geometrical isomerism - open chemistryopenchemistry.in/upload/geometricalisomerism.pdf · a visual...
TRANSCRIPT
![Page 1: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/1.jpg)
A visual Studyin
GEOMETRICAL ISOMERISM
By
S.K.SinhaResonance Kota
Checkout the unique 3D visual presentation for the 1st time at
https://play.google.com/store/apps/details?id=air.geo.isomer
S.K.S
inha
![Page 2: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/2.jpg)
STEREOISOMERISM1. Isomers with different orientation
or distribution of atoms or groupof atoms in space are calledstereoisomers.
2. Stereo-isomers have identicalconnectivity of atoms and groups( bond pattern)( bond pattern).
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 3: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/3.jpg)
1. Example: cis and trans 2-
STEREOISOMERISM
pbutene has identical bondpattern.
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 4: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/4.jpg)
1. Geometrical Isomerism is a
STEREOISOMERISM
form of configurational stereoisomers.
2. Any two configurationalisomers are stereoisomers, butcan not be interconvertedcan not be interconverted
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 5: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/5.jpg)
1. These isomers differ in the
STEREOISOMERISM
configuration (The spatialarrangement) or Arrangementof atoms in space.p
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 6: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/6.jpg)
1. Configurational isomerism
CONFIGURATIONAL ISOMERISM
garises due to non-interconvertibility of bonds atroom temperature.p
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 7: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/7.jpg)
1. They are non interconvertible ,
CONFIGURATIONAL ISOMERISM
y ,they can be separated byphysical and chemicalmethods.
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 8: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/8.jpg)
1. Isomers with different
GEOMETRICAL ISOMERISM
1. Isomers with differentgeometrical arrangement ofgroup of atoms or atoms inspace are known asspace are known asgeometrical isomers
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 9: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/9.jpg)
1. Example
GEOMETRICAL ISOMERISM
1. Example
O
C C
C O HH
HCO
O H
OO H
O HFumaric Acid
C O HCO
C C
HH HH
Maleic Acid
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 10: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/10.jpg)
GEOMETRICAL ISOMERISM
2. Example2. Example
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 11: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/11.jpg)
Conditions for G.I.
GEOMETRICAL ISOMERISM
Conditions for G.I.
Cis-trans isomerism
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 12: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/12.jpg)
Conditions For GI :
GEOMETRICAL ISOMERISM
1. For GI to occur, presence of a functional group or condition of restricted rotation isof restricted rotation is required . It is represented by GRR (i.e. -C=C- , -C=N- , -N=N-or ring str )or ring str.)
2. GRR = Group with restricted rotationS.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 13: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/13.jpg)
Conditions for G.I :
GEOMETRICAL ISOMERISM
Co d t o s o G2. Non-convertability
aa ba
Xbb ab
X
a ba a
Xb ab b
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 14: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/14.jpg)
Conditions for G.I :
GEOMETRICAL ISOMERISM
3. Different groups should beattached at each doublybonded atom (or on the sidesbonded atom (or on the sidesof GRR GROUP)
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 15: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/15.jpg)
GEOMETRICAL ISOMERISM
aa baa
b
a
a
b
a
a
a
and are identical but not G.I.
aa ba
bb ab
andaa
can show G.I.
cbS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 16: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/16.jpg)
Conditions for G.I :
GEOMETRICAL ISOMERISM
4. Different groups should be in one plane (Planarity)
1. example
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 17: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/17.jpg)
1 following types of compound
GEOMETRICAL ISOMERISM
1. following types of compound can show geometrical isomers :
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 18: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/18.jpg)
A. Compounds with C=C(Alkene )
GEOMETRICAL ISOMERISM
p ( )
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 19: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/19.jpg)
trans-2-Butene has lesser
GEOMETRICAL ISOMERISM
dipole moment than cis -2-butene.
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 20: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/20.jpg)
Cis has high B.P. than trans.
GEOMETRICAL ISOMERISM
gBut trans has high mp than cis.
