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High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas, May 14-15, 2015

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Page 1: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

High-Efficiency Water Treatment for Oil & Gas Markets

Keynote Address North American Petroleum Accounting Conference

Dallas, Texas, May 14-15, 2015

Page 2: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Founded in 2007 to develop algae growth and harvesting technology

• Developed Electro Water Separation - a patented proprietary OriginClear technology for the removal of non-soluble contaminants from large quantities of water

• Applications in algae harvesting, wastewater treatment and oil & gas flowback & produced water treatment

• Long term strategy is licensing while commercializing the technology

History & Applications

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Page 3: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Electro Water Separation™ (EWS) • A first stage technology for all O&G water • Removes essentially all TPH, TSS, and bacteria • EWS is a patented licensable technology

• EWS PRIME • A commercial process incorporating EWS • Suitable for most water treatment applications • Precursor to downstream desalination processes. • To be manufactured by licensees with other processes to achieve

beneficial use

A Technology & A Process

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Page 4: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

EWS The Technology

EWS PRIME

EWS Custom Solutions

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

One Technology, Many Solutions New Frack Water

Irrigation Water

Aquifer Recharge

Potable Water

Water Flooding

Steam Flooding

Enhanced Oil Recovery

Clean Brine

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Page 5: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Heavy Brine for drilling fluid, completions and work overs.

Potential Process Road Map

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Page 6: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Electro Water Separation • Process Flow Diagram

– Post upfront oil-water separator – Integrated single equipment

• The Essentials – Continuous & very low energy – No chemical addition – Mobile or centralized facility

• Function – Targets dispersed 1 to 25 micron size oil droplets

and suspended solids – Coalesces to 25 micron plus – Disinfects bacteria – Oxidizes and co-precipitates specific dissolved ions

EWS PRIME P1000 With Electro-Coagulation Reactors

on Right

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Page 7: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Basic EWS Technologies • Proprietary electro-coagulation

– Breaks the oil-water emulsion – Neutralizes charge on droplets & particles – Coalesces 1 to 25 micron droplets & particles – Coalesces to 25 plus for gravity separation

• Proprietary electro-oxidation – Creates oxidizing agents – Disinfects bacteria – Oxidizes heavy metals – Breaks up dissolved organics

• Proprietary electro-flotation – Creates cloud of micron-sized gas bubbles – Lifts oil & solids into a surface mat

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Page 8: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Proprietary Electro-Coagulation – Unique electrode configuration for minimum power and

maintenance – Unique choice of donating and non-donating anode & cathode

materials – High mass transfer & pressurized reactor to keep gas in solution – Pressure released in flotation chamber for immediate dispersion

of gas – In-line flocculation of oil & suspended solids

Differentiation - EC

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Page 9: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Proprietary Electro-Flotation – 100% of water exposed to micron gas bubbles – Unique non-sacrificial anode/ cathode configuration for low power – Four-chambered flotation chamber

Differentiation - EF

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Page 10: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Proprietary Electro-Oxidation – Generation of oxidizing agents for bacteria disinfection – Low energy, chemical free process

• Proprietary SCADA process control – Touch screen control – PLC algorithms for real time control and off site monitoring and

control

Differentiation – EO, SCADA

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Page 11: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Best Value-Added Process

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Page 12: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• Three Unique Produced & Flowback Water Trials – Gas wells from western slope of Colorado – Niobrara – West Texas Intermediate oil wells of west Texas – Permian – Heavy oil CSG wells of Bakersfield – Monterey basin

• EWS PRIME used for all three trials – System throughput 1000 barrels per day – Spiral Water self cleaning filter for BS&W – EWS for 90% removal of all non-soluble contaminants & bacteria – Ultra-filtration polishing to achieve non-detectable levels

Field Case Studies

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Page 13: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

380 370

176

28 20 7 0.1 0.0 1.5 0

50

100

150

200

250

300

350

400

450

500

Turbidity (NTU) TSS (mg/l) Oil (mg/l)

