Inorganic Membranes

Proceedingsof

Eighth International Conferenceon

Inorganic Membranes

Cincinnati, Ohio, USAJuly 18-22, 2004

TIB/UB Hannover 89128 006 358

EditorsF. T. Akin and Y.S. Lin

Table of Contents

Plenary LectureHydrogen and syngas production using ion transport membranes,M Carolan 1

Plenary LectureNew approaches in the design of ceramic membranes, A. Ayral 9

Oral Papers

Ceramic ion conductive membranes based on cerium/gadolinium oxidematerials, synthesis and oxygen transport characteristics, C. Guizard, A. Julbe,O. Robbe, S. Sarrade 18

Novel cobalt-free oxygen permeable membrane, X. Zhu, H. Wang, W. Yang 22

Processing and properties of homogeneous supported gamma-aluminamembranes, M. Mottern, G. Quickel, D. Yu, H. Verweij 26

Synthesis and characterization of bimodal pore silicalite particles andmembranes, C. Cooper, Y.S. Lin 30

Preparation and characterization of a mesoporous MCM-48 membrane on aporous alumina tube, C. Liu, J. Wang, H. long 34

Advances in oxygen transport membranes for gas separations, J. Chen, J. Lane,H. Chen, B. vanHassel.P. Apte, R. Prasad 38

Fabrication of supported Sr-Co-Fe-0 membranes from aerosol-derived powders,H. Xia, T. Ward 42

Synthesis of a nanocrystalline YSZ-SDC heterophase thin film and studies on itselectrical properties and structural stability, A. Kulkarni, J. Dong, P. Fuierer, S.Spealcman 46

Synthesis and hydrogen permeation properties of thin proton-conductingceramic membranes, S. Cheng, V. Gupta, Y.S. Lin 50

Development of proton conductive titanium phosphorus membranes for fuel cellsystems, T. Tsuru, Y. Kinoshita, K. Yagi, T. Yoshioka, M. Asaeda 54

Porous ceramic membranes for reducing the droplet size of emulsions by microstatic dispersion, L. Correia, P. Pex, A. van derPadt, A. Poortinga 59

Mesoporous molecular sieves for size selective separation of biomolecules,A. Katiyar, L. Ji, P. Smirniotis, N. Pinto 63

Ceramic nanofiltration membranes for the retention of homogeneous catalysts,/. Voigt, P. Puhlfur, G. Dudziak, M. Mutter 67

Fully predictive model for NF, combining charge-regulation with irreversiblethermodynamics, W. De Lint, N. Benes, H. Bouwmeester, H. Verweij 72

Preparation of monodispersed O/W emulsion by ceramic membrane jet-flowemulsification, W. Jing, W. Xing, W. Jin, N. Xu 76

Long term pervaporation performance of microporous methylated silicamembranes, J. Vente, J. Campaniello, C. Engelen, W. Haije, P. Pex 81

Hydrostability and scaling-up molecular sieve silica (MSS) membranes forH2/CO separation in fuel cells, M.Duke, J. da Costa, G. Lu and P. Gray 85

Effect of selective ion adsorption and pH on ion flux through amphoteric NFmembranes, R. Takag 89

Percolation properties of porous ceramic support coatings for molecularseparation membranes, minimizing defect density by multiple filmcoating, B.Bonekamp, A. van Horssen, L. Correia, P. Pex 94

Study of permselectivity of gases through silica/carbon nanocompositemembranes, R. Rajagopalan, A. Merritt, H. Foley 98

Hydrophobic ceramic membranes: preparation and application in membranedistillation process, L. Gazagnes, A. Larbot, E. Prouzet, H. Butkiewicz, W.Kujawski 102

Paramagnetic and diamagnetic gas separation by novel high-Tc superconductingmembrane, E. Jang, J. Chang, J. Gwak, V. Rouessac, A. Ayral, L. Cot,J. Choy 107

Cured organosilicon plasma-polymers films for hydrophobic microporousmembranes, V. Rouessac, L. Favennec, A. Julbe, J. Durand 110

Mesoporous anatase coatings for coupling membrane separation andphotocatalyzed reactions, F. Bosc, A. Ayral, C. Guizard 114

