international quality assurance programme (iqap) … · 2013. 10. 9. · o0lrtk heroin (dam) and...

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)

INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

Summary ReportSEIZED MATERIALS

2013/1

This report contains the data received from laboratories participating in the current exercise. The results compiled in this report are not intended to be an overview of the quality of work and cannot be interpreted as such. These comments do not reflect the general state of the art within the profession.

Participant results are reported using a randomly assigned "WebCode". This code maintains participant's anonymity, provides linking of the various report sections, and will change with every report.

Samples Substances from the ICE Menu Concentrations Comments on substancesSample 1 Heroin 47.9 %

Caffeine N/A

Sample 2 Morphine 68.7 %

Sample 3 Lactose N/A

Nimetazepam 3.7 %

Sample 4 Amfetamine 10.3 %

Test Samples Information

Samples Comments on samplesSample 1 SM-1 was prepared from a seizure containing 47.9% Heroin base. The seizure also contained 6-

monoacetylmorphine, acetylcodeine, caffeine, papaverine, dextrometorphan and codeine. Trace amounts of morphine and noscapine could also be detected

Sample 2 SM-2 was prepared from a seizure containing 68.7% Morphine base. The seizure also contained codeine and trace amounts of 6-monoacetylmorphine and heroin.

Sample 3 SM-3 was prepared from a seizure containing 3.7% Nimetazepam. The seizure also contained lactose and glucose

Sample 4 SM-4 was prepared from a seizure containing 10.3% Amfetamine base. The seizure also contained sucrose and trace amounts of methamphetamine and diphenylisopropylamine

2013/1-SM Copyright (c) 2013 UNODC

INTERNATIONAL QUALITY ASSURANCE PROGRAMME (IQAP)INTERNATIONAL COLLABORATIVE EXERCISES (ICE)

Table of contents Introduction Page 3 Comments from the International Panel of Forensic Experts Page 3 Codes and Abbreviations Page 5 Sample 1 Analysis Page 6 Identified substances Page 6 Statement of findings Page 10 Identification methods Page 19 Summary Page 23 Z-Scores Page 24 Sample 2 Analysis Page 27 Identified substances Page 27 Statement of findings Page 30 Identification methods Page 38 Summary Page 42 Z-Scores Page 43 Sample 3 Analysis Page 45 Identified substances Page 45 Statement of findings Page 48 Identification methods Page 56 Summary Page 60 Z-Scores Page 61 Sample 4 Analysis Page 63 Identified substances Page 63 Statement of findings Page 66 Identification methods Page 74 Summary Page 78 Z-Scores Page 79

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Introduction An important element of the UNODC International Quality Assurance Programme (IQAP) is the implementation of the International Collaborative Exercises (ICE). The exercises allow laboratories, from both developing and developed countries, to continuously monitor their performance in drug testing on a truly global scale. This report provides information on analytical results of laboratories participating in the Seized Materials (SM) group. In order to maintain confidentiality, the participating laboratories have been assigned random “Web Codes”, which change every round. Two rounds are offered per year with each round presenting participants with four different test samples for analysis. The analytical results returned by laboratories participating in ICE are evaluated by UNODC and a confidential report is provided to each laboratory on its own performance. The overall analytical results are reviewed by the UNODC’s International Panel of Forensic Experts which oversees the implementation of these exercises, and offers guidance and support in addressing relevant quality issues. The exercises provide an overview of the performance and capacity of participating laboratories and enable UNODC to tailor technical support in the laboratory sector for greatest impact.

Comments from the International Panel of Forensic Experts Participation of Laboratories Samples within both the Seized materials (SM) and Biological Specimens (BS) test groups were sent to 165 laboratories in 57 countries. Within the SM test group, samples were sent to 139 laboratories and 132 laboratories (95%) submitted the results of their analysis in time for inclusion in the summary report, with 128 (97%) using the ICE portal for return of results. The almost universal usage of the ICE portal is a high endorsement of its utility. Some laboratories had difficulty in obtaining import authorization particularly for the new psychoactive substances included in the ICE menu and this resulted in an extension of the deadline for submission of results. It is hoped that these delays will be decreased in the future as both participants and competent authorities become more familiar with the international import/export requirements for these emerging substances. Qualitative Analysis The results for the qualitative identification of the controlled substances were good for all test samples in the SM group. In particular, with correct identification of the heroin in SM-1 and the morphine in SM-2 by 100% and 95% of participants respectively. SM-3 containing nimetazepam and SM-4 containing amphetamine were identified by 91% and 94% of participants respectively. Some 89.4% of participants overall used GC-MS for the qualitative analysis indicating access to this technique which is one of the most commonly used tandem techniques for the confirmation of controlled substances. It is encouraging to note that only six false positive results for controlled substances within the ICE menu were reported for the four test samples in the SM group, while there were a total of 24 false negative results. The seizure used for SM-1 contained at least nine components and 35 laboratories identified the trace amounts of morphine present. Participants who identified the morphine may have in error received a false positive result upon submission of results via the portal. As the amount of morphine present was low, those laboratories who did not identify it need not consider the result a false negative. For SM-4, five laboratories using GC/MS also identified trace amounts of methamphetamine present and similarly, this result need not be considered a false positive. The detection limits of the different analytical techniques shall be taken into consideration when ascribing false positive results in future ICE rounds. Quantitative Analysis A modified Z-score was used for the statistical examination of the quantitative results, as it is a robust method based on absolute deviations from the median of all participant values and is relatively insensitive to outliers. The proportion of participants who carried out quantitative analysis, 90 (68%) for SM-1, 54 (41%) for SM-2, 41 (31%) for SM-3 and 76 (58%) for SM-4 continues to be encouraging. The percentages of laboratories performing quantitative analysis for heroin has remained stable at 68% for ICE 2012/1, 70% for ICE 2012/2 and 68% for this current round. The percentages of laboratories performing quantitative analysis for morphine is also stable at 46% for ICE 2011/1 and 41% for the current round. Similarly, the percentages of laboratories performing quantitative analysis for amphetamine are comparable with 59% for


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both ICE 2011/2 and 2012/1, and 58% for the current round. Nimetazepam is a new substance on the ICE menu for this current round and it is encouraging to see 31% of laboratory already performing quantitative analysis for this drug. It is understood that quantitative analysis of controlled substances is often governed by local legislation and the prosecution requirements. Analysis of the Z-scores showed that 77 out of 90 (86%) of participants provided acceptable quantitative results with Z-scores within 3.5 for heroin in SM-1, 52 out of 54 (96%) for morphine in SM-2, 32 of 41 (78%) laboratories for nimetazepam in SM-3 and 68 of 76 (87%) for the amphetamine in SM-4. Participants with Z-scores outside acceptable limits should review their quantification procedures. 69% of participants in this round quantified at least one test sample and 30% quantified all four test samples. Z-score values obtained from quantitative analysis assist participating laboratories in evaluating their performance and Z-scores should be monitored over time as part of each laboratory’s quality assurance programme.


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Codes and Abbreviations

Tech Code Name140 Colorimetric reactions

141 Marquis reagent (sulphuric acid, formaldehyde)

142 Cobalt thiocyanate

150 Thin Layer Chromatography

160 High/Ultra High Performance Liquid Chromatography

161 High Performance Liquid Chromatography with diode array detection

170 Gas Chromatography NPD

171 Gas Chromatography FID

172 Gas Chromatography ECD

180 Gas Chromatography/Mass Spectrometry

190 Fourier Transform Infrared Spectrometry

200 Spectrophotometry (visible, UV)

210 Others (specify)

211 NMR

220 Microcrystal test

230 Liquid chromatography/mass spectrometry

231 Liquid chromatography/tandem mass spectrometry

(+) “positive”: Indicates that the analyte is identified; for presumptive tests (e.g. colour reactions), indicates that a positive reaction was obtained.

(-) “negative”: Indicates that the analyte is not identified.

(ANP): Analysis not performed.

2013/1-SM Copyright (c) 2013 UNODC(5)


Identified substances for Test Sample 1

Code Identified Substances00H0DT heroin

0DAKSM Heroin

0SRDXD heroin

0T0BVS HEROINA

1HR18P Heroin, 6-Monoacetylmorphine, acetylcodeine

1R7FTA Heroin and Monoacetylmorphines

1SWNJJ heroin, caffeine

22JWSL Heroine

2ACHVO opiates

2FELET Heroin

2IOV6B héroine

2QK02D Heroína Clorhidrato

2SMWYX Herion,caffeine,6-monoacetylmorphine

3E3XE3 Heroin, 6-MAM, Acetylcodeine, Dextromethorphane, caffeine

400BTP Heroin

424NFI Heroin

4ED4U4 Diamorphine

4FLYLL HEROINE

4P9OST Heroin

4ZRH5B Heroine

5AL4YL Heroine and codeine

5ZSPFZ Heroin

6CS6GB Heroina

77H7IH Heroin

78CN24 morphine, héroïne, lidocaïne

7BREL7 Heroin, Monoacetylmorphine, Morphine

7H5WS7 heroine

88O8O8 heroin.morphine.

8KXYZQ Heroin

8LLTJE caffeine, dextromethorphane, morphine, 6-acetylcodeine, 6-monoacetylmorphine, diacethylmorphine

8QXEZ5 heroine

99WMWJ heroin,mprphine,codiene,papaverine

9EU3UC heroin

9WEC99 HEROIN; MORPHINE

AJWS6O Diamorphine

AMA50Q Heroin. Traces of dextromethorphan, codeine and morphine

APYADP we found heroin

B824TN Heroin and morphine

BBEBBB Heroin HCl

BPBBMB Heroin

Sample 1 Analysis



Code Identified SubstancesBZBJBP Heroin

C2WUON Heroin,Morphine,Caffeine,Paracetamol

C5ZRZ2 HEROIN

CIIE5Y YES, MORPHINE Y CODEINE, ACETAMINOPHEN.)

