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Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
Project No. 12-384-D
June 2013
Geotechnical Factual Report - 20130627
Appendix I, P09842A01 June 2013
Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
Project No. 12-384-D
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
TABLE OF CONTENTS
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P09842A01 June 2013
1 INTRODUCTION .............................................................................................................................. 1
2 PREVIOUS INVESTIGATIONS .......................................................................................................... 2
3 2013 SITE INVESTIGATION PROGRAM ........................................................................................... 3 3.1 Scope of Work ................................................................................................................. 3
3.2 Utility Locates ................................................................................................................. 3
3.3 Geotechnical Drill Holes .................................................................................................. 3
3.4 Rock Mapping ................................................................................................................. 3
3.5 Soil and Water Testing .................................................................................................... 4
4 LABORATORY TESTING ................................................................................................................... 6 4.1 KCB Laboratory Testing ................................................................................................... 6
4.2 AGAT Laboratories .......................................................................................................... 6
4.2.1 Rock Testing ..................................................................................................... 6
4.2.2 Soil Testing ....................................................................................................... 6
4.2.3 Water Testing .................................................................................................. 7
5 DISCLAIMER ................................................................................................................................... 9
REFERENCES ............................................................................................................................................. 10
List of Tables
Table 3‐1 Field Water Testing Results .............................................................................................. 5 Table 4‐1 Water Sample Analytical Results and BC Approved and Working Guidelines ................. 7
List of Figures
Figure 1 Site Investigation Plan A
Figure 2 Site Investigation Plan B
Figure 3 Site Investigation Plan C
Figure 4 Site Investigation Plan D
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
TABLE OF CONTENTS (continued)
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List of Appendices
Appendix I Drill Hole Logs
Appendix II KCB Laboratory Testing Results
Appendix III Rock Mapping Results
Appendix IV AGAT Laboratory Testing Results
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
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1 INTRODUCTION
It is understood that the Ministry of Transportation (MoT) proposes to widen Highway 7 to four lanes from Silverdale Avenue to Nelson Road in Mission, BC, and that R.F. Binnie & Associates Ltd (Binnie) have been retained to perform the design for the project.
Klohn Crippen Berger Ltd (KCB) was retained by Binnie to perform a limited site investigation to supplement existing geotechnical data. This report summarizes the site investigation program and the results of the subsequent testing program.
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
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2 PREVIOUS INVESTIGATIONS
A previous geotechnical investigation was performed by CBA Engineering Ltd, and was summarized in their January 1973 report, “Site Investigation Report for Phase V of Mission Roadworks”.
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
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3 2013 SITE INVESTIGATION PROGRAM
3.1 Scope of Work
The 2013 site investigation program comprised six drill holes, surficial soil and water sampling, and rock outcrop mapping.
Drill hole locations, surficial soil sampling locations, and water sampling locations were referenced to existing infrastructure and surveyed with a WAAS‐enabled, hand‐held Global Positioning System (GPS). Coordinates presented are in UTM NAD83 and are accurate to approximately 4 m.
The scope of the investigation was limited to 6 drill holes east of STA 109+30. Drill hole locations were limited to the shoulder of the highway due to safety concerns and traffic control limitations imposed by the Ministry of Transportation.
3.2 Utility Locates
A BC One Call was conducted by KCB prior to the start of the investigation program. Western Leakage Services Ltd., of Coquitlam, was retained to confirm that each drill hole location was clear of underground services prior to the drill holes being advanced.
3.3 Geotechnical Drill Holes
Drilling was conducted by Downrite Drilling Ltd. of Chilliwack, BC, using a truck‐mounted drill rig. A total of six solid stem auger holes (AH13‐1 to AH13‐6) were advanced to a maximum depth of 4.6 m (15 feet). Drilling was conducted on April 2, 2013 and during the evening of April 8, 2013.
Drilling of all drill holes was observed by a KCB geotechnical engineer. Soil stratigraphy was logged and representative samples for testing were collected. Soil strength was assessed by pocket penetrometer testing and Torvane hand‐held shear testing, carried out at regular intervals on cohesive soils returned on the auger flights.
Drill holes were backfilled using cuttings and compacted using the drill string. A nominally 300 mm thick layer of cold patch asphaltic concrete was used to seal all drill holes at the surface.
Drill hole logs were prepared using an MoT template and are presented in Appendix I. Soil index test results are presented in Appendix II.
Drill hole locations are depicted in Figures 1 through 4.
3.4 Rock Mapping
Rock mapping was carried out on March 22, 2013 by a KCB engineer. Rock outcrops were observed at the proposed L100 and L600 alignments. For the L100 alignment, three separate outcrops were observed. A total of two scanline surveys (SC13‐01 and SC13‐02) were carried out on the two larger outcrops totalling approximately 180 m from station (STA) 102+40 to STA 104+30, approximately. The
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
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outcrops varied in height from 0 m to approximately 3 m to 4 m. A small outcrop was located near STA 105+80 to 105+90. This small outcrop was approximately 0.5 m high.
For the L600 alignment, a small bedrock outcrop was observed at approximate STA 603+60. No mapping was performed on the outcrop as it was very small and partially vegetated.
The first scanline survey, SC13‐01, started at STA 102+40 and ended at approximate STA 103+60. From STA 102+90 to 103+10 the rock slope was partially vegetated. For scanline SC13‐01, a total of 19 discontinuities were mapped. The second survey, SC13‐02, was carried out from STA 103+90 to 104+30, approximately. For scanline SC13‐02, a total of 9 discontinuities were mapped. No scanline survey was carried out on the small outcrop. The discontinuities are presented in Appendix III. Scan line locations are depicted in Figures 1 through 4.
Fresh rock samples were collected using a geological hammer. The fresh samples were visually inspected using a hand lens.
A ‘fizz‐test’ was performed on selected samples using 10% HCl acid to assess if carbonates were present in the rock. None of the samples tested positive.
The collected rock samples were taken to KCB’s Vancouver office for further visual inspection. A total of two representative sample bags were sent to AGAT Laboratories to test for the Acid Rock Drainage and Metal Leaching (ARD/ML) potential.
From visual inspection, the rock was identified as a quartz diorite with hornblende and biotite, fine to medium grained, slightly weathered, strong to very strong, with an approximate GSI of 70 to 80 and widely jointed; the GSI from near STA 102+40 to 102+80 was much lower, approximately 40 to 50 and the rock was moderately weathered.
3.5 Soil and Water Testing
At the time of the rock mapping, soil and water samples were collected along the L100 alignment to assess for indications of ARD/ML. A total of four soil samples and five water samples were collected and sent to AGAT Laboratories for ARD/ML potential testing.
Ditch water was tested for pH, temperature, and conductivity in the field using a portable multi‐meter (HACH HQ40d with pH and conductivity probes). Water samples were then bottled using plastic bottles provided by AGAT Laboratories. Two separate samples were taken at each location, one 500 mL (general parameters and anions) and one 120 mL (metals). Nitric acid was added as preservative to the 120 mL bottles after water collection. All water samples were stored in a cooler with ice pack immediately after collection.
Soil samples were collected just below the organic layer in the vicinity of the water samples. The collected samples were stored in small plastic bags provided by AGAT Laboratories and stored in the cooler along with the water samples.
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Table 3‐1 presents the results of the field water testing, the approximate location of the water samples collected, and the corresponding soil samples collected. Sample locations are depicted on Figures 1 through 4.
Table 3‐1 Field Water Testing Results
Soil Sample No.
Water Sample No.
Northing* [m]
Easting* [m]
pH Temperature
[oC] Conductivity [µS/cm]
SS13‐01 WS13‐001 5444756 544055 6.23 8.3 97.8
SS13‐02 WS13‐002 5444544 544444 6.62 7.2 64.4
SS13‐03 WS13‐003 5444141 545085 5.87 7.9 60.2
SS13‐04 WS13‐004 5443551 546037 6.40 9.1 153.4
‐ WS13‐005 5444612 544423 7.65 8.1 5.81
* Location is approximate; coordinates were taken using a handheld device
All samples were sent to AGAT Laboratories for testing. Testing for soil sample SS13‐01 was cancelled as the soil was not considered native.
SS13‐02 consisted of medium‐plastic clay, stiff to firm, brown mottled grey, moist, with some rootlets. SS13‐03 consisted of medium‐to‐high‐plastic clay, soft, grey, moist, with trace rootlets. SS13‐04 consisted of high‐plastic clay, soft, grey, moist.
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Geotechnical Factual Report
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4 LABORATORY TESTING
4.1 KCB Laboratory Testing
Laboratory testing comprised moisture content, Atterberg limits and particle grain size distribution (PSD) analyses.
Laboratory test results are presented in Appendix II. Moisture content, fines content, and Atterberg limits tests are also plotted graphically on the drill hole logs presented in Appendix I
4.2 AGAT Laboratories
Surficial rock, soil, and water samples that were obtained during the field investigation were sent to AGAT Laboratories for testing. The results of the water testing are included in Appendix IV.
4.2.1 Rock Testing
Two rock samples were sent to AGAT for testing, SS 13‐01‐01 and SS 13‐01‐03. The rock samples were tested for the following suite of tests:
Modified Acid‐base Accounting (ABA) package;
Trace Metals by Aqua Regia digestion with ICP‐MS finish (AGAT method 201074);
Whole Rock analysis Lithium borate with ICP‐OES finish (AGAT method 201076);
Shake Flask Extraction (with blank); and
Mineralogy XRD with Rietveld‐refinement.
The results of the testing are presented in Appendix IV.
4.2.2 Soil Testing
Testing was carried out on three soil samples, SS13‐02, SS13‐03, and SS13‐04. The soils samples were tested for the following suites:
Modified ABA package;
Surface Rinse pH on < 2 mm fraction (MEND method);
Trace Metals by Aqua Regia digestion with ICP‐MS finish (AGAT Method 201074); and
Shake Flask Extraction (with blank).
The results of the testing are presented in Appendix IV.
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Geotechnical Factual Report
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4.2.3 Water Testing
All five water samples were sent to AGAT Laboratories for testing. The water samples were tested for the following parameters:
pH/ EC /Sulphate
Fluoride / Chloride
Alkalinity
Total Dissolved Solids (TDS) / Total Suspended Solids (TSS)
Total Metals by ICP‐MS
The analytical results are shown with the BC Approved and Working Guidelines in Table 4‐1, and are presented in Appendix IV.
