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HYDRATION
NATION
A Facilitator’s Guide to Water
Page 2 of 41
In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Our Vision Canadians recognize that Science1 is intrinsic to their lives and acknowledge the
fundamental importance of a quality Science education to prepare young people for our
rapidly changing world.
Our Mission Let’s Talk Science is striving
to improve Science literacy through innovative educational
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through Science education. 1Our Science includes life and physical sciences, technology, engineering and mathematics.
Let’s Talk Science National Office Health Sciences Addition, H004 The University of Western Ontario London, Ontario, Canada N6A 5C1 Tel: 519-474-4081 Fax: 519-474-4085 Email: [email protected] www.letstalkscience.ca Charitable Number: BN88540 0846 RR0001
Developed by Maria Boetzkes, Laura Brown, Kimberley Chung, Glenda Lloyd and Susan O’Leary For ©2002 Let’s Talk Science
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Used under License.
Page 3 of 41
In-class workshops, Hydration Nation
©2002 Let’s Talk Science
A. Description of Workshop
Grade for Workshop/
Appropriate Age
This activity is designed
for use in Grade 6-9
classrooms or with
children ages 11-15.
Overview of Workshop
Students will join the best hydrological research
team in Canada, to survey a newly discovered island.
They will determine drinking water quality on the
island through testing the chemistry and physical
properties of the main bodies of water and
comparing results to the Canadian drinking water
guidelines. Students will make recommendations on
which water source could be used for drinking and
what should be done with the island.
Overall Objectives
Students will realize the value
of water as a natural
resource.
Students will gain a basic
understanding of the
processes that must be
carried out for analysis of
potable water.
Students will realize human
impact on water resources
and ways to minimize negative
impacts.
Science Topics
Water
Chemistry
Physical
Attributes
of Water
Fluids
Human
Impact
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
B. How to Run This Workshop
Physical Requirements
Overhead Projector
6 groups of desks or tables
Materials and Set-up – 2 Stations/Activity for #1, 2 & 3 (written down as
materials for just one station, so you know what is needed per station.
Double the materials for two stations)
See next page Note: For more detail, see Kit List
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Activity #1 – Water
Chemistry
Activity #2 –
Physical Properties
Activity #3 –
Hydrometers
Activity #4 –
Environmental
Crisis
Introduction/
Wrap Up
1A pH Testing of water
samples
2A Erosion and
Deposition
*Cut ruled paper –
2/group
6 Plastic tubs Introduction
*Scotch tape Laminated river activity 50 Stainless steel
(rustproof) round
head nuts (6/32 x ½”)
Buzzer or alarm Map
transparency
2 Types of pH paper cut
in half (1 – 14 and 4.5 –
8.5)
Washable marker 20 Test tubes 6 Oil spill info.
packages: pictures
and cleaning
materials
Story
*Paper towel Erosion/Deposition Task
Card
2 – 250 mL (1 cup)
measuring cups
Overhead
projector
pH Testing of Water
Task Card 2B Turbidity 4 Glass cylinders *Paper towels Questions
Laminated pH scales 3 Secchi disks *Fine grained salt (in
2 containers)
*Cooking oil
(couple
capfuls/container)
*Data Report
(1/group)
3 Wooden spoons
*6 Labelled plastic
bottles (3 water samples,
washing soda (1 c water, 2
tsp washing soda), lemon
juice and distilled or
deionized water)
Sukita River= tap water
Camada Lake= 1/2 tsp
baking soda in 1 L of
distilled water.
Kisula Bog= PC Brand Free
& Clear white grape, low-
cal sparkling water
beverage with aspartame
*3 Water samples-
Sukita- 1Tbsp sand
Camada –1 Tbsp topsoil
Kisula – 1 Tbsp sand, 1
Tbsp topsoil, 1 Tbsp peat
Pre-made solutions:
Kisula- 24 tsp salt + 4
c water
Sukita- 12 tsp salt + 4
c water
Camada- no salt + 4 c
water
*6 Zip-bags with
cleaning materials:
straws, string,
cotton balls,
pipette
Laminated map
with river
activity on back
Ruler 2 Shaking bottles Scissors Wrap Up
Turbidity Task Card 2 – 5 mL (1 tsp)
Measuring spoons
*Oil colouring or
cocoa
Chart (drawn on
chalkboard) 2C Filtration
*Filter materials: filter
paper, cotton balls, sand,
gravel
-screen door fabric,
elastics (in all – one
without filter materials
labelled control)
Real hydrometer
example
1 Pipette
4 Funnels (2 labelled
“Dry”, 2 labelled
“Wet”)
1 Small clear
plastic cup
1B Water Quality
Guidelines
Measuring cup (50 mL) 2 Hydrometer Task
Cards
1 Plastic test
tube Wooden spoon
Lab Report /Instructions
Task Card
Filtration Task Card 1 Bottle for water Food colouring
Canadian Guidelines
Chart
5 Filtration bottles
(clear)
Waste bucket 1 L bottle
*Kisula Bog sample to
filter (recipe above)
*Consumable items
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Timing of Activity
Part of Workshop: Suggested Timing: Cumulative Timing:
General Introduction 5 min. 5 min.
Introduction to Topic 20 min. 25 min.
Explanation of Stations 10 min. 35 min.
Activity #1 20 min. 55 min.
Activity #2 20 min. 75 min.
Activity #3 20 min. 95 min.
Activity #4 20 min. 115 min. (OPTIONAL)
Wrap-up 15 min. 130 min
C. Introduction to Topic
Objectives of Introduction
Discover prior knowledge of water with questions touching on human use,
measurements, accessibility and properties.
Give students scenario to understand objective of workshop.
Suggested Discussion, Q & A
Today our workshop is going to look very closely at water. To help make the
decision about who will be going on assignment today, the government has decided
to test your present knowledge about water.
Water is everywhere! Can anyone tell me 5 different ways water affects our lives? Survival, Recreation, Cleaning, Power Generation, Growing Food …
Water Trivia game - get into 6 groups; each group gets one question to themselves
to discuss and answer.
DELIVERY HINT: Keep the game going quite quickly. In game
show style, give other groups a chance to agree or disagree.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Group questions:
1. What % of the human body is water? (a) 25-30%
(b) 40-50%
(c) 60-80%
(d) 90-100%
Answer: c
Our bodies are made up of about 70% water. Water makes up about 75%
of the brain and 83% of blood.
2. How much fresh water in the world is accessible for drinking? (a) 0.001% (1/1000 of a percent)
(b) 2.5%
(c) 10%
(d) 50%
Answer: a
Although about 2.5% of the world’s water is fresh water, the majority of
that is locked up in glaciers and ice.
3. How much of the world's fresh water does Canada have? (a) 10%
(b) 20%
(c) 40%
(d) 60%
Answer: b
4. How much water does a person need each day to stay healthy? (a) 0-0.5L
(b) 1-2L
(c) 3-4L
(d) 5-6L
Answer: b
To make this question visual, you could hold up a 1L or 2L container, to
show the relation. We get the water we need through plain water, juices,
other drinks and even the food we eat.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
5. How much water does the average person use each day? (a) 0-5L
(b) 5-25L
(c) 50-150L
(d) 200-800L
Answer: d
Health Canada says that the average North American uses 650L of water
per day. If you think about all the water we use flushing a toilet (up to
20L, depending on the toilet), or taking a shower at 11-20L per minute, it
becomes easy to see why this is the case.
