is 1486 (1978): specification for copper oxychloride, technicalis:1486-1978 ( continued from page i...

18
Disclosure to Promote the Right To Information Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public. इंटरनेट मानक !ान $ एक न’ भारत का +नम-णSatyanarayan Gangaram Pitroda “Invent a New India Using Knowledge” प0रा1 को छोड न’ 5 तरफJawaharlal Nehru “Step Out From the Old to the New” जान1 का अ+धकार, जी1 का अ+धकारMazdoor Kisan Shakti Sangathan “The Right to Information, The Right to Live” !ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता ह Bharthari—Nītiśatakam “Knowledge is such a treasure which cannot be stolen” IS 1486 (1978): Specification for Copper Oxychloride, Technical [FAD 1: Pesticides and Pesticides Residue Analysis]

Upload: others

Post on 25-Feb-2021

7 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

Disclosure to Promote the Right To Information

Whereas the Parliament of India has set out to provide a practical regime of right to information for citizens to secure access to information under the control of public authorities, in order to promote transparency and accountability in the working of every public authority, and whereas the attached publication of the Bureau of Indian Standards is of particular interest to the public, particularly disadvantaged communities and those engaged in the pursuit of education and knowledge, the attached public safety standard is made available to promote the timely dissemination of this information in an accurate manner to the public.

इंटरनेट मानक

“!ान $ एक न' भारत का +नम-ण”Satyanarayan Gangaram Pitroda

“Invent a New India Using Knowledge”

“प0रा1 को छोड न' 5 तरफ”Jawaharlal Nehru

“Step Out From the Old to the New”

“जान1 का अ+धकार, जी1 का अ+धकार”Mazdoor Kisan Shakti Sangathan

“The Right to Information, The Right to Live”

“!ान एक ऐसा खजाना > जो कभी च0राया नहB जा सकता है”Bhartṛhari—Nītiśatakam

“Knowledge is such a treasure which cannot be stolen”

“Invent a New India Using Knowledge”

है”ह”ह

IS 1486 (1978): Specification for Copper Oxychloride,Technical [FAD 1: Pesticides and Pesticides ResidueAnalysis]

Page 2: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee
Page 3: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee
Page 4: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

Gr4

IS : 1486 • 1978

Indian StandardSPECIFICAnON FOR

COPPER OXYCHLORIDE, TECHNICAL

(Second Revision)

Second Reprint MAY 1990

UDC 632.952:661.856.322

@ Copyright 1978

BUREAU OF INDIAN STANDARDSMANAK BHAVAN, 9 BAHADUR SHAH ZAFARMARG

NEW DELHI 110002

November 1978

(Reaffirmed 2012)

Page 5: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS 1486· 1978

Indian StandardSPECIFICATION FOR

COPPER OXYCHLORIDE, TECHNICAL

( Second Revision)

Pest Control Sectional Committee, AFCDC 6

Chairman

Dll S. N. BAN~llJEE

Representing

Directorate of Plant Prore-ct ion . Quarantine &Storage ( Minisrry 01" Agriculture & Irrigarion ),Farida bad

DR N. K. BAsu

DR N. S. AG.UtWAL

DR S. R. BAROOAH

Pesticides Association of India, New DelhiCentral Forensic Science Laboratory, Central

Bureau of Investigation, New DelhiPesticides Formulators Association of India

( S. S. I. ), BombayAlkali & Chemical Corporation of India Limited,

CalcuttaDR T. V. RAGRURAMAN ( Alternate)

Du A. K. BH."l'NAGAR Hindustan Insecticides Limited, New DelhiSHm C. C. A1lllAHAM ( Alternate)

SHRI V. G. DESHPANIJE Ciba-Geigy of India Limited, Bombay.SnRI E. A. ALMEIDA ( Alternate)

SHRI O. P. DIIAMI.TA Export Inspection Council of India, New DelhiSHIll P. K. CUATTEllJEE ( Alternate)

DR M. S. DHATT National Malaria Eradication Programme, DelhiDmECTOIl GENEllAL ARMED Directorate General of Armed Forces Medical

FORCES MEDICAL SF.IWICES Services ( Ministry of Defence ), New DelhiRr.:.<\R-ADM: M. S. MAf,HOTRA ( Alternate)

DIRECTOR OF AGRICULTURE Department of Agriculture, Government of UttarPradesh, Lucknow

Minisrrv of Agriculture & In igation ( Departmentof Food ), New Delhi

DR K. KRISHNAMUltTHY ( Alternate)DR P. N. AGAltWAL Ministry of Defence ( R&D)

DR N. P. RAO ( Alternate)SHRI H. S. BAHLDR H. L. BAM!

