from: [email protected] [mailto:[email protected]] … · 2018-04-07 · from:...

From: [email protected] [mailto:[email protected]] Sent: Friday, June 02, 2017 5:56 PMTo: Rich McGuire <[email protected]>; Terry Turpin <[email protected]>Subject: Data for Rover Stark Site

Hi Rich and Terry,

As you know, Ohio EPA recently discovered that diesel fuel constituents are present in the bentonite drilling mud associated with Rover’s large inadvertent return in Stark County. Out of an abundance of caution, Ohio EPA has begun ground water and drinking water well sampling near that Rover pipeline project.

Attached are the data results (originally sent you on May 26, 2017) from 2 separate sampling initiatives that resulted from 2 complaints of diesel fuel being added to the drilling fluid at the Stark site. The lab analyzed them using EPA Method 8015C for Diesel Range Organics (DRO). The attached pdf labeled “DRO Results” included 5 individual sampling locations and collection dates as follows:

1) IR Mud Breakout collected on 4/18/172) IR Mud Silo collected on 5/12/173) IR Mud Grid C1-D1 collected on 5/12/174) IR Mud 54 Return collected on 5/12/175) IR Mud W Reclaim Pit collected on 5/12/17

All of the above samples detected the presence of DRO.

Also attached are the lab data results (originally sent you on May 26, 2017) from supplemental sampling which were initiated based upon the DRO data. The lab analyzed them using EPA Method 8260B (Total VOCs), EPA Method 8270C (Total SVOCs), TCLP VOCs, TCLP SVOCs and TCLP Metals. The attached pdf labeled “Totals and TCLP Results prelim” included 7 individual sampling locations and collection dates as follows:

1) OSG Disposal Pit collected on 5/19/172) IR Mud Original collected on 5/19/173) IR Mud Silo collected on 5/19/174) IR Mud Grid A3 New collected on 5/19/175) West Borehole Return M collected on 5/19/176) West Reclaimer Pit collected on 5/19/177) East Reclaimer New Mud collected on 5/19/17

These results indicate that presence of petroleum hydrocarbons in 6 of the 7 samples. The sample of the new mud that has not been run through the machine came back as the cleanest of all samples. These results are consistent with the earlier DRO data, further confirming the presence of petroleum hydrocarbon constituents commonly found in diesel fuel. These results also include TCLP data which confirms that, although VOCs and SVOCs are present in the drilling fluid slurry, none of these constituents leach when subjected to the TCLP procedure. For your records, please find attached the final laboratory report of these samples for your records. At the time the email was sent on May 26, 2017, Ohio EPA had only received the preliminary data from the lab. The final lab report for the 7 samples collected on May 19, 2017 are attached and labeled as, “Totals and TCLP Results Final”.

20170605-4006 FERC PDF (Unofficial) 06/05/2017

At this time, the information obtained through Ohio EPA’s sampling efforts has not revealed diesel fuel contamination that constitutes an imminent threat to human health and the environment. However, Ohio EPA continues to be concerned with the presence of diesel fuel constituents in the bentonite mud generated by Rover and as a result, Ohio EPA will continue ground water monitoring to ensure that drinking water systems in the area remain safe. It is our understanding that FERC, with Ohio EPA coordination, will be requiring Rover to provide to FERC a plan to assume responsibility for ground water monitoring and, if necessary, response actions.

Ed

Please consider the environment before printing this email.


Laboratory Report Number: L17050904

Frank ZingalesOhio Environmental Protection Agency2110 East Aurora RoadTwinsburg, OH 44087

Please find enclosed the analytical results for the samples you submitted to Microbac Laboratories. Review and compilation of your report was completed by Microbac’s Ohio Valley Division (OVD). If you have any questions, comments, or require further assistance regarding this report, please contact your service representative listed below.

Laboratory Contact:Michelle Taylor – Client Services Specialist(740) [email protected]

I certify that all test results meet all of the requirements of the accrediting authority listed below. All results for soil samples are reported on a 'dry-weight' basis unless specified otherwise. Analytical results for water and wastes are reported on a 'as received' basis unless specified otherwise. A statement of uncertainty for each analysis is available upon request. This laboratory report shall not be reproduced, except in full, without the written approval of Microbac Laboratories. The reported results are related only to the samples analyzed as received.

This report was certified on May 18 2017

Leslie Bucina – Managing Director State of Origin: OHAccrediting Authority: N/A ID:OH00218QAPP: Microbac OVD

Microbac Laboratories * Ohio Valley Division158 Starlite Drive, Marietta, OH 45750 * T: (740) 373-4071 F: (740) 373-4835 * www.microbac.com

Page 1

L17050904 / Revision: 0 / 27 total pages Generated: 05/18/2017 14:40


Lab Report #: L17050904

Lab Project #: 2755.044

Project Name: NORTHEAST DISTRICT OFFICE #3

Lab Contact: Michelle Taylor

Record of Sample Receipt and InspectionComments/DiscrepanciesThis is the record of the shipment conditions and the inspection records for the samples received and reported as a sample delivery group (SDG). All of the samples were inspected and observed to conform to our receipt policies, except as noted below.

The following discrepancies were noted:Discrepancy Resolution

Sample ID: 17-0751 IR Mud Grid C1-D1 (5/12 @ 16:52). Container was received broken but a portion of the sample was still intact in the jar. Portion split out by lab to perform analyses. BRG

Please proceed. MRT

Sample ID: 17-0751 IR Mud Breakout (4/18 @ 11:30). No time on container. Will log per information on COC. BRG

Please log per the COC. MRT

Sample ID: 17-90751 IR Mud Breakout (4/18/17 @ 11:30). Sample received out of hold for DRO analyses. BRG

Please proceed. MRT

CoolersCooler # Temperature

GunTemperature COC # Airbill # Temp Required?

00114971 H 5.0 1Z98X0V30397689369 X

Inspection Checklist

# Question Result

1 Were shipping coolers sealed? Yes

2 Were custody seals intact? Yes

3 Were cooler temperatures in range of 0-6? Yes

4 Was ice present? Yes

5 Were COC's received/information complete/signed and dated? Yes

6 Were sample containers intact and match COC? No

7 Were sample labels intact and match COC? No

8 Were the correct containers and volumes received? Yes

9 Were samples received within EPA hold times? No

10 Were correct preservatives used? (water only) NA

11 Were pH ranges acceptable? (voa's excluded) NA

12 Were VOA samples free of headspace (less than 6mm)? NA

Microbac Laboratories ● Ohio Valley Division158 Starlite Drive, Marietta, OH 45750 ● T: (740)373-4071 F: (740)373-4835

www.microbac.com

Page 2







Samples ReceivedClient ID Laboratory ID Date Collected Date Received

17-0751 IR MUD SILO L17050904-01 05/12/2017 16:30 05/16/2017 10:11

17-0751 IR MUD GRID C1-D1 L17050904-02 05/12/2017 16:52 05/16/2017 10:11

17-0751 IR MUD 54 RETURN L17050904-03 05/12/2017 18:22 05/16/2017 10:11

17-0751 IR MUD WE RECLAIM PIT L17050904-04 05/12/2017 18:33 05/16/2017 10:11

17-0751 IR MUD BREAKOUT L17050904-05 04/18/2017 11:30 05/16/2017 10:11


www.microbac.com

Page 3







Certificate of AnalysisSample #: L17050904-01 PrePrep Method: N/A Instrument: HP14

Client ID: 17-0751 IR MUD SILO Prep Method: 3546 Prep Date: 05/16/2017 11:21

Matrix: Soil Analytical Method: 8015C Cal Date: 05/09/2017 13:30

Workgroup #: WG614544 Analyst: LJH Run Date: 05/16/2017 17:43

Collect Date: 05/12/2017 16:30 Dilution: 1 File ID: 14G67541

Sample Tag: 01 Units: ug/kg Percent Solid: 51.8

Analyte CAS # Result Qual RL MDL

Diesel Range (C10-C28) 68334-30-5 30400 18200 4540

Surrogate Recovery Lower Limit Upper Limit Q

o-Terphenyl 26.2 43 136 *

Octacosane 36.2 25 162

* Surrogate or spike compound out of range

Sample #: L17050904-02 PrePrep Method: N/A Instrument: HP14

Client ID: 17-0751 IR MUD GRID C1-D1

Prep Method: 3546 Prep Date: 05/16/2017 11:21






Diesel Range (C10-C28) 68334-30-5 233000 96300 24100



Octacosane 9.41 25 162 *



Client ID: 17-0751 IR MUD 54 RETURN







Diesel Range (C10-C28) 68334-30-5 256000 43900 11000


o-Terphenyl 53.4 43 136

Page 1 of 2 Generated at May 18, 2017 14:44

Page 4







Certificate of AnalysisOctacosane 52.3 25 162


Client ID: 17-0751 IR MUD WE RECLAIM PIT







Diesel Range (C10-C28) 68334-30-5 20500 J 30800 7700





J The analyte was positively identified, but the quantitation was below the RL


Client ID: 17-0751 IR MUD BREAKOUT Prep Method: 3546 Prep Date: 05/16/2017 11:21






Diesel Range (C10-C28) 68334-30-5 17300 J,H1 27800 6950





J,H1 The analyte was positively identified, but the quantitation was below the RL. Sample analysis performed past holding time.