CLW6JW Heroin

CQC6CC HEROIN

CSDDCC HEROIN CHLORHYDRATE

DDXKOD HEROIN. CAFFEINE

DVAVS7 heroin, caffeine

EIJIBE HEROIN

EK1BZR Heroin

EYBQOO Heroin, morphine

EYEEEV Heroin, codeine, papaverine, morphine, caffeine, 6-acetylmorphine, 6-acetylcodeine, dextromethorphan

F66RUS Heroin

FF11HE heroin

G9XDGK Heroine

GUEUUR Diamorphine

HPPPFP Héroin, probably morphine, 6MAM, acétylcodeine

HRHXY5 Heroin

HSJGXV Heroin

IBADDP Diamorphine, Caffeine, Dextromethorphan indicated

IQXIII heroin

IYZYBB opiates (heroin)

J9KZ5A Morphine, codeine, heroin

JBRMJJ Heroin

JCJPKW Diamorphine

JGOKP5 Heroin

JNYC8O Heroin, Morphine, Caffeine

JQIGMD HEROIN

JTSJJD Heroin, Caffeine

JUNUUU heroin, caffeine, acetylcodeine, 6-MAM

K7QIQW Heroin, Codeine, 6-monoacetylmorphine, Acetylcodeine, Dextromethorphan

KBTTYE heroin

KFTKVQ heroin, morphine

KW3BDH heroin (DAM) and monoacetylmorphine (MAM)

L1N1AS Heroin, Morphine

LACFSF Heroina, Cafeina

LLDWGL heroin

LTLGBL Heroin

LTXFMY Heroin; caffeine;Mephedrone

M5FWNJ heroin

MDPWHT heroin

MKND72 Heroin, Morphine, 6-monoacetylmorphine,Acetylcodeine



Code Identified SubstancesMMHHSD Heroin

MRHASS Heroin

N0NNLS heroin

N1M8LG Heroin

N666MQ Heroin and Caffeine.

NA2AKJ Diamorphine HCL

NO9OBB Heroine HCl

NPDHYI heroin

O0LRTK heroin (DAM) and monoacetylmorphine (MAM)

OPBW2C Heroin

OVCNJF Heroin

PCIBIV dextromethorphan

PDGMFW Heroin, Morphine, O6-MAM, Codeine

PPHC9X heroin

PQLTDR heroin

PSOAIJ Heroin

PUS7H2 6-Monoacetilmorfina, Acetilcodeina, Morfina y Heroina

QJIQTJ Heroin

R8O18R Heroine

RIJOTJ heroin

RPGPEM heroin hydrochloride

RXGBPA heroine

S2O5GO Heroína

S6OORI heroine

SADCGQ Heroin, Morphine

SOQRQ9 HEROIN

SSOSVY Heroin

SSSCSJ heroin, morphine

T0QNTU Heroin

TBBUSK heroin, morphine

TDDURM DIACETIYL MORPHFINE (HEROIN) (MORPHINE)

TXQHJG heroin, caffeine, 6 Mono acetilmorphine and acetilcodeine.

UHMVSZ HEROINA, MORFINA, CODEINA, MONOACETILMORFINA Y CAFEINA

UT6VEX 6-Monoacetylmorphine and Diacetylmorphine

UTL3JI Heroin

VFLGQF Heroin,

VLZ8LL heroine, morphine

VMSX5E HEROIN HCL

W4SM4Y Heroin

WKJAI3 heroine

WPYVIW Base Heroin

XKGJ2G Diamorphine

XPE2VZ Heroin

YCSW1Z heroin



Code Identified SubstancesYETFFI Heroin hydrochloride

YULAAJ heroin, caffeine

YYMCDP heroin

Z4FNNZ Heroin



Code Caffeine Heroin00H0DT - +

Heroin is controlled by law (KB 31/12/1930 changed by KB 8/10/1963).

0DAKSM - +The sample contains the controlled drug heroin 47.36 %, m/m.

0SRDXD + +The powder is a mixture of heroin and caffeine. The concentration of heroin in the sample is 47.3% by weight

0T0BVS ANP +La sustancia analizada se trata de heroína

1HR18P + +Caffeine

1R7FTA + +Based on the above analysis, the sample was found to contain Heroin and Monoacetylmorphines

1SWNJJ + +

22JWSL + +The sample SM-1 contains a mixture of caffeine, heroine, 6-acetylcodeine and dextromethorphan.

2ACHVO + +heroinmorphinecafeineacetyl codeine

2FELET - +SM-1 was found to be contain Heroin. Monoacetyl Morphine and acetyl codeine also was detected in this sample

2IOV6B + +6 monoacetylmorphine , acetylcodéine, levometorphane, papvérine, noscapine

2QK02D + +Se detectan cafeína, 6-Monoacetilmorfina, Acetilcodeína y Codeína.

2SMWYX + +SM1 was prepared from a seizure containing 39.8% w/w herion base. The seizure also contained caffeine and 6-monoacetylmorphine.

3E3XE3 + +

400BTP + +In the dust sample analyzed was detected the presence of Heroin, Acetylcodeine,6 monoacetylmorphine and caffeine.

Statement of findings for Test Sample 1



Code Caffeine Heroin424NFI + +

Sample 2013/1/SM-1 consists of light yellow powder. Heroin, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains morphine, codeine, methadone, acetylcodeine and 6-mono-acetyl-morphine.

4ED4U4 + +0.228 grams of a powder containing 54% Diamorphine. Diamorphine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

4FLYLL + +

4P9OST + +Sample 2013/1/SM-1 was found to contain controlled substance HEROIN, a Schedule I drug under the Single Convention on Narcotic Drugs.

4ZRH5B + +the sizure also contained heroine, acetylcodeine, 6-monoacetylmorphine, dextrometorphan, cofeine and trace amounds of codeine and morphine

5AL4YL + +

5ZSPFZ + +we found aswell in this sample caffeine and 6-acetyl morphineand acetyl codeine

6CS6GB + +Cafeina, Acetil Codeina, 6-Monoacetil Morfina

77H7IH + +We found Heroin in SM-1 as controlled drug

78CN24 - +l'analyse de l'échantillon 2013/1/SM-1 révèle la présence de la morphine, de l'héroïne et de la lidocaïne

7BREL7 + +On analysis, i found the substances to contain 47.59% of heroin, 1.31% of morphine and 16.09% of monoacetylmorphine

7H5WS7 ANP +The seizure contained heroine

88O8O8 ANP +

8KXYZQ + +Sample contain heroin. The sample contain also caffeine, acetyl-codeine, and 6-monoacetyl-morphine

8LLTJE + +heroin was as hydrochloride form

8QXEZ5 + +heroine, caffeine, dextromethorphane,6-monoacetylmorphine,morphine,codeine



Code Caffeine Heroin99WMWJ + +

the sample conatins 41.2 % Heroin and 2.8 % Morphine

9EU3UC + +

9WEC99 + +/

AJWS6O ANP +One glass bottle labelled '2013/1/SM-1 containing 0.225g of beige coloured powder. This powder contained on average of 45% diamorphine which is commonly referred to as 'heroin'. Diamorphine is a class A controlled drug under the misuse of Drugs Act (1971)(as ammended).

AMA50Q + +Cream-coloured powder containing heroin. Also dected traces of dextromethorphan, codeine and morphine, as well as acetylcodeine, monoacetylmorphine and caffeine.

APYADP + +the sample also contains caffeine and 6MAM and acetylcodeine as metabolites

B824TN + +Heroin and morphine and caffeine

BBEBBB + +SM 1 contain also Coffeine and Dextromethorphan

BPBBMB + +SM-1 was identified as illicit Heroin

BZBJBP + +Heroin. The seizure also contained 6-monoacetylmorphine, acetylcodein, dextromethorphan and trace amounds of morphine, codeine and morphine-3-acetate

C2WUON + +-

C5ZRZ2 + +CAFFEINE, ACETYLCODEINE, MONOACETILMORPHINE

CIIE5Y + +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-1 WAS FOUND HEROIN, MORPHINE, CAFFEINE, CODEINE, PAPAVERINE AND NOSCAPINE.

CLW6JW + +Diluted with caffeine

CQC6CC + +HEROIN 48.2% AS BASE. CAFFEINE WAS IDENTIFIED AS ADULTERANT

CSDDCC + +caffein, glucose



Code Caffeine HeroinDDXKOD + +

The sample 2013/1/SM-1 was found to contain and Caffeine.

DVAVS7 + +The sample contains heroin which is scheduled as illicit drug in XXXX. Caffeine is also present as cutting agent.

EIJIBE + +HEROIN CHLORIDRATE (45.4% as base) - CAFFEINE

EK1BZR + +The powder was analysed and found to contain heroin (diamorphine).

EYBQOO + +SM-1 contains heroin, 46% and trace quantity of morphine

EYEEEV + +*Results of screening tests were positive for opiates. *Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained with heroin, codeine, papaverine, morphine, caffeine, 6-acetylmorphine, 6-acetylcodeine and dextromethorphan.

F66RUS + +Sample contain drug- Heroin

FF11HE + +mixture of heroin and coffeine

FNZI88 + +

G9XDGK + +The sample SM1 contained 44.1 % heroine calculated as a base.In this sample was identified caffenie, dextromethorphan, codeine, acethylcodeine, 6-monoacetylmorphine, diacetylmorphine (heroine), papaverine, noscapine

GUEUUR + +One glass vial with lid attached containing 218mg of pale brown powder containing an average of 46% diamorphine (heroin) together with the adulterant caffeine.

HPPPFP + +Morphine, 6MAM, acetylcodeine are not quantified routinely in our laboratory

HRHXY5 + +The saple contains heroin (47.2%), caffeine, acetylcodeine and 6-monoacetylmorphine.

HSJGXV + +Heroin (47.65% base), caffein, monoacetylmorphine and acetylcodeine.

IBADDP + +On analysis, the powder was found to contain diamorphine.



Code Caffeine HeroinIQXIII + +

found heroin with 46.3% w/w , 6-monoacetylmorphine, 6-acetylcodeine, caffeine, levomethorphan and oleamide

IYZYBB + +we have not received standards

J9KZ5A + +Souble in Methanol, The Sample contains 47.5% Heroine, 1.7% Morphine as a base. In the sample was identified caffeine as adulterant .

JBRMJJ + +

JCJPKW + +Brown powder found to contain diamorphine at a concentration of 41 per cent

JGOKP5 + +Related compound: Morphine;Adulterant: Caffeine

JNYC8O + +50.71% +/- 5.58% Heroin detected in sample SM-1.Morphine detected in sample SM-1 but quantitation not performed.

JQIGMD + +THE SAMPLE ALSO CONTAINS CAFEIN AND d,l-methorphan

JTSJJD + +At first Screening Test was performed and confirmed by TLC method in two different solvent system.

JUNUUU + +color test : Marquis = purple violet , Mecke = deep green , Frohde = purple becoming green/purple TLC : TA = heroin or 6-MAM , system diehtylether :acetone: diethylamine (85:8:7) = heroin, acetylcodeine, 6-MAM, caffeine

GC : Heroin base = 46.13%, caffeine 9.81%GC/MS : Heroin, acetylcodeine, 6-MAM ,caffeine

K7QIQW + +Heroin was found and the purity was 53.41%. Other drugs found were Codeine, 6-monoacetylmorphine, Acetylcodeine, Dextromethorphan.

