0 2 4 6 8 10 12

Cr2O3

0

4

8

12

CaO

0 2 4 6 8 10 12 14

Cr2O3

4

8

12

16

20

FeO

0 2 4 6 8 10 12 14

Cr2O3

0

0.4

0.8

1.2

1.6

2

TiO2

0 2 4 6 8 10 12 14

Cr2O3

8

12

16

20

24

M gO

0 2 4 6 8 10 12 14

Cr2O3

0

0.05

0.1

0.15

0.2

0.25

Na2O

0 2 4 6 8 10 12 14

Cr2O3

0

0.2

0.4

0.6

0.8

NiO

K om som o lsk ay aConcentrateXenoliths

0 0.05 0.1 0.15 0.2

N iO %

0

4

8

12

16

20

N

45 47 49 51 53 55

T iO 2 %

04812162024

N

44 48 52

T iO 2 %

0.0

1.0

2.0

3.0

4.0

A l2 O 3 %

44 48 52

T iO 2 %

0.0

1.0

2.0

3.0

4.0

5.0

C r2 O 3 %44 48 52

0

10

20

30

40

50

FeO %

44 48 52

0

4

8

12

16

M gO %44 48 52

0.0

0.2

0.4

0.6

0.8

1.0

M nO %

44 48 52

0.0

0.1

0.2N iO %

0 0.2 0.4 0.6 0.8 1

A l2 O 3 %

0

10

N

28 32 36 40 44

FeO %

0

4

8 N

0 2 4 6 8

M gO %

0

4

8

12 N

0 0.2 0.4 0.6

M nO %

0510152025303540 N

0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5

C r2 O 3 %

0

10

20

30

40

N

30.0

40.0

50.0

60.0 T i O 2 %

0 4 8 12 16 20

M gO %

0 % F e2O 3

20 % F e2 O 3

40 % F e2O 3

60 %F e2O 380 % F e2O 3 100 % F e 2O 3

44 48 52

0.0

0.2

0.4

0.6

0.8

1.0

V 2 O 5 %

0 0.1 0.2 0.3 0 .4 0.5 0.6 0 .7 0.8

V 2 O 5 %

0

4

8

12

16

20

N

La Pr Eu Tb Ho Tm Lu

0.01

0.10

1.00

10.00

100.00

Sam

ple

/C1

Rb Th Nb La Pb Nd Sm Zr Gd Ho Er Lu

0.00

0.01

0.10

1.00

10.00

100.00

Sam

ple

/PM

Garnets

Ilm enites

Chr

Ce Nd Sm Gd Dy Er Yb Cs Ba U Ta Ce Pr Sr Hf Eu Dy Y Yb

Cs Ba U Ta Ce Pr Sr Hf Eu Dy Y Yb

La Pr Eu Tb Ho Tm Lu

0.01

0.10

1.00

10.00

Sam

ple

/PM

La Pr Eu Tb Ho Tm Lu

0.01

0.10

1.00

10.00

Sam

ple

/PM

Ce Nd Sm Gd Dy Er Yb Rb Th Nb La Pb Nd Sm Zr Gd Ho Er Lu

0.01

0.10

1.00

10.00

Sam

ple

/PM

Ce Nd Sm Gd Dy Er Yb Rb Th Nb La Pb Nd Sm Zr Gd Ho Er Lu

0.00

0.01

0.10

1.00

10.00

100.00

1000.00

Sam

ple

/PM

Cs Ba U Ta Ce Pr Sr Hf Eu Dy Y YbLa Pr Eu Tb Ho Tm Lu

0.01

0.10

1.00

10.00

Sa

mp

le/P

M

Rb Th Nb La Pb Nd Sm Zr Gd Ho Er Lu

0.00

0.01

0.10

1.00

10.00

100.00

1000.00

Sam

ple

/PM

La Pr Eu Tb Ho Tm Lu

0.10

1.00

10.00

100.00

1000.00

Sa

mp

le/P

M

Ce Nd Sm Gd Dy Er Yb Rb Th Nb La Pb Nd Sm Zr Gd Ho Er Lu

0.10

1.00

10.00

100.00

1000.00

Sam

ple

/PM

Cs Ba U Ta Ce Pr Sr Hf Eu Dy Y Yb

1 . 2 . 3 . 4 . 5 .6 .7 .

1 . 2 . 3 . 4 . 5 . 6 .

1 .2 .3 .

1 .

1 .2 .

Clinopyroxenes

Ilm

Phl

0 20 40 60 80

Cr2O3

0

4

8

12

16

TiO 2

0 20 40 60

Cr2O3

10

20

30

40

50

FeO

0 20 40 60

Cr2O3

0

10

20

30

40

50

Al2O 3

0 20 40 60

Cr2O3

0

0.2

0.4

0.6

0.8

1

1.2

MnO

0 20 40 60 80

Cr2O 3

0

0.1

0.2

0.3

0.4

NiO

0 20 40 60 80

Cr2O3

0

0.1

0.2

0.3

0.4

0.5

V2O 5

0 20 40 60 80

Cr2O3

4

8

12

16

20

MgO

ConcentrateXenoliths

2 4 6FeO %

0

1

2

3

4

5

Cr 2

O3

%

2 4 6FeO %

0

0.2

0.4

0.6

0.8

1

TiO

2 %

2 4 6

2

4

6

Na

2O %

2 4 6

4

8

12

Al 2

O3

%

8 16MgO %

2

4

6

8

10

Na

2O %

ConcentrateXenolithsMetasomatites with richteriteDiamond inclusions

Diamond Eclogites (Spetsius, 2008; Pernet-Fisher et al.,2014)

Garnet and chromite- bearing mantle peridotite xenoliths from

Komsomolskaya pipe, Alakit field, YakutiaIgor Ashchepkov (1), Alla Logvinova (1), Nikolai Valdykin (2), Igor Makovchuk (3), Mikhail Karpenko (3),

Zdislav Spetsius (3), Olga Khmelnikova (1), and Stanislav Palessky (1) Sobolev Institute of Geology and Mineralogy SD RAS, Koptyug ave 3, Novosibirsk, Russia (1)

Institute of Geochemistry SB RAS, Irkutsk Russia, (2), ALROSA Stock company, Russia (3)Fresh xenoliths in Alakit field in Siberian platform are rare. In the xenoliths from Komsomolskaya pipe there were found 30 xenoliths with fresh Cpx, Gar as well as chromites, phlogopites and ilmenites which allows to construct the Cpx - based geotherm which was before constructed for the Yubileynaya pipe (Ashchepkov et al., 2004). The comparison of the garnets from the breccias and porphyric kimberlites show more depleted and Cr- rich varieties of garnets as it is common for the other pipes. Only relatively fresh material from the dark - grey breccia good relatively fresh xenoliths could be used for themineral thermobarometry. Large xenolths from the Komsomolskaya pipe belong mainly to the Gar harzburgite or rarely refertilized lherzolite types as also detected on the Cr2O3 - CaO diagram where they belong mainly to the 5-11% Cr2O3 interval. The low Cr varieties are mainly referring to the Fe- enriched pyroxenites or to Phl metasomatites. In SCLM beneath Komsomolskaya pipe is essentially more heated then those beneath Yubileynaya and Sytykanskaya pipes and in lower part they are close to the PTXFO2 are closer in conditions to the ilmenites which determined the . Peridotites from the lithosphere base (7-6GPa) are enriched in Fe and belong to the porphyroclustic or deformed type by chemistry Fe# =0.14-0.15. the relatively HT conditions were determined also for the peridotites from the 5.0-4. GPa. The most of the Cpx- refertilized varieties give the conditions of the middle part of the mantle section. Their garnets are enriched in CaO probably reflection reactions with the Ca- rich protokimberlites. The Na- richterite bearin xenoliths are from the same PT interval The cold clot in the 60-5.5 GPa (34 mwm-2) are represented by the peridotites of low Fe# 7-9 Fe- low peridotites with the garnets of sub-Ca types.But there are also varieties of reduced Cr and the Fe-enriched which are closer to the pyroxenites or Phl metasomatites which in Pt are from the upper part of mantle sections. The picroilmenites from the Komsomolskaya pipe belong to the two pressure intervals 6.5 to 5.0 and 5.0 to 4.0 GPa. They are forming two differentiations branches in the lower part of the mantle section. In the upper part the Cr- content is continuously rising together with Fe due to the AFC differentiation. But the typical metasomatic sporadic ilmenites are close in low Fe# 7-9 to the mantle peridotites. they are essentially higher in Cr2O3 to 4-6%. But ilmenites from refertilized peridotites have only 2-3 Cr2O3. The trace elements for the Cpx of mantle peridotites of refertilized type reveal high inclination of the REE patterns. they reveal Nb-Ta , Zr depression and varying peak in Pb but enrichment in U. Many of garnet shopw the slightly S- type REE pattern.Grants 11-05-00060; 11-05-91060-PICS and joint research projects of IGM SB RAS and ALROSA Stock company 77-2, 65-03, 02-05.

