jillian janssen 15:37:04 -08'00' · 2020. 2. 29. · f102b_srfpm_20190325 5hylvhg 5hsruw...

Jillian Janssen 2019.09.06 15:37:04 -08'00'

e-Sample Receipt Form

If samples received without a temperature blank, the "cooler temperature" will be documented instead & "COOLER TEMP" will be noted to the right. "ambient" or "chilled" will

be noted if neither is available.

Holding Time / Documentation / Sample Condition Requirements

°C

Yes

@

If <0°C, were sample containers ice free?

Yes

***Note: If sample information on containers differs from COC, SGS will default to COC information.

Yes

Were samples received within holding time?

*If >6°C, were samples collected <8 hours ago?

Were proper containers (type/mass/volume/preservative***)used?

Additional notes (if applicable):

Note to Client: Any "No", answer above indicates non-compliance with standard procedures and may impact data quality.

Do samples match COC** (i.e.,sample IDs,dates/times collected)?

N/AWere Trip Blanks (i.e., VOAs, LL-Hg) in cooler with samples?Were all water VOA vials free of headspace (i.e., bubbles ≤ 6mm)?

N/A

N/A

Note: Refer to form F-083 "Sample Guide" for specific holding times.

Volatile / LL-Hg Requirements

Were all soil VOAs field extracted with MeOH+BFB? N/A

Yes

Were analytical requests clear? (i.e., method is specified for analyses with multiple option for analysis (Ex: BTEX, Metals)

N/A

Therm. ID:

Yes

**Note: If times differ <1hr, record details & login per COC.

Cooler ID:

Cooler ID:

Therm. ID:

°CTherm. ID:

Cooler ID:

Note: Identify containers received at non-compliant temperature . Use form FS-0029 if more space is needed.

**Exemption permitted if chilled & collected <8 hours ago, or for samples where chilling is not required1 @

N/A

HD

Exceptions Noted below

Ambient

Were Custody Seals intact? Note # & location

Cooler ID:

N/AChain of Custody / Temperature Requirements

Temperature blank compliant* (i.e., 0-6 °C after CF)?

@

***Exemption permitted for metals (e.g,200.8/6020A).

Therm. ID:

°C

@ Therm. ID:

Cooler ID:

DOD: Were samples received in COC corresponding coolers?

@

N/A °CYes

°C

SGS Workorder #: 1194022 1194022Exemption permitted if sampler hand carries/delivers.Yes

Yes

Condition (Yes, No, N/A)Review Criteria

COC accompanied samples?

F102b_SRFpm_20190325

09/06/19

Technical Report for

SGS North America, Inc1194022

SGS Job Number: FA67037

Sampling Date: 07/23/19

Report to:

[email protected]

Total number of pages in report:

Certifications: FL(E83510), LA(03051), KS(E-10327), IL(200063), NC(573), NJ(FL002), NY(12022), SC(96038001)DoD ELAP(ANAB L2229), AZ(AZ0806), CA(2937), TX(T104704404), PA(68-03573), VA(460177),AK, AR, IA, KY, MA, MS, ND, NH, NV, OK, OR, UT, WA, WVThis report shall not be reproduced, except in its entirety, without the written approval of SGS.Test results relate only to samples analyzed.

SGS North America Inc. • 4405 Vineland Road • Suite C-15 • Orlando, FL 32811 • tel: 407-425-6700 • fax: 407-425-0707

Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable.

Client Service contact: Andrea Colby 407-425-6700

Caitlin Brice, M.S.General Manager

Orlando, FL 09/06/19

e-Hardcopy 2.0Automated Report

16

SGS is the sole authority for authorizing edits or modifications to this document.Unauthorized modification of this report is strictly prohibited.Review standard terms at: http://www.sgs.com/en/terms-and-conditions

The results set forth herein are provided by SGS North America Inc.