KBTTYE ANP +After analysis, the sample was found to contain heroin.

KFTKVQ + +On analysis, I found the substance to contain morphine and 46.99% Heroin.

KW3BDH + +powder containing 43.1% of heroin and 13.9% of 6-monoacetylmorphine. The sample contains also caffeine, methorphan and acetylcodeine not quantified

L1N1AS + +heroin and Morphine were identified by TLC and GC/MS. Caffeine and lactose were also identified by TLC and GC/MS



Code Caffeine HeroinLACFSF + +

Las pruebas químicas y la coincidencia en los tiempos de retención y fragmentos de masas del material de referencia usado en las mismas condiciones que la muestra analizada, indican la presencia de heroina y cafeina.

LLDWGL + +Sample contains 49.4 ± 2.9 % heroin-base. Sample also contains caffeine, acetylcodeine, 6-monoacetylmorphine, papaverin and dextrometorphan.

LTLGBL + +

LTXFMY + +Marquis reagent, Scott reagent have been applied, the TLC and GC/FID

M5FWNJ + +caffeine, acetylcodeine, 6-monoacetylmorphine, papaverine, dextrometorphan

MDPWHT + +The sample is heroin.

MKND72 + +

MMHHSD + +Beige, fine powder with acrid smell, tested positive for Heroin, a substance listed in Table A of the Law on Addictive Substances.

MRHASS + +The sample contains heroin, 6-monoacetylmorphine, acetylcodeine and caffeine.

N0NNLS + +

N1M8LG + +We also found 6-acethyl-codeine, 6-acethyl-morphine, caffein, papaverine and noscapine and traces of dextrometrorphane, codeine and morphine and also traces of glucose and lactose.

N666MQ + +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM1 contains Heroin and Caffeine.

NA2AKJ ANP +One brown glass bottle containing 222mg of a yellow powder. this yellow powdercontained an average of 58% of diamorphine hydrochloride (also known as heroin).

NO9OBB + +The power contained Heroine chlorhydrate with caféine.

NPDHYI + +Presence of heroin hydrochloride, acetylcodeine, monoacetylmorphine, papaverine, noscapine, methorphan, glucose and caffeine was detected in the sample.

O0LRTK + +white powder containing heroin (52.1%) and monoacetylmorphine (6.6%). It contains also acetylcodeine and caffeine



Code Caffeine HeroinOPBW2C - +

OVCNJF + +Beige powder containing Heroin with a 37.99% as a base.

PCIBIV + +

PDGMFW + +Caffeine, Metorphan, Noscapine, Papaverine, Acetyl Codeine

PPHC9X + +powder contains heroin with caffeine

PQLTDR + +acetil-kodein, 6-MAM, koffein, dextromorphan

PSOAIJ ANP +Positive to heroin , contains morphine, 6- Monoacetylmorphine, Acetylcodein

PUS7H2 + +Cafeina y Dextromethorphan

QJIQTJ +

R8O18R + +Powder contains Heroine wich is a controlled substance

RIJOTJ + +yellow powder containing heroin (42.1%), 6-monoacetylmorphine, acetylcodeine, and caffeine.

RPGPEM + +sample contains also caffeine, O6-monoacetylmorphine and acetylcodeine

RXGBPA + +cafeine, dextromethorphane, morphine, acetylcodeine,6MAM,noscapine

S2O5GO ANP +Pruebas colorimétricas, Marquis, Lieberman, FT-IR, UV-visible y TLC

S6OORI + +acetyl-codein, 6-monoacetyl-morphine, dextromorphan,

SADCGQ + +

SOQRQ9 + +POWDER CONTAINING HEROIN. ADDITIONALLY IDENTIFIED CAFFEINE, ACETYLCODEINE, 6-MONOACETYLMORPHINE, METHORPHAW, STEREOCHEMICAL COMPOSITION NOT DETERMINED.



Code Caffeine HeroinSSOSVY + +

The sample contains heroin which is listed as a controlled drug according to XXX order, appendix I of February 22nd 1990.

SSSCSJ - +

T0QNTU + +In the test sample 2013/1/SM-1 were detected heroin, acetylcodeine, 6-monoacetylmorphine, noscapine, dextromethorphan and caffeine

TBBUSK + +browny powder, other alkaloids - papaverine, morphine, noscapine, and 6-MAM, dextromethorphan, caffeine as diluent ingredient

TDDURM + +The sample correspond: Diacetyl (morphine) mixed with morphine, cafeine and dextrormetofano.

TXQHJG + +

UHMVSZ + +

UT6VEX - +Test sample 2013/1/SM-1 was found to contain the following controlled drugs 6-Monoacetylmorphine and Diacetylmorphine

UTL3JI - +The results of the tests of the SM 1 (20) received confirmed that the mentioned sample contains heroín with 56.3 percentage by weight (56.3%)

VFLGQF + +The sample was founf to contain Heroin, 6-MAM, acetylcodeine, Dextrometorphan and caffeine

VLZ8LL + +The sample SM-1 found to contain 47,5 % heroine, 2,2 % morphine. The seizure also contains caffeine, dextromethorphan, codeine, acetylcodeine, 6-monoacetylmorphine, papaverine, noscapine.

VMSX5E + +caffeine 10.84, acetylcodeine, 06 Monoacetylmorphine, noscapine, papaverine, glucose

W4SM4Y + +One glass bottle containing 0.22 grammes of a mixture containing 0.11 grammes of heroin hydrochloride (being a salt of heroin).

WKJAI3 + +CR, TLC, FTIR, GC, GC/MS

WPYVIW + +Base Heroin 47,2 +/-2,14% (w/w); Acetylcodeine, 6-Monoacetylmorphine, Morphine,Dextrometorphane, Caffeine

XKGJ2G + +The sample was found to contain 46.5% of diamorphine (as base).



Code Caffeine HeroinXPE2VZ + +

In the 0,225 g unknown powder it is found 39% Heroin.

YCSW1Z + +This sample also contains 6-monoacetyl-morphine, acetyl-codeine, dextrometorphan and caffeine.

YETFFI + +This sample contains heroin HCl (44.9 % as base) cut with caffein (10.7%), dextromethorphan (

Identification methods for Test Sample 1

Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

00H0DT I S

0DAKSM I SI

0SRDXD I I I SI I I XRD

0T0BVS SI I

1HR18P I SI

1R7FTA S I

1SWNJJ I SI SI

22JWSL S S I I

2ACHVO SI I

2FELET S S I I

2IOV6B SI I I I

2QK02D SI S I I SI I

2SMWYX SI

3E3XE3 SI

400BTP S S I I

424NFI S S I I I I

4ED4U4 S S I

4FLYLL I SI

4P9OST S I

4ZRH5B SI

5AL4YL S I

5ZSPFZ S I

6CS6GB S I

77H7IH S I I

78CN24 S I

7BREL7 S S S I

7H5WS7 I SI

88O8O8 SI S S I

8KXYZQ SI ASAP-TOF

8LLTJE S I

8QXEZ5 SI I I I I

99WMWJ SI

9EU3UC S I I

9WEC99 I SI SI

Analytical Technique Codes

Legend: S ... used for Screening I ... used for Identification SI ... used for both



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

AJWS6O S S I

AMA50Q S SI I SI

APYADP S S I

B824TN I I SI I

BBEBBB I S I I I

BPBBMB S SI I I

BZBJBP SI I

C2WUON SI

C5ZRZ2 S I I

CIIE5Y S S S I

CLW6JW S S S I I

CQC6CC I SI I

CSDDCC SI

DDXKOD S S S I I

DVAVS7 I SI

EIJIBE S S S I

EK1BZR S S I I

EYBQOO SI S S S I I I

EYEEEV S S I I

F66RUS I SI I I LCMS

FF11HE S I I I I

FNZI88 SI

G9XDGK I I

GUEUUR S S I I

HPPPFP S I I SI I

HRHXY5 S S I I

HSJGXV S I

IBADDP I

IQXIII SI

IYZYBB I I S IMMUNOCHEMICAL

J9KZ5A I I SI

JBRMJJ SI

JCJPKW S S I

JGOKP5 I SI

JNYC8O S S I I

JQIGMD S S I I

JTSJJD S S I S 210(Fast Blue B salt Test)

JUNUUU S I I I

K7QIQW S S S I



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

KBTTYE S I

KFTKVQ S S S I

KW3BDH SI

L1N1AS S S S I I

LACFSF S S I

LLDWGL SI SI

LTLGBL S S S I I

LTXFMY S SI S I

M5FWNJ S SI I

MDPWHT S I I

MKND72 S S SI SI

MMHHSD S S S I I

MRHASS SI

N0NNLS S I I

N1M8LG SI I

N666MQ S S I

NA2AKJ I I

NO9OBB I SI I

NPDHYI S S S S I I I

O0LRTK I I SI

OPBW2C I SI

OVCNJF S S S I I

PCIBIV I S S SI I SI I

PDGMFW I I SI

PPHC9X SI I

PQLTDR S SI I I

PSOAIJ S I I

PUS7H2 S I

QJIQTJ I

R8O18R SI I I

RIJOTJ SI

RPGPEM S I I I

RXGBPA SI I

S2O5GO I S I I SI I I I liberman

S6OORI I SI I

SADCGQ I SI

SOQRQ9 SI

SSOSVY I I

SSSCSJ I SI



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

T0QNTU I

TBBUSK SI I

TDDURM I SI

TXQHJG S I I

UHMVSZ S S I I

UT6VEX SI

UTL3JI S I

VFLGQF I S Immunochromatography

VLZ8LL S S S S I I

VMSX5E SI

W4SM4Y S S I SI I

WKJAI3 SI S SI I I

WPYVIW S S S I I I I XRD

XKGJ2G SI I UPHLC/ELSD

XPE2VZ S I I

YCSW1Z I SI I

YETFFI S S I I

YULAAJ S S I

YYMCDP S I

Z4FNNZ S I I I RAMAN





Section

Response SummaryParticipants: 132

Caffeine: 114

Heroin: 132

Frequency of use of screening and identification techniques:

Summary for test sample 1The response summary of all 126 participating laboratories for the identification of SM-1, frequency of use of screening andidentification techniques and false positives and negatives:

Identification of test sample 1:

False positives for Test Sample 1 (controlled substances)

