ionol cp your health, our safety data sheet...2017/05/30 · ionol cp safety data sheet according...

IONOL CPSafety Data SheetAccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830Revision date: 5/30/2017 Supersedes: 9/1/2015 Version: 5.0

5/30/2017 EN - English / GB - United Kingdom

Your health, our commitment

SECTION 1: Identification of the substance/mixture and of the company/undertaking1.1. Product identifierProduct form : SubstanceSubstance name : IONOL CPChemical name : 2,6-di-tert-butyl-p-cresolEC-No. : 204-881-4CAS-No. : 128-37-0REACH registration No : 01-2119565113-46Formula : C15H24OSynonyms : 2.6-di terc-butyl-4-methyl phenol

1.2. Relevant identified uses of the substance or mixture and uses advised against

1.2.1. Relevant identified usesIndustrial/Professional use spec : Industrial

For professional use onlyUse of the substance/mixture : Stabilizer for cosmetics, pharmaceuticals and essential oils.

Food grade antioxidant (E-321), also applied to food packaging.Antioxidant for lubricants and greases.Antioxidant in coatings, printing inks, adhesives, waxes and leather treatment industry.Antioxidant for natural and synthetic rubbers/elastomers.Antioxidant for lubricants, industrial oils, adhesives, PVC and polyethylene.Antioxidant for plastics and synthetic resins.Antioxidant for petroleum products.Polymerization inhibitor

Title Life cycle stage Use descriptorsManufactureX PROC1, ERC1FormulationX SU5, SU6a, SU7, SU10, SU11, SU12, PC1, PC8, PC9a, PC13,

PC15, PC16, PC17, PC18, PC23, PC24, PC25, PC28, PC31, PC32, PC39, PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9, AC5, AC6b, AC8, AC10, AC13, ERC2

Coatings and inksX Industrial SU7, PC1, PC9a, PC15, PC18, PC23, PC31, PROC3, PROC5, PROC10, AC6, AC8, ERC6b

Coatings and inksX Professional PC1, PC9a, PC15, PC18, PC23, PC31, PROC10, PROC11, ERC8bCoatings and inksX Consumer PC1, PC5, PC10, PC15, PC18, PC23, PC31LubricantsX Industrial SU3, PC16, PC17, PC24, PC25, PROC1, PROC2, PROC7,

PROC8a, PROC8b, PROC9, PROC10, PROC13, PROC14, PROC17, ERC4

LubricantsX Professional PC16, PC17, PC24, PC25, PROC1, PROC8a, PROC8b, PROC10, PROC13, PROC17, ERC9a

LubricantsX Consumer PC24, ERC9aPaper industryX Industrial SU6b, PC8, PROC2, AC8, ERC4PolymerX Industrial SU11, SU12, PC32, PROC3, PROC4, ERC6dFuelsX Professional PC13, PROC9, PROC16, ERC9bFuelsX Consumer PC24, ERC9bCosmeticsX Consumer PC28, PC39, ERC8a

Full text of use descriptors: see section 16

1.2.2. Uses advised againstNo additional information available

1.3. Details of the supplier of the safety data sheetOxiris Chemicals S.ACtra.C-35 Km 59 - Pol. Ind. Nord-Est08470 Sant Celoni - SpainT +34 93 867 49 [email protected]

1.4. Emergency telephone numberEmergency number : +34 93 551 72 85 (CECAT) (24 h)

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mailto:[email protected]

IONOL CPSafety Data SheetAccording to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830



SECTION 2: Hazards identification2.1. Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]Hazardous to the aquatic environment — Acute Hazard, Category 1

H400

Hazardous to the aquatic environment — Chronic Hazard, Category 1

H410

Full text of hazard classes and H-statements : see section 16

Adverse physicochemical, human health and environmental effectsVery toxic to aquatic life with long lasting effects.

2.2. Label elements

Labelling according to Regulation (EC) No. 1272/2008 [CLP] Extra labelling to displayExtra classification(s) to display Hazard pictograms (CLP) :

GHS09

Signal word (CLP) : WarningHazard statements (CLP) : H410 - Very toxic to aquatic life with long lasting effectsPrecautionary statements (CLP) : P273 - Avoid release to the environment

P391 - Collect spillageP501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation.

