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Published by The Academy of Chemistry Teachers Thiruvananthapuram, Kerala Website : www.actkerala.org Journal of the Academy of Chemistry Teachers a biannual peer -reviewed research journal of chemistry Vol. 1 (2) ISSN 2395-6801 Dec 2015

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Page 1: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

The Academy of Chemistry TeachersThiruvananthapuram, Kerala

www.actkerala.org

Published by

The Academy of Chemistry TeachersThiruvananthapuram, KeralaWebsite : www.actkerala.org

Journal of theAcademy of Chemistry Teachersa biannual peer -reviewed research journal of chemistry

Vol. 1 (2)

ISSN 2395-6801

Dec 2015

Page 2: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

JOURNAL OF THE ACADEMY OFCHEMISTRY TEACHERS

a biannual peer-reviewed research journal of chemistry

Vol : 1 (2) Dec 2015

Journal of the Academy of Chemistry Teachers (JACT) is a biannual peer-reviewed researchjournal of Chemistry published by the Academy of Chemistry Teachers (ACT), Thiruvananthapuram. It isissued half-yearly (Jan-June & July-Dec). JACT solicits research articles in any branch of Chemistry forpublication. The journal will cover all aspects of Chemistry from Organic and Inorganic Chemistry toPhysical Chemistry, including frontier areas like Computational Chemistry, Combinatorial Chemistry,Green Chemistry and Nanochemistry. JACT will publish short articles of popular interest. Submission ofan article implies that it has not been previously published. We hope JACT will usher in a new era ofambitious and innovative research in various novel fields of chemistry. JACT is intended to become agood journal for chemistry in its broadest sense. Manuscripts may be sent as email attachment to theEditor. All manuscripts are subject to peer-review and copy-editing.

Editor:Dr Reena RavindranAssociate Professor of Chemistry,Sree Narayana College, ChempazhanthyEmail: [email protected] Mob : 9349321464

Editorial Board:Dr. Sophia K.PhilipAssociate Professor of Chemistry, Christian College,Chenganoor. Email : [email protected]

Dr. R. Sudha DeviAssociate Professor of Chemistry M.G College, ThiruvananthapuramEmail : [email protected]

Dr. Suma. SAssociate Professor of ChemistrySree Narayana College, Chempazhanthy, ThiruvananthapuramEmail : [email protected]

Dr. Noeline B. FernandezAssistant Professor of Chemistry, Fatima Mata National College, KollamEmail : [email protected]

Dr.Radhika R. NathAssistant Professor of Chemistry, DB college Sasthamkottah, KollamEmail : [email protected]

Annual Subscription Fee Rs. 300/-

Page 3: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

ADVISORY COMMITTEE

Prof. George K ThomasDean (Academic Affairs)IISER, Thiruvananthapuram

Dr. Mangalam S. NairChief ScientistCSIR-NIIST, Thiruvananthapuram

Dr. K. N. RajasekharanEmeritus ProfessorDepartment of ChemistryUniversity of Kerala, KariavattomThiruvananthapuram

Dr. Suresh MathewProfessor & DirectorSchool of Chemical SciencesMahatma Gandhi UniversityKottayam

Dr. M. R. Prathapachandra KurupProfessorDepartment of Applied ChemistryCochin University of Science & TechnologyKochi.

Prof. K.K. Aravindakshan Professor (Retd),Department of ChemistryUniversity of Calicut

Dr. K Anoop KrishnanScientist CNational Centre for Earth Science StudiesAkkulam, Thiruvananthapuram.

Dr SMA ShibliProfessor & Head Department of ChemistryUniversity of Kerala

Dr T.S AnirudhanProfessorDepartment of ChemistryUniversity of Kerala.