Table 4‐1 Water Sample Analytical Results and BC Approved and Working Guidelines
Parameter Unit Freshwater Aquatic Life
Irrigation Water
Livestock Minimum Guideline
Routine Detection Limit
WS13‐001
WS13‐002
WS13‐003
WS13‐004
WS13‐005
pH pH units 6.5‐ 9.0 5.0 ‐9.0 5.0‐9.5 N/A 0.01 6.70 6.90 6.86 6.99 7.36
Electrical Conductivity
uS/cm N/A 700 N/A 700 1 95 64 60 151 52
Alkalinity (pH 4.5)
mg CaCO3/L
Sensitivity ranking
N/A N/A N/A 1 23 25 24 61 21
Total Dissolved Solids
mg/L N/A 500 1000 500 5 <5 15 15 35 13
Total Suspended
Solids mg/L N/A N/A N/A N/A 2 331 159 3 2 3
Chloride mg/L 150 100 600 100 0.05 13.2 2.30 2.84 11.4 2.14
Sulphate mg/L Hardness dependent
N/A 1000 1000 0.5 4.0 2.5 2.1 4.2 1.7
Fluoride mg/L hardness dependent
1 1 1 0.02 0.05 0.05 0.03 0.04 0.03
Aluminum Total
µg/L pH
dependent (dissolved)
5000 5000 5000 1 1220 491 302 123 239
Antimony Total
µg/L 20 N/A N/A 20 0.05 0.14 <0.05 <0.05 0.12 <0.05
Arsenic Total µg/L 5 100 25 5 0.1 0.6 0.7 0.6 0.9 0.2
Barium Total µg/L 5000 N/A N/A 5000 0.1 15.1 11.3 7.8 15.2 3.1
Beryllium Total
µg/L 5.3 100 100 5.3 0.05 <0.05 <0.05 <0.05 <0.05 <0.05
Boron Total µg/L 1200 500 5000 500 2 15 8 6 11 6
Cadmium Total
µg/L hardness dependent
5.1 80 5.1 0.01 0.05 0.02 0.01 0.01 <0.01
Calcium Total
µg/L Acid
sensitivity N/A 1000000 1000000 50 6680 6390 5780 20400 4910
Chromium Total
µg/L 1 4.9 50 1 0.5 2.3 1.2 0.8 1.0 <0.5
Cobalt Total µg/L 4 50 1000 4 0.05 0.88 0.56 0.31 0.68 0.14
Copper Total µg/L hardness 200 300 200 0.5 13.7 4.1 2.4 8.8 1.6
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Parameter Unit Freshwater Aquatic Life
Irrigation Water
Livestock Minimum Guideline
Routine Detection Limit
WS13‐001
WS13‐002
WS13‐003
WS13‐004
WS13‐005
dependent
Iron Total µg/L 1000 ‐ N/A ‐ 10 1570 840 580 2240 210
Lead Total µg/L hardness dependent
200 100 50 0.01 1.52 0.12 0.08 0.77 0.04
Lithium Total µg/L 14 2500 N/A N/A 0.1 0.8 0.4 0.3 0.2 0.2
Magnesium Total
µg/L N/A N/A N/A N/A 50 1230 1840 1650 1770 1450
Manganese Total
µg/L Hardness dependent
200 N/A 200 1 54 42 37 108 4
Mercury Total
µg/L 1 2 3 1 0.003 <0.003 0.003 <0.003 0.004 <0.003
Molybdenum Total
µg/L 2000 50 50 50 0.1 0.2 0.3 0.2 0.4 <0.1
Nickel Total µg/L hardness dependent
200 1000 200 0.5 2.9 3.4 1.7 2.3 <0.5
Selenium Total
µg/L 2 10 30 10 0.3 <0.3 <0.3 <0.3 <0.3 <0.3
Silver Total µg/L hardness dependent
N/A N/A N/A 0.01 0.01 <0.01 <0.01 0.02 <0.01
Sodium Total µg/L N/A N/A N/A N/A 100 11600 3500 3800 7800 3800
Thallium Total
µg/L 1.7 N/A N/A N/A 0.01 <0.01 <0.01 <0.01 <0.01 <0.01
Titanium Total
µg/L 2000 #N/A N/A 2000 1 63 36 26 44 19
Uranium Total
µg/L 300 10 200 10 0.01 0.04 0.03 0.01 0.02 <0.01
Vanadium Total
µg/L 6 100 100 6 0.5 3.0 2.7 2.1 1.4 1.2
Zinc Total µg/L hardness dependent
pH depende
nt 2000 2000 5 21 <5 6 <5 <5
Total Hardness (calc)
ug CaCO3/L
N/A N/A N/A N/A 100 21700 23500 21200 58200 18200
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REFERENCES
CBA Engineering Ltd. (1973). Mission Roadworks, Phase V, Site Investigation Report, Report No. 731.
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
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FIGURES
Figure 1 Site Investigation Plan A
Figure 2 Site Investigation Plan B
Figure 3 Site Investigation Plan C
Figure 4 Site Investigation Plan D
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APPENDIX I
Drill Hole Logs
A
A
A
A
A
GP
ML
ML
CI
ML
0.11m
0.41m
2.44m
3.05m
3.96m
4.57m
pp = 75
pp = 125
pp = 50
60.7
0.9
30.3
19.5
9.0
79.6
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately1.6 m from the edge-of-road, on the shoulder.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally fine to coarse GRAVEL, sandy,trace silt, maximum observed particle size70 mm, brown, moist. Gravel is typicallysub-angular to rounded (base course?).Sand is typically fine to coarse. (FILL)Generally SILT, sandy, trace carbonaceousmaterial, orange-brown, moist. Sand istypically fine grained. (FILL)
Generally SILT, sandy, trace carbonaceousmaterial, low plasticity, stiff, light brown,dilatant, typically wetter than plastic limit.(FILL)CLAY, trace to some fine to medium sand,medium plasticity, very stiff, light brown,wetter than plastic limit. Top 50 mm containstrace to some organic matter (rootlets andhumic matter), possibly former topsoil.
SILT and fine grained SAND, low plasticity,firm to stiff, brownish grey, wetter thanplastic limit, dilatant.
End of Hole at 4.57 m
24
20
41
28
27.6
36.0
31.1
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-1Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-02 to 2013-04-02
N: 5444567 m , E: 544437 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
AA
A
A
GP
CH
CI
0.27m0.45m
3.81m
4.57m
pp = 125
pp = 125
pp = 100
pp = 75
pp = 50
pp = 75
pp = 125
pp = 125
70.6 21.3 8.1
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately1.9 m from the edge-of-road, on the laneway.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally fine to coarse GRAVEL, sandy,trace silt, maximum observed particle size70 mm, brown, moist. Gravel is typicallysub-angular to rounded (base course?).Sand is typically fine to course. (FILL)
Generally CLAY, trace fine grained sand,trace organics (rootlets and carbonaceousmaterial), medium to high plasticity, verystiff, brown stained orange-brown, equal toor wetter than plastic limit, non-dilatant.(FILL)From 2.1 m, moisture content generallyincreases, stiff.From 2.44 m, generally some fine grainedsand, low plasticity, some grey mottling
CLAY, trace fine to medium sand, mediumplasticity, very stiff, moisture drier than orequal to plastic limit. Trace to some rootletsand humic matter from 3.81 to 3.85 (formertopsoil?).
End of Hole at 4.57 m
26
24
45
45
29.0
31.9
34.7
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-2Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-02 to 2013-04-02
N: 5444345 m , E: 544793 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
A
A
A
A
GP
CH
CH
0.16m
0.76m
3.66m
4.57m
pp = 88
pp = 63
pp = 50
FV = 35pp = 38
76.5 19.2 4.3
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately0.6 m from the edge-of-road, on the shoulder.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally GRAVEL, fine to coarse, sandy,some cobbles to 100 mm in diameter, tracesilt, sub-angular to rounded, brown, moist(base course?). (FILL)
from 1.5 m, generally wetter than plasticlimit.
Generally CLAY, trace to some fine tomedium sand, medium to high plasticity,stiff, grey and brown with traceorange-brown staining, equal to or wetterthan plastic limit. (FILL)
CLAY, trace to some fine to medium sand,medium to high plasticity, firm, grey, wetterthan plastic limit.
End of Hole at 4.57 m
26
26
51
50
36.5
40.2
42.7
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-3Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-08 to 2013-04-08
N: 5444110 m , E: 545162 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
A
A
A
A
GP
CH
CH
0.15m
0.61m
3.05m
4.57m
pp = 75
pp = 40
pp = 50
FV = 43pp = 50
75.6 19.0 5.4
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately1.8 m from the edge-of-road, on the shoulder.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally GRAVEL, fine to coarse, sandy,trace to some cobbles to 100 mm indiameter, trace silt, sub-angular to rounded,brown, moist (base-course?). (FILL)
Generally CLAY, trace fine to coarse sand,medium to high plasticity, stiff, grey withsome brown mottling, wetter than plasticlimit. (FILL)from 2.0 m, generally firm.
CLAY, trace fine to medium sand, highplasticity, firm, grey mottled brown, wetterthan plastic limit.
End of Hole at 4.57 m
26
31
54
62
45.8
48.3
47.4
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-4Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-08 to 2013-04-08
N: 5443908 m , E: 545491 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
A
A
A
A
SP-GP
GP
SP-GP
MH
OL
CH
0.08m0.2m
0.76m
1.22m
3.35m3.51m
4.57m
pp = 55
pp = 125
pp = 88
FV = 50pp = 40 FV = 32
FV = 45pp = 37.5
58.3
63.9
31.2
26.3
10.5
9.8
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately1.5 m from the edge-of-road, on the shoulder. The shoulderseems to have been paved differently than the laneway at thislocation.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally fine to coarse GRAVEL, and fineto coarse sand, trace to some silt, 70 mmmaximum particle size observed, typicallysubangular to rounded, brown, moist (basecourse?). Sand is typically fine to coarse.(FILL)Generally GRAVEL, fine to coarse, sandy,trace cobbles to 100 mm in diameter, tracesilt, sub-angular to rounded, brown, moist(sub-base?). (FILL)Generally SAND, fine to coarse, gravelly,trace silt, brown, moist. (FILL)Generally SILT, trace to some fine tomedium sand, trace brown fibrous toamorphous organic matter, high plasticity,stiff to very stiff, grey with some brown zones(intermixed organic content), wetter thanplastic limit. (FILL)ORGANIC SILT, trace fine to medium sand,low plasticity, firm, brown, wetter than plasticlimit, somewhat fibrous.CLAY, trace fine to medium sand, highplasticity, firm, grey, wetter than plastic limit.
End of Hole at 4.57 m
31
25
59
51
51.1
42.8
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-5Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-08 to 2013-04-08
N: 5443675 m , E: 545863 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
A
A
A
A
GP
GP
SP
SC
0.12m
0.46m
3.05m
3.96m
4.57m
49.6
45.3
42.1
48.6
8.3
6.0
Notes:
1) Borehole advanced using a truck-mounted drilling rig.
2) Borehole advanced using solid-stem augers. An 8-inch tc-bitwas used to advance the hole through the pavement to a depthof approximately 1.0 m, and was removed for the remainder ofthe borehole.
3) Borehole was backfilled with cuttings and compacted usingthe drill-string. A nominally 300 mm thick layer of cold-patchwas placed at the surface and compacted using the drilling rig.
4) Borehole located on north side of Highway 7, approximately2.0 m from the edge-of-road, on the shoulder.
5) Coordinates surveyed using a hand-held GPS and are inNAD83 UTM.
6) Borehole terminated due to maximum predetermined depthof investigation being achieved.
_
_
_
_
ASPHALTIC CONCRETE, aggregate andbitumen, black.Generally fine to coarse GRAVEL, sandy,trace silt, brown, moist. Gravel is subangularto rounded (base course). Sand is typicallyfine to coarse. (FILL)
Generally GRAVEL, fine to coarse, sandy,trace silt, trace cobbles (inferred from drillingaction), brown, moist. Sand is typically fineto coarse. (FILL)
Generally SAND, fine to coarse, some finegravel, trace silt, grey-brown, wet. (FILL)
SAND, fine to coarse, clayey, some fine tocoarse gravel to gravelly, trace organics(rootlets, roots), brown, wet.
End of Hole at 4.57 m
Rec
over
y (m
)
She
arS
tren
gth
(kP
a)
SK
Description
Drilling
and
Groundwater
Details
UFV
LV
Rpp
-----
San
d
Gra
vel
SHEET 1 of 1NOTE: Brackets ( ) denote Driller's estimate
AugerCoreDenisonSplit SpoonShelby TubeWash
Fin
es
Project:Location:
Highway 7 Four Laning
Driller: Downright DrillingMethod: Solid Stem Auger
Elevation:
Ministry of Transportationand Infrastructure
Highway 7 at Chester Street, Mission
Dep
th (
m)
KCB # P09842A01
SP
T N
(blo
ws/
0.3
m)
JMFEngineer:Checked:
Sam
ple
Typ
e
Unconfined CompressionField VaneLab VaneRemouldedPocket Penetrometer (readings/2)
BH13-6Coordinates:
Geotechnical andMaterials Branch
wL
------
ACDST
W
SAMPLE TYPE
1
2
3
4
5
6
7
8
9
w
PREPARED By:
wP
MQ, R, S
CDS
wL, wP
w
------
Mechanical AnalysisTriaxial CompressionConsolidationDirect ShearLiquid, Plastic LimitsMoisture Content
FILE No.
SUMMARY LOG
Cla
ssifi
catio
n
Dates: 2013-04-08 to 2013-04-08
N: 5443454 m , E: 546216 m
TESTS
TEST HOLE No.
