isco with enhanced fracture network battelle 2014 - uppal
TRANSCRIPT
ISCO of TCE-Impacted Groundwater in Bedrock through an Enhanced
Fracture Network
Authors: Omer J. Uppal, Brian Blum, Kyle Warren,
Erica Sterzinar, and Annie Lee
PRESENTATION OUTLINE
• Site Background • COCs, geology/hydrogeology, remedial objective
previous ISCO remedial actions/timeline
• ISCO Implementation - 2011 • Enhanced Fracture Network
• Permanganate Injections
• Post-Remediation Results
• Next Steps • Technical Impracticability
SITE BACKGROUND
• 200 Acre Industrial R&D Facility Since the 1940s
• Trichloroethene (TCE) plume identified in the early 1980s
• The plume occupies an area of approximately 3 million square feet.
• ISRA triggered in 1996
Intermediate Zone TCE Plume
SOURCE ZONE “B”
SOURCE ZONE “A”
SITE GEOLOGY
• Four stratigraphic units
• Glacial Till
• Saprolite
• Columnar Basalt – Target Formation
• Feltville Formation
• Vertical faults and columnar nature of joints likely facilitated vertical migration of contaminants.
• Poorly connected fractures form a complex network with low hydraulic connectivity.
PREVIOUS REMEDIAL ACTIVITIES
• DNAPL Source Zone Pilot Tests
• Implementation of SVE Pilot Test – 2003
• Implementation of ISCO Pilot Test – 2003
• Blast fracture trenches
installation – 2006
• 51,024 gallons (31,320 lbs.) 2.5% Potassium Permanganate & 10% Sodium Permanganate Solution injected from 2003 to 2009
NOVEMBER 2005
JANUARY 2008
INTERMEDIATE ZONE TCE PLUME
REMEDIAL ACTIVITIES
• 9 Blast fracture trenches totaling approximately 21,400 linear feet were installed on site to facilitate chemical oxidant injections
• 327 blast and injection boreholes
SEPTEMBER 2011
JANUARY 2008
INTERMEDIATE ZONE TCE PLUME
ISCO INJECTION - 2011
• Additional Injections October through November 2011
• The objective was to mitigate the residual “source” of TCE groundwater plume with concentrations greater than 1,000 ppb.
INTERMEDIATE ZONE TCE PLUME
SEPTEMBER 2011
ISCO INJECTION - 2011
• 43,200 gallons (9,151 lbs.) 2.5% Potassium Permanganate solution injected into 32 intermediate injection wells and 8 deep injection wells
• Hydraulic fracturing
• Injection pressures were up to 100 PSI.
ISCO INJECTION - 2011
• Techniques used to facilitate oxidant delivery
• Specially designed oxidant distribution manifolds
• High pressure wellhead assemblies
• Overnight gravity feed injection scheme
BEDROCK INJECTION STRATEGY
• Six deep injection wells and 1 Intermediate injection well were hydro-fractured to facilitate chemical oxidant injections.
• Overnight gravity feed to facilitate improved injection rates.
• The project scope was finished several weeks ahead of schedule and under budget due to these aggressive injection strategies.
ISCO ACTIVITIES
TOTAL OF ALL ISCO ACTIVITIES
Potassium
Permanganate
(lbs)
Sodium
Permanganate
(KMnO4 equiv lbs)1
10% Modified
Fenton's Reagent
(gallons)
Pilot Test
October 2003 to December 2003 4,320 -- --
Interim Remedial Measure
June 2006 to November 2007 5,870 18,480 1,270
DNAPL Entry Zone Oxidant Placement
October 2007 1,600 200 --
Supplemental Injections
October to November 2009 850 -- --
Additional Injections
October to November 2011 9,150 -- --
Totals 21,790 18,680 1,270
GRAND TOTAL 40,470 pounds
• Reduction in size of groundwater plume • 71% reduction in intermediate bedrock zone
• 21% reduction in deep 1 bedrock zone
• Reduction in average TCE concentrations by 88%
• Limited additional ISCO injection planned for the intermediate zone in 2014
• Remaining TCE concentrations are expected to decrease over time
REMEDIAL ACTION RESULTS
TECHNICAL IMPRACTABILITY WAIVER
• Groundwater contamination depth extends up to 585 feet bgs.
• Fracture diameter, spacing, orientation, vertical extent, and connectivity within and between formations cannot be accurately determined.
• Dissolved TCE contamination has diffused into interstitial spaces, dead-end fractures and solution voids along contaminated fracture flow paths.
• Approximately 1.6 million square feet of the plume underlies a developed residential area.
• Limitations of subsurface remediation technologies