gate metallurgical engineering 4
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GATE Metallurgical Engineering
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Stainless Steels
These are stain less as these have a minimum of 11 to 12% Cr which is
having more affinity for oxygen than iron, forms a very thin, continuous
protective and stable oxide (Cr 2O3) film on the surface. Thus Cr imparts
corrosion and oxidation resistance and pleasing appearance. Ni. Mo and Mn
enhance strength and improve corrosion resistance. Based on amount and
type of alloying elements these steels are classified into 5 types.
Ferritic: (% Cr – 17 × %C) > 12.7 i.e usually 17 to 26 % Cr. These alloys
are ferritic in structure up to the melting point. These can’t be heat treated.
Cold working is the only strengthening mechanism. These may containsmall additions of Mn, Si, Ni, Al, Mo and Ti. Carbon is kept very low to
increase toughness to avoid sensitization. Mo is added to improve resistance
to pitting corrosion; Nb and Ta are added to stabilize against intergranular
corrosion. These are not susceptible to stress corrosion cracking, thus used
in chemical plants. These are used as heat-resisting elements in the making
of furnace components. Less expensive, good machinability, higher thermal
conductivity, low thermal expansion than austenitic. These steels show
ductile to brittle transition. Ridging or roping, temper embrittlement, sigma
phase and grain growth in HAZ are few problems associated with these
steels.
Martensitic: (% Cr – 17 × %C) ≤ 12.7. Heat treatable steels (as these are
austenitic at tem ps 950 - 1000°C). As Cr content is more, air cooling is
enough to form martensite which is not brittle due to low carbon content.
(1) Low carbon high strength martensitic types are developed to ensure
good weldability, formability and impact toughness. Tempering temperature
of 440 – 550°C should be avoided (temper embrittlement). These are used
in petrochemical, chemical plants, compressors, discs, aircraft structural and
engine parts, propeller shafts. (2) High carbon high hardness martensitic
types (poor eldability, formability and ductility) are used in cutlery, surgical
instruments, springs, high quality ball bearings, razor blades, cool hammers.
Austenitic: (17 – 18% Cr, 8 – 10% Ni, C < 0.03%) these contain sufficient
amount of austenitic stabilizers Ni, Mn or N so that steels are austenitic
even at RT. To avoid intergranular corrosion and weld decay ‘C’ should be
less than 0.03%. Mo is added to improve pitting resistance and sulphuric
acid corrosion. Nb and Ti are added to take care of weld decay. Excellent
formability, high work hardening (low stacking fault energy), large uniform
elongation, non-magnetic, no ductile to brittle transition (tough even at verylow temperatures; cryogenic applications). These are not susceptible to
temper embrittlement, but shows reduced ductility in temperature range 750
– 950°C due to brittle intermetallic formation (sigma phase). These are
susceptible to stress corrosion cracking. These can be strengthened by cold
working or solid solution strengthening. These are used in chemical
industry, house hold, sanitary, biomedical, architectural, food industries,
nuclear and marine applications.
Duplex : these are developed to utilize combination of properties of ferrite
and austenite (Toughness, weldability with strength and localized corrosion
resistance). These are stronger than austenitic steels. Presence of δ-ferrite
cause grain-refinement of austenite hence increases strength. Further
refinement is obtained by using controlled rolling at 900 - 950°C which
results in very fine dispersion of ferrite and austenite grains. These steels
exhibit superplasticity (500% elongation at 950°C). Good corrosionresistance similar to Austenitic type. Not susceptible to stress corrosion
cracking and free from intergranular corrosion. These have ductile to brittle
transition temperature. These suffer from temper embrittlement and sigma
phase embrittlement.
Precipitation hardenable: these offer combination of properties but
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expensive and difficult to hot-process. These are used particularly for high
temperature applications such as power-plant. Strengthening is because of
precipitates like Ni3Al, Ni3Ti or Ni3Mo etc. on ageing. These are
susceptible to hydrogen embrittlement. The matrix can be (1) martensitic
(2) semi-austenitic (3) austenitic.
Labels: New in GATE 2012
What is New in GATE 2012?
Application Process:
In GATE 2012, candidates need to register and fill the application ONLINE only by
accessing the zonal GATE websites of IISc and seven IITs. The application process
is complete only when a print out of the filled ONLINE application with the
candidate's signature and a good quality photo affixed in the appropriate place is
received by the respective GATE office along with necessary documents, if any, on
or before 24 October 2011. Please note that sale of application forms through banks
and GATE office counters has been discontinued.
Downloadable Admit Card:
Sending Admit cards by post has been discontinued from this year. Admit cards can
only be downloaded from the zonal GATE websites from 2nd January 2012. Bring
the admit card to the test center along with at least one original (not photocopied /
scanned copy) and valid (not expired) photo identification.
Use of black ink ball point pen:
The use of pencils to darken the bubbles in the answer sheet has been discontinued
from this year. Candidates should use only black ink ball point pen for darkening of the bubbles in the answer sheet. Since bubbles darkened by the black ink ball point
pen cannot be erased, candidates should darken the bubbles in the answer sheet
very carefully.
ONLINE examination in two additional papers:
In GATE 2011, the papers with codes GG, TF, AE and MN had ONLINE
examination. In GATE 2012, two additional papers, AR and AG, will also have
ONLINE examination. The ONLINE examination will be conducted in two sessions
on Sunday, January 29, 2012.
Forenoon session (09:00 hrs to 12:00 hrs): AR, GG and TF.
Afternoon session (14:00 hrs to 17:00 hrs): AE, AG and MN.
Numerical answer type questions in ONLINE papers:
In the ONLINE papers (AE, AG, AR, GG, MN and TF), the question paper wil l
consist of questions of multiple choice type and questions of numerical answer
type. For multiple choice type questions, each question will have four choices for
the answer. For numerical answer type questions, each question will have a number
as the answer. The number of numerical answer type questions may vary between
5 and 10 in each question paper.
Pre-final year students:
Pre-final year students are not eligible to write GATE 2012. For details, refer to
eligibility for GATE examination.
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