Influence of operating conditions on the performance of catalytic three-phasemembrane reactor, M. Vospernik, A. Pintar, G. Bercic, J. Levee 118

Synthesis and characterisation of titanosilicate and related materialsmicroporous membranes, /. Tiscornia, V. Sebastian, Z. Lin, J. Rocha, C. Tellez,J. Coronas, J. Santamaria 122

Preparation of hydrogen permselective silica membranes for high temperatureapplications by using a counter diffusion chemical vapor deposition method, M.Nomura, K. Ono, S. Gopalakrishnan, T. Sugawara, T. Kai, H. Takaba,S. Nakao 126

High quality steam stable tubular silica membranes for gas separation, C.Huiskes, M. Luiten, H. Kruidhof, N. Benes.D. Blank, H. Bouwmeester 130

CsHSCu in hydrogen selective membranes at moderate temperatures, B.Bladergroen, S. Ji, V. Linkov 134

Catalyzed atomic layer deposition as a synthesis method for inorganicmembranes, W. DeSisto, B. McCool 138

Use of ceramic membranes in airlift membrane bioreactors, B. Bishop, S. Judd,J. Car din, H. Alvarez-Vazquez, B. Jefferson, R. Goldsmith 142

Synthesis of Sic ceramic foams by gel casting process, R.Mouazer, I. Thijs,S.Mullens, J.Luyten 146

Counter diffusion self assembly of ordered nanoporous silica membranes, H.Alsyouri, D. Li, Y.S. Lin 150

Porous ferrimagnetic and ferromagnetic membranes for magnetic separation, J.Gwak, A. Ayral, V. Rouessac, K. Kim, J. Grenier, L. Cot, J. Choy,C. Nishimura 154

Hybrid supramolecular membranes as selective biomimetic transport devices, B.Mihai 159

Development of dense ceramic membranes for hydrogen production andseparation from methane, U. Balchandran, B. Ma, T. Lee, S. Dorris 163

Nanoporous inorganic membranes for high selectivity hydrogen separation,Louis K. Mansur, Brian L. Bischoff, K. Dale Adcock, Lawrence, E. Powell andRoddie R. Judkins 167

Molecular sieve carbon membranes from lignin-based materials by rapidpyrolysis, H. Kita, T. Koga, K. Tanaka, K. Okamoto, M. Funaoka 171

Quantitative characterization of grain boundaries and defects withinmicroporous zeolite membranes and their effect upon transport properties, M.Snyder, D. Vlachos, L. Zhiping, M. Tsapatsis 175

Nanoporous silicon carbide membranes, preparation and reactive applications,B. Fayyaz, K. Molaai-Nehzad, H. Patel, R. Ciora, P. Liu, M. Sahimi, T. TsotsislSO

The characterization of mesoporous membranes by krypton adsorption and x-rayreflectivity, K. Chao, P. Liu, K. Huang, C. Chiu 184

Diffusion measurements during pervaporation through a zeolite membraneT. Bowen, J. Wyss, M. Yu, J. Falconer, R. Noble 188

Assessing the potential for gas separations using carbon nanotubes usingatomistic simulations, D. Sholl, H. Chen, J. Johnson, A. Skoulidas 192

Diffusion on an ideal Langmuir lattice applied to membrane and fuel celltransport, N. Benes, F. Zalar, H. Verweij 196

Diffusion through intercrystalline region in polymeric zeolite membranesinvestigated by molecular simulation and 1H PGSE NMR, H. Takaba, A.Yamamoto, K. Hayamizu, E. Akiba, S. Nakao 200

Importance of sorption in the pervaporation behavior of pure components, D.Van Baelen, S. Dekeyzer, V. Bart, V. Carlo, K. U.Leuven 204

Molecular sieving in nanoporous 6-oriented pure-silica-zeolite MFI monocrystalfilm, S. Li, X. Wang, D. Beving, Z. Chen, Y. Yan 208

Comparison of the dual control volume-grand canonical molecular dynamicsand the flux expansion method to calculate the adsorption resistance ofmicroporous membranes, D. Newsome, D. Sholl 212

