HI

1)Absorption2)REMPI references (slide 9)3)Energetics (slides 10-)

Files: www= open; heima: closedagust,www,...hi/PPT-220112ak.ppt(https://notendur.hi.is/agust/rannsoknir/rempi/hi/PPT-220112ak.ppt)agust,heima,...HI/PXP-220112ak.pxp (abs. spectrum)(https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-220112ak.pxp )agust,heima,...HI/PXP-230112ak.pxp (energetics)(https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-230112ak.pxp )agust,heima,....HI/XLS-230112ak.xls(https://notendur.hi.is/agust/rannsoknir/rempi/hi/XLS-230112ak.xls )o.fl.

Slide 4

Slide 5

Slides 6 and 7& IGOR

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agust,heima,...HI/PXP-220112ak.pxp = https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-220112ak.pxp

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https://notendur.hi.is/agust/rannsoknir/papers/jesrp144-127-05.pdf :

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https://notendur.hi.is/agust/rannsoknir/papers/jesrp144-127-05.pdf :

agust,heima,...HI/PXP-220112ak.pxp = https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-220112ak.pxp

https://notendur.hi.is/agust/rannsoknir/papers/jesrp144-127-05.pdf :

2) REMPI references:

https://notendur.hi.is/agust/rannsoknir/papers/HI/jcp102-1882-95.pdf https://notendur.hi.is/agust/rannsoknir/papers/HI/jcp101-238-94.pdf

i.e:

http://www.raunvis.hi.is/~agust/rempisvaedidir/jcp109585698.pdf

And our paper from 1998:

Abs. Ref.:https://notendur.hi.is/agust/rannsoknir/papers/HI/jms92-40-82.pdf :HI

https://notendur.hi.is/agust/rannsoknir/papers/HI/jms92-55-82.pdf: DI

See more in slide 23

3) Energetics:

http://www.sartep.com/chem/chartsandtools/bondenergy.cfm :

http://www.wiredchemist.com/chemistry/data/bond-energies-lengths:

H & H (book): D00= 3.054(1) eV

NIST:

HI D:

295kJ mol-1 http://www.sartep.com/chem/chartsandtools/bondenergy.cfm 24660.0711cm-1

3.054eV H&H book 24632.162cm-1 Factors:

f1: 8.36E+01cm-1 / (kJ mol-1)

f2: 3.50E+02cm-1 / (kcal mol-1)

f3: 8065.54093cm-1/eV E(6s) = 54633.460cm-1 E(6s)+D= 79265.62cm-1 IE(HI)= 10.386eV http://webbook.nist.gov/cgi/cbook.cgi?ID=C10035106&Units=SI&Mask=20#Ion-Energetics IE(HI)= 83768.7081cm-1 IE(I)= 84295.1cm-1 http://physics.nist.gov/cgi-bin/ASD/energy1.pl E(S/O;I)= 7602.97cm-1 http://physics.nist.gov/cgi-bin/ASD/energy1.pl E(H+I*(1/2))= 32235.132cm-1 E(H+I+ + e)= 108927.262cm-1 IE(H) = 109678.7717cm-1 E(H+ + e + I) 134310.9337cm-1 EA(I) = 3.0590463eV http://en.wikipedia.org/wiki/Electron_affinity_%28data_page%29 24672.8631cm-1E(H+ + I-)= 109638.0706cm-1 E(I+)-E(I*)= 76692.13cm-1

agust,heima,....HI/XLS-230112ak.xls; = https://notendur.hi.is/agust/rannsoknir/rempi/hi/XLS-230112ak.xls

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HI+ + e; 83768.7081

H + I 24642.162 cm-1

H + I* 32235.132

H + I**(min)79265.62

H + I+ + e; 108927.262H+ + I- 109638.0706

H+ + e + I; 134310.9337

agust,heima,...HI/PXP-230112ak.pxp (energetics)= https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-230112ak.pxp

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HI+ + e; 83768.7081

H + I 24642.162 cm-1

H + I* 32235.132

H + I**(min)79265.62

H + I+ + e; 108927.262

H+ + I- 109638.0706

H+ + e + I; 134310.9337

HI

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Abs.spectrum

https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-230112ak.pxp

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https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-230112ak.pxp

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The A-band

Abs.spectrum

HI+ + e; 83768.7081

https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-260112ak.pxp

Experiments:

https://notendur.hi.is/agust/rannsoknir/papers/HI/jcp102-1882-95.pdf

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HI spectraPressure: 3 bar pure HILaser Power: 14 mWVrepeller: 2000VVexractor: 540 VNozzle open time: 400 S

I+

(HI)+ H

+

THE first HI-REMPI data!:

https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-260312ak.pxp

Dye: C540A

http://www.raunvis.hi.is/~agust/rempisvaedidir/jcp109585698.pdf:

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HI spectraPressure: 3 bar pure HILaser Power: 14 mWVrepeller: 2000VVexractor: 540 VNozzle open time: 400 S

I+

(HI)+ H

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70854 cm-1Large I(I+)/I(HI+)ratio! ..and seems to increase with J´(?)

Is this Iatomic line?70814.3 cm-1

https://notendur.hi.is/agust/rannsoknir/rempi/hi/PXP-260312ak.pxp

Dye: C540A

1.5 0.5 exp. Peak

0 7602.97 70814.3

70814.3 78417.27

NIST (http://www.nist.gov/pml/data/asd.cfm ):

i.e. 5s25p4(1D2)6p, 2[1]°, (J=3/2) <-<- 5s25p5  2P° (J=1/2)and(5s25p4(3P0)7s,  2[0] , (J=1/2) <-<- 5s25p5  2P° (J=1/2))

The latter of which should not be allowed (s <-<- p)

https://notendur.hi.is/agust/rannsoknir/rempi/hi/XLS-260312ak.xls

I atomic line:

Judging fromE(v´=0) is very close to V(v´=m+6), which is slightly higher in energy:

http://www.raunvis.hi.is/~agust/rempisvaedidir/jcp109585698.pdf

ERGO: one would indeed expect the I(I+)/I(HI+)ratio to increase with J´ (see slide 19)

The first data are promishing, indeed!

https://notendur.hi.is/agust/rannsoknir/papers/HI/jms92-40-82.pdf :

Abs. Spectra and assignments: