 3 leptons

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example

• A top quark has an approximate charge of

1. -1.07 ×10-19 C

2. -2.40 ×10-19 C

3. +1.07 ×10-19 C

4. +2.40 ×10-19 C

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example

• Compared to a proton, an alpha particle has

– Hint: An alpha particle is a helium nucleus.

1. the same mass and twice the charge

2. twice the mass and the same charge

3. twice the mass and four times the charge

4. four times the mass and twice the charge

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example

• What is the charge-to-mass ratio of an electron?

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example• During the process of beta (β-) emission, a neutron in

the nucleus of an atom is converted into a proton, an electron, an electron antineutrino, and energy. 

• neutron  proton + electron + electron antineutrino + energy 

• Based on conservation laws, how does the mass of the neutron compare to the mass of the proton?

1. The mass of the neutron is greater than the mass of the proton.

2. The mass of the proton is greater than the mass of the neutron.

3. The masses of the proton and the neutron are the same.