Page 4: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

CONTENTS

1. Spiroborate Esters of Diols- A ReviewJeena John, Sudha Devi R & Balachandran S .............................................. 1

2. Vibrational Spectroscopic Studies and Computational Calculations of Acetone-N(4) - PhenylsemicarbazoneV.L. Siji, M.R. Sudarsanakumar, S. Suma & Abraham George .................. 9

3. Effect of MgO Doping on the Lattice of Beta-Tricalciumphosphate (Beta-TCP)Rahul Sasidharan Pillai & Vincenzo M. Sglavo ............................................ 16

4. Removal of a Cationic Dye from Aqueous Solutions Using Polymer GraftedCellulose - A Green Chemistry ApproachNoeline B. Fernandez, Manohar D. Mullassery & Surya R. ................................. 22

5. A Brief Review of Proton Transfer Salts and their ComplexesShiji Fazil & Reena Ravindran ...................................................................... 31

6. Antimicrobial Study of 1H-2,2-Dimethyl-3H-Phenothiazin-4[10H]-one and itsZn(II) and Cd(II) ComplexesR. Minitha & Reena Ravindran ..................................................................... 36

7. Transition Metal Complexes of Schiff Base Ligand - Bonding Aspects andBiological ApplicationS. Renjusha & Shyama Nair ........................................................................... 40

Page 5: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

INSTRUCTIONS TO CONTRIBUTORS

Submission of PapersAll manuscripts should be submitted electronically toEmail: [email protected]

Manuscript PreparationGeneral: Manuscripts must be in double-spaced form. A font size of12 pt is required. The corresponding author should be identified(include a Full postal address, E-mail address).

Paper Length: Research papers should not exceed 8 printed pagesincluding text, references, figures and tables. The number of figuresand/or tables should not exceed five. Every page of the manuscript,including the title page, references, tables, etc should be numbered.

Abstracts: Abstracts should not exceed 100 words, and should notcontain any references.

Keywords: 4-6 keywords must be included on a separate line belowthe main abstract and labelled’ Keywords’.

Text: Follow this order when composing manuscripts: Title, Authors,Affiliations, Abstract, Keywords, Text, References, Figure Captions,Figures and then Tables. Do not import the Figures or Tables intoyour text. The corresponding author should be identified with anasterisk and footnote.

References: References should be given as shown below; 1. Love JC, Estroff LA, Kriebel JK, Nuzzo RG & Whitesides GM,Chem Rev; 105 2005, 1103-1169.

Processing Charge : Rs. 1000 per accepted article (maximum of8 printed pages). Rs. 100 for each additional page, if any. Extraamount will be charged for colour print.

Page 6: Journal of the Academy of Chemistry Teachersactkerala.org/journal/2015-2.pdfJOURNAL OF THE ACADEMY OF CHEMISTRY TEACHERS a biannual peer-reviewed research journal of chemistry Vol

Statement of Ownership and other particulars aboutJournal of the Academy of Chemistry Teachers

a biannual peer-reviewed research journal of chemistry

Form IV (See Rule 8)

1. Place of Publication : Thiruvananthapuram

2. Periodicity of Publication : Biannual

3. Publisher’s Name : Dr.S.BalachandranNationality & Address (General Secretary, ACT)

& Associate Professor ofChemistry M.G College,ThiruvananthapuramEmail : [email protected]

4. Printer’s Name, Nationality Dr.S.Balachandran& Address : (General Secretary, ACT)

& Associate Professor ofChemistry, M.G College,Thiruvananthapuram

6. Name(s) of the printing press(es) : Sri.N Gopalakrishnanwhere printing is conducted and Tandem Reprographicspremises on which the Statue-Gen.Hospital Road, Statuepress is/are installed Thiruvananthapuram-695 001

7. Editor’s Name, Nationality Dr Reena Ravindran& Address : (Vice President, ACT)

Associate Professor of ChemistrySree Narayana CollegeChempazhanthy,Thiruvananthapuram.

8. Name and address of the : Dr.S.Balachandranindividuals who own the Associate Professor of Chemistryjournal and partners or M.G College, Thiruvananthapuramshareholders holding morethan one percent of thetotal capital

For private circulation onlyI Dr.S.Balachandran, Associate Professor of Chemistry, MG College,

Thiruvananthapuram, do hereby declare that the particular given above are true to thebest of my belief.

Sd/-Dr.S. Balachandran