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H2 FROM H2O A market assessment for a catalyst technology A market assessment for a catalyst technology that produces hydrogen from water C2M Analysis Team Ald W d MBA 2012 Alden Woodrow, MBA 2012 Hannah Murnen, Ph.D 2012 Ivor Castelino, MBA 2011 Kyle Sandburg, MBA 2011 May 2011

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Page 1: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

H2 FROM H2O A market assessment for a catalyst technologyA market assessment for a catalyst technology 

that produces hydrogen from water

C2M Analysis TeamAld W d MBA 2012Alden Woodrow, MBA 2012Hannah Murnen, Ph.D 2012Ivor Castelino, MBA 2011Kyle Sandburg, MBA 2011

May 2011

Page 2: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

THE HYDROGEN CATALYST TEAM

Alden Woodrow MBA 2012 Scientist Sponsors Energy & Cleantech Finance focus Environmental Strategy Consultant

Hannah Murnen Ph.D 2012

• Jeffrey Long, PhD

• Christopher Chang, PhD

Hannah Murnen Ph.D 2012 Sustainable Materials focus Materials Self Assembly Researcher

I C t li MBA 2011

Academic Advisors

• Beverly Alexander

• Dariush Rafinejad, PhDIvor Castelino MBA 2011 Energy & Cleantech Sales focus Technology Consultant

• Ryan Hanley

• Brooks Kincaid

Kyle Sandburg MBA 2011 Sustainable Product Development focus Technology & Sustainability Consultant

UC Berkeley: Cleantech to Market ‐ Confidential 2

Page 3: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

OBJECTIVE:  ANALYZE THE MARKET POTENTIAL FOR A HYDROGEN GENERATING CATALYST 

AND RECOMMEND A PATH TO MARKET

The hydrogen landscape

Our technology Path to marketlandscape technology

UC Berkeley: Cleantech to Market ‐ Confidential 3

Page 4: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

WHAT HAS LIMITED THE ADOPTION OF CLEAN HYDROGEN?

The hydrogen landscape

Our technology Path to marketlandscape technology

O i• Overview

• Production

• Use

Di t ib ti• Distribution

UC Berkeley: Cleantech to Market ‐ Confidential 4

Page 5: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HYDROGEN IS EVERYWHERE

– The most abundant chemical element on earth

– Requires transformation to isolate hydrogen gas

H

– Energy source and chemical constituent

– Clean burning, future of energy?

UC Berkeley: Cleantech to Market ‐ Confidential 5

Page 6: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HYDROGEN IS MAINLY PRODUCED FROM FOSSIL SOURCES…

U.S. PRODUCTION(bil kg/year)

Electrolysis 0.3~$4/kg

(SMR) Steam methane reformation

H2

~$1/kg reformation 6.9

UC Berkeley: Cleantech to Market ‐ Confidential 6

Sources: 2008 National Hydrogen Association, US Department of Energy, Google Images

Page 7: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

…AND MAINLY USED IN OIL AND CHEMICAL PRODUCTION

U.S. PRODUCTION

H FCVLight FCVsUtilitiesStationary fuel cellsU.S. USE

(bil kg/year)

Electrolysis 0.3 Other 0.2AerospaceFoodHeavy FCVs

Other

Electronics

Chemicals

(SMR) Steam methane reformation

Other Chemicals2.4

Refining

H2

reformation 6.9 Metals

Refining4.6

UC Berkeley: Cleantech to Market ‐ Confidential 7

Sources: 2008 National Hydrogen Association, US Department of Energy

Page 8: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HYDROGEN IS EXPENSIVE TO DISTRIBUTE AT LOW VOLUMES

($/k )$2.00pipeline

large onsite

Price ($/kg)

large onsite

small onsite

generators

$6.00

$10.00

liquid

tube trailer

$40.00cylinders<200 2,000 20,000 200,000 kg

UC Berkeley: Cleantech to Market ‐ Confidential 8

Sources: Air Products Diagram, EPRI Briefing to DOE, National Academies Press (assuming gas at 60 degrees F and 1 atmosphere)

Page 9: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

CLEAN HYDROGEN HAS NOT MET EXPECTATIONS BUT CAN BE COMPETITIVE

Electrolysis has not replaced carbon‐intensive SMR

High costs and limited infrastructure are barriers to adoption 

Opportunity at small distributed scale where willingness to payOpportunity at small distributed scale where willingness to pay is high

