information of the public in accordance with § 11 of the accident
TRANSCRIPT
Leuna chemical complex
INFORMATION OF THE PUBLIC in accordance with § 11 of the Accident Regulation
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Table of contents
Preamble
InfraLeuna GmbH
ARKEMA GmbH
CRI Catalyst Leuna GmbH
DOMO Caproleuna GmbH
Dow Olefinverbund GmbH
GHC GERLING, HOLZ & CO. Handels GmbH
Hexion Leuna GmbH & Co. KG
Innospec Leuna GmbH
LCP Leuna Carboxylation Plant GmbH
LEUNA-Harze GmbH
LEUNA-Tenside GmbH
Linde AG Geschäftsbereich Linde Gas
Linde Gas Produktionsgesellschaft mbH & Co. KG
Hydromotive GmbH & Co. KG
MinAscent Leuna Production GmbH
Quadrimex Sulfur Chemicals GmbH & Co. KG
TAMINCO Germany GmbH
TOTAL Raffinerie Mitteldeutschland GmbH
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Dear Citizens of Leuna, Merseburg and Spergau
This is the seventh, updated edition of the brochure for the information of the public by companies of the chemical com-plex Leuna in accordance with the regulation on hazardous incidents. The regulation on hazardous incidents commits the operators of incident areas to inform all persons and all facilities with public access, which could be affected by an incident, about the safety measures and the right behaviour in case of an incident. The information has to be checked regularly.
On behalf of the clarity and the comprehensibility the operators of incident areas at the chemical complex Leuna and the InfraLeuna GmbH as the responsible on-site infrastructure service provider have decided to fulfil the aforementioned dutyto inform with a common information brochure.Accordingly the objective of the brochure is to inform the citizens as well as the facilities of cities and communitieslocated within the immediate neighbourhood of the chemical complex Leuna about measures for the preventive avoidance of danger and about danger averting measures in an improbable however possible case.
As you can see in the brochure the measures to prevent hazardous incidents and the averting measures in case of anincident have the highest priority in the mission statement. This ensures that the facilities in hazardous areas are operated on a very high safety standard and hazardous incidents are improbable. For the case of an incident which howevercannot be ruled out completely (however-incident) the affected companies have made all technical, organizational andother arrangements to fight and embank immediately such a however-incident at any time.With the handover of this brochure the publisher would like to ask you to have the information concerning behaviour onhazardous incidents at the Leuna chemical complex handy available at any time. Please transmit all notes, suggestions and comments to the contact persons named in this brochure.
InfraLeuna GmbHDr. Christof GüntherManaging Director
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InfraLeuna GmbH provides infrastructure services for companies based on the closed Leuna chemical complex and therefore operates appropriate equipment, facilities and networks. With the exception of a storage and trans-shipment cen-ter for hazardous goods, containers for petroleum products and for substances with toxic, very toxic, oxidizing, inflamma-tory, flammable, highly flammable and / or environmental hazardous characteristics, the equipment, facilities and networks are not subject to the Hazardous Incident Ordinance.
The approval compliant operation of the storage and trans-shipment center for hazardous containers is ensured by the strict compliance with applicable safety and fire protection regulations as well as regular inspections by qualified operating personnel. The stored goods will be delivered in sealed, approved and for transporting suitable containers, stored and retrieved. Here no emissions are caused during normal operation.An internal alarm and hazard prevention plan and a safety report have been created for this operating unit, which are regu-larly updated and revised. Should it come to the release of substances in spite of all precautionary measures in connection with the operation of the storage, technical systems will secure the retention of the dangerous goods and the immediate alerting of the sites fire brigade to fight the effects of the incident. A safety analysis and a concept for the prevention of hazardous incidents have demonstrated that the consequences of a release of substances have no adverse effects on the public.
On the basis of appropriate agreements and regulatory approvals InfraLeuna GmbH also provides a variety of services for the operators of plants on the Leuna chemical complex which are subject to the Hazardous Incident Ordinance for the prevention, fighting and containment of incidents. The department safety / quality / environmental protection supports companies with plants subject to the application of the Hazardous Incident Ordinance especially in matters of prevention and security coordination. This concerns, for example, the elaboration of the internal alarm and danger prevention plans that need to be created by each company with critical areas and have to be submitted to the responsible authorities for confirmation. For increased clarity, these legally binding internal alarm and danger prevention plans are summarized into an informal, legally non-binding alarm and danger prevention plan for the Leuna chemical complex in coordination with the companies concerned. Finally, the department safety / quality / environmental protection coordinates the publishing of this brochure.
The department site security / works fire brigade also provides services in the field of prevention, particularly for fire pre-vention. It has all necessary human and technical resources to fight any incidents and to limit the spread of pollutants. The control center of this department provides therefore the necessary information and ensures the coordination with all affected parties, including the control center of the district administration of the Saalekreis.
The operational capability of the squad and the technology of the works fire brigade, which also includes a rescue service, is guaranteed „around the clock“ at a high level. The site-based information- and incident management of InfraLeuna GmbH for example includes:
- a siren warning system (with voice modules),- a digital alarm and conference server (information system with the help of selected telephone connections at the Leuna chemical complex),- a direct telephone connection to the control center of the district administration Saalekreis and - an opportunity for the computer-aided calculation of the spread of pollutants in the atmosphere.