2.3. Other hazardsThis substance/mixture does not meet the PBT criteria of REACH regulation, annex XIIIThis substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

SECTION 3: Composition/information on ingredients3.1. SubstancesChemical name : 2,6-di-tert-butyl-p-cresolCAS-No. : 128-37-0EC-No. : 204-881-4

Name Product identifier %2,6-di-tert-butyl-p-cresol (CAS-No.) 128-37-0

(EC-No.) 204-881-4(REACH-no) 01-2119565113-46

>= 99,9

Full text of H-phrases: see section 16

3.2. MixturesNot applicable

SECTION 4: First aid measures4.1. Description of first aid measuresFirst-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical

advice (show the label where possible).First-aid measures after inhalation : Assure fresh air breathing. Allow the victim to rest.First-aid measures after skin contact : Remove affected clothing and wash all exposed skin area with mild soap and water, followed

by warm water rinse.First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness

persists.First-aid measures after ingestion : Rinse mouth. Do not induce vomiting. Obtain emergency medical attention.

4.2. Most important symptoms and effects, both acute and delayedSymptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use.

4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.

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SECTION 5: Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.Unsuitable extinguishing media : Do not use a heavy water stream.

5.2. Special hazards arising from the substance or mixtureFire hazard : Not classified as flammable but will burn.Hazardous decomposition products in case of fire

: Carbon monoxide. Carbon dioxide.

5.3. Advice for firefightersFirefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any

chemical fire. Prevent fire fighting water from entering the environment.Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

SECTION 6: Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures

6.1.1. For non-emergency personnelEmergency procedures : Evacuate unnecessary personnel.

6.1.2. For emergency respondersProtective equipment : Equip cleanup crew with proper protection.Emergency procedures : Ventilate area.

6.2. Environmental precautionsPrevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. Avoid release to the environment.

6.3. Methods and material for containment and cleaning upMethods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away

from other materials. Do not use any water to clean up. Collect spills and put it into appropriated container. Recover and reclaim or recycle, if practical. Dispose in a safe manner in accordance with local/national regulations.

6.4. Reference to other sectionsSee Heading 8.

SECTION 7: Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or

smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour.

7.2. Conditions for safe storage, including any incompatibilitiesTechnical measures : Ground/bond container and receiving equipment.Storage conditions : Keep only in the original container in a cool, well ventilated place away from : acids and bases,

Heat sources. Keep container closed when not in use. In case of food use, do not store together with harmful, toxic or very toxic products.

Incompatible products : Strong bases. Strong acids. Oxidizing agent.Incompatible materials : Sources of ignition. Direct sunlight.Storage temperature :




2,6-di-tert-butyl-p-cresol (128-37-0)PNEC aqua (intermittent, freshwater) 1.99 µg/LPNEC (Sediment)PNEC sediment (freshwater) 99.6 mg/kgPNEC sediment (marine water) 9.96 mg/kgPNEC (Soil)PNEC soil 47.69 µg/kg

8.2. Exposure controls

Personal protective equipment:

Avoid all unnecessary exposure. Hand protection:

Protective gloves made of PVC

Eye protection:

Chemical goggles or safety glasses

Skin and body protection:

Wear suitable protective clothing Respiratory protection:

Wear appropriate mask

Other information:

Do not eat, drink or smoke during use.

SECTION 9: Physical and chemical properties9.1. Information on basic physical and chemical propertiesPhysical state : Solid

Appearance : Crystalline.Colour : White.

Odour : Characteristic.

Odour threshold : No data available

pH : No data available

Relative evaporation rate (butylacetate=1) : No data available

Melting point : 70 °C

Freezing point : Not applicable

Boiling point : 265 °C (Handbook and/or Scientific papers)

Flash point : 127 °C (Handbook and/or Scientific papers)

Auto-ignition temperature : Not applicable

Decomposition temperature : No data available

Flammability (solid, gas) : Not flammable.