Code Name TechniqueLTXFMY Mephedrone 141, 150

Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4

31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%

Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7

7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%

# labs using this technique

47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%

Response Summary Participants: 132

Z-Scores for Test Sample 1

CODEHeroinMAD: 1.7

Conc. * AbsDev ZScore

00H0DT 47.2 0.0 0.0

0DAKSM 47.4 0.2 0.1

0SRDXD 47.3 0.1 0.0

1HR18P 49.6 2.4 0.9

1SWNJJ 47.0 0.2 0.1

22JWSL 46.0 1.2 0.5

2FELET 77.9 30.7 12.0

2IOV6B 47.4 0.2 0.1

2SMWYX 39.8 7.4 2.9

3E3XE3 44.3 2.9 1.1

4ED4U4 54.0 6.8 2.7

4FLYLL 63.0 15.8 6.2

4P9OST 50.0 2.8 1.1

4ZRH5B 49.3 2.1 0.8

5ZSPFZ 45.6 1.6 0.6

7BREL7 47.6 0.4 0.2

88O8O8 47.2 0.0 0.0

8LLTJE 65.2 18.0 7.0

8QXEZ5 43.0 4.2 1.6

99WMWJ 41.2 6.0 2.3

9EU3UC 47.9 0.7 0.3

9WEC99 46.5 0.7 0.3

AJWS6O 45.0 2.2 0.9

BBEBBB 45.5 1.7 0.7

BPBBMB 36.0 11.2 4.4

BZBJBP 52.5 5.3 2.1

C2WUON 50.1 2.9 1.1

C5ZRZ2 49.9 2.7 1.1

CQC6CC 48.2 0.9 0.4

CSDDCC 47.0 0.2 0.1

DVAVS7 46.0 1.2 0.5

EIJIBE 45.4 1.8 0.7

EYBQOO 46.0 1.2 0.5

FF11HE 22.0 25.2 9.8

FNZI88 48.9 1.7 0.7

G9XDGK 44.1 3.1 1.2

GUEUUR 46.0 1.2 0.5

HPPPFP 46.0 1.2 0.5

HRHXY5 47.2 0.0 0.0

HSJGXV 47.7 0.4 0.2

IBADDP 49.0 1.8 0.7



CODEHeroinMAD: 1.7


IQXIII 46.3 0.9 0.4

IYZYBB 61.3 14.1 5.5

J9KZ5A 47.5 0.3 0.1

JBRMJJ 56.3 9.1 3.6

JCJPKW 41.0 6.2 2.4

JGOKP5 45.7 1.5 0.6

JNYC8O 50.7 3.5 1.4

JQIGMD 46.7 0.5 0.2

JUNUUU 46.1 1.1 0.4

K7QIQW 53.4 6.2 2.4

KBTTYE 48.2 1.0 0.4

KFTKVQ 47.0 0.2 0.1

KW3BDH 43.1 4.1 1.6

L1N1AS 48.1 0.9 0.4

LLDWGL 49.4 2.2 0.9

MDPWHT 48.2 1.0 0.4

MKND72 52.5 5.3 2.1

MMHHSD 45.2 2.0 0.8

MRHASS 33.3 13.9 5.4

N1M8LG 64.9 17.7 6.9

NA2AKJ 51.0 3.8 1.5

NO9OBB 46.7 0.5 0.2

NPDHYI 45.0 2.2 0.9

O0LRTK 52.1 4.9 1.9

OPBW2C 45.2 2.0 0.8

OVCNJF 38.0 9.2 3.6

PDGMFW 47.8 0.6 0.2

PPHC9X 48.2 1.0 0.4

RIJOTJ 42.1 5.1 2.0

RPGPEM 48.0 0.8 0.3

RXGBPA 52.7 5.5 2.1

SADCGQ 52.6 5.4 2.1

SOQRQ9 47.4 0.2 0.1

SSOSVY 45.5 1.7 0.7

SSSCSJ 59.0 11.8 4.6

T0QNTU 48.0 0.8 0.3

TBBUSK 49.0 1.8 0.7

UHMVSZ 33.5 13.7 5.3

UTL3JI 56.3 9.1 3.6

VLZ8LL 47.5 0.3 0.1

VMSX5E 47.1 0.1 0.1

W4SM4Y 46.2 1.0 0.4

CODEHeroinMAD: 1.7


WKJAI3 46.0 1.2 0.5

WPYVIW 47.2 0.0 0.0

XKGJ2G 46.5 0.7 0.3

XPE2VZ 39.0 8.2 3.2

YETFFI 44.9 2.3 0.9

YULAAJ 47.6 0.4 0.2

YYMCDP 40.6 6.6 2.6

*) Concentration: w/w %

Z-Score has been calculated as modified Z-Score as it is a robust method and therefore relatively insensitive to outliers.Modified Z-Score = 0.6745 * AbsDev/MADAbsDev = Absolute value of the difference between a laboratory value and the median of all the laboratory values for the given drug;MAD = median absolute deviation about the median.Modified Z-scores with an absolute value of greater than 3.5 should be considered as potential outliers.Reference:Iglewicz, B. and Hoaglin, D. C.: 1993 How to Detect and Handle Outliers, American Society for Quality Control, Milwaukee, WI

2013/1-SM Copyright (c) 2013 UNODC


(25)

Substance: SM-1/Heroin 1.7MAD =Lab Median = 47.2

Round: 2013/1


Z-Score Report per Sample per Substance

UNODC value = 47.9

(26)


Code Identified Substances00H0DT morphine

0DAKSM Morphine

0SRDXD morphine, codeine

0T0BVS MORFINA

1HR18P Morphine, Codeine

1R7FTA Morphine and Codeine

1SWNJJ morphine

22JWSL Morphine

2ACHVO opiates

2FELET Morphine

2IOV6B morphine

2QK02D Morfina

2SMWYX Morphine,codeine.

3E3XE3 Morphine, Codeine

400BTP Morphine

424NFI Morphine

4ED4U4 Morphine & Codeine

4FLYLL MORPHINE

4P9OST Morphine

4ZRH5B morphine

5AL4YL Morphine

5ZSPFZ morphine, codeine

6CS6GB Morfina

77H7IH Morphine

78CN24 Morphine

7BREL7 Morphine

7H5WS7 morphine

88O8O8 morphine

8KXYZQ Morphine

8LLTJE codeine, morphine

8QXEZ5 morphine

99WMWJ Codeine and Morphine

9EU3UC Morphine

9WEC99 MORPHINE; CODEIN

AJWS6O Codeine and morphine

AMA50Q Morphine, as well as codeine

APYADP we found morphine

B824TN Morphine

BBEBBB Morphine HCL

BZBJBP codeine and morphine

Sample 2 Analysis



Code Identified SubstancesC2WUON Morphine

C5ZRZ2 MORPHINE

CIIE5Y YES, MORPHINE Y CODEINE.

CLW6JW Morphine

CQC6CC MORPHINE

CSDDCC MORPHIN CHLORHYDRATE, CODEIN

DDXKOD MORPHINE

DVAVS7 morphine

EIJIBE MORPHINE

EK1BZR Morphine and codeine

EYBQOO Morphine

EYEEEV morphine, codeine

F66RUS Morphine

FF11HE morfphine

G9XDGK Morphine, codeine

GUEUUR Codeine and morphine

HPPPFP Morphine and codeine

HRHXY5 Morphine

HSJGXV Morfine

IBADDP Codeine, Morphine

IQXIII morphine

IYZYBB opiates (morphine)

J9KZ5A Morphine, codeine

JBRMJJ Heronin and morphine

JCJPKW Codeine and morphine

JGOKP5 Morphine

JNYC8O Morphine, Codeine

JQIGMD MORPHINE AND CODEINE

JTSJJD Morphine, Codeine

JUNUUU Morphine, codeine phosphate

K7QIQW Morphine

KBTTYE Morphine

KFTKVQ morphine

L1N1AS Morphine

LACFSF Morfina

LLDWGL morphine

LTLGBL Morphine

LTXFMY Morphine, m-CPP HCl

M5FWNJ codeine, morfin

MDPWHT morphine, codeine

MKND72 Morphine, Codeine

MMHHSD Morphine and Codeine

MRHASS Morphine

N0NNLS morphine, codeine



Code Identified SubstancesN1M8LG Morphine

N666MQ Morphine and Codeine.

NA2AKJ Morphine hydrochloride and codeine

NO9OBB Morphine, codeine

NPDHYI morphine

O0LRTK morphine

OPBW2C Morphine

OVCNJF Morphine

PDGMFW Morphine, Codeine

PPHC9X morphine, codeine

PQLTDR morfin, kodein

PSOAIJ Morphine

PUS7H2 Codeina y Morfina

R8O18R Morphine

RIJOTJ morphine

RPGPEM morphine hydrochloride

RXGBPA morphine

S2O5GO Morfina

S6OORI morphine, codein

SADCGQ Morphine

SOQRQ9 MORPHINE AND CODEINE

SSOSVY Morphine

SSSCSJ morphine

T0QNTU Morphine

TBBUSK morphine

TDDURM MORPHINE and CODEINE

TXQHJG morphine and codeine

UHMVSZ MORFINA Y CODEINA

UT6VEX Morphine

UTL3JI morphine

VFLGQF codeine

VLZ8LL morphine

VMSX5E MORPHINE HCL

W4SM4Y Morphine

WKJAI3 morphine, codeine

WPYVIW Morphine hidrochlorhide

XKGJ2G Morphine and Codeine

XPE2VZ Morphine & Codeine

YCSW1Z morphine, codeine

YETFFI Morphine hydrochloride

YULAAJ codeine, morphine

YYMCDP morphine

Z4FNNZ Morphine and Codeine



Code Morphine00H0DT +

Morphine is controlled by law (KB 31/12/1930 changed by KB 8/10/1963).

0DAKSM +The sample contains the controlled drug morphine 70.67 %, m/m and codeine 12.94 %, m/m.

0SRDXD +the powder is a mixture of morphine and codeine. The concentration of morphine in the sample is 90.3% by weight, codeine is 9% by weight.

0T0BVS +La sustancia analizada se trata de morfina

1HR18P +

1R7FTA +Based on the above analysis, the sample was found to contain Morphine and Codeine

1SWNJJ +

22JWSL +The sample SM-2 contains a mixture of morphine and codeine.

2ACHVO +codeinemorphine

2FELET +SM-1 was found to be contain Morphine. Codeine also was detected in this sample.

2IOV6B +codéine, 6 monoacetylmorphine

2QK02D +Ademas Codeína.

2SMWYX +SM2 was prepared from a seizure containing 60.6% w/w morphine base. The seizure also contained codeine.

3E3XE3 +

400BTP +In the powder sample analyzed was detected the presence of morphine and codeine.

424NFI +Sample 2013/1/SM-2 consists of white powder. Morphine, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample. The seizure also contains codeine.




