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Heat Xfer Coeff for Sphere Assignment 8
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CM3215
Fundamentals of Chemical Engineering Laboratory
Professor Faith Morrison
Department of Chemical EngineeringMichigan Technological University
© Faith A. Morrison, Michigan Tech U.
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CM3215 Fundamentals of Chemical Engineering Laboratory
In the previous lab, we practiced
curve-fitting data to an empirical model
In this lab, we use this skill to deduce a quantity that is meaningful to us
from an analytical model:
Heat transfer coefficient, h
© Faith A. Morrison, Michigan Tech U.
• It’s convenient to have a functional form for future use
• The parameters may have no meaning
• Model an actual experiment (physics)
• Goal is to determine a quantity that appears as a parameter in the model
• Fit data to model to determine the parameter
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Heat Xfer Coeff for Sphere Assignment 8
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CM3215 Fundamentals of Chemical Engineering Laboratory
Question: What is the heat-transfer coefficient to a small object in a particular well stirred vessel?
Answer: We will measure heat flow and back-out h from modeling our data.
© Faith A. Morrison, Michigan Tech U.
Newton’s Law of Cooling:
(a boundary condition)
(What is heat transfer coefficient? Answer: go back to the definition
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CM3215 Fundamentals of Chemical Engineering Laboratory
© Faith A. Morrison, Michigan Tech U.
Experiment: Measure T(t) for an unsteady state scenario:
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Initially:
Heat Xfer Coeff for Sphere Assignment 8
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CM3215 Fundamentals of Chemical Engineering Laboratory
© Faith A. Morrison, Michigan Tech U.
Experiment: Measure T(t) for an unsteady state scenario:
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Initially: Suddenly:
CM3215 Fundamentals of Chemical Engineering Laboratory
© Faith A. Morrison, Michigan Tech U.
Experiment: Measure T(t) for an unsteady state scenario:
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Initially: Suddenly:
t(s) T(oC)9.50E-02 7.46E+002.11E-01 7.44E+003.09E-01 7.44E+004.09E-01 7.57E+005.24E-01 7.46E+006.23E-01 7.49E+007.39E-01 7.53E+008.37E-01 7.46E+009.54E-01 7.59E+001.05E+00 7.53E+001.15E+00 7.58E+001.27E+00 7.48E+001.37E+00 7.57E+00… …
Excel:
(already done for you)
Heat Xfer Coeff for Sphere Assignment 8
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CM3215 Fundamentals of Chemical Engineering Laboratory
© Faith A. Morrison, Michigan Tech U.
How do we set up the model for this problem?
Where does h come into it?
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© Faith A. Morrison, Michigan Tech U.
www.chem.mtu.edu/~fmorriso/cm310/energy2013.pdf8
Microscopic Energy Balance
Heat Xfer Coeff for Sphere Assignment 8
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© Faith A. Morrison, Michigan Tech U.
www.chem.mtu.edu/~fmorriso/cm310/energy2013.pdf9
You try.
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Unsteady State Heat Transfer to a Sphere
1≡
Boundary conditions:
,
00,
Microscopic energy balance in the sphere:
Initial condition:
10
0, ∀
∀
0
(“∀” means “for all”)
• Unsteady
• Solid 0
• , symmetry
• No current, no rxn
Heat Xfer Coeff for Sphere Assignment 8
6
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Unsteady State Heat Transfer to a Sphere
1≡
Boundary conditions:
,
00,
Microscopic energy balance in the sphere:
Initial condition:
11
0, ∀
∀
0
(“∀” means “for all”)
• Unsteady
• Solid 0
• , symmetry
• No current, no rxnNow, Solve
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
Solution:
(Carslaw and Yeager, 1959, p237)
, ≡,
Bi ≡
2Bisin sin Bi 1
Bi Bi 1
Fo ≡
12
where the eigenvalues satisfy this equation:tan
Bi 1 0
(Bi=Biot number; Fo=Fourier number)
Characteristic Equation
Heat Xfer Coeff for Sphere Assignment 8
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Depends on material ( and heat transfer at
surface
2Bisin sin Bi 1
Bi Bi 1
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
Solution:
(Carslaw and Yeager, 1959, p237)
, ≡,
Bi ≡ Fo ≡
13
where the eigenvalues satisfy this equation:tan
Bi 1 0
(Bi=Biot number; Fo=Fourier number)
Characteristic Equation
Let’s plot it to find out. © Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
Solution: ≡
Bi ≡
2Bisin sin Bi 1
Bi Bi 1
Fo ≡
14
where the eigenvalues satisfy this equation:tan
Bi 1 0
But what does this look like?
Characteristic Equation
Heat Xfer Coeff for Sphere Assignment 8
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2Bi
sin sin Bi 1Bi Bi 1
‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Unsteady State Heat Transfer to a Sphere
15
Fo ≡,≡
,
result (9 terms)
Bi ≡
For a fixed Bi
‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Unsteady State Heat Transfer to a Sphere
16
Fo ≡,≡
,
result (9 terms)
•It is an infinite sum of terms.
