heterogeneous integration of autonomous smart films … · 2017. 4. 22. · final convergence...

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Heterogeneous integration of autonomous Heterogeneous integration of autonomous Heterogeneous integration of autonomous Heterogeneous integration of autonomous smart films smart films smart films smart films based based based based on on on on electrochromic electrochromic electrochromic electrochromic transistors transistors transistors transistors NEWSLETTER #5 NEWSLETTER #5 NEWSLETTER #5 NEWSLETTER #5 www.smart www.smart www.smart www.smart-ec.eu ec.eu ec.eu ec.eu

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  • Heterogeneous integration of autonomous Heterogeneous integration of autonomous Heterogeneous integration of autonomous Heterogeneous integration of autonomous

    smart filmssmart filmssmart filmssmart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    NEWSLETTER #5NEWSLETTER #5NEWSLETTER #5NEWSLETTER #5

    www.smartwww.smartwww.smartwww.smart----ec.euec.euec.euec.eu

  • SMART-EC has finalized last August 2014; it aimed at the development of self-poweredelectrochromic (EC) display device with improved speed and lifetime for multifunctional applications

    as automotive, ID-cards and smart packaging. The simplified concept for the final demonstrators is

    shown below, where the display in combined with energy harvesting modules (solar cell or/and

    battery and power controller) and RFID communication or temperature sensor, in case of smart

    cards or smart packing, respectively.

    OOOO b j e c t i v e sb j e c t i v e sb j e c t i v e sb j e c t i v e sHeterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    MMMM a j o ra j o ra j o ra j o r a c h i e v em e n t sa c h i e v em e n t sa c h i e v em e n t sa c h i e v em e n t s

    LLLL a t e s ta t e s ta t e s ta t e s t e v e n t se v e n t se v e n t se v e n t s

    SMART-EC integratedbattery

    SMART-ECElectrochromicTFT

    Electrodes

    Standard integratedPV

    Anode

    TFB

    CathodeEC

    AnodeEC

    Gate

    Absorbing layers

    TCO

    Cathode

    TFB

    Electrolyte

    EC

    Drain Source

    Electrolyte

    EC

    M36 Review Meeting

    European Commission, Brussels

    24th – 25th November 2013

    M42 Technical meeting

    EMRS Spring Meeting, Lille

    May 27th 2014

    Roll to roll full integration of functionalities

    and geometries for both co-integrated and

    convergence architectures for all

    demonstrators.

    Printed 8x8 inorganic

    electrochromic passive matrix

    and scaling up in pilot line

    facilities

    Optimized optical inspection tools for

    scanning webs in roll to roll systems

    Subsystems assembling

    (Smart ID-card example)

    Final Review Meeting

    European Commission, Brussels

    October 1st-2nd 2014

    2nd SMART-EC Symposium/Workshop Technical

    EMRS Spring Meeting, Lille

    May 28th-30th 2014

  • TTTT e c h n i c a l e c h n i c a l e c h n i c a l e c h n i c a l AAAA c h i e v e m e n t sc h i e v e m e n t sc h i e v e m e n t sc h i e v e m e n t sHeterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart filmsbasedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    SP1SP1SP1SP1 ---- S y s t e m s d e s i g n a n d S y s t e m s d e s i g n a n d S y s t e m s d e s i g n a n d S y s t e m s d e s i g n a n d r e q u i r e m e n t sr e q u i r e m e n t sr e q u i r e m e n t sr e q u i r e m e n t sThe main objectives of this sub-project that was finalized at M36 were:

    i) System and sub-system definition and design.

    ii) Definition of the characteristics pertaining to the sub-systems and validation protocols for

    demonstrators assessment

    iii) Electrical and geometrical design of the demonstrators

    iv) Materials selection suitable to the assembling of the prototypes, including substrates

    v) Definition of production processes for deposition and integration

    Example of the automotive demo backplane containing the circuitry for the interconnection phase to attach:

    flexible EC display (8x8 matrix); flexible polymer or TFB; flexible or glass PV cells; thin IC component.