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 21: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/21.jpg)
A Compounds with C=C
GEOMETRICAL ISOMERISM
p
O
C
O
OHH
C C
HCO
OOH
HCO
OH
C
O
OHC
OH
O
Fumaric Acid
C C
HH HH
Maleic Acid
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 22: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/22.jpg)
Maleic acid form Anhydride
GEOMETRICAL ISOMERISM
y
CCO
OH O
OH C CO
OO
C C
HH
CC
H H
Maleic Acid Maleicanhydride
Fumaric acid: No AnhydrideMaleic Acid y
HCO
OH
C C
HCO
CH OH
No anhydride
O
Fumaric Acid
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 23: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/23.jpg)
cis and trans 1,2-Dichloroethene
GEOMETRICAL ISOMERISM
,
Z: 1.28 g/cm³Boiling Z: 60.3 °CDensity
g/
E: 1.26 g/cm³
o g
point
60 3 C
E: 47.5 °C
Melting
point
Z: ‐81 °C
E: 81 °C
Dipole
t
Z (cis): 1.9
D
E (t ) 0point E: ‐81 C moment E (trans): 0
D
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 24: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/24.jpg)
cis and trans StilbeneGEOMETRICAL ISOMERISM
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 25: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/25.jpg)
cis and trans Stilbene
GEOMETRICAL ISOMERISM
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 26: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/26.jpg)
cis-Stilbene has a melting point GEOMETRICAL ISOMERISM
g pof 5-6 °C, while trans-stilbenemelts around 125 °C
CC H
C HCH
C HC H
H
C C
CC
C C H
CH C H
H
CHCHCH
CH C H
C H C H
CH
CH
CHCH
CHCHCH
CHCH
CHC
CH
C C
CCH
H H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 27: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/27.jpg)
B. Compound with C=N bond
GEOMETRICAL ISOMERISM
p(imine, oxime )
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 28: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/28.jpg)
Compounds with C=N: Hydrazones
GEOMETRICAL ISOMERISM
p y
NNH2
CH3
CH
E-AcetaldehydehydrazoneNH2
NNH2
CH3
CH3
Z-Acetaldehydehydrazone
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 29: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/29.jpg)
Compounds with C=N: Phenyl
GEOMETRICAL ISOMERISM
p yhydrazones.
HNHC
CHCH
CH
Ph
CNCHCH
Ph
E-Benzaldehydephenylhydrazone
H
C
H
NC
CHCH
CHPhNHC
CHCH
CH
Z-Benzaldehydephenylhydrazone
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 30: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/30.jpg)
Compounds with C=N:
GEOMETRICAL ISOMERISM
pSemicarbazone
C
O
NHCH3
C N
NH NH2
H
O
C
O
N H 2H
C N
N H N H 2
CH 3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 31: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/31.jpg)
C. Compounds with N=N (Azo)
GEOMETRICAL ISOMERISM
p ( )
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 32: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/32.jpg)
Compounds with N=N :
GEOMETRICAL ISOMERISM
pAzobenzene
CHCH CHCHCH
CH
CH
CH CH
CHCH
CH
CCH CHC
N N
CHCH
CH NC
CHCH
CCH
CHN
NC
CHCH
CH
CH
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 33: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/33.jpg)
D. Compounds with Cycles
GEOMETRICAL ISOMERISM
p y
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 34: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/34.jpg)
D Compounds with Cycles
GEOMETRICAL ISOMERISM
D Compounds with Cycles
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 35: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/35.jpg)
D. Compounds with Cycles
GEOMETRICAL ISOMERISM
p y
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 36: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/36.jpg)
D Compounds with Cycles
GEOMETRICAL ISOMERISM
p y
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 37: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/37.jpg)
E. Cyclooctene or higher alkene
GEOMETRICAL ISOMERISM
E. Cyclooctene or higher alkene
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 38: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/38.jpg)
F. Cumulene with odd no
GEOMETRICAL ISOMERISM
F. Cumulene with odd no
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 39: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/39.jpg)
G. Spirane with odd rings
GEOMETRICAL ISOMERISM
p g
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 40: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/40.jpg)
spirane with odd no of rings
GEOMETRICAL ISOMERISM
p g
trans Spiranetrans‐Spirane
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 41: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/41.jpg)
H. spiroallene with odd no of
GEOMETRICAL ISOMERISM
p( + rings)
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 42: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/42.jpg)
I. Decaline
GEOMETRICAL ISOMERISM
I. Decaline
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 43: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/43.jpg)
CONCEPT TESTING
GEOMETRICAL ISOMERISM
CONCEPT TESTING
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 44: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/44.jpg)