6. How much water does it take to produce a loaf of bread? (for the whole process from growing the wheat to baking the bread) (a) 2L
(b) 10L
(c) 100L
(d) 600L
Answer: d
Now that we know you can handle it, here is what’s happened.
(Put up map transparency.)
Scenario:
The Canadian satellite, Radarsat, has discovered a new tropical island.
There are currently no people on the island and it has an active and healthy
ecosystem that has never been disturbed.
The best environmental scientists in the world have been assembled to study
the island. The Canadian government has chosen your team of hydrologists (people
who study water) to represent Canada.
You will carry out this assignment by testing and using natural water
resources in a sustainable manner. Your survey will include analysis of three bodies
of water on the island – Camada Lake, Sukita River and Kisula Bog – using three
different quality tests. You will be filling in a data report as you go. At the
completion of your assignment, you will make recommendations about the potability
(drinkability) of water on the island and, with other scientists, on the future use
of the island.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
D. Activities
Objectives of Activity
Understand acids and bases.
Test pH of various samples and the three main water sources.
Analysis of other water quality factors related to the Canadian guidelines
for drinking water.
ACTIVITY #1A and #1B – WATER QUALITY
GUIDELINES AND pH TESTING OF WATER SAMPLES
(15 min. + 5 min. clean up)
Use Lab Report Task Card, Canadian Water Quality
Guidelines Task Card and pH Testing Task Card
DELIVERY HINT: Have stations already set up and explain
the Task Cards before letting them start.
DELIVERY HINT: Use the Activity “Suggested Q & A”
as introduction to stations.
DELIVERY HINT: Hand out the laminated maps and
Data Sheets (Reports) to each group after
introduction to stations.
CHOICE: Activity #4 – The Oil Spill – is meant to be
a surprise. Throw it in after students have
completed 1 or 2 stations, depending on the timing of
your workshop. If you don’t have enough time, you
can omit this activity.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Suggested Instructions, Q & A
What is pH? Where is the term used? pH is a scale used to measure how acidic substances are. It is used in
chemistry.
Why do we care about the pH of water? The Canadian guideline for the pH of potable (drinkable) water, is 6.5 – 8.5.
Our body can tolerate different levels of acidity – we can drink fruit juices
and pop which have pH between 2.5 and 4.0 - but it is easier on our bodies if
it is in the guideline’s range. We also need to understand pH for the effect it
has on animals and plants, pool water, pipes, etc.
At this station, you are going to determine pH of various samples and then analyze
data from a lab report using the Canadian guidelines for drinking water.
Your first task as a group, is to test a variety of solutions to understand and to
determine the pH of different solutions, including the 3 water samples. You will be
using a strip of pH paper with a range of 1-14 per sample (orange paper). You will
tape these to your data report along the pH scale. Remember to label which paper
tested which solution.
Next, as a group, you will test only the water from the 3 areas on the island again,
using one strip of pH paper with a range of 4.5 - 8.5 for each sample (green paper).
This will give you a more accurate pH measure. Record your groups results by
taping the paper to your data report and writing down the pH value for each water
sample.
REMEMBER you need 6 orange papers and 3 green papers!
After you have determined the pH of your 3 test water samples, use the
CHOICE: If the class seems to know a lot about pH, feel free to
give them the full definition – A measure of hydrogen ions in a
solution. More hydrogen ions means a solution is more acidic.
For facilitator information, an even more complicated definition is
- pH is actually the measure of hydronium ions (H3O+) because H+
reacts with H2O. This definition is quite complex so it is easier
for students to understand hydrogen ions.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Hydration Nation Lab Report results, along with the Canadian Guidelines for safe
drinking water to analyze the 3 water samples for other important water quality
factors –bacteria, nitrates and fluoride levels.
The guidelines will provide some information about the sources (origins) of these
potential pollutants, their effects on humans, and the acceptable levels of these
factors in drinking water. Be sure to look at the maximum acceptable levels for
each factor!
Rank the water samples in terms of pH, coliform bacteria levels, nitrate levels and
fluoride on the Data Sheet. You might want to consider the effects and
treatments of each factor. For example, a high pH level would be easier to
correct than a high nitrate level. Circle a 1 on the chart if you think that the
sample represents the best level for drinking water, a 2 for the next best, and a 3
for the poorest sample.
Objective of Activity
Look at the effects of watersheds, erosion and deposition on drinking water
quality.
Show methods to clean water.
Suggested Instructions, Q & A
What is a watershed? An area that collects all the surface and ground water and allows it to drain
to the same point (eventually to a body of water such as a lake or an ocean)
Everyone look at the map on the overhead and find the watershed on the island.
As the water runs down the terrain of the watershed, it collects different
materials and carries them as well. Does anyone know what it’s called when moving water picks up pieces of the land?
ACTIVITY #2– PHYSICAL PROPERTIES OF WATER
(15 min. + 5 min. clean up)
Use Erosion and Deposition Task Card, Turbidity Task
Card and Filtration Task Card
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Erosion. The opposite of that is deposition - when the water lets things go
and they settle out, usually at slower points in the flow of water.
When erosion occurs, it makes the water more turbid. This means that there is
more material being held in the water, decreasing the water quality for drinking
and many other things. At this station you are going to examine how materials get
into the water and some methods to clean the water, to make it potable.
First, based on the flow speed of the rivers, determine where erosion and
deposition processes are happening and mark that on your sheet. Compare your
sheet to Sukita River on our island and determine where these processes are
happening.
Next, move to the turbidity test where we will be using a Secchi disk. For this
test, you will need to stir up the sample you will be testing and slowly lower the
Secchi disk into the water until you can’t see it anymore. You need to look straight
down at the disk to determine where it disappears. Once it has disappeared, pinch
the string at the surface of the water and pull it up slowly. Measure the length of
string between the disk and your finger and record it on your data report. The
shorter the measurement, the more turbid the water.
Lastly, we know that we will probably have to filter the water on the island in some
way to make it potable. We need to decide, using materials we have found on the
island, how to build a filter that will remove the most debris from the water. Stir
the water and put 50 mL through each filter. Start with the control filter (the
one with only screen) and compare each of the other filter materials to that one.
Observe what happens and decide what order you would put the filter materials in,
to remove the most material possible to create clean drinking water. When you’re
done, pour the filtered water back into the sample water.
DELIVERY HINTS: Have extra Secchi disks ready – they
may break. Wrap sand and gravel in nylon to avoid messes.
Also, you don’t need to change filtration materials between
groups.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
Objective of Activity
Introduce hydrometers.
Fluid principles- buoyancy and density.
Suggested Instructions, Q & A
Since we are on an island, surrounded by ocean, what kind of water is all around us? Salt water – 97% of the Earth’s water is salt water.
