international quality assurance programme (iqap ... · the test sample also contained glucose,...

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)

INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

Summary ReportSEIZED MATERIALS

2015/1

Samples Substances to be identified from ICE menu Concentrations Comments on substances

Sample 1 Caffeine 0 % quantification not required

Cocaine 5.2 %

Lidocaine (Lignocaine) 0 % quantification not required

Procaine 0 % quantification not required

Sample 2 Amfetamine 5.5 %

Caffeine 0 % quantification not required

Sample 3 [blank sample]

Sample 4 Heroin 72.2 %

Morphine minor component 0 %

Full test Samples Information

Samples Comments on samples

Sample 1 SM-1 was prepared from a seizure containing 5.2 % (w/w) cocaine base. The test sample also contained glucose, caffeine, lidocaine, procaine and trace amounts of creatine and levamisole.

Sample 2 SM-2 was prepared from a seizure containing 5.5 % (w/w) amfetamine base. The test sample also contained caffeine and creatine.

Sample 3 SM-3 was a blank test sample containing no substances from the ICE menu.

Sample 4 SM-4 was prepared from a seizure containing 72.2%(w/w) heroin base. the seizure also contained acetylcodeine, 6-monoacetylmorphine, papaverine, noscapine and trace amounts of morphine.

2015/1-SM Copyright (c) 2015 UNODC

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

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Table of contents Introduction Page 3 Comments from the International Panel of Forensic Experts Page 3 NPS reported by ICE participants Page 4

Codes and Abbreviations Page 7

Sample 1 Analysis Page 8 Identified substances Page 8

Statement of findings Page 12 Identification methods 1

Summary Page 26 Z-Scores Page 27 Sample 2 Analysis Page 31

Identified substances Page 31 Statement of findings Page 35

Identification methods Page 44 Summary Page 49

Z-Scores Page 50

Sample 3 Analysis Page 53

Identified substances Page 53 Statement of findings Page 55 Identification methods Page 60 Summary Page 65

Sample 4 Analysis Page 66

Identified substances Page 66 Statement of findings Page 71 Identification methods Page 80 Summary Page 85

Z-Scores Page 86

quantification not required

Introduction An important element of the UNODC International Quality Assurance Programme (IQAP) is the implementation of the International Collaborative Exercises (ICE). The exercises allow laboratories, from both developing and developed countries, to continuously monitor their performance in drug testing on a truly global scale. This report provides information on analytical results of laboratories participating in the Seized Materials (SM) group. In order to maintain confidentiality, the participating laboratories have been assigned random “Web Codes”, which change every round. The analytical results returned by laboratories participating in ICE are evaluated by UNODC and a confidential report is provided to each laboratory on its own performance. The overall analytical results are reviewed by the UNODC International Panel of Forensic Experts which oversees the implementation of these exercises, and offers guidance and support in addressing relevant quality issues. The exercises provide an overview of the performance and capacity of participating laboratories and enables UNODC to tailor technical support in the laboratory sector for greatest impact.

Comments from the International Panel of Forensic Experts Participation of Laboratories In the 2015/1 round of the ICE programme, results were submitted within both the Seized materials (SM) and Biological Specimens (BS) test groups by 207 laboratories in 66 countries. Within the SM test group, there were 177 participating laboratories from 65 countries and within the BS test group, results were submitted by 85 laboratories from 46 countries. Qualitative Analysis The analytical technique most commonly used for screening of test samples in the SM test group was the marquis reagent (41% of participants), while GC-MS (90%) was the most commonly used technique for identification/confirmation of the components in the test samples followed by FTIR (36%). The results for the qualitative identification of the controlled substances were excellent for all test samples in the SM group as shown in the table 1.

Table 1. Performance of participants for the qualitative analysis in the 2015/1 round of ICE.

Test sample SM-1

(Cocaine) SM-2

(Amfetamine) SM-3 (Blank) SM-4

(Heroin)

Correct identification by participants

98% 92% N/A 98%

With regard to the false positive results for controlled substances in the ICE menu there were a total of thirteen, (two each for SM-1 and SM-4, three for SM-2 and six for the blank test sample of plant material (SM-3). There were a total of eighteen false negative results in the three SM test samples containing controlled substances, 67% of which were for SM-2 where the amfetamine was not identified. While the overall number of false positive/negative results reported by ICE participants is encouragingly low, Laboratories reporting false positive or false negative results should investigate the reasons for this and corrective actions should be taken in order to continuously improve performance. Quantitative Analysis The proportion of participants who carried out quantitative analysis, 127 (72%) for SM-1, 93 (53%) for SM-2 and 122 (69%) for SM-4 continues to be encouraging, particularly the high percentage of participants who quantified the cocaine in SM-1. It is also encouraging to note that 130 (73%) of participants in the SM test group performed quantitation and of these, 94 (72%) quantified all three test samples. It is understood that quantitative analysis of controlled substances is often governed by local legislation and the requirements of prosecution. With regard to the analytical techniques used by participants performing quantitation, 53% used GC-FID, 27% used HPLC and 19% used GC-MS. z-scores obtained by participants in quantification are shown in the table 2 (Percentage and number of laboratories are indicated).

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Table 2. Performance of participants for quantitative analysis in the 2015/1 round of ICE .

z-score Test sample

SM-1 (Cocaine) SM-2 (Amfetamine) SM-4 (Heroin) |z| < 2, satisfactory 81% (103) 82% (76) 80% (98)

2 ≤ |z| ≤ 3, questionable 7% (9) 6% (6) 7% (7) |z| > 3, unsatisfactory 12% (15) 12% (11) 12% (12)

According to the recommendations in ISO 13528:2005, an unsatisfactory z-score is considered to give an action signal and a questionable z-score is considered to give a warning signal. A single action signal or warning signals in two successive rounds shall be taken that an anomaly has occurred that requires investigation. Participants with z-scores outside acceptable limits should review their quantification procedures. In the 2014/2 round of ICE, nine laboratories obtained questionable z-scores with 2 ≤ |z| < 3. Of these laboratories, eight (100%) who performed quantification obtained acceptable z-scores with |z| < 2 in the current 2015/1 round of ICE for at least one substance. However, two of these laboratories still obtained questionable z-scores and two laboratories also obtained unsatisfactory z-scores in 2015/1. Fourteen laboratories obtained unsatisfactory z-scores in ICE 2014/2 with |z| ≥ 3, and of these, ten (71%) improved their performance in quantification in the current 2015/1 ICE round in at least one substance, although seven (50%) still obtained unsatisfactory z-scores in at least one substance in 2015/1. Laboratories that need to perform quantitation routinely are encouraged to participate regularly in external proficiency testing or collaborative exercises such as the ICE programme. This will enable laboratories to assess the quality of their quantitative methods through the z-score values obtained. Laboratories reporting false positive or false negative results should investigate the root causes and corrective actions taken promptly in order to continuously improve performance. Participation in the ICE programme also helps in monitoring the effect of corrective actions. UNODC would like to acknowledge the valuable contribution of the Chemical Metrology Laboratory of the Health Sciences Authority, Singapore, for the provision of specific software used for the quantitative statistical calculations in the ICE programme.

New Psychoactive Substances (NPS) reported by laboratories participating in the 2015/1 round of the ICE programme During the 2015/1 round of ICE, participating laboratories provided information on NPS that had been identified in their laboratories. In total there were 246 reports of 118 substances. The most commonly reported substances were synthetic cannabinoids (33%) followed by synthetic cathinones (29%) and phenethylamine group substances (19%) as shown in figure 1. In general, this is the same trend that was reported in the 2014/2 round of ICE.

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Figure 1. NPS reported by ICE laboratories during the 2015/1 round of ICE

NPS most commonly reported by laboratories participating in ICE 2015/1 The substance most often reported by ICE participants was the synthetic cathinone methylone followed by the phenethylamines DOC (2,5-Dimethoxy-4-chloroamphetamine) and 25I-NBOMe. These were followed by the synthetic cannabinoids, 5F-AKB-48 and AB-CHMINACA. All these are shown in table 3.

Table 3. NPS most commonly reported by ICE participants in the 2015/1 round of ICE

Substance IUPAC name Structure

Methylone 1-(1,3-benzodioxol-5-yl)-2-

(methylamino)propan-1-one

25I-NBOMe 2-(4-iodo-2,5-dimethoxyphenyl)-N-(2-

methoxybenzyl)ethan-1-amine

DOC 1-(4-chloro-2,5-dimethoxyphenyl)propan-2-

amine

33%

19%

29%

4%

9%

2%2% 2%

Synthetic cannabinoids

Phenethylamines

Synthetic cathinones

Tryptamines

Others

Piperazines

Ketamine and phencyclidinetype substances

Aminoindanes

5

5F-AKB-48 N-(adamantan-1-yl)-1-(5-fluoropentyl)-1H-

indazole-3-carboxamide

AB-CHMINACA (S)-N-(1-amino-3-methyl-1-oxobutan-2-yl)-1-

(cyclohexylmethyl)-1H-indazole-3-carboxamide

ICE participants can obtain further details of all the NPS reported to UNODC by logging on to the UNODC ICE portal and selecting the icon for the Early Warning Advisory on New Psychoactive Substances

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Codes and Abbreviations

Tech Code Name

140 Colorimetric reactions

141 Marquis reagent (sulphuric acid, formaldehyde)

142 Cobalt thiocyanate

150 Thin Layer Chromatography

160 High/Ultra High Performance Liquid Chromatography

161 High Performance Liquid Chromatography with diode array detection

170 Gas Chromatography NPD

171 Gas Chromatography FID

172 Gas Chromatography ECD

180 Gas Chromatography/Mass Spectrometry

190 Fourier Transform Infrared Spectrometry

200 Spectrophotometry (visible, UV)

210 Others (specify)

211 NMR

220 Microcrystal test

230 Liquid chromatography/mass spectrometry

231 Liquid chromatography/tandem mass spectrometry

(+) “positive”: Indicates that the analyte is identified; for presumptive tests (e.g. colour reactions), indicates that a positive reaction was obtained.

(-) “negative”: Indicates that the analyte is not identified.

(ANP): Analysis not performed.



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Identified substances for Test Sample 1

Code Identified Substances0B00MA COCAINE

0BPIQK Cocaine

15KHZZ Cocaine

1NBQEB cocaine

1OFS4X Cocaine

1X1W9X Cocaine

20222K Cocaine

2C5GCK Cocaine

2JJEMT cocaine, procaine, lidocaine, caffeine

2KHKFK cocaine

333WNF Cocaine, Lidocaine, Procaine, Caffeine

3I4END Cocaine

3XMCSS COCAINE

4IHDMJ cocaine

4MQGMT cocaine

4QDDDD cocaine hydrochloride

4WAP4I cocaine

5B9R5Q Cocaine

5D5Q5X COCAINE

6HXWOM Cocaine

6I9L3N cocaine

6P0WWW Cocaine, Caffeine, Lidocaine and Procaine

6TZBOI cocaine

72SXT7 Cocaine

7CVHQG Cocaine

88CBR8 Cocaine

8EKCQE cocaine

8P8J9S Cocaine

8Z1D82 Cocaine

999FTE cocaine

9AQQ5Z Cocaine

9E9RV9 Cocaine, Caffeine, Lidocaine and Procaine

9G1IGG cocaine

A55MTH cocaine

AFUPAX Cocaine HCl

AG4RDN Cocaine

AGX9RJ Cocaine

AM75RV Cocaine, Procaine, Lidocaine and Caffeine

ASAZSF Cocaine

ATMMIK Cocaine

Sample 1 Analysis



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Code Identified SubstancesAXEI96 Cocaine, Lidocaine, Procaine and Caffeine

BCQF5M cocaine

BFDDDR Cocaine

BUBXUF COCAÍNE

C0ZZJN COCAINE

C77B7S cocaine

CLWMLL cocaïne

CML6FN Cocaine

CRVCAC cocaine,caffeine,lidocaine,procaine

DF8IPB cocaine

DPMUDD Cocaine, purity 5%

DSTAS1 COCAINE

DXGEZT cocaine

EAEWNG cocaine

EGOAAA cocaine

EH8THK Cocaine

EIUUUK cocaine

EK1CYF Cocaine

EKXNNH cocaine

ERGL66 cocaine, caffeine, lignocaine, procaine

FG6OYO cocaine

FSLFBU Cocaine

FSOGSM Cocaine

FUEK6X COCAINE AND LODOCAINE

G5W4WW Cafeine + Lidocaine + Procaine+ Cocaine

GB3OEY Cocaine

GBX7ZC Cocaine

GFXM5C Cocaina

GGUVGQ Cocaine

GMGJSG Cocaine

GOT2LZ cocaine

GTTTTX COCAINE 5,1% + CAFFEINE + LIDOCAINE + PROCAINE

H22O82 cocaine

HFQF1Q cocain

HKZ1VR Cocaine, Caffeine, Lidocaine.

HPMMRG COCAINE

HUA51A cocaine

HV22C2 cocaine

ICJJYI Cocaine

ILI0KV cocaine

INVI3H cocaine

IO7IOO caffeine, lidocaine and cocaine

IPDQJN Cocaine

ISSSPG COCAINE



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Code Identified SubstancesITHPL9 cocaine

IUPHSS Cocaine

IWH4C5 Cocaine

IWII3P Cocain

JBOJJJ Cocaine

JSAGFJ COCAINE

JZAFXP Amphetamine

KFXSJH cocaína

KHBFT2 Cocaine

KHMABJ cocaine

LHLHFD Cocaine

LZIOS8 Cocaine

MHLLML Cocaine

MMUMRC cocaine

N8RGKU cocaine

NANRGN COCAINE, PROCAINE, LIDOCAINE

NSUV95 Cocaine

NXTOSM cocaine

NYXHZT COCAINE

ODCD2V cocaine

ODZFBN Cocaine

OIXWB8 cocaine

OWVZ9H COCAINE

P5ABC7 COCAINE,CAFFEINE, LIDOCAINE, PROCAINE

P659G5 cocaine, cafeine, lidocaine, procaine and lactose

PVZFPA Cocaine, Procaine, Lidocaine and Caffeine

Q772TV Cocaine

Q8LGQQ Cocaine

QCYBCZ Cocaine and Caffeine

QHH5X6 cocaine

QK1XXA cinnamonyl cocaine - procaine

QMWQTQ Cocaine

QRWM3W Cocaine

QRXCOO Pseudococaine, Caffeine, Lidocaine

QVHXRP COCAINE

QYI8XO COCAINE

QYYLCY Cocaine

R2EIGV Cocaine

RB8OK5 cocaine

RHRRWR cocaine, caffeine, lidocaine, procaine

RIJIJC COCAINE

RJRT8O cocaine

RNIHSP Cocaine

RQJY2X cocaine, lidocaine, caffeine and procaine



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Code Identified SubstancesRQQ9IG cocaine

RRERCL cocaine

RV1ATU Cocaine

S6JCMD cocaine

SEQGAQ cocaine

SFILGT cocaine, lidocaine,procaine, caffeine

SWTTQX Cocaine

TEKB5H cocaine

TFLCTJ cocaine

TK1XDK Cocaine

TMIOPH cocaine

TNQR0R Cocaine

TOTXN0 Cocaine

TRJR2R Cocaine

UJJUU1 COCAINE

UJZXBO Cocaine

UU0EDU cocain

V0TJCT Cocaine

V5A5C5 cocaine

V7777W Cocaine

V7UKSS cocaine

VHRVSQ Cocaine hydrochloride

VIBSI3 COCAINE

VJEFF1 Cocaine

VVRYSV Cocaine, Lidocaine, Procaine, Caffeine and Glucose

VWKVJV cocaine

VWVVHY Cocaine

WATIXT chlorhydrate cocaine

WH4B44 Cocaine

WVV99T COCAINE

X1WS11 cocaine

XI5JGO Cocaine

XIXNGM cocaine

XKKPPR cocaine

XNJQCT Cocaine

XY5KFG ocaine

Y6HBAA Cocaine, Lidocaine , Procaine

YSMOUG Cocaine

YSNVND Cocaine

YZSZMS Cocaína

Z9MTOM Cocaine

ZCYZZA COCAINA

ZO7E6M cocaine HCl



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Code Caffeine Cocaine Lidocaine (Lignocaine) Procaine

0B00MA + + - -

Cocaine hcl, Caffeine, Creatine, purity 3,7+/-0,43 % (w/w)as base cocaine

0BPIQK + + + -

It has been detected the presence of cocaine in the sample.

15KHZZ + + + +

White powder containing cocaine. Also detected caffeine, procaine, lidocaine and cinnamoylcocaine.

1NBQEB + + + +

After analyzing the sample with colorimetrics tests and confirmation with GC/MS methods and subsequent quantifcation with GC/FID, we confident that the sample contains 6.38% of cocaine base. Other substances: caffeine, lidocaine and procaine.

1OFS4X + + + +

Sample contains 5.10 ± 0.20 % cocaine base.Caffeine, lidocaine, procaine and creatine were also detected.

1QHP1K ANP ANP ANP ANP

1X1W9X + + + +

Sample contains 5.3% of cocain

20222K + + + +

The sample contains 5.5% ± 3.6 % of Cocaine. Also contain Caffeine, Lidocaine and Procaine (trace amounts)

2C5GCK + + + +

Presence of cocaine hydrochloride, caffeine, creatine, glucose was detected in the sample.

