how ftir works ftir spectrometer electronics / µc external computer data storage results moduled...

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How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum transmitted infrared light CALCMET™ software Fourier analysis infrared source cuvette measuring value displays absorptio n spectrum detector interferome ter sample cell external eductor Sample cell interferometer detector

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Page 1: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

How FTIR worksFTIR spectrometer

Electronics / µC

external computer data storage

results

moduledinfrared spectrum

meas. signal

continuousinfrared spectrum

transmittedinfrared light

CALCMET™software

Fourier analysis

infrared source

cuvette

measuring value displays

absorptionspectrum

detector

interferometer

sample cell

externaleductor

Samplecell

interferometer

detector

Page 2: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

measuring ...

How FTIR works

digital library

ref. values

FFT

+

measuring valuesm1, m2, m3, ...x

transmission spectrum standardized spectruminterferogramm

absorbance spectrum

identical spectrum f1

f2

f3

factors

reference spectra

zero gas measured background spectrum

Page 3: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

GASMET CEMS APPLICATIONS

Gasmet CEMS and reference measurements:

SO2 measurementBFB boiler: wood, peat, bark, sludge

150.0

200.0

250.0

300.0

350.0

400.0

17:2

6

17:5

8

18:3

0

19:0

2

19:3

4

20:0

6

20:3

8

21:1

0

21:4

2

22:1

4

22:4

6

23:1

8

23:5

0

0:22

0:54

1:26

1:58

2:30

3:02

3:34

4:06

4:38

5:10

5:42

6:14

6:46

7:18

Time

Co

nce

ntr

atio

n (

mg

/Nm

3)

UV-fluorescence

FT-IR

Page 4: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

GASMET CEMS APPLICATIONS

NOx measurementBFB boiler: wood, peat, bark, sludge

200.0

250.0

300.0

350.0

400.0

450.0

7:5

1

8:1

5

8:2

8

8:4

1

8:5

4

9:0

7

9:2

0

9:3

3

9:4

6

9:5

9

10

:12

10

:25

10

:38

10

:51

11

:04

11

:17

11

:30

11

:43

11

:56

12

:09

12

:22

12

:35

12

:48

Time

Co

nc

en

tra

tio

n

(mg

NO

2/N

m3

)

Chemiluminescence

FT-IR

Page 5: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

0.00

5.00

10.00

15.00

20.00

25.00

0 10 20 30 40 50 60 70

Unit Run Sequence

PPM

NO

x

CEM NOx FTIR NOx

CEM NOx

FTIR NOx

FTIR Dev

Average 9.38 9.25 -0.29 Min 1.70 1.19 -9.45 Max 24.87 35.65 10.78 Std Dev 5.21 5.89 3.61 CI 0.82

Austin Energy Sandhill Unit #1 Demonstration Results

Page 6: How FTIR works FTIR spectrometer Electronics / µC external computer data storage results moduled infrared spectrum meas. signal continuous infrared spectrum

GASMET CEMS APPLICATIONS

Gasmet CEMS and reference measurements:

CO measurementBFB boiler: wood, peat, bark, sludge

0.0

500.0

1000.0

1500.0

2000.0

2500.0

3000.0

7:5

1

8:1

3

8:2

4

8:3

5

8:4

6

8:5

7

9:0

8

9:1

9

9:3

0

9:4

1

9:5

2

10

:03

10

:14

10

:25

10

:36

10

:47

10

:58

11

:09

11

:23

11

:34

11

:45

11

:56

12

:07

12

:18

12

:29

12

:40

12

:51

Time

Co

nc

en

tra

tio

n (

mg

/Nm

3)

NDIRFT-IR