Code Morphine4ED4U4 +

0.225 grams of a powder containing Morphine. Morphine is a Class A controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

4FLYLL +

4P9OST +Sample 2013/1/SM-2 was found to contain controlled substance MORPHINE, a Schedule I drug under the SingleConvention on Narcotic Drugs.

4ZRH5B +morphine and codeine

5AL4YL +

5ZSPFZ +

6CS6GB +Monomorfinan-6-ol

77H7IH +We found Morphine in SM-2 as controlled drug

78CN24 +L'analyse de l'échantilon 2013/1/SM-2 révèle la présence de la morphine

7BREL7 +On analysis, i found the substances to contain 63.14% of morphine.

7H5WS7 +The seizure contained morphine

88O8O8 +

8KXYZQ +sample contain Morphine.

8LLTJE +morphine was as hydrochloride form

8QXEZ5 +morphine, codeine

99WMWJ +The sample contains 8.3 % Morphine.

9EU3UC +



Code Morphine9WEC99 +

/

AJWS6O +One glass bottle labelled '2013/1/SM-2' containing 0.221g of off-white powder. This powder contained codeine and morphine.Please see part 5 (4) for further comments.

AMA50Q +White powder containing morphine and codeine.

APYADP +the sample also contains codeine and acetylcodeine as metabolite

B824TN +Morphine

BBEBBB +SM 2 contain also Codeine

BPBBMB -Analysis of the Powder did not reveal the presence of any controlled drugs

BZBJBP +codeine and morphine

C2WUON +-

C5ZRZ2 +CODEINE

CIIE5Y +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-2 WAS FOUND MORPHINE Y CODEINE.

CLW6JW +With codeine also

CQC6CC +MORPHINE AND CODEINE WERE IDENTIFIED

CSDDCC +

DDXKOD +The sample 2013/1/SM-2 was found to contain Morphine.

DVAVS7 +The sample contains morphine which is scheduled as illicit drug in France.

EIJIBE +MORPHINE CHLORYDRATE (67.4% as base) - CODEINE CHLORYDRATE (11.6 as base)



Code MorphineEK1BZR +

The powder was analysed and found to contain morphine and codeine.

EYBQOO +SM-2 contains morphine, 59%

EYEEEV +*Results of screening tests were positive for opiates. *Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained with morphine and codeine.

F66RUS +Sample contain drug- Morphine

FF11HE +mixture of morphine and codeine

FNZI88 +

G9XDGK +The sample SM2 contained morphine and codeine. Quantification of morphine we do not performed.

GUEUUR +One glass vial with lid attached containing 217mg of off-white powder containing codeine and morphine.

HPPPFP +Morphine and codeine are not quantified routinely in our laboratory

HRHXY5 +The sample contains morphine and codeine.

HSJGXV +Morfine (not quantified) and codeine

IBADDP +On analysis, the powder was found to contain morphine.

IQXIII +found morphine with 59.0% w/w, 6-acetylcodeine, and oleamide (calibration curve performed with UNODC standard)

IYZYBB +we have not received standards

J9KZ5A +Souble in Methanol, The Sample contains 64.9% Morphine, 11.8% Codeine as a base.

JBRMJJ +



Code MorphineJCJPKW +

Off-white powder found to contain codeine and morphine. I am satisfied that morphine is present at a concentration greater than 0.2%.

JGOKP5 +Also found Codeine

JNYC8O +Morphine and Codeine detected in sample SM-2 but quantitation not performed.

JQIGMD +MORPHINE 79.6%CODEINE 13.3%

JTSJJD +At first Screening Test was performed and confirmed by TLC method in two different solvent system.

JUNUUU +color test : Marquis = purple violet , Mecke = deep green , Frohde = purple becoming green/purple TLC : TA = Morphine or codeine, system diehtylether :acetone: diethylamine (85:8:7) = Morphine and codeine

GC : Morphine base = 78.66%, codeine base 13.33%GC/MS : Heroin, acetylcodeine, 6-MAM ,caffeine

K7QIQW +Morphine was found and the purity was 72.03%. Other drug found was codeine.

KBTTYE +After analysis, the sample was found to contain morphine.

KFTKVQ +The sample was found to contain morphine.

KW3BDH -

L1N1AS +Morphine was identified by TLC and GC/MS

LACFSF +Las pruebas químicas y la coincidencia en los tiempos de retención y fragmentos de masas del material de referencia usado en las mismas condiciones que la muestra analizada, indican la presencia de morfina.

LLDWGL +Sample contains 72,8 ± 3.2 % morphine-base. Sample also contains codeine.

LTLGBL +

LTXFMY +Marquis reagent and Scott reagent have been applied, the TLC and GC/FID



Code MorphineM5FWNJ +

MDPWHT +The sample is a mixture of morphine and codeine.

MKND72 +

MMHHSD +White, odourless powder, tested positive for Morphine and Codeine, substances listed in Table B and C respectively of the Law on Addictive Substances.

MRHASS +The sample contains morphine and codeine.

N0NNLS +

N1M8LG +We also found codeine and traces of heroin.

N666MQ +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM2 contains Morphine and Codeine.

NA2AKJ +One brown glass bottle containing 224mg of an off-white powder. This off-white powder contained morphine hydrochloride and codeine.

NO9OBB +The power contained morphine and codéine.

NPDHYI +Presence of morphine and codeine was detected in the sample.

O0LRTK +white powder containing morphine (69.4%). In addition is present codeine

OPBW2C +

OVCNJF +The analyze sample was identify as Morphine, however the quantification was not possible due to the degradation of the standard sample.

PCIBIV +

PDGMFW +

PPHC9X +powder contains morphine and codeine



Code MorphinePQLTDR +

PSOAIJ +Positive to morphine, contains codeine sulfate.

PUS7H2 +

QJIQTJ ANP

R8O18R +Powder contains morphine wich is a controlled substance

RIJOTJ +white powder containing morphine (58.9%) and codeine

RPGPEM +

RXGBPA +codeine

S2O5GO +Pruebas colorimétricas, Marquis, Lieberman, FT-IR, UV-visible , TLC y microcristales

S6OORI +

SADCGQ +

SOQRQ9 +POWDER CONTAINING MORPHINE AND CODEINE

SSOSVY +The sample contains morphine which is listed as controlled drug according to french order, appendix I of February 22nd 1990.

SSSCSJ +

T0QNTU +In the test sample 2013/1/SM-2 were detected codeine and morphine

TBBUSK +white powder, mixture of the morphine and codeine

TDDURM +The sample correspond: MORPHINE mixed with CODEINE



Code MorphineTXQHJG +

UHMVSZ +

UT6VEX +Test sample 2013/1/SM-2 was found to contain the following controlled drug Morphine

UTL3JI +The results of the tests of the SM 2 (29) received confirmed that the mentioned sample contains morphine but we are not able to give a cuantification result because we have not got the pattern of the mentioned controlled drug. The SM 2 also contains codein as not controlled drug

VFLGQF -the sample was found to contain codeine

VLZ8LL +The sample SM-2 found to contain 73,0 % morphine. The seizure also contains codeine.

VMSX5E +codéine

W4SM4Y +One glass bottle containing 0.22 grammes of a powder containing 0.15 grammes of morphine.

WKJAI3 +CR, TLC, FTIR, GC, GC/MS

WPYVIW +Morphine hidrochloride, Codeine

XKGJ2G +The sample was found to contain 68.4% of morphine (as base) and 12.5% of codeine (as base).

XPE2VZ +In the 0,230 g unknown powder it is found 50% Morphine and 10% Codeine.

YCSW1Z +

YETFFI +This sample contains morphine HCl (67.3% as base) and codein (13.8% as base)

YULAAJ +

YYMCDP +marquis reagent is positive (violet) ant Scott reagent is positive too. In the chromatogram the retention time is like morphine. So, the substance is morphine.

Z4FNNZ +Test Sample 2013/1/SM-2 contains Morphine and Codeine




Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

00H0DT I S

0DAKSM I SI


0T0BVS SI I

1HR18P I SI

1R7FTA S I

1SWNJJ I SI SI

22JWSL S S I I

2ACHVO SI I

2FELET S S I I

2IOV6B SI I I I


2SMWYX SI

3E3XE3 SI

400BTP S S I I

424NFI S S I I I I

4ED4U4 S S I

4FLYLL I SI

4P9OST S I

4ZRH5B SI

5AL4YL S I

5ZSPFZ S I

6CS6GB S I

77H7IH S I I

78CN24 S I

7BREL7 S S S I

7H5WS7 I SI

88O8O8 SI S S I

8KXYZQ SI ASAP-TOF

8LLTJE S I

8QXEZ5 SI I I I I

99WMWJ SI

9EU3UC S I I

9WEC99 I SI SI





Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

AJWS6O S S I

AMA50Q S SI I SI

APYADP S S I

B824TN I I SI I

BBEBBB I S I I I

BPBBMB S SI I I

BZBJBP SI I

C2WUON SI

C5ZRZ2 S I I

CIIE5Y S S S I

CLW6JW S S S I I

CQC6CC I SI I

CSDDCC SI

DDXKOD S S S I I

DVAVS7 I SI

EIJIBE S S S I

EK1BZR S S I I


EYEEEV S S I I


FF11HE S I I I I

FNZI88 SI

G9XDGK I I

GUEUUR S S I I

HPPPFP S I I SI I

HRHXY5 S S I I

HSJGXV S I

IBADDP I

IQXIII SI


J9KZ5A I I SI

JBRMJJ SI

JCJPKW S S I

JGOKP5 I SI

JNYC8O S S I I

JQIGMD S S I I


JUNUUU S I I I

K7QIQW S S S I



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

KBTTYE S I

KFTKVQ S S S I

KW3BDH SI

L1N1AS S S S I I

LACFSF S S I

LLDWGL SI SI

LTLGBL S S S I I

LTXFMY S SI S I

M5FWNJ S SI I

MDPWHT S I I

MKND72 S S SI SI

MMHHSD S S S I I

MRHASS SI

N0NNLS S I I

N1M8LG SI I

N666MQ S S I

NA2AKJ I I

NO9OBB I SI I


O0LRTK I I SI

OPBW2C I SI

OVCNJF S S S I I


PDGMFW I I SI

PPHC9X SI I

PQLTDR S SI I I

PSOAIJ S I I

PUS7H2 S I

QJIQTJ I

R8O18R SI I I

RIJOTJ SI

RPGPEM S I I I

RXGBPA SI I


S6OORI I SI I

SADCGQ I SI

SOQRQ9 SI

SSOSVY I I

SSSCSJ I SI



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

T0QNTU I

TBBUSK SI I

TDDURM I SI

TXQHJG S I I

UHMVSZ S S I I

UT6VEX SI

UTL3JI S I


VLZ8LL S S S S I I

VMSX5E SI

W4SM4Y S S I SI I

WKJAI3 SI S SI I I



XPE2VZ S I I

YCSW1Z I SI I

YETFFI S S I I

YULAAJ S S I

YYMCDP S I







Morphine: 126





Code Name TechniqueLTXFMY 1-(3-Chlorophenyl)piperazine 141, 150

False negatives for SM-2 (techinque(s) used or ANP) . Code - BPBBMB (180), VFLGQF (180), QJIQTJ (ANP),KW3BDH (ANP)

Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4

31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%

Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7

7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%


47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%



CODEMorphineMAD: 5.4


00H0DT 87.1 18.6 2.3

0DAKSM 70.7 2.2 0.3

0SRDXD 90.3 21.8 2.7

1HR18P 77.8 9.3 1.2

1SWNJJ 76.1 7.6 1.0

2FELET 65.8 2.7 0.3

2IOV6B 78.8 10.4 1.3

2SMWYX 60.6 7.9 1.0

3E3XE3 81.0 12.5 1.6

4P9OST 65.0 3.5 0.4

4ZRH5B 77.8 9.3 1.2

7BREL7 63.1 5.3 0.7

8LLTJE 81.5 13.0 1.6

8QXEZ5 35.0 33.5 4.2

99WMWJ 8.3 60.2 7.5

9EU3UC 51.8 16.7 2.1

BBEBBB 58.0 10.5 1.3

BZBJBP 75.5 7.0 0.9

C2WUON 71.6 3.1 0.4

CSDDCC 63.0 5.5 0.7

EIJIBE 67.4 1.1 0.1

EYBQOO 59.0 9.5 1.2

FF11HE 68.9 0.5 0.1

FNZI88 71.4 3.0 0.4

IQXIII 59.0 9.5 1.2

IYZYBB 80.3 11.8 1.5

J9KZ5A 64.9 3.6 0.4

JGOKP5 61.2 7.3 0.9

JQIGMD 79.6 11.1 1.4

JUNUUU 78.7 10.2 1.3

K7QIQW 72.0 3.6 0.4

L1N1AS 67.4 1.0 0.1

LLDWGL 72.8 4.3 0.5

MKND72 74.5 6.0 0.8

MRHASS 69.7 1.3 0.2

N1M8LG 76.9 8.4 1.1

NPDHYI 67.3 1.2 0.1

O0LRTK 69.4 0.9 0.1

OPBW2C 71.8 3.3 0.4

PDGMFW 67.2 1.3 0.2

RIJOTJ 58.9 9.6 1.2



CODEMorphineMAD: 5.4


RPGPEM 83.8 15.3 1.9

RXGBPA 81.0 12.5 1.6

SADCGQ 73.8 5.3 0.7

SOQRQ9 68.0 0.5 0.1

SSSCSJ 64.0 4.5 0.6

UHMVSZ 87.5 19.0 2.4

VLZ8LL 73.0 4.5 0.6

VMSX5E 81.0 12.5 1.6

W4SM4Y 66.9 1.6 0.2

WKJAI3 79.0 10.5 1.3

XKGJ2G 68.4 0.1 0.0

XPE2VZ 50.0 18.5 2.3

YETFFI 67.3 1.2 0.1

*) Concentration: w/w %

Substance: SM-2/Morphine 5.4MAD =Median = 68.5

Round: 2013/1



UNODC value = 68.8

(44)


Code Identified Substances00H0DT nimetazepam

0DAKSM Nimetazepam

0SRDXD nimetazepam

0T0BVS NIMETAZEPAM

1HR18P Nimetazepam

1R7FTA Nimetazepam

1SWNJJ nimetazepam, lactose

22JWSL Nimetazepam

2ACHVO benzodiazepines

2FELET Nimetazepam

2IOV6B nimétazepam

2QK02D Nimetazepam

2SMWYX Nimetazepam

3E3XE3 Nimetazepam

400BTP Nimetazepam

4ED4U4 Nimetazepam

4P9OST NIMETAZEPAM

4ZRH5B nimetozepam

5AL4YL Nimetazepam

5ZSPFZ nimetazepam

6CS6GB Nimetazepam

77H7IH Nimetazepam

78CN24 Lidocaïne

7BREL7 Nimetazepam

8KXYZQ Nimetazepam

8QXEZ5 nimetazepam

99WMWJ Nimetazepam

9EU3UC Nimetazepam

9WEC99 NIMETAZEPAM

AJWS6O Nimetazepam

AMA50Q Nimetazepam

APYADP we found nimetazepam

B824TN Nimetazepam

BBEBBB Nimetazepam

BPBBMB Nimetazepam

BZBJBP Nimetazepam

C2WUON Nimetazepam

C5ZRZ2 NIMETAZEPAM

CIIE5Y YES, NIMETAZEPAM

CLW6JW Nimetazepam

Sample 3 Analysis



Code Identified SubstancesCQC6CC NIMETAZEPAM

DDXKOD Nimetazepam

DVAVS7 nimetazepam, lactose

EIJIBE MIMETAZEPAM

EK1BZR Nimetazepam

EYBQOO Nimetazepam

EYEEEV Nimetazepam, lactose

F66RUS Nimetazepm

G9XDGK Nimetazepam

GUEUUR Nimetazepam

HPPPFP Nimetazepam

HRHXY5 Nimetazepam

HSJGXV Nimetazepam

IBADDP Nimetazepam

IQXIII nimetazepam

IYZYBB benzodiazepines (nimetazepam)

J9KZ5A Nimetazepam

JBRMJJ controlled substance

JCJPKW Nimetazepam

JGOKP5 Nimetazepam

JNYC8O Nimetazepam

JQIGMD NIMETAZEPAM

JTSJJD Nimetazepam

JUNUUU Nimetazepam

K7QIQW Nimetazepam

KBTTYE Nimetazepam

KFTKVQ Nimetazepam

KW3BDH nimetazepam

L1N1AS Nimetazepam

LACFSF Nimetazepam

LLDWGL Nimetazepam

LTLGBL Nimetazepam

LTXFMY Nimetazepam

M5FWNJ nimetazepam

MDPWHT nimetazepam

MKND72 Nimetazepam

MMHHSD Nimetazepame

MRHASS Nimetazepam

N0NNLS nimetazepam

N1M8LG Nimetazepam

N666MQ Nimetazepam.

NA2AKJ Nimetazepam

NO9OBB NIMETAZEPAM

NPDHYI nimetazepam



Code Identified SubstancesO0LRTK nimetazepam

OPBW2C Nimetazepam and Lactose

OVCNJF Nimetazepam

PDGMFW Nimetazepam

PPHC9X nimetazepam

PSOAIJ Nimetazepam

PUS7H2 Nimetazepam

R8O18R Nimetazepam

RIJOTJ nimetazepam

RPGPEM nimetazepam

RXGBPA nimetazepam

SADCGQ Nimetazepam

SOQRQ9 NIMETAZEPAM

SSOSVY Nimetazepam

SSSCSJ nimetazepam

TDDURM Nimetazepam

TXQHJG nimetazepam

UTL3JI NONE

VFLGQF methamphetamine

VLZ8LL nimetazepam

VMSX5E NIMETAZEPAM

W4SM4Y Nimetazepam

WKJAI3 nimetazepam

WPYVIW Nimetazepam

XKGJ2G Nimetazepam

XPE2VZ Nimetazepam

YCSW1Z nimetazepam

YETFFI Nimetazepam

YULAAJ nimetazepam

Z4FNNZ Nimetazepam



Code Lactose Nimetazepam00H0DT ANP +

Nimetazepam is controlled by law (KB 22/01/1998).

0DAKSM + +The sample contains the controlled drug nimetazepam 3.75 %, m/m and lactose.

0SRDXD + +The powder is a mixture of nimetazepam and lactose. The concentration of nimetazepam in the sample is 10% by weight.

0T0BVS ANP +La sustancia analizada se trata de una benzodiacepina, probablemente nimetazepam

1HR18P ANP +

1R7FTA ANP +Based on the above analysis, the sample was found to contain Nimetazepam

1SWNJJ + +

22JWSL + +The sample SM-3 contains a mixture of lactose and nimetazepam

2ACHVO ANP +nimetazepam

2FELET - +SM-1 was found to be contain Nimetazepam.

2IOV6B + +lactose

2QK02D + +Se detecto lactosa.

2SMWYX - +SM3 was prepared from a seizure containing 3.78% w/w nimetazepam.

3E3XE3 ANP +

400BTP + +In the powder sample analyzed was detected the presence of Nimetazepam and Lactose.

424NFI + ANPSample 2013/1/SM-3 consists of light pink powder. No prohibited sudstances are detected in this sample.




Code Lactose Nimetazepam4ED4U4 ANP +

0.220 grams of a powder containing Nimetazepam. Nimetazepam is a Class C controlled drug subject to the provisions of the Misuse of Drugs Act 1971.

4FLYLL + -

4P9OST ANP +Sample 2013/1/SM-3 was found to contain controlled substance NIMETAZEPAM, a Schedule IV drug under the international Convention on Psychotropic Substances.

4ZRH5B - +nimetozepam

5AL4YL ANP +lactose and Nimetazepam

5ZSPFZ ANP +

6CS6GB ANP +Fenil Alanina

77H7IH ANP +We found Nimetazepam in SM-3 as controlled drug

78CN24 - -Après analyse, l'échantillon 2013/1/SM-3 contient la Lidocaïne

7BREL7 + +On analysis, i found the substances to contain 3.58% of nimetazepam.

7H5WS7 ANP ANP

88O8O8 ANP ANP

8KXYZQ ANP +Sample contain Nimetazepam.

8LLTJE ANP +

8QXEZ5 - +nimetazepam

99WMWJ ANP +the sample contains Nimetazepam

9EU3UC + +



Code Lactose Nimetazepam9WEC99 + +

/

AJWS6O ANP +One glass bottle labelled '2013/1/SM-3' containing 0.231g of pink powder. This powder contained Nimetazepam. Nimetazepam is a class C controlled drug under the misuse of Drugs Act (1971)(as ammended).

AMA50Q ANP +Pink powder containing nimetazepam.

APYADP ANP +the sample was confirmed by gc ms

B824TN + +Nimetazepam and lactose

BBEBBB + +SM 3 contain also Lactose

BPBBMB ANP +Analysis of the powder revealed the presence of Nimetazepam

BZBJBP + +Nimetazepam, lactose

C2WUON ANP +-

C5ZRZ2 + +LACTOSE, GLUCOSE

CIIE5Y - +IN THE SAMPLE RECEIVED IN BOTTLE AMBER LID GREEN LETTERING 2013/1/SM-3 WAS FOUND NIMETAZEPAM.