•Each term corresponds to one eigenvalue,
•The first term is the biggest
•The terms alternate in sign (positive and negative)
Bi ≡
For a fixed Bi
Heat Xfer Coeff for Sphere Assignment 8
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© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
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‐20
‐10
0
10
20
30
40
0 2 4 6 8 10 12 14 16
characteristic equation
Rn
Biot number= 1.0000
Characteristic Equation:tan
Bi 1 0
• The are the roots of the characteristic equation
• There is a different set of for each value of Biot number Bi
Bi ≡
For Bi=1, 1.5, 4.6
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
18
Characteristic Equation:
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
0.001 0.1 10 1000
R
n
Biot Number
first mode
second mode
third mode
fourth mode
high Bi is low conductivity
low Bi is high k, low h
high Bi islow k, high h
• The are the roots of the characteristic equation
• They depend on Biot number Bi
Bi ≡
The roots of the characteristic equation vary with Bi
tanBi 1 0
Heat Xfer Coeff for Sphere Assignment 8
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© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
19
Characteristic Equation:
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
0.001 0.1 10 1000
R
n
Biot Number
first mode
second mode
third mode
fourth mode
high Bi is low conductivity
low Bi is high k, low h
high Bi islow k, high h
• The are the roots of the characteristic equation
• They depend on Biot number Bi
Bi ≡
The roots of the characteristic equation vary with Bi
tanBi 1 0
At low Bi, the temperature is uniform
in the sphere; heat transfer is limited by
rate of heat transfer to the surface (h).
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
20
Characteristic Equation:
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
0.001 0.1 10 1000
R
n
Biot Number
first mode
second mode
third mode
fourth mode
high Bi is low conductivity
low Bi is high k, low h
high Bi islow k, high h
• The are the roots of the characteristic equation
• They depend on Biot number Bi
Bi ≡
The roots of the characteristic equation vary with Bi
tanBi 1 0
At high Bi, the surface temperature equals
the bulk temperature; heat transfer is limited by conduction in the
sphere.
Heat Xfer Coeff for Sphere Assignment 8
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© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
21
Characteristic Equation:
0.0
2.0
4.0
6.0
8.0
10.0
12.0
14.0
0.001 0.1 10 1000
R
n
Biot Number
first mode
second mode
third mode
fourth mode
high Bi is low conductivity
low Bi is high k, low h
high Bi islow k, high h
• The are the roots of the characteristic equation
• They depend on Biot number Bi
Bi ≡
The roots of the characteristic equation vary with Bi
tanBi 1 0
At moderate Bi, heat transfer is affected by both conduction in the sphere and the rate of heat
transfer to the surface.
2Bi
sin sin Bi 1Bi Bi 1
‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Unsteady State Heat Transfer to a Sphere
22
Fo ≡,≡
,
result (9 terms)
The key to analyzing data is determining
the Biot number.
Heat Xfer Coeff for Sphere Assignment 8
12
‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
23
Fo ≡
,≡
,
result (9 terms)
For 0.2, the higher-order terms
make no contribution
‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
24
Fo ≡
,≡
,
result (9 terms)
For 0.2, the higher-order terms
make no contribution
The higher-order terms are working to get the solution right
for shorter and shorter times (low Fo)
Heat Xfer Coeff for Sphere Assignment 8
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‐0.6
‐0.4
‐0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
0 0.1 0.2 0.3 0.4
Biot number= 1.0000
first term
second term
third term
fourth term
fifth term
sixth term
seventh term
eighth term
ninth term
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
25
Fo ≡
,≡
,
result (9 terms)
For 0.2, the higher-order terms
make no contribution
The higher-order terms are working to get the solution right
for shorter and shorter times (low Fo)
We already know the short-time behavior; we
thus concentrate on long times to get Bi (and
therefore need only one term of the summation)
© Faith A. Morrison, Michigan Tech U.
Unsteady State Heat Transfer to a Sphere
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0.001
0.01
0.1
1
10
0.0 0.2 0.4 0.6 0.8 1.0
Scaled Temperature
Fourier number
nineterms
firstterm
,≡
,
Fo ≡
• Plotted log-linear, the solution is linear for 0.2
• The slope depends on Biotnumber
Bi ≡
1Bi
Heat Xfer Coeff for Sphere Assignment 8
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From Geankpolis, 4th edition, page 374
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
27
Heisler charts (Geankoplis; see also Wikipedia)Solution to Unsteady State Heat Transfer to a Sphere
From Geankpolis, 4th edition, page 374
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
28
Heisler charts (Geankoplis; see also Wikipedia)Solution to Unsteady State Heat Transfer to a Sphere
The Heisler Chart is a catalog of all the long-time slopes for various values of Biot number.
Heat Xfer Coeff for Sphere Assignment 8
15
From Geankpolis, 4th edition, page 374
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
29
Heisler charts (Geankoplis; see also Wikipedia)Solution to Unsteady State Heat Transfer to a Sphere
The Heisler Chart is a catalog of all the long-time slopes for various values of Biot number.
Our data correspond to only one of these lines; when we know which
one, we know Bi.
From Geankpolis, 4th edition, page 374
Heisler charts (Geankoplis; see also Wikipedia)Solution to Unsteady State Heat Transfer to a Sphere
© F
aith
A.
Mor
rison
, M
ichi
gan
Tech
U.
Also, x1 is the sphere radius
Note: the parameter m from the Geankoplis Heisler chart is NOT the
slope of the line! It is Bi.
30
1Bi
Heat Xfer Coeff for Sphere Assignment 8
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CM3215 Fundamentals of Chemical Engineering Laboratory
Assignment 8: Unsteady Heat Transfer to a Sphere
•Using the time-dependent temperature versus time data measured by others, calculate the heat transfer coefficient for the conditions in the laboratory experiment (sphere in a beaker).
•Report the parameters of the fit.
•Demonstrate the “goodness of fit” with a plot of data (symbols) and model (solid line).
•Conduct and report your uncertainty analysis.
© Faith A. Morrison, Michigan Tech U.
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CM3215 Fundamentals of Chemical Engineering Laboratory
•In your lab notebook, outline how you plan to proceed
•Obtain / and for brass ahead of time and record both in notebook (with reference)
© Faith A. Morrison, Michigan Tech U.
Pre-lab Assignment (due in lab Tuesday):
•Have your calibration curves in your lab notebook for collection by the TA
Reminder:
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