1 Is G I possible in given compound ?
GEOMETRICAL ISOMERISM
1. Is G.I. possible in given compound ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 45: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/45.jpg)
GEOMETRICAL ISOMERISM
2 Is G I possible in given compound ?2. Is G.I. possible in given compound ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 46: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/46.jpg)
GEOMETRICAL ISOMERISM
3 Is G I possible in given compound ?3. Is G.I. possible in given compound ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 47: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/47.jpg)
GEOMETRICAL ISOMERISM
4 Is G I possible in given compound ?4. Is G.I. possible in given compound ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 48: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/48.jpg)
GEOMETRICAL ISOMERISM
5 Is G I possible in given compound ?5. Is G.I. possible in given compound ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 49: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/49.jpg)
GEOMETRICAL ISOMERISM
6 Is G I possible in given compound ?
A. 1,2-dichloropropene
6. Is G.I. possible in given compound ?
B. 2,3- dichloro -1-butene
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 50: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/50.jpg)
GEOMETRICAL ISOMERISM
7 Is G I possible in given compound ?
A. 1,1-dichlorocyclopropaneB 1 2 –dichlorocyclopropane
7. Is G.I. possible in given compound ?
B. 1,2 –dichlorocyclopropaneC. 1,3-dichlorocyclohexene
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 51: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/51.jpg)
GEOMETRICAL ISOMERISM
Solution
1. Yes2 No
Solution
2. No3. No4. Yes5. No6. A Yes B No7. A No B Yes C No
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 52: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/52.jpg)
GEOMETRICAL ISOMERISM
Formation of Oxime.Formation of Oxime.Symmetrical aldehyde /ketone
form one oxime.
C
CH2
CH2
CH2
CH2
CH2 O N OHH
HC
CH2
CH2
CH2
CH2
CH2N
OH
22 2
sym ald/ketone only one oximeS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 53: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/53.jpg)
GEOMETRICAL ISOMERISM
Formation of OximeFormation of OximeSymmetrical aldehyde /ketone
form one oxime.Unsymmetrical aldehyde
/ketone form two oxime.
C
CHCH
CH O N OH
H
C
CHCH
CH2 N
OH
CH2CH2 OH
C
CH2CH2
CH2 O N OH
H
C
CH2CH2
CH2 N
CH2CH2 H
C
C 2
CH
C 2
CH
CH2 N
OH
unsym ald/ketone form two oxime
C
CHCH
CH2 O N OH
H
y S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 54: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/54.jpg)
GEOMETRICAL ISOMERISM
Formation of OximeFormation of OximeUnsymmetrical aldehyde
/ketone form two oxime.
C
CH3
O N OH
H
C
CH3
N
OH
C
CH2CH3
O N OH
H
C
CH2CH3
N
CHCH
C
CH2
CH3
CH3
N
OH
C
CH2
CH3
CH3
O N OH
H
H
unsym ald/ketone form two oximeS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 55: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/55.jpg)
GEOMETRICAL ISOMERISM
Formation of HydrazoneFormation of HydrazoneUnsymmetrical aldehyde
/ketone form two
H H H NH2
Hydrazones.