SHEAR STRENGTH kPa
Gradation (%)
SPT N = Standard Penetration Test (ASTM-1586)
Klohn Crippen Berger
Index
Properties (%)
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
P09842A01 ‐ Geotechnical Factual Report ‐ 20130627.docx
P09842A01 June 2013
APPENDIX II
KCB Laboratory Testing Results
0
10
20
30
40
50
60
0 20 40 60 80 100
PLASTICITY CHART
% FINES
CL-ML
CL
CI
ML or OL
CH
MH or OH
DEPTH (m)
U-LINE
24
20
26
24
26
26
26
31
31
25
3.7
4.3
0.5
4.3
1.1
4.3
1.2
4.3
2.6
4.4
HOLE REMARKS/SAMPLE DESCRIPTION
LIQUID LIMIT (%)
PL
AS
TIC
ITY
IN
DE
X (
%)
A-LINE
SAMPLE WL WP PI
BH13-1
BH13-1
BH13-2
BH13-2
BH13-3
BH13-3
BH13-4
BH13-4
BH13-5
BH13-5
SA4
SA5
SA2
SA4
SA2
SA4
SA2
SA4
SA3
SA4
17
8
19
21
25
24
27
32
28
26
41
28
45
45
51
50
54
62
59
51
KC
B_A
TT
ER
BE
RG
-SI
P09842A
01 H
IGH
WA
Y 7
.GP
J
SIE
VE
.GD
T
5/1
/13
DRAWN BY: CHECKED BY:SH JG
PROJECT NO.:
PROJECT:
LOCATION:
FIGURE:
Mission, B.C.
P09842A01
Highway 7 Four Laning
0
10
20
30
40
50
60
70
80
90
100
0.0010.010.1110100
D85
PE
RC
EN
T F
INE
R B
Y W
EIG
HT
GRAIN SIZE(mm)
D10 %FINES
L PDEPTH (m)
HOLE
coarse
D15
GRAIN SIZE DISTRIBUTION
D50 %GRAVEL %SANDD60
CU = COEFFICIENT OF UNIFORMITY = D60/D10 PARTICLE SIZES, e.g. D85, in mm Tested by Wet Sieving Method (ASTM D1140 & D422)
SAMPLE
COBBLESGRAVEL
HOLE
37.469
0.095
31.025
39.079
36.586
0.096
0.121
0.539
0.390
0.256
0.338
1.692
1.386
60.7
0.9
70.6
76.5
75.6
WW%
fine coarse medium fine
REMARKS / SAMPLE DESCRIPTIONPI
BH13-1
BH13-1
BH13-2
BH13-3
BH13-4
SANDSILT OR CLAY
DEPTH (m) CU
W
0.1
1.1
0.3
0.3
0.2
12.011
18.108
17.749
17.615
7.863
13.345
13.819
13.112
125.682
150.163
32.901
45.146
30.3
19.5
21.3
19.2
19.0
9.0
79.6
8.1
4.3
5.4
BH13-1
BH13-1
BH13-2
BH13-3
BH13-4
0.1
1.1
0.3
0.3
0.2
SA1
SA2
SA1
SA1
SA1
KC
B_G
RA
IN_S
IZE
-SI
P09842A
01 H
IGH
WA
Y 7
.GP
J
SIE
VE
.GD
T
5/1
/13
SIEVE OPENINGS IN INCHES U.S. SIEVE NUMBERS
6 3 1.5 3/4 3/8 4 10 20 40 60 100 200
DRAWN BY: CHECKED BY:SH JG
PROJECT NO.:
PROJECT:
LOCATION:
FIGURE:
Mission, B.C.
P09842A01
Highway 7 Four Laning
0
10
20
30
40
50
60
70
80
90
100
0.0010.010.1110100
D85
PE
RC
EN
T F
INE
R B
Y W
EIG
HT
GRAIN SIZE(mm)
D10 %FINES
L PDEPTH (m)
HOLE
coarse
D15
GRAIN SIZE DISTRIBUTION
D50 %GRAVEL %SANDD60
CU = COEFFICIENT OF UNIFORMITY = D60/D10 PARTICLE SIZES, e.g. D85, in mm Tested by Wet Sieving Method (ASTM D1140 & D422)
SAMPLE
COBBLESGRAVEL
HOLE
18.216
25.948
13.958
26.202
0.079
0.113
0.160
0.250
0.229
0.280
0.257
58.3
63.9
49.6
45.3
WW%
fine coarse medium fine
REMARKS / SAMPLE DESCRIPTIONPI
BH13-5
BH13-5
BH13-6
BH13-6
SANDSILT OR CLAY
DEPTH (m) CU
W
0.1
0.2
0.1
0.5
8.525
9.386
6.741
7.077
6.191
7.063
4.635
2.939
131.935
118.219
59.416
44.189
31.2
26.3
42.1
48.6
10.5
9.8
8.3
6.0
BH13-5
BH13-5
BH13-6
BH13-6
0.1
0.2
0.1
0.5
SA1
SA2
SA1
SA2
KC
B_G
RA
IN_S
IZE
-SI
P09842A
01 H
IGH
WA
Y 7
.GP
J
SIE
VE
.GD
T
5/1
/13
SIEVE OPENINGS IN INCHES U.S. SIEVE NUMBERS
6 3 1.5 3/4 3/8 4 10 20 40 60 100 200
DRAWN BY: CHECKED BY:SH JG
PROJECT NO.:
PROJECT:
LOCATION:
FIGURE:
Mission, B.C.
P09842A01
Highway 7 Four Laning
Hole Sample Depth Wet Weight Dry Weight Tare Water Total Dry Water
Number Number (m) + Tare (g) + Tare (g) (g) Weight (g) Weight (g) Content (%)
BH13-1 SA3 2.7 476.85 410.58 170.49 66.27 240.09 27.60
BH13-1 SA4 3.7 446.51 375.52 178.19 70.99 197.33 35.98
BH13-1 SA5 4.3 549.46 457.50 161.76 91.96 295.74 31.09
BH13-2 SA2 0.5 436.31 375.11 163.95 61.20 211.16 28.98
BH13-2 SA3 2.7 461.39 387.79 157.16 73.60 230.63 31.91
BH13-2 SA4 4.3 423.72 354.97 156.74 68.75 198.23 34.68
BH13-3 SA2 1.1 411.15 346.67 170.15 64.48 176.52 36.53
BH13-3 SA3 2.7 439.95 360.30 162.07 79.65 198.23 40.18
BH13-3 SA4 4.3 448.95 360.99 155.03 87.96 205.96 42.71
BH13-4 SA2 1.2 416.93 339.46 170.16 77.47 169.30 45.76
BH13-4 SA3 2.7 461.02 363.61 162.03 97.41 201.58 48.32
BH13-4 SA4 4.3 399.32 321.74 157.93 77.58 163.81 47.36
BH13-5 SA3 2.6 498.39 384.30 161.14 114.09 223.16 51.12
BH13-5 SA4 4.4 456.29 373.78 181.20 82.51 192.58 42.84
PROJECT NO: P09842A01
PROJECT: Highway 7 Four Laning
LOCATION: BC
DATE: April 25, 2013
TESTED BY: SH CHECKED BY: JG
WATER CONTENT OF SOIL
(ASTM D2216)
January 2013 Doc. #IT-15 Rev. #2
U:\Staff\Lab\2013\P09842A02 - Highway 7\Working files\P09842A01 Water Content.xlsx
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
P09842A01 ‐ Geotechnical Factual Report ‐ 20130627.docx
P09842A01 June 2013
APPENDIX III
Rock Mapping Results
Scanline measurements
P09842A02 Project name: Date: 22-Mar-13
5445065 Easting [m]: Elevation [m]:
~115 Outcrop height [m]: 0.5 to 3-4 Outcrop dip/dip direction [°]:
SC13-01 135 Scanline length [m]: ~110
Varies
Discontinuity data:
Above Below Left Right
86 283 B U RC FC AJ 5 Rusty sand dry 0 - 20 J
21 50 B P AJ AJ 2-3 Brecciated dry B
80 280 Roughness U RC FC 10-20 - Brecciated dry 20-30 J
13 215 B P 2-3 AJ AJ 2-3 - sand dry 30 J
68 294 B U 1 RC FC 2-3 - Brecciated dry 31 J
38 184 B P 2-3 AJ AJ 1-2 - - dry 35 J
14 63 B U 2-3 AJ AJ 10-20 - dry 33 J
85 320 B U 2-3 RC FC 1-2 - dry 38 J
90 266 B U 2-3 RC FC 1-3 - dry 40 J
87 240 F U 2-3 RC FC 1-3 - dry 51 J
87 279 F U 2 RC FC - gauge dry 50 J
77 84 B U 1 AJ AJ 10 - dry 55 J
42 264 B P 1-2 RC UN AJ UN - - dry J
90 235 B P 1-2 RC FC - dry J
85 76 B P 1-2 RC FC 10 - dry 58 J
86 270 B S 1-2 RC FC 1-2 - dry 70 J
87 281 B S 1-2 RC FC 1-2 - dry 75 J
77 88 B S 1-2 RC FC 1-2 - Brecciated dry 90 J
42 45 B S 2-3 RC FC UN 1-3 - Brecciated dry 110 J
Notation:
R Rough S Stepped AJ S Shear
B Smooth U Undulating IR J Joint
F Slickensided P Planar FC V Vein (sealed)
RC C Cleavage
UN B Bedding
F Foliation
Scanline plunge [°]:
Termination Position along line [m] Type
Unknown
Type
Another joint
Intact rock
Floor censored
Roof censored
WavinessRoughness Termination (T1)
Scanline ID:
Outcrop GSI:
Comments:
Weathering Infilling Water conditionDip [°] Dip direction [°] Roughness
Scanline trend [°]:
Waviness Trace length [m] Aperture [mm]
Rock description:
MoT Hwy 7 4 Laning
543802
Project no:
Northing [m]:
Outcrop width [m]:
Scanline measurements
P09842A02 Project name: Date: 22-Mar-13
5444983 Easting [m]: Elevation [m]:
33 Outcrop height [m]: 2 Outcrop dip/dip direction [°]:
SC13-02 130 4 Scanline length [m]: 33
Varies
Discontinuity data:
Above Below Left Right
50 59 R U 1 RC FC UN AJ 10-20 - sand dry 1 J
28 75 R U 2-3 RC FC UN IR 3-4 - - dry 7 J
73 343 R S 2-3 RC FC UN 10 - - dry 9 J
37 65 R S 5 RC FC UN 1-2 - - dry 18-Dec J
88 105 R S 1-2 RC FC 0-3 - - dry 19 J
90 354 R S 1 RC FC UN 0 - - dry 22 J
77 78 R S 2 RC FC UN 1 - - dry 24 J
67 65 R S 4 RC FC UN 2 - sand dry 24 J
90 326 R S 1 RC FC 30 - Brecciated dry 28 J
Notation:
R Rough S Stepped AJ S Shear
B Smooth U Undulating IR J Joint
F Slickensided P Planar FC V Vein (sealed)
RC C Cleavage
UN B Bedding
F Foliation
Scanline plunge [°]:
Termination Position along line [m] Type
Unknown
Type
Another joint
Intact rock
Floor censored
Roof censored
WavinessRoughness Termination (T1)
Scanline ID:
Outcrop GSI:
Comments:
Weathering Infilling Water conditionDip [°] Dip direction [°] Roughness
Scanline trend [°]:
Waviness Trace length [m] Aperture [mm]
Rock description:
MoT Hwy 7 4 Laning
543881
Project no:
Northing [m]:
Outcrop width [m]:
R.F. Binnie and Associates Highway 7 Four Laning – Silverdale to Nelson Street
Geotechnical Factual Report
P09842A01 ‐ Geotechnical Factual Report ‐ 20130627.docx
P09842A01 June 2013
APPENDIX IV
AGAT Laboratory Testing Results
CLIENT NAME: KLOHN CRIPPEN BERGER#500-2955 VIRTUAL WAYVANCOUVER, BC V5M4X6 (604) 669-3800
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
Angela Bond, Technical ReviewerWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 8
Apr 04, 2013
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (778) 452-4000
13V699518AGAT WORK ORDER:
ATTENTION TO: Veronica Lau
PROJECT NO: P09842A02
Laboratories (V1) Page 1 of 8
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers, Geologists and Geophysicists of Alberta (APEGGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items tested
WS13-002WS13-001 WS13-003 WS13-004 WS13-005SAMPLE DESCRIPTION:
WaterWaterWater Water WaterSAMPLE TYPE:
3/22/20133/22/2013 3/22/2013 3/22/20133/22/2013DATE SAMPLED:
4216630 4216631 4216632 4216633 4216634G / S RDLUnitParameter
13.2 2.30 2.84 11.4 2.14Chloride 0.05mg/L
4.0 2.5 2.1 4.2 1.7Sulphate 0.5mg/L
0.05 0.05 0.03 0.04 0.03Fluoride 0.02mg/L
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2013-03-23
Certificate of Analysis
ATTENTION TO: Veronica LauCLIENT NAME: KLOHN CRIPPEN BERGER
AGAT WORK ORDER: 13V699518
DATE REPORTED: 2013-04-04
PROJECT NO: P09842A02
Anion Scan
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 8
WS13-002WS13-001 WS13-003 WS13-004 WS13-005SAMPLE DESCRIPTION:
WaterWaterWater Water WaterSAMPLE TYPE:
3/22/20133/22/2013 3/22/2013 3/22/20133/22/2013DATE SAMPLED:
4216630 4216631 4216632 4216633 4216634G / S RDLUnitParameter
1220 491 302 123 239Aluminum Total 1µg/L
0.14 <0.05 <0.05 0.12 <0.05Antimony Total 0.05µg/L
0.6 0.7 0.6 0.9 0.2Arsenic Total 0.1µg/L
15.1 11.3 7.8 15.2 3.1Barium Total 0.1µg/L
<0.05 <0.05 <0.05 <0.05 <0.05Beryllium Total 0.05µg/L
15 8 6 11 6Boron Total 2µg/L
0.05 0.02 0.01 0.01 <0.01Cadmium Total 0.01µg/L
6680 6390 5780 20400 4910Calcium Total 50µg/L
2.3 1.2 0.8 1.0 <0.5Chromium Total 0.5µg/L
0.88 0.56 0.31 0.68 0.14Cobalt Total 0.05µg/L