Page 5







Sample #: L17050904-01 Client ID: 17-0751 IR MUD SILO Matrix: Soil Collect Date: 05/12/2017 16:30

Analyte Result Units Qualifier

Percent Solids 51.8 weight %

Sample #: L17050904-02 Client ID: 17-0751 IR MUD GRID C1-D1 Matrix: Soil Collect Date: 05/12/2017 16:52



Sample #: L17050904-03 Client ID: 17-0751 IR MUD 54 RETURN Matrix: Soil Collect Date: 05/12/2017 18:22



Sample #: L17050904-04 Client ID: 17-0751 IR MUD WE RECLAIM PIT

Matrix: Soil Collect Date: 05/12/2017 18:33



Sample #: L17050904-05 Client ID: 17-0751 IR MUD BREAKOUT Matrix: Soil Collect Date: 04/18/2017 11:30




Page 6



Microbac LaboratoriesCase Narrative

Login Number: L17050904Department: General ChromatographyAnalyst: Lacey Hendershot

Preparation 3546

Analysis SW-846 8015

HOLDING TIMES

Sample Preparation: Sample 05 was received and extracted 14 days out of hold. All other holding times were met.

Sample Analysis: All holding times were met.

PREPARATION

Sample preparation proceeded normally.

CALIBRATION

Initial Calibration: For all compounds that yielded a %RSD greater than 20%, linear or higher order equations were applied. All acceptance criteria were met.

Alternate Source Standards: All acceptance criteria were met.

Continuing Calibration and Tune: All acceptance criteria were met.

BATCH QA/QC

Method Blank: Analytes were detected above the applicable reporting limit for the following analytes: Diesel Range (C10-C28). Please see the applicable QC report for a detailed presentation of the failures. The result was marginally above the MDL, but less than 1/2 of the RL.

Laboratory Control Sample: All acceptance criteria were met.

Matrix Spikes: There were no MS/MSD results associated with this sample delivery group, due to insufficient volume of sample. The laboratory included an LCS and LCS duplicate in the preparation batch in lieu of the NELAC prescribed MS/MSD. Microbac recommends site specific MS/MSD samples to avoid possible data qualification.


Page 7



SAMPLES

Samples: All acceptance criteria were met.

Surrogates: Recoveries out of range were observed for the following analytes: o-Terphenyl, Octacosane. Please see the applicable QC report for a detailed presentation of the failures. Samples 01, 04, and 05 were not re-extracted for low surrogates; the recoveries were greater than 10%. Sample 02 had insufficient volume to re-extract.

Sample # Analyte Date Result Lower Upper Type

L17050904-01 o-Terphenyl 2017-05-16 17:43:27 26.2 43 136 Recovery



L17050904-02 Octacosane 2017-05-16 19:41:32 9.41 25 162 Recovery


Manual Integration Reason Codes

Reason #1: Data System Fails to Select Correct Peak In some cases the chromatography system selects and integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper peak. Other times the system may miss the peakcompletely.

Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak This phenomena is common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into multiple peaks or integrated as a main peak with one or more rider peaks resulting in low areacounts for the target compound.

Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by manual integration. Prime examples are benzo(k)fluoranthene andbenzo(b)fluoranthene which are often unresolved and integrated improperly when both are present at low concentrations in standards or samples.

Reason #4: System Establishes Incorrect Baseline There are numerous situations in chromatography where the system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected via manual procedures.

Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Laboratory Director or the QA/QC Supervisor will be required.

I certify that this data package is in compliance with the terms and conditions agreed to by the client and Microbac Laboratories Inc., both technically and for completeness, except for the conditions noted above. Release of the data contained in this hard copy data package has been authorized by the Laboratory Manager or designated person, as verified by the following signature.

Narrative ID: 125510Approved By: Eric Lawson


Page 8



of 3 Generated at May 18, 2017 12:03

Page 9



Microbac Laboratories Inc.Ohio Valley Division Analyst List

May 18, 2017

001 - BIO-CHEM TESTING WVDEP 220 002 - REIC Consultants, Inc. WVDEP 060003 - Sturm Environmental 004 - MICROBAC PITTSBURGH005 - ES LABORATORIES 006 - ALCOSAN LABORATORIES007 - ALS LABORATORIES 008 - BENCHMARK LABORATORIES010 - MICROBAC CHICAGOLAND AC - AMBER R. CARMICHAELADC - ANTHONY D. CANTER ADG - APRIL D. GREENEALS - ADRIANE L. STEED AWE - ANDREW W. ESSIGAZH - AFTER HOURS BJO - BRIAN J. OGDENBLG - BRENDA L. GREENWALT BNB - Brandi N. BentleyBRG - BRENDA R. GREGORY CAS - Craig A. SmithCEB - CHAD E. BARNES CLC - CHRYS L. CRAWFORDCLS - CARA L. STRICKLER CPD - CHAD P. DAVISCSH - CHRIS S. HILL CV - Carl VolkmanDAK - DEAN A. KETELSEN DCM - DAVID C. MERCKLEDEV - DAVID E. VANDENBERG DIH - DEANNA I. HESSONDLB - DAVID L. BUMGARNER DLP - DOROTHY L. PAYNEDSM - DAVID S. MOSSOR DTG - DOMINIC T. GEHRETECL - ERIC C. LAWSON EPT - ETHAN P. TIDDERP - ERIN R. PORTER FJB - FRANCES J. BOLDENHRF - HEATHER R. FAIRCHILD JDH - JUSTIN D. HESSONJDS - JARED D. SMITH JKP - JACQUELINE K. PARSONSJLD - JESSICA L. DELONG JST - JOSHUA S. TAYLORJTP - JOSHUA T. PEMBERTON JWR - JOHN W. RICHARDSJWS - JACK W. SHEAVES JYH - JI Y. HUKAK - KATHY A. KIRBY KDD - Katelyn D. DaleyKEB - KATIE E. BARNES KHR - KIM H. RHODESKKB - KERRI K. BUCK KRA - KATHY R. ALBERTSONKRP - KATHY R. PARSONS LJH - Lacey J. HendershotLLS - LARRY L. STEPHENS LSB - LESLIE S. BUCINALSJ - LAURA S. JONES MAP - MARLA A. PORTERMBK - MORGAN B. KNOWLTON MES - MARY E. SCHILLINGMMB - MAREN M. BEERY MRT - MICHELLE R. TAYLOROJE - OMOYEMWEN J. ENGLISH PDM - PIERCE D. MORRISPIT - MICROBAC WARRENDALE REK - BOB E. KYERRLB - BOB BUCHANAN RNP - RICK N. PETTYSAV - SARAH A. VANDENBERG SCA - SUEELLEN C. ADAMSSCB - SARAH C. BOGOLIN SCJ - SUE ELLEN C. JOHNSONSDC - SHALYN D. CONLEY TB - TODD BOYLETMB - TIFFANY M. BAILEY TMM - TAMMY M. MORRISVC - VICKI COLLIER WTD - WADE T. DELONGXXX - UNAVAILABLE OR SUBCONTRACT ZTB - ZACH T. BARNES

Page 10



List of Valid QualifiersMay 18, 2017

Qualkey: STD_ND=U

Microbac Laboratories Inc.