C O
CH3
N NH2
H
C N
CH3
C N
NH2CH3
C
CH3
H
O N NH2
H
H
H
unsym ald/ketone form two hydra
H H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 56: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/56.jpg)
GEOMETRICAL ISOMERISM
Formation of HydrazoneFormation of HydrazoneSymmetrical aldehyde /ketone
form one Hydrazone.
H H H NH2
C O
H
N NH2
H
C N
H
sym ald/ketoneform one hydra
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 57: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/57.jpg)
GEOMETRICAL ISOMERISM
Formation of OximeFormation of OximeSymmetrical aldehyde /ketone
form one oxime.
C
CH3
O N
H
H
OH C
CH3
N
OH
CHCH3 H CH3
sym ald/ketoneform one oximS.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 58: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/58.jpg)
GEOMETRICAL ISOMERISM
Nomenclature in G I
Cis / trans: similarity of groups1 Similar groups on the same
Nomenclature in G.I
1. Similar groups on the same side or nearest : cis
2. Similar groups on the opposite side or farthest : transS.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 59: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/59.jpg)
CONCEPT TESTING
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 60: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/60.jpg)
Q1 Are these two cis trans GEOMETRICAL ISOMERISM
isomers?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 61: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/61.jpg)
GEOMETRICAL ISOMERISMQ2 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 62: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/62.jpg)
GEOMETRICAL ISOMERISMQ3 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 63: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/63.jpg)
GEOMETRICAL ISOMERISMQ4 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 64: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/64.jpg)
GEOMETRICAL ISOMERISMQ5 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 65: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/65.jpg)
GEOMETRICAL ISOMERISMQ6 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 66: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/66.jpg)
GEOMETRICAL ISOMERISMQ7 Are these two cis trans isomers ?
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 67: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/67.jpg)
GEOMETRICAL ISOMERISM
Q8 Relation between the given pair
Cl
Q8 Relation between the given pair of compound is …………………………..
C CH2
Cl
HHH
C C
CC
H
Cl HH H
Cl
CC
H
Cl
H
H
C CH2
Cl
HHCl
C C
CC
H
H HH H
CC
H
H
H
H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 68: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/68.jpg)
GEOMETRICAL ISOMERISM
Q9 Relation between the given pair
Cl
Q9 Relation between the given pair of compound is …………………………..
C
C CH2
C
Cl
ClHH
C C
CCH HH H
H HCl
C CH2H
HH
C C
CC
H
Cl HH H
CC
H
Cl
H
H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 69: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/69.jpg)
GEOMETRICAL ISOMERISM
Q10 Relation between the given pair Q10 Relation between the given pair of compound is …………………………..
CH2
CH3
C CH2CH3 C CH3
ClCl
CH
CH3
CH3CH2
CC
CH2CH3
Cl
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 70: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/70.jpg)
GEOMETRICAL ISOMERISM
Q11 Relation between the given pair Q11 Relation between the given pair of compound is …………………………..
CH3CH2
CH2CH
CHCH2
CH2CH3
CH3CH
CHCH2
CH2CH2
CH2CH3CH CH2 CH2 CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 71: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/71.jpg)
GEOMETRICAL ISOMERISM
Q12 Relation between the given pair Q12 Relation between the given pair of compound is …………………………..
CH3CH2
CH2CH
CHCH3
CH3 CH CH2 CH3CH3CH
CHCH2
CH2CH2
CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 72: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/72.jpg)
GEOMETRICAL ISOMERISM
Q13 Relation between the given pair
H
Q13 Relation between the given pair of compound is …………………………..
C H 2 C
H
CH 2
C H 2 C
C C H 2
C H 3 C H 3H
H
CH2 C CH2
H
CH3 C CH2 CH3
HH
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 73: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/73.jpg)
GEOMETRICAL ISOMERISM
Q14 Relation between the given pair
H
Q14 Relation between the given pair of compound is …………………………..