Turb

idity

/ T

SS /

Oil

in W

ater

(NTU

, mg/

l, m

g/l)

Feed EWS EWS Prime

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Niobrara Performance

Feed water for testing: Produced & frac flowback from Colorado Western Slope disposal well facility

Better than 99% removal of Turbidity, TSS and Oil observed

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Page 14: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Permian Robustness

Recovered Oil

Water Samples

Wide variations in feed from many different truckloads and tank mixing over two weeks of operation in the Permian

14

0

200

400

600

800

1000

1200

1400

1600

EWS

Turb

idity

(FN

U)

Operation Date

Extended EWS Prime Performance Parsley Energy Raw SWD EWS Prime Effluent

Page 15: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Monterey Clarity

Field operations to treat CSS produced water to steam boiler make-up and irrigation quality

Beneficial Re-use

Water Samples

15

0

200

400

600

800

1000

1200

0 100 200 300 400

Turb

isity

(NTU

)

Run Time (Hours)

Vaquero FWKO Feed Turbidity EWS Prime Effluent Turbidity

Page 16: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

High Energy Efficiency

No observable membrane fouling even at high production capacity due to complete produced water pre-treatment

0

5

10

15

20

25

30

0

5

10

15

20

25

30

35

0 50 100 150 200 250 300 350

Spec

ific F

lux

(gfd

/psi)

Mod

ule

Flux

(gfd

)

Run Time (Hours)

UF System Flux UF Specific Flux

Vaquero Site in Monterey Formation

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Page 17: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Independent Lab Data

All data generated by Zalco Laboratories Sampled 18 Feb 2015 at Hershey Tank Battery, Vaquero Energy (Bakersfield CA)

Parameter (ppm) Vaquero Feed

EWS PRIME Effluent EWS Custom Effluent

BOD 20 7.2 5.9

COD 530 110 41

TSS 100 64 3*

TRPH (HEM)* 142 9 <5.0*

Diesel Range Organics 108 6.4 0.7

Gasoline Range Organics 0.46 0.19 .063

Motor Oil Range Organics 196 8.8 1.03

* Detection Limit TRPH: Total Recoverable Petroleum Hydrocarbons HEM: Hexane Extractable Material

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Page 18: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• EWS PRIME Specific Energy Consumption (SEC) – 0.28 kWh per barrel or 6.7 kWh/kgal - including EWS & UF – $0.042 per barrel at $0.15 per kWh

• EWS PRIME Operating Expense w/o Labor – $0.042 per barrel energy cost – $ 0.053 per barrel consumable (weekly partial anode replacement) – $0.047 per barrel typical process equipment maintenance

• Total Operating Expense $0.14/bbl • EWS PRIME Capital Cost: $0.20/bbl

– Amortized over 5 years at 3% interest • EWS PRIME Total Cost w/o Labor: $0.34/bbl

Cost Performance

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Page 19: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

• EWS PRIME performed in wide range of environments – Gas wells to WTI to Heavy Oil – Truck load to truck load (black to yellow) – Salinities from 900 to 160,000 ppm

• Contaminants removed by EWS PRIME – TPH is below detection limits of 5 ppm – TSS to below detection limits of 3 ppm – Gasoline, Diesel, Motor Oil Range to less than 1 ppm – Bacteria removal expected to be higher than 99.5%

• Eliminates plugging of downstream desalination

Bottom Line Performance

• Desalination requires total removal of oil and TSS.

• EWS PRIME is the most cost effective solution.

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Page 20: High-Efficiency Water Treatment for Oil & Gas …...High-Efficiency Water Treatment for Oil & Gas Markets Keynote Address North American Petroleum Accounting Conference Dallas, Texas,

North American Petroleum Accounting Conference © 2015 OriginClear, Inc.

Sales or Licensing Questions?

+1 877-999-6645 ext 4 [email protected]

Contact Information

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