Qualifier Description

*+<>AB

B1B3C

CGDLE

EDLEMPCF, SFL

FP1H1IJ

J,BJ,H1J,PJ,SLL1L2MN

NAND, SND,LNFNFLNINRNSPQ

QNSRARES

SMISPTIC

TNTCU

U,H1UJWX

X, SYZ

Surrogate or spike compound out of rangeCorrelation coefficient for the MSA is less than 0.995Result is less than the associated numerical value.Result is greater than the associated numerical value.See the report narrativeAnalyte present in method blankTarget analyte detected in method blank at or above the method reporting limitTarget analyte detected in calibration blank at or above the method reporting limitConfirmed by GC/MSConfluent growthSurrogate or spike compound was diluted outEstimated concentration due to sample matrix interferenceElevated sample reporting limits, presence of non-target analytesEstimated Maximum Possible ConcentrationEstimated result below quantitation limit; method of standard additions(MSA)Free LiquidDid not ignite.Sample analysis performed past holding time.Semiquantitative result (out of instrument calibration range)The analyte was positively identified, but the quantitation was below the RLAnalyte detected in both the method blank and sample above the MDL.The analyte was positively identified, but the quantitation was below the RL. Sample analysis performed past holding timeEstimate; columns don't agree to within 40%Estimated concentration; analyzed by method of standard addition (MSA)Sample reporting limits elevated due to matrix interferenceThe associated blank spike (LCS) recovery was above the laboratory acceptance limits.The associated blank spike (LCS) recovery was below the laboratory acceptance limits.Matrix effect; the concentration is an estimate due to matrix effect.Tentatively identified compound(TIC)Not applicableNot detected; analyzed by method of standard addition (MSA)Not detected; sample reporting limit (RL) elevated due to interferenceNot found by library searchNo free liquidNon-ignitableAnalyte is not required to be analyzedNot spikedConcentrations >40% difference between the two GC columnsOne or more quality control criteria failed. See narrative.Quantity of sample not sufficient to perform analysisReanalysis confirms reported resultsReanalysis confirms sample matrix interferenceAnalyzed by method of standard addition (MSA)Sample matrix interference on surrogateReported results are for spike compounds onlyLibrary Search CompoundToo numerous to countNot detected at or above adjusted sample detection limitNot detected; sample analysis performed past holding time.Undetected; the MDL and RL are estimated due to quality control discrepancies.Post-digestion spike for furnace AA out of control limitsExceeds regulatory limitExceeds regulatory limit; method of standard additions (MSA)This analyte is not on the laboratory's current scope of accreditation.Cannot be resolved from isomer - see below

Page 11



Organic QA/QC

Page 12



05/17/2017 10:07Report generated5297722PDF File ID:


METHOD BLANK SUMMARY

Report Name: BLANK_SUMMARY

14G67536

05/16/17 11:21

05/16/17 14:27

WG614544

WG614301-01

HP14

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8015CMethod:

LJHAnalyst:

L17050904Login Number:

LCS

LCS2

17-0751 IR MUD 54 RETURN

17-0751 IR MUD SILO

17-0751 IR MUD WE RECLAIM PIT

17-0751 IR MUD BREAKOUT

17-0751 IR MUD GRID C1-D1

WG614301-02

WG614301-03

L17050904-03

L17050904-01

L17050904-04

L17050904-05

L17050904-02

14G67537

14G67538

14G67540

14G67541

14G67542

14G67543

14G67544

05/16/17 15:06

05/16/17 15:45

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41

This Method Blank Applies To The Following Samples:

Client ID Lab Sample ID Lab File ID Time Analyzed TAG

01

01

01

01

01

01

01

Page 13




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5297723

17-MAY-2017 10:07

o-Terphenyl

Octacosane

69.6

62.6

Surrogates % Recovery Surrogate Limits

43

25

-

-

136

162

Qualifier

PASS

PASS

Analytes Concentration Dilution Qualifier

Diesel Range (C10-C28) 12500 10000 J3900

ND Analyte Not detected at or above reporting limit

* |Analyte concentration| > RL

14G67536

WG614544

Instrument ID:HP14

File ID:

Prep Date:05/16/17 11:21

Run Date:05/16/17 14:27

Analyst:LJH

Workgroup (AAB#): ug/kgUnits:

8015CMethod:

SoilMatrix:

L17050904Login Number: WG614301-01Sample ID:

09-MAY-17Cal ID: HP14-OT900917Contract #:

3546Prep Method:

MDL RL

MDL

RL

Method Detection Limit

Reporting/Practical Quantitation Limit

Page 14



LCS_LCS2 - Modified 03/06/2008

05/17/2017 10:07Report generated:5297724PDF File ID:

LABORATORY CONTROL SAMPLE (LCS)


Diesel Range (C10-C28)

LCS LCS2

4.13137000 143000

Analytes %RPD

250000 250000

Found FoundKnown Known

54.9 57.2

% REC % REC

26

RPDLmt

%RecLimits

35 120-

Q

Sample ID:

Sample ID:

WG614301-02

WG614301-03

LCS

LCS2

14G67537

14G67538

File ID:

File ID:

o-Terphenyl

Octacosane

LCS LCS2

69.7 73.4

68.2 74.9

Surogates% Recovery % Recovery

Surrogate Limits

43

25

136

162

-

-

Qualifier

PASS

PASS

Run Date:

Run Date:

05/16/2017 15:06

05/16/2017 15:45

WG614544

Instrument ID:HP14

Analyst:LJH


8015CMethod:SoilMatrix:

L17050904Login Number: 3546Prep Method:

* EXCEEDS %REC LIMIT

# EXCEEDS RPD LIMIT

STDQC Key: STD81195Lot #:

Page 15



SURROGATES - Modified 03/06/2008


SURROGATE STANDARDS


L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

01

01

01

01

01

01

01

01

1 2Sample Number Dilution Tag

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

-

-

o-Terphenyl

Octacosane

8015Method:

HP14Instrument Id:


SoilMatrix:WG614544Workgroup (AAB#):

Underline = Result out of surrogate limits

26.2 36.2

12.6 9.41

53.4 52.3

30.9 30.4

39.5 34.6

69.6 62.6

69.7 68.2

73.4 74.9

43

25

-

-

136

162

Surrogates Surrogate Limits

DL = surrogate diluted out

HP14CAL ID: -09-MAY-17

ND = surrogate not detected

Page 16



CCV - Modified 03/05/2008


CONTINUING CALIBRATION VERIFICATION (CCV)


Diesel Range (C10-C28) 1000000 1000000 51200 0.384

Analyte Expected Found Q

* Exceeds

%D

Criteria %D

RF

14G67535

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:09:32

Analyst:LJH

Workgroup (AAB#):

8015CMethod:


09-MAY-17HP14 -Cal ID:

UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 17







Diesel Range (C10-C28) 1000000 1040000 53300 4.46


* Exceeds

%D

Criteria %D

RF

14G67546

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:20:59

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 18



Response Factor Report HP14

Method : C:\MSDCHEM\1\METHODS\DROQUANT.M (Chemstation Integrator) Title : SOP:GCS02 8015B/C/D DRO ICAL 05/09/17 Last Update : Tue May 09 14:01:47 2017 WG613451 Calibration Files 10k =14G67512.D 5000 =14G67513.D 2500 =14G67514.D 1000 =14G67515.D 500 =14G67516.D 100 =14G67517.D

Compound 10k 5000 2500 1000 500 100 Avg %RSD -------------------------------------------------------------------------- 1) h Diesel Range (C1 4.697 4.957 4.498 4.973 5.404 6.089 5.103 E4 11.19 2) s O-Terphenyl 5.179 5.829 5.070 5.462 5.901 5.320 5.460 E4 6.25 3) s Octacosane 3.011 4.001 3.424 3.684 3.921 3.732 3.629 E4 10.02 -------------------------------------------------------------------------- (#) = Out of Range

DROQUANT.M Tue May 09 14:42:19 2017

Page 19



ALT - Modified 09/06/2007

05/17/2017 10:07Version 1.5Report generated

5297726PDF File ID:

ALTERNATE SOURCE CALIBRATION REPORT


Diesel Range (C10-C28) 1000000 1040000 53300ug/L 4.40

Analyte Expected Found

* Exceeds

%D

Limit %D

RF

14G67518

WG613451

Instrument ID:HP14

File ID:

Run Date:05/09/2017

Run Time:14:09

Analyst:LJH

ICal Workgroup:

8015CMethod:



QUCL20

Units

QC Key:STD

Page 20



Instrument Run Log

Run Log ID:82035

Page: 1 Approved: 09-MAY-17


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HP14

LJH

8015 DRO

050917

NA

GCS02 19

Column 1 ID: Column 2 ID:RTX-CLP2 NA

Method: SOP: Rev:8015D OVAP GCS02 1

1

2

3

4

5

6

7

8

9

10

14G67509

14G67510

14G67511

14G67512

14G67513

14G67514

14G67515

14G67516

14G67517

14G67518

RINSE

PRO RT STD

T1005 RT STD

WG613451-01 10,000PPM DRO STD

WG613451-02 5,000PPM DRO STD

WG613451-03 2,500PPM DRO STD

WG613451-04 1,000PPM DRO STD

WG613451-05 500PPM DRO STD

WG613451-06 100PPM DRO STD

WG613451-07 1,000PPM ALT DRO STD

1

1

1

1

1

1

1

1

1

1

STD81451

STD81010

STD81110

STD81110

STD81110

STD81110

STD81110

STD81110

STD81381

05/09/17 08:17

05/09/17 08:56

05/09/17 09:35

05/09/17 10:14

05/09/17 10:53

05/09/17 11:33

05/09/17 12:12

05/09/17 12:51

05/09/17 13:30

05/09/17 14:09

Seq. File ID Sample Information Dil Reference Date/TimeMat

1

1

1

1

1

1

1

1

1

1

NAInternal STD: Surrogate STD: NA

Comments:

WG613451 (ICAL)Workgroups:

Comments

Seq. Rerun Dil. AnalytesReason

Maintenance Log ID:

STD81110 04/10/17Calibration STD

Syringe Filter Lot#:

STD81110CCV STD: LCS STD: MS/MSD STD:

Eluent ID#:

Page 21



Instrument Run Log

Run Log ID:82172



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HP14

LJH

8015 DRO

051617

NA

GCS02 19

Column 1 ID: Column 2 ID:RTX-CLP2 NA

Method: SOP: Rev:8015D OVAP GCS02 1

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

14G67533

14G67534

14G67535

14G67536

14G67537

14G67538

14G67539

14G67540

14G67541

14G67542

14G67543

14G67544

14G67545

14G67546

14G67547

14G67548

14G67549

RINSE

PRO RT STD

WG614359-01 1,000PPM DRO STD

WG614301-01 BLANK

WG614301-02 LCS

WG614301-03 LCS2

L17050774-01 DRO

L17050904-03 DRO

L17050904-01 DRO

L17050904-04 DRO

L17050904-05 DRO

L17050904-02 DRO

L17050767-01 DRO

WG614359-02 1,000PPM DRO STD

RINSE

RINSE

RINSE

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD81451

STD81110

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

STD81110

05/16/17 08:14

05/16/17 08:53

05/16/17 09:32

05/16/17 14:27

05/16/17 15:06

05/16/17 15:45

05/16/17 16:24

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41

05/16/17 20:20

05/16/17 20:59

05/16/17 21:38

05/16/17 22:17

05/16/17 22:56


1

1

1

7

7

7

7

7

7

7

7

7

7

1

1

1

1

NAInternal STD: Surrogate STD: NA

Comments:

WG614544Workgroups:

4

9

10

11

12

O-Terphenyl

O-Terphenyl

O-Terphenyl

O-Terphenyl, Octacosane

Surrogate standard failure




WG614301-01 BLANK had a hit in the Diesel Range (C10-C28), but was less than 1/2 the RL.

L17050904-01 DRO

L17050904-04 DRO

L17050904-05 DRO

L17050904-02 DRO needs re-extracted due to both surrogate recoveries being low. QNS-jar broken, not enough sample.

Comments


Maintenance Log ID:

STD81110 04/10/17Calibration STD



Eluent ID#:

Page 22



Sample Extract Log

EXTRACT - Modified 10/22/2008 PDF ID:Report generated: 05/17/2017 09:40


5297589

Reviewer:Analyst:

L17050767-01

L17050774-01

L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

SAMPLE #

22.51 g

20.26 g

21.25 g

17.32 g

17.55 g

19.09 g

19.39 g

20 g

20 g

20 g

Init Amnt

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

Final Vol Color

Transparent

Transparent

Transparent

Transparent

Transparent

Transparent

Transparent

Transparent

Transparent

Transparent

Type

SAMP

SAMP

SAMP

SAMP

SAMP

SAMP

SAMP

BLANK

LCS

LCS2

WG614301

Method:3546

Analyst:JLD

Workgroup:

Run Date:05/16/2017 11:21

EXMW01-15 Revision SOP:

Spike Witness: JDH

Methylene Chloride Lot #:

sand Lot #:

Diatomaceous Earth Lot #:

Na2SO4, Anhydrous, Granular Lot #:

Prod

DRO

DRO

DRO

DRO

DRO

DRO

DRO

DRO

DRO

DRO

1

2

3

4

5

6

7

8

9

10

Spike Amnt

1 mL

1 mL

STD81081

COA19678

COA19640

COA19577

COA19660

Surr Solution:

Surr Amnt

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

1 mL

L17050904-05 RAN OUT OF HOLD

JLDSpike Analyst:

Spike Sol

STD81195

STD81195

Reference pH

Due to insufficient sample volume, this preparation batch failed to include the method prescribed MS and MSD.

Page 23



Internal Chain of Custody Report

Login:

Account:

Project:

Samples:

Due Date:

L17050904

2755

2755.044

5

19-MAY-2017

A1 - Sample Archive (COLD)A2 - Sample Archive (AMBIENT)F1 - Volatiles Freezer in LoginV1 - Volatiles Refrigerator in LoginW1 - Walkin Cooler in Login


L17050904-01

L17050904-02

L17050904-03

L17050904-04

909520

909521

909522

909523

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

4

1

2

3

4

1

2

3

4

1

2

3

4

LOGIN

PREP

PREP

STORE

LOGIN

PREP

PREP

STORE

LOGIN

PREP

PREP

STORE

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

COOLER

W1

EXT

DIG

COOLER

W1

EXT

DIG

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

W1

EXT

DIG

A2

W1

EXT

DIG

A2

W1

EXT

DIG

A2

16-MAY-2017 11:04

16-MAY-2017 11:07

16-MAY-2017 15:10

16-MAY-2017 16:46

16-MAY-2017 11:04

16-MAY-2017 11:07

16-MAY-2017 15:10

16-MAY-2017 16:46

16-MAY-2017 11:04

16-MAY-2017 11:07

16-MAY-2017 15:10

16-MAY-2017 16:46

16-MAY-2017 11:04

16-MAY-2017 11:07

16-MAY-2017 15:10

16-MAY-2017 16:46

BRG

JDH

AC

BRG

BRG

JDH

AC

BRG

BRG

JDH

AC

BRG

BRG

JDH

AC

BRG

CLS

JLD

AC

CLS

JLD

AC

CLS

JLD

AC

CLS

JLD

AC

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

From

From

From

From

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

DRO

DRO

DRO

DRO

pH

pH

pH

pH

Page 26




Login:

Account:

Project:

Samples:

Due Date:

L17050904

2755

2755.044

5

19-MAY-2017



L17050904-05 909524

Samplenum Container ID

1Bottle:

1

2

3

4

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

16-MAY-2017 11:04

16-MAY-2017 11:07

16-MAY-2017 15:10

16-MAY-2017 16:46

BRG

JDH

AC

BRG

CLS

JLD

AC

Seq. Purpose From To Date/Time Accept Relinquish

Products

DRO

pH

Page 27



Laboratory Report Number: L17051231 (Preliminary)








