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GC/MS BATCH NUMBER: O10106

ESSENTIAL OIL: ORANGE BLOOD

BOTANICAL NAME: CITRUS SINENSIS

ORIGIN: ITALY

KEY CONSTITUENTS PRESENT IN THIS BATCH OF

ORANGE BLOOD OIL

%

LIMONENE 93.2

MYRCENE 1.8

Comments from Robert Tisserand: Full-bodied, sweet citrus odor quality. All thirteen key ISO

constituents are within range.

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Date : May 25, 2018

CERTIFICATE OF ANALYSIS – GC PROFILING

SAMPLE IDENTIFICATION

Internal code : 18E18-PTH3-1-CC

Customer identification : Orange Blood - Italy - O1010682R

Type : Essential oil

Source : Citrus sinensis

Customer : Plant Therapy

ANALYSIS

Method: PC-PA-014-17J19 - Analysis of the composition of an essential oil, or other volatile liquid, by

FAST GC-FID (in French); identifications validated by GC-MS.

Analyst : Sylvain Mercier, M. Sc., Chimiste

Analysis date : May 24, 2018

Checked and approved by :

Alexis St-Gelais, M. Sc., chimiste 2013-174

Note: This report may not be published, including online, without the written consent from Laboratoire

PhytoChemia.

This report is digitally signed, it is only considered valid if the digital signature is intact.

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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PHYSICOCHEMICAL DATA

Physical aspect: Bright yellow/orange liquid

Refractive index: 1.4715 ± 0.0003 (20 °C)

CONCLUSION

No adulterant, contaminant or diluent has been detected using this method.

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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ANALYSIS SUMMARY