Among the services of the works fire brigade which have to be provided by InfraLeuna GmbH in case of an incident, the following tasks are also included:
- the blocking of roads and gates,- the containment and the closing off of dangerous areas and- the direct information in endangered areas using megaphones.
In case of an incident InfraLeuna GmbH is the primary contact for authorities, for the public and for media representatives. Additional information can be obtained at any time through our Info-Telephone: +49 (0) 3461 / 43-96920.
InfraLeuna GmbH Dr. Christof Günther Managing Director
InfraLeuna GmbHAm Haupttor D-06237 LeunaGermany
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ARKEMA GmbH operates inside the area of the chemical site Leuna a unit for the manufacturing of hydrogen peroxide in aqueous solutions. Hydrogen peroxide is a very environmentally attractive substance that releases oxygen when de-composing, and only water remains when reacting with oxidizable substances. Main applications are its use as bleaching agent in pulp and paper industries, as oxidizer in chemical industries as well as a disinfectant in food and pharmaceutical industries.
For manufacturing of hydrogen peroxide a so-called working-solution is used as a media for the reaction of hydrogen with atmospheric oxygen to form hydrogen peroxide. The working solution is composed of different solvents and converted in successive process steps with hydrogen and atmospheric oxygen. An aqueous solution of Hydrogen peroxide is formed by a scrubbing process for further cleaning and separation of the working solution. Eventually rail tank cars or road tankers allow dispatching the final product to our customers.
Another on-site company supplies the raw material hydrogen.
The ARKEMA site has to comply with the German Hazardous Incidents Ordinance.
ARKEMA operates its facility at Leuna in accordance to a certified management system for safety, environmental pro-tection, energy management and quality. Our philosophy is to avoid any incident by consequent application of safe work procedures in all areas of our activities. Therefore, we have implemented and documented all sustainable safety measures and duly submitted to the competent authorities. Our internal alarm and emergency danger plans have been agreed with the competent authorities and the safety responsible of the Leuna platform. Stipulated by contract the professional fire brigade of InfraLeuna GmbH is taking care of preventive fire protection and operative danger defence.
Hazardous incident relevant substances are
Substances Characteristics
Hydrogen highly flammable, able to form explosive atmospheres with airWorking solution environmentally hazardous; should not seep into soil or waterAqueous hydrogen peroxide solution oxidizing, corrosiveMethanol highly flammable, toxicFumes / fire gases harmful, toxic
Person to contact for information of our neighbourhood:
Plant Manager: Mr. Steffen Schaffarczyk, phone +49 (0) 3461 / 43 4960 Additional contact: Production Manager Mr. Fred Seyfarth, phone +49 (0) 3461 / 43 3918
ARKEMA GmbHNiederlassung LeunaDr. Steffen SchaffarczykPlant Manager
ARKEMA GmbHNiederlassung LeunaAm HaupttorBau 2410 D-06237 LeunaGermany
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CRI Catalyst Leuna GmbH manufactures inorganic products at the chemical site Leuna which are mainly used as catalysts in chemical processes. These catalysts consist mainly of chemically nearly inactive materials (e.g. alumina, silicates) and certain heavy metal or noble metal parts. They are used very versatilely e.g. for the refining of petrochemical and oleo-chemical intermediates as well as in the sector of environmental protection.
The production facilities used for the manufacturing of catalysts are in the south-eastern part of the chemical site. All raw and auxiliary materials as well as the intermediates and finished products are stored there. In the sense of the Federal Immission Control Act (Bundesimmissionsschutzgesetz/ BlmSchG) these facilities are an operating area for which, basi-cally because of the handling of respirable nickel dusts, apply extended safety obligations according to the regulation on hazardous incidents which are completely fulfilled by our company. This has been confirmed by independent experts as a result of conducted safety analysis.
A safety report, a concept for the prevention of hazardous incidents and an internal alarm and danger fighting plan have been submitted to the charged authority which has accepted them. Furthermore a reliable safety organisation within our company in cooperation with the articled works fire brigade, with other on-site facilities acting to prevent danger and with the state surveillance authority guarantees that the facilities within the operating area of CRI Catalyst Leuna GmbH are only operated under strict compliance with the safety regulations.
In case that despite all preventative safety measurements substances which are subject to the regulation on hazardous incidents are uncontrollably released, it is ensured that we immediately and comprehensively fulfil our information duty as well as our obligation to fight the hazardous incident and so limit or eliminate any damaging effects on the neighbour- hood.
Substances that may be accidentally released into the neighbouring vicinity are:
Substances Characteristics
Hydrogen, Natural gas flammableAmmonia toxic, flammable, causticHeavy metal compounds (Nickel, Cobalt, Copper as toxic, hazardous to waterssalt solutions, suspensions or solids) Nitric acid, Caustic soda solution corrosive/caustic, hazardous to waters
For further information about our company: +49 (0) 3461 / 43 4384 or +49 (0) 3461 / 43 3447.