Please share your ideas abouthow we can serve you better at:[email protected]

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FA67037

Table of Contents-1-

Sections:

Section 1: Sample Summary ................................................................................................... 3Section 2: Case Narrative/Conformance Summary .............................................................. 4Section 3: Summary of Hits .................................................................................................... 5Section 4: Sample Results ........................................................................................................ 6

4.1: FA67037-1: TAP/31901314001 ............................................................... 7Section 5: Misc. Forms ............................................................................................................ 8

5.1: Chain of Custody ........................................................................................................... 9Section 6: MS Semi-volatiles - QC Data Summaries ............................................................ 13

6.1: Method Blank Summary ................................................................................................ 146.2: Blank Spike Summary ................................................................................................... 156.3: Matrix Spike/Matrix Spike Duplicate Summary ........................................................... 16

12

34

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Sample Summary

SGS North America, IncJob No:: FA67037

1194022

Sample Collected Matr ix ClientNumber Date Time By Received Code Type Sample ID

This report contains results reported as ND = Not detected. The following applies:Organics ND = Not detected above the RL

FA67037-1 07/23/19 11:18 07/26/19 DW Drinking Water CLITHROE TAP/31901314001

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SAMPLE DELIVERY GROUP CASE NARRATIVE

Client: SGS North America, Inc Job No: FA67037

Site: 1194022 Report Date 8/21/2019 11:02:35

1 Sample was collected on 07/23/2019 and were received at SGS North America Inc - Orlando on 07/26/2019 properly preserved and intact. This Sample received an SGS Orlando job number of FA67037. A listing of the Laboratory Sample ID, Client Sample ID and dates of collection are presented in the Results Summary Section. Except as noted below, all method specified calibrations and quality control performance criteria were met for this job. For more information, please refer to QC summary pages.

MS Semi-volatiles By Method EPA 537.1 REV 1.0 Matrix: DW Batch ID: OP76397

All samples were extracted within the recommended method holding time. All samples were analyzed within the recommended method holding time. Sample(s) FA67040-1MS, FA67040-1MSD were used as the QC samples indicated. All method blanks for this batch meet method specific criteria.

SGS Orlando certifies that this report meets the project requirements for analytical data produced for the samples as received at SGS Orlando and as stated on the COC. SGS Orlando certifies that the data meets the Data Quality Objectives for precision, accuracy and completeness as specified in the SGS Orlando Quality Manual except as noted above. This report is to be used in its entirety. SGS Orlando is not responsible for any assumptions of data quality if partial data packages are used. Narrative prepared by: ______________________________________ Ariel Hartney, Client Services (Signature on File)

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Summary of Hits Page 1 of 1Job Number: FA67037Account: SGS North America, IncProject: 1194022Collected: 07/23/19

Lab Sample ID Client Sample ID Result/Analyte Qual RL MDL Units Method

FA67037-1 CLITHROE TAP/31901314001

Perfluorohexanoic acid 0.0167 0.0019 ug/l EPA 537.1 REV 1.0Perfluoroheptanoic acid 0.00373 0.0019 ug/l EPA 537.1 REV 1.0Perfluorooctanoic acid 0.00613 0.0019 ug/l EPA 537.1 REV 1.0Perfluorobutanesulfonic acid a 0.00406 0.0019 ug/l EPA 537.1 REV 1.0Perfluorohexanesulfonic acid 0.00488 0.0019 ug/l EPA 537.1 REV 1.0

(a) Associated BS recovery outside control limits.

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Sample Results

Report of Analysis

Orlando, FLSection 4

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Report of Analysis Page 1 of 1

Client Sample ID: CLITHROE TAP/31901314001 Lab Sample ID: FA67037-1 Date Sampled: 07/23/19Matrix: DW - Drinking Water Date Received: 07/26/19Method: EPA 537.1 REV 1.0 EPA 537 Percent Solids: n/aProject: 1194022

File ID DF Analyzed By Prep Date Prep Batch Analytical BatchRun #1 Q62496.D 1 08/16/19 05:45 MV 08/05/19 15:40 OP76397 SQ1414Run #2