UC Berkeley: Cleantech to Market ‐ Confidential 9

Page 10: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

LBNL CATALYST LOWERS ELECTROLYSIS COST

The hydrogen landscape Path to market

Our technologylandscape

El t l i

technology

• Electrolysis

• A new catalyst

• Cost advantage

UC Berkeley: Cleantech to Market ‐ Confidential 10

Page 11: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

ELECTROLYSIS SPLITS WATER INTO HYDROGEN AND OXYGEN

Hydrogen OxygenHydrogen Oxygen

4H2O + 4e– 2H2O ‐ 4e–

2H2 + 4OH– O2 + 4H+

WaterCatalyst

Cathode Anode

Power supply

UC Berkeley: Cleantech to Market ‐ Confidential 11

pp y1.23 V

Page 12: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

CATALYST IS MAJORITY OF ELECTROLYZER CAPITAL COST

Electrolyzer capital cost breakdown

2% 2%

5%

5%

2%3%

Catalyst

Membrane

6%JDL

Bipolar Plate

Seal

CatalystCatalyst 77%

Balance of System

AssemblyCatalyst

UC Berkeley: Cleantech to Market ‐ Confidential 12

Sources: REVIEW OF SMALL STATIONARY REFORMERS FOR HYDROGEN PRODUCTION (Dr. Joan M. Ogden); NREL Electrolyzer Capital Cost study 

Page 13: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

LBNL CATALYST HAS SIGNIFICANT ADVANTAGES OVER PLATINUM

MolyOxo catalyst Standard catalyst

Material cost $1/oz $1800/oz$ / $ /

Water quality No treatment Treatment

Durability Robust Easily fouled

Energy  ~50% ~65%gyConversion

UC Berkeley: Cleantech to Market ‐ Confidential 13

Source: Nature May 2010

Page 14: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

IMPACT OF CAPITAL COST REDUCTION GREATEST AT SMALL SCALE

H2 d ti l li d t ($/k ) i id l t l iH2 production levelized cost ($/kg) using grid electrolysis

Capital cost 66% 53% 35%$20 00

$18.43 

$16.00 

$18.00 

$20.00 

$/kg $10.31 

$10.00 

$12.00 

$14.00 

Electricity Costs

Fixed O&M$

$6.83 

$

$6.00 

$8.00 

$ Fixed O&M

Capital Costs

$0.00 

$2.00 

$4.00 

UC Berkeley: Cleantech to Market ‐ Confidential 14

Source: NREL Electrolyzer Capital Cost study 10 kg/ day 100 kg/ day 1000 kg/ day

Page 15: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

LBNL CATALYST MAKES ELECTROLYSIS COMPETITIVE AT SMALL SCALE

$6,000

Capital Cost Comparison (SMR Vs Electrolyzer)

$5,000 

$6,000 SMR (Small scale)

Electrolyzer 

$3,000 

$4,000  (existing)

Electrolyzer (with LBNL catalyst)

$/kW

$1,000 

$2,000 

$0 

10 kg/ day 100 kg/ day 1000 kg/ day

UC Berkeley: Cleantech to Market ‐ Confidential 15

Sources: Review of Small Stationary Reformers for Hydrogen Production (Dr. Joan M. Ogden); NREL Electrolyzer Capital Cost study 

Page 16: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

REDUCTION IN CATALYST VOLTAGE INPUT HAS LARGEST IMPACT ON COST OF PRODUCED H2

Baseline Cost ($18.43)

Voltage input (0.5V to 1.5V)

Cost of electricity (+/‐ 30%) 

Catalyst cost reduction (‐90% to ‐25%)

$15.00 $16.00 $17.00 $18.00 $19.00 $20.00 $21.00

UC Berkeley: Cleantech to Market ‐ Confidential 16

Source: C2M Team Analysis based on electrolysis cell potential

Page 17: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HOW SHOULD THE LBNL CATALYST BE BROUGHT TO MARKET?

The hydrogen landscape Path to market

Our technologylandscape

A li ti fit

technology

• Application fit

• Competition

• Optimal business model

P f t t• Performance targets

UC Berkeley: Cleantech to Market ‐ Confidential 17

Page 18: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

SMALL SCALE APPLICATIONS OFFER GREATEST OPPORTUNITY

Insight Market CriteriaInsight Market Criteria

Large decrease in capital cost Markets where capital cost is high percent of overall costpercent of overall cost

SMR has strong cost advantages at  Niche markets where large scale electrolysis has advantage

Feed stock electricity costs drive economics

Markets with access to cheap electricity

UC Berkeley: Cleantech to Market ‐ Confidential 18

Page 19: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

LBNL CATALYST ALIGNS BEST WITH FOUR APPLICATIONS

Ammonia Production

Oil Refining

Metal Fabrication

Barriers to entry Semiconductors

Framework Criteria

Metal Fabricationentry

Switchingcosts

/

Food & Bev

Commercial Marine

Yachting

Hydrogen Peroxide

Float GlassSubstitution/ competition

Volume usageFuel Cell Vehicles

g

Medical Drugs

Grid Storage

Market size/ potential

B t Fit A li tiBest Fit Applications• Distributed small scale energy generation• Power generator coolant• On‐board ICE hydrogen booster