CRI Catalyst Leuna GmbH Holger GünschelManaging Director
CRI Catalyst Leuna GmbHAm HaupttorGebäude 8322 D-06237 LeunaGermany
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We as DOMO Caproleuna GmbH produce both organic and inorganic substances. Our customers polymerise this main product Caprolactam to form Polyamide 6 plastic granulate. This granulate is mainly processed to polyamide fibres.
In Part I of the chemical site Leuna we operate three plants, and in Part II, we operate 6 plants as follows.
Plant Brief Description of Activities
Ammonia liquid Unloading, pressure storage and distribution of liquid AmmoniaAmmonia solution Production of Ammonia solution to 35 percent by weight of liquid AmmoniaAmmonium sulphate Production of fertilizer through crystallisation of Ammonium sulphate solution Cumene Production of Cumene through liquid phase alkylation of Benzene with Propene at 23 barPhenol Production of Phenol and Acetone using the HOCK-process by Cumene oxidationSulphuric acid Production of Sulphuric acid and Oleum using the double contact processHAS Production of Hydroxyl ammonium sulphate through pressure hydrogenation of Nitrogen monoxideCyclohexanone Production of Cyclohexanone through Phenol hydrogenation at 160 °C and 2,5 bar pressureCaprolactam Production of Caprolactam by oximation of Cyclohexanone with HAS and following rearrangement, in presence of Oleum, to Caprolactam
Both operational areas fall under the application area of the Hazardous Incident Regulation. Any resulting material and organizational duties required by the responsible authorities have been fulfilled.The operational areas handle the most important substances listed below. These substances partially have properties that are classified as dangerous to men and environment.
Substances Characteristics
Gases/Vapours Ammonia toxic, caustic, environmentally hazardous Sulphur dioxide toxic, caustic Propene, Propane, Gas, Hydrogen Flammable gases, potentially explosive Liquids Ammonia solution caustic, environmentally hazardous Benzene highly flammable liquid, carcinogenic, toxic Cumene highly flammable liquid, hazardous to health, environmentally hazardous
Trichloroethylene carcinogenic, irritating, environmentally hazardous Sulphuric acid / Oleum caustic, corrosive/caustic, irritating, reacts violently with water, corrosive Phenol toxic, caustic Acetone highly flammable liquid, irritates the eyes
Our principle is to avoid accidents, and, therefore, we have undertaken all safety measures imaginable. These measures have been recorded in writing and have been submitted to the responsible authorities. Additionally we have a comprising operational alarm and hazard prevention plan, which we have designed in close cooperation with the safety and environ-mental protection authorities at the Leuna chemical site and the responsible authorities.
Contact PartnerLuc de Raedt, Managing Director phone: +49 (0) 3461 / 43 2200.Daniel Gräfe, Accident Manager phone: +49 (0) 3461 / 43 2785.
DOMO Caproleuna GmbHLuc de RaedtManaging Director
DOMO Caproleuna GmbHAm HaupttorBau 3101D-06237 LeunaGermany
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Dow Olefinverbund GmbHWerk LeunaAm Haupttor, Bau 3803D-06237 LeunaGermany
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Dow Olefinverbund GmbH operates two synthesis plants for the production of plastics (polyethylene) through the chemical conversion of ethylene. The product is manufactured as a granulate, and is the preliminary stage for further processing in the plastics manufacturing industry, e.g. foil and cable production.The raw material ethylene enters the plant continually as a gas. The obsolete ethylene, which cannot be used anymore, is collected and burned in a state-of-the-art exhaust combustor.
The running processes are operated at very high pressure and high temperature. Therefore the plant is subject to the Federal Immission Control Act (Bundes-Immissionsschutzgesetz) and the Accident Regulation. The regulative bodies of the Federal Republic of Germany require comprehensive safety measures. All of these required technical and operational measures have been implemented and have been certified by various authorities.
We designed hazard prevention plans and safety analyses, which were surveyed by independent experts, and received operational approval by the corresponding authority. We have also fulfilled the highest safety and fire protection require-ments.
The Leuna chemical site has a Professional Fire Brigade that will immediately take action if substances are released or a fire breaks out, and they will limit the damage of such accidents.
Substances that may cause an accident and may be released into the neighbouring vicinity are:
Substances Characteristics
Gases (Ethene) flammable, explosiveLiquids (Oils, Peroxide) flammable, hazardous to watersPolyethylene and compound products flammable
For further information please phone +49 (0) 3461 / 49 7814.
Dow Olefinverbund GmbH Werk Leuna Robert Gärtner Production Leader
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For more than 100 years GHC GERLING, HOLZ & CO. Handels GmbH globally supplies the industry with speciality gases. These gases are used for example for the production of pharmaceuticals, automobile tyres or for the disinfection of drinking water.
At the Leuna chemical site GHC purifies and liquefies hydrogen sulphide (H2S). The substance is filled into transportable receptacles and stored afterwards. The product is used by our customer’s e. g. for the refinement of mineral oils, the syn-thesis of flavours, the production of pigments, or the production of semiconductors.
Our plants are equipped with state of the art safety installations. They are surveyed by gas detectors twenty-four seven.Even beyond production hours, these detectors are directly connected to the on-site professional fire brigade.
Our plants are subject to strict safety regulations. They are permanently checked by internal and external experts and the supervisory authorities respectively. They are maintained and serviced regularly by qualified and trained personnel.
In case of an accident the following substances might reach the neighbourhood:
Substance Characteristics
Hydrogen sulphide very toxic, extremely flammable, hazardous to water
Hydrogen sulphide will be observed even at low concentrations (already at 0.025 - 0.1 ppm), which are not hazardous to human health, by the intense smell of rotten eggs.
If - despite all safety and security measures - any incident will occur, which might endanger the environment, a special emergency plan comes into force. This emergency plan is adapted to the local circumstances and tested in safety trainings regularly. The plan is coordinated with the on-site professional fire brigade and external emergency authorities (police, civil protection).
In case of any questions, please do not hesitate to contact us:
Phone: +49 (0) 40 / 853123-0E-mail: [email protected]: www.ghc.de
GHC GERLING, HOLZ & CO. Handels GmbHppa. Norbert Niewel
GHC GERLING, HOLZ & CO. Handels GmbHStandort LeunaAm HaupttorBau 3651D-06237 LeunaGermany
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Hexion Leuna GmbH & Co. KG is a 100% affiliated company of Hexion. It operates a chemical facility to manufacture latices at the chemical site Leuna.
Synthetic latices are produced using the emulsion polymerisation process, and are basic substances for the paint and construction industry besides the adhesive market.
The various substances used for the operation of the plant as well as the intermediate and finished products are stored within the plant. The plant is subject to the application of the Accident Regulations (so called SEVESO Regulation). The manufacturing processes are partly operated under increased pressure and temperature and are therefore subject to very strict safety regulations.
The concept documents regarding the prevention of accidents and the safety reports of Hexion Leuna GmbH & Co. KG have been examined by independent experts. Considering the relevant substances, environmental and operational ha-zards, described in the safety report and the relevant measures to prevent incidences, it can be said that the plant does not represent a serious hazardous risk.
We have a contractual agreement with the Professional Fire Brigade of InfraLeuna to undertake all necessary tasks of preventative fire protection and operative hazard prevention.
If there should be an accident despite all these safety measures the release of the following substances could not be ex-cluded and may reach the neighbouring vicinity:
Substances Characteristics
In case of Fire: Fumes (Smoke) Hazardous to health with toxic componentsGas: Butadiene (liquefied by pressure) Hazardous to health, highly flammableLiquids: Styrene Hazardous to health, flammable Acrylates flammable, hazardous to environment Acids and Bases corrosive, flammable, hazardous to environment
Other raw materials toxic, corrosive, flammable, hazardous to environment
For further information about the company please call +49 (0) 3461 / 43 930.
Hexion Leuna GmbH & Co. KG Jan Martinec, Ph.D.Managing Director
Hexion Leuna GmbH & Co. KGAm HaupttorBau 6101D-06237 LeunaGermany
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Innospec Leuna GmbH operates at the Leuna chemical site a plant for the production of plastics and waxes through poly-merisation of ethylene, or ethylene and vinyl acetate and a plant for the oxidation of waxes. Our plastics are processed by the plastic processing industry into injection moulding parts, profiles, foams and foils with very good flexible characteristics and low temperature resistance. Our waxes have numerous applications like printing ink, gloss paint, cleaning agents, textile and paper industry products and are also used as an additive in diesel and heating fuel.
We mainly obtain our raw materials via pipeline (ethylene) or tank lorries (vinyl acetate).
Polymerisation is carried out under high pressure and temperatures.
The plant is subject to approval and to the stipulations of the Federal Immission Control Act (Bundes-Immissionsschutz-gesetz) and to the Accident Regulations (Seveso III). The operation of the plant is carried out in accordance with the statu-ary regulations and has a high technical and organisational safety standard.
ln case of accidents we have undertaken measures that will limit the effect of an accident to the plant area (e.g. operational alarm and accident prevention plan, Professional Fire Brigade).
Accident relevant substances are:
Substances Characteristics
Ethylene (gaseous) Flammable (forms explosion capable mixture with air)Vinyl acetate (liquid) Highly flammableFinished products (solid) FlammableLiquid mineral oil products
Further information about our company can be obtained under phone +49 (0) 3461 / 43 4066.
Innospec Leuna GmbH Adin L. ClarkeDietrich von der Wense Managing Directors
Innospec Leuna GmbHAm HaupttorBau 6310D-06237 LeunaGermany
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LCP GmbH operates a chemical plant to manufacture carboxylation products at the chemical site Leuna.
Para-hydroxybenzoic acid is the basis for special polymers and is also used for the extraction of antimicrobial effective para-hydroxybenzoic (PHBA)-esters and their salts. PHBA Salicylic acid and cresotinic acids are the base materials for active pharmaceutical ingredients and medicinal preparations.
The ingredients and auxiliary materials as well as the intermediates and finished products, which are required in connection with the operation of the plant, are stored in the plant. The plant comes within the Hazardous Incidents Ordinance. The processes within the plant run partly under raised pressure and temperature and are therefore operated on strict safety precautions.