Page 1








There were no discrepancies.Discrepancy Resolution



0016980 I 2.0 X


# Question Result

1 Were shipping coolers sealed? NA

2 Were custody seals intact? NA




6 Were sample containers intact and match COC? Yes

7 Were sample labels intact and match COC? Yes


9 Were samples received within EPA hold times? Yes





www.microbac.com

Page 2








17-0751 OSG DISPOSAL PIT L17051231-01 05/19/2017 13:24 05/19/2017 20:10


17-0751 IR MUD ORIGINAL L17051231-03 05/19/2017 15:00 05/19/2017 20:10

17-0751 IR MUD ORIGINAL L17051231-04 05/19/2017 15:00 05/19/2017 20:10

17-0751 IR MUD SILO L17051231-05 05/19/2017 14:45 05/19/2017 20:10

17-0751 IR MUD SILO L17051231-06 05/19/2017 14:45 05/19/2017 20:10

17-0751 IR MUD GRID A3 NEW L17051231-07 05/19/2017 15:30 05/19/2017 20:10

17-0751 IR MUD GRID A3 NEW L17051231-08 05/19/2017 15:30 05/19/2017 20:10

17-0751 WEST BOREHOLE RETURN M

L17051231-09 05/19/2017 16:18 05/19/2017 20:10


L17051231-10 05/19/2017 16:18 05/19/2017 20:10

17-0751 WEST RECLAIMER PIT L17051231-11 05/19/2017 16:30 05/19/2017 20:10


17-0751 EAST RECLAIMER NEW MUD

L17051231-13 05/19/2017 17:12 05/19/2017 20:10


L17051231-14 05/19/2017 17:12 05/19/2017 20:10


www.microbac.com

Page 3




Login Number: L17051231Department: SemivolatilesAnalyst: Mary Schilling

METHOD

Preparation 3510C/1311/3546

Analysis SW-846 8270C

HOLDING TIMES

Sample Preparation: All holding times were met.


PREPARATION


CALIBRATION




BATCH QA/QC

Method Blank: Analytes were detected above the applicable reporting limit for the following analytes: Benzoic Acid. Please see the applicable QC report for a detailed presentation of the failures.


WG615091-01 Benzoic Acid 2017-05-23 11:25:00 343 250.0 RL


Matrix Spikes: All acceptance criteria were met.


Page 4



SAMPLES


Internal Standards: All acceptance criteria were met.

Surrogates: All acceptance criteria were met.






Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be required.


Narrative ID: 125853Approved By: Mary Schilling


Page 5




Login Number: L17051231Department: MetalsAnalyst: Kerri Buck

METHOD

Preparation: SW-846 3015

Analysis: SW-846 6010

HOLDING TIMES



PREPARATION


CALIBRATION

Initial Calibration: All acceptance criteria were met.


Interference Check Standards: All acceptance criteria were met.

Continuing Calibration Verification: All acceptance criteria were met.

Continuing Calibration Blank: All acceptance criteria were met.

BATCH QA/QC

Method Blank: All acceptance criteria were met.


Serial Dilution/Post Digestion Spikes: WG615308 - All acceptance criteria were met.


Page 6




SAMPLES


Narrative ID: 125811Approved By: Kim Rhodes


Page 7




Login Number: L17051231Department: Metals - AAAnalyst: Laura Jones

METHOD



HOLDING TIMES



PREPARATION


CALIBRATION






BATCH QA/QC





Page 8




SAMPLES




Page 9







Certificate of AnalysisSample #: L17051231-02 PrePrep Method: N/A Instrument: HPMS9

Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:14

Matrix: Soil Analytical Method: 8260B Cal Date: 05/23/2017 14:46

Workgroup #: WG615352 Analyst: ADC Run Date: 05/23/2017 20:47

Collect Date: 05/19/2017 13:24 Dilution: 1 File ID: 9M980452



Acetone 67-64-1 U 19.4 9.68

Benzene 71-43-2 5.32 J 9.68 0.968

Bromobenzene 108-86-1 U 9.68 0.968

Bromochloromethane 74-97-5 U 9.68 1.94

Bromodichloromethane 75-27-4 U 9.68 0.968

Bromoform 75-25-2 U 9.68 0.968

Bromomethane 74-83-9 U 19.4 1.94

2-Butanone 78-93-3 U 19.4 4.84

n-Butylbenzene 104-51-8 20.0 9.68 0.968

sec-Butylbenzene 135-98-8 6.38 J 9.68 0.968

tert-Butylbenzene 98-06-6 3.66 J 9.68 0.968

Carbon disulfide 75-15-0 4.53 J 9.68 0.968

Carbon tetrachloride 56-23-5 U 9.68 0.968

Chlorobenzene 108-90-7 U 9.68 0.968

Chlorodibromomethane 124-48-1 U 9.68 0.968

Chloroethane 75-00-3 U 19.4 1.94

2-Chloroethyl vinyl ether 110-75-8 U 19.4 3.87

Chloroform 67-66-3 U 9.68 0.968

Chloromethane 74-87-3 U 19.4 3.87

2-Chlorotoluene 95-49-8 U 9.68 0.968

4-Chlorotoluene 106-43-4 U 9.68 0.968

1,2-Dibromo-3-chloropropane 96-12-8 U 9.68 3.87

1,2-Dibromoethane 106-93-4 U 9.68 0.968

Dibromomethane 74-95-3 U 9.68 0.968

1,2-Dichlorobenzene 95-50-1 U 9.68 0.968



Dichlorodifluoromethane 75-71-8 U 19.4 1.94

1,1-Dichloroethane 75-34-3 U 9.68 1.94


1,1-Dichloroethene 75-35-4 U 9.68 0.968

cis-1,2-Dichloroethene 156-59-2 U 9.68 0.968

trans-1,2-Dichloroethene 156-60-5 U 9.68 0.968


Page 10







Certificate of AnalysisAnalyte CAS # Result Qual RL MDL

1,2-Dichloropropane 78-87-5 U 9.68 0.968



cis-1,3-Dichloropropene 10061-01-5 U 9.68 0.968

trans-1,3-Dichloropropene 10061-02-6 U 9.68 0.968

1,1-Dichloropropene 563-58-6 U 9.68 0.968

Ethylbenzene 100-41-4 5.91 J 9.68 0.968

2-Hexanone 591-78-6 45.8 19.4 4.84

Hexachlorobutadiene 87-68-3 U 9.68 0.968

Isopropylbenzene 98-82-8 3.50 J 9.68 0.968

p-Isopropyltoluene 99-87-6 9.17 J 9.68 0.968

4-Methyl-2-pentanone 108-10-1 U 19.4 4.84

Methylene chloride 75-09-2 U 9.68 1.94

Naphthalene 91-20-3 11.0 J 19.4 0.968

n-Propylbenzene 103-65-1 6.84 J 9.68 0.968

Styrene 100-42-5 U 9.68 0.968

1,1,1,2-Tetrachloroethane 630-20-6 U 9.68 0.968


Tetrachloroethene 127-18-4 3.54 J 9.68 0.968

Toluene 108-88-3 16.3 9.68 0.968

1,2,3-Trichlorobenzene 87-61-6 15.7 9.68 0.968

1,2,4-Trichlorobenzene 120-82-1 U 9.68 0.968

1,1,1-Trichloroethane 71-55-6 U 9.68 0.968


Trichloroethene 79-01-6 U 9.68 0.968

Trichlorofluoromethane 75-69-4 U 19.4 1.94

1,2,3-Trichloropropane 96-18-4 U 9.68 1.94

1,2,4-Trimethylbenzene 95-63-6 28.7 9.68 0.968


Vinyl acetate 108-05-4 U 19.4 4.84

Vinyl chloride 75-01-4 U 19.4 1.94

o-Xylene 95-47-6 29.2 9.68 0.968

m-,p-Xylene 179601-23-1 23.0 9.68 0.968


Dibromofluoromethane 100 80 120

1,2-Dichloroethane-d4 99.1 80 120

Toluene-d8 115 81 117

4-Bromofluorobenzene 150 74 121 *



Page 11







Certificate of AnalysisJ The analyte was positively identified, but the quantitation was below the RL

U Not detected at or above adjusted sample detection limit

Sample #: L17051231-02 PrePrep Method: N/A Instrument: HPMS12

Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 3546 Prep Date: 05/22/2017 11:48


Workgroup #: WG615227 Analyst: SCB Run Date: 05/23/2017 15:49




1,2,4-Trichlorobenzene 120-82-1 U 351 175

1,2-Dichlorobenzene 95-50-1 U 351 175



2,4,5-Trichlorophenol 95-95-4 U 351 175


2,4-Dichlorophenol 120-83-2 U 351 175

2,4-Dimethylphenol 105-67-9 U 351 175

2,4-Dinitrophenol 51-28-5 U 1750 875

2,4-Dinitrotoluene 121-14-2 U 351 175


2-Chloronaphthalene 91-58-7 U 351 175

2-Chlorophenol 95-57-8 U 351 175

2-Methylnaphthalene 91-57-6 497 351 175

2-Methylphenol 95-48-7 U 351 175

2-Nitroaniline 88-74-4 U 1750 875

2-Nitrophenol 88-75-5 U 351 175

3,3'-Dichlorobenzidine 91-94-1 U 701 351

3-,4-Methylphenol 65794-96-9 U 351 175

3-Nitroaniline 99-09-2 U 1750 875

4,6-Dinitro-2-methylphenol 534-52-1 U 1750 875

4-Bromophenyl-phenylether 101-55-3 U 351 175

4-Chloro-3-methylphenol 59-50-7 U 351 175

4-Chloroaniline 106-47-8 U 351 175

4-Chlorophenyl-phenyl ether 7005-72-3 U 351 175

4-Nitroaniline 100-01-6 U 1750 875

4-Nitrophenol 100-02-7 U 1750 875

Acenaphthene 83-32-9 U 351 175

Acenaphthylene 208-96-8 U 351 175

Anthracene 120-12-7 U 351 175


Page 12








Benzo(a)anthracene 56-55-3 U 351 175

Benzo(a)pyrene 50-32-8 U 351 175

Benzo(b)fluoranthene 205-99-2 U 351 175

Benzo(g,h,i)Perylene 191-24-2 U 351 175

Benzo(k)fluoranthene 207-08-9 U 351 175

Benzoic acid 65-85-0 U 10600 701

Benzyl alcohol 100-51-6 U 351 175

Bis(2-Chloroethoxy)Methane 111-91-1 U 351 175

Bis(2-Chloroethyl)ether 111-44-4 U 351 175

bis(2-Chloroisopropyl)ether 39638-32-9 U 351 175

bis(2-Ethylhexyl)phthalate 117-81-7 U 351 175

Butylbenzylphthalate 85-68-7 U 351 175

Chrysene 218-01-9 U 351 175

Di-N-Butylphthalate 84-74-2 U 351 175

Di-n-octylphthalate 117-84-0 U 351 175

Dibenzo(a,h)Anthracene 53-70-3 U 351 175

Dibenzofuran 132-64-9 U 351 175

Diethylphthalate 84-66-2 U 351 175

Dimethylphthalate 131-11-3 U 351 175

Fluoranthene 206-44-0 U 351 175

Fluorene 86-73-7 U 351 175

Hexachlorobenzene 118-74-1 U 351 175

Hexachlorobutadiene 87-68-3 U 351 175

Hexachlorocyclopentadiene 77-47-4 U 1590 797

Hexachloroethane 67-72-1 U 351 175

Indeno(1,2,3-cd)pyrene 193-39-5 U 351 175

Isophorone 78-59-1 U 351 175

Diphenylamine/n-Nitrosodiphenylamine 86-30-6 755 351 175

N-Nitrosodipropylamine 621-64-7 U 351 175

Naphthalene 91-20-3 372 351 175

Nitrobenzene 98-95-3 U 351 175

Pentachlorophenol 87-86-5 U 1750 875

Phenanthrene 85-01-8 193 J 351 175

Phenol 108-95-2 U 351 175

Pyrene 129-00-0 U 351 175


2,4,6-Tribromophenol 101 19 122

2-Fluorobiphenyl 77.8 30 115

2-Fluorophenol 67.6 25 121


Page 13







Certificate of AnalysisNitrobenzene-d5 86.7 23 120

p-Terphenyl-d14 92.1 18 137

Phenol-d5 69.3 24 113




Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:15






Acetone 67-64-1 23.9 22.1 11.1

Benzene 71-43-2 3.16 J 11.1 1.11

Bromobenzene 108-86-1 U 11.1 1.11



Bromoform 75-25-2 U 11.1 1.11


2-Butanone 78-93-3 U 22.1 5.53

n-Butylbenzene 104-51-8 1.44 J 11.1 1.11

sec-Butylbenzene 135-98-8 U 11.1 1.11

tert-Butylbenzene 98-06-6 U 11.1 1.11







Chloroform 67-66-3 U 11.1 1.11


2-Chlorotoluene 95-49-8 U 11.1 1.11

4-Chlorotoluene 106-43-4 U 11.1 1.11


1,2-Dibromoethane 106-93-4 U 11.1 1.11






Page 14




















Ethylbenzene 100-41-4 2.42 J 11.1 1.11

2-Hexanone 591-78-6 U 22.1 5.53


Isopropylbenzene 98-82-8 U 11.1 1.11

p-Isopropyltoluene 99-87-6 U 11.1 1.11



Naphthalene 91-20-3 4.18 J 22.1 1.11

n-Propylbenzene 103-65-1 U 11.1 1.11

Styrene 100-42-5 U 11.1 1.11




Toluene 108-88-3 6.40 J 11.1 1.11

1,2,3-Trichlorobenzene 87-61-6 2.10 J 11.1 1.11







1,2,4-Trimethylbenzene 95-63-6 5.53 J 11.1 1.11


Vinyl acetate 108-05-4 U 22.1 5.53


o-Xylene 95-47-6 4.26 J 11.1 1.11

m-,p-Xylene 179601-23-1 7.99 J 11.1 1.11


Page 15







Certificate of AnalysisSurrogate Recovery Lower Limit Upper Limit Q


1,2-Dichloroethane-d4 100 80 120

Toluene-d8 113 81 117






Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 3546 Prep Date: 05/22/2017 11:48














2,4-Dinitrophenol 51-28-5 U 1720 861





2-Methylnaphthalene 91-57-6 U 345 172


2-Nitroaniline 88-74-4 U 1720 861

2-Nitrophenol 88-75-5 U 345 172


3-,4-Methylphenol 65794-96-9 U 345 172

3-Nitroaniline 99-09-2 U 1720 861






Page 16









4-Nitroaniline 100-01-6 U 1720 861

4-Nitrophenol 100-02-7 U 1720 861



Anthracene 120-12-7 U 345 172






Benzoic acid 65-85-0 U 10500 690







Chrysene 218-01-9 U 345 172








Fluorene 86-73-7 U 345 172






Isophorone 78-59-1 U 345 172

Diphenylamine/n-Nitrosodiphenylamine 86-30-6 U 345 172


Naphthalene 91-20-3 U 345 172



Phenanthrene 85-01-8 U 345 172


Page 17








Phenol 108-95-2 U 345 172

Pyrene 129-00-0 U 345 172


2,4,6-Tribromophenol 85.5 19 122



Nitrobenzene-d5 89.2 23 120


Phenol-d5 67.6 24 113



Client ID: 17-0751 IR MUD SILO Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:20