2JJEMT + + + +

cocaine and adulterants usually found in cocaine seizures

2KHKFK + + + +

we found cocaine, lidocaine, procaine and caffeine in the sample

333WNF + + + +

3I4END + + + +

Caffeine, Lidocaine, Procaine

3XMCSS + + + +

In the sample there are also glucose.

4IHDMJ + + + +

Powder containing cocaine

4MQGMT + + + +

also includes procaine, lidocaine and caffeine

4QDDDD + + + +

Sample also include caffeine, creatine, lidocaine and procaine.

4WAP4I + + + -

cocained existed in salt form. we were found caffeine and lidocaine in the sample

5B9R5Q - + + +

Analysis detected the presence of cocaine with an approximate purity of 6% (as base). Lidocaine and procaine were also detected.

5D5Q5X + + + +

The sample contains a controlled substance as cocaine and other substances besides cutting caffeine, procaine and lidocaine

Statement of findings for Test Sample 1



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6HXWOM + + + +

Caffeine, procaine and lidocaine are also detected.It is a sample of steet cocaine ( as is has common adulterants) with low concentration of cocaine

6I9L3N + + + +

The sample contains cocaine, caffeine, lidocaine and procaine

6P0WWW + + + +

Cocaine 5.29%, Caffeine, Lidocaine, Procaine and Glucose

6TZBOI + + + +

The sample also contain creatine.

72SXT7 + + + +

Test sample 2015/1/SM-1 contains cocaine base 5.59 %, m/m, procaine, caffeine, lidocaine and ceratinine.

7CVHQG + + + -

Lidocaine,Caffeine, Creatinine and trace amount of Glucose

88CBR8 + + + +

we have found cocaine, caffeine, lidocaine and procaine by using GC-MS.

8EKCQE + + + +

also contains lidocaine, procaine and cafeine analyzed by GCMS and HPTLC

8P8J9S + + + +

Sample contains cocaine hydrochloride (6.76% as base), caffeine, lidocaine, procaine and glucose.

8Z1D82 + + + -

The sample SM1 was found to contain the controlled substance Cocaine. In addition it was found to contain Caffeine and Lidocaine.

999FTE + + + +

procaine, caffeine, lidocaine, levamisole

9AQQ5Z + + + +

By using LC-MS and LC-MS-MS , the sample contain Cocaine 5.2 % w/w, Caffiene, Procaine and Lidocaine.

9E9RV9 + + + +

Cobalt thiocyanate (CT) positive, GC/MS retention time and mass charge ratio (M/Z) similar characteristics with the substances used as standard or pattern

9G1IGG + + + +

A55MTH + + + +

We have not received LSD standard

AFUPAX + + + -

SM1 contains Cocaine HCl with 5.4 % Cocaine base.SM1 also contains Lidocaine, Caffeine, Creatinine, Glucose and trace amounts of Procaine

AG4RDN + + + +

This sample is cocaine.

AGX9RJ + + + +

Was found Caffeine, lidocaine and procaine. Cocaine Quantification results: 5.43 +-3.4

AM75RV + + + +

SM-1 gives positive blue color to Cobalt Thiocyanate test. Identification with TLC and GCMS, SM-1 contains Cocaine, Lidocaine, Procaine and Caffeine.Quantitation with GC, SM-1 contains Cocaine base 5.25%, Caffeine 4.95%, Lidocaine 3.8% and Procaine 1.08%.

ASAZSF + + + -

Sample also contain caffeine, lidocaine



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ATMMIK - + + +

A sample of the powder was analysed and found to contain cocaine, which had a purity of 5%. This sample was also found to contain caffeine, lidocaine and procaine

AXEI96 + + + +

Cocaine, Lidocaine, Procaine and Caffeine detected in sample 2015/1/SM-1. Quantitative analysis not performed.

BCQF5M + + + -

SM-1 is positive for cocaine.

BFDDDR ANP + - -

The sample obtains with positive result with cobalt thiocyanate reagent.TLC: The Rf sample obtain with the same Rf Cocaine Standard.GC: The Rt sample obtain with the same Rt Cocaine Standard.

BUBXUF + + + -

The results of the tests of SM1 (58) received confirmed that the mentioned sample contains cocaína with 6.9 percentage by weight (6.9%).The sample 1 contains also caffeín and lidocaíne as not controlled drugs.

C0ZZJN + + + +

Sample 2015/1/SM-1, a white, odourless powder, gave a positive result for cocaine, a controlled substance under national legislation on drugs.

C77B7S + + + +

Identified cocaine

CLWMLL + + + -

The powder contains 6% og cocaïne as free base, lidocaïne 4%, caféine 5% and glucose. Cocaïne is a controlled substance in France.

CML6FN ANP + ANP ANP

Quantity of white powder weighing 0.22grams analysed and confirmed to contain Cocaine. Procaine, Lignocaine and caffeine were indicated however not confirmed.Cocaine is a class A controlled drug within the provisions of the Misuse of Drugs Act 1971.

CRVCAC + + + +

CXZ7SL - + - +

DF8IPB + + + -

- Primary screening revealed cocaïne - GC/MS alowed identification of cocaïne and cutting agents :(lidocaine and caffeine)

DPMUDD + + + +

Cocaine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

DSTAS1 + + + -

COCAINE

DXGEZT + + + +

Cocaine is controlled by law (K.B. 31/12/1930, changed by K.B. 8/10/1963)

EAEWNG + + + -

found cocaine with 5.2%ww

EGOAAA + + + +

cocaine, lidocaine, procaine, caffeine

EH8THK + + + +

The sample contains cocaine. The content of cocaine (as cocainehydrochloride) is determined to 6 %. Cocaine is a controlled substance in Norway.

EIUUUK + + + +

The sample also contains caffeine, lidocaine, procaine and creatine-monohydrate.



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EK1CYF + + + -

sample found to contain cocaine, caffeine and lidocaine

EKXNNH + + + +

The sample contains Cocaine, Lidocaine, Procaine and Caffeine.

ERGL66 + + + +

Powder was found to contain cocaine. purity was determined to be 5% calculated as base.

FG6OYO + + + +

the sample contains cocaine (scheduled as illicit drug in France), caffeine, lidocaine, procaine, creatine, glucose, mannitol

FSLFBU + + + +

The white powder was analysed and found to contain cocaine.

FSOGSM + + + -

Test sample 2015/1/SM-1 contains cocaine, a dangerous drug. It also contains caffeine and lidocaine.

FUEK6X + + + -

THE SAMPLE SM-1 WAS ANALYSED AND FOUND TO TO CONTAIN COCAINE AND LIDOCAINE

G5W4WW + + + +

For sample 2015/1/SM-1 was first a preliminary test to determine the presence of what kind of drugs we have used two Scott reagent tests (tyocianato of Cobalte) and the Marquis reagent. After a TLC and to that end we used a 20 × 20, silica as a solvent dichloromethane was used and how the Methanol eluent. Finally there was a gas chromatography using flame Ionization Detector (GC-FID), in the preparation of the samples used as solvent, chloroform/ethanol mixture and tetracosano (internal standard), and the column TRACSIL TRB-50 (50%) Diphenyl-(50%) dimethyl polysiloxane, Flow Rate of 1.5 ml/min and Pressure of 14.7 psi.

GB3OEY + + + -

One glass bottle containing 0.23 grammes of a powder containing 0.01 grammes of cocaine.

GBX7ZC ANP + ANP ANP

GFXM5C + + + -

The chemical tests and the coincidence in the time of retention and mass fragmentogram with the material of reference used in the same conditions that the analyzed sample, indicate in this one the cocaine presence.

GGUVGQ + + - +

GMGJSG + + + +

cocaine+Procaine+Lidocaine+Cafine

GOT2LZ + + + +

COCAINE 5.9% AS BASE, caffeine, lidocaine and procaine

GTTTTX + + + +

H22O82 + + + -

The sample contained 5.1% w/w Cocaine.Substances detected include Caffeine and Lidocaine.

HFQF1Q + + + -

lidocain 4.8 %, caffein 5.08%, parcetamol 1.4 %

HKZ1VR + + + -

The Sample ICE2015/1/SM1 was found to contain Cocaine, Caffeine and Lidocaine.

HPMMRG + + + -

LIDOCAINE AND CAFEINE



15


HUA51A + + + -

cocaine, caffeine, lidocaine

HV22C2 + + + +

cocaine(5%), cafeine, procaine (1%),lidocaine(4%)

ICJJYI + + + -

quantification results: 5,1% +/- 0,5

ILI0KV + + + -

cocaine was detected by GC/MS screening and it was quantified by GC/FID using calibration curve

INVI3H + + + -

a substance is related to drug - cocaine

IO7IOO + + + ANP

the sample SM1 contains caffeine, lidocaine and cocaine

IPDQJN + + + -

Cocaine

ISSSPG + + + -

COCAINE-LIDOCAINE Y CAFFEINE

ITHPL9 + - + +

contained glucose, caffeine, lidocaine, procaine

IUPHSS + + + -

The sample contains cocaine

IWH4C5 + + + +

Lidocaine, Procaine, Caffeine

IWII3P + + + +

6.5%

JBOJJJ + + + +

The sample contains cocaine (5.6%), lidocaine, caffeine and procaine.

JMMMUB + + + -

JSAGFJ - + - -

Field Test was performed employing Cobalt Thiocynate test gave a positive result for the presence of Cocaine.

JZAFXP - - - -

Sample no1 contains stimulant (Amphetamine)

KFXSJH + + + +

pruebas cromáticas, marquis, Scottinstrumentales: GC-MS, ESPECTROMETRIA UV

KHBFT2 ANP + ANP ANP

Contains Cocaine.

KHMABJ + + + -

The sample contains cocaine, creatine, caffeine and lidocaine.

LHLHFD + + + +

Cocaine, Lidocaine, Procaine and Caffeine

LZIOS8 + + + +

The percentage of cocaine is 6.1 %

MHLLML + + + +

Usual substance and adulterants.

MMUMRC + + + +

contained caffeine, lidocaine, procaine, methylecgonidine,glucose,creatinine



16


N8RGKU + + + +

Sample 2015/1/SM-1 consists of white powder. Cocaine, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample.

NANRGN + + + +

In the sample are caffeine, levamisole and other cinnamoleocaina such as cis-, and trans-cinnamo leocaine

NSUV95 + + + +

The exhibit were found to contain Cocaine, Methyl Ester Ecgonidine, Lidocaine, Procaine and Caffeine.

NXTOSM + + + ANP

NYXHZT + + + +

PROCAINE, LIDOCAINE, CAFFEINE

ODCD2V + + + +

Cocaine, caffeine, lidocaine, procaine, phenyltetrahydroimidathiazole, creatine, and dextrose confirmed in 1 unit tested of 1 unit received.

ODZFBN + + + +

The sample contains cocaine, caffeine, procaine, lidocaine and creatine.

OIXWB8 + + + +

cocaine 5.8%ww, caffeine, lidocaine, procaine, glucose

OWVZ9H + + - +

White powder that contains controlled substance COCAINE.

P5ABC7 + + + +

WHITE POWDER SAMPLE ANALYZED CONTAINS : COCAINE,CAFFEINE, LIDOCAINE, PROCAINE.

P659G5 + + + +

PVZFPA + + + +

Examination revealed the presence of Cocaine, Procaine and Lidocaine

Q772TV + + + -

Caffeine and Lidocaine

Q8LGQQ + + + +

*Results of screening tests were positive for cocaine. *Retention time and fragmentation pattern obtained with sample are equivalent to those obtained with cocaine, lidocaine, procaine and caffeine.

QCYBCZ + + - -

Caffeine is not included in UN notified precursor chemicals. But in our country, Myanmar, we notified it as precursor chemical.

QHH5X6 + + + +

white powder containing caffeine and cocaine

QK1XXA + + + -

QMWQTQ + + + +

Cocaine was identified in the sample and also Caffeine, Lidocaine and Procaine were identified.Further analysis revealed that the percentage of cocaine is 36.3.

QRWM3W + + + +

Caffeine, Lidocine and procaine

QRXCOO + + + -

Blue color appear with Cobalt Thiocyanate test and blue color reappear in the lower chloroform layer by modified Cobalt Thiocyanate test which indicates possible presence of Cocaine.Purple color with Amalic Acid test indicates possible presence of caffeine. Analysis by GCMS show the similarity as pseudococaine, caffeine and lidocaine.



17


QVHXRP + + + +

CREATINE, CAFFEINE AND OTHER COCA PRODUCTS WERE IDENTIFIED

QYI8XO + + + +

The sample contains ; Cocaine , Lidocaine, Caffeine and Procaine

QYYLCY + + + +

the sample contains cocaine,caféine, lidocaine,et procaine. Cocaine is scheduled as illicit drug.

R2EIGV + + + +

In the test sample 2015/1/SM-1 were detected cocaine, caffeine, lidocaine and procaine

RB8OK5 + + + -

No determinado con creatina monohidrato, lidocaina y cafeina

RHRRWR + + + +

The sample was found to contain cocaine, lidocaine, procaine and caffeine.

RIJIJC + + + -

the powder is a mixture of cocaine hydrochloride, glucose, creatine hydrate, caffeine and lidocaine. The concentration of cocaine, as free base, in the sample is 6.5% by weight.

RJRT8O + + + +

Cocaine was as hydrochloride form

RNIHSP + + + +

RQJY2X + + + +

In the sample labeled as 2015/1 / SM-1 was found cocaine, procaine, lidocaine and caffeine.

RQQ9IG + + + ANP

after chemical analysis was performed the sample contain . 1- cocaine 7.55%2- caffeine 3- lidocaine

RRERCL + + + +

RV1ATU + + + +

Presence of caffeine, lidocaine and procaine. FTIR analysis detected the presence of creatine.

S6JCMD + + + +

The sample was found to contain 5.3% of cocaine (as base). The sample was also found to contain caffeine, lidocaine, procaine, fructose and glucose.

SEQGAQ - + - -

sample contained cocaine HCl as a controlled drug

SFILGT + + + +

SWTTQX + + - -

Cocaine and caffeine are detected.

TEKB5H + + + -

the white powder contains cocaine (5.2%ww) which is controlled by national laws. In addition caffeine and lidocaine have been found in the sample.

TFLCTJ + + + +

TK1XDK - + + -

The sample found to contain Cocaine

TMIOPH + + + -

The sample contain cocaine, caffeine, lidocaine and creatine.



18


TNQR0R + + + +

contained cocaine, lidocaine, cofeine, procaine, creatinine and trace of methylecgonidine, cinnamoilcocaine. cis-cinnamoilcocaine

TOTXN0 + + + +

The sample contains cocaine, lidocaine, procaine and caffeine.

TRJR2R + + + +

caffeinecreatinelidocaineprocaine

UJJUU1 + + + -

Cocaine is a Class A controlled drug under the provisions of the Misuse of Drugs Act 1971 (as amended).

UJZXBO + + + +

The test sample 2015/1/SM-1 was found to contain the controlled drug cocaine. The sample was also found to contain caffeine, lidocaine and procaine.

UU0EDU + + + +

adulterant/diluents: caffeine, creatine, prokain, lidokain

V0TJCT + + + +

V5A5C5 + + + +

the sample is mxture of cocaine with lidocaine, procaine, caffeine and creatinine

V7777W + + + +

The powder was found to contain 5% cocaine; caffeine, lignocaine and procaine were also detected. Cocaine is controlled by the Misuse of Drugs Act (as amended) as a Class A drug. Caffeine, lignocaine and procaine are not controlled by the Misuse of Drugs Act 1971 (as amended).

V7UKSS + + + -

Narcotics: cocaine, approximately 6 % as free base

VHRVSQ + + + +

Item 2015/1/SM-1 contained Cocaine hydrochloride, at a purity of six per cent.

VIBSI3 + + + -

VJEFF1 - + + -

The sample contains cocaine which is listed as a controlled drug according to french order, appendix I of February 22nd 1990.

VVRYSV + + + +

The Test sample 2015/1/SM-1 was analyzed by colour test and Thin Layer Chromatography technique and found to contain Cocaine, Lidocaine, Procaine, Caffeine and Glucose.

VWKVJV + + + +

VWVVHY + + + +

WATIXT + + + +

chlorhydrate cocaïne is present (6.3% w/w as base) with caffeine lidocaine procaïne creatine and glucose.

WH4B44 ANP + ANP ANP

-

WVV99T + + + +

White powder containing Cocaine (List I CU 1961) 5.63% and other substances as adulterants: Caffeine, Lidocaine and Procaine



19


X1WS11 ANP + ANP ANP

XI5JGO + + + -

XIXNGM + + + +

./.

XKKPPR + + + +

white powder, other compounds - caffeine, lidocaine and procaine

XNJQCT + + + +

The sample contained cocaine with lidocaine, procaine and caffeine.

XODXXJ + + + +

XRRKRK + + + +

XY5KFG ANP + ANP +

There was evidence that the test sample 2015/1/SM-1 contained cocaine

Y6HBAA + + + +

The sample contains Cocaine Hydrochloride (8.2% as base) with Lidocaine, Procaine and Caffeine.

YN88GB - - ANP ANP

No se detectó

YSMOUG + + + +

Based on the above analysis, the sample was found to contain cocaine, lidocaine, procaine, caffeine and levamisole.

YSNVND + + + +

We found cocaine as controlled drug and also lidocaine, procaine, and caffeine as adulterants

YZSZMS + + + -

La muestra contiene además cafeína y lidocaína

Z9MTOM + + + +

caffeine, lidocaine, procaine, glucose and creatine

ZCYZZA + + + +

CAFEINA - LIDOCAINA - PROCAINA

ZO7E6M + + + +

additional substances: creatine, lidocaine, procaine, caffeine



20

Identification methods for Test Sample 1

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

0B00MA S S S I I I XRD

0BPIQK SI I

15KHZZ S I I SI

1NBQEB SI SI S I I

1OFS4X S SI I SI SI

1X1W9X SI

20222K S I I

2C5GCK SI I I I

2JJEMT SI I

2KHKFK I SI I

333WNF S S S I I

3I4END I SI

3XMCSS SI I

4IHDMJ SI

4MQGMT SI SI

4QDDDD S I I I

4WAP4I S I I I

5B9R5Q S S S I I

5D5Q5X S I SI

6HXWOM I I SI I

6I9L3N S S S I S

6P0WWW S I

6TZBOI S SI SI I

72SXT7 I SI

7CVHQG S I I

88CBR8 SI

8EKCQE SI SI I I

8P8J9S S S I

8Z1D82 I S

999FTE SI

9AQQ5Z SI I

9E9RV9 S S S I

9G1IGG SI I

A55MTH I

Analytical Technique Codes

Legend: S ... used for Screening I ... used for Identification SI ... used for both



21

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

AFUPAX I S I I

AG4RDN S I I

AGX9RJ S S S I I

AM75RV S S S I I

ASAZSF SI ASAP-TOF

ATMMIK S S I S Miscroscopy

AXEI96 S SI

BCQF5M S I

BFDDDR S S S I

BUBXUF S S S I I

C0ZZJN S S S I

C77B7S S S S SI

CLWMLL I I I S I GC MS + Derivatization

CML6FN S I

CRVCAC I SI SI

CXZ7SL S I

DF8IPB S I I

DPMUDD S S S I

DSTAS1 SI I

DXGEZT S I S

EAEWNG SI

EGOAAA SI

EH8THK I I

EIUUUK S SI SI I

EK1CYF S I I I

EKXNNH S S S I SI I

ERGL66 I I

FG6OYO S I I I

FSLFBU S I I

FSOGSM S S S I I I Chen Kao Reagent

FUEK6X S S I I

G5W4WW

S S S I I

GB3OEY S S SI

GBX7ZC I

GFXM5C S S S I

GGUVGQ SI

GMGJSG I S ION-SCAN

GOT2LZ S S S I

GTTTTX S S S SI I I



22

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

H22O82 S S S I I I

HFQF1Q SI

HKZ1VR S S S I I

HPMMRG I SI

HUA51A S S S SI I SI

HV22C2 S I I

ICJJYI S I

ILI0KV SI

INVI3H SI

IO7IOO S S S I S Tanred

IPDQJN I SI SI

ISSSPG S S S I I

ITHPL9 SI

IUPHSS I SI I

IWH4C5 SI I

IWII3P SI

JBOJJJ S S S I I

JMMMUB S S SI I I I

JSAGFJ S S S I I I S TEST STRIPS

JZAFXP I SI SI immunoassay

KFXSJH S S SI I I

KHBFT2 S S S I I

KHMABJ S S SI SI I

LHLHFD SI SI I

LZIOS8 S S S I I SI S I Tollens reag.

MHLLML S I I I SI FEHLING

MMUMRC SI

N8RGKU S S I I I

NANRGN S S I I I cloruro de mercurio

NSUV95 I I S

NXTOSM S S S I

NYXHZT S S S SI I

ODCD2V I SI I

ODZFBN I I

OIXWB8 I I SI

OWVZ9H S S I I

P5ABC7 S S I

P659G5 S S I I

PVZFPA S SI



23

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Q772TV S I

Q8LGQQ S S S I I

QCYBCZ I I SI

QHH5X6 SI

QK1XXA S S S SI SI I I

QMWQTQ

I S S I I I I I fast blue B

QRWM3W

I SI

QRXCOO S S S I SI Amalic Acid test

QVHXRP I SI I

QYI8XO S I I

QYYLCY I SI I

R2EIGV I

RB8OK5 S I I

RHRRWR S I

RIJIJC I I I SI I SI XRD

RJRT8O SI

RNIHSP S S I I

RQJY2X S S I

RQQ9IG S S I

RRERCL S S S I I

RV1ATU I I I SI

S6JCMD SI I ELSD

SEQGAQ S S I I S n.a.

SFILGT I SI I

SWTTQX S S I

TEKB5H I I SI

TFLCTJ I SI

TK1XDK S S I

TMIOPH S SI I SI I

TNQR0R SI

TOTXN0 SI

TRJR2R SI SI

UJJUU1 S S I I S PIPERAZINES

UJZXBO S S S I I

UU0EDU I SI SI

V0TJCT S I I

V5A5C5 S S SI I I I I

V7777W S S I



24

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

V7UKSS I SI I

VHRVSQ S I I

VIBSI3 SI S

VJEFF1 I I

VVRYSV S S I S Fast Blue B Salt Test

VWKVJV SI

VWVVHY S I

WATIXT I I

WH4B44 SI

WVV99T S S S I SI

X1WS11 SI SI SI I

XI5JGO S S SI

XIXNGM I SI SI

XKKPPR SI I

XNJQCT SI

XODXXJ SI I

XRRKRK S S I S Duquenois levin

XY5KFG SI I

Y6HBAA SI S S I I

YN88GB S S I I

YSMOUG S I S Simon reagent

YSNVND S S SI I S Duquinoise

YZSZMS S S S I I

Z9MTOM S I I

ZCYZZA S I I

ZO7E6M SI I XRD



25


Frequency of use of screening and identification techniques:

Summary for test sample 1The response summary of all 177 participating laboratories for the identification of SM-1, frequency of use of screening andidentification techniques and false positives and negatives:

Identification of test sample 1:

False positives for Test Sample 1

Code Name Technique

Response Summary Participants: 130

ITHPL9 Cannabidiol 180

JZAFXP Amfetamine 161/180

False negatives for SM-1 (techinque(s) used or ANP)

Code: ITHPL (180), JZAFXP (161/180), YN88GB (150), IQHPIK (ANP)

142 150 160 161 190 200 220

Response SummaryParticipants: 177

Caffeine: 160

Cocaine: 173

Lidocaine (Lignocaine): 159

Procaine: 116

Section 140 141 142 150 160 161 170 171 180 190 200 211 231 210


Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 67 72 62 20 0 2 1 3 71 11 3 0 1 1 15

37.9% 40.7% 35.0% 11.3% 0.0% 1.1% 0.6% 1.7% 40.1% 6.2% 1.7% 0.0% 0.6% 0.6% 8.5%

Identification 9 3 2 44 12 19 2 29 159 60 5 2 1 4 13

5.1% 1.7% 1.1% 24.9% 6.8% 10.7% 1.1% 16.4% 89.8% 33.9% 2.8% 1.1% 0.6% 2.3% 7.3%

# labs using this technique

73 72 62 51 12 19 2 30 160 63 8 2 1 4 23

41.2% 40.7% 35.0% 28.8% 6.8% 10.7% 1.1% 16.9% 90.4% 35.6% 4.5% 1.1% 0.6% 2.3% 13.0%


26

Z-Scores for Test Sample 1



Concentration (mass%)

Deviation from robust average

z-scoreConcentration

(mass%)

Deviation from robust

averagez-score

BFDDDR 1.45 4.0 -8.4 DPMUDD 5.30 0.1 -0.3GGUVGQ 2.70 2.7 -5.8 QYYLCY 5.30 0.1 -0.30B00MA 3.70 1.7 -3.7 S6JCMD 5.30 0.1 -0.3JSAGFJ 4.04 1.4 -3.0 TNQR0R 5.30 0.1 -0.3VIBSI3 4.20 1.2 -2.6 VJEFF1 5.30 0.1 -0.39G1IGG 4.40 1.0 -2.2 XODXXJ 5.34 0.1 -0.2HUA51A 4.50 0.9 -2.0 QRXCOO 5.37 0.0 -0.2GB3OEY 4.60 0.8 -1.8 QRWM3W 5.38 0.0 -0.2ODCD2V 4.70 0.7 -1.6 4IHDMJ 5.40 0.0 -0.1DSTAS1 4.70 0.7 -1.6 AFUPAX 5.40 0.0 -0.1RJRT8O 4.80 0.6 -1.4 NXTOSM 5.40 0.0 -0.1WH4B44 4.85 0.6 -1.3 ODZFBN 5.40 0.0 -0.188CBR8 4.86 0.5 -1.3 R2EIGV 5.40 0.0 -0.13XMCSS 4.90 0.5 -1.2 VWVVHY 5.40 0.0 -0.12KHKFK 5.00 0.4 -1.0 XIXNGM 5.40 0.0 -0.1CML6FN 5.00 0.4 -1.0 XKKPPR 5.40 0.0 -0.1ERGL66 5.00 0.4 -1.0 AGX9RJ 5.43 0.0 -0.1FG6OYO 5.00 0.4 -1.0 4QDDDD 5.45 0.0 0.0HV22C2 5.00 0.4 -1.0 V7UKSS 5.45 0.0 0.0TRJR2R 5.00 0.4 -1.0 ATMMIK 5.46 0.1 0.0UJJUU1 5.00 0.4 -1.0 QHH5X6 5.46 0.1 0.0V7777W 5.00 0.4 -1.0 20222K 5.50 0.1 0.1X1WS11 5.09 0.3 -0.8 4WAP4I 5.50 0.1 0.11OFS4X 5.10 0.3 -0.8 5B9R5Q 5.50 0.1 0.14MQGMT 5.10 0.3 -0.8 ISSSPG 5.50 0.1 0.18Z1D82 5.10 0.3 -0.8 IWH4C5 5.50 0.1 0.1GFXM5C 5.10 0.3 -0.8 RB8OK5 5.50 0.1 0.1GTTTTX 5.10 0.3 -0.8 IUPHSS 5.56 0.2 0.2H22O82 5.10 0.3 -0.8 MHLLML 5.58 0.2 0.3ICJJYI 5.10 0.3 -0.8 72SXT7 5.59 0.2 0.3

MMUMRC 5.10 0.3 -0.8 999FTE 5.59 0.2 0.3Q8LGQQ 5.10 0.3 -0.8 IO7IOO 5.60 0.2 0.3RV1ATU 5.10 0.3 -0.8 JBOJJJ 5.60 0.2 0.3Z9MTOM 5.10 0.3 -0.8 TOTXN0 5.60 0.2 0.3RV1ATU 5.10 0.3 -0.7 CRVCAC 5.62 0.2 0.3A55MTH 5.15 0.3 -0.6 HFQF1Q 5.63 0.2 0.4P659G5 5.19 0.2 -0.6 WVV99T 5.63 0.2 0.49AQQ5Z 5.20 0.2 -0.5 2C5GCK 5.70 0.3 0.5EAEWNG 5.20 0.2 -0.5 DXGEZT 5.70 0.3 0.5EH8THK 5.20 0.2 -0.5 AG4RDN 5.72 0.3 0.6TEKB5H 5.20 0.2 -0.5 6HXWOM 5.80 0.4 0.7VWKVJV 5.20 0.2 -0.5 EKXNNH 5.80 0.4 0.73I4END 5.23 0.2 -0.5 KHMABJ 5.80 0.4 0.7QVHXRP 5.24 0.2 -0.5 OIXWB8 5.80 0.4 0.7AM75RV 5.25 0.2 -0.4 YZSZMS 5.80 0.4 0.7333WNF 5.28 0.1 -0.4 ITHPL9 5.81 0.4 0.7IPDQJN 5.28 0.1 -0.4 NYXHZT 5.83 0.4 0.8

6P0WWW 5.29 0.1 -0.4 GOT2LZ 5.90 0.5 0.9RRERCL 5.29 0.1 -0.41X1W9X 5.30 0.1 -0.36I9L3N 5.30 0.1 -0.3

Code

Cocaine

Code

Cocaine

27



Concentration (mass%)

Deviation from robust

averagez-score

7CVHQG 6.00 0.6 1.18EKCQE 6.00 0.6 1.1CLWMLL 6.00 0.6 1.1VHRVSQ 6.00 0.6 1.1LZIOS8 6.10 0.7 1.4Q772TV 6.10 0.7 1.4ILI0KV 6.27 0.9 1.7C77B7S 6.30 0.9 1.8WATIXT 6.30 0.9 1.8ZO7E6M 6.30 0.9 1.81NBQEB 6.40 1.0 1.9IWII3P 6.50 1.1 2.2RIJIJC 6.50 1.1 2.2XI5JGO 6.70 1.3 2.68P8J9S 6.76 1.4 2.7BUBXUF 6.90 1.5 3.00BPIQK 7.00 1.6 3.3RQQ9IG 7.55 2.2 4.4V5A5C5 7.56 2.2 4.45D5Q5X 7.90 2.5 5.1DF8IPB 7.98 2.6 5.3Y6HBAA 8.20 2.8 5.8TFLCTJ 9.85 4.5 9.3KFXSJH 11.30 5.9 12.3BCQF5M 13.42 8.0 16.8FUEK6X 14.96 9.6 20.0INVI3H 35.65 30.3 63.6

QMWQTQ 36.30 30.9 65.0

Cocaine

Code

28

Substance: SM-1; Cocaine

Round: 2015/1

Z-Score Report per Sample per Substance

Robust average = 5.4%UNODC value = 5.2%

z-scores can be interpreted by participants in line with ISO 13528:2005, section 7.4.2 and ISO/IEC guide43-1:1997(E) as follows:

|z| < 2 = satisfactory 2 ≤ |z| ≤ 3 = questionable

|z| > 3 = unsatisfactory

According to the recommendations in ISO 13528:2005, an unsatisfactory z-score is considered to give an action signal and a questionable z-score is considered to give a warning signal. A single action signal or warning signals in two successive rounds shall be taken that an anomaly has occurred that requires investigation.

29

‐3.7

‐3.0

‐2.6

‐2.2‐2.0‐1.8‐1.6 ‐1.6 ‐1

.4 ‐1.3

‐1.3 ‐1.2‐1.0

‐1.0

‐1.0

‐1.0

‐1.0

‐1.0

‐1.0

‐1.0‐0.8 ‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8

‐0.8 ‐0.7 ‐0.6 ‐0.6

‐0.5

‐0.5

‐0.5

‐0.5

‐0.5 ‐0.5

‐0.5 ‐0.4 ‐0.4

‐0.4

‐0.4

‐0.4

‐0.3

‐0.3

‐0.3

‐0.3

‐0.3

‐0.3

‐0.3 ‐0.2 ‐0.2

‐0.2 ‐0.1

‐0.1

‐0.1

‐0.1

‐0.1

‐0.1

‐0.1

‐0.1 ‐0.1 0.0

0.0

0.0

0.0 0.1

0.1

0.1

0.1

0.1

0.1 0.

2 0.3 0.3

0.3 0.3

0.3

0.3 0.3 0.4

0.4 0.

50.5 0.6 0.

70.7

0.7

0.7

0.7 0.7 0.8 0.

91.1

1.1

1.1

1.11.4

1.4

1.7 1.8

1.8

1.8 1.

92.2

2.2

2.6 2.

73.03.3

‐4.0

‐3.0

‐2.0

‐1.0

0.0

1.0

2.0

3.0

4.0

BFDD

DR

GGUVG

Q0B

00MA

JSAG

FJVIBSI3

9G1IGG

HUA5

1AGB3

OEY

DSTAS

1ODC

D2V

RJRT

8OWH4

B44

88CB

R83X

MCSS

FG6O

YOTR

JR2R

ERGL66

2KHKFK

HV22

C2CM

L6FN

UJJUU1

V7777W

X1WS11

RV1A

TUQ8LGQQ

GFXM

5C1O

FS4X

8Z1D

82H22

O82

Z9MTO

MGT

TTTX

ICJJYI

4MQGM

TMMUMRC

RV1A

TUA5

5MTH

P659

G5

VWKV

JVEA

EWNG

TEKB

5HEH

8THK

9AQQ5Z

3I4E

ND

QVH

XRP

AM75

RV33

3WNF

IPDQ

JNRR

ERCL

6P0W

WW

6I9L3N

QYYLCY

VJEFF1

1X1W

9XS6JCMD

TNQR0

RDPM

UDD

XODX

XJQRX

COO

QRW

M3W

VWVV

HY

XIXN

GM

4IHDM

JAF

UPA

XXK

KPPR

ODZFBN

R2EIGV

NXTOSM

AGX9

RJ4Q

DDDD

V7UKSS

QHH5X

6AT

MMIK

RB8O

K520

222K

ISSSPG

IWH4

C55B

9R5Q

4WAP

4IIUPH

SSMHL

LML

72SXT7

999FTE

IO7IOO

TOTX

N0

JBOJJJ

CRVC

ACHFQ

F1Q

WVV

99T

DXGEZT

2C5G

CKAG

4RDN

OIXWB8

YZSZMS

KHMAB

J6H

XWOM

EKXN

NH

ITHP

L9NYXHZT

GOT2

LZ7C

VHQG

8EKC

QE

CLWMLL

VHRV

SQQ772T

VLZIOS8

ILI0KV

WAT

IXT

ZO7E

6MC7

7B7S

1NBQ

EBRIJIJC

IWII3

PXI5JGO

8P8J9S

BUBX

UF

0BPIQK

RQQ9IG

V5A5

C55D

5Q5X

DF8IPB

Y6HBA

ATFLCTJ

KFXSJH

BCQF5M

FUEK

6XINVI3H

QMWQTQ

‐8.4

63.6205.8

9.35.35.1 65

16.812.34.4

4.4

Round: 2015/1


-10.0

-8.0

-6.0

-4.0

-2.0

0.0

2.0

4.0

6.0

8.0

10.0

z-sc

ore

Dispersion of z-scores using different analytical techniques for the quantification of cocaine in 2015/1 SM-1

HPLC GC-FID GC/MS

30


Code Identified Substances0B00MA AMPHETAMINE

0BPIQK amphetamine

15KHZZ Amphetamine

1NBQEB amphetamine

1OFS4X Amfetamine

1X1W9X Amphetamine

20222K Amfetamine

2C5GCK Amphetamine

2JJEMT amphetamine, caffeine

2KHKFK Amphetamine

333WNF Amphetamine, Caffeine

3I4END Amphetamine

3XMCSS AMPHETAMINE

4IHDMJ amphetamine

4MQGMT amphetamine

4QDDDD amphetamine sulphate

4WAP4I amfetamine

5B9R5Q Amphetamine

5D5Q5X AMPHETAMINE

6HXWOM Amphetamine

6I9L3N anfetamine

6P0WWW Amphetamine and Caffeine

6TZBOI amphetamine

72SXT7 Amphetamine

7CVHQG Amfetamin

88CBR8 amfetamine

8EKCQE amfetamine

8P8J9S Amphetamine

8Z1D82 Amphetamine

999FTE amphetamine

9AQQ5Z Amphtamine

9E9RV9 Caffeine

9G1IGG amphetamine

AFUPAX Amfetamine Sulphate

AG4RDN Amphetamine

AGX9RJ amphetamine

AM75RV Amphetamine and Caffeine

ASAZSF Amphetamine

ATMMIK Amphetamine

AXEI96 Amphetamine and Caffeine

Sample 2 Analysis



31

Code Identified SubstancesBCQF5M Amphetamine

BFDDDR Amphetamine

BUBXUF AMPHETAMINE

C0ZZJN AMPHETAMINE

C77B7S Amphetamine

CLWMLL Amfétamine

CML6FN Amphetamine

CRVCAC amfetamine,caffeine

DF8IPB Amphetamine

DPMUDD Amfetamine, purity 5%

DSTAS1 AMFETAMINE

DXGEZT Amfetamine

EAEWNG amfetamine

EGOAAA amphetamines

EH8THK Amphetamine

EIUUUK amfetamine

EK1CYF Amphetamine

EKXNNH Amfetamine

ERGL66 Amphetamine, caffeine

FG6OYO amphetamine

FSLFBU Amphetamine

FSOGSM Amphetamine

G5W4WW Methanphetamine + Cafeine

GB3OEY Amphetamine

GBX7ZC Anphetamine

GFXM5C Amfetamine

GGUVGQ Amphetamine

GMGJSG Amfetamine

GOT2LZ amphetamine

GTTTTX ANFETAMINE 5,9 % + CAFFEINE

H22O82 Amphetamine

HFQF1Q amfetamin

HKZ1VR Amphetamine, Caffeine.

HPMMRG AMPHETAMINE

HUA51A amfetamine

HV22C2 amphetamine

ICJJYI amphetamine

ILI0KV amfetamine

IO7IOO amphetamine and caffeine

IPDQJN Amphetamine

ISSSPG AMFETAMINE

ITHPL9 amfetamine

IUPHSS Amphetamine

IWH4C5 Amphetamine



32

Code Identified SubstancesIWII3P Amphetamine

JBOJJJ Amfetamine

JSAGFJ Amphetamine and Paracetamol

JZAFXP cocaine, lidocaine, procaine, caffeine

KFXSJH ANFETAMINA

KHBFT2 Amphetamine

KHMABJ amphetamine

LHLHFD Amfetamine

LZIOS8 Amfetamine

MHLLML Amphetamine

MMUMRC amfetamine

N8RGKU amfetamine

NANRGN amphetamine

NXTOSM amfetamine

NYXHZT AMFETAMINE

ODCD2V d,l amphetamine

ODZFBN Amphetamine

OIXWB8 d-l-amfetamine

OWVZ9H AMPHETAMINE

P5ABC7 AMPHETAMINE, CAFFEINE

P659G5 amphetamine and cafeine

PVZFPA Amphetamine and Caffeine

Q772TV Amphetamine

Q8LGQQ Amfetamine

QCYBCZ Caffeine

QHH5X6 amfetamine

QK1XXA n- benzyl -2 methyl aziridin

QRWM3W Amfetamine

QRXCOO Amfetamine, Caffeine

QVHXRP AMFETAMINE

QYI8XO Amfetamine

QYYLCY Amphetamine

R2EIGV Amfetamine

RB8OK5 amfetamine

RHRRWR amphetamine, caffeine

RIJIJC amfetamine

RJRT8O amfetamine

RNIHSP Amphetamine

RQJY2X caffeine and amphetamine

RQQ9IG amphetamine

RRERCL amphetamine

RV1ATU Amphetamine

S6JCMD amphetemine

SEQGAQ amfetamine



33

Code Identified SubstancesSFILGT amphetamine, caffeine

SWTTQX Alpha Methyl Benzeneethanamine and caffeine are detected.

TEKB5H amfetamine

TFLCTJ amfetamine

TK1XDK Amphetamine

TMIOPH amphetamine

TNQR0R Amfetamine

TOTXN0 Amfetamine

TRJR2R amfetamine

UJJUU1 AMPHETAMINE

UJZXBO Amphetamine

UU0EDU amphetamine

V0TJCT Amfetamine

V5A5C5 amphetamine

V7777W Amphetamine

V7UKSS amphetamine

VHRVSQ Amphetamine

VIBSI3 amfetamine

VJEFF1 Amfetamine

VVRYSV Caffeine

VWKVJV sulfat amphetamine

VWVVHY Amphetamine

WATIXT sulphate amfetamine

WH4B44 Amfetamine

WVV99T Amfetamine

X1WS11 anfetamine

XI5JGO Amphetamine

XIXNGM AMFETAMINE

XKKPPR amphetamine

XNJQCT Amphetamine

XY5KFG Mescaline

Y6HBAA Amphetamine

YN88GB Cafeína

YSMOUG Amphetamine

YSNVND Amphetamine

YZSZMS Amfetamina

Z9MTOM amfetamine

ZCYZZA ANFETAMINA

ZO7E6M amphetamine sulphate



34

Code Amfetamine Caffeine

0B00MA + +

Amphetamine sulphate, Caffeine, Creatinepurity 6,4% as base amphetamine

0BPIQK + +

It has been detected the presence of amphetamine in the sample.

15KHZZ + +

White powder containing amphetamine. Also detected caffeine.

1NBQEB + +

After analyzing the sample with colorimetrics tests and confirmation with GC/MS methods and subsequent quantifcation with GC/FID, we confident that the sample contains 5.01% of amphetamine base. Other substances: caffeine.

1OFS4X + +

Sample contains 5.55 ± 0.43 % amfetamine base.Caffeine and creatine were also detected.

1QHP1K ANP ANP

1X1W9X + +

Sample contains 5.6 % of amphetamine

20222K + +

Also contain Caffeine

2C5GCK + +

Presence of amphetamine sulphate, caffeine, creatine was detected in the sample.

2JJEMT + +

2KHKFK + +

we found amphetamine and caffeine in the sample

333WNF + +

3I4END + +

Caffeine

3XMCSS + +

4IHDMJ + +

Powder containing amphetamine

4MQGMT + +

also includes caffeine

4QDDDD + +

Sample also include caffeine, creatine.

4WAP4I + +

we were found caffeine in the sample

5B9R5Q + +

Analysis detected the presence of amphetamine with an approximate purity of 24% (as base). Caffeine was also detected.

5D5Q5X + +

The sample contains a controlled substance as well as substance amphetamine and caffeine cutting

6HXWOM + +

Caffeine is also detected. It is a sample of street amphetamine with low concentration of amphetamine




35


6I9L3N + +

The sample contains anfetamine and caffeine

6P0WWW + +

Amphetamine 4,89% and Caffeine

6TZBOI + +

The sample also contain creatine.

72SXT7 + +

Test sample 2015/1/SM-2 contains amphetamine base 5.52 %, m/m, caffeine and ceratinine.

7CVHQG + +

Caffeine and Creatinine

88CBR8 + +

We have found amfetamine and caffeine by using GC-MS.

8EKCQE + +

also contains cafeine analyzed by GCMS

8P8J9S + +

Sample contains Amphetamine Sulfate and caffeine. Amphetamine is below the level of quantification for our laboratory (<0.04%). Quantitative analysis was performed by GC-FID.

8Z1D82 + +

The sample SM2 was found to contain the controlled substance Amphetamine. In addition it was found to contain Caffeine.

999FTE + +

caffeine

9AQQ5Z + +

By using LC-MS and LC-MS-MS , the sample contain Amphetamine 5.3 % w/w and Caffiene.

9E9RV9 - +

Cobalt thiocyanate (CT) negative, GC/MS retention time and mass charge ratio (M/Z) similar characteristics with the substances used as standard or pattern

9G1IGG + +

A55MTH - +

AFUPAX + +

SM2 contains Amfetamine Sulphate with 6.22 % Amfetamine base.SM2 also contains Caffeine and Creatinine

AG4RDN + +

This sample is amphetamine.

AGX9RJ + +

was found caffeine

AM75RV + +

SM-2 gives positive to Marquis' and Simon's test. Identification with TLC and GCMS, SM-2 contains Amphetamine and Caffeine.Quantitation with GC, SM-2 contains Amphetamine base 5.74% and Caffeine 28.59%.

ASAZSF + +

Sample also contain caffeine

ATMMIK + +

A sample of this powder was analysed and found to contain amphetamine at purity of 4%. This sample was also found to contain caffeine.

AXEI96 + +

Amphetamine and Caffeine detected in sample 2015/1/SM-2. Quantitative analysis not performed.

BCQF5M + +

SM-2 is positive for amphetamine.



36


BFDDDR + ANP

The sample obtains with positive result with Marquis reagent.TLC: The Rf sample obtain with the same Rf Amphetamine Standard.GC: The Rt sample obtain with the same Rt Amphetamine Standard.

BUBXUF + +

The results of the tests of SM2 (62) received confirmed that the mentioned sample contains amphetamine but we are not able to give a cuantification result .The sample 2 contains also caffeín as not controlled drug.

C0ZZJN + +

Sample 2015/1/SM-2, a white powder with acrid odour, gave a positive result for amphetamine, a controlled substance under national legislation on drugs.

C77B7S + +

Identified Amphetamine and coffeine

CLWMLL + +

The powder contains amfétamine and caféine. Amfétamine is a controlled substance in France.

CML6FN + ANP

Quantity of off-white powder weighing 0.21grams analysed and confirmed to contain Amphetamine. Caffeine was indicated however not confirmed. Amphetamine is a class B controlled drug within the provisions of the Misuse of Drugs Act 1971.

CRVCAC + +

CXZ7SL - -

DF8IPB + +

- Primary screening revealed Amphetamine- GC/MS and HPLC allowed identification of Amphetamine and Caffeine

DPMUDD + +

Amfetamine is a Class B controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

DSTAS1 + +

AMFETAMINE

DXGEZT + +

Amfetamine is controlled by law (K.B. 22/1/1998)

EAEWNG + +

found amfetamine with 5.1%ww

EGOAAA + +

amphetamine, cafeine

EH8THK + +

The sample contains amphetamine. The content of amphetamine (as amphetaminesulphate) is determined to 7 %. Amphetamine is a controlled substance in Norway.

EIUUUK + +

The sample also contains caffeine and creatine-monohydrate.

EK1CYF + +

sample found to contain amphetamine and caffeine

EKXNNH + +

The sample contains Amfetamine and Caffeine.

ERGL66 + +

Powder was found to contain amphetamine.

FG6OYO + +

the sample contains amphetamine (scheduled as ilicit drug in France), caffeine and creatine



37


FSLFBU + +

The white powder was analsyed and found to contain amphetamine.

FSOGSM + +

Test sample 2015/1/SM-2 contains amphetamine, a dangerous drug. It also contains caffeine.

FUEK6X - +

G5W4WW - +


GB3OEY + +

One glass bottle containing 0.23 grammes of a powder containing 0.01 grammes of amphetamine.

GBX7ZC + ANP

GFXM5C + -

The chemical tests and the coincidence in the time of retention and mass fragmentogram with the material of reference used in the same conditions that the analyzed sample, indicate in this one the amfetamine presence.

GGUVGQ + -

GMGJSG + +

Amfetamine+Cafeine

GOT2LZ + +

AMPHETAMINE 5.7% AS BASE, CAFFEINE

GTTTTX + +

H22O82 + +

-Analysis of quantification on Amphetamine is not routinely carried out by our laboratory.-Substance detected include Caffeine.

HFQF1Q + +

caffein 30 %

HKZ1VR + +

The sample ICE2015/1/SM2 was found to contain Amphetamine and Caffeine.

HPMMRG + +

CAFEINE.

HUA51A + +

amfetamine, caffeine

HV22C2 + +

amphetamine(5%),cafeine

ICJJYI + -

Not quantificated

ILI0KV + +

amfetamine was detected by GC/MS screening and it was quantified by LC/MS/MS

INVI3H + +

IO7IOO + +

the sample SM2 contains amphetamine and caffeine



38


IPDQJN + +

ISSSPG + +

AMFETAMINE Y CAFEINE

ITHPL9 + +

contained caffeine

IUPHSS + +

The sample contains amphetamine

IWH4C5 + +

Caffeine

IWII3P + +

5.02%

JBOJJJ + +

The sample contains amfetamine (5.6%) and caffeine.

JMMMUB - +

JSAGFJ + -

Field test employing the Marquis test showed positive. TLC analysis and HPLC was employed to confirm.

JZAFXP - +

sample no 2 contain cocaine and some bulking agents.

KFXSJH + +

PRUEBAS CROMATICAS: MARQUIS, SCOTT, SIMON´SINSTRUMENTALES: FT-IR, GC-MS

KHBFT2 + ANP

Contains Amphetamine.

KHMABJ + +

The sample contains amphetamine, caffeine and creatine.

LHLHFD + +

Amfetamine and Caffeine

LZIOS8 + +

The percentage of amfetamine is 5.7 %

MHLLML + +

Usual as well.

MMUMRC + +

contained caffeine, creatinine

N8RGKU + +

Sample 2015/1/SM-2 consists of white powder. Amfetamine, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample.

NANRGN + +

In the sample is detected amphetamine and caffeine,

NSUV95 - +

The exhibit were found to contain caffeine and N-Methyliminopropylbenzene but no controlled substances.

NXTOSM + +

NYXHZT + +

CAFFEINE



39


ODCD2V + +

d,l amphetamine, caffeine, and creatine confirmed in 1 unit tested of 1 unit received.

ODZFBN + +

The sample contains amphetamine, caffeine and creatine.

OIXWB8 + +

amfetamine 5.4%ww, caffeine

OWVZ9H + +

Dark white powder that contains controlled substance AMPHETAMINE.

P5ABC7 + +

CREAM WHITE POWDER SAMPLE ANALYZED CONTAINS: AMPHETAMINE AND CAFFEINE.

P659G5 + +

PVZFPA + +

Examination revealed the presence of Amphetamine

Q772TV + +

Caffeine

Q8LGQQ + +

*Results of screening tests were positive for primary amphetamines. *Retention time and fragmentation pattern obtained with sample are equivalent to those obtained with amfetamine and caffeine.

QCYBCZ - +

Caffeine is not included in UN notified precursor chemicals. But in our country, Myanmar, we notified it as precursor chemical.

QHH5X6 + +

white powder containing caffeine and amfetamine

QK1XXA + +

QMWQTQ - +

Caffeine was identified in the sample

QRWM3W + +

Caffeine

QRXCOO + +

Orange color appear with Marquis test and purple color appear by Simon test with Acetone which indicates possible presence of Amfetamine.Purple color with Amalic Acid test indicates possible presence of Caffeine. Analysis by GCMS shows similarity as Amfetamine and Caffeine.

QVHXRP + +

CREATINE AND CAFFEINE WERE IDENTIFIED

QYI8XO + +

The sample contains : amphetamine and caffeine

QYYLCY + +

The sample contains amphétamine and cafein.Amphetamine is a scheduled as illicit drug.

R2EIGV + +

In the test sample 2015/1/SM-2 were detected amfetamine and caffeine

RB8OK5 + +

No determinada pureza, con creatina monohidrato y cafeina

RHRRWR + +

The sample was found to contain amphetamine and caffeine.



40


RIJIJC + +

the powder is a mixture of amfetamine sulfate, creatine hydrate, and caffeine. The concentration of amfetamine, as free base, in the sample is 5.4% by weight.

RJRT8O + +

amfetamine was as sulphat form

RNIHSP + +

RQJY2X + +

In the sample labeled as 2015/1 / SM-2 was found amphetamine and caffeine.

RQQ9IG + +

after chemical analysis was performed the sample contain .1- amphetamine 5.1 %2-caffeine

RRERCL + +

RV1ATU + +

Presence of caffeine. FTIR analysis detected the presence of creatine.

S6JCMD + +

The sample was found to contain amphetamine, caffeine and fructose.

SEQGAQ + -

sample contained amfetamine as a controlled drug

SFILGT + +

SWTTQX + +

Alpha Methyl Benzeneethanamine and caffeine are detected.

TEKB5H + +

the yellow powder contains amfetamine (4.6%ww) which is controlled by national law. The sample contains caffeine too.

TFLCTJ + +

TK1XDK + +

The sample found to contain Amphetamine

TMIOPH + +

The sample contain amphetamine, caffeine and creatine.

TNQR0R + +

contained amfetamine and cofeine

TOTXN0 + +

The sample contains amphetamine and caffeine.

TRJR2R + +

caffeinecreatine

UJJUU1 + +

Amphetamine is a Class B controlled drug under the provisions of the Misuse of Drugs Act 1971 (as amended).

UJZXBO + +

The test sample 2015/1/SM-2 was found to contain the controlled drug amphetamine. The sample was also found to contain caffeine.

UU0EDU + +

adulterant/diluents: caffeine, creatine

V0TJCT + +



41


V5A5C5 + +

the sample contains amphetamine, caffeine, creatinine

V7777W + +

The powder was found to contain less than 5% amphetamine; caffeine was also detected. Amphetamine is controlled by the Misuse of Drugs Act 1971 (as amended) as a Class B drug. Caffeine is not controlled by the Misuse of Drugs Act 1971 (as amended).

V7UKSS + +

Narcotics: amphetamine, approximately 6 % as free base

VHRVSQ + +

Item 2015/1/SM-2 contained Amphetamine, at a purity of six per cent.

VIBSI3 + +

VJEFF1 + +

The sample contains amfetamine which is listed as a controlled drug according to french order, appendix III of February 22nd 1990.

VVRYSV - +

The Test sample 2015/1/SM-2 was analyzed by colour test and Thin Layer Chromatography technique and found to contain Caffeine.

VWKVJV + +

VWVVHY + +

WATIXT + +

sulphate amfetamine is present (6.8% w/w as base) with caffeine and creatine

WH4B44 + ANP

-

WVV99T + +

White powder containing Amfetamine (List II C 1971) 5.16% and other substance as adulterant: Caffeine

X1WS11 + ANP

XI5JGO + +

XIXNGM + +

./.

XKKPPR + +

white powder, other compounds caffeine and creatine

XNJQCT + +

The sample contained amphetamine with caffeine.

XODXXJ + +

XRRKRK + +

XY5KFG - ANP

Mescaline was detected from sample 2015/1/SM-2. However the results are not indicated in the Analytical Results Form because it is not among the list of of drugs provided

Y6HBAA + +

The sample contains Amphetamine Hydrochloride (5.8% as base) with Caffeine.

YN88GB - +

La sustancia decomisada contiene cafeína



42


YSMOUG + +

Based on the above analysis, the sample was found to contain amphetamine and caffeine.

YSNVND + +

We found amphetamine as controlled drug and caffeine as adulterants

YZSZMS + +

La muestra contiene además cafeína

Z9MTOM + +

caffeine and creatine

ZCYZZA + +

CAFEINA

ZO7E6M + +

additional substances: creatine, caffeine



43


Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0BPIQK SI I

15KHZZ S I I SI

1NBQEB SI SI S I I

1OFS4X S SI I SI SI

1X1W9X SI

20222K S I I

2C5GCK SI I I I

2JJEMT SI I

2KHKFK I SI I

333WNF S S S I I

3I4END I SI

3XMCSS SI I

4IHDMJ SI

4MQGMT SI SI

4QDDDD S I I I

4WAP4I S I I I

5B9R5Q S S S I I

5D5Q5X S I SI

6HXWOM I I SI I

6I9L3N S S S I S

6P0WWW S I

6TZBOI S SI SI I

72SXT7 I SI

7CVHQG S I I

88CBR8 SI

8EKCQE SI SI I I

8P8J9S S S I

8Z1D82 I S

999FTE SI

9AQQ5Z SI I

9E9RV9 S S S I

9G1IGG SI I

A55MTH I





44

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

AFUPAX I S I I

AG4RDN S I I

AGX9RJ S S S I I

AM75RV S S S I I

ASAZSF SI ASAP-TOF


AXEI96 S SI

BCQF5M S I

BFDDDR S S S I

BUBXUF S S S I I

C0ZZJN S S S I

C77B7S S S S SI


CML6FN S I

CRVCAC I SI SI

CXZ7SL S I

DF8IPB S I I

DPMUDD S S S I

DSTAS1 SI I

DXGEZT S I S

EAEWNG SI

EGOAAA SI

EH8THK I I

EIUUUK S SI SI I

EK1CYF S I I I

EKXNNH S S S I SI I

ERGL66 I I

FG6OYO S I I I

FSLFBU S I I


FUEK6X S S I I

G5W4WW

S S S I I

GB3OEY S S SI

GBX7ZC I

GFXM5C S S S I

GGUVGQ SI

GMGJSG I S ION-SCAN

GOT2LZ S S S I

GTTTTX S S S SI I I



45

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

H22O82 S S S I I I

HFQF1Q SI

HKZ1VR S S S I I

HPMMRG I SI


HV22C2 S I I

ICJJYI S I

ILI0KV SI

INVI3H SI


IPDQJN I SI SI

ISSSPG S S S I I

ITHPL9 SI

IUPHSS I SI I

IWH4C5 SI I

IWII3P SI

JBOJJJ S S S I I

JMMMUB S S SI I I I



KFXSJH S S SI I I

KHBFT2 S S S I I

KHMABJ S S SI SI I

LHLHFD SI SI I



MMUMRC SI

N8RGKU S S I I I


NSUV95 I I S

NXTOSM S S S I

NYXHZT S S S SI I

ODCD2V I SI I

ODZFBN I I

OIXWB8 I I SI

OWVZ9H S S I I

P5ABC7 S S I

P659G5 S S I I

PVZFPA S SI



46

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Q772TV S I

Q8LGQQ S S S I I

QCYBCZ I I SI

QHH5X6 SI


QMWQTQ


QRWM3W

I SI


QVHXRP I SI I

QYI8XO S I I

QYYLCY I SI I

R2EIGV I

RB8OK5 S I I

RHRRWR S I


RJRT8O SI

RNIHSP S S I I

RQJY2X S S I

RQQ9IG S S I

RRERCL S S S I I

RV1ATU I I I SI

S6JCMD SI I ELSD


SFILGT I SI I

SWTTQX S S I

TEKB5H I I SI

TFLCTJ I SI

TK1XDK S S I

TMIOPH S SI I SI I

TNQR0R SI

TOTXN0 SI

TRJR2R SI SI


UJZXBO S S S I I

UU0EDU I SI SI

V0TJCT S I I


V7777W S S I



47

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

V7UKSS I SI I

VHRVSQ S I I

VIBSI3 SI S

VJEFF1 I I


VWKVJV SI

VWVVHY S I

WATIXT I I

WH4B44 SI

WVV99T S S S I SI

X1WS11 SI SI SI I

XI5JGO S S SI

XIXNGM I SI SI

XKKPPR SI I

XNJQCT SI

XODXXJ SI I


XY5KFG SI I

Y6HBAA SI S S I I

YN88GB S S I I



YZSZMS S S S I I

Z9MTOM S I I

ZCYZZA S I I

ZO7E6M SI I XRD



48



Summary for test sample 2The response summary of all 177 participating laboratories for the identification of SM- 2, frequency of use of screening andidentification techniques and false positives and negatives:



Code Name Technique

G5W4WW Metamfetamine 150/171

JZAFXP Cocaine 161/180

XY5KFG Mescaline 141

CXZ7SL Heroin 150


QK1XXA N-benzyl-2methylaziridine 150/180

NSUV95 N-methyliminopropylbenzene 190/180

False negatives for SM-2 (techinque(s) used or ANP)

Code: 9E9RV9 (180) A55MTH (180), FUEK6X (180), G5W4WW (150/171), JMMMUB (150)

142 150 160 161 190 200 220


Caffeine: 163

Amfetamine 163

Section 141 142 150 160 161 170 171 180 190 200 211 231


JZAFXP (180), NSUV95 (190), QCYBCZ (150), QMWQTQ (171), VVRYSV (150), XY5KFG (141), YN88GB (150) CXZ7SL (150) 1GHP1K (ANP)

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 67 72 62 20 0 2 1 3 71 11 3 0 1 1 15

37.9% 40.7% 35.0% 11.3% 0.0% 1.1% 0.6% 1.7% 40.1% 6.2% 1.7% 0.0% 0.6% 0.6% 8.5%

Identification 9 3 2 44 12 19 2 29 159 60 5 2 1 4 13

5.1% 1.7% 1.1% 24.9% 6.8% 10.7% 1.1% 16.4% 89.8% 33.9% 2.8% 1.1% 0.6% 2.3% 7.3%


73 72 62 51 12 19 2 30 160 63 8 2 1 4 23

41.2% 40.7% 35.0% 28.8% 6.8% 10.7% 1.1% 16.9% 90.4% 35.6% 4.5% 1.1% 0.6% 2.3% 13.0%


49



Concentration

(mass%)

Deviation from

robust average

z-scoreConcentra

tion (mass%)

Deviation from

robust average

z-score

GGUVGQ 0.61 5.0 -7.0 V7UKSS 5.65 0.1 0.04WAP4I 3.50 2.1 -2.9 DXGEZT 5.70 0.1 0.1BFDDDR 3.69 1.9 -2.7 GOT2LZ 5.70 0.1 0.10BPIQK 4.00 1.6 -2.3 LZIOS8 5.70 0.1 0.1V7777W 4.00 1.6 -2.3 RV1ATU 5.70 0.1 0.1ATMMIK 4.40 1.2 -1.7 TRJR2R 5.70 0.1 0.1333WNF 4.51 1.1 -1.5 X1WS11 5.70 0.1 0.1TEKB5H 4.60 1.0 -1.4 RV1ATU 5.70 0.1 0.14QDDDD 4.68 0.9 -1.3 QRWM3W 5.73 0.1 0.2C77B7S 4.80 0.8 -1.1 AM75RV 5.74 0.1 0.2XI5JGO 4.80 0.8 -1.1 CRVCAC 5.77 0.2 0.2

6P0WWW 4.89 0.7 -1.0 QVHXRP 5.79 0.2 0.2VWKVJV 4.90 0.7 -1.0 Y6HBAA 5.80 0.2 0.2Z9MTOM 4.90 0.7 -1.0 XODXXJ 5.85 0.3 0.3CML6FN 5.00 0.6 -0.9 ODCD2V 5.80 0.2 0.3FG6OYO 5.00 0.6 -0.9 GB3OEY 5.90 0.3 0.4HV22C2 5.00 0.6 -0.9 GTTTTX 5.90 0.3 0.41NBQEB 5.01 0.6 -0.9 EKXNNH 6.00 0.4 0.5IWII3P 5.02 0.6 -0.8 UJJUU1 6.00 0.4 0.5

EAEWNG 5.10 0.5 -0.7 VHRVSQ 6.00 0.4 0.5MMUMRC 5.10 0.5 -0.7 3I4END 6.05 0.5 0.6RQQ9IG 5.10 0.5 -0.7 AG4RDN 6.14 0.5 0.7XKKPPR 5.10 0.5 -0.7 2C5GCK 6.20 0.6 0.8YZSZMS 5.10 0.5 -0.7 AFUPAX 6.22 0.6 0.8WH4B44 5.14 0.5 -0.7 RJRT8O 6.30 0.7 0.9WVV99T 5.16 0.4 -0.6 0B00MA 6.40 0.8 1.13XMCSS 5.20 0.4 -0.6 88CBR8 6.48 0.9 1.2ILI0KV 5.25 0.4 -0.5 2KHKFK 6.50 0.9 1.2

9AQQ5Z 5.30 0.3 -0.4 DSTAS1 6.70 1.1 1.56HXWOM 5.40 0.2 -0.3 MHLLML 6.71 1.1 1.58Z1D82 5.40 0.2 -0.3 WATIXT 6.80 1.2 1.69G1IGG 5.40 0.2 -0.3 KHMABJ 7.10 1.5 2.1EH8THK 5.40 0.2 -0.3 5D5Q5X 7.16 1.6 2.1OIXWB8 5.40 0.2 -0.3 NYXHZT 7.92 2.3 3.2RIJIJC 5.40 0.2 -0.3 HUA51A 8.30 2.7 3.7999FTE 5.46 0.1 -0.2 QRXCOO 8.62 3.0 4.24IHDMJ 5.50 0.1 -0.2 TFLCTJ 8.62 3.0 4.24MQGMT 5.50 0.1 -0.2 DF8IPB 8.79 3.2 4.4DPMUDD 5.50 0.1 -0.2 7CVHQG 9.00 3.4 4.7ODZFBN 5.50 0.1 -0.2 INVI3H 19.48 13.9 19.2TNQR0R 5.50 0.1 -0.2 IUPHSS 23.21 17.6 24.4RRERCL 5.51 0.1 -0.2 5B9R5Q 23.90 18.3 25.472SXT7 5.52 0.1 -0.1 BCQF5M 27.83 22.2 30.8IPDQJN 5.53 0.1 -0.1R2EIGV 5.53 0.1 -0.11OFS4X 5.55 0.0 -0.1ITHPL9 5.56 0.0 -0.11X1W9X 5.60 0.0 0.0IWH4C5 5.60 0.0 0.0JBOJJJ 5.60 0.0 0.0

Code

Amfetamine

Code

Amfetamine

50

Substance: SM-2; Amfetamine

Round: 2015/1







‐2.9

‐2.7

‐2.3

‐2.3

‐1.7 ‐1

.5 ‐1.4 ‐1.3 ‐1

.1

‐1.1 ‐1.0

‐1.0

‐1.0 ‐0

.9

‐0.9

‐0.9

‐0.9

‐0.8 ‐0.7

‐0.7

‐0.7

‐0.7

‐0.7 ‐0.7 ‐0.6 ‐0.6 ‐0.5 ‐0.4 ‐0.3

‐0.3

‐0.3

‐0.3

‐0.3

‐0.3 ‐0.2 ‐0.2

‐0.2

‐0.2

‐0.2

‐0.2

‐0.2

‐0.1

‐0.1

‐0.1 ‐0.1

‐0.1 0.0

0.0

0.0

0.0 0.1

0.1

0.1

0.1

0.1

0.1

0.1 0.2

0.2 0.2 0.2

0.2

0.3 0.3 0.4

0.4 0.5

0.5

0.5 0.6 0.7 0.8 0.8 0.9 1.1 1.2 1.2

1.5

1.5 1.6

2.1 2.1

3.2

3.7

‐4.0

‐3.0

‐2.0

‐1.0

0.0

1.0

2.0

3.0

4.0

GGUV

GQ

4WAP

4I

BFDD

DR

0BPIQK

V777

7W

ATMMIK

333W

NF

TEKB

5H

4QDD

DD

XI5JGO

C77B

7S

6P0W

WW

VWKV

JV

Z9MTO

M

FG6O

YO

HV2

2C2

CML6FN

1NBQ

EB

IWII3P

EAEW

NG

YZSZMS

XKKP

PR

RQQ9IG

MMUM

RC

WH4B

44

WVV

99T

3XMCSS

ILI0KV

9AQQ5Z

RIJIJC

OIXWB8

8Z1D

82

EH8THK

9G1IGG

6HXW

OM

999FTE

4IHDM

J

ODZ

FBN

4MQGMT

TNQR0

R

DPMUDD

RRER

CL

72SXT7

R2EIGV

IPDQ

JN

1OFS4X

ITHP

L9

1X1W

9X

JBOJJJ

IWH4

C5

V7UKSS

DXGEZT

RV1A

TU

TRJR2R

GOT2LZ

X1WS11

LZIOS8

RV1A

TU

QRW

M3W

AM75

RV

CRVC

AC

QVH

XRP

Y6HBA

A

ODC

D2V

XODX

XJ

GB3

OEY

GTTTTX

EKXN

NH

UJJUU

1

VHRV

SQ

3I4END

AG4R

DN

2C5G

CK

AFUPA

X

RJRT

8O

0B00MA

88CB

R8

2KHK

FK

DSTA

S1

MHLLML

WAT

IXT

KHMAB

J

5D5Q

5X

NYX

HZT

HUA5

1A

TFLCTJ

QRX

COO

DF8IPB

7CVH

QG

INVI3H

IUPH

SS

5B9R

5Q

BCQF5M

‐7.0

4.230.824.4

19.24.44.7

25.44.2

51

Round: 2015/1


-10.0

-8.0

-6.0

-4.0

-2.0

0.0

2.0

4.0

6.0

8.0

10.0

z-sc

ore

Dispersion of z-scores using different analytical techniques for the quantification of amfetamine in 2015/1 SM-2

HPLC GC-FID GC/MS

52


Code Identified Substances15KHZZ None

1X1W9X No drug was found

333WNF Heroin

4QDDDD None.

8EKCQE anp

9E9RV9 None controlled drugs

AM75RV None

ATMMIK None

BUBXUF NONE

C0ZZJN -

CLWMLL None

DSTAS1 Negative

G5W4WW Blank, no substance from the ICE menu included

HKZ1VR NIL

HPMMRG NONE

HUA51A -

INVI3H amphetamine

ITHPL9 drugs not found

IWII3P -

JSAGFJ None detected.