UC Berkeley: Cleantech to Market ‐ Confidential 19

O boa d C yd oge booste• Oxygen concentrator

Page 20: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

CASE STUDY: POWER PLANT COOLING

d l h h l h f d

Strengths

Hydrogen gas circulates within thermal generators to remove heat from windings

+ Access to low cost electricity+ Volume output alignment+ Exceeds payback criteria+ Growth in Asia energy demand+ Thermal conductivity properties

Limitations

– Switching costs– Best with coal and natural gas

Market Details

• H2 Market Size:  2011: 25M 2020: $100M1

• Avg. H2 Purchase Price: $50/kg H2g– Limited benefits of being ‘green’

g 2  $ / g 2• Key buyers: Large utilities, Independent Power Producers

• Potential partners:  GE, Siemens, ABB

UC Berkeley: Cleantech to Market ‐ Confidential 20

Sources: 1 – Cost Model (Assumed $200k per plant, 30% of plants, and 30% of electrolyzer), Google Images, GE Energy

Page 21: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

ADDRESSABLE MARKET SIZE TO GROW FROM $400M TODAY TO $32B IN 2020

Energy Source: Fuel Cell Vehicles 

Energy Source: Mobile Military

Energy Source: Telecom 

O C

Hydrogen ICE booster

Energy Source: Materials Handling 2020

2011

Power Plant Cooling

Oxygen Concentrator

$0 $5,000 $10,000

Total addressable market size (in USD millions)

UC Berkeley: Cleantech to Market ‐ Confidential 21

Source: C2M Team Analysis based on various market potentials

Page 22: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

NEW CATALYSTS ARE STARTING TO TRANSFORM ELECTROLYSIS MARKET

Hydrogen Gas($40B)($40B)

ElectrolyzerEquipment($300M)

CatalystProducer($200M)

UC Berkeley: Cleantech to Market ‐ Confidential 22

Sources: Freedonia, Proton Energy Systems, Johnson Matthey, Google Images

Page 23: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

MOST ATTRACTIVE BUSINESS MODELS ARE TO LICENSE OR PRODUCE THE CATALYST

Addressable market

Cost of entry

Value of technology

Expertise/ ability to 

d

Time to Marketmarket entry technology

produceMarket

Produce H2 Produce electrolyzers

Produce catalyst License to electrolyzer 

manufacturer License to catalyst License to catalyst 

producer

UC Berkeley: Cleantech to Market ‐ Confidential 23

Page 24: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

EMERGING FORCES WOULD RAPIDLY CHANGE THE ADOPTION OF ELECTROLYSIS

Low cost intermittent

Large scale production of fuel

Global prices for intermittent 

renewable sourcesproduction of fuel 

cell vehiclesGHG emissions

UC Berkeley: Cleantech to Market ‐ Confidential 24

Sources: Google Images

Page 25: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

FURTHER RESEARCH WILL IMPROVE COMMERCIAL POTENTIAL

• Basic research– Reduce thermodynamic over potentialy p

– Research impacts of direct solar energy

• Applied research– Develop a complete electrolysis cell

– Research the use of the catalyst for fuel cellsy

• Prototype– Expand beyond lab scale

UC Berkeley: Cleantech to Market ‐ Confidential 25

Sources: Google Images

Page 26: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

LOW COST CATALYST CREATES VALUE FOR SMALL SCALE DISTRIBUTED HYDROGEN GENERATION

The hydrogen landscape

Our technology Path to marketlandscape technology

Cost & infrastructure barriers have limited electrolysis adoption

Lower capital cost catalyst = small scale advantage

License or produce catalyst for growing markets

UC Berkeley: Cleantech to Market ‐ Confidential 26

Page 27: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

THANK YOU

Venture Capital Research Catalysis

Equipment Producers Hydrogen Providers Hydrogen Users

UC Berkeley: Cleantech to Market ‐ Confidential 27

Page 28: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

QUESTIONS & ANSWERS

UC Berkeley: Cleantech to Market ‐ Confidential 28

Page 29: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

SUPPORT SLIDES

UC Berkeley: Cleantech to Market ‐ Confidential 29

Page 30: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HOW DID YOU GET TO UC‐BERKELEY TODAY?

• “Bush touts benefits of hydrogen fuel” –Feb. 2003

• “'Hydrogen Highway' Plans Riding on Misconceptions” – 2003

• Governor Schwarzenegger signs executive order to construct hydrogen highway – Apr. 2004

• “Has Schwarzenegger's hydrogen highway gone bust?” – 2009

• “R.I.P. hydrogen economy? Obama cuts y g yhydrogen car funding” ‐ 2009

UC Berkeley: Cleantech to Market ‐ Confidential 30

Sources: CNN, Scientific American, LA Times, EXECUTIVE ORDER S‐7‐04 

Page 31: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

HOW DOES LBNL CATALYST FARE AGAINST PLATINUM ON A $/KG OF PRODUCED HYDROGEN BASIS?