DF.PUTY DIREc'roR (PLANTPROTECTION) ( Alternate)

( Continued on page 2 )

© Copyright 1978

: BUREAU OF INDIAN STANDARDSThis publication is protected under the Indian Copyright Act (XIV of 1957) andreproduction in whole or in part by any means except with written permission of thepublisher shall be deemed to be an infringement of copyright under the said Act.

Page 6: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS: 1486 -1978

( Continued from page I )

Members

Dnnos CONTnOI,J.1m ( INDIA )

Representing

Indian Pharmacopoeia Committee (MinistryHealth & Family Welfare ), New Delhi

of

Snnr M. RAVIKANT ( Alternate)SnRI G, D. GOKJlALE Bombay Chemicals Private Limited, Bombay

SHIH V, V. KETKAR ( Alternate)JOINT DlRECTOlt OF AUHICUL'l'UHE Department of Agriculture, Government of

( DEVELOBlEN1' & ICP) Karnataka, MysoreDEPUTY DIRECTOIt 0"1' AURI-

'CULT1JIU; ( PLANT PROTEC-'I'ION ) ( Alternate)

DR R, L. KAI,RA Punjab Agriculrural University, LudhianaDIt R. P. CHAWLA ( Alternate)

Dn KISHAN SINGH Indian Institute of Sugarcane Research ( ICAR ).Lucknow

DR S. C. SmvAS'fAVA ( Altertzate)SURt S. G. KRISHNAN National Organic Chemical Industries Limited.

BombayDR J. S. VEltMA ( Alternate)

SHRI S. K. MAJU~IDAR Central Food Technological Research Institute( CSIR ), Mysore

SHltI M. MUTlIu ( Alternate)Snnr K. S, MElITA Bharat Pulverising Mills Private Limited. Bombay

SHIU S. ClIATTEltJI ( Alternate sDR A. L. MOO1n;RJ~;E Cyanamid India Limited, Bombay

SHRI J. P. PAltIKH ( Alternate )DR S. K. MUKEltJEE Agricultural Chemicals Division, Indian Agricultural

Research Institute ( ICAR ). New Delhi

DR K. S. SINGH

DR K. D. SHARMA

DR N. K. Roy ( Allernale)DR K. D. PAHARIA 'Central Insecticides Board, Directorate of Plant

Protection, Quaranrine ze Storage ( Ministry ofAgriculture & Irrigation) Faridabad

DR S. Y. PANDIT Bayer (India) Limited, BombaySHRI D. N. NAKHATE ( Alternate )

DR T. N. PARTHASARA'l'HY Regional Research Laboratory ( CSIR ), HyderabadSHRI M. A. PA'rEL Department of Agriculture, Government of Gujarat,

AhmadabadRallis India Limited, BombaySHRIY.A.PRADHAN

DR Z. J. KAPADIA ( Alternate )DR F. RAHMAN Tea Research Association, Calcutta

DR G. SATYANARAYANA ( Alternate )SHRI G. K. RAo Ministry of Defence ( DGI )

DR A. K. SEN ( Alternate )SHltI K. R. NARAYANA RAo Food Corporation of India, New Delhi

SMTK. K. M. BHAVNANI ( Alternate)DR RATTAN LAL Entomology Division, Indian Agricultural Research

Institute ( ICAR ), New DelhiDirectorate General of Technical Development,

New DelhiIndian Veterinary Research Institute (ICAR),

IzatnagarSHRI S. C, SRIVASTAVA ( Alternau )

( Continued onpage 12 )

2

Page 7: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 • 1978

Indian StandardSPECIFICATION FOR

COPPER OXYCHLORIDE, TECHNICAL

(Second Revision)

o. FOR E WO R D

0.1 This Indian Standard (Second Revision) was adopted by theIndian .Standards Institution on 31 August 1978, after the draft finalizedby the Pest Control Sectional Committee had been approved by theAgricultural and Food Products Division Council and Chemical DivisionCouncil.