KHMABJ /

LHLHFD -

LZIOS8 SM-3 is a blank sample

MHLLML None

MMUMRC drugs not found

NANRGN none

OWVZ9H NONE

Q772TV No found

QCYBCZ -

QMWQTQ JWH 073

QRXCOO 2-Propan-1-one

QYI8XO The sample does not contain controlled substances

RQJY2X none

SWTTQX None

TMIOPH -

WH4B44 Heroin

XI5JGO None

XY5KFG Amphetamine

Y6HBAA Nil

YSMOUG None

Sample 3 Analysis



53

Code Identified SubstancesYSNVND -

ZO7E6M none



54

Code [blank sample]

0B00MA

0BPIQK Any drug of abuse has been detected.

15KHZZ Green powder, negative for drugs. Detected traces of caffeine.

1NBQEB Negative

1OFS4X Sample does not contain any controlled drugs.

1QHP1K

1X1W9X Sample doesn`t contain any illegal substances

20222K No substance from the ICE menu included

2C5GCK Presence of substances from the ICE menu was not detected in the sample. Blank test sample is plant powder.

2JJEMT

2KHKFK there is no controlled substances in the sample

333WNF

3I4END

3XMCSS

4IHDMJ

4MQGMT no drugs can be found

4QDDDD

4WAP4I

5B9R5Q The powder was analysed for the presence of a range of controlled drugs but none could be confirmed.

5D5Q5X In this sample has not identified any drug, it has detected the presence of stigmasterol / sitosterol

6HXWOM No substance of toxicological interest is detected

6I9L3N the sample does not contain any controlled drugs

6P0WWW

6TZBOI

72SXT7 Test sample 2015/1/SM-3 contains plant material.

7CVHQG

88CBR8 We haven't found any drug in SM-3.

8EKCQE anp

8P8J9S Sample contains lactose

8Z1D82

999FTE

9AQQ5Z By using LC-MS and LC-MS-MS , the sample is free from any drugs

9E9RV9 Colorimetric reactions (CR) Negative, GC/MS retention time, and mass charge ratio (M/Z) No similar characteristics with the subtances used as pattern

9G1IGG

A55MTH

AFUPAX SM3 contains Glucose and Zaccharose

AG4RDN This sample does not contain drugs.




55

Code [blank sample]

AGX9RJ No drugs found

AM75RV SM-3 gives negative to Marquis' test. No spot on TLC and no peak by GC and GCMS. No specific matched to controlled substances on FTIR

ASAZSF No drugs found on the analyzed sample

ATMMIK A sample of the vegetable matter was analysed and found to contain no controlled substance(s).

AXEI96 No controlled drugs detected in sample 2015/1/SM-3

BCQF5M SM-3 is blank

BFDDDR

BUBXUF We have not found any controlled drug in the SM 3 (97)

C0ZZJN Sample 2015/1/SM-3, a green powder with fruity odour, was not found to contain any controlled substance under national legislation on drugs.

C77B7S

CLWMLL The powder doesn't contain controlled substance in France.

CML6FN Quantity of green powder weighing 0.22grams was analysed for the presence of controlled drugs within the provisions of the Misuse of Drugs Act 1971 with a negative result. There were no non-controlled drugs indicated in the sample also.

CRVCAC

CXZ7SL

DF8IPB - Primary screening allowed negative results- GC/MS and HPLC allowed negative results- Iode test and FTIR (code 190) revealed strach

DPMUDD No controlled substances were detected.

DSTAS1 Negative

DXGEZT Sample is a herbal mixture.

EAEWNG

EGOAAA

EH8THK The sample is not identified. With the methods used, no controlled substance are detected in the sample.

EIUUUK

EK1CYF sample found to contain pthalate

EKXNNH The sample does not contain any drugs.

ERGL66 No controlled drugs detected.

FG6OYO No illicit drug was detected in the sample.

FSLFBU The green material was analysed for controlled drugs with a negative result.

FSOGSM Test sample 2015/1/SM-3 does not contain dangerous drugs.

FUEK6X

G5W4WW For sample 2015/1/SM-3 was first a preliminary test to determine the presence of what kind of drugs we have used two Scott reagent tests (tyocianato of Cobalte) and the Marquis reagent. After a TLC and to that end we used a 20 × 20, silica as a solvent dichloromethane was used and how the Methanol eluent. Finally there was a gas chromatography using flame Ionization Detector (GC-FID), in the preparation of the samples used as solvent, chloroform/ethanol mixture and tetracosano (internal standard), and the column TRACSIL TRB-50 (50%) Diphenyl-(50%) dimethyl polysiloxane, Flow Rate of 1.5 ml/min and Pressure of 14.7 psi.

GB3OEY One glass bottle containing 0.21 grammes of a solid which did not contain any substances controlled under the Dangerous Drugs Ordinance.

GBX7ZC



56

Code [blank sample]

GFXM5C

GGUVGQ

GMGJSG

GOT2LZ

GTTTTX

H22O82 The sample did not contain any controlled substance

HFQF1Q CELLULOSE , vegetal substance

HKZ1VR The Sample ICE2015/1/SM3 was to contain no drug.

HPMMRG IT IS CONTAINING PLANT MATERIALS

HUA51A -

HV22C2 henna

ICJJYI not found any psycothropic or narcotic substance

ILI0KV

INVI3H a substance is related to drug - amphetamine

IO7IOO the sample SM3 hasn't got drugs

IPDQJN Negative

ISSSPG

ITHPL9 drugs not found

IUPHSS

IWH4C5

IWII3P -

JBOJJJ No controlled drugs detected.

JMMMUB

JSAGFJ No drug was found.

JZAFXP

KFXSJH PRUEBAS CROMATICAS: MARQUIS, SCOTT, SIMON´S, CHEN CAO, DUQUENOIS-LEVINE.INSTRUMENTALES: FT-IR, GC-MS, UV-VISIBLE

KHBFT2 Negative for controlled drugs.

KHMABJ The sample is plant material. No drugs found in the samples.

LHLHFD -

LZIOS8

MHLLML Nothing relevant found.

MMUMRC drugs not found

N8RGKU Sample 2015/1/SM-3 consists of green powder. No prohibited substances are detected in this sample.

NANRGN Sample 2015/1 / SM-3 is pulverized plant material

NSUV95

NXTOSM

NYXHZT

ODCD2V



57

Code [blank sample]

ODZFBN Plant material without drugs.

OIXWB8

OWVZ9H Olive green powder that contains none controlled substance.

P5ABC7 GREEN POWDER SAMPLE ANALYZED NOT CONTAINS CONTROLLED DRUGS.

P659G5 arabic gum

PVZFPA Examination did not reveal the presence of any controlled substances.

Q772TV

Q8LGQQ Spectroscopic parameters obtained with sample are equivalent to those obtained with lactose.

QCYBCZ

QHH5X6 green vegetable material containing no substances in the ICE list

QK1XXA

QMWQTQ A synthetic Cannabinoid JWH 073 was identified in the sample. The percentage of JWH 073 in the sample was 3.68 .

QRWM3W

QRXCOO No reaction with Marquis test, Simon test, Chen-Kao test and Fast Blue B Salt test. Analysis by GCMS shows similarity as 2-Propan,1-One.

QVHXRP

QYI8XO The sample does not contain controlled substances

QYYLCY

R2EIGV In the test sample 2015/1/SM-3 were not detected substances

RB8OK5 sin identificar, sustancia o material vegetal

RHRRWR The sample did not contain any drugs.

RIJIJC the powder doesn't contain controlled drugs

RJRT8O

RNIHSP

RQJY2X In the sample labeled as 2015/1 / SM-3 no drugs were found

RQQ9IG

RRERCL

RV1ATU

S6JCMD No common controlled drug was detected.

SEQGAQ sample was found to contain no drugs of abuse

SFILGT

SWTTQX Hexadecanoic Acid was detected.

TEKB5H the green powder doesn't contain drugs controlled by national law.

TFLCTJ

TK1XDK no drugs found

TMIOPH The sample is negative.

TNQR0R Drugs not found

TOTXN0

TRJR2R



58

Code [blank sample]

UJJUU1 Not controlled drugs were detected in this powder.

UJZXBO The test sample 2015/1/SM-3 do not found to contain the controlled drugs as well as the substances listed in the menu of ICE 2015/1.

UU0EDU

V0TJCT

V5A5C5 mixture of spices

V7777W Nothing of significance was detected.

V7UKSS Negative

VHRVSQ No controlled drug were detected in item 2015/1/SM-3.

VIBSI3

VJEFF1 The analysis did not reveal any controlled drug according to french order, decree of February 22nd 1990.

VVRYSV The Test sample 2015/1/SM-3 was analyzed by colour test and Thin Layer Chromatography technique and found not to contain the drug listed under Seized Material Samples

VWKVJV

VWVVHY None controlled substance was detected.

WATIXT

WH4B44 -

WVV99T Herbal mixture possibly containing a synthetic cannabinoid that it was not possible to identify

X1WS11

XI5JGO

XIXNGM

XKKPPR green powder - negative

XNJQCT The sample contained traces of caffeine.

XODXXJ

XRRKRK

XY5KFG Test sample 2015/1/SM-3 showed evidence that it contained amphetamines

Y6HBAA No drugs Detected in the sample.

YN88GB Se trata de restos vegetales. No fue posible identificar en qué tipo de vegetal consisten estos restos.

YSMOUG Based on the above analysis, the sample was found to contain no controlled drug.

YSNVND no drug content found in test sample

YZSZMS

Z9MTOM

ZCYZZA CARBOHIDRATOS

ZO7E6M methods used for identification: GC-MS, ATR, XRD, QTOF



59


Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0BPIQK SI I

15KHZZ S I I SI

1NBQEB SI SI S I I

1OFS4X S SI I SI SI

1X1W9X SI

20222K S I I

2C5GCK SI I I I

2JJEMT SI I

2KHKFK I SI I

333WNF S S S I I

3I4END I SI

3XMCSS SI I

4IHDMJ SI

4MQGMT SI SI

4QDDDD S I I I

4WAP4I S I I I

5B9R5Q S S S I I

5D5Q5X S I SI

6HXWOM I I SI I

6I9L3N S S S I S

6P0WWW S I

6TZBOI S SI SI I

72SXT7 I SI

7CVHQG S I I

88CBR8 SI

8EKCQE SI SI I I

8P8J9S S S I

8Z1D82 I S

999FTE SI

9AQQ5Z SI I

9E9RV9 S S S I

9G1IGG SI I

A55MTH I





60

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

AFUPAX I S I I

AG4RDN S I I

AGX9RJ S S S I I

AM75RV S S S I I

ASAZSF SI ASAP-TOF


AXEI96 S SI

BCQF5M S I

BFDDDR S S S I

BUBXUF S S S I I

C0ZZJN S S S I

C77B7S S S S SI


CML6FN S I

CRVCAC I SI SI

CXZ7SL S I

DF8IPB S I I

DPMUDD S S S I

DSTAS1 SI I

DXGEZT S I S

EAEWNG SI

EGOAAA SI

EH8THK I I

EIUUUK S SI SI I

EK1CYF S I I I

EKXNNH S S S I SI I

ERGL66 I I

FG6OYO S I I I

FSLFBU S I I


FUEK6X S S I I

G5W4WW

S S S I I

GB3OEY S S SI

GBX7ZC I

GFXM5C S S S I

GGUVGQ SI

GMGJSG I S ION-SCAN

GOT2LZ S S S I

GTTTTX S S S SI I I



61

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

H22O82 S S S I I I

HFQF1Q SI

HKZ1VR S S S I I

HPMMRG I SI


HV22C2 S I I

ICJJYI S I

ILI0KV SI

INVI3H SI


IPDQJN I SI SI

ISSSPG S S S I I

ITHPL9 SI

IUPHSS I SI I

IWH4C5 SI I

IWII3P SI

JBOJJJ S S S I I

JMMMUB S S SI I I I



KFXSJH S S SI I I

KHBFT2 S S S I I

KHMABJ S S SI SI I

LHLHFD SI SI I



MMUMRC SI

N8RGKU S S I I I


NSUV95 I I S

NXTOSM S S S I

NYXHZT S S S SI I

ODCD2V I SI I

ODZFBN I I

OIXWB8 I I SI

OWVZ9H S S I I

P5ABC7 S S I

P659G5 S S I I

PVZFPA S SI



62

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Q772TV S I

Q8LGQQ S S S I I

QCYBCZ I I SI

QHH5X6 SI


QMWQTQ


QRWM3W

I SI


QVHXRP I SI I

QYI8XO S I I

QYYLCY I SI I

R2EIGV I

RB8OK5 S I I

RHRRWR S I


RJRT8O SI

RNIHSP S S I I

RQJY2X S S I

RQQ9IG S S I

RRERCL S S S I I

RV1ATU I I I SI

S6JCMD SI I ELSD


SFILGT I SI I

SWTTQX S S I

TEKB5H I I SI

TFLCTJ I SI

TK1XDK S S I

TMIOPH S SI I SI I

TNQR0R SI

TOTXN0 SI

TRJR2R SI SI


UJZXBO S S S I I

UU0EDU I SI SI

V0TJCT S I I


V7777W S S I



63

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

V7UKSS I SI I

VHRVSQ S I I

VIBSI3 SI S

VJEFF1 I I


VWKVJV SI

VWVVHY S I

WATIXT I I

WH4B44 SI

WVV99T S S S I SI

X1WS11 SI SI SI I

XI5JGO S S SI

XIXNGM I SI SI

XKKPPR SI I

XNJQCT SI

XODXXJ SI I


XY5KFG SI I

Y6HBAA SI S S I I

YN88GB S S I I



YZSZMS S S S I I

Z9MTOM S I I

ZCYZZA S I I

ZO7E6M SI I XRD



64






Code Name Technique

INVI3H Amfetamine 180

QMWQTQ JWH-073 171/180

WH4B44 Heroin 180

XY5KFG Amfetamine 141

JMMMUB JWH-073 160/180


333WNF Heroin 150/180

142 150 160 161 190 200 220


SM-3 was a blank test sample prepared

from plant material

Section 140 141 142 171 180 190 200 211 231


Analyses not performed SM-3 Code: 8EKCQE

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 67 72 62 20 0 2 1 3 71 11 3 0 1 1 15

37.9% 40.7% 35.0% 11.3% 0.0% 1.1% 0.6% 1.7% 40.1% 6.2% 1.7% 0.0% 0.6% 0.6% 8.5%

Identification 9 3 2 44 12 19 2 29 159 60 5 2 1 4 13

5.1% 1.7% 1.1% 24.9% 6.8% 10.7% 1.1% 16.4% 89.8% 33.9% 2.8% 1.1% 0.6% 2.3% 7.3%


73 72 62 51 12 19 2 30 160 63 8 2 1 4 23

41.2% 40.7% 35.0% 28.8% 6.8% 10.7% 1.1% 16.9% 90.4% 35.6% 4.5% 1.1% 0.6% 2.3% 13.0%


65


Code Identified Substances0B00MA HEROIN

0BPIQK heroin and products of acetalization of morphine

15KHZZ Heroin

1NBQEB heroine

1OFS4X Heroin, 6-MAM

1X1W9X Heroine

20222K Heroin

2C5GCK Heroine

2JJEMT heroine, monoacetylmorphine

2KHKFK Heroine

333WNF Heroin

3I4END Heroine

3XMCSS HEROIN

4IHDMJ heroin

4MQGMT heroin, morphine

4QDDDD Heroine free base.

4WAP4I heroin

5B9R5Q Heroin

5D5Q5X HEROIN

6HXWOM Heroin

6I9L3N heroin

6P0WWW Heroin

6TZBOI heroine, 6-monoacetylmorphine

72SXT7 Heroin

7CVHQG Heroin

88CBR8 heroin

8EKCQE heroin and codeine

8P8J9S Heroin

8Z1D82 Heroin

999FTE heroine, 6-MAM

9AQQ5Z Heroin

9E9RV9 Heroine, codeine acetate, 6-mono acetyl morphine, Papaverine and Noscapine.

9G1IGG heroine

A55MTH Heroin, morphine

AFUPAX Heroin base

AG4RDN Heroin

AGX9RJ Heroin

AM75RV Heroin and Acetyl codeine

ASAZSF Heroin

ATMMIK Diacetylmorphine

Sample 4 Analysis



66

Code Identified SubstancesAXEI96 Heroin

BCQF5M Heroin

BFDDDR Heroine

BUBXUF HEROÍN

C0ZZJN HEROIN

C77B7S Heroine,acetylcodeine,6 monoacetylmorphine

CLWMLL Heroin

CML6FN Diamorphine (Heroin)

CRVCAC heroin

DF8IPB Heroine

DPMUDD Heroin (Diamorphine), purity 74%

DSTAS1 HEROIN

DXGEZT Heroin

EAEWNG heroin

EGOAAA heroin

EH8THK Heroine

EIUUUK heroin

EK1CYF Heroin, Morphine

EKXNNH Heroin

ERGL66 Diamorphine

FG6OYO heroin

FSLFBU Diamorphine (heroin)

FSOGSM Heroin

FUEK6X DIACETYLMORPHINE

G5W4WW Heroine + nimetazepam

GB3OEY Heroin

GBX7ZC Heroin

GFXM5C Heroine

GGUVGQ Heroin

GMGJSG Heroine

GOT2LZ HEROIN

GTTTTX HEROIN 69,1 % + 6-MONOACETYLMORPHINE + ACETYLCODEINE + NOSCAPINE + PAPAVERINE

H22O82 Heroin

HFQF1Q HEROIN

HKZ1VR Heroin, 6-Acetylcodeine

HPMMRG HEROINE, MONOACETILMORPHINE

HUA51A heroine

HV22C2 heroin(69%)

ICJJYI heroin

ILI0KV heroin

INVI3H heroin

IO7IOO Heroin, acetylcodeine, monoacetylmorphine and papaverine

IPDQJN Diamorphine

ISSSPG HEROINE



67

Code Identified SubstancesITHPL9 heroin

IUPHSS Heroin

IWH4C5 Heroine

IWII3P Heroin

JBOJJJ Heroin

JSAGFJ Heroin, Morphine and Codeine

JZAFXP Heroine, 6MAM, Noscapine, Papaverine, acetylcodeine

KFXSJH HEROINA

KHBFT2 Heroin

KHMABJ heroine

LHLHFD Heroin

LZIOS8 Heroine

MHLLML Heroine

MMUMRC heroin

N8RGKU heroin

NANRGN HEROINE

NSUV95 Heroin

NXTOSM heroine

NYXHZT HEROIN

ODCD2V heroin

ODZFBN Heroine

OIXWB8 heroin

OWVZ9H HEROINE

P5ABC7 HEROIN, ACETHYL MORPHINE, ACETHYL CODEINE.