$19.64 $18.43 

$18.00 

$20.00 

$14.00 

$16.00 

$

$8 00

$10.00 

$12.00 Fixed O&M

Electricity Costs

Capital Costs

$/kg

$4.00 

$6.00 

$8.00 

$0.00 

$2.00 

Pt Catalyst LNBL Catalyst

UC Berkeley: Cleantech to Market ‐ Confidential 31

Pt Catalyst LNBL Catalyst

Page 32: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

PRIORITY APPLICATIONSPower Plant Cooling ‐ Access to low cost electricityPower Plant Cooling Access to low cost electricity

‐ Low volume demands ‐ Currently customers pay > $40/kg for delivered H2

Hydrogen booster for  ‐ Increased mileage by 15‐20%diesel engines ‐ No substitute technology

‐ Relatively inexpensive retrofits required

Materials Handling (Forklifts)

‐ Large addressable market (>$1 billion)Adoption of Fuel cell powered forklifts has increased in last(Forklifts) ‐ Adoption of Fuel cell powered forklifts has increased in last 2 years

Military (Mobile) ‐ Large market open to trying new technologies ‐ Unique needs unmet by other technologies (Weight of q y g ( g

battery pack, noise factor)

Telecom ‐ Very large market that has severe power disruption issues in developing regions (70% of towers have diesel gensets)

‐ Fuel Cells and other renewables starting to become more pervasive

‐ Easier to transport water than fossil fuels

Refueling stations for  ‐ Need for H2 refueling infrastructure to support penetration 

UC Berkeley: Cleantech to Market ‐ Confidential 32

Fuel Cell Vehicles of FCVs‐ Lack of competition in small scale home refueling systems

Page 33: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

d d d f l l f l ll h l

CASE STUDY: FCV HOME REFUELING

Strengths

Hydrogen gas produced to refuel personal fuel cell vehicle

+ Large potential market+ EV stations priming market+ Expansion in home PV systems+ Limited set of buyers

Limitations

– No market today– Could increase cost of ownership

Market Details

• H2 Market Size :  2011: 0M 2020: $XM• Avg. H2 Purchase Price: $50/kg H2p

– Buyers have lots of leverageg 2  $ / g 2

• Key buyers: Auto Manufacturers• Potential partners:  Utilities, Smart Grid technology companies

UC Berkeley: Cleantech to Market ‐ Confidential 33

Source> Google Images

Page 34: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

d f d l d h d d d b

CASE STUDY: OXYGEN CONCENTRATOR

Strengths

Oxygen is used for medical support and hydrogen is used to power distribution

+ High growth market+ Uses both H2 and O2 output+ Low‐cost catalyst needed to change dynamics

+ Size (produce 5‐10 Liters of O2)

Limitations

– Must compete with PSA on cost– Limited electrolysis solutions

Market Details

• Market Size:  2011: $380M 2020: $2,000M• Avg. Equipment Price: $800y

– Must receive FDA approvalg q p $

• Key buyers: Medical supply; Equipment• Potential partners:  Hospitals, Insurance

UC Berkeley: Cleantech to Market ‐ Confidential 34

Source> Google Images, Oxygen Concentrator market WinterGreen Research

Page 35: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

EQUIPMENT MANUFACTURERS AND CATALYST PRODUCERS SHARE COMMON MARKET ENTRY

Factors of Competition

Hydrogen Gas

Electrolyzer Equipment

Catalyst ProducerFactors of Competition q p

Market Size Lifecycle Stage Lifecycle Stage Market share concentration Capital Intensity Cost Structure Average

Attractiveness Positive Neutral Negative

UC Berkeley: Cleantech to Market ‐ Confidential 35

Attractiveness Positive Neutral Negative

Page 36: Hydrogen from Water€¦ · Energy & Cleantech Finance focus ... – Energy source and chemical constituent – Clean burning, future of energy? UC Berkeley: Cleantech to Market ‐Confidential

EXTERNAL FORCES MAINTAIN INDUSTRY STATUS QUO

High impact Petroleum Price VolatilityL t l Price Volatility

Clean Energy Investment

Low natural gas prices

US Shifts Focus Away From Hydrogen

International Government Support

Carbon MarketsX

Japan Nuclear Explosion

BP Gulf Oil Spill

Clean Energy Fund Performance

Climate Change Support

PositiveInfluence

Negative Influence

Low ImpactExplosion

Neutral Influence

UC Berkeley: Cleantech to Market ‐ Confidential 36