13.7 4.1 2.4 8.8 1.6Copper Total 0.5µg/L
1570 840 580 2240 210Iron Total 10µg/L
1.52 0.12 0.08 0.77 0.04Lead Total 0.01µg/L
0.8 0.4 0.3 0.2 0.2Lithium Total 0.1µg/L
1230 1840 1650 1770 1450Magnesium Total 50µg/L
54 42 37 108 4Manganese Total 1µg/L
<0.003 0.003 <0.003 0.004 <0.003Mercury Total 0.003µg/L
0.2 0.3 0.2 0.4 <0.1Molybdenum Total 0.1µg/L
2.9 3.4 1.7 2.3 <0.5Nickel Total 0.5µg/L
<0.3 <0.3 <0.3 <0.3 <0.3Selenium Total 0.3µg/L
0.01 <0.01 <0.01 0.02 <0.01Silver Total 0.01µg/L
11600 3500 3800 7800 3800Sodium Total 100µg/L
<0.01 <0.01 <0.01 <0.01 <0.01Thallium Total 0.01µg/L
63 36 26 44 19Titanium Total 1µg/L
0.04 0.03 0.01 0.02 <0.01Uranium Total 0.01µg/L
3.0 2.7 2.1 1.4 1.2Vanadium Total 0.5µg/L
21 <5 6 <5 <5Zinc Total 5µg/L
21700 23500 21200 58200 18200Total Hardness (calc) 100ug CaCO3/L
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2013-03-23
Certificate of Analysis
ATTENTION TO: Veronica LauCLIENT NAME: KLOHN CRIPPEN BERGER
AGAT WORK ORDER: 13V699518
DATE REPORTED: 2013-04-04
PROJECT NO: P09842A02
British Columbia CSR- Schedule 6 Total Metals
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
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CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 8
WS13-002WS13-001 WS13-003 WS13-004 WS13-005SAMPLE DESCRIPTION:
WaterWaterWater Water WaterSAMPLE TYPE:
3/22/20133/22/2013 3/22/2013 3/22/20133/22/2013DATE SAMPLED:
4216630 4216631 4216632 4216633 4216634G / S RDLUnitParameter
6.70 6.90 6.86 6.99 7.36pH 0.01pH units
95 64 60 151 52Electrical Conductivity 1uS/cm
23 25 24 61 21Alkalinity (pH 4.5) 1mg CaCO3/L
<5 15 15 35 13Total Dissolved Solids 5mg/L
331 159 3 2 3Total Suspended Solids 2mg/L
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:4216630-4216634 Literature holding time is exceeded for pH analysis.
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2013-03-23
Certificate of Analysis
ATTENTION TO: Veronica LauCLIENT NAME: KLOHN CRIPPEN BERGER
AGAT WORK ORDER: 13V699518
DATE REPORTED: 2013-04-04
PROJECT NO: P09842A02
Routine Water Analysis
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
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CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 4 of 8
Anion Scan
Chloride 17706 4216630 13.2 13.2 0.0% < 0.05 104% 85% 115% 99% 90% 110%
Sulphate 17706 4216630 4.0 4.0 0.0% < 0.5 104% 85% 115% 103% 90% 110%
Fluoride 17706 4216630 0.05 0.05 0.0% < 0.02 99% 85% 115% 97% 90% 110%
Routine Water Analysis
pH 15660 4216630 6.70 6.73 0.4% < 0.01 99% 90% 110% 100% 95% 105%
Electrical Conductivity 15660 4216630 95 96 1.0% < 1 106% 90% 110% 99% 90% 110%
Alkalinity (pH 4.5) 15660 4216630 23 23 0.0% < 1 108% 85% 115% 105% 90% 110%
Total Dissolved Solids 15671 4223260 6200 6440 3.8% < 5 85% 85% 115% 90% 70% 130%
Total Suspended Solids
15671 4223260 22 19 14.6% < 2 89% 80% 120% 80% 70% 130%
British Columbia CSR- Schedule 6 Total Metals
Aluminum Total 11969 4216630 1220 1100 10.3% < 1 87% 85% 115% 99% 85% 115%
Antimony Total 11969 4216630 0.14 0.12 15.4% < 0.05 103% 85% 115% 102% 90% 110%
Arsenic Total 11969 4216630 0.6 0.6 0.0% < 0.1 107% 85% 115% 99% 90% 110%
Barium Total 11969 4216630 15.1 14.1 6.8% < 0.1 88% 85% 115% 94% 90% 110%
Beryllium Total
11969 4216630 <0.05 <0.05 0.0% < 0.05 107% 85% 115% 108% 90% 110%
Boron Total 11969 4216630 15 15 0.0% < 2 98% 85% 115% 105% 80% 120%
Cadmium Total 11969 4216630 0.05 0.05 0.0% < 0.01 100% 85% 115% 103% 90% 110%
Calcium Total 11969 4216630 6680 6690 0.1% < 50 101% 85% 115% 103% 90% 110%
Chromium Total 11969 4216630 2.3 2.1 9.1% < 0.5 100% 85% 115% 107% 90% 110%
Cobalt Total
11969 4216630 0.88 0.86 2.3% < 0.05 99% 85% 115% 106% 90% 110%
Copper Total 11969 4216630 13.7 13.7 0.0% < 0.5 101% 85% 115% 109% 90% 110%
Iron Total 11969 4216630 1570 1420 10.0% < 10 105% 85% 115% 102% 90% 110%
Lead Total 11969 4216630 1.52 1.44 5.4% < 0.01 99% 85% 115% 106% 90% 110%
Lithium Total 11969 4216630 0.8 0.7 13.3% < 0.1 107% 90% 110%
Magnesium Total
11969 4216630 1230 1170 5.0% < 50 105% 85% 115% 108% 90% 110%
Manganese Total 11969 4216630 54 50 7.7% < 1 103% 85% 115% 103% 90% 110%
Mercury Total 11949 4217014 <0.003 <0.003 0.0% < 0.003 98% 85% 115% 108% 90% 110%
Molybdenum Total 11969 4216630 0.2 0.2 0.0% < 0.1 96% 85% 115% 104% 90% 110%
Nickel Total 11969 4216630 2.9 2.8 3.5% < 0.5 101% 85% 115% 107% 90% 110%
Selenium Total
11969 4216630 <0.3 <0.3 0.0% < 0.3 110% 85% 115% 87% 85% 115%
Silver Total 11969 4216630 0.01 0.01 0.0% < 0.01 104% 90% 110%
Sodium Total 11969 4216630 11600 11600 0.0% < 100 102% 85% 115% 106% 90% 110%
Thallium Total 11969 4216630 <0.01 <0.01 0.0% < 0.01 92% 85% 115% 95% 90% 110%
Titanium Total 11969 4216630 62 58 6.7% < 1 109% 90% 110%
Uranium Total
11969 4216630 0.04 0.04 0.0% < 0.01 100% 90% 110%
Vanadium Total 11969 4216630 3.6 3.8 5.4% < 0.5 98% 85% 115% 108% 90% 110%
Zinc Total 11969 4216630 21 22 4.7% < 5 109% 85% 115% 108% 80% 120%
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699518
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: P09842A02
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Apr 04, 2013 REFERENCE MATERIAL
MethodBlank
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
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QUALITY ASSURANCE REPORT (V1) Page 5 of 8
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699518
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: P09842A02
Water Analysis (Continued)
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: Apr 04, 2013 REFERENCE MATERIAL
MethodBlank
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
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Certified By:QUALITY ASSURANCE REPORT (V1) Page 6 of 8
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
Chloride INOR-181-6002 Modified from SM 4110 B ION CHROMATOGRAPH
Sulphate INOR-181-6002 Modified from SM 4110 B ION CHROMATOGRAPH
Fluoride INOR-181-6002 Modified from SM 4110 B ION CHROMATOGRAPH
Aluminum TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Antimony TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Arsenic TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Barium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Beryllium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Boron TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Cadmium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Calcium TotalMET-181-6101, LAB-181-4009
Modified from SM 3120 B ICP/OES
Chromium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Cobalt TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Copper TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Iron TotalMET-181-6101, LAB-181-4009
Modified from SM 3120 B ICP/OES
Lead TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Lithium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Magnesium TotalMET-181-6101, LAB-181-4009
Modified from SM 3120 B ICP/OES
Manganese TotalMET-181-6101, LAB-181-4009
Modified from SM 3120 B ICP/OES
Mercury Total MET-181-6103 Modified from EPA 245.7 CV/AA
Molybdenum TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Nickel TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Selenium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Silver TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Sodium TotalMET-181-6101, LAB-181-4009
Modified from SM 3120 B ICP/OES
Thallium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Titanium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Uranium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Vanadium TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699518
Method Summary
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: P09842A02
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 7 of 8
Zinc TotalMET-181-6102, LAB-181-4009
Modified from SM 3125 B ICP-MS
pH INOR-181-6000 Modified from SM 4500-H+ PH METER
Electrical Conductivity INOR-181-6000 Modified from SM 2510B PC TITRATE
Alkalinity (pH 4.5) INOR-181-6000 Modified from SM 2320 B PC TITRATE
Total Dissolved Solids INOR-181-6007 SM 2540 C, D & E GRAVIMETRIC
Total Suspended Solids INOR-181-6007 SM 2540 C, D & E GRAVIMETRIC
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699518
Method Summary
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: P09842A02
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 8 of 8
Klohn Crippen Berger AGAT Work Order: 13V699729
500-2955 Virtual Way Report Version: 1
Vancouver BC, V5M 4X6 Pages (Including Cover): 4
Veronica Lau
604-669-3800 Analysis Reviewed By: Andrew Garrard, General Manager
604-251-8510 Report Certified By: Andrew Garrard
MOT HWY-7 4-Lane Signature:
PO 9842A02
Reported To: 1 Veronica Lau ([email protected])
2
3
4
03-May-13
Results:
Notes:
CERTIFICATE OF ANALYSIS ▪ COVER PAGE
Should you require any further information regarding this analysis please contact your client services representative at (778) 452 4000
Contact No:
Client:
Mailing Address:
Attention To:
E-mail Address:
Date Reported:
Fax No:
Client Project Name:
Client Project Number:
Veronica Lau ([email protected])
03-May-13
Page: 1 of 4
Invoice:
Results relate only to the items tested and all the items testedNote: All samples are stored at no charge for 90 days. Please contact the lab if you require additional sample storage time.