Can we drink salt water? No – drinking salt water actually dehydrates us. Our body tries to keep the
concentrations of things equal inside and outside of our cells. To keep our
body balanced, cells lose water to try to dilute the additional salts coming in.
This takes water away from other parts of our body that need it.
Your team must determine which water on the island is fresh and which is salty.
You’ll be using an instrument called a hydrometer. It is used to measure density
and we can use this to help us determine how much salt there is in the water.
Show real hydrometer.
What is density? How much “stuff” there is in a certain amount of space (ex. lead vs.
Styrofoam – if we have the same volume of lead and Styrofoam, lead is more
dense because it has more “stuff” in it).
Why would we use an instrument that measures density to help us figure out if there’s salt in the water? Salt will make the water more dense – adding salt to fresh water, puts more
“stuff” in it.
ACTIVITY #3 – HYDROMETERS
(15 min. + 5 min. clean up)
Use Hydrometer Calibration Task Card
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In-class workshops, Hydration Nation
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Your team’s hydrometers broke on the trip to the island, so you have to make them
from the materials you have. Each group is going to make 2 hydrometers by taking
a test tube and putting 5 round head nuts and a piece of grid paper into it.
To get an accurate reading on our homemade hydrometer, we need to calibrate it. Does anyone know what that means? Create a scale of known values on our unmarked hydrometer
To calibrate it, you are going to test it in a variety of solutions that you make
based on the recipes you are given. This way, we will know how much salt is in the
water and therefore the approximate density of the water. To test the
hydrometer, place it gently in the solution and watch it float. Does anyone know the scientific principle that explains why our hydrometer floats? Buoyancy – an object pushes water out of the way (displaces it) through
gravity. In return the water exerts a lifting force that we call buoyancy.
This works as long as the object has less mass than the water it has pushed out of
the way. If it has more it would sink.
Once the hydrometer is steady, determine where the level of water is compared to
the grid paper and note this on the grid paper on your data sheet. Be careful when
you look at the water level. You will see a curve called a meniscus. Take the lowest
point of the water in the meniscus as your measurement. Repeat this for the
solution you make.
CHOICE: You can use pre-made hydrometers if you
want – add nuts, grid paper and seal with wax.
DELIVERY HINT: Draw the meniscus on the board as you
talk about it (diagram on task card).
DELIVERY HINT: Pre-make the lake, river, and bog solutions
in kit (good for at least 10 workshops).
Kisula Bog - 1.10 g/mL 24 tsp salt + 4 cups of water
Sukita River - 1.05 g/mL 12 tsp salt + 4 cups of water
Camada Lake - 1.0 g/mL no salt + 4 cups of water
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In-class workshops, Hydration Nation
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When you’ve calibrated your hydrometer, test the three water samples from the
island. Be sure to record your results.
Objective of Activity
Introduce an environmental crisis to the program.
Show human impact on ecosystems.
Show different methods of clean-up for oil spills.
Suggested Instructions, Q & A
Set off alarm or buzzer.
Oh No!! There has been an environmental crisis on the island. A plane had to make
an emergency landing and has landed in the Slippery Slope watershed area. No one
was hurt, but oil is leaking and entering the water system. It is already having a
serious effect on the animals and plants that live in and around the lake, as well as
drinking water quality. You must act immediately to minimize the impact this spill
will have on the environment. Using the materials you have, contain the spill and
clean as much of it as possible. If you would like some hints, look at the
information sheet to see how real oil spills are handled. Remember – contain, then
clean!
(Hand out tubs with water and oil and the materials needed for the activity.)
ACTIVITY #4 – ENVIRONMENTAL CRISIS
(15 min. + 5 min. clean up)
Use Oil Spill Information Package and Pictures, Oil Tubs,
Incident Report Form, Clean Up Materials
CHOICE: This station can be omitted if you don’t have
enough time. If you use it, it should be added in the middle
of the program, after at least one other station is done and
preferably after two – whatever works in the time you have.
DELIVERY HINT: Debrief immediately after activity.
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In-class workshops, Hydration Nation
©2002 Let’s Talk Science
How did you contain the oil spill? In real spills, the oil is contained by booms that encircle the spill. This keeps
it from spreading while it is cleaned up.
What worked best to clean the spill? Was it just one way, or a combination? Workers use a combination of materials to clean oil spills. Absorbents are
used to help soak up the oil (like cotton balls) (you can show example of real
absorbent here). Vacuums are used to skim oil off the surface and get into
cracks.
Hopefully this gives you an idea of how badly oil spills can damage an environment
and why it’s important to clean them up right away.
E. Wrap-Up Suggested Q & A
What were your findings at each of the stations on the quality of the three possible fresh water sources? Let’s start with erosion.
Based on what you learned about erosion and deposition, did you notice a pattern as to where these processes occur on the example rivers? on Sukita River? (Put up
river answers transparency, then island map transparency)
Erosion occurs on the outside of a curve and deposition occurs on the inside.
Water tends to pick up speed along the outside of the curves and slingshots to
the next curve, thereby producing the “S”- shape of meandering rivers.
Use the chart below to help tie all findings together. You can use lines beside the
chart for other pHs and a filter picture for the complex filter question.
1 = best quality, 3 = worst quality
DELIVERY HINT: When charting the findings, you may get
some different answers. The difference could just be
judgement of a group on a particular test. Use this as an
opportunity for discussion.
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Water
Sample
Physical
Properties
Hydrometers Water Chemistry
Turbidity Salinity pH Bacteria Nitrates Fluoride
Camada
Lake
2 1 1 3 1 1
Sukita
River
1 2 2 1 2 2
Kisula
Bog
3 3 3 2 3 3
Which sample was the least turbid, and therefore most potable (the greatest Secchi depth is the least turbid). If you had to build a complex filter, what order would you like the materials in? Use picture of filter on board: Need to remove large particles first and smaller
particles last. A complex filter might look like this: Gravel, Cotton, Filter
Paper, Sand
Answers will vary and might bring up some interesting discussion.
What were the results in the salinity tests for our bodies of water? Which would be the best to drink? What were the pHs of the lemon juice, washing soda and deionized water? Lemon Juice: 2-3
Washing Soda: 9-10
Deionized/Distilled Water: 6-7
What were the pHs of our bodies of water? Which would you rather drink? Camada Lade: ~ 8-9
Sukita River: ~ 6 (or whatever the pH is of tap water)
Kisula Bog: ~ 4-5
When considering the water quality guidelines (for bacteria, nitrates, pH and fluoride), which water sample did you decide would be the best source for drinking water?
Looking at our overall findings from all of our stations, can you suggest which water would be the best for drinking? Inconclusive – Camada Lake ranks top for most of the tests, but the bacteria
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count is very high and could be very dangerous. Sukita River seems to be
average in everything. Kisula Bog will most probably be ranked last.
Are there any ways we could suggest to make the water more potable? Filtration, Desalinization, Water Treatment, etc… Have to look at costs and
resources to see if these are viable options.
We have now determined the water quality for this island. What would you recommend the governments do with the island? Should they colonize or leave it as a wildlife reserve? What other scientists would they have to consult to make an informed decision? Biologists, Geologists, Geographers, Planners, etc…
Throughout this workshop we have examined some of the physical and chemical
characteristics of water and its importance in our life and environment. Water is
important because it helps to maintain the Earth’s climate and dilute pollutants in
the environment. Since all living things are made up mostly of water, it is also
essential to all life. There is no life without water –what is the first thing we look for on other planets? Water – if there’s water, there could be life. Water Distribution Demo
We take water for granted and expect that there will always be a ready and
plentiful supply of fresh water as close as our kitchen sink. But let’s consider for a
moment the amount of fresh water that is readily available to us on the Earth.
Let’s say this 1 litre bottle represents all the water that exists on the Earth’s
surface.
(Show the students the bottle filled with coloured water.)
Unfortunately, about 97% of the Earth’s water is too salty to use. This leaves 3%
of the remaining water as fresh water.
[Pour 30 mL of water into a small clear plastic cup (small wine glass)].
Of this 3% fresh water, over ¾ of this is unavailable because it is frozen as
glaciers, the polar icecaps and icebergs.
(Pour 5 mL of the water into a clear plastic test tube.)
This 5 mL of water represents the liquid, fresh water on Earth. Of this liquid
portion, most is found in underground aquifers. In fact, it is estimated that there
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is about 40 times more fresh water in the ground than found in rivers, lakes and
streams.
Actually, most of the fresh water we use comes from surface water in the form of
lakes, rivers and streams.
(Using the pipette, pull out another 3 drops (1 mL) of water.) I have removed about 3 drops from the test tube. One of these drops represents
the water that is in the air and surface soil (squirt 1 drop on floor), and the last 2
drops represent the available, fresh surface water left on Earth (squirt on the
back of your hand).
Does this seem like much water to you? No
What can we do to make sure we always have a good supply of clean drinking water? Conserve water, reduce water consumption, stop pollution.
What station did you like best today? What did you learn today? Did you have fun?
F. Glossary
Acid/Acidic
Having a pH of less than 7.0, such as lemon juice or vinegar. It has high number of
H+ ions.
Acidity
The strength (concentration of hydrogen H+ ions) of an acidic substance; measured
as pH.
DELIVERY HINT: If you want to make this more dramatic,
you can let the last two drops fall into your mouth.
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Acid Rain
Rain with a pH of less than 5.6 which results from atmospheric moisture mixing
with sulphur and nitrogen oxides (SO2 and NOX) emitted from burning fossil fuels
or from volcanic activity; may cause damage to buildings, monuments, car finishes,
crops, forests, wildlife habitats and aquatic life. Most normal rainwater has a pH
of 5.6 to 5.8 – slightly acidic because of the carbon dioxide picked up in the
Earth’s atmosphere by the rain and converted to carbonic acid (H2CO3).
Algal bloom
A heavy growth of algae in and on a body of water; usually results from high
nitrate and phosphate concentrations entering water bodies from fertilizers and
detergents.
Alkalinity
The ability of water to neutralize acids. The sum of all the bases in water.
Base/Basic
Having a pH of greater than 7.0, such as lye or soap. Has high number of OH- ions.
Bioremediation
The use of oil-eating organisms (petrophiles) such as bacteria and fungi to remove
pollutants. These petrophiles need oxygen, oil and nutrients to survive and grow in
numbers. This involves the addition of fertilizing nutrients such as nitrogen and
phosphorus which stimulate the growth of the micro-organisms concerned, thus
promoting the process of bioremediation.
Blue Baby Syndrome
A condition called methemoglobinemia, in which the blood’s capacity for oxygen
transport is reduced, resulting in bluish skin discoloration in infants. Ingestion of
water contaminated with nitrates or certain other substances is a cause.
Booms and skimmers
Booms are used to surround and isolate an oil slick, or to block the passage of a
slick to a vulnerable or sensitive location. Boom types vary from inflatable
neoprene tubes to solid, but buoyant material. Most rise up about a metre above
the water line. Some are designed to sit flush on tidal flats while others are used
in deeper water and have skirts which hang down about a metre below the
waterline.
Skimmers float across the top of the slick contained within the boom and suck or
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scoop the oil into storage tanks on nearby vessels or on the shore.
Buoyancy
Buoyancy is a property of fluids (liquids and gases). When an object is floating in
water it actually pushes water out of the way or displaces it. The water exerts a
lifting force called buoyancy. Buoyancy depends on gravity and without gravity
there is no buoyancy.
Calibrate
Creating a scale of known values on an unmarked device.
Chemical Surfactants
A surfactant is a substance which lowers the surface tension of water. Detergents
widely used in a variety of cleaning and personal care products and to purify water
are surfactants.
Coliforms
Bacteria found in the intestinal tract of warm-blooded animals; can also come from
dead, decaying organic matter. It is used as an indicator of fecal contamination in
water.
Corrosion
A chemical reaction between a metal and the gases in the air.
Dehydration
An abnormal loss of body fluids.
Deionized Water
Water from which anions and cations have been removed by an ion exchange
process. Generally, deionized water is considered higher quality than distilled
water and is more economical to produce.
Density
Density is mass divided by volume. Mass is a measure of the amount of matter in
an object or the specific volume of liquid or gas – or how much stuff is in a certain
space.
Deposition
Settling of materials from fluids when they are too heavy, or the when flow of the
fluid slows down.
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Desalination
The process of removing dissolved salts from water. Desalination is a very
expensive process. It costs about $100 million ($US) to set up a desalination
plant. The cost for desalination is $2.70 ($1.70 US) per thousand gallons in the
first year and $3.30 ($2.08 US) per thousand gallons over the life of the plant.
Dispersants
Dispersants (chemical surfactants) act by reducing the surface tension that stops
oil and water from mixing. Small droplets of oil are then formed which helps
promote rapid dilution of the oil by water movements. Creating smaller droplets
increases the oil’s exposure to natural evaporation and bacterial action.
Dispersants are most effective when used within an hour or two of the initial spill.
They are not appropriate for all types of oils and all locations.
Distilled Water
Water which has had salts removed by distillation. It is very pure, but does contain
some dissolved gases.
Distillation
The process of heating a liquid or solid until it sends off a gas or vapour and then
cooling the gas or vapour until it becomes a liquid.
Erosion
Wearing away of land surface by wind or water. Fast water flow will erode the
land around and underneath the water.
Fluoride
A binary compound of fluorine with another element. It is added to some drinking
water to help prevent tooth decay, although it is found naturally in waters.
Groundwater
Water that infiltrates into the Earth and is stored in usable amounts in the soil
and rock below the Earth’s surface.
Hydration
To cause to take up water. Replenishing of body fluids.
Hydrometer
A hydrometer is used for measuring the density of fluids.
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Incrustation
A growth or accumulation of a substance that causes it to form a crust.
Meniscus
In a column of liquid, the surface that is curved. Measurements should be taken at
the lowest point of the liquid in the curve.
Methemoglobinemia
See Blue Baby Syndrome.
Mousse
The thick water and oil emulsion that the wave action of the ocean causes.
Natural Dispersion
Allowing oil spills to disperse by natural means such as wind, sun, current and wave
action.
Nitrates
Term used generically for materials containing this ion group, NO3-, made of
nitrogen and oxygen. Sources include animal wastes and some fertilizers.
Oil Spill
The accidental release of oil into a body of water, as from a tanker, offshore
drilling rig or underwater pipeline, which often presents a hazard to marine life
and the environment.
pH
A measure of the concentration of hydrogen ions in a solution; the pH scale ranges
from 0 to 14, where 7 is neutral and values less than 7 are acidic and values
greater than 7 are basic or alkaline; pH is an inverted logarithmic scale so that
every unit decrease in pH means a 10-fold increase in hydrogen ion concentration.
Thus, a pH of 3 is 10 times as acidic as a pH of 4 and 100 times as acidic as a pH of
5.
Potable
To be suitable for drinking. In this case it must meet standards that are set by
Health Canada. For standards, see poster accompanying kit.
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Salinity
Measurement of the dissolved salts in water. It is calculated by determining the
ratio of salts to water, and is expressed in the unit "parts per thousand" or ppt.
Secchi Disk
An instrument designed to measure water clarity. Used in deep bodies of water
such as lakes or ponds.
Surface Water
Precipitation that does not soak into the ground or return to the atmosphere by
evaporation or transpiration. It is stored in streams, lakes, rivers, ponds, wetlands,
oceans and reservoirs.
Tar ball
A lump or blob of solidified tar resulting from an oil spill, natural seepage from the
sea, or other source, that resists biodegradation and often washes up on beaches.
Turbidity
The measure of the amount of suspended particles in a water sample.
Watershed/Drainage Basin
An area that drains all surface run-off and groundwater into a river or stream
system that eventually has the same outlet such as a lake or the ocean.
G. Background Information
Activity #1 Natural rain: The purest rain, without any pollution has a pH of 5.6-5.8. This is
due to the presence of carbon dioxide in our atmosphere. Carbon dioxide dissolves
in raindrops in the sky and reacts with the water forming carbonic acid. The
reaction is:
CO2 + H2O H2CO3
carbon dioxide + water carbonic acid
pH and Bodies of Water:
A pH between 6.7 and 8.6 supports a well-balanced fish population. Most species
can tolerate values lower than 6.7 but only for a limited time. If the pH is not in
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this general range, plants and algae are also affected as it slows down their
nutrient uptake. As a lake ages, the pH typically drops. This can be due to the
decay of organic matter, which releases acids into the water along with the carbon
dioxide, released through respiration of fish and other animals.
Many factors can affect the pH of a lake. If the area has limestone or dolomite
bedrock, it will create a more basic lake or neutralize it if the area experiences
acid rain. Acid spills by industries affect the pH and also smelters and coal-
burning power plants put sulphur dioxide into the air, which creates sulphuric acid
in the atmosphere. Volcanoes can also do this. Sewage usually raises the pH of
water. The decay of sewage by bacteria also produces bases – ammonia, which is a
base, is a by-product of this process.
pH and Drinking water:
The pH of drinking water is normally between 6.5 and 8.5 depending on the source
of the information. In one paper, it stated that there are no specific health
effects on which to base limits for the pH of drinking water. The main purpose of
controlling pH is to produce water in which corrosion and incrustation are
minimized. These processes result from complex interactions between pH and
other parameters such as dissolved solids, dissolved gases, hardness, alkalinity and
temperature. Generally metal corrosion may be significant with a pH of less than
6.5 and incrustation and scaling problems usually occur with a pH above 8.5.
pH of some common substances:
2.2-2.4 Lemons
2.4-3.4 Vinegar
2.5-3.5 Soft Drinks**
3.0-4.0 Oranges
4.0-4.4 Tomatoes
6.3-6.6 Cow’s milk
6.4-6.9 Human saliva (during rest)
6.6-7.6 Human milk
6.5-8.0 Drinking water
7.0-7.3 Human saliva (while eating)
7.3-7.5 Human blood
7.6-8.0 Fresh eggs
7.8-8.3 Seawater
10.5 Milk of Magnesia
10.5-11.9 Household ammonia
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**Neat Fact – Pop contains citric acid, which is also found in oranges. Why is pop
more acidic? Pop contains dissolved CO2 which creates a lot of carbonic acid.
Nitrates:
Nitrogen is present in all proteins and is thus found in all living things. It can exist
as ammonia or NITRATE. In the nitrogen cycle, ammonia is changed to nitrite and
then to nitrates. Nitrogen is a key nutrient for all living things but if it is
excessive, it can cause problems. It can be harmful to wildlife and also to humans
(if there is too much in drinking water). Infants are probably the most susceptible
to its effects as it can cause methemoglobinemia (Blue Baby Syndrome). If the
concentration of nitrogen is high in a water source such as a lake, an algal bloom
could result which in turn, could be detrimental to the ecology of that water
source.
Coliforms:
Coliforms are bacteria that live in plants, soil or in the large intestines of many
animals. Fecal coliforms that are found in animals (including humans) have a
mutualistic relationship with the animal. The animal provides water, food and other
necessities to the bacteria, while the bacteria helps the animal make nutrients like
certain vitamins. 80 – 95% of the coliforms that leave the human body in dry
feces are of the species Escherichia coli, or E. coli. Fecal coliforms are used as
indicators of fecal pollution in the water in populated areas.
Fluoride:
Fluoride is naturally present in water but is increased by human use and waste.
High concentrations can cause spotting on children’s teeth and palatability may be
affected. Most urban drinking water in Canada contains fluoride in small amounts
to help prevent tooth decay.
Activity #2
Watersheds/Drainage Basins
An area that drains all surface run-off and groundwater into a river or stream
system that eventually has the same outlet such as a lake or the ocean. The terms
watersheds and drainage basins are interchangeable. These areas are defined by
divides (usually ridges of some kind), in which water flows in the opposite direction
on the other side. The major watersheds in Canada are illustrated below.
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Adapted from: Statistics Canada Website, http://www.statcan.ca/english/ads/11-
509-XPE/basin.htm April 22, 2002.
Rivers
Running water meanders (the “S” shape often seen in rivers). Straight running
water is the exception, not the rule. It often occurs when the substrate that
surrounds it is difficult to break up or erode, and usually describes mountain rivers
and streams. Meandering rivers (the name is taken from the Menderes River in
Turkey that twists back and forth on itself many times) illustrate the normal
progression of a river and changes the landscape. Erosion and deposition processes
create valleys, flood plains and more.
A meander is defined as a curve in the river (half of the “S” shape). The outside
curve of a meander always has faster running water and therefore erosion occurs
on this side. Often the water will under–cut the river bank creating a “cut bank”.
On the inside curve of a meander, the water tends to slow down and allow materials
to settle out or deposit. This creates a “slip-off slope”.
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Due to these processes, an older river will often cut itself off creating an oxbow
lake. This process is as follows (x=erosion, o=deposition):
Regular Curve becomes Water takes the least Oxbow Lake
Meandering more pronounced. resistant path. created from
River curve that is cut
off.
As the oxbow lake is cut off the processes start again in the main portion of the
river.
Turbidity
Turbidity is measured in NTU or Nephelometeric turbidity units. In North
America the turbidity of surface water ranges from 1NTU to >100NTU.