Identification DB-5 (%) DB-WAX (%) Classe

Hexanal tr tr Aliphatic aldehyde

Heptanal tr tr Aliphatic aldehyde

α-Thujene tr tr Monoterpene

α-Pinene 0.46 0.47 Monoterpene

Camphene tr tr Monoterpene

Sabinene 0.44* 0.38 Monoterpene

β-Pinene [0.44]* 0.06 Monoterpene

Myrcene 1.82 1.82 Monoterpene

α-Phellandrene 0.31* 0.03 Monoterpene

Octanal [0.31]* 0.29 Aliphatic aldehyde

Δ3-Carene 0.13 0.13 Monoterpene

para-Cymene 93.14* 0.02 Monoterpene

Limonene [93.14]* 93.23 Monoterpene

1,8-Cineole [93.14]* 0.21 Monoterpenic ether

(Z)-β-Ocimene tr tr Monoterpene

(E)-β-Ocimene 0.02 0.03 Monoterpene

γ-Terpinene tr 0.01 Monoterpene

cis-Sabinene hydrate 0.01 0.01 Monoterpenic alcohol

Octanol 0.05 0.05 Aliphatic alcohol

Isoterpinolene tr tr Monoterpene

Terpinolene 0.04 0.04 Monoterpene

Linalool 0.58 0.59 Monoterpenic alcohol

Nonanal 0.07 0.07 Aliphatic aldehyde

trans-para-Mentha-2,8-dien-1-ol 0.02 0.01 Monoterpenic alcohol

cis-Limonene oxide 0.02 0.02 Monoterpenic ether

cis-para-Mentha-2,8-dien-1-ol 0.01 0.09* Monoterpenic alcohol

trans-Limonene oxide 0.02 0.02 Monoterpenic ether

Citronellal 0.06 0.06 Monoterpenic aldehyde

Terpinen-4-ol 0.01 0.01 Monoterpenic alcohol

α-Terpineol 0.10 0.12* Monoterpenic alcohol

cis-Piperitol tr tr Monoterpenic alcohol

Decanal 0.33 0.31 Aliphatic aldehyde

Octyl acetate 0.02 0.01 Aliphatic ester

trans-Carveol 0.01 0.01 Monoterpenic alcohol

Nerol 0.01 0.01 Monoterpenic alcohol

cis-Carveol 0.01 0.01 Monoterpenic alcohol

Neral 0.09 [0.09]* Monoterpenic aldehyde

(E)-Isogeraniol? 0.01 0.01 Monoterpenic alcohol

Geraniol 0.02 0.01 Monoterpenic alcohol

Perillaldehyde 0.02 0.02 Monoterpenic aldehyde

Geranial 0.12 0.12 Monoterpenic aldehyde

Limonen-10-ol 0.01 0.01 Monoterpenic alcohol

Undecanal 0.02 0.01 Aliphatic aldehyde

Neryl acetate tr 0.01 Monoterpenic ester

α-Copaene 0.03 0.03 Sesquiterpene

Geranyl acetate 0.03 0.03 Monoterpenic ester

β-Elemene 0.01 0.01 Sesquiterpene

Dodecanal 0.05 0.05 Aliphatic aldehyde

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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β-Caryophyllene 0.02 0.02 Sesquiterpene

β-Copaene 0.02 0.02 Sesquiterpene

α-Humulene 0.01 0.01 Sesquiterpene

(E)-β-Farnesene 0.01 0.01 Sesquiterpene

γ-Muurolene tr 0.01 Sesquiterpene

Germacrene D 0.02 [0.12]* Sesquiterpene

Valencene 0.04 0.04 Sesquiterpene

α-Muurolene 0.01 tr Sesquiterpene

γ-Cadinene 0.01 0.04 Sesquiterpene

δ-Cadinene 0.03 [0.04] Sesquiterpene

Caryophyllene oxide 0.01 0.01 Sesquiterpenic ether

β-Sinensal 0.02 0.02 Sesquiterpenic aldehyde

α-Sinensal 0.01 0.02 Sesquiterpenic aldehyde

Myristic acid 0.04 0.04 Aliphatic acid

Palmitic acid 0.08 0.09 Aliphatic acid

Linoleic acid 0.05 0.04 Aliphatic acid

Oleic acid 0.03 0.08* Aliphatic acid

cis-Vaccenic acid? 0.02 [0.08]* Aliphatic acid

Stearic acid 0.15 0.14 Aliphatic acid

Tetramethoxyflavone isomer 0.02 Flavonoid

Tangeretin 0.02 Flavonoid

3,3',4',5,6,7,8-Heptamethoxyflavone tr Flavonoid

Nobiletin 0.01 Flavonoid

Total identified 98.76% 99.03%

*: Two or more compounds are coeluting on this column

[xx]: Duplicate percentage due to coelutions, not taken account in the identified total

tr: The compound has been detected below 0.005% of total signal. Note: no correction factor was applied

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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This page was intentionally left blank. The

following pages present the complete data of the

analysis.

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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FULL ANALYSIS DATA