Submitted To:
Date Submitted:
AGAT WORK ORDER: 13V699729 CLIENT NAME: Klohn Crippen Berger
REPORT VERSION: 1 PROJECT NO: PO 9842A02
S. No.AGAT Sample ID
Client Sample ID Sample Type Condition Received Sample
Wt (g) Sample Receipt Info:1 4216635 SS13-001 Tailings Wet 695 Date Samples Received: 25-Mar-13 / 28-Mar-13
2 4216636 SS13-002 Tailings Wet 275 No. of Samples Received: 6
3 4216637 SS13-003 Tailings Wet 320 Samples Received By: Sandra Napier
4 4216728 SS13-004 Tailings Wet 477
5 4232389 SS13-01-01 Rock Dry 443
6 4232397 SS13-01-03 Rock Dry 474 Analytical Instructions:From: Veronica Lau
Date: 28-Mar-13
Date of Analysis:Paste pH: 24-Apr-13
Fizz Rating: 24-Apr-13
Rinse pH: 26-Apr-13
Total Sulphur: 30-Apr-13
Sulphate Sulphur: 23-Apr-13
Neutralization Potential (NP): 25-Apr-13
2684
Page: 2 of 4
CERTIFICATE OF ANALYSIS ▪ SAMPLE DETAILS
Results relate only to the items tested and all the items tested
Total Sample Weight Received (g):
AGAT WORK ORDER: 13V699729 CLIENT NAME: Klohn Crippen Berger
REPORT VERSION: 1 PROJECT NO: PO 9842A02
Mod. ABA NPS. No. AGAT Client Paste Fizz Rinse Total Sulphate Sulphide Maximum Potential Neutralization Net Neutralization Neutralization
Sample ID Sample ID pH Rating pH Sulphur Sulphur Sulphur Acidity (MPA) Potential (NP) Potential (NNP) Potential Ratio (NPR)Units: pH Units pH Units (wt %) (wt %) (wt %) (kg CaCO3/tonne) (kg CaCO3/tonne) (kg CaCO3/tonne)
0.1 0.1 0.005 0.005 0.005 0.21 4216636 SS13-002 7.1 None 6.3 0.012 0.008 <0.005 <0.2 8.1 8.1 60.3
2 4216637 SS13-003 6.2 None 5.7 0.042 0.010 0.033 1.0 2.8 1.8 2.8
3 4216728 SS13-004 6.2 None 5.4 0.042 0.011 0.031 1.0 4.5 3.5 4.6
4 4232389 SS13-01-01 8.9 None 0.107 <0.005 0.107 3.3 25.3 22.0 7.6
5 4232397 SS13-01-03 8.6 None 0.041 <0.005 0.041 1.3 42.4 41.1 33.1
1 4216636 SS13-002 7.1 None 0.012 0.008 <0.005 <0.2 8.1 8.1 60.3
1 R 4216636 R SS13-002 7.1 None 0.011 0.008 <0.005 <0.2 7.8 7.8 86.1
2 4216637 SS13-003 5.7
2 R 4216637 R SS13-003 5.7
SU-1b RTS-1 KZK-1
14.14 1.26 58.9
14.20 1.09 52.5
<0.01
110
Notes:pH of DI water used: 5.78
EC of DI water used: 1.0 µS/cm
R = Replicate; D = Duplicate
CERTIFICATE OF ANALYSIS ▪ ABA RESULTS
Reported Detection Limit (RDL):
Page: 3 of 4 Results relate only to the items tested and all the items tested
Ref. Material Certified/Informational Value
Reference Material Results
QUALITY ASSURANCE
Method Blank Spike Recovery (%)
Replicate Analysis:
Reference Material
Method Blank Results
Reference Material Analysis:
Method Blank Analysis:
AGAT WORK ORDER: 13V699729 CLIENT NAME: Klohn Crippen Berger
REPORT VERSION: 1 PROJECT NO: PO 9842A02
Parameter AGAT S.O.P Analytical Technique
Sample Preparation ARD-181-18007 Crusher/Pulverizer
Paste pH (Near Saturation) ARD-181-18003 pH Meter
Rinse pH ARD-181-18002 pH Meter
Total Sulphur MIN-200-12000 LECO
ARD-181-18009 MEND Report 1.20.1, Version 0, (2009); HCl Extraction
INOR-181-6028 UV-Vis Spectrophotometer
Sulphide Sulphur Calculation
Maximum Potential Acidity Calculation
Net Neutralization Potential Calculation
Neutralization Potential Ratio Calculation
Page: 4 of 4
ABA: Air-dried or oven dried at 55 ± 5 °C (if samples arrive wet), crushed (if necessary), split by riffling, and pulverized to 80% passing 200 mesh (75 µm).
Modified ABA NP: A pulp sample is digested with a known excess of standardized HCl at room temperature for a period of 24 hours in order to determine the amount of neutralizing bases present in the sample. The residual acid solution is titrated to pH 8.3 with standardized NaOH in order to determine the amount of acid consumed by the original sample.
Paste pH: DDI water is added to the prepared sample to form a paste at near saturation. The volume of water added varies depending on the sample's tendency to absorb water. A pH probe is placed in the paste slurry and the pH is read directly from the meter.
Fizz Rating: One to two drops of 25% HCl is added to a sample aliquot and the degree of reaction observed and rated. The presence of CaCO3 is indicated by a bubbling or audible "fizz" sound.
Rinse pH: Samples are sieved to <2 mm without crushing or pulverization. A sample aliquot is mixed in a 1:1 soil:water ratio and the resulting supernatant pH measrued using a pH meter.
Sulphate Sulphur: Pulp samples are treated with dilute hydrochloric acid and boiled for 30 minutes at ~80 °C. The digested sample is then re-constituted with DI water and filtered. Filtered extracts are then analyzed by the turbidimetric method using a UV-Vis spectrophotometer. The analytical results are back-calculated to the initial pulp sample weight and expressed in weight % Sulphate Sulphur.
Titration
Results relate only to the items tested and all the items tested
Analytical
Sample Preparation
METHOD DESCRIPTIONS:
CALCULATIONS:
Sulphide Sulphur: difference between total sulphur and sulphate sulphur
Maximum Potential Acidity (MPA): is based on sulphide sulphur
Net Neutralization Potential (NNP): difference between NP and MPA
Neutralization Potential Ratio (NPR): NP/MPA
CERTIFICATE OF ANALYSIS ▪ METHOD SUMMARY
Fizz Rating ARD-181-18000
Lawrence, R. W., Poling, G.P. and Marchant, P.B.; Investigation of predictive techniques for acid mine drainage, MEND Report 1.16.1a (1989); MEND Acid Rock Drainage Prediction Manual, MEND Project 1.16.1b (sect. 6.2.3 p. 34-37) (March 1991)
MEND Report 1.20.1, Chapter 11.6 (2009)
ASTM E1915-07a
Observation
Literature Reference
ASTM E877-08; MEND Report 1.20.1, Version 0 (2009)
Sobek, A.A., Schuller, W.A., Freeman, J.R. and Smith, R.M.; EPA-600/2-78-054 (1978)
SM 4500-SO42- E
Sulphate Sulphur
Neutralization Potential (Modified ABA NP) ARD-181-18000
Lawrence, R. W., Poling, G.P. and Marchant, P.B.; Investigation of predictive techniques for acid mine drainage, MEND Report 1.16.1a (1989); MEND Acid Rock Drainage Prediction Manual, MEND Project 1.16.1b (sect. 6.2.3 p. 34-37) (March 1991)
CLIENT NAME: MISC AGAT CLIENT ON, ON(403)
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Yufei Chen, AnalystSOLID ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 19
Apr 09, 2013
Should you require any information regarding this analysis please contact your client services representative at (905) 501-9998
13T703326AGAT WORK ORDER:
ATTENTION TO: KLOHN CRIPPEN BERGER
PROJECT NO: 13V699729
Laboratories (V1) Page 1 of 19
All samples are stored at no charge for 90 days. Please contact the lab if you require additional sample storage time.
*NOTES
Results relate only to the items tested and to all the items tested
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Ag 0.07ppm 0.01 Apr 08, 2013 Apr 07, 2013
Al 2.91% 0.01 Apr 08, 2013 CL Apr 07, 2013
As 8.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Au <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
B <5ppm 5 Apr 08, 2013 CL Apr 07, 2013
Ba 237ppm 1 Apr 08, 2013 CL Apr 07, 2013
Be 0.48ppm 0.05 Apr 08, 2013 Apr 07, 2013
Bi 0.14ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ca 0.70% 0.01 Apr 08, 2013 CL Apr 07, 2013
Cd 0.18ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ce 34.0ppm 0.01 Apr 08, 2013 Apr 07, 2013
Co 17.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Cr 225ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Cs 0.94ppm 0.05 Apr 08, 2013 Apr 07, 2013
Cu 41.4ppm 0.1 Apr 08, 2013 CL Apr 07, 2013
Fe 3.89% 0.01 Apr 08, 2013 CL Apr 07, 2013
Ga 8.76ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ge 0.13ppm 0.05 Apr 08, 2013 Apr 07, 2013
Hf 0.05ppm 0.02 Apr 08, 2013 Apr 07, 2013
Hg 0.04ppm 0.01 Apr 08, 2013 Apr 07, 2013
In 0.038ppm 0.005 Apr 08, 2013 Apr 07, 2013
K 0.27% 0.01 Apr 08, 2013 CL Apr 07, 2013
La 16.3ppm 0.1 Apr 08, 2013 Apr 07, 2013
Li 15.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Mg 1.00% 0.01 Apr 08, 2013 CL Apr 07, 2013
Mn 720ppm 1 Apr 08, 2013 Apr 07, 2013
Mo 2.44ppm 0.05 Apr 08, 2013 Apr 07, 2013
Na 0.14% 0.01 Apr 08, 2013 CL Apr 07, 2013
Nb 0.21ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ni 46.7ppm 0.2 Apr 08, 2013 CL Apr 07, 2013
P 692ppm 10 Apr 08, 2013 CL Apr 07, 2013
Pb 12.8ppm 0.1 Apr 08, 2013 Apr 07, 2013
Rb 15.6ppm 0.1 Apr 08, 2013 Apr 07, 2013
Re <0.001ppm 0.001 Apr 08, 2013 Apr 07, 2013
S 0.013% 0.005 Apr 08, 2013 CL Apr 07, 2013
Sb 0.64ppm 0.05 Apr 08, 2013 Apr 07, 2013
Sc 8.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216636A - (Client ID: SS13-002)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244852
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 2 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Se 0.3ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sn 0.8ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sr 116ppm 0.2 Apr 08, 2013 Apr 07, 2013
Ta <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
Te 0.08ppm 0.01 Apr 08, 2013 Apr 07, 2013
Th 4.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Ti 0.118% 0.005 Apr 08, 2013 CL Apr 07, 2013
Tl 0.15ppm 0.01 Apr 08, 2013 Apr 07, 2013
U 1.21ppm 0.05 Apr 08, 2013 Apr 07, 2013
V 85.6ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
W 0.18ppm 0.05 Apr 08, 2013 Apr 07, 2013
Y 12.8ppm 0.05 Apr 08, 2013 Apr 07, 2013
Zn 78.1ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Zr 3.3ppm 0.5 Apr 08, 2013 Apr 07, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216636A - (Client ID: SS13-002)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244852
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 3 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Ag 0.17ppm 0.01 Apr 08, 2013 Apr 07, 2013
Al 2.95% 0.01 Apr 08, 2013 CL Apr 07, 2013
As 6.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Au <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
B <5ppm 5 Apr 08, 2013 CL Apr 07, 2013