CLW6JW + +Diluted with lactose

CQC6CC + +NIMETAZEPAM IN LACTOSE POWDER

CSDDCC + +NIMETAZEPAM, LACTOSE, GLUCOSE

DDXKOD ANP +The Sample 2013/1/SM-3 was found to contain Nimetazepam.

DVAVS7 + +The sample contains nimetazepam which is scheduled as psychotrope in France. Lactose is also present as cutting agent.

EIJIBE ANP +NIMETAZEPAM CHLORYDRATE



Code Lactose NimetazepamEK1BZR + +

The powder was analysed and found to contain nimetazepam.

EYBQOO - +SM-3 contains nimetazepam, 7,2%

EYEEEV + +*Retention time and fragmentation pattern obtained with the sample are equivalent to those obtained nimetazepam. *The spectroscopic parameters obtained with the sample are equivalent to those obtained lactose.

F66RUS + +Sample contain drug- Nimetazepam

FF11HE + +mixture of lactose and nimetazepam

FNZI88 - +

G9XDGK + +The sample SM3 contained nimetazepam and lactose.Pharmaceuticals with psychoactive compunds, we do not quantify.

GUEUUR + +One glass vial with lid attached containing 210mg of pink powder cotaining nimetazepam

HPPPFP + +Probably nimetazepam (We don't have the standard product in the laboratory). This product is not found en France.Lactose and probably glucose traces

HRHXY5 ANP +The sample contains nimetazepam.

HSJGXV - +Nimetazepam

IBADDP ANP +On analysis, the powder was found to contain nimetazepam.

IQXIII ANP +sample was found to contain nimetazepam but quantification was not performed

IYZYBB + +we have not received standards

J9KZ5A + +The sample contains 3.8% Nimetazepam and Lactose.

JBRMJJ - +Nimetazepam is a benzodiacepine drugs



Code Lactose NimetazepamJCJPKW ANP +

Pink powder found to contain nimetazepam

JGOKP5 ANP +

JNYC8O + +3.33% +/- 0.30% Nimetazepam detected in sample SM-3.

JQIGMD - +

JTSJJD - +At first Screening Test was performed and confirmed by TLC method in two different solvent system.

JUNUUU ANP +TLC : TA and TE = nimetazepamGC : Nimetazepam 3.59%GC/MS : Nimetazepam

K7QIQW - +Nimetazepam was found and the purity was 2.75%.

KBTTYE ANP +After analysis, the sample was found to contain nimetazepam.

KFTKVQ - +On analysis, I found the substance to contain 3.07 % nimetazepam.

KW3BDH ANP +powder containing nimetazepam

L1N1AS + +Nimetazepam was identified by TLC and GC/MS

LACFSF ANP +El análisis cromatográfico realizado a la muestra produjo coincidencias significativas con la librería de compuestos del software, lo que indica la presencia de Nimetazepam en la muestra analizada.

LLDWGL + +Sample contains nimetazepam and lactose. According to the Hungarian low we not quantify nimetazepam routinely.

LTLGBL + +

LTXFMY ANP +Marquis reagent and Scott reagent have been applied, the TLC and GC/FID

M5FWNJ ANP +



Code Lactose NimetazepamMDPWHT + +

The sample contains nimetazepam.

MKND72 ANP +

MMHHSD ANP +Pink, odourless powder, tested positive for Nimetazepam, a substance listed in Table D of the Law on Addictive Substances.

MRHASS + +The sample contains nimetazepam and lactose.

N0NNLS - +

N1M8LG + +We also found lactose

N666MQ ANP +Applied chemical tests and instrumental chemical analysis, that sample 2013/1/SM3 contains Nimetazepam.

NA2AKJ ANP +One brown glass bottle containing 231mg of a pink powder. this pink powder contained nimetazepam.

NO9OBB + +The power contained Nimetazepam with lactose. Nimetazepam is a psychotropic substance

NPDHYI + +Presence of nimetazepam and lactose was detected in the sample.

O0LRTK + +Pink powder containing nimetazepam. The amount of nimetazepam was not quantified. The sample contains also lactose and glucose (not quantified)

OPBW2C + +

OVCNJF + +Pink powder containing Nimetazepam with a 24.8% of base. Nimetazepam is clasify as a psychotropic by the Ministry of Health of Guatemala, it is not clasify as a seized material.

PCIBIV - +

PDGMFW + +Sugar

PPHC9X + +powder contains nimetazepam

PQLTDR + +nimetazepam, laktóz



Code Lactose NimetazepamPSOAIJ + +

Positive to Nimetazepam and lactose

PUS7H2 ANP +

QJIQTJ ANP ANP

R8O18R ANP +Powder contains Nimetazepam wich is a controlled substance

RIJOTJ ANP +Pink powder containing nimetazepam. The amount of nimetazepam was not determined because there is not the righr standard reference material in the laboratory.

RPGPEM + +sample contains also lactose

RXGBPA + +suggar, fatty acids

S2O5GO + ANPPruebas colorimétricas, Marquis, Scott, Lieberman, Chen Cao,FT-IR.

S6OORI - +nimatazepam

SADCGQ - +

SOQRQ9 ANP +POWDER CONTAINING NOMETAZEPAM

SSOSVY + +The sample contains nimetazepam which is listed as a controlled psychotropic substance according to french order, 1st part of appendix of February 22nd 1990.

SSSCSJ ANP +

T0QNTU - +In the test sample 2013/1/SM-3 was detected nimetazepam

TBBUSK + +white powder, mixture of the nimetazepam and lactose

TDDURM - +The sample correspond: Nimetazepam mixed with lactoce

TXQHJG + +



Code Lactose NimetazepamUHMVSZ - -

UT6VEX ANP -Test sample 2013/1/SM-3 was found to contain No controlled drugs .

UTL3JI - -we have not found any controlled drug in the SM 3 (36)

VFLGQF ANP ANPthe sample was found to contain methamphetamine

VLZ8LL + +The sample SM-3 found to contain 3,6 % nimetazepam. The seizure also contains lactose.

VMSX5E + +lactose, glucose

W4SM4Y + +One glass bottle containing 0.23 grammes of a powder containing 7 milligrammes of nimetazepam.

WKJAI3 + +TLC, FTIR, GC, GC/MS

WPYVIW + +Nimetazepam, Lactose

XKGJ2G + +The sample was found to contain nimetazepam.

XPE2VZ - +In the 0,230 g unknown powder it is found 10% Nimetazepam.

YCSW1Z + +This sample also contains lactose.

YETFFI + +This sample contains Nimetazepam (not quantified) with lactose.

YULAAJ ANP +

YYMCDP ANP ANPmarquis reagent is negative ant Scott reagent is positive. In the chromatogram the retention time does not like the retention time patterns we have. So, we can not know the drug.

Z4FNNZ + +Test Sample 2013/1/SM-3 contains Nimetazepam and Lactose




Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

00H0DT I S

0DAKSM I SI


0T0BVS SI I

1HR18P I SI

1R7FTA S I

1SWNJJ I SI SI

22JWSL S S I I

2ACHVO SI I

2FELET S S I I

2IOV6B SI I I I


2SMWYX SI

3E3XE3 SI

400BTP S S I I

424NFI S S I I I I

4ED4U4 S S I

4FLYLL I SI

4P9OST S I

4ZRH5B SI

5AL4YL S I

5ZSPFZ S I

6CS6GB S I

77H7IH S I I

78CN24 S I

7BREL7 S S S I

7H5WS7 I SI

88O8O8 SI S S I

8KXYZQ SI ASAP-TOF

8LLTJE S I

8QXEZ5 SI I I I I

99WMWJ SI

9EU3UC S I I

9WEC99 I SI SI





Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

AJWS6O S S I

AMA50Q S SI I SI

APYADP S S I

B824TN I I SI I

BBEBBB I S I I I

BPBBMB S SI I I

BZBJBP SI I

C2WUON SI

C5ZRZ2 S I I

CIIE5Y S S S I

CLW6JW S S S I I

CQC6CC I SI I

CSDDCC SI

DDXKOD S S S I I

DVAVS7 I SI

EIJIBE S S S I

EK1BZR S S I I


EYEEEV S S I I


FF11HE S I I I I

FNZI88 SI

G9XDGK I I

GUEUUR S S I I

HPPPFP S I I SI I

HRHXY5 S S I I

HSJGXV S I

IBADDP I

IQXIII SI


J9KZ5A I I SI

JBRMJJ SI

JCJPKW S S I

JGOKP5 I SI

JNYC8O S S I I

JQIGMD S S I I


JUNUUU S I I I

K7QIQW S S S I



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

KBTTYE S I

KFTKVQ S S S I

KW3BDH SI

L1N1AS S S S I I

LACFSF S S I

LLDWGL SI SI

LTLGBL S S S I I

LTXFMY S SI S I

M5FWNJ S SI I

MDPWHT S I I

MKND72 S S SI SI

MMHHSD S S S I I

MRHASS SI

N0NNLS S I I

N1M8LG SI I

N666MQ S S I

NA2AKJ I I

NO9OBB I SI I


O0LRTK I I SI

OPBW2C I SI

OVCNJF S S S I I


PDGMFW I I SI

PPHC9X SI I

PQLTDR S SI I I

PSOAIJ S I I

PUS7H2 S I

QJIQTJ I

R8O18R SI I I

RIJOTJ SI

RPGPEM S I I I

RXGBPA SI I


S6OORI I SI I

SADCGQ I SI

SOQRQ9 SI

SSOSVY I I

SSSCSJ I SI



Code 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

T0QNTU I

TBBUSK SI I

TDDURM I SI

TXQHJG S I I

UHMVSZ S S I I

UT6VEX SI

UTL3JI S I


VLZ8LL S S S S I I

VMSX5E SI

W4SM4Y S S I SI I

WKJAI3 SI S SI I I



XPE2VZ S I I

YCSW1Z I SI I

YETFFI S S I I

YULAAJ S S I

YYMCDP S I







Lactose: 60

Nimetazepam: 120






False negatives for SM-3 (techinque(s) used or ANP) . Code - 4FLYLL (180), 78CN24 (150), UHNVSZ (171/180 ), UT6VEX ( 180)UTL3JI (180), 424NFI (ANP), 7H5W57 (ANP), 88O8O8 (ANP),QJIQTJ (ANP), S2O5GO (ANP), YYMCDP (ANP), VFLGQF (ANP)