CHCH2
OCH2
CC
CHCH3 O C CH3
H
H
CH2 C
CH
O CH2 C H
CHCH3 CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 74: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/74.jpg)
GEOMETRICAL ISOMERISM
Q15 Relation between the given pair
CH2 CH2
Q15 Relation between the given pair of compound is …………………………..
CH2CH CH
CH2
CH2C
CHC
H
H
H H
CH2 C CH CH
H
CHC
CCH2
CHCH2
H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 75: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/75.jpg)
GEOMETRICAL ISOMERISM
Q16 Relation between the given pair
ClB
Q16 Relation between the given pair of compound is …………………………..
C CCl
ClBr
CH2
C
C
C
H HCH2 H
ClCl
C CH
ClCl
CH 2
CH
CH H
CH 2 Br
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 76: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/76.jpg)
GEOMETRICAL ISOMERISM
Q17 Relation between the given pair
C H 3
Q17 Relation between the given pair of compound is …………………………..
C HCH
CH C HC H
3
C H 2
C H 2
CH 2
CH 2
C H
C H 2C H 2C H 2
CH 2 C H 2C H 2
CH2
CH2CH2 CH
CH2 CH3
CHCH
CH2 CH2CHCH2 CH
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 77: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/77.jpg)
GEOMETRICAL ISOMERISM
Answer
1. No2. No3. No4. No4. No5. Yes6. No7. No7. No8. Geometrical8. Positional10 Geometrical10. Geometrical11. Positional12. Homologous13 Identical13. Identical14. Geometrical15. Geometrical16 Geometrical16. Geometrical17. Geometrical
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 78: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/78.jpg)
GEOMETRICAL ISOMERISM
Nomenclature in G I
Cis / trans: similarity of groups1 Similar groups on the same
Nomenclature in G.I
1. Similar groups on the same side or nearest : cis
2. Similar groups on the opposite side or farthest : transS.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 79: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/79.jpg)
GEOMETRICAL ISOMERISM
Nomenclature in G I
E and Z : Based on seniority Seniors /high priority groups on the
Nomenclature in G.I
Seniors /high priority groups on thesame side or nearest : Z
(Z = zusammen = together)
Seniors /high priority groups on the opposite side or farthest :E
(E = entgegen = opposite)S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 80: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/80.jpg)
GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)
• Rules for seniority
Sequence rules : (CIP rules)
Rule I : Greater the atomic number of 1st atom , greater the senior group.
I > Br > Cl > S > F > O > N > C
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 81: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/81.jpg)
Sequence rules : (CIP rules)GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)
Rule II : If atomic number is same then isotopes with the greater mass no has greater priority .
Ex. (a) – T > – D > – H
(b) –C14H3 > – C12H3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 82: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/82.jpg)
GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)Sequence rules : (CIP rules)
Rule III : If the first atom is identical than second atom is observed for seniority.
Ex. (a)– CH2Cl > – CH2OH > –CH2NH2 > –CH2CH3 > – CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 83: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/83.jpg)
GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)Sequence rules : (CIP rules)
Rule IV : Groups containing double or triple bonds are assigned seniority as if the bonds are connected with
t tseparate atoms..
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 84: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/84.jpg)
GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)Sequence rules : (CIP rules)
Ex. for deciding seniority among – C ≡ C and – CH= CH2 , their h pothetical eq i alents arehypothetical equivalents are compared.
CH CH CCH3
CH3 CH CH2 CH3 C CH3H
CH3 C CH CH3 CCH3
CH33CH3S.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 85: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/85.jpg)
GEOMETRICAL ISOMERISM
Sequence rules : (CIP rules)Sequence rules : (CIP rules)
Rule V : Bond pair is senior to lone pair. H
NHHH
H
H N+
H
H
Greater Priority
H N+ H
Greater PriorityH
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 86: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/86.jpg)
CONCEPT TESTING
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 87: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/87.jpg)
GEOMETRICAL ISOMERISM
Q1 Check if the given compound is Q1 Check , if the given compound is Z or E.