Ba 276ppm 1 Apr 08, 2013 CL Apr 07, 2013
Be 0.57ppm 0.05 Apr 08, 2013 Apr 07, 2013
Bi 0.20ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ca 0.70% 0.01 Apr 08, 2013 CL Apr 07, 2013
Cd 0.62ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ce 39.6ppm 0.01 Apr 08, 2013 Apr 07, 2013
Co 14.8ppm 0.1 Apr 08, 2013 Apr 07, 2013
Cr 251ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Cs 1.05ppm 0.05 Apr 08, 2013 Apr 07, 2013
Cu 79.9ppm 0.1 Apr 08, 2013 CL Apr 07, 2013
Fe 3.15% 0.01 Apr 08, 2013 CL Apr 07, 2013
Ga 9.00ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ge 0.13ppm 0.05 Apr 08, 2013 Apr 07, 2013
Hf 0.09ppm 0.02 Apr 08, 2013 Apr 07, 2013
Hg 0.07ppm 0.01 Apr 08, 2013 Apr 07, 2013
In 0.044ppm 0.005 Apr 08, 2013 Apr 07, 2013
K 0.28% 0.01 Apr 08, 2013 CL Apr 07, 2013
La 20.1ppm 0.1 Apr 08, 2013 Apr 07, 2013
Li 16.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Mg 0.89% 0.01 Apr 08, 2013 CL Apr 07, 2013
Mn 454ppm 1 Apr 08, 2013 Apr 07, 2013
Mo 2.45ppm 0.05 Apr 08, 2013 Apr 07, 2013
Na 0.07% 0.01 Apr 08, 2013 CL Apr 07, 2013
Nb 1.19ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ni 51.5ppm 0.2 Apr 08, 2013 CL Apr 07, 2013
P 816ppm 10 Apr 08, 2013 CL Apr 07, 2013
Pb 31.3ppm 0.1 Apr 08, 2013 Apr 07, 2013
Rb 16.7ppm 0.1 Apr 08, 2013 Apr 07, 2013
Re <0.001ppm 0.001 Apr 08, 2013 Apr 07, 2013
S 0.035% 0.005 Apr 08, 2013 CL Apr 07, 2013
Sb 0.82ppm 0.05 Apr 08, 2013 Apr 07, 2013
Sc 8.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216637A - (Client ID: SS13-003)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244853
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 4 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Se 0.6ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sn 0.8ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sr 73.7ppm 0.2 Apr 08, 2013 Apr 07, 2013
Ta <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
Te 0.08ppm 0.01 Apr 08, 2013 Apr 07, 2013
Th 4.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Ti 0.098% 0.005 Apr 08, 2013 CL Apr 07, 2013
Tl 0.16ppm 0.01 Apr 08, 2013 Apr 07, 2013
U 1.44ppm 0.05 Apr 08, 2013 Apr 07, 2013
V 90.6ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
W 0.19ppm 0.05 Apr 08, 2013 Apr 07, 2013
Y 14.3ppm 0.05 Apr 08, 2013 Apr 07, 2013
Zn 120ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Zr 4.0ppm 0.5 Apr 08, 2013 Apr 07, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216637A - (Client ID: SS13-003)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244853
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 5 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Ag 0.13ppm 0.01 Apr 08, 2013 Apr 07, 2013
Al 2.19% 0.01 Apr 08, 2013 CL Apr 07, 2013
As 1.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Au <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
B 6ppm 5 Apr 08, 2013 CL Apr 07, 2013
Ba 156ppm 1 Apr 08, 2013 CL Apr 07, 2013
Be 0.30ppm 0.05 Apr 08, 2013 Apr 07, 2013
Bi 0.02ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ca 1.70% 0.01 Apr 08, 2013 CL Apr 07, 2013
Cd 0.05ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ce 52.6ppm 0.01 Apr 08, 2013 Apr 07, 2013
Co 8.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Cr 130ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Cs 0.47ppm 0.05 Apr 08, 2013 Apr 07, 2013
Cu 193ppm 0.1 Apr 08, 2013 CL Apr 07, 2013
Fe 3.62% 0.01 Apr 08, 2013 CL Apr 07, 2013
Ga 9.98ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ge 0.15ppm 0.05 Apr 08, 2013 Apr 07, 2013
Hf 0.19ppm 0.02 Apr 08, 2013 Apr 07, 2013
Hg 0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
In 0.023ppm 0.005 Apr 08, 2013 Apr 07, 2013
K 0.22% 0.01 Apr 08, 2013 CL Apr 07, 2013
La 24.3ppm 0.1 Apr 08, 2013 Apr 07, 2013
Li 6.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Mg 0.92% 0.01 Apr 08, 2013 CL Apr 07, 2013
Mn 354ppm 1 Apr 08, 2013 Apr 07, 2013
Mo 2.05ppm 0.05 Apr 08, 2013 Apr 07, 2013
Na 0.49% 0.01 Apr 08, 2013 CL Apr 07, 2013
Nb 1.36ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ni 5.5ppm 0.2 Apr 08, 2013 CL Apr 07, 2013
P 2630ppm 10 Apr 08, 2013 CL Apr 07, 2013
Pb 2.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Rb 4.3ppm 0.1 Apr 08, 2013 Apr 07, 2013
Re 0.002ppm 0.001 Apr 08, 2013 Apr 07, 2013
S 0.121% 0.005 Apr 08, 2013 CL Apr 07, 2013
Sb 0.06ppm 0.05 Apr 08, 2013 Apr 07, 2013
Sc 6.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232389A - (Client ID: SS13-01-01)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244854
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 6 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Se 0.3ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sn 1.3ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sr 160ppm 0.2 Apr 08, 2013 Apr 07, 2013
Ta 0.02ppm 0.01 Apr 08, 2013 Apr 07, 2013
Te 0.04ppm 0.01 Apr 08, 2013 Apr 07, 2013
Th 0.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Ti 0.279% 0.005 Apr 08, 2013 CL Apr 07, 2013
Tl 0.07ppm 0.01 Apr 08, 2013 Apr 07, 2013
U 0.20ppm 0.05 Apr 08, 2013 Apr 07, 2013
V 162ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
W 0.20ppm 0.05 Apr 08, 2013 Apr 07, 2013
Y 15.6ppm 0.05 Apr 08, 2013 Apr 07, 2013
Zn 50.3ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Zr 4.2ppm 0.5 Apr 08, 2013 Apr 07, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232389A - (Client ID: SS13-01-01)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244854
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 7 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Al2O3 16.3% 0.01
BaO 0.11% 0.01
CaO 4.58% 0.01
Cr2O3 0.03% 0.01
Fe2O3 7.08% 0.01
K2O 2.22% 0.01
MgO 2.62% 0.01
MnO 0.12% 0.01
Na2O 5.39% 0.01
P2O5 0.55% 0.01
SiO2 56.5% 0.01
TiO2 1.22% 0.01
SrO 0.07% 0.01
V2O5 0.04% 0.01
LOI 2.43% 0.01 Apr 08, 2013 FO
Total 99.2% 0.01 Apr 08, 2013 SYS Apr 08, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232389A - (Client ID: SS13-01-01)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244854
PROJECT NO: 13V699729
Lithium Borate Fusion - Summation of Oxides, XRF finish (201676)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 8 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Ag 0.05ppm 0.01 Apr 08, 2013 Apr 07, 2013
Al 3.68% 0.01 Apr 08, 2013 CL Apr 07, 2013
As 3.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Au <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
B 6ppm 5 Apr 08, 2013 CL Apr 07, 2013
Ba 111ppm 1 Apr 08, 2013 CL Apr 07, 2013
Be 0.26ppm 0.05 Apr 08, 2013 Apr 07, 2013
Bi 0.02ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ca 2.63% 0.01 Apr 08, 2013 CL Apr 07, 2013
Cd 0.06ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ce 42.7ppm 0.01 Apr 08, 2013 Apr 07, 2013
Co 19.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Cr 185ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Cs 0.85ppm 0.05 Apr 08, 2013 Apr 07, 2013
Cu 39.5ppm 0.1 Apr 08, 2013 CL Apr 07, 2013
Fe 3.42% 0.01 Apr 08, 2013 CL Apr 07, 2013
Ga 11.3ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ge 0.11ppm 0.05 Apr 08, 2013 Apr 07, 2013
Hf 0.19ppm 0.02 Apr 08, 2013 Apr 07, 2013
Hg 0.02ppm 0.01 Apr 08, 2013 Apr 07, 2013
In 0.018ppm 0.005 Apr 08, 2013 Apr 07, 2013
K 0.13% 0.01 Apr 08, 2013 CL Apr 07, 2013
La 21.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Li 7.8ppm 0.1 Apr 08, 2013 Apr 07, 2013
Mg 2.16% 0.01 Apr 08, 2013 CL Apr 07, 2013
Mn 450ppm 1 Apr 08, 2013 Apr 07, 2013
Mo 1.37ppm 0.05 Apr 08, 2013 Apr 07, 2013
Na 0.61% 0.01 Apr 08, 2013 CL Apr 07, 2013
Nb 0.16ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ni 76.1ppm 0.2 Apr 08, 2013 CL Apr 07, 2013
P 2000ppm 10 Apr 08, 2013 CL Apr 07, 2013
Pb 4.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Rb 3.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Re <0.001ppm 0.001 Apr 08, 2013 Apr 07, 2013
S 0.062% 0.005 Apr 08, 2013 CL Apr 07, 2013
Sb 0.15ppm 0.05 Apr 08, 2013 Apr 07, 2013
Sc 4.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232397A - (Client ID: SS 13-01-03)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244855
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 9 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Se 0.2ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sn 0.6ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sr 613ppm 0.2 Apr 08, 2013 Apr 07, 2013
Ta <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
Te 0.04ppm 0.01 Apr 08, 2013 Apr 07, 2013
Th 1.7ppm 0.1 Apr 08, 2013 Apr 07, 2013
Ti 0.207% 0.005 Apr 08, 2013 CL Apr 07, 2013
Tl 0.06ppm 0.01 Apr 08, 2013 Apr 07, 2013
U 0.18ppm 0.05 Apr 08, 2013 Apr 07, 2013
V 117ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
W 0.13ppm 0.05 Apr 08, 2013 Apr 07, 2013
Y 9.94ppm 0.05 Apr 08, 2013 Apr 07, 2013
Zn 63.5ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Zr 4.3ppm 0.5 Apr 08, 2013 Apr 07, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232397A - (Client ID: SS 13-01-03)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244855
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 10 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Al2O3 15.4% 0.01
BaO 0.08% 0.01
CaO 7.55% 0.01
Cr2O3 0.05% 0.01
Fe2O3 8.17% 0.01
K2O 1.45% 0.01
MgO 6.42% 0.01
MnO 0.14% 0.01
Na2O 3.51% 0.01
P2O5 0.41% 0.01
SiO2 50.5% 0.01
TiO2 0.95% 0.01
SrO 0.12% 0.01
V2O5 0.03% 0.01
LOI 5.11% 0.01 Apr 08, 2013 FO
Total 99.9% 0.01 Apr 08, 2013 SYS Apr 08, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4232397A - (Client ID: SS 13-01-03)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244855
PROJECT NO: 13V699729
Lithium Borate Fusion - Summation of Oxides, XRF finish (201676)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 11 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Ag 0.10ppm 0.01 Apr 08, 2013 Apr 07, 2013