0.2 Copper oxychloride is extensively used for agricultural and horti­cultural purposes in fungicidal formulations.

0.3 Copper oxychloride is the common name for basic cupric chlorides.

0.4 This standard was first issued in 1959. This was revised in 1969 toincorporate improved requirement for total soluble alkalinity andspecifying soluble copper salts in view of the better manufacturingtechnique becoming available. This revision has been taken up to bringit in alignment with the requirements as stipulated by Central Insecti­cides Board ( CIB ).

0.5 In the preparation of this standard due consideration has been givento the provisions of the Insecticides Act, 1968 and the Rules framedthereunder. However, this standard is subject to the restrictions imposedunder these, wherever applicable.

0.6 For the purpose of deciding whether a particular requirement ofthis standard is complied with, the final value, observed or calculated,expressing the result of a test or analysis, shall be rounded off inaccordance with IS : 2-1960*. The number of significant places retainedin the rounded off value should be the same as that of the specifiedvalue in this standard.

*Rules for rounding off numerical values ( revised).

3

Page 8: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS :1486·1978

1. SCOPE

1.1 This standard prescribes the requirements and the methods ofsampling and test for copper oxychloride, technical.

2. REQ.UIREMENTS

2.1 The material shall be in the form of bluish-green coloured homo­geneous powder or in such a form that it is possible to easily powder itby crushing under a knife, without a grinding action. It shall be freefrom foreign matter.

2.2 The material shall also comply with the requirements given inTable 1.

TABLE 1 REQ.UlREMENTS OF COPPER OXYCHLORIDE, TECHNICAL

SL CHARACTEIUSTIC REQUIREMENTS METROD OF TEST,

No. REF TO

v) Soluble copper salts, ppm, Max

vi) Lead (as Pb), percent bymass, Max

i) Moisture content, percent bymass, Max

ii) Copper content, percent bymass, Min

(4)

Clause 11.3.2 ofIS : 6940-1973-

Appendix B ofIS : 1506-1977t

Appendix B

Appendix C

Clauss 4.2 ofIS : 6940-1973-

Appendix A ofIS : 1506-1977t

Appendix A

(3)

1'0

0'05

30

0'05

57'0

15'5

(2)

Total chlorine content, percentby mass, Min

iv) Acidity (as H.SOt ) , percentby mass, Max

ORAlkalinity (as Na.CO.), per­

cent by mass, Max

(I)

iii)

vii) Arsenic (as As), percent bymass, Max

O'O~ Appendix D

.Methods of tests for pesticides and their formulations.tSpecification for copper oxychloride, dusting powders (slcllndrevision).

3. PACKING AND MARKING

3.1 Packing - The material shall be packed according to IS: 8190( Part I )-1976*.

-Requirements for packing of pesticides: Part I Solid pesticides.

4

Page 9: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486·1978

3.2 Marking - The following information shall be marked legibly andindelibly on each container in addition to the information as requiredunder the.Insecticides Act and Rules:

a) Name of the material;b) Copper content, percent, ( mlm );c) Name of the manufacturer;d) Batch number;e) Net mass of contents;f) Date of manufacture; andg) The cautionary notice as worded in Insecticides Act and Rules.

3.2.1 When packed in bags (see 3.1 ), the pictorial marking for'USE NO HOOKS. DO NOT PUNCTURE' as prescribed inIS : 1260 ( Part II )-1973* shall be stencilled on the bags.