The concepts to prevent hazardous incidents and the safety reports have been worked out and checked by independent experts. The material, environmental and operational sources of danger as well as the respectively executed counterme-asures which are relevant for the plant and which are described in the safety reports, show that no serious danger ema-nates from the plant.
There are contractual agreements with the site fire brigade of InfraLeuna GmbH to fulfil all tasks of fire-prevention and the operative prevention of hazards.
Should it come to a hazardous incident despite all the safety precautions, it would be possible that the following substances are released which could then reach the neighbourhood:
Substances Characteristics behaviour at danger
fire gases (fumes) harmful to health with toxic elements close windows, doors, stay in buildingsliquids (phenol, cresols) toxic, flammable, hazardous to waters further substances caustic, hazardous to waters (acid, lye)
lf you require further information on the plant please do not hesitate to contact us on + 49 (0) 3461 / 43 4350.
LCP Leuna Carboxylation Plant GmbHHans-Jürgen JähmeManaging Director
LCP Leuna Carboxylation Plant GmbHAm HaupttorBau 7629D-06237 LeunaGermany
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LEUNA-Harze GmbHAm HaupttorBau 6619D-06237 LeunaGermany
LEUNA-Harze GmbH operates plants for the manufacture of resins by various chemical processes such as synthesis, saponification, polycondensation and polymerisation.
The plants produce liquid and solid epoxy resins, epoxy resin hardeners, modification agents, ketone resin and bisphenol F as well as epichlorohydrin as base material. The required raw materials like glycerine, bisphenol A, epichlorohydrin, caustic soda solution, phenol, fatty alcohols are supplied via rail tank wagons or tank lorries to Leuna. The finished products are delivered in tank lorries or barrels and small-sized packages via road. The products are known under the brand names: Epilox and L-Harze.
The operational areas of LEUNA-Harze GmbH are subject to the application of the Accident Regulation. The plants operate mainly under normal pressure or vacuum conditions and are operated adhering to very strict safety regulations. The use of modern process control systems allows comprehensive safety checks to prevent accidents.
By applying an integrated management system for the quality assurance, environmental protection and operational safety (ISO 9001, ISO 14001 and EU Eco-audit-regulation) the company and each employee is committed to an up to quality standard, ecosensitive and safe method of operation.
The Professional Fire Brigade also cooperates with LEUNA-Harze GmbH and will take immediate action in case of acci-dents and fires and will limit the consequences of such accidents.
Substances that may be accidentally released into the neighbouring vicinity are:
Substances Characteristics
fumes (smoke) health hazard, causticgases / vapours of organic liquids, Hydrochloric toxic, health hazard, odorous, flammable, explosion capableacid (gaseous), chlorine liquids (ketone, aromatic solvents, epichlorohydrin, oxic, health hazard, flammable, explosion capable, caustic, haz-phenol, amines, resins) ardous to waters and environment
Under the telephone numbers +49 (0) 3461 / 43 3094 and +49 (0) 3461 / 43 3639 further information about our company can be caught up.
LEUNA-Harze GmbHKlaus PaurManaging Director
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LEUNA-Tenside GmbH is specializing in the production of anionic and nonionic tensides and special chemicals.
LEUNA-Tenside GmbH operates, on the Leuna chemical site, plants for the production of substances achieved through a chemical conversion process, especially - Alkane sulfonates as basic substances for emulsion polymerisation and the production of washing agents,
- Fatty acid-N-methyltaurinate for the production of detergents and textile appliances and pesticides,- Sodium-isethionate for the production of body care products and detergents,- Chloroparaffins as flame retardant,- nonionic tensides as cleaning agents,- Fatty alcohols for detergents and cleanser, creams, body lotions, leather and textile auxiliaries, as surfactant.
The plants are subject to the application of the Accident Regulation. Due to the substances used, the plants are operated under very strict safety measures. In accordance to the Accident Regulations LEUNA-Tenside GmbH prepared a safety report about the operational area, which has been approved by independent experts and submitted to the relevant autho-rities.The Leuna chemical site has a Professional Fire Brigade, which will take immediate action in case of substance release or fire, and will in cooperation with company staff and emergency and rescue services take the appropriate measures to fight any incident and do its utmost to limit the effect of the incident.To fight the effects of an incident outside of the works area, an external alarm and hazard prevention plan has been desi-gned. The directions of the emergency and rescue services must be adhered to.
Substances that could cause an incident and reach the neighbouring vicinity are:
Substances Characteristics
Chlorine fatal if inhaledSulphur dioxide toxic if inhaledEthylene oxide toxic, extremely flammablePropylene oxide extremely flammableMethanol toxic, highly flammable liquid and vapourPhosphorus trichloride fatal if swallowed or if inhaled Other substancese.g. Acids, Lyes, Methylamine solution caustic, hazardous to waters
For further information about our company please contact us under phone +49 (0) 3461 / 43 4397.
LEUNA-Tenside GmbHDr. Kiril MateewManaging Director
LEUNA-Tenside GmbHAm HaupttorBau 7302D-06237 LeunaGermany
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Linde Gas, which is a business unit of Linde AG, including their other subsidiaries Linde Gas Produktionsgesellschaft mbH & Co. KG and Hydromotive GmbH & Co. KG, has specialised in the manufacture and sale of technical gases.