Preparation of silicalite-1 membranes on Pt/TiO2 particles and their use inreactant selective hydrogenation, N. Nishiyama, K. Ichioka, Y. Egashira, K.Ueyama, L. Gora, W. Zhu, F. Kapteijn, J. Moulijn 216

Light gas separations using defect free ZSM-5 and silicalite zeolite membranes,M. Welk, T. Nenoff 220

Preparation of A-type zeolite membranes by using electrophoretic techniqueA. Huang, J. Liu, Y. Li, W. Yang 224

Inorganic porous membranes for separation of aqueous organic acid solutions,M. Asaeda, T. Waki, M. Ishida, S. Yoshinaga 229

Mass-transport in methylated silica membrane for the separation of organicmixtures, F. de Bruijn, Z. Olujic, F. Kapteijn, P. Jansens 234

Mesoscopic modeling of transport through polycrystalline microporousmembranes, M. Snyder, D. Vlachos 238

Molecular dynamics simulation of transport and separation of condensable andnon-condensable gas mixtures through microporous silica membranes, T.Yoshioka, J. Tanaka, T. Tsuru, M. Asaeda 242

Permeation of supercritical CO2 through porous membranes,X. Goo, X. F. Liu, B. Q. Zhang, Y. S. Lin 246

Synthesis of highly acid-resistant zeolite membranes and their permeationproperties, H. Kita, X. Li, K. Takei, X. Zhang, K. Okamoto, K. Itabashi 250

Atomically-detailed simulations of the permeation of short chain alkanesthrough macroscopic silicalite membranes, S. Chong, D. Sholl 254

Separation of CO2 from CH4 using SAPO-34 membranes, S. Li, J. Falconer,R. Noble 258

Synthesis and characterization of zeolite ZSM-35 membrane on a porous]A-A12O3 tube, G. Zhu, J. Wang, G. Zhu 262

Methanol separation from organics by pervaporation with modified silicamembranes, H. van Veen, Y. van Delft, B. Bongers, C. Engelen, P. Pex 266

Treatment of acid mine drainage in a membrane reactor, R. Govind, P. Rao 271

Successful applications of ceramic nanofiltration in non-aqueous solvents,A. Buekenhoudt, C. Dotremont, S. Aerts, I. Vankelecom,P. Jacobs, K. Leuven 278

Preparation of NaY zeolite membrane and application in the separation ofdichloroethane and nitrogen mixture, L. Bangmin, H. Ling, W. Jinqu 282

Reactive separations for ignition enhancement by in situ generated C2additives for natural gas combustion, J. Langille, J. Pasale, J. Ren, F.Egolfopoulos, T. Tsotsis 286

Stainless-steel-supported MFI membranes for membrane reactors, G. Mabande,A. Avhale, W. Schwieger, M. Hanebuth, R. Dittmeyer, T. Selvam 290

Catalysis-spillover-membrane-3. rate enhancement of n-hexane steamreforming reaction in a catalytic membrane reactor, B. Rei, M Yeh 294

A study on steam reforming of methane in a Pd-stainless steel tubularmembrane reactor, M. Khan, M. Rahman, S. Bias 297

Test of the hydrogen separation from gas mixture using a thin Pd/ceramichollow fiber membrane module, W. Wang, X. Pan, X. Zhang, G. Xiong,W. Yang 301

Quick start hydrogen generator by a catalytic membrane reactor, B. Rei, M.Wang 306

Preparation and characterization of tunisian clay based support and icrofiltrationmembrane and zirconia ultrafiltration membrane, S. Khemakhem,A. Larbot, R. Ben Amar, R. Ben Hassenl, M. Medhioub 310

A design tool for shell and tube vapor permeation modules, P. Perez, P.Jans ens, Z. Olujic 314

Effects of ceramic membrane microstructure on microfiltration of BSAsolutions, W. Li, W. Xing, Y. Fan, N. Xu 318

Nafion/acid functionalized zeolite nanocomposite fuel cell membranes,B. Holmberg, X. Wang, Y. Yan 322

Surface modification of porous vycor glass membrane using organo-silanes,R. Singh, J. Way 326