3.2.2 Each container may also be marked with the lSI CertificationMark.

NOTE - The use of the lSI Certification Mark is governed by the provisions ofthe Indian Standards Institution (Certification Marks) Act and the Rules andRegulations made thereunder. The lSI Mark on products covered by an IndianStandard conveys the assurance that they have been produced to comply with therequirements of that standard under a well-defined system of inspection testing andquality control which is devised and supervised by lSI and opera~ed by theproducer. lSI marked products are also continuously checked by lSI for conformityto that standard as a further safeguard. Details of conditions under which a licencefor the use of the lSI Certification Mark may be granted to manufacturers orprocessors, may be obtained from the Indian Standards Institution.

4. SAMPLING

4.1 Representative samples of the material shall be drawn as prescribedin 'Indian Standard methods for sampling of pesticides and theirformulation' ( under preparation).

NOTE - Till such time the standard under preparation is published, the mattershall be as agreed to between the parties concerned.

5. TESTS

5.1 Tests shall be carried out by appropriate methods as referred to incol 4- of Table 1.

5.2 Quality of Reagents - Unless specified otherwise, pure chemicalsand distilled water (see IS : I070-1977t ) shall be employed in tests.

NOTE - , Pure chemicals' shall mean chemicals that do not contain impuritieswhich affect the-results of tests.

*Pictorial markings for handling and labelling of goods: Part II General goods(first recision ).

tSpecification for water for general laboratory use ( second recision ).

5

Page 10: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 - 1978

APPENDIX A[ Table 1, Item (iii) ]

DETERMINATION OF TOTAL CHLORINE CONTENT

A-I. REAGENTS

A-I.I Dilute Nitric Acid Solution - 5 percent ( v/v ).A-l.2 Sta.ndard Silver Nitrate Solution - 0'1 N.

A-I.3 Ferric Ammonium Sulphate Solution - 10 percent ( m]» ).

A-I.4 Standard Potassium Thiocyanate Solution - 0·1 N.

A-2. PROCEDURE

A-2.1 Weigh accurately about 0·25 g of the material into a 250-mlErlenmeyer flask. Add to this about 30 ml of dilute nitric acid solutionand shake to dissolve the contents of the flask. Add 20 ml of thestandard silver nitrate solution, about 5 ml of ferr ic ammonium sulphatesolution, .and titrate the mixture against the standard potassiumthiocyanate solution.

A-2.2 Alternatively, direct titration may be carried out potentiometri­cally.

A-3. CALCULATION

A-3.1 Total chlorine content,percen t by mass

3·546 X ( 20 - A X 1) X NM

whereA = volume in ml of the standard potassium thiocyanate

solution required for the test with the material,1 = correction factor ( see A-3.2 ),N = normality of the standard silver nitrate solution, andiV! = mass in g of the material taken for the test.

A-3.2 Correction factor (1) is the equivalent value of I mlof the 0·1 Npotassium thiocyanate solution in terms of 1 ml of the 0·1 N silver nitratesolution:

FI1= -- ­F

whereF1 = normality of the standard potassium thiocyanate solution,

andF = normality of the standard silver nitrate solution.

6

Page 11: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 - 1978

APPENDIX B[ Table 1, Item (v) ]

D-ETERMINATION OF SOLUBLE COPPER SALTS

B-1. APPARATUS

B-l.1 Nessler Cylinders - 100 ml capacity.

B-2. REAGENTS

B-2.l Concentrated Hydrochloric Acid

B-2.2 Concentrated Nitric Acid

B-2.3 Citric Acid

B-2.4 Standard AmDlonium Hydroxide Solution - approximately5N.

B-2.5 SodiuDl DiethyldithiocarbaDlate Solution - Dissolve 1'0 g ofsodium diethyldithiocarbamate in 1 000 ml of copper-free water. Filterand keep in an amber bottle and protect from strong light.

B-2.6 Standard Copper Solution - Dissolve 0'3928 g of coppersulphate pentahydrate in copper-free water and make up the volume toI 000 ml so that I ml of this solution is equivalent to 0'1 mg of copper.

B-3. PROCEDURE

B-3.1 Weigh 25'0 g of sample and extract with cold water and filterinto 250-ml volumetric flask and make the volume to 250 ml. Thefiltrate should be clear. Mix well and take 100 ml out of 250 ml for theestimation of copper.