    SP2 SP2 SP2 SP2 ---- D e p o s i t i o n D e p o s i t i o n D e p o s i t i o n D e p o s i t i o n t e c h n o l o g i e st e c h n o l o g i e st e c h n o l o g i e st e c h n o l o g i e sThe SP2 scope was the optimization of deposition technologies of materials for their integration

    in the building blocks. The SP2 objectives of the second year of project was the identification of

    the critical process parameters and the identification of the interaction between processes and

    materials.

    EC dual phase printable films with

    improved electrochemical response

    and reversibility.

    LiFePO4/Carbon composite cathodic material with

    high Crate (commonly the capacity drops around 5C).

    Changing from crystalline to pre-lithiated amorphous

    V2O5 Resulted in better solid-solid interfacial

    resistance and improved capacity for TFBs.

  • Heterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistorsSP3 SP3 SP3 SP3 –––– B u i l d i n g B l o c k sB u i l d i n g B l o c k sB u i l d i n g B l o c k sB u i l d i n g B l o c k sThe SP3 was devoted to the development of building blocks to be integrated in the final

    multifunctional system. The specific objectives within this work are related to :

    - electrochemical (electrochromic) thin film transistors (ECTFT) for future integration in display,

    - flexible energy harvesting module (automotive and packaging),

    - RF antenna coupled with IC for wireless communication.

    Concerning this sub-project, in the last year were mainly focused

    on:

    • Upscaling (in a pilot line facility at ACREO) of the passive

    electrochromic 8x8 passive matrix displays using printed WO3.• EC transistors for integration of EC active matrices

    • Energy harvesting and storage subsystem, namely the

    production of the batteries and selection of the PV cells to be

    integrated in the demonstrators

    •Optimization of the auxiliary electronics and communication

    systems

    All building blocks produced in SP3 were transferred to SP4. Before integration they were

    tested to determine if they fit the specifications.

    In the last year the electrochromic transistors (electrolyte gated with WO3 as channel layer)

    were optimized and integrated in active matrix EC displays made by PVD at UNINOVA.

    Array of 64 Inorganic (WO3 )EC

    displays (UNINOVA/ACREO)

    Thin Film Battery and

    Polymer Battery

    (CEA and POLITO)

    RF antenna

    (ACREO/BIoaAge)

    PV modules

    (SOLEMS)

    Electrochromic transistors layout, transfer curves, and

    channel layer coloration in operation

    Active matrix EC display integrating electrochromic transistors

  • SP4 SP4 SP4 SP4 –––– H e t e r o g e n e o u s H e t e r o g e n e o u s H e t e r o g e n e o u s H e t e r o g e n e o u s i n t e g r a t i o ni n t e g r a t i o ni n t e g r a t i o ni n t e g r a t i o nThe objective of the SP4 was the fabrication of the backplanes and integration of the building

    blocks optimized in SP3 by heterogeneous integration involving dry, wet processes and

    lamination steps.

    Heterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    Co-integrated prototypes

    built starting with different

    backplane materials (PI,

    PET, PC), for each type of

    demonstrators (automotive,

    packaging, ID card)

    Co-integrated architecture prototypes

    The fabrication of prototypes included the following steps: backplane development, pick&place,

    lamination and vias interconnections.

    From backplane CAD to

    film produced by R2R is

    shown. The film includes all

    different demonstrators

    backplane and all masks for

    auxiliary and IC electronics

    (BioAge and EMFT).

    Convergence architecture prototypes

    The final convergence integration architecture was composed by a thin film battery or hybridized

    battery with an electrochromic device (powered by the battery) made using at least three

    common materials (metal contacts, one electrode and the electrolyte). Two different convergent

    subsystems were tested. The fabrication procedure involved a collaborative work between CEA,

    UNINOVA and POLITO.

    Final convergence subsystem combining printed battery and EC display (left )and

    polymer battery and wet deposited WO3 (right).

  • SP5 SP5 SP5 SP5 –––– D e m o n s t r a t o r s i n t e g r a t i o nD e m o n s t r a t o r s i n t e g r a t i o nD e m o n s t r a t o r s i n t e g r a t i o nD e m o n s t r a t o r s i n t e g r a t i o nThe SP5 objective was the development of prototypes and demonstrators based on the

    knowledge on design, deposition and integration processes developed in SP2, SP3 and SP4.