Al 3.53% 0.01 Apr 08, 2013 CL Apr 07, 2013
As 4.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Au <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
B 5ppm 5 Apr 08, 2013 CL Apr 07, 2013
Ba 240ppm 1 Apr 08, 2013 CL Apr 07, 2013
Be 0.44ppm 0.05 Apr 08, 2013 Apr 07, 2013
Bi 0.12ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ca 0.76% 0.01 Apr 08, 2013 CL Apr 07, 2013
Cd 0.15ppm 0.01 Apr 08, 2013 Apr 07, 2013
Ce 24.0ppm 0.01 Apr 08, 2013 Apr 07, 2013
Co 13.3ppm 0.1 Apr 08, 2013 Apr 07, 2013
Cr 236ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Cs 1.31ppm 0.05 Apr 08, 2013 Apr 07, 2013
Cu 41.8ppm 0.1 Apr 08, 2013 CL Apr 07, 2013
Fe 3.44% 0.01 Apr 08, 2013 CL Apr 07, 2013
Ga 10.2ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ge 0.12ppm 0.05 Apr 08, 2013 Apr 07, 2013
Hf 0.07ppm 0.02 Apr 08, 2013 Apr 07, 2013
Hg 0.05ppm 0.01 Apr 08, 2013 Apr 07, 2013
In 0.042ppm 0.005 Apr 08, 2013 Apr 07, 2013
K 0.26% 0.01 Apr 08, 2013 CL Apr 07, 2013
La 11.9ppm 0.1 Apr 08, 2013 Apr 07, 2013
Li 14.8ppm 0.1 Apr 08, 2013 Apr 07, 2013
Mg 1.18% 0.01 Apr 08, 2013 CL Apr 07, 2013
Mn 418ppm 1 Apr 08, 2013 Apr 07, 2013
Mo 1.22ppm 0.05 Apr 08, 2013 Apr 07, 2013
Na 0.14% 0.01 Apr 08, 2013 CL Apr 07, 2013
Nb 0.59ppm 0.05 Apr 08, 2013 Apr 07, 2013
Ni 38.5ppm 0.2 Apr 08, 2013 CL Apr 07, 2013
P 430ppm 10 Apr 08, 2013 CL Apr 07, 2013
Pb 7.6ppm 0.1 Apr 08, 2013 Apr 07, 2013
Rb 13.2ppm 0.1 Apr 08, 2013 Apr 07, 2013
Re <0.001ppm 0.001 Apr 08, 2013 Apr 07, 2013
S 0.016% 0.005 Apr 08, 2013 CL Apr 07, 2013
Sb 0.42ppm 0.05 Apr 08, 2013 Apr 07, 2013
Sc 10.5ppm 0.1 Apr 08, 2013 Apr 07, 2013
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216728A - (Client ID: SS13-004)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244857
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 12 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
RESULT DATE PREPAREDPARAMETER DATE ANALYZED INITIALRDLUNIT
Se 0.6ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sn 0.7ppm 0.2 Apr 08, 2013 Apr 07, 2013
Sr 79.9ppm 0.2 Apr 08, 2013 Apr 07, 2013
Ta <0.01ppm 0.01 Apr 08, 2013 Apr 07, 2013
Te 0.03ppm 0.01 Apr 08, 2013 Apr 07, 2013
Th 2.4ppm 0.1 Apr 08, 2013 Apr 07, 2013
Ti 0.171% 0.005 Apr 08, 2013 CL Apr 07, 2013
Tl 0.17ppm 0.01 Apr 08, 2013 Apr 07, 2013
U 0.97ppm 0.05 Apr 08, 2013 Apr 07, 2013
V 110ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
W 0.12ppm 0.05 Apr 08, 2013 Apr 07, 2013
Y 13.2ppm 0.05 Apr 08, 2013 Apr 07, 2013
Zn 82.4ppm 0.5 Apr 08, 2013 CL Apr 07, 2013
Zr 3.2ppm 0.5 Apr 08, 2013 Apr 07, 2013
COMMENTS:
RDL - Reported Detection Limit
Results relate only to the items tested and to all the items tested
SAMPLE DESCRIPTION: 4216728A - (Client ID: SS13-004)
Certificate of Analysis
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
DATE SAMPLED: Apr 05, 2013
DATE RECEIVED: Apr 05, 2013
DATE REPORTED: Apr 09, 2013
SAMPLE TYPE: Soil SAMPLE ID: 4244857
PROJECT NO: 13V699729
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)
AGAT WORK ORDER: 13T703326
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
Page 13 of 19CERTIFICATE OF ANALYSIS (V1)
Certified By:
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)REPLICATE #1
Parameter Sample ID Original Replicate RPD
Ag 1.80 1.81 0.6%
Al 0.454 0.461 1.5%
As 14.7 15.0 2.0%
Au 0.68 0.66 3.0%
B 87 83 4.7%
Ba 212 217 2.3%
Be 0.563 0.620 9.6%
Bi 0.185 0.223 18.6%
Ca 0.40 0.40 0.0%
Cd 1.49 0.25
Ce 50.6 53.2 5.0%
Co 9.04 9.45 4.4%
Cr 62.4 61.6 1.3%
Cs 0.301 0.319 5.8%
Cu < 0.1 < 0.1 0.0%
Fe 52.0 52.5 1.0%
Ga 9.21 9.85 6.7%
Ge 0.13 0.13 0.0%
Hf 0.28 0.33 16.4%
Hg 0.02 0.02 0.0%
In 0.0523 0.0525 0.4%
K 0.01 0.01 0.0%
La 26.6 27.7 4.1%
Li 4.49 5.06 11.9%
Mg 0.015 0.015 0.0%
Mn 196 208 5.9%
Mo 2.28 2.16 5.4%
Na < 0.01 < 0.01 0.0%
Nb 0.204 0.210 2.9%
Ni 19.8 19.7 0.5%
P 2820 2770 1.8%
Results relate only to the items tested and to all the items tested
CLIENT NAME: MISC AGAT CLIENT ON ATTENTION TO: KLOHN CRIPPEN BERGER
PROJECT NO: 13V699729
AGAT WORK ORDER: 13T703326
Quality Assurance - Replicate 5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
QUALITY ASSURANCE REPORT Page 14 of 19
Pb 4.6 4.1 11.5%
Rb 8.29 8.55 3.1%
Re < 0.001 < 0.001 0.0%
S 0.0432 0.0437 1.2%
Sb 0.223 0.237 6.1%
Sc 3.6 3.8 5.4%
Se 0.3 0.3 0.0%
Sn 0.6 0.6 0.0%
Sr 8.9 9.2 3.3%
Ta < 0.01 < 0.01 0.0%
Te 0.20 0.20 0.0%
Th 4.6 4.8 4.3%
Ti 0.036 0.036 0.0%
Tl 0.04 0.04 0.0%
U 2.00 2.05 2.5%
V 1060 1040 1.9%
W 3.05 3.47 12.9%
Y 7.15 7.36 2.9%
Zn 30.9 28.2 9.1%
Zr 9.2 10.7 15.1%
Lithium Borate Fusion - Summation of Oxides, XRF finish (201676)REPLICATE #1
Parameter Sample ID Original Replicate RPD
Al2O3 4244854 16.32 16.21 0.7%
BaO 4244854 0.11 0.13 16.7%
CaO 4244854 4.58 4.57 0.2%
Cr2O3 4244854 0.03 0.03 0.0%
Fe2O3 4244854 7.08 7.05 0.4%
K2O 4244854 2.22 2.24 0.9%
MgO 4244854 2.62 2.61 0.4%
MnO 4244854 0.12 0.12 0.0%
Na2O 4244854 5.39 5.37 0.4%
P2O5 4244854 0.55 0.55 0.0%
SiO2 4244854 56.53 56.34 0.3%
Results relate only to the items tested and to all the items tested
CLIENT NAME: MISC AGAT CLIENT ON ATTENTION TO: KLOHN CRIPPEN BERGER
PROJECT NO: 13V699729
AGAT WORK ORDER: 13T703326
Quality Assurance - Replicate 5623 McADAM ROADMISSISSAUGA, ONTARIO
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QUALITY ASSURANCE REPORT Page 15 of 19
TiO2 4244854 1.22 1.23 0.8%
SrO 4244854 0.07 0.07 0.0%
V2O5 4244854 0.04 0.03 28.6%
Results relate only to the items tested and to all the items tested
CLIENT NAME: MISC AGAT CLIENT ON ATTENTION TO: KLOHN CRIPPEN BERGER
PROJECT NO: 13V699729
AGAT WORK ORDER: 13T703326
Quality Assurance - Replicate 5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
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QUALITY ASSURANCE REPORT Page 16 of 19
Aqua Regia Digest - Metals Package, ICP/ICP-MS finish (201074)CRM #1 (CU186)
Parameter Expect Actual Recovery Limits
Ag 14 13 92% 80% - 120%
Cu 6000 5682 95% 80% - 120%
Mo 360 340 94% 80% - 120%
Lithium Borate Fusion - Summation of Oxides, XRF finish (201676)CRM #1
Parameter Expect Actual Recovery Limits
Al2O3 20.69 20.63 99% 90% - 110%
BaO 0.04 0.04 100% 90% - 110%
CaO 8.05 7.96 98% 90% - 110%
Fe2O3 6.21 6.31 101% 90% - 110%
K2O 1.66 1.65 99% 90% - 110%
MgO 0.54 0.53 98% 90% - 110%
MnO 0.108 0.10 92% 90% - 110%
Na2O 7.10 7.18 101% 90% - 110%
P2O5 0.131 0.12 91% 90% - 110%
SiO2 49.9 49.68 99% 90% - 110%
TiO2 0.287 0.29 101% 90% - 110%
SrO 0.14 0.14 100% 90% - 110%
Results relate only to the items tested and to all the items tested
CLIENT NAME: MISC AGAT CLIENT ON ATTENTION TO: KLOHN CRIPPEN BERGER
PROJECT NO: 13V699729
AGAT WORK ORDER: 13T703326
Quality Assurance - Certified Reference materials 5623 McADAM ROADMISSISSAUGA, ONTARIO
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QUALITY ASSURANCE REPORT Page 17 of 19
Solid Analysis
Ag MIN-200-12017 ICP-MS
Al MIN-200-12017 ICP/OES
As MIN-200-12017 ICP-MS
Au MIN-200-12017 ICP-MS
B MIN-200-12017 ICP/OES
Ba MIN-200-12017 ICP-MS
Be MIN-200-12017 ICP-MS
Bi MIN-200-12017 ICP-MS
Ca MIN-200-12017 ICP/OES
Cd MIN-200-12017 ICP-MS
Ce MIN-200-12017 ICP-MS
Co MIN-200-12017 ICP-MS
Cr MIN-200-12017 ICP/OES
Cs MIN-200-12017 ICP-MS
Cu MIN-200-12017 ICP-MS
Fe MIN-200-12017 ICP/OES
Ga MIN-200-12017 ICP-MS
Ge MIN-200-12017 ICP-MS
Hf MIN-200-12017 ICP-MS
Hg MIN-200-12017 ICP-MS
In MIN-200-12017 ICP-MS
K MIN-200-12017 ICP/OES
La MIN-200-12017 ICP-MS
Li MIN-200-12017 ICP-MS
Mg MIN-200-12017 ICP/OES
Mn MIN-200-12017 ICP/OES
Mo MIN-200-12017 ICP-MS
Na MIN-200-12017 ICP/OES
Nb MIN-200-12017 ICP-MS
Ni MIN-200-12017 ICP-MS
P MIN-200-12017 ICP/OES
Pb MIN-200-12017 ICP-MS
Rb MIN-200-12017 ICP-MS
Re MIN-200-12017 ICP-MS
S MIN-200-12017 ICP/OES
Sb MIN-200-12017 ICP-MS
Sc MIN-200-12017 ICP-MS
Se MIN-200-12017 ICP-MS
Sn MIN-200-12017 ICP-MS
Sr MIN-200-12017 ICP-MS
Ta MIN-200-12017 ICP-MS
Te MIN-200-12017 ICP-MS
Th MIN-200-12017 ICP-MS
Ti MIN-200-12017 ICP/OES
Tl MIN-200-12017 ICP-MS
U MIN-200-12017 ICP-MS
V MIN-200-12017 ICP/OES
W MIN-200-12017 ICP-MS
Y MIN-200-12017 ICP-MS
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13T703326
Method Summary
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
PROJECT NO: 13V699729
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
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METHOD SUMMARY (V1) Page 18 of 19
Zn MIN-200-12017 ICP-MS
Zr MIN-200-12017 ICP-MS
Al2O3 MIN-200-12027 XRF
BaO MIN-200-12027 XRF
CaO MIN-200-12027 XRF
Cr2O3 MIN-200-12027 XRF
Fe2O3 MIN-200-12027 XRF
K2O MIN-200-12027 XRF
MgO MIN-200-12027 XRF
MnO MIN-200-12027 XRF
Na2O MIN-200-12027 XRF
P2O5 MIN-200-12027 XRF
SiO2 MIN-200-12027 XRF
TiO2 MIN-200-12027 XRF
SrO MIN-200-12027 XRF
V2O5 MIN-200-12027 XRF
LOI MIN-200-12021 GRAVIMETRIC
Total MIN-200-12027 CALCULATION
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13T703326
Method Summary
ATTENTION TO: KLOHN CRIPPEN BERGER
CLIENT NAME: MISC AGAT CLIENT ON
PROJECT NO: 13V699729
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
5623 McADAM ROADMISSISSAUGA, ONTARIO
CANADA L4Z 1N9TEL (905)501-9998FAX (905)501-0589
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 19 of 19
CLIENT NAME: KLOHN CRIPPEN BERGER#500-2955 VIRTUAL WAYVANCOUVER, BC V5M4X6 (604) 669-3800
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
Marie England, Inorganics Lab ManagerWATER ANALYSIS REVIEWED BY:
DATE REPORTED:
PAGES (INCLUDING COVER): 7
May 03, 2013
VERSION*: 1
Should you require any information regarding this analysis please contact your client services representative at (778) 452-4000
13V699729AGAT WORK ORDER:
ATTENTION TO: Veronica Lau
PROJECT NO: PO9842A02
Laboratories (V1) Page 1 of 7
All samples will be disposed of within 30 days following analysis. Please contact the lab if you require additional sample storage time.