P659G5 Heroine and acetylcodein

PVZFPA Heroin, Acetyl Codeine, Monoacetylmorphine, Noscapine and Papaverine

Q772TV Heroine

Q8LGQQ Heroin

QCYBCZ Heroin. HCl

QHH5X6 heroine, morphine, 6-monoacetylmorphine

QK1XXA morphine( trace)- codeine( trace) papaverine- 6- acetyl mophine - meconin - noscapine- acetyl codeine

QMWQTQ Heroin Base and Morphine

QRWM3W Heroin

QRXCOO Heroin

QVHXRP HEROIN

QYI8XO Heroin

QYYLCY Heroin base

R2EIGV Heroin

RB8OK5 heroin

RHRRWR Heroin

RIJIJC heroin

RJRT8O heroin

RNIHSP heroine, morphine



68

Code Identified SubstancesRQJY2X heroin

RQQ9IG heroin

RRERCL heroin

RV1ATU Heroin

S6JCMD diamorphine

SEQGAQ heroin

SFILGT heroin, morphine, 6-MAM, noscapine, acetylcodeine, papaverine

SWTTQX Heroin

TEKB5H heroin

TFLCTJ heroin

TK1XDK Heroin

TMIOPH heroin

TNQR0R Heroine

TOTXN0 Heroin

TRJR2R heroin

UJJUU1 DIAMORPHINE (HEROIN)

UJZXBO Heroin

UU0EDU heroin

V0TJCT Heroin

V5A5C5 heroine

V7777W Diamorphine

V7UKSS Heroine

VHRVSQ Diamorphine

VIBSI3 heroin

VJEFF1 Heroin

VVRYSV Heroin, Acetyl Codeine, 6-monoacetyl Morphine and Papaverine

VWKVJV heroin

VWVVHY Heroin

WATIXT heroin

WH4B44 Heroin,Morphine

WVV99T Heroin

X1WS11 Heroine

XI5JGO Heroin

XIXNGM Heroin

XKKPPR heroin

XNJQCT Heroine

XY5KFG Morphine, cocaine

Y6HBAA Diamorphine, Morphine, 6-monoacetylmorphine and Acetylcodeine

YN88GB Heroína

YSMOUG Heroin and monoacetylmorphine

YSNVND Heroin

YZSZMS Heroina

Z9MTOM heroin

ZCYZZA HEROINA - ACETILCODEINA



69

Code Identified SubstancesZO7E6M heroin base



70

Code Heroin Morphine minor comp.

0B00MA + -

Base Heroin, Acetyilcodeine, 6.Monoacetylmorphine, Papaverine and Noscapine, purity 72,6+/-3,29% (w/w)

0BPIQK + +

It has been detected the presence of heroin and subproducts of the acetalization of morphine in the sample.

15KHZZ + -

Beige powder containing heroin. Also detected acetylcodeine, monoacetylmprphine, papaverine and noscapine.

1NBQEB + -

After analyzing the sample with colorimetrics tests and confirmation with GC/MS methods and subsequent quantifcation with GC/FID, we confident that the sample contains 74.64 % of heroine base. Other substances caffeine

1OFS4X + -

Sample contains 72.2 ± 4.2 % heroin base.6-monoacetylmorphine, acetylcodeine, papaverine and noscapine were also detected.

1QHP1K ANP ANP

1X1W9X + -

Sample contain 82.8 % of heroine

20222K + -

Trace amounts of Acetilcodeine

2C5GCK + -

Presence of heroine was detected in the sample. The sample also contained acetylcodeine, 6-MAM, papaverine, noscapine and trace amounts of meconine, morphine and acetylthebaol.

2JJEMT + -

acetilcodeine traces

2KHKFK + -

we found heroine, 6-MAM, acetylcodeine, papeverine and noscapine in the sample

333WNF + -

3I4END + -

6-monoacetylmorphineacethylcodeine

3XMCSS + -

In the sample there are all the opium alcaloids: 6-MAM, ACETYLCODEINE, MORPHINE, PAPAVERINE, NARCOTINE

4IHDMJ + -

Powder containing heroin

4MQGMT + +

includes a few (<%1) morphine as trace

4QDDDD + -

Sample also include codeine, papaverine, noscapine and 6-acetylomorphine.

4WAP4I + -

we were found MAM-6 and Acetyl codeine in the sample

5B9R5Q + -

Analysis detected the presence of heroin (diamorphine) with an approximate purity of 68% (as base).




71


5D5Q5X + ANP

The sample contains a controlled substance as heroin, and other substances such as codeine and noscapine

6HXWOM + +

6-MAM, morphine, acetylcodeine, papaverine and noscapine are also detected. It is a sample of semi synthetic heroine as acetylcodeine is detected, partially degradated (6-MAM is detected) with an "usual" concentration of heroin in street samples.

6I9L3N + ANP

The sample contains heroine

6P0WWW + -

Heroin 72,79%, Acetylcodeine and Monoacetylmorphine.

6TZBOI + -

The sample also contain acetylcodeine, noscapine, papaverine.

72SXT7 + -

Test sample 2015/1/SM-1 contains heroin base 75.92 %, m/m with impurities.

7CVHQG + -

Acetylcodeine and Lactose

88CBR8 + -

We have found heroin and acetylcodeine by using GC-MS.

8EKCQE + -

analyzed by GCMS

8P8J9S + -

Sample contains heroin base (72,9%), 6-acetylmorphine, 6-acetylcodeine, papaverine and noscapine.

8Z1D82 + -

The sample SM4 was found to contain the controlled substance Heroin.

999FTE + -

meconine, acetylcodeine, noscapine, popaverine

9AQQ5Z + +

By using LC-MS and LC-MS-MS , th esample contain Heroin 80 % w/w , 6-monoacetylmorphine, Papaverine and Noscapine.Morphine found in trace amount.

9E9RV9 + -

Cobalt thiocyanate (CT) and Marquis reagent (MR), GC/MS retention time and mass charge ratio (M/Z) similar characteristics with the substances used as standard or pattern

9G1IGG + -

A55MTH + +

AFUPAX + -

SM4 contains 70.4 % Heroine base

AG4RDN + -

This sample is heroin.

AGX9RJ + -

acetylcodeine, papaverine, noscapine, 6-O-monoacetylmorphine

AM75RV + -

SM-4 gives positive to Marquis', Mecke and Froehde reagent. By TLC, found spots of Heroin and Acetyl Codeine.By GCMS, found peaks of Heroin, Acetyl Codeine and traces of codeine, 6-MAM and papaverine.Quantitaion with GC, SM-4 contains Heroin base 73.15%



72


ASAZSF + -

Sample also contain 6-monoacetylmorphine, acetylcodeine

ATMMIK + -

A sample of this powder was analysed an found to contain diacetylmorphine at a purity of 71%.

AXEI96 + -

Sample 2015/1/SM-1 contain 68.1% +/- 7.4% Heroin.

BCQF5M + -

SM-4 is positive for heroin.

BFDDDR + -

The sample obtains with positive result with Marquis reagent.TLC: The Rf sample obtain with the same Rf Heroine Standard.GC: The Rt sample obtain with the same Rt Heroine Standard.

BUBXUF + -

The results of the tests of SM4 (45) received confirmed that the mentioned sample contains heroín with 72.7 percentage by weight (72.7%).

C0ZZJN + -

Sample 2015/1/SM-4, a beige odourless powder, gave a positive result for heroin, a controlled substance under national legislation on drugs.

C77B7S + -

Identified Heroine,acetylcodeine,6 monoacetylmorphine and noscapine

CLWMLL + -

The powder contains 74% of héroïne as free base and 15% of narcotine. Heroïne is a controlled substance in France.

CML6FN + -

Quantity of brown powder weighing 0.19 grams analysed and confirmed to contain Diamorphine. Diamorphine is a class A controlled drug within the provisions of the Misuse of Drugs Act 1971.

CRVCAC + -

CXZ7SL + -

DF8IPB + -

- Primary screening allowed positive results for Heroine- GC/MS , FTIR and HPLC confirmed above results

DPMUDD + -

Diamorphine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

DSTAS1 + -

HEROIN

DXGEZT + -

Heroin is controlled by law (K.B. 31/12/1930, changed by K.B. 8/10/1963)

EAEWNG + -

found heroin with 69.4%ww

EGOAAA + -

heroin

EH8THK + -

The sample contains heroine. The content of heroine (as heroinebase) is determined to 83 %. Heroine is a controlled substance in Norway.

EIUUUK + -

The sample also contains acetil-codeine, noscapine, papaverin and 6-MAM (6-monoacetil-morphine).



73


EK1CYF + +

sample found to contain Heroin, Morphine, Acetylcodeine and 6-monoacetylmorphine

EKXNNH + -

The sample contains Heroin, Papaverine, Noscapine, 6-acetylmorphine and Acetylcodein.

ERGL66 + -

Powder was found to contain diamorphine, purity was determined to be 69% calculated as base.

FG6OYO + -

the sample contains heroin (scheduled as illicit drug in France)and noscapine

FSLFBU + -

The brown powder was analysed and found to contain diamorphine.

FSOGSM + -

Test sample 2015/1/SM-4 contains heroin.

FUEK6X + -

THE SAMPLE SM-4 WAS ANALYSED AND FOUND TO TO CONTAIN DIACETYLMORPHINE A DRUG

G5W4WW + -


GB3OEY + -

One glass bottle containing 0.22 grammes of a powder containing 0.15 grammes of heroin.

GBX7ZC + ANP

GFXM5C + -

The chemical tests and the coincidence in the time of retention and mass fragmentogram with the material of reference used in the same conditions that the analyzed sample, indicate in this one the Heroine presence.

GGUVGQ + -

GMGJSG + -

Heroin+6MAM+Acetyl-Codein+Papaverine+Noscapine

GOT2LZ - -

HEROIN 79.4% AS BASE

GTTTTX + -

H22O82 + -

The sample contained 67.3% w/w Heroin.

HFQF1Q + -

NOSCAPINE 17%, ACETYLCODEINE, PAPAVERIN, O6 MAM

HKZ1VR + -

The sample ICE2015/1/SM4 was found to contain Heroin and 6- Acetylcodeine.

HPMMRG + -

CODEINE, PAPAVERINE, NOSCAPINE AND TEBAINE

HUA51A + -

acetylcodeine, monoacetylmorphine, papaverine, noscapine

HV22C2 + ANP

heroin(69%), papaverine,noscapine



74


ICJJYI + -

quantification results: 76% +/-7

ILI0KV + -

heroin was detected by GC/MS screening and it was quantified by GC/FID using calibration curve.

INVI3H + -

a substance is related to drug - heroin

IO7IOO + -

the sample SM4 contains Heroin, acetylcodeine, monoacetylmorphine and papaverine

IPDQJN + -

Diamorphine (commonly known as Herion)

ISSSPG + -

HEROIN

ITHPL9 + -

containedacetylcodeine, 6-monoacetylmorphine, papaverine, noscapine

IUPHSS + -

The sample contains heroin

IWH4C5 + -

Acetylcodeine, 6-MAM, Noscapine, Papaverine

IWII3P + -

71.8%

JBOJJJ + -

The sample contains heroin (70.8%).

JMMMUB + -

JSAGFJ + +

Field test employing Marquis test was positive, TLC AND HPLC analysis performed to confirm. JZAFXP + -

sample no4 contains heroin, its origination is from opium without extraction

KFXSJH + ANP

PRUEBAS CROMATICAS: MARQUIS, MECKE, MICROCRISTALESINSTRUMENTALES: ESPECTROMETRIA UV, FT-IR, GC-MS

KHBFT2 + -

Contains Heroin (Diamorphine).

KHMABJ + -

The sample contains heroine, acetyl codeine, monoacetylmorphine, papaverine, noscapine.

LHLHFD + -

Heroin

LZIOS8 + -

The percentage of heroine is 63 %

MHLLML + -

Usual substance, unusual high potency.

MMUMRC + -

containedacetylcodeine, 6-monoacetylmorphine, papaverine, noscapine

N8RGKU + -

Sample 2015/1/SM-4 consists of light-brown powder. Heroin, a prohibited substance included in the National Law for Narcotics, is found to be present in this sample.



75


NANRGN + -

Sample 2015/1 / SM-4 is positive for heroin and also alcaloidales impurities such as 6- and acetylcodeine detected monoacetylmorphine

NSUV95 + +

The exhibit were found to contain Diacetylmorphine (heroin), 6-Monoacetylmorphine, Acetylcodeine, Morphine, Noscapine and meconin.

NXTOSM + ANP

NYXHZT + -

ACETYLCODEINE

ODCD2V + -

Heroin base confirmed in 1 unit tested of 1 unit received.

ODZFBN + -

The sample contains heroine (6-monoacetylmorphine, diacetylmorphine, papaverine, noscapine).

OIXWB8 + -

heroin 70.7%ww, 6-MAM (5,0%ww), acetyl-codeine

OWVZ9H + -

Light brown powder that conatins controlled substance HEROINE.

P5ABC7 + -

BROWN POWDER SAMPLE ANALYZED CONTAINS: HEROIN, ACETHYL MORPHINE, ACETHYL CODEINE.

P659G5 + -

PVZFPA + -

Examination revealed the presence of Heroin.

Q772TV + -

AcetylCodeine and Narcotine

Q8LGQQ + -

*Results of screening tests were positive for opiates. *Retention time and fragmentation pattern obtained with sample are equivalent to those obtained with heroin, 6-monoacetylmorphine and acetylcodeine.

QCYBCZ + -

QHH5X6 + +

brown powder containing heroine, morphine and 6-monoacethylmorphine, acethylcodeine, papaverine, noscapine

QK1XXA + -

QMWQTQ + +

Heroin (diacetylmorphine) and Morphine were identified in the sample. The percentage of the heroin in the sample was 66.88.

QRWM3W + -

acetycodenine, 6-monoacetylmorphine, papaverin and noscapine

QRXCOO + -

Violet color with Marquis test and yellow changing to light green color with Nitric Acid test indicates possible presence of Heroin. Analysis by GCMS shows the similarity as Heroin.

QVHXRP + -

HEROIN IS PRESENT IN BASE FORM. ACETYLCODEINE, 6-MAM, PAPAVERINE AND NOSCAPINE WERE IDENTIFIED

QYI8XO + -

The sample contains Heroin



76


QYYLCY + -

The sample contains heroin base ,6- mono-acetyl morphine and acetyl-codeine.Heroin is a scheduled as illicit drug.

R2EIGV + -

In the test sample 2015/1/SM-4 were detected heroin, 6-monoacetylmorphine and acetylcodeine

RB8OK5 + -

base, con acetato de codeina y monoacetil morfina como impurezas

RHRRWR + ANP

The sample was found to contain 67.90 % of heroin.

RIJIJC + -

The powder contains heroin and other opiates. The concentration of heroin, as free base, in the sample is 68.3% by weight.

RJRT8O + ANP

Heroin was as free base form

RNIHSP + +

RQJY2X + -

In the sample labeled as 2015/1 / SM-4 was found heroin, noscapine and papaverine.

RQQ9IG + -

after chemical analysis was performed the sample contain .1- heroin 90.3%2- alkaloid substance

RRERCL + -

RV1ATU + -

The GC/MS detected acetylcodeine, monoacetylmorphine and papaverine, but one can't confirm this substances because it haven't the standards.

S6JCMD + -

The sample was found to contain 72.0% of diamorphine (as base). The sample was also found to contain O6-MAM, papaverine and narcotine.

SEQGAQ + -

sample contained heroin HCl as a controlled drug

SFILGT + +

SWTTQX + +

Heroin detected.

TEKB5H + -

the light-brown powder contains heroin (69.1%ww) and 6-MAM (5.3%) which are substances controlled by national law.

TFLCTJ + -

TK1XDK + -

The sample found to contain Heroin

TMIOPH + -

The sample contain heroin.

TNQR0R + -

contained heroine and trace of acetylcodeine, 6-monoacetylmorphine, papaverine, noscapine

TOTXN0 + -

The sample contains heroin, acetylcodeine, papaverine and 6-monoacetylmorphine.