Vapour pressure : 3.82 Pa (24,85 ºC)

Relative vapour density at 20 °C : No data available

Relative density : 1.048 (Handbook and/or Scientific papers)

Solubility : Water: 0.6 g/ml (Handbook and/or Scientific papers)

Log Pow : 5.2 (Handbook and/or Scientific papers)

Viscosity, kinematic : 3,47 cSt (80 ºC), 1,54 cSt (120 ºC), 0,920 cSt (160 ºC) (Handbook and/or Scientific papers)

Viscosity, dynamic : No data available

Explosive properties : No data available

Oxidising properties : The study does not need to be conducted because the substance is incapable of reacting exothermically with combustible materials.

Lower explosive limit (LEL) : 7.5 g/m³

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9.2. Other informationOther properties : Surface tension: Not applicable.

pKa: 12,2 (20 °C).Particle size distribution : 2mm (10 Mesh): 0.4%; 1.5mm: 10.6%; 1mm (18 Mesh): 21.7%; 0.75mm: 18.4%; 0.50mm (35

Mesh): 11.7%; 0.40mm: 7.8%; 0.250mm (60 Mesh): 16.5%; 2000 mg/kg Sprague Dawley rat (OECD 402 method)

Skin corrosion/irritation : Not classifiedSerious eye damage/irritation : Not classified (Read-across)Respiratory or skin sensitisation : Not classified (Read-across)Germ cell mutagenicity : Not classified (Weight of evidence. Scientific papers)Carcinogenicity : Not classified (Weight of evidence. Scientific papers)

Reproductive toxicity : Not classified (Weight of evidence. Scientific papers)STOT-single exposure : Not classified

2,6-di-tert-butyl-p-cresol (128-37-0)NOAEL (oral, rat) 100 mg/kg bodyweight

STOT-repeated exposure : Not classified

2,6-di-tert-butyl-p-cresol (128-37-0)NOAEL (oral, rat, 90 days) 25 mg/kg bodyweight/day Target organ(s): digestive organs: liver; urogenital organs: kidneys;

thyroid gland, adrenal glandsAspiration hazard : Not classified

Potential adverse human health effects and symptoms

: May irritate eyes and skin.

SECTION 12: Ecological information12.1. ToxicityEcology - water : Very toxic to aquatic life with long lasting effects.

2,6-di-tert-butyl-p-cresol (128-37-0)LC50 fish 1 0.199 mg/kg (estimated value)EC50 (aquatic invertebrates) 0.48 mg/l Test method EU C.2 (OECD 202 method). 0.39 - 0.70 mg/ml.ErC50 (algae) 0.758 mg/l (estimated value)NOEC (acute) 0.15 mg/l

12.2. Persistence and degradability2,6-di-tert-butyl-p-cresol (128-37-0)Persistence and degradability Not readily biodegradable. May cause long-term adverse effects in the environment.

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12.3. Bioaccumulative potential2,6-di-tert-butyl-p-cresol (128-37-0)Bioconcentration factor (BCF REACH) 598Log Pow 5.2 (Handbook and/or Scientific papers)Bioaccumulative potential Not established.

12.4. Mobility in soil2,6-di-tert-butyl-p-cresol (128-37-0)Mobility in soil Substance sinks in water. Adsorbs into the soilSurface tension Not applicable

12.5. Results of PBT and vPvB assessment2,6-di-tert-butyl-p-cresol (128-37-0)This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIIIThis substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII

12.6. Other adverse effectsAdditional information : Avoid release to the environment

SECTION 13: Disposal considerations13.1. Waste treatment methodsWaste treatment methods : Dispose of this material and its container to hazardous or special waste collection point, in

accordance with local, regional, national and/or international regulation.Ecology - waste materials : Avoid release to the environment.