Ordered MCM-48 membranes containing surface amino groups for CO2/N2

separation, S. Kim, J. Ida, V. Guliants, Y.S. Lin 330

Inorganic-organic hybrid mesoporous membranes for the gas separation,M. Kapoor, S. Inagaki 334

Oxygen and hydrogen transport membranes for combined hydrocarbonreforming and hydrogen separation, A. Sammells, M. Mundschau, X. Xie 338

Experimental study on hydrogen production by methane steam reformingwith membrane reactor, N. Mori, O. Sakai, A. Takahashi, T. Hattori 342

CO removel from reformed fuels using metal-loaded zirconia catalyticmembranes, K. Kusakabe, M. Oda, F. Shibao 346

Systematic Design of Catalytic Membrane Reactors, R. Govind, J. Fang 350

Bao.5Sro.5Coo.sFeo.2O3 membrane reactors for catalytic partial oxidation ofhydrocarbon to syngas, W. Zhu, G. Xiong, W. Han, W. Yang 355

H2S poisoning resistance of palladium-copper membrane alloys over a widetemperature range, B. Howard, R. Killmeyer, M. Ciocco,B. Morreale, Parsons, R. Enick 359

Influence of surface coating on the performance of V-Cu, V-Ti, and Tamembranes for hydrogen separation, S. Paglieri, D. Pesiri,R. Dye, C. Tewell, R. Snow, F. Smith, S. Birdsell 363

In-situ annealing strategies for alloying of Pd/Ag-alloy-porous stainless steel(PSS) membranes used for hydrogen separation, M. Ayturk, E. Engwall,Y. Ma 367

Ab-initio models and experimental measurements of hydrogen flux throughPdCu alloy membranes P. Kamakoti, D. Sholl, B. Howard, M. Ciocco, B.Morreale 372

Facilitated transport through porous metallic membranes, R. Govind,P. Prasad 376

MSS membrane reactor for the dehydrogenation of cyclohexane, E. Shoko,P. Werneck Teixiera, J. Beltramini, J. da Costa 381

Evidence of a single-step membrane process for the two-step nonoxidativeconversion of methane to higher hydrocarbons, X. Gu, J. Dong, T. Nenoff 385

Stainless steel supported silica composite membranes prepared by thesoaking-rolling method and their application to methanol reformingmembrane reactor, D. Lee, Nam, B. Sea, K. Lee 389

Wet air oxidation of waste waters in a catalytic membrane reactor,H. Raeder, R. Bredesen, E. Iojoiu, S. Miachon, J. Dalmon,A. Pintar, G. Bercic, J. Levee 394

SrCoo.4Feo.5Zro.1O3 Dense Oxygen-permeable Membrane for Partial Oxidation ofMethane to Syngas, P. Zhang, Z. Wu, W. Jin, N. Xu 398

Effect of CO2, H2O, CO on a electrolessly deposited palladium ceramiccomposite membrane, F. Roa, D. Way, G. Alptekin, S. de Voss 402

A new method for preparation of Pd-based composite membranes, H. Klette, H.Raeder, Y. Larring, R. Bredesen 406

Fabrication of thin supported palladium alloy membranes for fuel cellapplications, S. Rathod, T. Ward, A. Chellappa, T. Vencill 410

Preparation of zirconia membranes on porous alumina support with ZrO2/A12O3 composite as transition layer, Q. Chang, X. Liu, D. Peng,G. Meng 414

Surface exchange of oxygen in La0.1Sr0.9Co0.9Fe0.1O3-a perovskiteoxides, Q. Yin, Y.S. Lin 418

Perturbation of hydrogen permeation through a palladium membrane with ahydrogen mixture, B. Rei, M. Hsu, K. Hung 422

Factors affecting rejection of salts in nanoporous ceramic membranes, J.Skluzacek, I. Tejedor-Anderson, M. Anderson 426

FILTANIUM: the 100% titanium dioxide ceramic membrane, J. Bergel, P.Lescoche 429

Kerasep diamond: the new generation of ceramic membranes formicrofiltration, ultrafiltration and nanofiltration, J. Jean-Pierre, T. Valerie 434