    The high degree of multifunctionality of the novel self-powered flex devices is a key factor for

    a potential application in: Autonomous systems for automotive, Multifunctional flexible foils

    for ID-cards and Multifunctional flexible foils for smart packaging.

    Heterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    Automotive demo ID card demo

    Smart packaging demo

    A very important exploitable result of SMART-EC is

    represented by the Orbotech on-line monitoring and

    recognition tool compatible with R2R. The final result is

    a Demonstration of operation on a moving foil with

    delivery level: demonstration system that shows multi-

    cameras full width scanning, real time acquisition and

    low level imaging and offline registration to cam data.

    Inspection tool from Orbotech with user interface

    Autonomous systems for automotive - novel dynamic

    concepts of interior surfaces increased comfort

    (novel reconfigurable icons, transparent displays)

    Multifunctional flexible foils for ID-cards -

    innovative ID solutions for high security and

    displays for delivery of information.

    Multifunctional flexible foils for smart

    packaging – innovative track and trace systems,

    displays for information delivery with

    integrated sensors for consumer information

    and satisfaction

  • LLLL a t e s ta t e s ta t e s ta t e s t EEEE v e n t sv e n t sv e n t sv e n t sHeterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    M42 Technical meeting

    Lille, 27th May 2014The M42 technical meeting was held in Lille, May 2014, during the

    SMETEC-EC symposium at the EMRS Spring Meeting. This meeting

    was focused in checking the status of the achievements in SP5 and

    SP6, according to the recommendation received from the PO and

    the reviewers after the M36 review meeting.

    P R O J E C T M E E T I N G SP R O J E C T M E E T I N G SP R O J E C T M E E T I N G SP R O J E C T M E E T I N G S

    M36 Review meeting

    European Commission (Brussels) 24th -25th November 2013The M36 review was held in Brussels (Belgium) in November 2013. During the meeting the final

    outputs of SP2 and SP3 were presented together with advancements in SP4 and SP5.

    S Y M P O S I U M A N D W O R K S H O PS Y M P O S I U M A N D W O R K S H O PS Y M P O S I U M A N D W O R K S H O PS Y M P O S I U M A N D W O R K S H O P

    EMRS 2014 Spring Meeting

    Lille (France) May 26th-30th

    Symposium R – Towards flexible ion based devicesPartners UNINOVA, AVREO, CEA, POLITO and CRF have organize the

    SMARTEC 2nd symposium, this time at the prestigious ERMS Spring

    Meeting. The aim was to promote discussion among the international

    scientific community dealing with this topic. The conference had

    about 4000 attendees and several other running parallel symposiums

    (30 in total, some on several topics related with SMART-EC, namely on

    transparent conductors and electrochromic materials and devices).

    The SMARTEC symposium had a 3 days program with more than 50

    contributors coming from different countries including contributions

    from SMART-EC consortium

    Final Review meeting

    European Commission (Brussels) 1st – 2nd October 2014The final review meeting was held in in Brussels (Belgium) in October

    2014. The latest achievements of the project were presented together

    with the latest version of the optical inspections system and the final

    demonstrators.

  • Heterogeneous integration Heterogeneous integration Heterogeneous integration Heterogeneous integration

    of autonomous smart filmsof autonomous smart filmsof autonomous smart filmsof autonomous smart films

    basedbasedbasedbased on on on on electrochromicelectrochromicelectrochromicelectrochromic transistorstransistorstransistorstransistors

    CCCC O N S O R T I U MO N S O R T I U MO N S O R T I U MO N S O R T I U M

    Con t a c tC o n t a c tC o n t a c tC o n t a c t

    Vito Lambertini

    Group Materials Labs

    Centro Ricerche Fiat S.C.p.A.

    Strada Torino 50

    10043 Orbassano (TO), Italia

    Tel. +39 011 9080 431

    E-mail: [email protected] www.smartwww.smartwww.smartwww.smart----ec.euec.euec.euec.eu