SECTION 14: Transport informationIn accordance with ADR / IMDG / IATA

14.1. UN numberUN-No. (ADR) : 3077UN-No. (IMDG) : 3077UN-No. (IATA) : 3077

14.2. UN proper shipping nameProper Shipping Name (ADR) (ADR) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-butyl-p-cresol)Proper Shipping Name (ADR) (IMDG) : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-butyl-p-cresol)Proper Shipping Name (ADR) (IATA) : Environmentally hazardous substance, solid, n.o.s. (2,6-di-tert-butyl-p-cresol)Transport document description (ADR) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-butyl-

p-cresol), 9, III, (E)Transport document description (IMDG) : UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (2,6-di-tert-butyl-

p-cresol), 9, III, MARINE POLLUTANTTransport document description (IATA) : UN 3077 Environmentally hazardous substance, solid, n.o.s. (2,6-di-tert-butyl-p-cresol), 9, III

14.3. Transport hazard class(es)ADRTransport hazard class(es) (ADR) : 9Danger labels (ADR) : 9

:

IMDGTransport hazard class(es) (IMDG) : 9Danger labels (IMDG) : 9

:

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IATATransport hazard class(es) (IATA) : 9Hazard labels (IATA) : 9

:

14.4. Packing groupPacking group (ADR) : IIIPacking group (IMDG) : IIIPacking group (IATA) : III

14.5. Environmental hazardsDangerous for the environment : YesMarine pollutant : YesOther information : No supplementary information available

14.6. Special precautions for user

- Overland transportClassification code (ADR) : M7 Special provisions (ADR) : 274, 335, 601, 375Limited quantities (ADR) : 5kgExcepted quantities (ADR) : E1Transport category (ADR) : 3Hazard identification number (Kemler No.) : 90 Orange plates :

Tunnel restriction code (ADR) : E EAC code : 2Z

- Transport by seaLimited quantities (IMDG) : 5 kgExcepted quantities (IMDG) : E1EmS-No. (Fire) : F-AEmS-No. (Spillage) : S-FStowage and handling (IMDG) : SW23MFAG-No : 171

- Air transportPCA Excepted quantities (IATA) : E1PCA Limited quantities (IATA) : Y956PCA limited quantity max net quantity (IATA) : 30kgG

14.7. Transport in bulk according to Annex II of Marpol and the IBC CodeNot applicable

SECTION 15: Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

15.1.1. EU-RegulationsThe following restrictions are applicable according to Annex XVII of the REACH Regulation (EC) No 1907/2006:

3. Liquid substances or mixtures which are regarded as dangerous in accordance with Directive 1999/45/EC or are fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008

2,6-di-tert-butyl-p-cresol

3(c) Substances or mixtures fulfilling the criteria for any of the following hazard classes or categories set out in Annex I to Regulation (EC) No 1272/2008: Hazard class 4.1

2,6-di-tert-butyl-p-cresol

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2,6-di-tert-butyl-p-cresol is not on the REACH Candidate List2,6-di-tert-butyl-p-cresol is not on the REACH Annex XIV List

15.1.2. National regulationsNo additional information available

15.2. Chemical safety assessmentFor this substance a chemical safety assessment has been carried out

SECTION 16: Other informationIndication of changes:According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830.

Section Changed item Change Comments2.1 Classification according to

Directive 67/548/EEC [DSD] or 1999/45/EC [DPD]

Removed

8.1 Professional exposure limits Added9.1 Explosive properties Removed9.1 Lower explosive limit (LEL) Added15.1 REACH Annex XVII Added

Data sources : REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006.

Full text of H- and EUH-statements:Aquatic Acute 1 Hazardous to the aquatic environment — Acute Hazard, Category 1Aquatic Chronic 1 Hazardous to the aquatic environment — Chronic Hazard, Category 1H400 Very toxic to aquatic lifeH410 Very toxic to aquatic life with long lasting effectsAC10 Rubber articlesAC13 Plastic articlesAC5 Fabrics, textiles and apparelAC6 Leather articlesAC6bAC8 Paper articlesERC1 Manufacture of substancesERC2 Formulation of preparationsERC4 Industrial use of processing aids in processes and products, not becoming part of articlesERC6b Industrial use of reactive processing aidsERC6d Industrial use of process regulators for polymerisation processes in production of resins, rubbers, polymersERC8a Wide dispersive indoor use of processing aids in open systemsERC8b Wide dispersive indoor use of reactive substances in open systemsERC9a Wide dispersive indoor use of substances in closed systemsERC9b Wide dispersive outdoor use of substances in closed systemsPC1 Adhesives, sealantsPC10 Building and construction preparations not covered elsewherePC13 FuelsPC15 Non-metal-surface treatment productsPC16 Heat Transfer FluidsPC17 Hydraulic FluidsPC18 Ink and TonersPC23 Leather tanning, dye, finishing, impregnation and care productsPC24 Lubricants, Greases and Release ProductsPC25 Metal Working FluidsPC28 Perfumes, FragrancesPC31 Polishes and Wax BlendsPC32 Polymer preparations and compoundsPC39 Cosmetics, personal care productsPC5 Artists Supply and Hobby preparationsPC8 Biocidal products (e.g. Disinfectants, pest control)

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PC9a Coatings and paints, thinners, paint removersPROC1 Use in closed process, no likelihood of exposurePROC10 Roller application or brushingPROC11 Non industrial sprayingPROC13 Treatment of articles by dipping and pouringPROC14 Production of preparations or articles by tabletting, compression, extrusion, pelletisationPROC16 Using material as fuel sources, limited exposure to unburned product to be expectedPROC17 Lubrication at high energy conditions and in partly open processPROC2 Use in closed, continuous process with occasional controlled exposurePROC3 Use in closed batch process (synthesis or formulation)PROC4 Use in batch and other process (synthesis) where opportunity for exposure arisesPROC5 Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or

significant contact)PROC7 Industrial sprayingPROC8a Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non

dedicated facilitiesPROC8b Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated

facilitiesPROC9 Transfer of substance or preparation into small containers (dedicated filling line, including weighing)SU10 Formulation [mixing] of preparations and/or re-packaging (excluding alloys)SU11 Manufacture of rubber productsSU12 Manufacture of plastics products, including compounding and conversionSU3 Industrial uses: Uses of substances as such or in preparations* at industrial sitesSU5 Manufacture of textiles, leather, furSU6a Manufacture of wood and wood productsSU6b Manufacture of pulp, paper and paper productsSU7 Printing and reproduction of recorded media

Safety Data Sheet applicable for regions : GB - United Kingdom

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product

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IONOL CP Safety Data Sheet

01/09/2015 EN (English) SDS Ref.: -


Annex: Exposure Scenarios

9.1.1. Exposure scenario Manufacture stage ..................................................................................... 11 9.2.1. Exposure scenario Coatings and Inks sector. Industrial end-use. ........................................ 12 9.3.1. Exposure scenario Coatings and Inks sector. Professional end-use ................................... 16 9.4.1. Exposure scenario Coatings and Inks sector. Consumer end-use stage ............................ 18 9.5.1. Exposure scenario Paper Sector. Industrial end-use stage................................................... 19 9.6.1. Exposure scenario Cosmetics. Consumer use ........................................................................ 21 9.7.1. Exposure scenario Lubricants sector. Industrial end-use stage ........................................... 22 9.8.1. Exposure scenario Lubricants sector. Professional end-use stage ...................................... 28 9.9.1. Exposure scenario Lubricants sector. Consumer end-use stage ......................................... 34 9.10.1. Exposure scenario Fuels sector. Consumer end-use of fuels ............................................. 34 9.11.1. Exposure scenario Professional end-use stage .................................................................... 35 9.12.1. Exposure scenario Coatings and Inks sector. Industrial end-use....................................... 37 9.13.1. Exposure scenario Formulation stage 2 ................................................................................. 39

9.1.1. Exposure scenario Manufacture stage Manufacture stage

Environment: ERC 1

Worker

Process during manufacturing PROC 1

Operational conditions and risk management measures

Closed system

Control of environmental exposure: Manufacture stage

Product characteristics

Amounts used

Daily use at a site




Conditions and measures related to municipal sewage treatment plant

Municipal STP Yes [Water: 100%]

Discharge rate of STP >= 2E3 m3/d

Application of the STP sludge on agricultural soil No

Conditions and measures related to external treatment of waste for disposal

Waste incineration waste incinerated [Water: 100%; Air: 100%; Soil: 100%]

Conditions and measures related to external recovery of waste

Additional good practice advice beyond the REACH CSA

Control of workers exposure for "Process during manufacturing " [PROC 1]

Inhal*) Derm*)

Loc Sys Loc Sys


Substance in preparation No L

Dustiness Medium L

concentration < 5 % L L

Amounts used

Frequency and duration of use/exposure

Duration of activity >4 hours L

Human factors not influenced by risk management

Other given operational conditions affecting workers exposure

Place of use Indoors L

Surface of skin exposed One hand face only (240 cm2) L

Technical conditions and measures at process level (source) to prevent release

Level of containment Use in closed process, no likelihood of exposure L

Technical conditions and measures to control dispersion from source towards the worker

Local Exhaust Ventilation No L L

Organisational measures to prevent /limit releases, dispersion and exposure

Conditions and measures related to personal protection, hygiene and health evaluation

Respiratory protection Respiratory protection capable offering a 90% reduction in inhaled concentrations of the substance

L

gloves chemically resistant gloves with specific activity training [Dermal: 95%]

L

wear chemically resistant gloves (tested to EN374) in combination with specific activity training (PPE17)


*) The route of exposure (Inhalation, Dermal) and type of effect (Local, Systemic and Acute or Long term) for which the determinant has been used for exposure estimation are reported.

9.2.1. Exposure scenario Coatings and Inks sector. Industrial end-use.

According to Regulation (EC) No. 1907/2006 (REACH) with its amendment Regulation (EU) 2015/830

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Coatings and Inks sector. Industrial end-use.

Market sector: Adhesives (PC 1) Coatings and Inks (PC 9a) Toners and Inks (PC 18) Non-metal surface treatment(PC 15) Leather treatment (PC 23) Polishes (PC 31)

Sector of use: SU 3 – Industrial uses SU 5 – Manufacture of textiles, leather, fur SU 6a – Manufacture of wood and wood products

SU 7 - Printing and reproduction of recorded media

Environment: ERC 6b

Worker

Use in batch PROC 3

Mixing PROC 5

Application by roller or brush PROC 10


Control of environmental exposure: Industrial end-use stage


Amounts used

Daily use at a site = 2E3 m3/d





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Control of workers exposure for " Use in batch" [PROC 3]

Inhal*) Derm*)

Loc Sys Loc Sys


Substance in preparation Yes < 5% L

Dustiness Medium L

Amounts used








Level of containment Use in closed batch process (synthesis or formulation)

L


Local Exhaust Ventilation Yes L L




L

gloves chemically resistant gloves with basic training [Dermal: 90%]

L

wear chemically resistant gloves (tested to EN374) in combination with basic employee training



Control of workers exposure for "Mixing" [PROC 5]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Medium L

Amounts used





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Control of workers exposure for "Roller or brush application" [PROC 10]

Inhal*) Derm*)

Loc Sys Loc Sys


Substance in preparation Yes L

Dustiness Low L


Amounts used


Duration of activity 15 mins - 1 hour L




Surface of skin exposed Two hands (960 cm2) L







L


L




Control of workers exposure for "Non industrial spraying" [PROC 11]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L

Amounts used






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Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L





Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L

Amounts used






16/45 15/45







Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L





Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L

Amounts used






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Surface of skin exposed Two hands and upper wrists (1500 cm2) L







L


L




9.4.1. Exposure scenario Coatings and Inks sector. Consumer end-use stage Coatings and Inks sector. Consumer end-use stage

Market sector: Adhesives (PC 1) Coatings and Inks (PC 9a) Toners and Inks (PC 18) Non-metal surface treatment(PC 15) Leather treatment (PC 23) Polishes (PC 31)

Environment: ERC 8c

Consumer

Roller or brush application PROC 10 PC 5; PC 9; PC10


Control of environmental exposure: Consumer end-use stage


Up to 5% BHT

Amounts used*

500 g

Daily wide dispersive use = 5E-5 tonnes/day

Frequency and duration of use

Daily, during 2,2 hours (ECETOC TRA Consumers default)

Environment factors not influenced by risk management


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Receiving surface water flow rate >= 1.8E4 m3/d

CEPE 11 consumers CEPE 11 [Water: 99%; Air: 1%; Soil: 100%]

Other given operational conditions affecting environmental exposure


Municipal STP Yes [Water: 93.5%]


Application of the STP sludge on agricultural soil Yes




Control of consumers exposure for "Roller or brushing painting indoor" [PC 5; PC9a; PC 10]

Inhal*) Derm*) Oral*)

Loc Sys Loc Sys Loc Sys


BHT concentration in paints is typically 1%. This scenario covers up to 5%.