8-3.2 Add 0'5 ml of concentrated hydrochloric acid and five drops ofconcentrated nitric acid, boil for about 15 minutes to reduce the volumeto about 86 mland cool. Add 1 g of citric acid and adjust pH to 9 byadding standard ammonium hydroxide solution. Transfer the solutionto the Nessler cylinder and add 10 ml of sodium diethyldithiocarbamatesolution. Compare the yellow colour produced with a control using 3 mlof standard copper solution in p.lace of the material.

B-3.3 The material shall be considered not to have exceeded theprescribed limit if the intensity o~ the colour produced with the materialis not greater than that produced m the control test. Calculate solublecopper salts in terms of parts per million ( ppm).

7

Page 12: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS: 148»-1978

APPENDIX C[ Table 1, Item (vi) ]

DETERMINATION OF LEAD

C..().GENERAL

C-O.l Lead is extracted as the dithizonate from a solution of copperoxychloride and estimated photometrically.

c.r, REAGENTS

C-l.1 Dilute Nitric Acid - 50 percent ( vfv).

C-l.2 Thymolphthalein Indicator - 0'04 percent ( m]» ) in alcohol.

C-1.3 Ammonia-Cyanide Solution - Dissolve 13'3 g of potassium'cyanide in ZOO ml of water. Add 75 ml of ammonia solution (r.d. 0-9 )and make up the volume to 500 m l.

C-l.4 Hydroxylallline Hydrochloride

C-l.5 Tartaric Acid Solution - 50 percent. Dissolve 50 g m warmwater and dilute to 100 ml.

C-l.6 AlIlmoniulll Hydroxide Solution - r.d, 0'9.

C-l.7 Potassium Hydroxide Solution - 50 percent ( mJv ).

C-l.8 Potassiulll Cyanide Solution - 13'3 percent ( m]» ).

C-].9 Dithizone Solution - Dissolve 0'01 g of dithizone in 500 ml ofcarbon tetrachloride and filter.

C-I.IO Carbon Tetrachloride

C-l.11 Wash Solution - To 25 ml of dilute nitric acid solution,add 2 to 3 drops of thymolphthalein solution and ammonia-cyanidesolution till blue in colour. Dissolve 0'1 to 0'2 g hydroxylaminehydrochloride in this solution. (This wash solution should be preparedfreshly. )

C-2. PROCEDURE

C-2.1 Weigh accurately 2'5 g of the material and dissolve it in 50 ml ofdilute nitric acid. Boil for 2 to 3 minutes and then allow to cool.Transfer the solution to a 250-ml volumetric flask, make up to the markand mix well.

8

Page 13: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 -1978

C-2.2 Pipette out 25 ml of the solution into a beaker, add 5 ml oftartaric acid solution and 4- ml of ammonia solution. (If the solutionturns deep blue, decolourize it by adding further tartaric acid.) Cooland add to the decolourized solution potassium h¥-Groxide solutiondropwise ( 2 to 4 rnl ) until a deep blue colour is o15fiined. Cool and addpotassium cyanide solution ( 4 to 6 ml ) until the solution becomes water­white or light yellow. Add four drops of thyrnolphthalein indicatorsolution and adjust the pH of the solution as follows:

If the colour of the solution after adding the indicator is deepblue or dirty green ( dependiug on the colour before adding theindicator ), add tartaric acid until the colour becomes light blue orlight yellow-green. When the solution is faint light blue (lightyellow-green), add ammonia solution till a deeper colour isobtained.

NOTE - The colour of the solution depends on the impurities present in thesolution.

C-2.3 Add 0'3 to 0'4 g of hydroxylamine hydrochloride to the solution,dissolve it and transfer the solution to a 250-ml separating funnel. Add25 ml of dithizone solution, shake and allow to settle•. Run the lowerlayer into a second separating funnel. Add 15 ml of dithizone and10 ml of carbon tetrachloride to the first funnel, shake, allow to settle andrun the lower layer into the second funnel. Then add 5 ml of ammoniasolution and 10 ml of carbon tetrachloride to the first funnel. Shake asbefore and examine the lower layer. If colourless or slightly green, runthe lower layer into the second funnel. If pink, add 10 ml of dithizonesolution, re-shake and run off the lower layer. Wash the aqueous layerwith another 10 ml of carbon tetrachloride solution and, if colourless,add it to the previous combined extracts. Discard the aqueous layer inthe first funnel.