Initial Volume Final VolumeRun #1 270 ml 1.0 mlRun #2

Perfluorinated Alkyl Acids

CAS No. Compound Result MCL RL Units Q

PERFLUOROALKYLCARBOXYLIC ACIDS307-24-4 Perfluorohexanoic acid 0.0167 0.0019 ug/l375-85-9 Perfluoroheptanoic acid 0.00373 0.0019 ug/l335-67-1 Perfluorooctanoic acid 0.00613 0.0019 ug/l375-95-1 Perfluorononanoic acid ND 0.0019 ug/l335-76-2 Perfluorodecanoic acid ND 0.0019 ug/l2058-94-8 Perfluoroundecanoic acid ND 0.0037 ug/l307-55-1 Perfluorododecanoic acid ND 0.0037 ug/l72629-94-8 Perfluorotridecanoic acid ND 0.0037 ug/l376-06-7 Perfluorotetradecanoic acid ND 0.0037 ug/l

PERFLUOROALKYLSULFONATES375-73-5 Perfluorobutanesulfonic acid a 0.00406 0.0019 ug/l355-46-4 Perfluorohexanesulfonic acid 0.00488 0.0019 ug/l1763-23-1 Perfluorooctanesulfonic acid ND 0.0019 ug/l

PERFLUOROOCTANESULFONAMIDOACETIC ACIDS2355-31-9 MeFOSAA ND 0.0074 ug/l2991-50-6 EtFOSAA ND 0.0074 ug/l

CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits

13C2-PFHxA 90% 70-130%13C2-PFDA 111% 70-130%d5-EtFOSAA 98% 70-130%

(a) Associated BS recovery outside control limits.

ND = Not detected J = Indicates an estimated valueMCL = Maximum Contamination Level (40 CFR 141) B = Indicates analyte found in associated method blankE = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound

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Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable:

• Chain of Custody


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FA67037: Chain of CustodyPage 1 of 4

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MS Semi-volatiles

QC Data Summaries

Includes the following where applicable:

• Method Blank Summaries• Blank Spike Summaries• Matrix Spike and Duplicate Summaries


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Method Blank Summary Page 1 of 1Job Number: FA67037Account: SGSAKA SGS North America, IncProject: 1194022

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP76397-MB Q62492.D 1 08/16/19 MV 08/05/19 OP76397 SQ1414

The QC reported here applies to the following samples: Method: EPA 537.1 REV 1.0

FA67037-1

CAS No. Compound Result RL Units Q

307-24-4 Perfluorohexanoic acid ND 0.0020 ug/l375-85-9 Perfluoroheptanoic acid ND 0.0020 ug/l335-67-1 Perfluorooctanoic acid ND 0.0020 ug/l375-95-1 Perfluorononanoic acid ND 0.0020 ug/l335-76-2 Perfluorodecanoic acid ND 0.0020 ug/l2058-94-8 Perfluoroundecanoic acid ND 0.0040 ug/l307-55-1 Perfluorododecanoic acid ND 0.0040 ug/l72629-94-8 Perfluorotridecanoic acid ND 0.0040 ug/l376-06-7 Perfluorotetradecanoic acid ND 0.0040 ug/l375-73-5 Perfluorobutanesulfonic acid ND 0.0020 ug/l355-46-4 Perfluorohexanesulfonic acid ND 0.0020 ug/l1763-23-1 Perfluorooctanesulfonic acid ND 0.0020 ug/l2355-31-9 MeFOSAA ND 0.0080 ug/l2991-50-6 EtFOSAA ND 0.0080 ug/l

CAS No. Surrogate Recoveries Limits


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Blank Spike Summary Page 1 of 1Job Number: FA67037Account: SGSAKA SGS North America, IncProject: 1194022

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP76397-BS Q62491.D 1 08/16/19 MV 08/05/19 OP76397 SQ1414