In Canada we have set goals of 1NTU as the quality of our drinking water. Levels
of up to 5NTU are acceptable if water disinfection and the microbiological quality
of the water is not compromised. In general, if we see a rise in turbidity there is
no corresponding increase in coliform bacteria (used to indicate dangerous
microorganisms). However studies by Health Canada have shown that during
periods of high water turbidity there is an increase in gastrointestinal illnesses.
Those with compromised immune systems are warned to boil their water at these
times.
How do we measure turbidity?
There are a variety of ways that turbidity can be measured. The one most
commonly used for drinking water uses a Nephelometer. This instrument measures
the light scattered at 90◦ to the incident beam. This is compared with a
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reference beam that is measured at 180◦. The ratio of these two readings is
electronically converted to NTU.
In deep water a Secchi disk is usually used. A measurement is taken of the depth
of water in which the Secchi disk just disappears from sight. Despite the
simplicity of this instrument it provides very reliable and repeatable data. The
Secchi depth is usually measured in meters. There is no easy way to convert
between Secchi depth and NTU. In theory these numbers are inversely related.
That is, the larger the Secchi depth the less turbid the water and therefore the
smaller the NTU.
What are the ways we deal with turbidity in our drinking water?
There are actually many ways we deal with turbidity in our drinking water. In large
part the methods are determined by the watershed. Areas of the country that
draw their water from lakes or rivers that are also used for transport or
recreation typically use intensive filtration and disinfection methods. In areas
such as BC, much of the water is drawn from watersheds that are inaccessible to
human activity. Therefore the water is naturally cleaner. During times of high run
off (that tends to cause higher turbidity) certain watersheds are taken off line
and watersheds with less suspended solids are used.
Filtration
Filtration / Water Treatment background info:
Please note that each area has a slightly different system of water treatment. In
some cases it is simply the order steps are taken. In other cases whole steps are
skipped.
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British Columbia
Greater Vancouver Regional District
Currently the GVRD treats water by passing it through large screens to
remove large debris and then chlorinates the water. As the water goes
through the cities’ systems it may go to a secondary treatment plant where
it will be re-chlorinated to deal with any contamination of the pipes or leaks
in the pipes.
The first filtration plant in the GVRD is scheduled to begin construction in
2002 and be completed by 2005. Currently there are three watersheds
serving the area. Capilano, Seymour and Coquitlam watersheds. The ones
most susceptible to increased turbidity are Capilano and Seymour.
For maps of local watersheds and treatment information go to:
www.gvrd.bc.ca
Alberta
Edmonton (and surrounding communities) draw their water from the North
Saskatchewan River
As the water enters the plant it goes through the following stages
1. Screening (to remove large debris)
2. Alum and Powdered Activated Carbon are added to help flocculate and
clean the water.
3. Sedimentation to remove sludge
4. Chlorine and Fluorine are added
5. Filtration of any remaining dissolved solids
6. Ammonia is then added to make the chlorine stable for longer periods of
time.
http://www.walkertoninquiry.com/part2info/commissuepapers/08doyle/2.5.4.edmonton.pdf
Ontario
London draws its water from Lake Huron and Lake Erie
Precise diagrams aren’t available (to our knowledge) but the London system
is run by the same people as Toronto so it is probably very similar.
http://www.city.london.on.ca/WaterSupply/water_welcome.ht
www.walkertoninquiry.com/part2info/commissuepapers/08doyle/2.5.4.toronto.pdf
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Toronto
All of Toronto’s water comes from Lake Ontario, the 14th largest fresh
water lake in the world.
There are four water treatment plants drawing water. The water intakes
are approximately 1-3 km offshore and up to 10 m below the surface.
Water is then passed through moving screens to remove large debris
As the water enters the plant it goes through 5 stages
1. Coagulation, Flocculation and Sedimentation
Chemicals used in this stage include alum (aluminum sulphate),
polyaluminium chloride and other polyelectrolytes.
2. Filtration
Water flows by gravity through dual media filters. These dual media
filters are made up of sand and anthracite (a coal- like mineral).
3. Disinfection
Chlorine is added in order to kill disease-causing organisms in the raw
and treated water. Sulphur dioxide is then added to remove residual
chlorine in order to bring chlorine levels to acceptable standards for
ammoniation.
4. Fluoridation
Fluoride is then added to the water to raise the level to 1.2mg/L This
is to help combat tooth decay. The fluorine actually replaces the
calcium in the enamel of teeth making them less susceptible to decay.
5. Ammoniation
Ammonia is added at the end of the treatment process and combines
with any residual chlorine in order to stabilize the chlorine so that it
can remain dissolved in the water for longer periods of time.
www.city.toronto.on.ca/water/process.htm
Activity #3
Archimedes' principle
This principle states that a body immersed in a fluid is buoyed up by a force equal
to the weight of the displaced fluid. The principle applies to both floating and
submerged bodies and to all fluids, i.e. both liquids and gases. If the body is less
dense than the fluid, it will float or, in the case of a balloon, it will rise. If the
body is denser than the fluid, it will sink.
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The story behind its name is that in 250 BC, the king of Syracuse (on the island of
Sicily) suspected that his goldsmith had secretly kept some of the gold that was
meant for the royal crown and replaced it with a cheaper metal. The King decided
to ask Archimedes, a Greek mathematician, to determine whether the crown was
made of pure gold.
Archimedes solved the problem by finding that the crown appeared to weigh less in
water than a bar of pure gold with the same mass. He put both the crown and the
gold bar in water and found that there was a greater buoyant force on the crown
(see the description for buoyancy.) In other words, Archimedes realized that the
crown displaced more water than the pure gold bar. He figured out that the
volume of the crown was equal to the volume of the water that it displaced.
Therefore, since the volume of the crown was greater than that of the gold bar he
found out that the crown had a lower density and was not made of pure gold.
According to the legend, Archimedes thought of this idea while taking a bath. He
was so happy that he leapt up and ran through the streets (naked) crying “Eureka”
(I found it).
Buoyancy
Buoyancy is a property of fluids (liquids and gases). When an object or substance
is floating on water, it seems to have less mass than water. What is actually
happening is that the fluid (in this case water) is pushing back in all directions on
the object. The upward part of the force exerted by fluids is called buoyancy. In
other words, when this object goes in the water, it pushes some of the water out
of the way or displaces it. Then the water exerts a lifting force called buoyancy.
In calculating the buoyant force on a body, one must also take into account the
shape and position of the body.
An object in water is buoyed up by a force that is equal to or greater than the
mass of the water it is displacing. An object that is floating in water has LESS
MASS than the quantity of water that it would take to fill up the same amount of
space. If an object has a GREATER MASS than the water that would occupy the
same amount of space, then it sinks. In other words, if the upward buoyant
force on an immersed object is GREATER than the downward force of gravity
(weight of the object), the object will rise.
Buoyancy is dependent on gravity because buoyancy is a result of the weight of
various substances. Without gravity there would be no buoyancy. We say that an
object has positive buoyancy, negative buoyancy or neutral buoyancy according to
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whether it rises, sinks or remains level in the fluid.