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Association of Professional Engineers, Geologists and Geophysicists of Alberta (APEGGA)Western Enviro-Agricultural Laboratory Association (WEALA)Environmental Services Association of Alberta (ESAA)
Member of:
*NOTES
Results relate only to the items tested and to all the items tested
SS13-003 SFESS13-002 SFE SS13-004 SFE SS13-01-01 SFE SS13-01-03 SFE
SFE Method
BlankSAMPLE DESCRIPTION:
SFESFESFE SFE SFE SFESAMPLE TYPE:
DATE SAMPLED:
4232954 4233134 4233281 4233282 4233292 4233293G / S RDLUnitParameter
50 50 50 245 245 250Weight of Dry Sample g
150 150 150 735 735 750Volume of DI Water mL
6.40 6.55 6.19 8.74 9.17 7.21pH 0.01pH units
36 61 28 67 105 <2Electrical Conductivity 2uS/cm
0.00012 0.00027 <0.00008 <0.00008 <0.00008 <0.00008Silver 0.00008mg/L
0.347 0.670 0.561 0.252 0.305 <0.001Aluminum 0.001mg/L
0.0007 0.0029 0.0007 0.0005 0.0288 <0.0002Arsenic 0.0002mg/L
0.15 0.17 0.13 0.03 0.04 <0.01Boron 0.01mg/L
0.0033 0.0329 0.0138 0.0006 0.0005 <0.0002Barium 0.0002mg/L
<0.0001 0.0001 <0.0001 <0.0001 <0.0001 <0.0001Beryllium 0.0001mg/L
0.0001 0.0002 <0.0001 <0.0001 <0.0001 <0.0001Bismuth 0.0001mg/L
0.39 4.63 1.48 4.29 3.08 <0.05Calcium 0.05mg/L
0.00001 0.00019 0.00002 <0.00001 <0.00001 <0.00001Cadmium 0.00001mg/L
0.0002 0.0014 0.0005 <0.0001 <0.0001 <0.0001Cobalt 0.0001mg/L
0.0010 0.0085 0.0037 <0.0005 <0.0005 <0.0005Chromium 0.0005mg/L
0.0133 0.0656 0.0162 0.0060 0.0057 0.0020Copper 0.0005mg/L
0.36 0.99 0.37 0.03 0.05 <0.02Iron 0.02mg/L
<0.0005 <0.0005 <0.0005 <0.0005 <0.0005 <0.0005Mercury 0.0005mg/L
0.28 3.14 2.00 0.45 1.72 <0.05Potassium 0.05mg/L
0.0006 0.0021 0.0008 <0.0001 <0.0001 <0.0001Lanthanum 0.0001mg/L
<0.0005 0.0009 <0.0005 0.0008 0.0007 <0.0005Lithium 0.0005mg/L
0.108 1.58 0.404 0.225 0.147 0.007Magnesium 0.005mg/L
0.0036 0.130 0.0131 0.0008 0.0004 <0.0002Manganese 0.0002mg/L
0.0003 0.0013 0.0001 0.0010 0.0016 <0.0001Molybdenum 0.0001mg/L
5.57 3.62 1.42 7.11 14.3 <0.02Sodium 0.02mg/L
0.0033 0.0175 0.0030 0.0006 0.0013 <0.0005Nickel 0.0005mg/L
0.08 0.48 0.06 0.08 0.08 <0.05Phosphorus 0.05mg/L
<0.0005 0.0026 <0.0005 <0.0005 <0.0005 <0.0005Lead 0.0005mg/L
1.0 2.7 1.2 1.5 1.8 <0.5Sulphur 0.5mg/L
0.0006 0.0014 0.0009 <0.0005 <0.0005 <0.0005Selenium 0.0005mg/L
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2013-03-22
Certificate of Analysis
ATTENTION TO: Veronica LauCLIENT NAME: KLOHN CRIPPEN BERGER
AGAT WORK ORDER: 13V699729
DATE REPORTED: 2013-04-30
PROJECT NO: PO9842A02
Shake Flask Extraction - Dissolved Metals
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 2 of 7
SS13-003 SFESS13-002 SFE SS13-004 SFE SS13-01-01 SFE SS13-01-03 SFE
SFE Method
BlankSAMPLE DESCRIPTION:
SFESFESFE SFE SFE SFESAMPLE TYPE:
DATE SAMPLED:
4232954 4233134 4233281 4233282 4233292 4233293G / S RDLUnitParameter
0.0007 0.0012 0.0004 0.0001 0.0003 <0.0001Antimony 0.0001mg/L
7.09 9.08 9.81 2.89 2.56 <0.05Silicon 0.05mg/L
<0.0005 0.0006 <0.0005 <0.0005 <0.0005 <0.0005Tin 0.0005mg/L
0.0076 0.0356 0.0125 0.0117 0.0100 <0.0002Strontium 0.0002mg/L
<0.0002 <0.0002 <0.0002 <0.0002 <0.0002 <0.0002Tellurium 0.0002mg/L
0.0003 0.0008 0.0002 <0.0001 <0.0001 <0.0001Thorium 0.0001mg/L
0.0216 0.0263 0.0191 0.0015 0.0018 <0.0005Titanium 0.0005mg/L
0.00006 <0.00005 <0.00005 <0.00005 <0.00005 <0.00005Thallium 0.00005mg/L
0.00017 0.00054 0.00020 <0.00005 0.00014 <0.00005Uranium 0.00005mg/L
0.0010 0.0084 0.0038 0.0078 0.0379 <0.0005Vanadium 0.0005mg/L
0.0001 0.0001 <0.0001 0.0001 <0.0001 <0.0001Tungsten 0.0001mg/L
0.020 0.011 0.007 <0.001 <0.001 0.004Zinc 0.001mg/L
0.0007 0.0059 0.0023 <0.0001 0.0001 <0.0001Zirconium 0.0001mg/L
RDL - Reported Detection Limit; G / S - Guideline / StandardComments:
Results relate only to the items tested and to all the items tested
DATE RECEIVED: 2013-03-22
Certificate of Analysis
ATTENTION TO: Veronica LauCLIENT NAME: KLOHN CRIPPEN BERGER
AGAT WORK ORDER: 13V699729
DATE REPORTED: 2013-04-30
PROJECT NO: PO9842A02
Shake Flask Extraction - Dissolved Metals
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
CERTIFICATE OF ANALYSIS (V1)
Certified By:Page 3 of 7
Shake Flask Extraction - Dissolved Metals
Silver 12148 4232954 0.00012 0.00014 15.4% < 0.00008 95% 85% 115%
Aluminum 12148 4232954 0.347 0.366 5.3% < 0.001 101% 85% 115%
Arsenic 12148 4232954 0.0007 0.0007 0.0% < 0.0002 110% 85% 115%
Boron 12148 4232954 0.15 0.14 6.9% < 0.01 95% 85% 115%
Barium
12148 4232954 0.0051 0.0051 0.0% < 0.0002 110% 85% 115%
Beryllium 12148 4232954 < 0.0001 < 0.0001 0.0% < 0.0001 101% 85% 115%
Bismuth 12148 4232954 0.0001 < 0.0001 NA < 0.0001 99% 85% 115%
Calcium 12148 4232954 0.39 0.39 0.0% < 0.05 99% 85% 115%
Cadmium 12148 4232954 0.00001 0.00002 NA < 0.00001 103% 85% 115%
Cobalt
12148 4232954 0.0002 0.0002 0.0% < 0.0001 93% 85% 115%
Chromium 12148 4232954 0.0010 0.0014 NA < 0.0005 92% 85% 115%
Copper 12148 4232954 0.0133 0.0140 5.1% < 0.0005 108% 85% 115%
Iron 12148 4232954 0.36 0.37 2.7% < 0.02 102% 85% 115%
Mercury 12148 4232954 < 0.0005 < 0.0005 0.0% < 0.0005 96% 85% 115%
Potassium
12148 4232954 0.28 0.25 11.3% < 0.05 94% 85% 115%
Lanthanum 12148 4232954 0.0006 0.0007 15.4% < 0.0001 99% 85% 115%
Lithium 12148 4232954 < 0.0005 < 0.0005 0.0% < 0.0005 100% 85% 115%
Magnesium 12148 4232954 0.133 0.135 1.5% < 0.005 102% 85% 115%
Manganese 12148 4232954 0.0062 0.0062 0.0% < 0.0002 97% 85% 115%
Molybdenum
12148 4232954 0.0003 0.0004 NA < 0.0001 102% 85% 115%
Sodium 12148 4232954 5.57 5.57 0.0% < 0.02 98% 85% 115%
Nickel 12148 4232954 0.0033 0.0037 11.4% < 0.0005 110% 85% 115%
Phosphorus 12148 4232954 0.08 0.08 0.0% < 0.05 90% 85% 115%
Lead 12148 4232954 < 0.0005 < 0.0005 0.0% < 0.0005 108% 85% 115%
Sulphur
12148 4232954 1.0 1.0 0.0% < 0.5 95% 85% 115%
Selenium 12148 4232954 0.0006 0.0007 15.4% < 0.0005 109% 85% 115%
Antimony 12148 4232954 0.0007 0.0006 15.4% < 0.0001 99% 85% 115%
Silicon 12148 4232954 7.09 7.04 0.7% < 0.05 97% 85% 115%
Tin 12148 4232954 < 0.0005 < 0.0005 0.0% < 0.0005 103% 85% 115%
Strontium
12148 4232954 0.0076 0.0081 6.4% < 0.0002 110% 85% 115%
Tellurium 12148 4232954 < 0.0002 < 0.0002 0.0% < 0.0002 110% 85% 115%
Thorium 12148 4232954 0.0003 0.0003 0.0% < 0.0001 96% 85% 115%
Titanium 12148 4232954 0.0216 0.0203 6.2% < 0.0005 101% 85% 115%
Thallium 12148 4232954 0.00006 < 0.00005 NA < 0.00005 99% 85% 115%
Uranium
12148 4232954 0.00017 0.00019 11.1% < 0.00005 106% 85% 115%
Vanadium 12148 4232954 0.0010 0.0014 NA < 0.0005 91% 85% 115%
Tungsten 12148 4232954 0.0002 0.0001 NA < 0.0001 108% 85% 115%
Zinc 12148 4232954 0.020 0.021 4.9% < 0.001 103% 85% 115%
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699729
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: PO9842A02
Water Analysis
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: REFERENCE MATERIAL
MethodBlank
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
QUALITY ASSURANCE REPORT (V1) Page 4 of 7
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699729
Dup #1 RPDMeasured
ValueRecovery Recovery
Quality Assurance
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: PO9842A02
Water Analysis (Continued)
UpperLower
AcceptableLimits
BatchPARAMETERSample
IdDup #2
UpperLower
AcceptableLimits
UpperLower
AcceptableLimits
MATRIX SPIKEMETHOD BLANK SPIKEDUPLICATERPT Date: REFERENCE MATERIAL
MethodBlank
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
Certified By:QUALITY ASSURANCE REPORT (V1) Page 5 of 7
AGAT Laboratories is accredited to ISO/IEC 17025 by the Canadian Association for Laboratory Accreditation Inc. (CALA) and/or Standards Council of Canada (SCC) for specific tests listed on the scope of accreditation. AGAT Laboratories (Mississauga) is also accredited by the Canadian Association for Laboratory Accreditation Inc. (CALA) for specific drinking water tests. Accreditations are location and parameter specific. A complete listing of parameters for each location is available from www.cala.ca and/or www.scc.ca. The tests in this report may not necessarily be included in the scope of accreditation.
Water Analysis
Weight of Dry Sample
Volume of DI Water
pH ARD-181-18011 Modified from SM 4500-H+ PH METER
Electrical Conductivity ARD-181-18012 Modified from SM 2510B EC METER
SilverARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
AluminumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ArsenicARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
BoronARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
BariumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
BerylliumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
BismuthARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
CalciumARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
CadmiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
CobaltARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ChromiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
CopperARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
IronARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
MercuryARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
PotassiumARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
LanthanumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
LithiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
MagnesiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ManganeseARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
MolybdenumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
SodiumARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
NickelARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
PhosphorusARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
LeadARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
SulphurARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699729
Method Summary
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: PO9842A02
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 6 of 7
SeleniumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
AntimonyARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
SiliconARD-181-18006, MET-181-6108
MEND Report 1.20.1 (2009), SM 3120B
ICP/OES
TinARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
StrontiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
TelluriumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ThoriumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
TitaniumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ThalliumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
UraniumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
VanadiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
TungstenARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ZincARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
ZirconiumARD-181-18006, MET-181-6107
MEND Report 1.20.1 (2009), SM 3125B
ICP-MS
Results relate only to the items tested and to all the items tested
AGAT WORK ORDER: 13V699729
Method Summary
ATTENTION TO: Veronica Lau
CLIENT NAME: KLOHN CRIPPEN BERGER
PROJECT NO: PO9842A02
AGAT S.O.P ANALYTICAL TECHNIQUELITERATURE REFERENCEPARAMETER
Unit 120, 8600 Glenlyon ParkwayBurnaby, British Columbia
CANADA V5J 0B6TEL (778)452-4000FAX (778)452-4074
http://www.agatlabs.com
METHOD SUMMARY (V1) Page 7 of 7