At Leuna industrial site, they operated plants for- the breakdown of air into its components oxygen, nitrogen and inert gases,- production of hydrogen, carbon dioxide, carbon monoxide,- liquefaction of hydrogen and carbon monoxide,- production and filling of acetylene as well as- Filling and storage of air and special gases to mobile pressure devices.
The customers (i.e. chemical industry, food industry and craft trades, hospitals as well as manufacturers of computer com-ponents) are supplied using the transport vehicle feet available on site and via pipelines.
A certified engineering office has worked out safety concepts for the operating units of Linde AG allowing us to prove to-wards the control authority and also to our neighbours that the operations carried out in our plant are always safe.Compliance with the applicable laws and regulations with regard to the installation and operation of our plants is a matter of course. In addition, we have introduced a certified quality, safety and environmental management system on a volunteer basis.
Please find below some information on the properties of substances which are listed in the regulation of hazardous inci-dents and handled by Linde AG during their activities:
Substances Characteristics Behaviour in case of danger
Oxygen chilled liquefied, oxidising, heavy fog formation Keep away from the fog patches, with humidity no fire, no smoking Acetylene, Hydrogen inflammable gases, mixtures with air are explosive No smoking, no fire, no sparking Toxic Gases toxic, partially caustic, partially odourless Comply with the instructions given by the emergency services, stay in closed rooms
For more information, please contact our SHEQ department (Phone: +49 (0) 89 / 7446-0) or management (Phone: +49 (0) 3461 / 853-100).
Linde AG Linde Gas Produktionsgesellschaft Hydromotive Geschäftsbereich Linde Gas mbH & Co. KG GmbH & Co. KG Olaf Reckenhofer Olaf Reckenhofer Florian Bahnmüller Managing Director Witold Balczarczyk Lutz Leopold Wolfgang Ott Managing Directors Managing Directors
Linde AGGeschäftsbereich Linde GasSpergauer StraßeD-06237 LeunaGermany
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MinAscent Leuna Production GmbH (formerly Minakem Leuna GmbH) operates a multi-purpose plant for the production of fine and specialty chemicals and associated storage facilities in the northern part of the chemical site of Leuna. The products manufactured, are used in the chemical and pharmaceutical industries.The operation performed falls within the scope of the Accident Regulation with extended obligations.The operation of the facilities is done under a tight safety system. Modern distributed control systems ensure a safe monito-ring and operation of the production processes. The stock quantities of starting materials are kept to a necessary minimum, in order to limit the impact on the surrounding neighbourhood in case of an accident.MinAscent is working in the direct responsibility and in the self-understanding, to continuously improve the protection of health and the environment and the safety of the employees and neighbours.
The MinAscent facilities are integrated in the security and emergency response system of the industrial complex of Leuna.
In case of a severe accident, materials with the following hazardous potential may be released besides fire and explosions and despite all the safety measures in place:
Substances Characteristics
acetone highly flammable liquid and vapour; causes serious eye irritation; may cause drowsiness or dizzinessammonia (liquefied) flammable gas; toxic if inhaled; causes severe skin burns and eye damagebenzene highly flammable liquid and vapour; may cause cancer; may cause genetic defects; may be fatal if swallowed and enters airwayscaustic soda and sulphuric acid causes severe skin burns and eye damage; may be corrosive to metalsdi-tert.-butyl-dicarbonate flammable liquid and vapour; may be fatal if inhaled; may cause an allergic skin reactiondichloromethane suspected of causing cancerdimethylsulfate toxic if swallowed; may be fatal if inhaled; suspected of causing genetic defects; may cause cancerethyl acetate and iso-propanol highly flammable liquid and vapour; causes serious eye irritation; may cause drowsiness or dizzinessheptane and toluene highly flammable liquid and vapour; may be fatal if swallowed and enters airways; may cause drowsiness or dizziness; suspected of damaging the unborn childhydrogen extremely flammable gashydrogen peroxide may cause fire or explosion; strong oxidiser; causes severe skin burns and eye damagemethyllithium Spontaneously Auto ignition if exposed to air; Harmful if swallowed; Causes severe skin burnsnitric acid may intensify fire; oxidiser; causes severe skin burns and eye damage; may be corrosive to metalsselenium toxic by inhalation and ingestion
For further information about our company please contact:
Mr. Dr. Poppe Managing Director Phone: +49 (0) 3461 / 43 4535Mr. Dr. Schuricht Head of Production Phone: +49 (0) 3461 / 43 4406
MinAscent Leuna Production GmbHDr. Olaf PoppeManaging Director
MinAscent Leuna Production GmbHAm HaupttorGebäude 4208D-06237 LeunaGermany
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uadrime
Quadrimex Sulfur Chemicals GmbH & Co. KG operates a plant for the production of sodium hydrosulfide at the Leuna Chemical site.In various parts of the plant ammonium hydrosulfide, sodium sulfide, and sodium hydrosulfide are produced in solution, in molten, or in solid form. These products are dispatched worldwide via dedicated dangerous goods transports. The produc-tion takes place in continuously working closed systems. The raw materials required are delivered either via pipeline from other on-site companies or via railway or road tankers from the region.
Sulfides are mainly used as flotation agent in the extraction process of heavy metals, for lignin splitting in pulp and paper industries, as well as in the leather processing for in the liming process of animal skins. These substances are also applied in the production of sulphurous organic chemicals such as e. g. thioglycolic acid, thioplasts or dyestuffs. Furthermore, they are applied in waste water and exhaust air treatment processes as precipitation agent for heavy metals removing.
The safety management system of Quadrimex Sulfur Chemicals GmbH & Co. KG including the related danger prevention plans and safety reports undergo permanent development and are coordinated with the public authorities. Independent experts and governmental supervising and monitoring authorities equally certify that the plant processes are operated subject to the strictest security regulations.
Permanent development, systematic checks and maintenance of plant and safety technology are part of the profound emergency concept for preventive and targeted prevention of hazards or pollutions as well as the comprehensive training of our employees. This also includes regular exercises together with the professional fire brigade of InfraLeuna GmbH.
Even if, despite of all the safety precautions, it comes to an incident, the release of the following substances cannot be ruled out:
Substances Characteristics
Gases: hydrogen sulfide very toxic, flammable Liquids: sulfide solution toxic, combustible, caustic, environmentally hazardoussodium hydroxide solution corrosive ln the event of fire: smoke, combustion gases are hazardous to health when containing toxic components (e. g. sulfur dioxide, nitrogen oxides, ammonia)
For further information about our company, please call: +49 (0) 3461 / 43 9801.
Quadrimex Sulfur Chemicals GmbH & Co. KG Martin ZieglerManaging Director
Quadrimex Sulfur Chemicals GmbH & Co. KGAm HaupttorGebäude 3651D-06237 LeunaGermany
1714
Our company operates, on the southern part of the chemical site, an operational area with plants for the production of me-thylamine, dimethylformamide and derivates of methylamine. The operational area is subject to the Accident Regulations.The plants produce a range of basic chemicals. Methylamines are made from methanol and ammonia and are catalytically synthesised using increased pressure and temperature before being purified in a number of distillation columns. Methyl-amines are raw materials used for solvents, vulcanisation accelerator, pesticides, ion exchangers, disinfectants, animal feed additives, corn growth stabilisers, colourings and pharmaceuticals.Dimethylformamide is synthesised in a further plant, from carbon monoxide and dimethylamine, using a methanol solution, derived from sodium methylate synthesised under high pressure and increased temperature and purified by a distillation unit. Dimethylformamide is a solvent used in many applications. It is for example used in the production of acrylic fibres and polyurethanes.In the derivatives plant we manufacture triazine, made of monomethylamine and formaldehyde solution, dimethylammoni-umchloride solution made of dimethylamine, hydrogen chloride and water and trimethylammoniumchloride solution made of trimethylamine, hydrogen chloride and water. Triazine is an absorption agent for acidic gases, the so-called chloride solutions serve as the basis for animal feed additives and pharmaceuticals. Chlorocholine chloride is used in agriculture as a growth control agent for stabilising stalks of cereals, and is made of the raw materials trimethylamine and dichlorethane. Most raw materials are acquired from other companies on site via pipelines, these are: methanol, ammonia, carbon mon-oxide, hydrogen chloride.
We handle the following hazardous substances in accordance with appendix 1 of the Accident Regulations:
Substances Characteristics
Gases / Vapours: Methylamine highly flammable liquefied gases, strong odourAmmonia flammable, toxicCarbon monoxide highly flammable, toxic, odourlessHydrogen highly flammableNatural Gas highly flammableFumes in an accident health hazard with toxic substances Liquids: Methylamine solutions highly flammable, strong odourMethanol/Methylate solutions easily flammable, toxicDistillery residue easily flammable, toxic, strong odourDimethylformamide flammableDichloroethane easily flammable, toxic
In order to limit any effect of an accident the following equipment has been provided:In case of leakages parts of the plant can be released and emptied via a blow-down-system with a flare.Flash gasses produced by the chlorocholine chloride plant are routed to a thermal after-burner.Stationary and remote controlled sprinkler systems to cool containers and control of water-soluble gases (ammonia, me-thylamine).Fire extinguishing and water retention facilities.
For further information please call phone: +49 (0) 3461 / 43 4502.
TAMINCO Germany GmbHRoel FrèreManaging Director
TAMINCO Germany GmbHAm HaupttorBau 8314D-06237 LeunaGermany
18
TOTAL Raffinerie Mitteldeutschland GmbHMaienweg 1D-06237 Leuna OT SpergauGermany
15
TOTAL Raffinerie Mitteldeutschland GmbH is the owner of the new refinery and the methanol plant. The plants are desi-gned in accordance with the latest technology and are operated by experienced and qualified staff. The main raw material crude oil is delivered via pipelines.
We produce gasoline, diesel fuels, fluid gases and raw materials (petrochemical naphtha, methanol, sulphur, propylene, heavy metal concentrates) and bitumen. The substances needed for the operation of the plant and any intermediate and finished products are stored in the plant area. The delivery of finished products is done via rail tank wagons and tank lorries as well as product pipelines.
