geology of the great orme, llandudno

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Geology of the Great Orme, Llandudno Professor Cathy Hollis, Dr Alanna Juerges, University of Manchester The Great Orme is of great interest to Earth Scientists because of its spectacular exposure of Lower Carboniferous Limestone. As well as forming a distinctive landscape, and supporting a unique ecosystem, limestone has significant socio-economic importance. It forms aquifers for the supply of freshwater and geothermal water, hosts mineralization that supplies copper, lead, barium and fluorine and reservoirs giant oil and gas reserves in some parts of the world. Limestone is often an important source of local building stone and aggregate, as well as supplying the raw materials for cement. Although not all of these resources are exploited on the Great Orme, the same rocks that outcrop here have been mined and quarried extensively across North Wales. In addition, the Great Orme provides an important record of continental break-up and mountain building during the Carboniferous period, which coincided with a major change in the Earth’s climate. The Great Orme Limestone: an ancient carbonate platform Carbonate platforms are accumulations of organisms and grains that are composed of calcium carbonate (CaCO3). In order for carbonate-secreting organisms to grow, it is usually necessary to have clear, warm shallow water – this occurs today largely in sub-tropical zones between the Tropic of Cancer and Tropic of Capricorn. It is at these latitudes that we find modern carbonate platforms, such as the Bahamas, British West Indies, Maldives and the Great Barrier Reef. Through geological time, however, the temperature of the World’s oceans has varied, and during warm periods it was possible for carbonate platforms to grow at higher latitudes. Figure 1 Bedded limestone of the Great Orme Limestone Formation, looking north-west from Llandudno Pier In the uppermost Lower Carboniferous (approximately 335 to 330 million years ago), the Earth’s climate was warm. It was on the brink of a major glaciation, however, that led to the formation of a large ice sheet in the southern hemisphere; the so-called Gondwana glaciation. The limestone that outcrops on the Great Orme is part of the North Wales Platform, which stretched from Anglesey to the Welsh Borders, and formed on the margin of a landmass, called the Wales-Brabant Massif. It was one of many carbonate platforms that formed in the shallowest parts of warm equatorial seas across an area covering modern day western Europe and north America, on the edge of the Euramerican continent.

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Page 1: Geology of the Great Orme, Llandudno

Geology of the Great Orme, Llandudno

Professor Cathy Hollis, Dr Alanna Juerges, University of Manchester

The Great Orme is of great interest to Earth Scientists because of its spectacular exposure of Lower

Carboniferous Limestone. As well as forming a distinctive landscape, and supporting a unique

ecosystem, limestone has significant socio-economic importance. It forms aquifers for the supply of

freshwater and geothermal water, hosts mineralization that supplies copper, lead, barium and

fluorine and reservoirs giant oil and gas reserves in some parts of the world. Limestone is often an

important source of local building stone and aggregate, as well as supplying the raw materials for

cement. Although not all of these resources are exploited on the Great Orme, the same rocks that

outcrop here have been mined and quarried extensively across North Wales. In addition, the Great

Orme provides an important record of continental break-up and mountain building during the

Carboniferous period, which coincided with a major change in the Earth’s climate.

The Great Orme Limestone: an ancient carbonate platform

Carbonate platforms are accumulations of organisms and grains that are composed of calcium

carbonate (CaCO3). In order for carbonate-secreting organisms to grow, it is usually necessary to

have clear, warm shallow water – this occurs today largely in sub-tropical zones between the Tropic

of Cancer and Tropic of Capricorn. It is at these latitudes that we find modern carbonate platforms,

such as the Bahamas, British West Indies, Maldives and the Great Barrier Reef. Through geological

time, however, the temperature of the World’s oceans has varied, and during warm periods it was

possible for carbonate platforms to grow at higher latitudes.

Figure 1 Bedded limestone of the Great Orme Limestone Formation, looking north-west from

Llandudno Pier

In the uppermost Lower Carboniferous (approximately 335 to 330 million years ago), the Earth’s

climate was warm. It was on the brink of a major glaciation, however, that led to the formation of a

large ice sheet in the southern hemisphere; the so-called Gondwana glaciation. The limestone that

outcrops on the Great Orme is part of the North Wales Platform, which stretched from Anglesey to

the Welsh Borders, and formed on the margin of a landmass, called the Wales-Brabant Massif. It

was one of many carbonate platforms that formed in the shallowest parts of warm equatorial seas

across an area covering modern day western Europe and north America, on the edge of the

Euramerican continent.

Page 2: Geology of the Great Orme, Llandudno

The Great Orme is largely made up of the Great Orme Limestone (Figure 1), which has a diverse

array of fauna such as crinoids (sea lilies), echinoids (sea urchins), corals, bryozoan, brachiopods and

small planktonic organisms called foraminifera. This suggests that environmental conditions were

good; the water was warm and clear with good light penetration. The presence of small coral –

crinoid – bryozoan rich mounds on Little Orme and Great Orme, as well as preservation of ancient

sedimentary structures that show evidence for wave activity, suggest that the margin of the North

Wales carbonate platform occurred in the vicinity of the Great Orme. To the north, a deeper water

ocean basin was connected to the Pennine Basin to the east.

Figure 2 Dark, bedded limestone of the Bishops Quarry Formation, with abundant Gigantoproductid

brachiopods (notebook for scale, ~20cm long)

At the top of the Orme, in the Bishops Quarry and Summit area, the character of the limestone

changes dramatically- it becomes darker and dominated by large brachiopods, called

Gigantoproductids (Figure 2). This suggests that by around 330Ma, the North Wales Carbonate

Platform had begun to decline, either because it was poisoned by suspended clay material derived

from the landmass or because sea level had begun to rise.

