innovations in corrosion protection istanbul, turkey 2012 polyurea coating development prospects
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INNOVATIONSIN CORROSION PROTECTION
Istanbul, Turkey 2012
POLYUREA COATING DEVELOPMENT PROSPECTS
INNOVATIONSIN CORROSION PROTECTION
Corporate structure
Scientific Research Center Manufacturing Sales Service Center
INNOVATIONS CREATION
PRODUCT INTRODUCTION
STANDARDS DEVELOPMENT
INNOVATIONSIN CORROSION PROTECTION
Products
Solutions for above-ground objects:SPECPROTECTDurability of over 10 years.
Solutions for transition areas:SPECIZOLDurability of over 15 years.
Solutions for underground objects:CARBOFLEXDurability of over 30 years.
PRODUCT ADVANTAGES
High abrasionresistance
Thermal Resistance(frost-resistance)
Fast reactiontime (5-30 sec.)
Resistance to moisture
Resistance toimpact loads
High corrosion resistance
INNOVATIONSIN CORROSION PROTECTION
Products
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
INNOVATIONSIN CORROSION PROTECTION
Collaboration
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
INNOVATIONSIN CORROSION PROTECTION
Collaboration
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
SpecPolymer,Scientific Production Association
LomonosovMoscow State University, Fundamental Physics and Chemistry Engineering Department
D. Mendeleev University of Chemical Technology of Russia, Polymer Composite Paint Materials and Coatings Chair
INNOVATIONSIN CORROSION PROTECTION
Innovations
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
+
Oligomer
Montmorillonite layers
Micro composite
IntercalatedNano composite
Exfoliated Nano composite
INNOVATIONSIN CORROSION PROTECTION
Innovations
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGESPolycarbamide Polyurea Montmorillonite
Disocyanate Polycarbamide
Tetrahedral structure
INNOVATIONSIN CORROSION PROTECTION
Equipment
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
INNOVATIONSIN CORROSION PROTECTION
Innovations
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
l, ar
. un.
200
CompositePolyurea
Substrate
Diffractogram of polyurea and nano composite based on it
INNOVATIONSIN CORROSION PROTECTION
Innovations
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
24
22
20
18
16
14
12
10
450
400
350
300
300
250
200
150
100
Tens
ile s
treng
th, M
Pa
Tensile strength, MPaModulus of elasticity, MPaElongation at break %
The dependence of the physical and mechanical properties of filled polyurea coatings on the content of montmorillonite
35
30
25
20
15
10
5
100
90
80
70
60
50
40
30
20
10
0
600
500
400
300
200
100
0El
onga
tion
at b
reak
%
mod
ulus
of e
last
icity
, MPa
Montmorillonite concentration in the coating, %
Type of coating: 1 - PM100, 2 - PM101
2211Te
nsile
stre
ngth
, MPa
mod
ulus
of e
last
icity
, MPa
Elon
gatio
n at
bre
ak
%
Montmorillonite concentration in the coating, %
INNOVATIONSIN CORROSION PROTECTION
Innovations
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGES
Illustration of penetration of the diffusing particles (oxygen, water vapor) through the film "pure" polymer and polymer silicate nano composite
50
45
40
35
30
25
20
15
10
5
0
300 400 500
Without fillers1% of clay
1 - Composite based on montmorillonit, 2 - Composite based on montmorillonit,
Contents of clay (%)
250
200
150
3,0
2,5
2,0
1,5
1,0
0,5
0,00 1 3 5 7
Perm
eabi
lity to
wat
er v
apor
(g/m
2 x
hour
)
Oxy
gen
perm
eabi
lity
12
polymer chainspolymer chains
trajectory of trajectory of penetrating particlespenetrating particles
polymer chainspolymer chains
polymer chainspolymer chains
trajectory of trajectory of penetrating particlespenetrating particles
lamellar fillerlamellar filler
polymer chainspolymer chains
product surfaceproduct surface product surfaceproduct surface
external environmentexternal environment external environmentexternal environment
the
rate
of c
orro
sion,
mm
| ye
ar
Filling, %
INNOVATIONSIN CORROSION PROTECTION
Resume
Solutions for of underground objects:CARBOFLEXDurability is over 30 years.
PRODUCT ADVANTAGESRESULTS: 1. A decrease of coating permeability after the introduction of 2-3% of montmorillonite nano-
particles.2. Overall protective coatings heat resistance and protective properties improvement increased by
20-30 degrees, which widens the temperature range of coatings exploitation.3. Improvement of the mechanical characteristics of the developed coatings.
INNOVATIONSIN CORROSION PROTECTION
Partners welcome
PRODUCT ADVANTAGES
г. БрянскЗАО «ДЕКО»
г. МоскваООО «УРБАНСТРОЙ»
Nizhny NovgorodVOLGOGAZ
Stary OskolStoilinsky Iron Ore Plant
GubkinLebedinsky Iron Ore Plant
OrenburgENERGOKHIMREMONT
IzhevskSpecgazavtotrans
VolgogradVolgogradneftemash
Volgodonsk-8 Volgodonskaya Nuclear Power Station
KhabarovskDalspecstroy
ChernogorskChernogorskaya Coal Company
ChelyabinskTrubodetal
KumertauURALHEFTEGAZTRANS
MikhaylovkaSebryakovcement
St. PetersburgRussian Innovation Technologies
MarkhamatUfa
ALEXANDER BOYTSOVGENERAL MANAGERELENA MERKOVICHDIRECTOR, QUALITY ASSURANCE, Ph.D. in Chemistry
www.www.spolymerspolymer..pprroo info@[email protected]
Tverskaya street, 12/1, office 24
125009, Moscow,RUSSIA