Parts of the production plant operate under increased pressure and temperature and are therefore mainly governed by the Accident Regulations. Any required technical and operational measures have been put into place accordingly. The necessary safety report has been written and submitted to independent safety experts who have examined it. An approval test was carried out with the participation of various expert authorities, and the operation of the plant was approved. The production and storage facilities are subject to a regular technical examination by independent experts.
The refinery has its own fire brigade, which would in case of product release and fire, immediately be activated and attempt to limit the possible consequences of such an incident.
Substances that may cause an incident and could be released into the neighbourhood are:
Substances Characteristics
Gases / Vapours: Hydrogen sulphide very toxic, highly flammable, dangerous to the environmentSulphur dioxide toxic, causticCarbon monoxide highly flammable, toxicAmmonia toxic, irritant, caustic, dangerous to the environmentHydrogen highly flammable, explosiveGaseous Hydrocarbon highly flammable, explosive Liquid Mineral Oil Products highly flammable, easily flammable, dangerous to the environmentMethanol easily flammable, toxicFumes (smoke) health hazard
For further information about the plant, product and further questions about the company please contact the department safety/environment/quality Hardy Schramm, phone: +49 3461 48-1158, e-Mail: [email protected] and communica-tion phone: +49 3461 48-1056, e-Mail: [email protected].
You can contact our central office under phone: +49 (0) 3461 / 48-0, as well as our citizens phone 0800 4848-112.
TOTAL Raffinerie Mitteldeutschland GmbHDr. Willi FrantzManaging Director
1916
Companies
1 ARKEMA GmbH
2 CRI Catalyst Leuna GmbH
3 DOMO Caproleuna GmbH
4 Dow Olefinverbund GmbH
5 GHC GERLING, HOLZ & CO. Handels GmbH
6 Hexion Leuna GmbH & Co. KG
7 InfraLeuna GmbH
8 Innospec Leuna GmbH
9 LCP Leuna Carboxylation Plant GmbH
10 LEUNA-Harze GmbH
11 LEUNA-Tenside GmbH
12 Linde AG Geschäftsbereich Linde Gas
Linde Gas Produktionsgesellschaft mbH & Co. KG
Hydromotive GmbH & Co. KG
13 MinAscent Leuna Production GmbH
14 Quadrimex Sulfur Chemicals GmbH & Co. KG
15 TAMINCO Germany GmbH
16 TOTAL Raffinerie Mitteldeutschland GmbH
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Infrastructure
Operational Areas of InfraLeuna
Chemicals/Gases/Industry
Service Providers
Refinery
Power Plants
Areas for Industrial Development
Hill (ashes)
Research facilities
1312
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1010
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11109
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Imprint:
Information of the public in accordance with § 11 of the Accident Regulations7. Edition May 2016
Editor:
InfraLeuna GmbHARKEMA GmbHCRI Catalyst Leuna GmbHDOMO Caproleuna GmbHDow Olefinverbund GmbHGHC GERLING, HOLZ & CO. Handels GmbHHexion Leuna GmbH & Co. KG Innospec Leuna GmbHLCP Leuna Carboxylation Plant GmbHLEUNA-Harze GmbHLEUNA-Tenside GmbHLinde AG Geschäftsbereich Linde Gas Linde Gas Produktionsgesellschaft mbH & Co. KGHydromotive GmbH & Co. KGMinAscent Leuna Production GmbHQuadrimex Sulfur Chemicals GmbH & Co. KGTAMINCO Germany GmbHTOTAL Raffinerie Mitteldeutschland GmbH
Editorial staff:InfraLeuna GmbH, department of safety/quality/environmental protection
Images:InfraLeuna GmbH, Ralf Lehmann
Information About the CorrectBehaviour in Case of an Incident
at the chemical complex Leuna
Recognising a Dangerous Situation
- Smell of fire or gas- Smoke plume or fire- Loud bang, explosive noises- Siren alarm: 1 minute up and decongestant howling
Safety Instructions
- Stay indoors!- Ascertain that all children are indoors.- Help disabled and elderly people.- Temporarily accommodate passers.
- Close windows and doors tightly.- If possible seek interior rooms on the upper floors.- Switch off any ventilation and air conditioning.- If you are using a car, stay inside the car, close all windows and switch off the ventilation, the air conditioning and the engine.
- If your health has been affected, call your doctor or the medical emergency.- Please leave your house or car only after you have heard the all-clear announcement (via radio or loudspeaker announcement).
- Switch on the radio (FM) and your television set.- Any announcements will be made via regional broadcasting services like: - MDR 1 Radio Sachsen-Anhalt (Frequencies 100,8 MHz / 106,5 MHz), - MDR TV station.- Listen for announcements.
1 Minute
- Keep calm!- Obey instructions of emergency personnel!- Listen to loudspeaker announcements! (Police, fire brigade, local government Saalekreis)
Important phone numbers- Control centre of the site security/fire brigade +49 (0) 3461 / 43 4333- Info-telephone of the chemical site +49 (0) 3461 / 43 96920
- Local government Saalekreis,- civil protection/district control center +49 (0) 3461 / 40 1255