C-2.4 Add the wash solution (see C-l.ll) to the combined extracts inthe separating funnel. Shake and allow to settle. The lower layershould have a .distinct pink colour and show no orange tint. Run thelower layer through a dry filter paper into a dry 100-ml volumetric flask.Extract the wash water with 10 ml of carbon tetrachloride and run itinto the 100 ml volumetric flask. Make up to the mark with carbontetrachloride.

C-2.5 Measure the intensity of the pink colour immediately on thespectrophotometer at 520 nm in l-cm cell using carbon tetrachloride asblank. The colour, finally measured. should be pink, as tendancy toan orange colour indicates the presence of oxidation products. Theextinction at 450 nm. should not be more than half of that at 520 nm,

9

Page 14: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 - 1978

C-3. CALCULATION

C-3.1 Calculate the amount of lead present in the solution by plottingthe intensity reading on the standard curve previously drawn by usingvarying concentrations of lead.

APPENDIX D[Table 1, Item (vii) ]

DETERMINATION OF ARSENIC

D-O. GENERAL

D-O.l Arsenic is precipitated as the element from a solution of copperoxychloride in hydrochloric acid by sodium hypophosphite. Theprecipitated arsenic is dissolved in iodine solution and estimatedphotometrically after reduction of arsene molybdate to ' molybdenumblue '.

D-I. REAGENTS

D-I.1 Dilute Nitric Acid - 50 percent ( v/v ).

D-1.2 Concentrated Sulphuric Add

D-1.3 Concentrated Hydrochloric Acid

D-l.4 Sodiutll. Hypophosphite

D-l.5 Standard Iodine-Solution - 0'02 N,

D-l.6 Sodrum Bicarbonate Solution - normal solution.

D-I.7 Sulphuric Molybdate Reagent - Prepared by mixing equalvolumes of 13 N sulphuric acid and 6'9 percent (TTl/v) solution ofammonium molybdate.

D-I.8 Sodiutll. Metablsulphite Solution - 5 percent ( mlo ),

D-I.9 Stannous Chloride Solution - 0'2 percent (prepared bydiluting concentrated stannous chloride solution with water as required ).

D-2. PROCEDURE

0-2.1 Weigh accurately 2'5000 g of the material and dissolve it in -25 mlof dilute nitric acid, Add 6 to 8 ml of concentrated sulphuric acidwhen the effervescence, if any, has ceased. Carefully boil the solutionuntil it fumes, to remove organic matter. Cool, add 10 ml of water andrefume, taking care to avoid ' spitting'. Cool, and then dissolve the

10

Page 15: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 - 1978

salts by warming with 25 001 of water. Add to the solution 30 001 ofconcentrated hydrochloric acid and 4 to 6 g of sodium hypophosphite.Warm the solution on a hot-plate until the precipitation is complete andthen boil gently for 5 minutes to coagulate the precipitate.

D-2.2 Filter through a No. 4 sintered glass funnel. Wash the beakertwice with 15-001 portions of hot freshly-boiled water, pouring washingsthrough the funnel. Then wash the funnel four times, using 15001 ofhot water each time. Discard the nearly colourless filtrate andthoroughly rinse out the filter flask. Put the filter funnel in position andadd 20 001 of iodine solution to the precipitate. Draw the solution veryslowly through the filter until all the arsenic is dissolved. ( It is easy todetermine when the arsenic has been dissolved, since it is always in theform of a dark-brown or black finely-divided powder which shows upwell even in traces on the filter.) Again add 20 001 of iodine solutionand slowly draw through the filter. Wash the filter with 20 to 30 001 ofwater until an traces of iodine have been washed out. Transfer thissolution to a 100 001 volumetric flask and make up to the mark withdistilled water.