The Great Orme as a record of sea level change

Across the Great Orme, the Great Orme Limestone shows a distinctive layering where beds of

limestone form apparently regular layers (Figure 1). Some of these layers are capped by red and

yellow coloured mudrocks, which are interpreted to be ancient soils (Figure 3). During the latest

Lower Carboniferous, the formation of the Gondawanan ice sheet in the southern hemisphere led to

a cooling of the Earth’s climate and a change in seawater chemistry. As the ice began to form, sea

level was lowered, rising again during inter-glacials. It is possible that these changes are recorded by

the ancient soils on the Great Orme; since limestone can only form beneath sea level, it will become

altered by rainfall and plant colonisation when it is exposed above sea level. It is also possible,

Page 3: Geology of the Great Orme, Llandudno

however, that there is no regularity in the pattern of soil formation on the Great Orme, and that soils

simply formed locally as a result of subtle changes in topography on the platform top.

Figure 3 Red-coloured palaeosol (ancient soil) on Marine Drive (East of Happy Valley) providing

evidence that the Great Orme Limestone became exposed above sea level and colonised by plants

during the Carboniferous.

The Great Orme as a record of mountain-building processes

As well as changes in the Earth’s climate in the Lower Carboniferous, major tectonic events were

leading to the collision of plates to form the super-continent Pangea. After carbonate deposition

stopped, around 330 million years ago, the North Wales Platform was buried to a depth of around

1km. The basin was inundated with sediment supplied by large river systems flowing southwards

from the Euramerican continent, forming the swampy conditions that led to deposition of the Upper

Carboniferous Coal Measures. In the latest Carboniferous and early Permian, closure of the Rheic

Ocean to the south of the North Wales Platform led to collision of the Euramerican plate with

Gondwana, to the south. The impact of this collision led to folding and faulting across North Wales

and Northern England. On the Great Orme, the effect of this collision is seen in a number of large

faults that cross cut the outcrop (Figure 4).

Page 4: Geology of the Great Orme, Llandudno

Figure 4 Fault zone on western Orme, near Tollhouse on Abbey Road / Marine Drive

Unravelling chemical processes in carbonate rocks

One of the characteristic features of the faults that cut the Great Orme Limestone is that they

exhibit alteration of the limestone to a magnesium-rich carbonate rock called dolostone. Dolostone

and the mineral that it comprises, dolomite (CaMg.(CO3)2), has intrigued geologists for centuries.

Although it is abundant in the Earth’s crust it does not form in modern sedimentary systems, even

though seawater is supersaturated with respect to magnesium.

Figure 5: contact between dolostone (brown) and limestone (white) within the Pier Dolomite, on the

beach near Llandudno Pier (left) and close-up (right) of dolostone-limestone contact, an ancient

reaction front

On the Great Orme, there is excellent exposure of dolostone in a number of locations. It can be

identified by it’s characteristic dark brown colour, which contrasts with the white colour of the Great

Orme Limestone, and its crystalline texture (Figure 5). It is particularly well exposed on the beach

near the Pier (the so-called ‘Pier Dolomite’). Here, the Pier Dolomite shows a spectacular example of

the termination of a dolostone body – an ancient reaction front formed when replacement of the

limestone by dolomite stopped (Figure 5). Geologists still don’t fully understand what controls these

Page 5: Geology of the Great Orme, Llandudno

reactions and their termination, which could be related to changes in fluid chemistry, temperature

or hydrology. At other locations on the Orme, dolostone is usually restricted to faults, forming a

zone – or halo- of alteration around the fault. This alteration zone ranges in thickness from a few

centimetres to several hundred metres, depending on the size of the fault.

Figure 6 Clasts of brown dolostone cemented by white dolomite cement within a fault zone on the

western side of the Great Orme (camera lens for scale, ~ 5cm)

The occurrence of dolostone along faults suggests that the fluids needed to form dolostone were

supplied along the faults which can act as very effective fluid conduits when they are activated by

plate tectonic events. Within a fault on the western side of the Orme, clasts of dolostone have been

broken up and healed by dolomite cement to form a breccia (Figure 6). Around some faults, and

within the Pier Dolomite, classic examples of so-called ‘zebra dolomite’ are observed. These

enigmatic features give dolostone a stripy, zebra-like, effect (Figure 7). Although their origin is not

fully understood, they are thought to form when stress is applied to rock prior to faulting.

Figure 7 ‘Zebra dolomite’ fabrics within the Pier Dolomite record stresses imposed on the dolostone

during plate collision and faulting in the Upper Carboniferous (pencil ~15 cm, camera lens cap ~ 5cm

diameter)

The Great Orme as a mineral deposit

The Great Orme is well-renowned for its copper deposits, which have been exploited since the

Bronze Age. The primary ore is chalcopyrite (CuFeS2), which has locally been oxidized to malachite

(Cu2CO3(OH)2). It is often observed within veins (fractures) in the rock, which cross-cut the dolostone

(Figure 8). This means that it must have formed after the dolostone, and microscopic examination of

Page 6: Geology of the Great Orme, Llandudno

the rocks suggests that it was one of the last geological events to occur on the Great Orme. Current

estimates suggest that copper ores were formed from fluids expelled into the Great Orme limestone

during the Alpine Orogeny in the late Cretaceous.

Figure 8 Zebra fabrics in Pier Dolomite cross cut by black veins (fractures) containing malachite