FA67037-1

Spike BSP BSPCAS No. Compound ug/l ug/l % Limits

307-24-4 Perfluorohexanoic acid 0.1 0.0918 92 70-130375-85-9 Perfluoroheptanoic acid 0.1 0.0963 96 70-130335-67-1 Perfluorooctanoic acid 0.1 0.0907 91 70-130375-95-1 Perfluorononanoic acid 0.1 0.0914 91 70-130335-76-2 Perfluorodecanoic acid 0.1 0.0868 87 70-1302058-94-8 Perfluoroundecanoic acid 0.1 0.0912 91 70-130307-55-1 Perfluorododecanoic acid 0.1 0.0849 85 70-13072629-94-8 Perfluorotridecanoic acid 0.1 0.0934 93 70-130376-06-7 Perfluorotetradecanoic acid 0.1 0.0784 78 70-130375-73-5 Perfluorobutanesulfonic acid 0.1 0.0684 68* a 70-130355-46-4 Perfluorohexanesulfonic acid 0.1 0.0757 76 70-1301763-23-1 Perfluorooctanesulfonic acid 0.1 0.0854 85 70-1302355-31-9 MeFOSAA 0.1 0.0864 86 70-1302991-50-6 EtFOSAA 0.1 0.0814 81 70-130

CAS No. Surrogate Recoveries BSP Limits


(a) Outside control limits.

* = Outside of Control Limits.

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Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1Job Number: FA67037Account: SGSAKA SGS North America, IncProject: 1194022

Sample File ID DF Analyzed By Prep Date Prep Batch Analytical BatchOP76397-MS Q62499.D 1 08/16/19 MV 08/05/19 OP76397 SQ1414OP76397-MSD Q62500.D 1 08/16/19 MV 08/05/19 OP76397 SQ1414FA67040-1 Q62498.D 1 08/16/19 MV 08/05/19 OP76397 SQ1414


FA67037-1

FA67040-1 Spike MS MS Spike MSD MSD LimitsCAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD

307-24-4 Perfluorohexanoic acid ND 0.106 0.102 96 0.102 0.101 99 1 70-130/30375-85-9 Perfluoroheptanoic acid ND 0.106 0.106 100 0.102 0.102 100 4 70-130/30335-67-1 Perfluorooctanoic acid ND 0.106 0.0986 93 0.102 0.0969 95 2 70-130/30375-95-1 Perfluorononanoic acid ND 0.106 0.0994 93 0.102 0.0939 92 6 70-130/30335-76-2 Perfluorodecanoic acid ND 0.106 0.0965 91 0.102 0.0976 96 1 70-130/302058-94-8 Perfluoroundecanoic acid ND 0.106 0.104 98 0.102 0.102 100 2 70-130/30307-55-1 Perfluorododecanoic acid ND 0.106 0.0959 90 0.102 0.0963 94 0 70-130/3072629-94-8 Perfluorotridecanoic acid ND 0.106 0.100 94 0.102 0.0993 97 1 70-130/30376-06-7 Perfluorotetradecanoic acid ND 0.106 0.0848 80 0.102 0.0837 82 1 70-130/30375-73-5 Perfluorobutanesulfonic acid ND 0.106 0.0725 68* 0.102 0.0671 66* 8 70-130/30355-46-4 Perfluorohexanesulfonic acid ND 0.106 0.0787 74 0.102 0.0776 76 1 70-130/301763-23-1 Perfluorooctanesulfonic acid ND 0.106 0.0920 86 0.102 0.0961 94 4 70-130/302355-31-9 MeFOSAA ND 0.106 0.0968 91 0.102 0.0982 96 1 70-130/302991-50-6 EtFOSAA ND 0.106 0.0905 85 0.102 0.0937 92 3 70-130/30

CAS No. Surrogate Recoveries MS MSD FA67040-1 Limits

13C2-PFHxA 111% 113% 103% 70-130%13C2-PFDA 107% 110% 117% 70-130%d5-EtFOSAA 105% 116% 94% 70-130%

* = Outside of Control Limits.

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