Poster Papers

Adsorption and diffusion behavior of hydrogen in ultramicropore ofmolecular sieving carbon membranes, H. Hatori, H. Takagi, Y. Yamada All

Adsorption of bovine serum zlbumin onto porous alumina membranes modifiedby self-assembled monolayers of n-alkanoic acids, C. Chang, S. Suen 442

Adsorption, gas phase transport and surface diffusion in porous glassmembranes, J. Yang, J. Eermdkov, P. Uchytil, C. Hamel,A. Seidel-Morgenstern 446

AIPO4-I8 synthesis: membrane preparation, M. Vilaseca, J. Coronas, S.Mintova, T. Bein, J. Santamaria 450

Characteristics of oxygen separation by ionic transport membrane usingcomplexed perovskite composition, P. Jung Hoon, Y. Yeo II, K. Jong Ki, W.Sang Kook, L. Shi Woo 454

Characterization and gas permeation of palladium-silver/zlumina compositemembrane by electroless co-deposition, C. Chu, M. Huang, P. Chiang, T.Huang, H. Chen 458

Determination of concentration-dependent hydrogen diffusivity foramorphous Zr-Ni-Hf alloys using gaseous hydrogen permeation,S. Hara, H. Huang, N. Itoh, K. Kita, K. Kato 463

Development of ceramic support substrates, microporous membranes andmembrane modules for hydrogen separation, B. Nair, Y. Yasushi,A. Kawahara, H. Taguchi 467

Fabrication of a palladium composite membrane using supercritical wet platingtechnique, S. Uemiya, Y. Makino, I. Miyazaki, T. Kawamura, R. Yoshiie, H.Mritomi, M. Nishimura 471

Flame assisted synthesis of catalytic ceramic membranes, M. Mosleh, J.Johansen, T. Johannessen, H. Livbjerg 475

Gas Transport Properties of Carbon Molecular Sieve Membranes Doped withNano Particles, H. Suda, K. Haraya 479

Growth of Zeolite NaA layers on porous stainless steel microchannels, G. Yang,X. Zhang, J. Wang, K. Yeung 483

Influence of seed size and supports with different pore sizes on growth andmicrostructure of silicalite-1 membranes, X. Zhang, H. Liu, J. Wan., K.Yeung 487

Highly permeable supported y-alumina membranes for water purification,D. Yu, M. Mottern, G. Quickel, H. Verweij, J. Bukowski, J. Lewis 491

Hydrogen separation performance and stability of Ni-doped silicamembranes in steam at high temperature, M. Asaeda, M. Kanezashi 495

Intrinsic gas transport and water stability of silica membranes for CO2/CH4

separations, D. Calabro, S. Jakubowicz, C. Yoon, T. Clark, H. Deckman, R.Chance, P. Pex, B. Bonekamp 500

Kinetic monte carlo simulations of hydrogen permeation process throughmulti-layered membranes, H. Kurokawa, K. Bada, M. Koyama,M. Kubo, A. Miyamoto 504

Lithium oxide membranes for high temperature CO2 separation,/. Kumakiri, N. Lecerf, R. Bredesen 508

New inorganic composite ultrafiltration membranes, N. Seffaj, S. Younssi, A.Albizane, M. Bouhria, M. Persin, A. Larbot 512

Novel modified zeolites for energy-efficient hydrocarbon separations, M.Ulutagay-Kartin, T. Nenoff 516

Optimization of preparation conditions of silicon carbide-based membranesfor hydrogen separation, H. Suda, H. Yamauchi, Y. Uchimaru,I. Fujiwara, K. Haraya 520

Palladium alloy membranes for energy efficient membrane reactors,P. Pex, Y. van Delft, L. Correia, H. van Veen, D. Jansen, J. Dijkstra 524

Permeation properties of faujasite membranes on stainless steel supports,Y. Kusumoto, H. Kita, K. Okamoto 528

Preparation of carbon membranes with polyphenylene oxide and their gaspermeation properties, H. Lee, H. Yamauchi, H. Suda, K. Haraya 532