0.05 0.10 0.15 0.20 0.25 0.30 0.35600 800 1000 1200 1400

Fe# Ol in equilibrium with Cpx, Opx, Gar, Chr, Ilm

0.0 4.0 12.0 16.0 -6.0 -4.0 -2.0 0.0

SEA

T oCK om so m olsk a y a

X en o lith s a n d D a m o n d in c lu sio n s

45 m w /m 2

35 m w /m 2

Sp

Gr

40 m w /m 2

Diamond

Graphite

1. CaO in Gar2. Al2O3 in Opx3. Cr2O3 in Cpx4. TiO2 in Chr5. Cr2O3 in Ilm

8

7

6

5

4

3

2

1

0

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

0-LogFO 2

Variation of Cpx, Opx, Gar, Chr, Ilm

AFG

1. OpxBrM c2. OpxBrM cDiIn3. CPx NT004.CpxAs5.EclCpx6.PxtCpx7.DI Cpx 8.GarOW 79As9.GarDI10.ChrAs11. ChrDiaInc 12. Ilm M eg13. Ilm Xen14. BrKo90 E

MO

G/D

Pyroxenites with mica

Deformed peridotite

Coarse Garnet harzburgites

Garnet lherzolites with amphiboles

Coarse Garnet harzburgites

0.05 0.10 0.15 0.20 0.25 0.30 0.35

Fe# Ol in equilibrium with Cpx, Opx, Gar, Chr, Ilm

600 800 1000 1200 1400 0.0 4.0 8.0

Variationa of Cpx, Opx, Gar, Chr, Ilm

-6.0 -4.0 -2.0 0.0

-LogFO 2

SEA

T oC

K o m so m o lsk ay a

45 m w /m 2

35 m w /m 2

Sp

Gr

40 m w /m 2

Diamond

Graphite

1. CaO in Gar2. Al2O3 in Opx3. Cr2O3 in Cpx4. TiO2 in Chr5. Cr2O3 in Ilm

8

7

6

5

4

3

2

1

0

P(G

Pa

)

8

7

6

5

4

3

2

1

P(G

Pa

)

8

7

6

5

4

3

2

1

P(G

Pa

)

8

7

6

5

4

3

2

1

00.95 0.90 0.85 0.80 0.75 0.70 0.65

Mg' Ol in equilibrium with Cpx, Opx, Gar, Chr, Ilm

EM

OG

/D

6 8Si (f.u.)

0

0.1

0.2

0.3

0.4

Cr

(f.u

.)

6 8Si (f.u.)

0

0.05

0.1

0.15

0.2

0.25

Ti (

f.u

.)

6 8

0.004

0.008

0.012

0.016

0.02

Mn

(f.

u.)

6 8

1

2

3

Al

(f.u

.)

1. Sytykan2. Yubileinaya3. Experimental(Konzett, Ulmer, 1999)

6 8

0.4

0.8

1.2

1.6

2

Ca

(f.u

.)

K2O%0.8

1.2

1.6

2

Na

(f.u

.)

6 8FeO %

0.2

0.4

0.6

0.8

K (

f.u

.)

6 8Si

0.8

1.2

1.6

2

2.4

2.8

K+

Na

(f.u

.)

Pa

rga

sit

e

Pa

rga

sit

e h

orb

len

de

Ho

rble

nd

e

Ric

hte

rite

Pa

rga

sit

e

Ho

rble

nd

e

Ric

hte

rite

Pa

rga

sit

e h

orb

len

de

6 8

0.2

0.4

0.6

Fe

(f.

u.)

6 8

3.6

4

4.4

4.8

5.2

Mg

(f.

u.)

0.05 0.10 0.15 0.20 0.25 0.30 0.35600 800 1000 1200 1400

Fe# Ol in equilibrium with Cpx, Opx, Gar, Chr, Ilm

0.0 4.0 12.0 16.0 -6.0 -4.0 -2.0 0.0

SEA

T oCS y ty k a n sk a y a A u to lith ic

B recc ia

45 m w /m 2

35 m w /m 2

Sp

Gr

40 m w /m 2

Diamond

Graphite

1. CaO in Gar2. Al2O3 in Opx3. Cr2O3 in Cpx4. TiO2 in Chr5. Cr2O3 in Ilm

8

7

6

5

4

3

2

1

0

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

0-LogFO 2

Variation of Cpx, Opx, Gar, Chr, Ilm

AFG

EM

OG

/D

1. CaO in Gar2. Al2O3 in Opx3. Cr2O3 in Cpx4. TiO2 in Chr5. Cr2O3 in Ilm

0.05 0.10 0.15 0.20 0.25 0.30 0.35600 800 1000 1200 1400

Fe# Ol in equilibrium with Cpx, Opx, Gar, Chr, Ilm

0.0 4.0 12.0 16.0 -6.0 -4.0 -2.0 0.0

SEA

T oCS y ty k a n sk a y a X en o lith s

45 m w /m 2

35 m w /m 2

Sp

Gr

40 m w /m 2

Diamond

Graphite

8

7

6

5

4

3

2

1

0

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

P(GPa) 8

7

6

5

4

3

2

1

0-LogFO 2

Variation of Cpx, Opx, Gar, Chr, Ilm

AFG

EM

OG

/D

Garnets

SpinelsAmphiboles

Ilmenites

Clinopyroxenes

Komsomolskaya

Sytykanskaya

TRE formantle peridotites

TRE for eclogites(Pettit- Fishes etc, 2014)