D-2.3 Transfer 5 001 of the above solution (01' less, arsenic contentis high) to a test tube with a mark at 9 001. Pipette out 1 001 of sodiumbicarbonate solution and 2 001 of sulphuric molybdate reagent into thetest tube. When the effervescence has ceased, add one to two drops ofsodium metabisulphite solution to decolourize the iodine. Make up thevolume to the 9 001 mark with water. Mix the solution well and "thenadd 1 001 of stannous chloride solution. Shake the test tube thoroughly.

D-2.4 After 5 minutes, measure the intensity of the blue colour developedon the spectrophotometer, preferably at 840 nm using a I-em cell anddistilled water as blank. If 840 nm cannot be attained by the spectro­photometer, a lower wavelength of 750 nm may be used.

D-3.CALCULATION

D-3.1 Calculate the amount of arsenic present in the material by plottingthe intensity of the colour so obtained on a standard curve previouslydrawn by using pure arsenic-free copper and arsenic trioxide ofanalytical reagent grade as standards in concentrations from 0 to 60 p.g.

11

Page 16: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS : 1486 • 1978

( Continu,dfiom pagt 2 )

A/embers Representint

SHitI K. VENKATACHALAM Department of Agriculture, Government ofAndhra Pradesh, Hyderabad

SHRI K. SATYANARANA RAo ( Alternate)Srrnr N. S. \'EN'KATARA:'.IAN Department of Agriculture, Government of

Tamil NaduDR P. R. VENKATESWARAN Union Carbide India Limited, New Delhi

DR K. N.,SHRIVAS'.r..A... VA ( Alternate)SHRI N. G. WAGLE Pest Control ( India) Private Limited, Bombay

SHRI M. R. BAJIKAR ( Alternate)DR B. L. WAT'l'AL National Institute of Communicable Diseases; DelhiSHRI T. PURNANANDAM, Director General, lSI ( Ex-officio Member)

Deputy Director ( Agri & Food)

Secretary

SHRI LAJINDER SINOHAssistant Director (t\gri & Food), lSI

Pesticides Subcommittee; AFCDC 6

Convener

OR K. D. PA-HARIA Centra! Insecticides Board; Directorate of PlantProtection; Quarantine & Storage ( Ministry ofAgriculture & Irrigation), Faridabad

DR N. K. Bxsrr

Members

DR N. S. AGARWAL

Agromore Limited, BangaloreAgricultural Chemicals Division, Indian Agricultural

Research Institure ( ICAR ), New Delhi

Ministry of Agriculture & Irrig:l.l-iori ( Departmentof Food ), New Delhi

DR K. KRISHNAMURTlIY ( Alternate)SlIRI E. A. ALMIEDA Ciba-Gcigy<>!fndia Limited, BombayDR H. L. BAMI Befitral Forensic Science Laboratory, Central Bureau

ofInvestigation, New DelhiAlkali & Chemical Corporation of India Limited,

CalcuttaDR A. p. DUTTA ( Alternate)

DR A. K. BHATNAGAR Hindustan Insecticides Limited, New DelhiSlIRI C. C. ABRAIIAM ( Alternate)

DR N. F. DESAI Sandoz ( India) Limited, ThaneDR p. S. PRADKE ( Alternate)

DR M. S. DHATT National Malaria Eradication Programme, DelhiSHRI G. D. GOKHALE Bombay Chemicals Private Limited, Bombay

SHRI V. V. KETKAR ( Alternate)DR KALYAN SINGH Chander Shekar Azad University of Agriculture &

Technology, KanpurSlIRI K. S. MEHTA Bharat Pulverising .Mills Private Limited, Bombay

SHRI S. CHNI'TEltJI ( Alternate)SlIRI L. S. MIRLEDR S. K. MUKERJEE

DR N. K. Roy ( Alternate)DR S. Y. PANDIT Bayer ( India) Limited, Bombay

SHIU D. N. NAKHATE( Alternate)

iContinued on page 13 )

12

Page 17: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

IS 1486· 1978

(Continued from page 12 )

MembersDR T. N. PARTHASARATHYPLAN'.r PIWTIW'l'I()~ ADVISER

THE GOVERNMENT OF INDIA

RepreJtnting

Regional Research Laboratory ( CSIR ), HyderabadTO Directorate of Plant Protection, Quarantine &