Amounts used

500 g/day


Daily, during 2,2 hours (ECETOC TRA Consumers default)


Other given operational conditions affecting consumers exposure

Conditions and measures related to information and behavioral advice to consumers

Use in a well-ventilated area. Keep away from naked flames and hot surfaces. Wash any residues off skin after use.

Conditions and measures related to personal protection and hygiene


Coatings and paints/decorative coatings, fillers, putties, thinners: Where more than 300g used, then open doors and windows to provide additional ventilation Building and construction preparations: Where more than 1Kg used, then open doors and windows to provide additional ventilation

*) The route of exposure (Inhalation, Dermal, Oral) and type of effect (Local, Systemic and Acute or Long term) for which the determinant has been used for exposure estimation are reported.

9.5.1. Exposure scenario Paper Sector. Industrial end-use stage Paper Sector. Industrial end-use stage

Market sector:

PC 8 - Biocidal Products (e. g. Disinfectants, pest control)

Sector of use:

SU 6b - Manufacture of pulp, paper and paper products

Environment: ERC 4

Worker


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Use in closed system with occasional exposure PROC 2


Control of environmental exposure: Industrial end-use stage [edit]


Preparation : BHT 4 hours L





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Surface of skin exposed Two hands face (480 cm2) L


Level of containment Use in closed, continuous process with occasional controlled exposure

L






L


L




9.6.1. Exposure scenario Cosmetics. Consumer use Cosmetics. Consumer use

Market sector: PC 28 perfumes

PC 39 - Cosmetics, personal care products

Environment: ERC 8a

Consumers: Covered by Cosmetic Directive


No applicable Control of environmental exposure: Cosmetics


< 5%

Amounts used

Daily wide dispersive use = 4.1E-6 tonnes/day












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9.7.1. Exposure scenario Lubricants sector. Industrial end-use stage Lubricants sector. Industrial end-use stage

Market sector:

PC 16 – heat transfer fluids PC 17 – Hydraulic fluids PC 24 - Lubricants, Greases, Release Products PC 25 – metal working fluids

Sector of use:

SU 3 – Industrial uses

Environment: ERC 4 ERC 7

Worker

Use in closed PROC 1

Use in closed with occasion for exposure PROC 2

Industrial spraying PROC 7

Charging/discharging PROC 8b

Filling small containers PROC 9

Application PROC 10

Dipping articles PROC 13

Lubrication PROC 17




Amounts used

Daily use at a site










Control of workers exposure for "Use in closed" [PROC 1]

Inhal*) Derm*)

Loc Sys Loc Sys


Substance in preparation yes L

Dustiness Medium L


Amounts used














L


L




Control of workers exposure for "Use in closed with occasion for exposure" [PROC 2]

Inhal*) Derm*)

Loc Sys Loc Sys




22/45




Dustiness Medium L


Amounts used








Level of containment Use in closed, continuous process with occasional controlled exposure

L






L


L




Control of workers exposure for "Industrial spraying" [PROC 7]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used


Duration of activity 1 - 4 hours L











23/45





L


L




Control of workers exposure for "Charging/discharging" [PROC 8b]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L




Control of workers exposure for "Filling small containers" [PROC 9]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


24/45





Amounts used













L


L




Control of workers exposure for "Application" [PROC 10]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


25/45





L




Control of workers exposure for "Dipping articles" [PROC 13]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L




Control of workers exposure for "Lubrication" [PROC 17]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L



26/45




Amounts used













L


L




9.8.1. Exposure scenario Lubricants sector. Professional end-use stage Lubricants sector. Professional end-use stage

Market sector:

PC 16 - Heat transfer fluids PC 17 – Hydraulic fluids PC 24 - Lubricants, Greases, Release Products PC 25 – metal working fluids

Sector of use:

SU 22 - Professional uses

Environment: ERC 9a

Worker

Use in closed system PROC 1

Transfer at non-dedicated facilities PROC 8a

Transfer at dedicated facilities PROC 8b

Application PROC 10

Spraying PROC 11

Dipping articles PROC 13

Lubircation PROC 17


Control of environmental exposure: Professional end-use stage


27/45





Amounts used







Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soil

ESVOC 14 ESVOC 14 [Water: 99%; Air: 99%; Soil: 99%]

Professional

Organizational measures to prevent/limit release from site








Control of workers exposure for "Use in closed system" [PROC 1]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used














L

gloves chemically resistant gloves with basic training L


28/45




[Dermal: 90%]




Control of workers exposure for "Transfer at non-dedicated facilities" [PROC 8a]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L




Control of workers exposure for "Transfer at dedicated facilities" [PROC 8b]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used


29/45
















L


L




Control of workers exposure for "Application" [PROC 10]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L


30/45







Control of workers exposure for "Spraying" [PROC 11]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L

Amounts used













L


L




Control of workers exposure for "Dipping articles" [PROC 13]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used




31/45














L


L




Control of workers exposure for "Lubircation" [PROC 17]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Low L


Amounts used













L


L



32/45






9.9.1. Exposure scenario Lubricants sector. Consumer end-use stage Lubricants sector. Consumer end-use stage

SU 21: consumer uses

Market sector:

PC 24 - Lubricants, Greases, Release Products

Environment: ERC 9a

Consumer: PROC 10


Control of environmental exposure: Consumer end-use stage


Amounts used*






ESVOC ESVOC 17

low release








9.10.1. Exposure scenario Fuels sector. Consumer end-use of fuels Fuels sector. Consumer end-use of fuels

Market sector:

PC 13 - Fuels

Environment: ERC 9b

Consumer PROC 9 PROC 16


Petrol station are equipped with Vapour’s capture systems


33/45




Control of environmental exposure: Consumer end-use of fuels


Amounts used*






ESVOC 30 fuels-consumers ESVOC 30 [Water: 100%; Air: 99.99%; Soil: 100%]

low volatility and solubility








9.11.1. Exposure scenario Professional end-use stage Professional end-use stage

Market sector:

PC 13 - Fuels

Sector of use:

SU 8 - Manufacture of bulk, large scale chemicals (including petroleum products)

Environment: ERC 9b

Worker

Filling aircraft fuel taks PROC 9

Use as fuel PROC 16


Control of environmental exposure: Professional end-use stage


Amounts used







34/45






ESVOC 29 ESVOC 29 [Water: 100%; Air: 99.99%; Soil: 100%]









Control of workers exposure for "Filling aircraft fuel taks" [PROC 9]

Inhal*) Derm*)

Loc Sys Loc Sys



Concentration of substance in product < 1 % L

Amounts used





Place of use Outdoors L








L


L




Control of workers exposure for "Use as fuel" [PROC 16]

Inhal*) Derm*)


35/45




Loc Sys Loc Sys



Concentration of substance in product < 1 % L

Amounts used












Respiratory protection Respiratory protection is not used L



9.12.1. Exposure scenario Coatings and Inks sector. Industrial end-use.

Coatings and Inks sector. Industrial end-use.

Market sector: Polymers (PC 32)

Sector of use: SU 3 – Industrial uses

Environment: ERC 6d

Worker

Use in batch PROC 3

Batch process with opportunity of exposure PROC 4




Amounts used

Daily use at a site




Annual use at a site = 1.8E4 m3/d




EFC 3 EFC 3 [Water: 100%; Air: 98.3%; Soil: 100%]


Wastes are incinerated









Control of workers exposure for " Use in batch" [PROC 3]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Medium L

Amounts used








Level of containment Use in closed batch process (synthesis or formulation)

L





Respiratory protection Respiratory protection capable offering a 90% reduction in inhaled concentrations of the

L


37/45




substance


L




Control of workers exposure for "Batch with opportunity of exposure" [PROC 4]

Inhal*) Derm*)

Loc Sys Loc Sys



Dustiness Medium L

Amounts used












Respiratory protection Respiratory protection capable offering a 90% reduction in

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