Code Name Technique 1

Section 140 141 142 150 160 161 170 171 180 190 200 220 230 231 210

Screening 42 50 35 18 0 2 0 2 45 7 0 0 0 1 4

31.8% 37.9% 26.5% 13.6% 0.0% 1.5% 0.0% 1.5% 34.1% 5.3% 0.0% 0.0% 0.0% 0.8% 3.0%

Identification 10 5 2 32 9 15 1 21 118 45 2 2 2 3 7

7.6% 3.8% 1.5% 24.2% 6.8% 11.4% 0.8% 15.9% 89.4% 34.1% 1.5% 1.5% 1.5% 2.3% 5.3%


47 52 37 41 9 16 1 22 118 46 2 2 2 3 1035.6% 39.4% 28.0% 31.1% 6.8% 12.1% 0.8% 16.7% 89.4% 34.8% 1.5% 1.5% 1.5% 2.3% 7.6%



CODENimetazepamMAD: 0.3


0DAKSM 3.8 0.0 0.1

0SRDXD 10.0 6.3 15.2

1HR18P 4.1 0.4 1.0

1SWNJJ 3.6 0.1 0.2

2FELET 0.1 3.7 8.8

2SMWYX 3.8 0.1 0.2

4ZRH5B 3.5 0.2 0.5

7BREL7 3.6 0.1 0.3

8LLTJE 2.8 0.9 2.2

8QXEZ5 7.0 3.3 8.0

9EU3UC 8.2 4.5 10.8

BBEBBB 3.5 0.2 0.5

BZBJBP 3.1 0.6 1.4

C2WUON 3.8 0.1 0.3

EYBQOO 7.2 3.5 8.4

FNZI88 3.0 0.7 1.6

IYZYBB 13.6 9.9 23.9

J9KZ5A 3.8 0.1 0.2

JGOKP5 3.8 0.1 0.2

JNYC8O 3.3 0.4 0.9

JUNUUU 3.6 0.1 0.3

K7QIQW 2.7 1.0 2.3

KBTTYE 3.5 0.2 0.5

KFTKVQ 3.1 0.6 1.5

L1N1AS 3.2 0.5 1.1

MKND72 2.9 0.8 1.9

MRHASS 3.8 0.1 0.2

N1M8LG 2.9 0.9 2.0

NPDHYI 3.8 0.1 0.2

OPBW2C 3.2 0.5 1.3

OVCNJF 24.8 21.1 50.9

PDGMFW 2.7 1.0 2.4

RPGPEM 3.7 0.0 0.0

RXGBPA 15.5 11.8 28.4

SADCGQ 3.7 0.1 0.1

SOQRQ9 3.8 0.1 0.2

SSSCSJ 4.0 0.3 0.7

VLZ8LL 3.6 0.1 0.2

W4SM4Y 3.4 0.3 0.7

WKJAI3 3.8 0.1 0.2

XPE2VZ 10.0 6.3 15.2



Substance: SM-3/Nimetazepam 0.3MAD =Median = 3.7

Round: 2013/1



UNODC value = 3.7

(62)


Code Identified Substances00H0DT amphetamine

0DAKSM Amfetamine

0SRDXD amphetamine

0T0BVS ANFETAMINA

1HR18P Amphetamine

1SWNJJ amfetamine

22JWSL Amfetamine

2ACHVO amphetamines

2FELET Amfetamine

2IOV6B metamphétamine

2QK02D Anfetamina

2SMWYX Amfetamine

3E3XE3 Amphetamine

400BTP Amphetamine

424NFI Amfetamine

4ED4U4 Amfetamine

4FLYLL AMFETAMINE

4P9OST Amphetamine

4ZRH5B amfetamine

5AL4YL amfetamine sulphate

5ZSPFZ anfetamine

6CS6GB Anfetamina

77H7IH Amphetamine

78CN24 Amphétamine

7BREL7 Amphetamine

88O8O8 amfetamine

8KXYZQ Amphetamine

8LLTJE amphetamine

8QXEZ5 amfetamine

99WMWJ Amfetamine

9EU3UC Amphetamine

9WEC99 AMFETAMINE

AJWS6O Amphetamine

AMA50Q Amphetamine

APYADP we found amphetamine

B824TN Amfetamine

BBEBBB Amphetamine Sulphate

BPBBMB Amphetamine

BZBJBP Amphetamine

C2WUON Amfetamine

Sample 4 Analysis



Code Identified SubstancesC5ZRZ2 AMPHETAMINE

CIIE5Y NO

CLW6JW Amphetamine

CQC6CC AMPHETAMINE

CSDDCC AMFETAMIN SULFATE

DDXKOD Amphetamine

DVAVS7 amphetamine

EIJIBE AMPHETAMINE

EK1BZR Amphetamine

EYBQOO Amfetamine, metamfetamine

EYEEEV amfetamine

F66RUS Amphetamine

FF11HE amphetamine

G9XDGK Amfetamine

GUEUUR Amphetamine

HPPPFP amphetamine

HRHXY5 Amfetamine

HSJGXV Amphetamine

IBADDP Amphetamine

IQXIII amphetamine

IYZYBB amphetamines (amphetamine)

J9KZ5A Amphetamine

JBRMJJ Amphetamine

JCJPKW Amphetamine

JGOKP5 Amphetamine

JQIGMD AMFETAMINE

JTSJJD Amfetamine

JUNUUU Amphetamine

KBTTYE Amphetamine

KFTKVQ Amphetamine

L1N1AS Amphetamine

LACFSF Anfetamina

LLDWGL Amfetamine

LTLGBL Amfetamine

LTXFMY Amphetamine

M5FWNJ amfetamine

MDPWHT amfetamine, metamfetamine

MKND72 Amfetamine

MMHHSD Amphetamine

MRHASS Amfetamine

N0NNLS amfetamine

N1M8LG Amphetamine

N666MQ Amfetamine.

NA2AKJ amphetamine sulphate



Code Identified SubstancesNO9OBB Amphetamine

NPDHYI amfetamine

O0LRTK amfetamine

OPBW2C Amphetamine and sucrose

OVCNJF Amfetamine

PCIBIV Isosorbide

PDGMFW Amphetamine

PPHC9X amfetamine

PQLTDR amfetamin

PSOAIJ Anfetamine

PUS7H2 Anfetamina

QJIQTJ amfetamine

R8O18R Amphetamine

RIJOTJ amphetamine

RPGPEM amphetamine sulphate

RXGBPA amfetamine

S2O5GO anfetamina

S6OORI amphetamine

SADCGQ Amfetamine

SOQRQ9 AMPHETAMINE

SSOSVY Amphetamine

SSSCSJ amfetamine

T0QNTU Amfetamine

TBBUSK amphetamine

TXQHJG amphetamine

UHMVSZ ANFETAMINA

UT6VEX Amfetamine

UTL3JI anphetamine

VFLGQF amphetamine

VLZ8LL amphetamine

VMSX5E AMFETAMINE SO4

W4SM4Y Amphetamine

WKJAI3 amphetamine

WPYVIW Amphetamine sulphate

XKGJ2G Amphetamine and Methamphetamine

XPE2VZ Amphetamine

YCSW1Z amfetamine

YETFFI Amfetamine sulphate

YULAAJ afetamine

YYMCDP amfetamine

Z4FNNZ Amphetamine



Code Amfetamine00H0DT +

Amphetamine is controlled by law (KB 22/01/1998).

0DAKSM +The sample contains the controlled drug amfetamine 9.55 %, m/m.

0SRDXD +The powder is a mixture of sucrose and amphetamine. The concentration of amphetamine in the sample is 4.9% by weight.

0T0BVS +La sustancia analizada se trata de anfetamina

1HR18P +

1R7FTA -Based on the above analysis, dangerous drugs were not detected in the sample

1SWNJJ +

22JWSL +The sample SM-4 contains amfetamine.

2ACHVO +amphetaminealso trace of methamphetamine

2FELET +SM-1 was found to be contain Amfetamine

2IOV6B -sucrose

2QK02D +se identificó como D-Anfetamina

2SMWYX +SM4 was prepared from a seizure containing 8.34% w/w amfetamine base.

3E3XE3 +

400BTP +In the sample analyzed was detected the presence of amphetamine, piperidine 2-(phenyl methyl) and sucrose.

424NFI +Sample 2013/1/SM-4 consists of white powder. Amfetamine, a prohibited sudstance included in the National Law for Narcotics, is found to be present in this sample.




Code Amfetamine4ED4U4 +

0.229 grams of a powder containing 10% Amfetamine. Amfetamine is a Class B drug subject to the provisions of the Misuse of Drugs Act 1971.

4FLYLL +

4P9OST +Sample 2013/1/SM-4 was found to contain controlled substance AMPHETAMINE, a Schedule II drug under the Convention on Psychotropic Substances.

4ZRH5B +amfetamine

5AL4YL +

5ZSPFZ +we found in that sample many different sugars.

6CS6GB +Hexosa, 1,6 Anhidro-alfa-D-Galactosa

77H7IH +We found Amphetamine in SM-4 as controlled drug

78CN24 +Après analyse, l'échantillon 2013/1/SM-4 contient l'amphétamine

7BREL7 +On analysis, i found the substances to contain 10.83% of amphetamine.

7H5WS7 ANP

88O8O8 +

8KXYZQ +Sample contain Amphetamine.

8LLTJE +amphetamine was as sulfate form

8QXEZ5 +amfetamine,sorbitol, trimethyltriborate

99WMWJ +The sample contains 8.3 % amfetamine

9EU3UC +



Code Amfetamine9WEC99 +

/

AJWS6O +One glass bottle labelled '2013/1/SM-4' containing 0.221g of off-white powder. This powder contained on average of 10% amphetamine. Amphetamine is a class B controlled drug under the misuse of Drugs Act (1971)(as ammended).

AMA50Q +White powder containing amphpetamine.

APYADP +the sample was confirmed by gc ms

B824TN +Amfetamine

BBEBBB +SM 4 contain also Sucrose

BPBBMB +Analysis of the powder revealed the presence of Amphetamine

BZBJBP +Amphetamine, sucrose

C2WUON +-

C5ZRZ2 +SORBITOL

CIIE5Y -IN THE SAMPLE RECEIVED IN COLOR AMBER GLASS BOTTLE WITH PLASTIC CAP STAMPED GREEN MISSING AS DRUGS 2013/1/SM-4.

CLW6JW +Diluted with sucrose

CQC6CC +AMPHETAMINE 10.3% AS BASE.

CSDDCC +saccharose, sorbitol or mannitol

DDXKOD +The sample 2013/1/SM-4 was found to contain Amphetamine.

DVAVS7 +The sample contains amphetamine which is scheduled as illicit drug in France.

EIJIBE +AMPHETAMINE SULFATE (15.5 as base)


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