CH3Cl
C C
CH3Cl
C C
CHB CHCH2Br CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 88: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/88.jpg)
GEOMETRICAL ISOMERISM
Q2 Check if the given compound is Q2: Check , if the given compound is Z or E.
OH
CHNH2 CH3
OH
C C
2 3
CH2Br CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 89: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/89.jpg)
GEOMETRICAL ISOMERISM
Q3 Check if the given compound is Q3: Check , if the given compound is Z or E.
CHCH3OH
CCH2
CH2 CH2
C
HCH2 CH2 HBr
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 90: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/90.jpg)
GEOMETRICAL ISOMERISM
Q4 Check if the given compound is Q4: Check , if the given compound is Z or E.
CH2
CHOH CH3
CH3
CCH2
CH2 CH2
C
CH3Br 3Br
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 91: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/91.jpg)
GEOMETRICAL ISOMERISM
Q5 Check if the given compound is Q5: Check , if the given compound is Z or E.
C CH
H
CH3
C
C
CH3
HS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 92: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/92.jpg)
GEOMETRICAL ISOMERISM
Q6 Check if the given compound is Q6: Check , if the given compound is Z or E.
CH CH
CH3
C C
CH2 C
CH CH
CH
CH2 C CHCl
CH CH
CH CHS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 93: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/93.jpg)
GEOMETRICAL ISOMERISM
Q7 Check if the given compound is Q7: Check , if the given compound is Z or E.
O HCH 3
C NC N
H
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 94: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/94.jpg)
GEOMETRICAL ISOMERISM
Q8 Check if the given compound is Q8: Check , if the given compound is Z or E.
CH
CH
C
CH
OH
C
CH
CH
C OH
Cl
C C
C CHCH2
CH CH
CH CH
I
CH CH
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 95: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/95.jpg)
GEOMETRICAL ISOMERISM
Q9 Check if the given compound is
CH
Q9: Check , if the given compound is Z or E.
CCH CH
CH3
C C
CCH3 CH2
C C
CCH2CH3 CCH2
CH
CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 96: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/96.jpg)
GEOMETRICAL ISOMERISM
Q10 Check if the given compound is Q10: Check , if the given compound is Z or E.
CCH CH
CH3
C
CH3
C C
CCH CH2C
CH3
CCH2
CH
CH2
CHCH CHCHCH2
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 97: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/97.jpg)
GEOMETRICAL ISOMERISM
Answer
1. Z2. E3. E4 E4. E5. E6. Z7. Z8. Z8 Z8. Z10. E
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 98: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/98.jpg)
Number of G I:
GEOMETRICAL ISOMERISM
Number of G I:
Numbers of geometricalNumbers of geometrical isomers can be found by calculating the number of gstereocenters in the compound.
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 99: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/99.jpg)
GEOMETRICAL ISOMERISM
Number of G I:
Step-1: Count total no of
Number of G I:
Step-1: Count total no. of possible stereocenterwhere GI is possible.
CH3CH
CHCH
CHCH
CHCH2
CHCH2
G.I not possibleG.I possibleS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 100: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/100.jpg)
GEOMETRICAL ISOMERISM
Number of G I:
Step-2: See if both ends are
Number of G I:
Step-2: See if both ends are identical or not.
If both ends are not identical then total no of possible GI = 2n ,
where n= no of stereo-centers.S.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 101: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/101.jpg)
GEOMETRICAL ISOMERISM
Number of G I:
Step-2: See if both ends are
Number of G I:
Step-2: See if both ends are identical or not.
If both ends are not identical then total no of possible GI = 2n ,
where n= no of stereo-centers.S.K
.Sinh
a
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 102: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/102.jpg)
GEOMETRICAL ISOMERISM
If both ends are not identical then total no of possible GI = 2n , where n= no of stereocentersstereocenters.