Acetone 67-64-1 88.2 20.5 10.2

Benzene 71-43-2 2.22 J 10.2 1.02

Bromobenzene 108-86-1 U 10.2 1.02



Bromoform 75-25-2 U 10.2 1.02


2-Butanone 78-93-3 19.9 J 20.5 5.12

n-Butylbenzene 104-51-8 14.5 10.2 1.02



Carbon disulfide 75-15-0 10.8 10.2 1.02






Chloroform 67-66-3 U 10.2 1.02



4-Chlorotoluene 106-43-4 U 10.2 1.02


Page 18









1,2-Dibromoethane 106-93-4 U 10.2 1.02

















Ethylbenzene 100-41-4 4.50 J 10.2 1.02

2-Hexanone 591-78-6 U 20.5 5.12






Naphthalene 91-20-3 10.8 J 20.5 1.02


Styrene 100-42-5 U 10.2 1.02




Toluene 108-88-3 9.84 J 10.2 1.02









Page 19










Vinyl acetate 108-05-4 U 20.5 5.12


o-Xylene 95-47-6 13.3 10.2 1.02

m-,p-Xylene 179601-23-1 15.5 10.2 1.02


Dibromofluoromethane 99.2 80 120


Toluene-d8 108 81 117

4-Bromofluorobenzene 118 74 121


















2,4-Dinitrophenol 51-28-5 U 1780 889







2-Nitroaniline 88-74-4 U 1780 889

2-Nitrophenol 88-75-5 U 356 178



Page 20








3-,4-Methylphenol 65794-96-9 U 356 178

3-Nitroaniline 99-09-2 U 1780 889






4-Nitroaniline 100-01-6 U 1780 889

4-Nitrophenol 100-02-7 U 1780 889



Anthracene 120-12-7 U 356 178






Benzoic acid 65-85-0 U 10800 712







Chrysene 218-01-9 U 356 178








Fluorene 86-73-7 U 356 178






Isophorone 78-59-1 U 356 178


Page 21










Naphthalene 91-20-3 466 356 178



Phenanthrene 85-01-8 263 J 356 178

Phenol 108-95-2 U 356 178

Pyrene 129-00-0 U 356 178







Phenol-d5 65.4 24 113




Client ID: 17-0751 IR MUD GRID A3 NEW

Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:22






Acetone 67-64-1 64.1 37.4 18.7

Benzene 71-43-2 U 18.7 1.87

Bromobenzene 108-86-1 U 18.7 1.87



Bromoform 75-25-2 U 18.7 1.87


2-Butanone 78-93-3 U 37.4 9.36

n-Butylbenzene 104-51-8 6.81 J 18.7 1.87






Page 22












Chloroform 67-66-3 U 18.7 1.87



4-Chlorotoluene 106-43-4 U 18.7 1.87


1,2-Dibromoethane 106-93-4 U 18.7 1.87

















Ethylbenzene 100-41-4 4.07 J 18.7 1.87

2-Hexanone 591-78-6 U 37.4 9.36






Naphthalene 91-20-3 5.16 J 37.4 1.87


Styrene 100-42-5 U 18.7 1.87





Page 23








Toluene 108-88-3 7.46 J 18.7 1.87










Vinyl acetate 108-05-4 U 37.4 9.36


o-Xylene 95-47-6 6.89 J 18.7 1.87

m-,p-Xylene 179601-23-1 8.61 J 18.7 1.87




Toluene-d8 110 81 117




















2,4-Dinitrophenol 51-28-5 U 3330 1660


Page 24












2-Methylnaphthalene 91-57-6 514 J 666 333


2-Nitroaniline 88-74-4 U 3330 1660

2-Nitrophenol 88-75-5 U 666 333


3-,4-Methylphenol 65794-96-9 U 666 333

3-Nitroaniline 99-09-2 U 3330 1660






4-Nitroaniline 100-01-6 U 3330 1660

4-Nitrophenol 100-02-7 U 3330 1660



Anthracene 120-12-7 U 666 333






Benzoic acid 65-85-0 U 20200 1330







Chrysene 218-01-9 U 666 333







Page 25










Fluorene 86-73-7 U 666 333






Isophorone 78-59-1 U 666 333







Phenol 108-95-2 U 666 333

Pyrene 129-00-0 U 666 333







Phenol-d5 62.2 24 113




Client ID: 17-0751 WEST BOREHOLE RETURN M







Acetone 67-64-1 U 23.2 11.6

Benzene 71-43-2 U 11.6 1.16

Bromobenzene 108-86-1 U 11.6 1.16



Page 26









Bromoform 75-25-2 U 11.6 1.16


2-Butanone 78-93-3 U 23.2 5.80

n-Butylbenzene 104-51-8 2.28 J 11.6 1.16









Chloroform 67-66-3 U 11.6 1.16



4-Chlorotoluene 106-43-4 U 11.6 1.16


1,2-Dibromoethane 106-93-4 U 11.6 1.16

















Ethylbenzene 100-41-4 1.46 J 11.6 1.16

2-Hexanone 591-78-6 U 23.2 5.80




Page 27











Naphthalene 91-20-3 2.93 J 23.2 1.16


Styrene 100-42-5 U 11.6 1.16




Toluene 108-88-3 2.31 J 11.6 1.16










Vinyl acetate 108-05-4 U 23.2 5.80


o-Xylene 95-47-6 2.08 J 11.6 1.16

m-,p-Xylene 179601-23-1 2.96 J 11.6 1.16




Toluene-d8 117 81 117













Page 28
















2,4-Dinitrophenol 51-28-5 U 1800 900







2-Nitroaniline 88-74-4 U 1800 900

2-Nitrophenol 88-75-5 U 360 180


3-,4-Methylphenol 65794-96-9 U 360 180

3-Nitroaniline 99-09-2 U 1800 900






4-Nitroaniline 100-01-6 U 1800 900

4-Nitrophenol 100-02-7 U 1800 900



Anthracene 120-12-7 U 360 180






Benzoic acid 65-85-0 U 10900 721





Page 29











Chrysene 218-01-9 U 360 180








Fluorene 86-73-7 U 360 180






Isophorone 78-59-1 U 360 180



Naphthalene 91-20-3 197 J 360 180




Phenol 108-95-2 U 360 180

Pyrene 129-00-0 U 360 180







Phenol-d5 43.6 24 113




Page 30








Client ID: 17-0751 WEST RECLAIMER PIT







Acetone 67-64-1 19.0 17.0 8.52

Benzene 71-43-2 U 8.52 0.852

Bromobenzene 108-86-1 U 8.52 0.852



Bromoform 75-25-2 U 8.52 0.852


2-Butanone 78-93-3 U 17.0 4.26

n-Butylbenzene 104-51-8 1.10 J 8.52 0.852









Chloroform 67-66-3 U 8.52 0.852


2-Chlorotoluene 95-49-8 U 8.52 0.852

4-Chlorotoluene 106-43-4 U 8.52 0.852


1,2-Dibromoethane 106-93-4 U 8.52 0.852











Page 31















Ethylbenzene 100-41-4 U 8.52 0.852

2-Hexanone 591-78-6 U 17.0 4.26






Naphthalene 91-20-3 1.10 J 17.0 0.852


Styrene 100-42-5 U 8.52 0.852




Toluene 108-88-3 1.43 J 8.52 0.852










Vinyl acetate 108-05-4 U 17.0 4.26


o-Xylene 95-47-6 1.14 J 8.52 0.852

m-,p-Xylene 179601-23-1 1.34 J 8.52 0.852




Toluene-d8 114 81 117



Page 32







Certificate of Analysis* Surrogate or spike compound out of range



















2,4-Dinitrophenol 51-28-5 U 1510 752







2-Nitroaniline 88-74-4 U 1510 752

2-Nitrophenol 88-75-5 U 301 151


3-,4-Methylphenol 65794-96-9 U 301 151

3-Nitroaniline 99-09-2 U 1510 752






4-Nitroaniline 100-01-6 U 1510 752

4-Nitrophenol 100-02-7 U 1510 752



Page 33









Anthracene 120-12-7 U 301 151






Benzoic acid 65-85-0 U 9130 603







Chrysene 218-01-9 U 301 151




Dibenzofuran 132-64-9 358 301 151



Fluoranthene 206-44-0 175 J 301 151

Fluorene 86-73-7 U 301 151






Isophorone 78-59-1 U 301 151



Naphthalene 91-20-3 1310 301 151



Phenanthrene 85-01-8 789 301 151

Phenol 108-95-2 U 301 151

Pyrene 129-00-0 194 J 301 151




Page 34







Certificate of Analysis2-Fluorobiphenyl 82.1 30 115




Phenol-d5 59.8 24 113




Client ID: 17-0751 EAST RECLAIMER NEW MUD







Acetone 67-64-1 U 502 251

Benzene 71-43-2 U 251 25.1

Bromobenzene 108-86-1 U 251 25.1

Bromochloromethane 74-97-5 U 251 50.2

Bromodichloromethane 75-27-4 U 251 25.1

Bromoform 75-25-2 U 251 25.1

Bromomethane 74-83-9 U 502 50.2

2-Butanone 78-93-3 U 502 125

n-Butylbenzene 104-51-8 U 251 25.1

sec-Butylbenzene 135-98-8 U 251 25.1

tert-Butylbenzene 98-06-6 U 251 25.1

Carbon disulfide 75-15-0 U 251 25.1

Carbon tetrachloride 56-23-5 U 251 25.1

Chlorobenzene 108-90-7 U 251 25.1

Chlorodibromomethane 124-48-1 U 251 25.1

Chloroethane 75-00-3 U 502 50.2

2-Chloroethyl vinyl ether 110-75-8 U 502 100

Chloroform 67-66-3 U 251 25.1

Chloromethane 74-87-3 U 502 100

2-Chlorotoluene 95-49-8 U 251 25.1


1,2-Dibromo-3-chloropropane 96-12-8 U 251 100

1,2-Dibromoethane 106-93-4 U 251 25.1

Dibromomethane 74-95-3 U 251 25.1


Page 35








1,2-Dichlorobenzene 95-50-1 U 251 25.1



Dichlorodifluoromethane 75-71-8 U 502 50.2

1,1-Dichloroethane 75-34-3 U 251 50.2


1,1-Dichloroethene 75-35-4 U 251 25.1