Density
In this workshop, we have defined density as weight divided by volume. Strictly
speaking, this definition is incorrect. Density should be defined as mass divided by
volume.
Density = mass
volume
The difference between mass and weight is as follows. Mass is a measure of the
amount of matter in an object or the specific volume of liquid or gas, whereas the
weight of something is a measure of the gravitational pull on it. Therefore, the
mass remains consistent regardless of which planet we are performing this
experiment on!
The density of a pure substance varies little from sample to sample and is often
considered a characteristic property of the substance. Most substances undergo
expansion when heated and therefore have lower densities at higher temperatures.
Many substances, especially gases, can be compressed into a smaller volume by
increasing the pressure acting on them. For these reasons, the temperature and
pressure at which the density of a substance is measured are usually specified.
The density of a gas is often converted mathematically to what it would be at a
standard temperature and pressure. Water is unusual in that it expands, and thus
decreases in density, as it is cooled below 3.98°C (its temperature of maximum
density).
Density often is taken as an indication of how heavy a substance is. Iron is denser
than cork, since a given volume of iron is more massive (and weighs more) than the
same volume of cork.
Neat Fact – the density of humans is ~1 (the same as water) because we are mostly
made of water.
Hydrometer
The hydrometer is a device used to determine the density of a liquid. It usually
consists of a thin glass tube closed at both ends. Unlike the hydrometer used in
this workshop, one end of commercial hydrometers is enlarged into a bulb. The
bulb contains fine lead shot or mercury to cause the instrument to float upright in
a liquid. Most hydrometers have a long, narrow stem, so that a small change in
displaced volume will represent a longer distance on the scale (* This is why our
hydrometers do not show a great difference between the different densities. Our
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hydrometer has a thicker stem.) This increases the sensitivity of the instrument.
It also increases its fragility. Commercial hydrometers are usually calibrated for
ordinary room temperature, which is taken to be 20°C (68°F), or for 4°C (39.2°F).
The scale of the hydrometer tells us the number of times heavier or lighter that
our test liquid is compared to water i.e., the density of the liquid.
The hydrometer works on Archimedes principle, that is, the upthrust on a body
immersed in a fluid (either liquid or gas) equals the weight of the fluid displaced.
According to this principle, the hydrometer will sink until it displaces its own mass.
The scale on the hydrometer measures density or, in other words, the mass of the
volume divided by the volume of the liquid displaced. For example, water has a
volume that is equal to the mass displaced and therefore is 1.0 g/mL. In our
experiment we increased the density by adding salt to our water solution.
Although not done in our experiments, most people that use hydrometers
recognize the fact that fluid density fluctuates with temperature. A separate
thermometer or a combined hydrometer containing its own thermometer is usually
used to determine the temperature of the sample. A temperature chart is then
used to determine the density of the liquid at room temperature. Since our
experiment is done at room temperature we have eliminated the thermometer
section. It is important to note, however, that there might be slight variations in
our measurements between winter and spring/fall workshops.
There are several different types of hydrometers. Some examples include the
alcoholometer that is used to test alcohol. Another type, called a acidimeter, is
used to determine the amount of acid in batteries. The strength of brine in boilers
of ships is tested with a salinometer. The salinometer is also used to test the salt
levels in sea water aquariums. This is the type of hydrometer that we will be using
in our experiment.
Salinity vs. Density
This chart was used to figure out the density of the water with varying amounts of
salt. If you wish to add additional samples you can use this chart to figure out
more density. Dilute the mL of salt with 100 mL of water.
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0
5
10
15
20
25
30
1 1.02 1.04 1.06 1.08 1.1 1.12 1.14 1.16
Density of Solution (g / mL)
NaC
l (m
L /
100 m
L w
ate
r)
Seawater
The majority of liquid water on Earth is found in oceans. Chlorine and sodium
make up the great majority (more than 85%) of the dissolved solids in seawater.
Other solids include sulfate, magnesium, calcium, and potassium. Tidal marshes,
wetlands, and estuaries have varying salinity values depending on the addition of
fresh water.
Salts dissolve in water and they exist as dissociated ions. Salinity is a
measurement of the dissolved salts in water. It is calculated by determining the
ratio of salts to water, and is expressed in the unit "parts per thousand" or ppt.
Therefore, salinity is actually measuring the number of parts of salt per thousand
parts of water (or the number of grams of dissolved salts in 1 kg of seawater). A
salinometer or floating hydrometer is used to determine the chloride
concentration in seawater (see hydrometer description). Open ocean water has a
salinity of about 35 parts per thousand (ppt) or 35 grams of dissolved solids per
1,000 grams of water. There are three main categories of salinity: Fresh water =
0 ppt-0.5 ppt; Brackish water = 0.5 ppt - 30 ppt; Salt water (sea water) = greater
than 30 ppt. Salinity, like temperature, also affects the amount of dissolved
oxygen in the water. At high salinities, most of the space between water molecules
is taken up by molecules of the salt so there is less space available to hold oxygen
molecules.
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Fresh water has very low salinity and certain types of organisms live in fresh water
and land animals, such as humans, depend on fresh water to survive. In coastal
waters, there are many different salinity levels and therefore we can find a
variety of ecosystems and different organisms living in each of these ecosystems
depending on the salinity level. Aquatic organisms are adapted to living in certain
salinity ranges. Organisms that live in high salt concentrations tend to be more
tolerant of a wider range of salinities, while organisms such as minnows and sunfish
that live in fresh water are less tolerant. The concentration of salt in the Dead
Sea is so high, that everything floats.
Activity #4
Oil Spills – Environmental Effects
Oil spills can have serious detrimental effects on the environment. The wave action
of the ocean can mix viscous oil into a thick water-and-oil emulsion called mousse.
The mousse washes ashore and forms tar balls, or tar balls sink to the bottom of
the ocean where they may remain for a long time, slowly releasing hydrocarbons
into the water.
The oil floating on the surface of water often affects seabirds first. Feathers
coated with oil lose their water-proofing and insulating qualities, causing birds to
die of hypothermia or drown. Similarly, sea mammals, such as sea otters, depend on
fur to insulate them from the cold. Oil can reduce the insulating ability of the fur
by 70%, causing otters to freeze to death. They may also be poisoned when they
ingest oil while cleaning their fur or inhaling petroleum fumes.
Oil disrupts every level of the food chain by killing zooplankton (they are killed by
the fact that they are filter feeders - they not only are affected externally by oil,
but internally as they ingest it) that are near the bottom of the food chain. When
small fish and fish fry eat the plankton, they also eat the oil. Larger fish, birds,
bears and humans who eat these fish will ingest oil too. The germination and
growth of marine plants is also obstructed by oil.
Sources of Oil Spills
Spills can happen on land or water when oil is incorrectly handled, there are truck
and railways accidents, tankers or barges collide, the insides of tankers are
washed, bilge oil, and natural oil deposits seep through cracks in the ocean floor.
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The largest contributor to ocean oil contamination (37%) results from urban run-
off and land-based industrial discharge. Natural seepages account for 7% of the
oil in the oceans.