CH3CH
CHCH
CHCH
CHCH2
CHCH2C 2 2
Here n=3
G.I not possibleG.I possible
Total no of GI = 23 =8
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 103: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/103.jpg)
GEOMETRICAL ISOMERISM
Step-i: if both ends are identical .Then see if the no of possibleno of possible stereocenters are odd/ even.
ii. If n = no of stereocenter is even then total no of GI = 2(n-1)+2 ((n/2)-1)
CH C H C H C H C HCH 3C H
C HC H
C HC H
C HC H
C HC H 3
Here n=4
G.I possible
Total no of GI = 10
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 104: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/104.jpg)
GEOMETRICAL ISOMERISM
Step-i: if both ends are identical .Then see if the no of possibleno of possible stereocenters are odd/ even.
ii. If n = no of stereocenter is odd then total no of GI = 2(n-1)+2 ((n-1)/2)
CH3CH2
CHCH
CHCH
CHCH
CH2CH3
G I ibl
Here n=3 Total no of GI = 6
G.I possible
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 105: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/105.jpg)
CONCEPT TESTING
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 106: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/106.jpg)
GEOMETRICAL ISOMERISM
Q:1 Find total no of geometrical isomer for
CHCH3
CCH
CHCH
CH
CH
CH2
CHCH
CCH2
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 107: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/107.jpg)
GEOMETRICAL ISOMERISM
Q:2 Find total no of geometrical isomer for
H
C HC H 2
CH 2
C HC
CH 2 C l
H
C H 2C
C HC H 2
C H
C H 2
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 108: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/108.jpg)
GEOMETRICAL ISOMERISM
Q:3 Find total no of geometrical isomer for
C
HCH3
CHCH
CH2
CHC
CH3
CH2C
2
CCH3
3
CH3
CCH3
CH22S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 109: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/109.jpg)
GEOMETRICAL ISOMERISM
Q:4 Find total no of geometrical isomer for
C H 3
C H 2
C HC H
CH 32
CC
CCH 3
CH 3 C H 3
CCH 3
N H
C H 3
N HS.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 110: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/110.jpg)
GEOMETRICAL ISOMERISM
Q:5 Find total no of geometrical isomer for
CH3
CH2 CH C C CH CH CH CH3
CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 111: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/111.jpg)
GEOMETRICAL ISOMERISM
Q:6 How many products are formed in given reaction
O
C
O
+NH2
OH
CH3 CH3
Q 7 H d t f dQ:7 How many products are formed in given reaction
O
+NH2
OHCH2
CCH2 +
CH2CH2
CH22
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 112: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/112.jpg)
GEOMETRICAL ISOMERISM
Q:8 How many products are formed in given reaction
O
C
O
CH2
C
CH2
CH2+
NH2 NH2
CH22
O
Q:9 How many products are formed inQ:9 How many products are formed in given reaction
C
O
CH3 C
CH2
+ NH2 OH
CH3
CCH3 CH3
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 113: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/113.jpg)
GEOMETRICAL ISOMERISM
10. How many products are formed in given reaction
C
CH
CH2CH2
C
O
+
NH2 OH
CH2C
C
O
O
O
11. How many products are formed in given reaction
CCH2
COO
NH2 OH
CH2C
CH2
CH2
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer
![Page 114: geometrical isomerism - Open Chemistryopenchemistry.in/upload/GeometricalIsomerism.pdf · A visual Study in GEOMETRICAL ISOMERISM By S.K.Sinha Resonance Kota Checkout the unique 3D](https://reader034.vdocuments.site/reader034/viewer/2022051508/5acc75067f8b9a63398ce450/html5/thumbnails/114.jpg)
GEOMETRICAL ISOMERISM
12 Write all Isomers of C H12.Write all Isomers of C4H8
13.Write all Isomers of C5H10
14.Write all GI of C2HClBr2
15 Write all GI of C HClBrI15.Write all GI of C2HClBrI
16.Write G.I of 1,3,5,7‐Octatetraene
S.K.S
inha
Checkout the unique 3D visual presentation for the 1st time at https://play.google.com/store/apps/details?id=air.geo.isomer