Identification Column DB-5 Column DB-WAX

R.T R.I % R.T R.I %

Hexanal 1.39 797 tr 1.86 1048 tr

Heptanal 2.56 901 tr 3.03 1151 tr

α-Thujene 2.91 924 tr 1.42 1004 tr

α-Pinene 2.98 929 0.46 1.36 995 0.47

Camphene 3.17 942 tr 1.69 1032 tr

Sabinene 3.58* 970 0.44 2.27 1088 0.38

β-Pinene 3.58* 970 [0.44] 2.09 1070 0.06

Myrcene 3.92 993 1.82 2.88 1139 1.82

α-Phellandrene 4.08* 1003 0.31 2.77 1131 0.03

Octanal 4.08* 1003 [0.31] 4.42 1255 0.29

Δ3-Carene 4.14 1007 0.13 2.58 1116 0.13

para-Cymene 4.65* 1039 93.14 4.09 1231 0.02

Limonene 4.65* 1039 [93.14] 3.39 1179 93.23

1,8-Cineole 4.65* 1039 [93.14] 3.40 1180 0.21

(Z)-β-Ocimene 4.70 1042 tr 3.71 1203 tr

(E)-β-Ocimene 4.83 1051 0.02 3.98 1223 0.03

γ-Terpinene 4.91 1056 tr 3.78 1209 0.01

cis-Sabinene hydrate 5.05 1065 0.01 6.86 1431 0.01

Octanol 5.21 1075 0.05 8.15 1529 0.05

Isoterpinolene 5.36 1084 tr 4.21 1240 tr

Terpinolene 5.38 1086 0.04 4.27 1244 0.04

Linalool 5.63 1102 0.58 8.03 1519 0.59

Nonanal 5.68 1105 0.07 5.85 1358 0.07

trans-para-Mentha-

2,8-dien-1-ol 5.88 1118 0.02 8.90 1587 0.01

cis-Limonene oxide 6.06 1129 0.02 6.40 1397 0.02

cis-para-Mentha-2,8-

dien-1-ol 6.10 1132 0.01 9.44* 1630 0.09

trans-Limonene oxide 6.14 1134 0.02 6.56 1409 0.02

Citronellal 6.42 1153 0.06 6.97 1440 0.06

Terpinen-4-ol 6.73 1172 0.01 8.53 1558 0.01

α-Terpineol 6.95 1187 0.10 9.74* 1654 0.12

cis-Piperitol 7.00 1190 tr 9.55 1639 tr

Decanal 7.25 1206 0.33 7.28 1463 0.31

Octyl acetate 7.39 1215 0.02 7.05 1446 0.01

trans-Carveol 7.43 1218 0.01 11.34 1789 0.01

Nerol 7.57 1227 0.01 11.02 1761 0.01

cis-Carveol 7.61 1230 0.01 11.68 1818 0.01

Neral 7.73 1238 0.09 9.44* 1630 [0.09]

(E)-Isogeraniol? 7.99 1255 0.01 11.14 1772 0.01

Geraniol 8.02 1257 0.02 11.59 1810 0.01

Perillaldehyde 8.15 1266 0.02 10.68 1733 0.02

Geranial 8.18 1269 0.12 10.07 1681 0.12

Limonen-10-ol 8.45 1286 0.01 13.08 1945 0.01

Undecanal 8.74 1306 0.02 8.64 1567 0.01

Neryl acetate 9.54 1363 tr 10.15 1688 0.01

α-Copaene 9.65 1371 0.03 7.12 1451 0.03

Geranyl acetate 9.86 1385 0.03 10.50 1717 0.03

Essential oil, Citrus sinensis Report prepared for Internal code: 18E18-PTH3-1-CC Orange Blood - Italy - O1010682R Plant Therapy

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β-Elemene 9.90 1388 0.01 8.39 1547 0.01

Dodecanal 10.18 1408 0.05 9.96 1672 0.05

β-Caryophyllene 10.22 1411 0.02 8.38 1546 0.02

β-Copaene 10.36 1422 0.02 8.32 1542 0.02

α-Humulene 10.68 1445 0.01 9.24 1614 0.01

(E)-β-Farnesene 10.83 1457 0.01 9.51 1636 0.01

γ-Muurolene 11.02 1471 tr 9.59 1642 0.01

Germacrene D 11.05 1474 0.02 9.74* 1654 [0.12]

Valencene 11.22 1486 0.04 9.86 1664 0.04

α-Muurolene 11.36 1497 0.01 10.00 1676 tr

γ-Cadinene 11.51 1508 0.01 10.33† 1703 0.04

δ-Cadinene 11.64 1518 0.03 10.38† 1707 [0.04]

Caryophyllene oxide 12.33 1572 0.01 12.72 1911 0.01

β-Sinensal 13.80 1693 0.02 15.39 2168 0.02

α-Sinensal 14.45 1749 0.01 16.34 2267 0.02

Myristic acid 14.65 1766 0.04 20.12 2696 0.04

Palmitic acid 16.82 1965 0.08 21.85 2915 0.09

Linoleic acid 18.49 2131 0.05 24.01 3212 0.04

Oleic acid 18.55 2137 0.03 23.64* 3160 0.08

cis-Vaccenic acid? 18.60 2142 0.02 23.64* 3160 [0.08]

Stearic acid 18.83 2166 0.15 23.40 3126 0.14

Tetramethoxyflavone

isomer 26.69 3132 0.02

Tangeretin 26.75 3139 0.02

3,3',4',5,6,7,8-

Heptamethoxyflavone27.61 3231 tr

Nobiletin 27.69 3238 0.01

Total identified 98.76% 99.03%

Total reported 98.76% 99.03%

*: Two or more compounds are coeluting on this column

[xx]: Duplicate percentage due to coelutions, not taken account in the identified total

†: Peaks apexes were resolved, but peaks overlapped and were summed for analysis

tr: The compound has been detected below 0.005% of total signal. Note: no correction factor was applied

R.T.: Retention time (minutes)

R.I.: Retention index