About 14% of the oil in the sea is directly attributed to the world’s oil industry,
where spills have occurred as a result of accidents with tankers or during the
exploration and production phase from rigs and platforms.
One-third (33%) of all oil spillage occurs during the operation of cargo vessels
other than those used by the oil industry. These are vessels that may be involved
in collisions that spill fuel and oil or they may discharge waste oil from ballast
tanks while at sea.
Cleaning up Oil Spills
There are a number of techniques for cleaning an oil spill. The technique varies
depending on the oil type involved, the location of the spill and weather conditions.
In general, in open waters, one or a combination of the following techniques may be
used.
- Leave the oil alone to break down by natural means
- Contain the spill with booms and collect it from the water surface using
skimmer equipment
- Use dispersants to break up the oil and speed its natural biodegradation
- Introduce biological agents (bioremediation) to the spill to hasten
biodegradation
Along a shoreline, oil can also be cleaned in several ways:
- Manual pickup with hand tools and bags
- Tarmat breakup and removal – tarmats, which are thick, asphalt-like coverings
of oil, can be broken with hand tools and then scattered or collected.
- Tilling/raking – oil under the soil surface is exposed by using a rake to turn
over the topsoil. This process helps with natural degradation or bioremediation.
- Spot washing – high-pressure washing tools are used to remove small
accumulations of oil. The runoff water is then collected.
- Bioremediation – the use of bacteria and fungi to remove pollutants.
Major Oil Spills
The Exxon Valdez - The supertanker ran aground in Prince William Sound, Alaska - The worst spill in U.S. history – 40,000 t (11 million gallons) - spread quickly over 900 miles of shoreline
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- weather conditions made it difficult to contain and clean up - workers collected more than 36,000 oiled birds and over 1,000 sea otters - the number killed was several times more than the number found - it may be 20-70 years before the seabird population recovers - cleanup costs exceeded $2 billion dollars - involved more than 10,000 people, several hundred boats and aircraft, and
special equipment
Persian Gulf War – Early 1991 - 2.5 to 4 million barrels of oil were dumped into the Persian Gulf
- oil covered some 600 square miles of sea surface and 300 miles of coastline
- it affected coral reefs, mangrove swamps, beds of sea grass and algae, birds,
sea turtles, fish and marine mammals.
- clean-up action was delayed due to the war
- booms and skimmers were set up to protect some areas
- people from all over the world helped with the cleanup.
H. Suggested Resources/Bibliography Websites
Air & Waste Management Association. Updated May 1, 2000. Oil Spills – A Fact
Sheet. (Online). Available:
http://www.awma.org/resources/education/oilspills.htm [February 26, 2002].
Australian Petroleum Production and Exploration Association Limited. (2002).
Oceans and Oil Spills. (Online). Available:
http://www.appea.com.au/edusite/html/pt/ocean.html [February 26,2002].
Canada. Environment Canada. Updated December 1, 2000. Oil pollution and birds.
(Online). Available:
http://www.cws-scf.ec.gc.ca/hww-fap/oilpl/oil.html [February 14, 2002].
Canada. Environment Canada. The pH Scale. (Online). Available:
http://www.ec.gc/water/en/manage/qual/e_ph.htm [February 14, 2002].
Canada. Environment Canada. Acid Rain and the Facts. (Online). Updated April 3,
2001. Available: http://www.ec.gc.ca/acidrain/acidfact.html [February 14, 2002].
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Canada. Environment Canada. Acid Rain and Water. (Online). Updated. Available:
http://www.ec.gc/ca/acidrain/acidwater.html [February 14, 2002].
Canada. Environment Canada. What is Canada Doing? (Online). Updated April 14,
1999. Available: http://www.ec.gc.ca/acidrain/done-canada.html [February 14,
2002].
Canada. Health Canada. Reprinted 1995. pH. (Online). Available:
http://www.hc-sc.gc.ca/waterquality
Enclyclopedia. Com. (2002) (Online). Available:
http://www.encyclopedia.com/articles/06204.html
Ertco Precision. (2002) (Online). Available:
http://www.ertco.com/hydrometers.html
Natural Resources Canada. (2002) (Online). Available:
http://atlas.gc.ca/english/facts/fresh.html
Discovery Channel School. Hydrometer (2002) (Online). Available:
http://www.discoveryschool.com/homeworkshelp/worldbook/atozscience/h/26928
0.html
Richard O’Hourne Middle School. Salinity of water: Measuring the Salinity of
Water. (2002) (Online). Available: http://library.bhbl.neric.org/outlab/salinity.html
SeaWorld Adventures Parks (Busch Gardens). Salty Solutions. (2002) (Online).
Available: www.seaworld.org/Water/salty.html
Statistics Canada. Human Activity and the Environment. (2002) (Online). Available:
http://www.statcan.ca/english/ads/11-509-XPE/basin.htm
Upper Midwest Aerospace Consortium. Environmental Effects of Acid Rain.
(Online). Available: http://www.umac.org/ocp/acid/environmental.htm [February 14,
2002].
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Books
Alexander, Nora L. (2000). “Unit 2: Fluids”. Science and Technology 8.
Scarborough: Nelson Thompson Learning.
Andrews, William. Investigating Aquatic Ecosystems. Toronto
Barker, J. et al. (1988). Discovering Density. “LHS Gems Great exploration in Math
and Science”. Berkley, California: Lawrence Hall of Science, University of California
at Berkley.
Gralla, Preston. (1994) How the Environment Works. Emeryville: Ziff-Davis Press.
Greater Vancouver Regional District. (1993). From Source to Sea.
Vancouver
Greater Vancouver Regional District. Water: A Community Resource.
Vancouver
Kauffman, Judson. (1990) Physical Geology. New Jersey: Prentice Hall, Inc.
Olivero, R. et al. (2000) Matter and Material: Fluids and Solids. Science and
Technology Activity Resource. Toronto: GTK Press.
Pipkin, Bernard W. (1994) Geology and the Environment. Minnesota: West
Publishing Company.
Press, Frank et al. (1994) Understanding Earth. New York: W.H. Freeman and
Company.
Snyder, Carl. The Extraordinary Chemistry of Ordinary Things. Toronto: John
Wiley & Sons, Inc.
Water Environment Federation. (1998). Water Sourcebook. Alabama: University of
South Alabama.
Personal Communication
Stairs, Gavin from “Stairs Small Systems” (personal communication)
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Thank You
Matt Clark – Adventures in Science volunteer – helped with hydrometer section.
Copyright Permission
Map of Watersheds in Canada
Statistics Canada information is used with the permission of the Minister of
Industry, as Minister responsible for Statistics Canada. Information on the
availability of the wide range of data from Statistics Canada can be obtained from
Statistics Canada’s Regional Offices, its World Wide Web site at
http://www.statcan.ca, and its toll-free access number 1-800-263-1136.
Oil Spill Pictures
With just a few exceptions, the photos on this website are considered public
information: you are free to copy and use them. The exceptions are a few
photos that are credited to other organizations. We request that you credit us
when you use our photos in your publications (we're the Office of Response and
Restoration, National Ocean Service, National Oceanic and Atmospheric
Administration). http://www.response.restoration.noaa.gov/photos/gallery.html