Preparation of mordenite membranes in the inner part of tubular supports,N. Navascues, R. Mallada, C. Tellez, J. Coronas,M. Menendez, J. Santamaria 536

Preparation of silicalite membrane on porous tubular support by hydrothermalsynthesis with electrophoretic deposition as a seeding technique,M. Okamoto, H. Negishi, T. Imura, D. Kitamoto, T. Ikegami,Y. Idemoto, N. Koura, T. Sano, K. Haraya, H. Yanagishita 540

Preparation of zeolite silicalite-1 membranes on tubular carbon supports,B. Zou, X. Zhang, J. Wang, T. Wang, K. Yeung 544

Preparation of zeolite NaA membranes by means of a continuous systemfor the pervaporation separation of ethanol/water mixtures,M. Pera-Titus, R. Mallada, J. Llorens, F. Cunill, J. Santamaria 548

Reverse osmosis of non-aqueous solutions through silica-zirconia porousmembranes, T. Tsuru, M. Miyawaki, T. Yoshioka, M. Asaeda 552

Separation of butane and isomer using a TS-1 type zeolite membrane, Y.Hasegawa, Y. Kiyozumi, F. Mizukami 557

Si-N based ceramic membranes, M. Yokoyama, K. Miyajima, B. Nair,Y. Ando, S. Nagaya, K. Komura, S. Watanabe 561

Separation of CO2 and N2 with NaY zeolite membrane under variouspermeation test conditions, Cho, H. Kim, M. Han, S. Hyun 565

Study of capillary condensation of butane in a vycor membrane, P. Uchytil,R. Petrickovic, A. Seidel-Morgenstern 569

Synthesis and characterization of mesoporous silica and zirconiamembranes templated with a non-ionic block copolymer, S. Higgins,R. Kennard, W. DeSisto 573

Synthesis and photoluminescence of SiC/SiO2 nano-composite film,W. Yuxia, H. Haiping, Z. Youming 578

Synthesis Of all-silica 8-Mr zeolite(CDS-l) membrane, Y. Kiyozumi, Y.Hasegawa, T. Ikeda, F. Mizukami 582

Synthesis of nanostructured titania membranes with improved thermalstability, J. Kim, J. Lee 587

Technical and economic evaluation of vapor permeation ethanol dehydrationprocess with ceramic membranes, P. Perez, Z. Olujic, R. Creusen,P. Jansens 591

Mixed conducting membranes with an oxygen flux higher than10 ml-cm"2-min"u J. Vente, W. Haije, Z. Rak 595

The Vapor Permeation Module Using Zeolite NaA Membrane forProducing Absolute Ethanol From Biomass Ethanol,T. Yamamura, M. Kondo, J. Abe, H. Kita, K. Okamoto 599

Hydrogen permeation characteristics of palladium-coated amorphous-Zr36Ni64 membrane and its long-term durability, H.Huang, S. Hara,M. Ishitsuka, N. Itoh, K. Kita, K. Kato 604

A study of P-type zeolite membrane on long tubular ceramic supports,G. Zhu, J. Wang 608

Dehydration of mixed-alcohols produced by Fischer-Tropsch process byzeolite-A membranes, Y. Li, H. Chen, A. Huang, J. Liu, Y.S. Lin, W. Yang 613

Development of lithium zirconate based ceramic materials and membranesfor high temperature CO2 separation, B. Nair, T. Yamaguchi,K. Nakagawa, S. Nakao 617

How static turbulence promoter can improve microfiltration performancein inorganic tubular membranes, D. Krstic, M. Tekic, M. Caric,S. Milanovic 621

Refining inosine from fermentation broth by MF and coagulation process,W. Xing, W. Jing, J. Zeng, N. Xu, J. Shi 626

TiO2 nanoparticles and films for the fabrication of photocatalytic membranesusing ionic liquid- and surfactant-based self assembling sol-gel methods,H. Choi, K. Yoo, D. Dionysious 630

Vapor phase dehydrogenation of methanol to methyl formate in the catalyticmembrane reactor with Pd/SiO2/ceramic composite membrane,Y. Guo.G. Lu, X. Mo, Y. Wang 635