Storage ( Ministry of Agriculture & Irrigation ),Faridabad

DR V. LAKSHMINARAYANA ( Alternate)SHRI Y. A. PRADHAN Rallis India Limited, Bombay

SHRIM. L. SHAH ( Alternate)DR V. S. RAMANATHAN Central Revenues Control Laboratory ( Ministry of

Finance ), New DelhiSHRI C. DHARMA RAO Pesticides Testing Laboratory, HyderabadSHRI D. N. V. RAO' Tara Chemicals Limited, Mithapur

SHm C. NEELKANTHAN ( Alternate)DR K. K. SAXENA Indofil Chemicals Limited, Bombay

SHRJ G. NATARAJAN (Alternate)S...rRJ A. C. SHROFF Excel Industries Limited, Bombay

SIIRJ P. V. KANGO ( Alternate)SHRJ K. SUNDARAM Hindustan Petroleum Corporation Limited, Bomba y

SIIRJ B. R. AJMANI ( Alternate)SHRJ N. S. VENKATARAMAN Pesticides Testing Laboratory, KovilpattiDR B. L. WATTAL National Institute of Communicable Diseases, Delhi

SIIRJ V. N. BHATNAGAR ( Alternate)

13

Page 18: IS 1486 (1978): Specification for Copper Oxychloride, TechnicalIS:1486-1978 ( Continued from page I ) Members Dnnos CONTnOI,J.1m ( INDIA ) Representing Indian Pharmacopoeia Committee

BUREAU OF INDIAN STANDARDS

53627331 77

251 71

52435

231083

{6 34 7169832

{21 687621 829262305

[621 041.62117

I 21843l 3 16 41

{

4 1 244241 25 1941 2916

6329295

Southern : C. I. T. Campus. MADRAS 600113

tWestern : Manakalaya, E9 MJDC, Marol, Andheri ( East l.BOMBAY 400093

Branch Offices:-Pushpak'. Nurmohamed Shaikh Marg, Khanpur,( 2 63 48

AHMADABAD 380001 1 2 63 49tPeenya Industrial Area 1st Stage, Bangalo.re Tumkur Road ~38 4955

BANGALORE 560058 l38 49 56Gangotri Complex, 5th Floor. Bhadbhada Road, T. T. Nagar. 6 67 16

BHOPAL 462003Plot No. 82/83. Lewis Road, BHUBANESHWAR 75100253/5. Ward No. 29, R.G. Barua Road, 5th Byelane,

GUWAHATI 7810035-8-56C L. N. Gupta Marg ( Nampally Station Road ).

HYDERABAD 500001

R14 Yudhister Marg, C Scheme, JAIPUR 302005

117/418 B Sarvodaya Nagar, KANPUR 208005

Patliputra tndustrial Estate, PATNA 800()13T.C. No. 14/1421. University p.O.• Palayam

TRIVANDRUM i>95035Inspection Offices ( With Sale Point ):Pushpanjali. First Floor. 205-A West High Court Road,

Shankar Nagar Square, NAGPUR 440010Institution of Engineers ( India) BUildiny, 1332 Shivaji Nagar,

PUNE'411005

Headquaners:Manak Bhavan, 9 Bahadur Shah Zatar Marg, NEW DELHI 110002Telephones: 331 01 31, 331 1375 Telegrams: Manaksanstha

( Common to all Offices)Telephone

p31 01 31l3311375

362499

Regional Offices:Central: Manak Bhavan, 9 Bahadur Shah Zatar Marg,

NEW DELHI 110002-Eastern: 1/14 C. J. T. Scheme VII M. V. J. P. Road,

Maniktola, CALCUTTA 700054Northern : SCO 445-446, Sector 35-C,

CHANDIGARH 160036

.Sale. Office in Calcutta i. at 5 Chowringhee Approach, P. O. Princep 2768 00Street. Calcutta 700072

tSale. Office in Bombay i. at Novelty Chambers, Grant Road. 89 6628Bombay 400007

tSales Office in Banllalore i. at unity Building. Narasimharaja Square. 22 36 71Bangalore 560002

Reprography Unit, BIS, New Delhi, India