TRJR2R + -



77


UJJUU1 - -

Diamorphine (Heroin) is a Class A controlled drug under the provisions of the Misuse of Drugs Act 1971 (as amended).

UJZXBO + -

The test sample 2015/1/SM-4 was found to contain the controlled drug heroin.

UU0EDU + -

others: 6-MAM, acetil-codeine, papaverine, noscapine

V0TJCT + -

V5A5C5 + -

sample contains heroin, acetylcodeine,6monoacetylmorphine,papaverine and noscapine

V7777W + -

The powder was found to contain 71% diamorphine. Diamorphine is controlled by the Misuse of Drugs Act 1971 (as amended) as a Class A drug.

V7UKSS + -

Narcotics: heroine, approximately 68 % as free base

VHRVSQ + -

Item 2015/1/SM-4 contained Diamorphine (commonly known as "heroin"), at a purity of seventy-one per cent.

VIBSI3 + -

VJEFF1 + -

The sample contains heroin which is listed as a controlled drug according to french order, appendix I of February 22nd 1990.

VVRYSV + -

The Test sample 2015/1/SM-1 was analyzed by colour test and Thin Layer Chromatography technique and found to contain Heroin, Acetyl Codeine, 6-monoacetyl Morphine and Papaverine.

VWKVJV + -

VWVVHY + -

WATIXT + -

Heroin base is present (74% w/w) with noscapine papaverine 6MAM and acetylcodeine

WH4B44 + ANP

-

WVV99T + -

Brown powder containing Heroin (List I & IV CU 1961)

X1WS11 + ANP

XI5JGO + -

XIXNGM + -

./.

XKKPPR + -

brownish powder, other compounds - acetylcodeine, 6-MAM, papaverine and noscapine

XNJQCT + -

The sample contained heroine with 6-Acetylmorphine, Acetylcodeine, Papaverine and Noscapine.

XODXXJ + -



78


XRRKRK + -

XY5KFG - +

There was evidence that sample 2015/1/SM-4 contained morphine and cocaine

Y6HBAA + +

The sample contains Diamorphine (63.5% as base), Morphine, 6-Monoacetylmorphine, Papaverine and Acetylcodeine which are constituents of Heroin.

YN88GB + ANP

La sustancia decomisada contiene heroína.

YSMOUG + -

Based on the above analysis, the sample was found to contain heroin, monoacetylmorphine, acetylcodeine, papaverine and noscapine.

YSNVND + -

We found Heroin as controlled drug and also found acetylcodeine, Monoacetylmorphine (MAM), papaverine, and noscapine in test sample

YZSZMS + -

Z9MTOM + -

acetilcodeine, 6-MAM, noscapine

ZCYZZA + -

ZO7E6M + -

6-monoacethylmorphine, acethylcodeine



79


Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210


0BPIQK SI I

15KHZZ S I I SI

1NBQEB SI SI S I I

1OFS4X S SI I SI SI

1X1W9X SI

20222K S I I

2C5GCK SI I I I

2JJEMT SI I

2KHKFK I SI I

333WNF S S S I I

3I4END I SI

3XMCSS SI I

4IHDMJ SI

4MQGMT SI SI

4QDDDD S I I I

4WAP4I S I I I

5B9R5Q S S S I I

5D5Q5X S I SI

6HXWOM I I SI I

6I9L3N S S S I S

6P0WWW S I

6TZBOI S SI SI I

72SXT7 I SI

7CVHQG S I I

88CBR8 SI

8EKCQE SI SI I I

8P8J9S S S I

8Z1D82 I S

999FTE SI

9AQQ5Z SI I

9E9RV9 S S S I

9G1IGG SI I

A55MTH I





80

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

AFUPAX I S I I

AG4RDN S I I

AGX9RJ S S S I I

AM75RV S S S I I

ASAZSF SI ASAP-TOF


AXEI96 S SI

BCQF5M S I

BFDDDR S S S I

BUBXUF S S S I I

C0ZZJN S S S I

C77B7S S S S SI


CML6FN S I

CRVCAC I SI SI

CXZ7SL S I

DF8IPB S I I

DPMUDD S S S I

DSTAS1 SI I

DXGEZT S I S

EAEWNG SI

EGOAAA SI

EH8THK I I

EIUUUK S SI SI I

EK1CYF S I I I

EKXNNH S S S I SI I

ERGL66 I I

FG6OYO S I I I

FSLFBU S I I


FUEK6X S S I I

G5W4WW

S S S I I

GB3OEY S S SI

GBX7ZC I

GFXM5C S S S I

GGUVGQ SI

GMGJSG I S ION-SCAN

GOT2LZ S S S I

GTTTTX S S S SI I I



81

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

H22O82 S S S I I I

HFQF1Q SI

HKZ1VR S S S I I

HPMMRG I SI


HV22C2 S I I

ICJJYI S I

ILI0KV SI

INVI3H SI


IPDQJN I SI SI

ISSSPG S S S I I

ITHPL9 SI

IUPHSS I SI I

IWH4C5 SI I

IWII3P SI

JBOJJJ S S S I I

JMMMUB S S SI I I I



KFXSJH S S SI I I

KHBFT2 S S S I I

KHMABJ S S SI SI I

LHLHFD SI SI I



MMUMRC SI

N8RGKU S S I I I


NSUV95 I I S

NXTOSM S S S I

NYXHZT S S S SI I

ODCD2V I SI I

ODZFBN I I

OIXWB8 I I SI

OWVZ9H S S I I

P5ABC7 S S I

P659G5 S S I I

PVZFPA S SI



82

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Q772TV S I

Q8LGQQ S S S I I

QCYBCZ I I SI

QHH5X6 SI


QMWQTQ


QRWM3W

I SI


QVHXRP I SI I

QYI8XO S I I

QYYLCY I SI I

R2EIGV I

RB8OK5 S I I

RHRRWR S I


RJRT8O SI

RNIHSP S S I I

RQJY2X S S I

RQQ9IG S S I

RRERCL S S S I I

RV1ATU I I I SI

S6JCMD SI I ELSD


SFILGT I SI I

SWTTQX S S I

TEKB5H I I SI

TFLCTJ I SI

TK1XDK S S I

TMIOPH S SI I SI I

TNQR0R SI

TOTXN0 SI

TRJR2R SI SI


UJZXBO S S S I I

UU0EDU I SI SI

V0TJCT S I I


V7777W S S I



83

Code 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

V7UKSS I SI I

VHRVSQ S I I

VIBSI3 SI S

VJEFF1 I I


VWKVJV SI

VWVVHY S I

WATIXT I I

WH4B44 SI

WVV99T S S S I SI

X1WS11 SI SI SI I

XI5JGO S S SI

XIXNGM I SI SI

XKKPPR SI I

XNJQCT SI

XODXXJ SI I


XY5KFG SI I

Y6HBAA SI S S I I

YN88GB S S I I



YZSZMS S S S I I

Z9MTOM S I I

ZCYZZA S I I

ZO7E6M SI I XRD



84






Code Name Technique

G5W4WW Nimetazepam 150/171


XY5KFG Cocaine 141/200

142 150 160 161 190 200 220


Heroin 173

Morphine (minor component) 15

Section 140 142 150 160 161 170 171 180 190 200 211 231

140 141 142 150 200 211 231


False negatives for SM-4 (technique(s) used or ANP)

Code: UJJUU1 (180/190), XY5KFG) (141/200), 1QHP1K (ANP)

Section 140 141 142 150 160 161 170 171 180 190 200 211 230 231 210

Screening 67 72 62 20 0 2 1 3 71 11 3 0 1 1 15

37.9% 40.7% 35.0% 11.3% 0.0% 1.1% 0.6% 1.7% 40.1% 6.2% 1.7% 0.0% 0.6% 0.6% 8.5%

Identification 9 3 2 44 12 19 2 29 159 60 5 2 1 4 13

5.1% 1.7% 1.1% 24.9% 6.8% 10.7% 1.1% 16.4% 89.8% 33.9% 2.8% 1.1% 0.6% 2.3% 7.3%


73 72 62 51 12 19 2 30 160 63 8 2 1 4 23

41.2% 40.7% 35.0% 28.8% 6.8% 10.7% 1.1% 16.9% 90.4% 35.6% 4.5% 1.1% 0.6% 2.3% 13.0%


85

Z-Scores for Test Sample 4



Concentration

(mass%)

Deviation from

robust average

z-scoreConcentrat

ion (mass%)

Deviation from

robust average

z-score

4MQGMT 0.10 70.9 -17.4 QVHXRP 70.40 0.6 -0.1A55MTH 0.16 70.8 -17.4 RRERCL 70.60 0.4 -0.1JSAGFJ 1.14 69.9 -17.1 VWVVHY 70.60 0.4 -0.1DF8IPB 9.99 61.0 -14.9 XODXXJ 70.60 0.4 -0.1FUEK6X 23.85 47.2 -11.5 OIXWB8 70.70 0.3 -0.1BFDDDR 24.58 46.4 -11.4 JBOJJJ 70.80 0.2 0.0A55MTH 27.93 43.1 -10.5 XIXNGM 70.80 0.2 0.0HUA51A 41.20 29.8 -7.3 EKXNNH 71.00 0.0 0.07CVHQG 59.05 12.0 -2.9 ITHPL9 71.00 0.0 0.0RB8OK5 60.00 11.0 -2.7 V7777W 71.00 0.0 0.0RJRT8O 62.30 8.7 -2.1 VHRVSQ 71.00 0.0 0.05D5Q5X 63.00 8.0 -1.9 VJEFF1 71.00 0.0 0.0LZIOS8 63.00 8.0 -1.9 ILI0KV 71.02 0.0 0.0Y6HBAA 63.50 7.5 -1.8 MHLLML 71.16 0.2 0.10BPIQK 64.00 7.0 -1.7 IWH4C5 71.20 0.2 0.1JZAFXP 64.00 7.0 -1.7 3I4END 71.28 0.3 0.1KHMABJ 65.80 5.2 -1.3 AG4RDN 71.32 0.3 0.1ZO7E6M 65.95 5.1 -1.2 GB3OEY 71.40 0.4 0.1UJJUU1 66.00 5.0 -1.2 ATMMIK 71.42 0.4 0.1WVV99T 66.82 4.2 -1.0 XKKPPR 71.50 0.5 0.1QMWQTQ 66.88 4.1 -1.0 88CBR8 71.78 0.8 0.2YZSZMS 66.90 4.1 -1.0 DSTAS1 71.80 0.8 0.2X1WS11 67.24 3.8 -0.9 IWII3P 71.80 0.8 0.2H22O82 67.30 3.7 -0.9 RV1ATU 71.90 0.9 0.2V7UKSS 67.75 3.3 -0.8 RV1ATU 71.90 0.9 0.25B9R5Q 67.90 3.1 -0.7 S6JCMD 72.00 1.0 0.3RHRRWR 67.90 3.1 -0.7 1OFS4X 72.20 1.2 0.3AXEI96 68.10 2.9 -0.7 4MQGMT 72.20 1.2 0.3

4QDDDD 68.27 2.7 -0.7 CRVCAC 72.20 1.2 0.3RIJIJC 68.30 2.7 -0.7 C77B7S 72.30 1.3 0.3

QHH5X6 68.62 2.4 -0.6 ODCD2V 72.90 1.9 0.4IPDQJN 68.70 2.3 -0.6 0B00MA 72.60 1.6 0.4R2EIGV 68.90 2.1 -0.5 BUBXUF 72.70 1.7 0.4

QRWM3W 68.99 2.0 -0.5 6P0WWW 72.79 1.8 0.5CML6FN 69.00 2.0 -0.5 MMUMRC 72.80 1.8 0.5DXGEZT 69.00 2.0 -0.5 8P8J9S 72.90 1.9 0.5ERGL66 69.00 2.0 -0.5 FG6OYO 73.00 2.0 0.5HV22C2 69.00 2.0 -0.5 Q8LGQQ 73.00 2.0 0.5GTTTTX 69.10 1.9 -0.5 VWKVJV 73.00 2.0 0.5TEKB5H 69.10 1.9 -0.5 KFXSJH 73.04 2.0 0.5EAEWNG 69.40 1.6 -0.4 AM75RV 73.15 2.2 0.52C5GCK 69.70 1.3 -0.3 Z9MTOM 73.30 2.3 0.64IHDMJ 69.80 1.2 -0.3 333WNF 73.43 2.4 0.6NYXHZT 69.81 1.2 -0.3 6I9L3N 73.70 2.7 0.7GGUVGQ 70.00 1.0 -0.2 999FTE 73.77 2.8 0.76HXWOM 70.10 0.9 -0.2 4WAP4I 73.80 2.8 0.7VIBSI3 70.20 0.8 -0.2 CLWMLL 74.00 3.0 0.7AFUPAX 70.40 0.6 -0.1 DPMUDD 74.00 3.0 0.7

WATIXT 74.00 3.0 0.7TNQR0R 74.10 3.1 0.8ODZFBN 74.30 3.3 0.8

Code

Heroin

Code

Heroin

86

*) Concentration: w/w %



Concentration

(mass%)

Deviation from

robust average

z-score

2KHKFK 74.50 3.5 0.91NBQEB 74.64 3.6 0.9BCQF5M 74.96 4.0 1.09G1IGG 75.00 4.0 1.072SXT7 75.92 4.9 1.2ICJJYI 76.00 5.0 1.2

WH4B44 76.00 5.0 1.2NXTOSM 76.30 5.3 1.3IUPHSS 77.66 6.7 1.68Z1D82 78.00 7.0 1.7GOT2LZ 79.40 8.4 2.1HFQF1Q 79.43 8.4 2.19AQQ5Z 80.00 9.0 2.2INVI3H 80.49 9.5 2.3TRJR2R 82.00 11.0 2.71X1W9X 82.80 11.8 2.9EH8THK 83.40 12.4 3.1V5A5C5 83.52 12.5 3.1XI5JGO 84.30 13.3 3.3TFLCTJ 86.30 15.3 3.8

QRXCOO 89.54 18.5 4.6RQQ9IG 90.30 19.3 4.73XMCSS 92.80 21.8 5.4

Heroin

Code

87

Substance: SM-4; Heroin

Round: 2015/1







‐2.9‐2.7

‐2.1 ‐1

.9‐1.9 ‐1.8 ‐1.7

‐1.7

‐1.3 ‐1.2

‐1.2‐1.0

‐1.0

‐1.0 ‐0.9

‐0.9 ‐0.8 ‐0.7

‐0.7 ‐0.7 ‐0.7

‐0.7 ‐0.6

‐0.6 ‐0.5

‐0.5

‐0.5

‐0.5

‐0.5

‐0.5

‐0.5

‐0.5 ‐0.4 ‐0.3

‐0.3

‐0.3 ‐0.2

‐0.2

‐0.2 ‐0.1

‐0.1 ‐0.1

‐0.1

‐0.1

‐0.1 0.0

0.0

0.0

0.0

0.0

0.0

0.0

0.0 0.1

0.1 0.1

0.1 0.1

0.1

0.1 0.2

0.2

0.2

0.2 0.2 0.3 0.3

0.3

0.3 0.3 0.4 0.4 0.4

0.5

0.5 0.5 0.5

0.5

0.5

0.5 0.5 0.6 0.6 0.7 0.7

0.7 0.7

0.7

0.7 0.8 0.8 0.9

0.9 1.0

1.01.2

1.2

1.2 1.3

1.6 1.7

2.1

2.1 2.2 2.3

2.72.9 3.

1 3.1 3.

33.8

‐4.0

‐3.0

‐2.0

‐1.0

0.0

1.0

2.0

3.0

4.0

4MQGMT

JSAG

FJ

FUEK

6X

A55M

TH

7CVH

QG

RJRT

8O

LZIOS8

JZAF

XP

KHMAB

J

UJJUU1

QMWQTQ

X1WS11

V7UKSS

5B9R

5Q

4QDD

DD

QHH5X

6

R2EIGV

DXGEZT

HV22

C2

TEKB

5H

EAEW

NG

4IHDM

J

GGUVG

Q

VIBSI3

QVH

XRP

RRER

CL

OIXWB8

JBOJJJ

EKXN

NH

VHRV

SQ

ILI0KV

IWH4C

5

AG4R

DN

ATMMIK

88CB

R8

DSTA

S1

RV1A

TU

CRVC

AC

4MQGMT

0B00

MA

ODC

D2V

MMUMRC

Q8LGQQ

VWKV

JV

AM75

RV

333W

NF

999FTE

WAT

IXT

DPMUDD

ODZFBN

1NBQ

EB

9G1IGG

WH4B

44

NXT

OSM

8Z1D

82

HFQF1Q

INVI3H

1X1W

9X

V5A5

C5

TFLCTJ

RQQ9IG

‐17.4

‐17.4

‐17.1

‐14.9

‐11.5

‐11.4

‐10.5

‐7.3

5.4

4.7

4.6

88

Round: 2015/1


-10.0

-8.0

-6.0

-4.0

-2.0

0.0

2.0

4.0

6.0

8.0

10.0

z-sc

ore

Dispersion of z-scores using different analytical techniques for the quantification of heroin in 2015/1 SM-4

HPLC GC-FID GC/MS

89

The Laboratory and Scientific SectionUNODC, International CentreWagramer Strasse 5, P.O. Box 500A-1400, Vienna, AUSTRIAEmail: [email protected]



90

international quality assurance programme (iqap ... · the test sample also contained glucose,...

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