cis-1,2-Dichloroethene 156-59-2 U 251 25.1

trans-1,2-Dichloroethene 156-60-5 U 251 25.1

1,2-Dichloropropane 78-87-5 U 251 25.1



cis-1,3-Dichloropropene 10061-01-5 U 251 25.1

trans-1,3-Dichloropropene 10061-02-6 U 251 25.1

1,1-Dichloropropene 563-58-6 U 251 25.1

Ethylbenzene 100-41-4 U 251 25.1

2-Hexanone 591-78-6 U 502 125

Hexachlorobutadiene 87-68-3 U 251 25.1

Isopropylbenzene 98-82-8 U 251 25.1

p-Isopropyltoluene 99-87-6 U 251 25.1

4-Methyl-2-pentanone 108-10-1 U 502 125

Methylene chloride 75-09-2 U 251 50.2

Naphthalene 91-20-3 U 502 25.1

n-Propylbenzene 103-65-1 U 251 25.1

Styrene 100-42-5 U 251 25.1

1,1,1,2-Tetrachloroethane 630-20-6 U 251 25.1


Tetrachloroethene 127-18-4 62.4 J 251 25.1

Toluene 108-88-3 U 251 25.1

1,2,3-Trichlorobenzene 87-61-6 U 251 25.1


1,1,1-Trichloroethane 71-55-6 U 251 25.1


Trichloroethene 79-01-6 U 251 25.1

Trichlorofluoromethane 75-69-4 U 502 50.2

1,2,3-Trichloropropane 96-18-4 U 251 50.2

1,2,4-Trimethylbenzene 95-63-6 U 251 25.1


Vinyl acetate 108-05-4 U 502 125


Page 36








Vinyl chloride 75-01-4 U 502 50.2

o-Xylene 95-47-6 U 251 25.1

m-,p-Xylene 179601-23-1 U 251 25.1




Toluene-d8 106 81 117




















2,4-Dinitrophenol 51-28-5 U 48700 24300




2-Chlorophenol 95-57-8 U 9740 4870


2-Methylphenol 95-48-7 U 9740 4870

2-Nitroaniline 88-74-4 U 48700 24300

2-Nitrophenol 88-75-5 U 9740 4870


3-,4-Methylphenol 65794-96-9 U 9740 4870

3-Nitroaniline 99-09-2 U 48700 24300


Page 37











4-Chloroaniline 106-47-8 U 9740 4870


4-Nitroaniline 100-01-6 U 48700 24300

4-Nitrophenol 100-02-7 U 48700 24300



Anthracene 120-12-7 U 9740 4870


Benzo(a)pyrene 50-32-8 U 9740 4870




Benzoic acid 65-85-0 U 295000 19500







Chrysene 218-01-9 U 9740 4870




Dibenzofuran 132-64-9 U 9740 4870



Fluoranthene 206-44-0 U 9740 4870

Fluorene 86-73-7 U 9740 4870






Isophorone 78-59-1 U 9740 4870




Page 38








Naphthalene 91-20-3 U 9740 4870




Phenol 108-95-2 U 9740 4870

Pyrene 129-00-0 U 9740 4870







Phenol-d5 49.0 24 113



Page 39







Certificate of Analysis

Sample #: L17051231-01 PrePrep Method: Instrument: HPMS8

Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 5030B/5030C/5035A Prep Date: N/A

Matrix: TCLP Leach Analytical Method: 8260B Cal Date: 04/17/2017 18:24

Workgroup #: WG615405 Analyst: TMB Run Date: 05/24/2017 14:22


Sample Tag: DL01 Units: ug/L

Analyte Result Qual RL MDL EPA HW# Reg. Limit

Benzene U 50.0 1.25 D018 500

Carbon tetrachloride U 50.0 2.50 D019 500

Chlorobenzene U 50.0 1.25 D021 100000

Chloroform U 50.0 1.25 D022 6000

1,2-Dichloroethane U 50.0 2.50 D028 500

1,1-Dichloroethene U 50.0 5.00 D029 700

Methyl Ethyl Ketone U 100 25.0 D035 200000

Tetrachloroethene U 50.0 2.50 D039 700

Trichloroethene U 50.0 2.50 D040 500

Vinyl chloride U 100 2.50 D043 200




Toluene-d8 107 88 110




Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 3510C Prep Date: 05/23/2017 14:05

Matrix: TCLP Leach Analytical Method: 8270C Cal Date: 04/10/2017 20:59

Workgroup #: WG615400 Analyst: MES Run Date: 05/24/2017 12:31


Sample Tag: 01 Units: ug/L


o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000

1,4-Dichlorobenzene U 50.0 25.0 D027 7500

2,4-Dinitrotoluene U 50.0 25.0 D030 130

Hexachlorobenzene U 50.0 25.0 D032 130

Hexachlorobutadiene U 50.0 25.0 D033 500

Hexachloroethane U 50.0 25.0 D034 3000


Page 40









Nitrobenzene U 50.0 25.0 D036 2000

Pentachlorophenol U 250 125 D037 100000

Pyridine U 250 125 D038 5000

2,4,5-Trichlorophenol U 50.0 25.0 D041 400000




Phenol-d5 29.6 10 94






Sample #: L17051231-01 PrePrep Method: N/A Instrument: ICP-THERMO4

Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 3015A Prep Date: 05/23/2017 09:43


Workgroup #: WG615308 Analyst: KKB Run Date: 05/23/2017 16:45

Collect Date: 05/19/2017 13:24 Dilution: 1 File ID: T4.052317.164558

Sample Tag: 01 Units: mg/L


Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.869 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1

Chromium, TCLP U 0.200 0.100 D007 5

Lead, TCLP U 1.00 0.500 D008 5

Selenium, TCLP U 0.800 0.400 D010 1

Silver, TCLP U 0.100 0.0500 D011 5


Sample #: L17051231-01 PrePrep Method: Instrument: CVAA1


Matrix: TCLP Leach Analytical Method: 7470A Cal Date: 05/23/2017 14:40

Workgroup #: WG615315 Analyst: LSJ Run Date: 05/23/2017 15:46

Collect Date: 05/19/2017 13:24 Dilution: 1 File ID: M7.052317.154615



Mercury U 0.00200 0.00100 D009 0.2


Page 41










Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 5030B/5030C/5035A Prep Date: N/A


Workgroup #: WG615282 Analyst: TMB/JDS Run Date: 05/23/2017 18:54




Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 110 88 110




Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000






Page 42












Pyridine U 250 125 D038 5000





Phenol-d5 22.6 10 94







Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 3015A Prep Date: 05/23/2017 09:43






Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.647 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5









Page 43









Mercury U 0.00200 0.00100 D009 0.2



Client ID: 17-0751 IR MUD SILO Prep Method: 5030B/5030C/5035A Prep Date: N/A






Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 113 88 110 *





Client ID: 17-0751 IR MUD SILO Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000



Page 44















Pyridine U 250 125 D038 5000





Phenol-d5 30.3 10 94




p-Terphenyl-d14 107 33 141



Client ID: 17-0751 IR MUD SILO Prep Method: 3015A Prep Date: 05/23/2017 09:43






Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.712 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5



Page 45















Mercury U 0.00200 0.00100 D009 0.2




Prep Method: 5030B/5030C/5035A Prep Date: N/A






Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 111 88 110 *





Page 46










Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 29.5 10 94








Prep Method: 3015A Prep Date: 05/23/2017 09:43






Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.391 0.100 0.0500 D005 100


Page 47









Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2










Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Page 48










Toluene-d8 111 88 110 *












o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 22.1 10 94







Page 49
















Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.512 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2










Benzene U 50.0 1.25 D018 500




Page 50









Chloroform U 50.0 1.25 D022 6000










Toluene-d8 108 88 110











o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 28.7 10 94




Page 51




















Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.441 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2



Page 52
















Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 108 88 110











o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000






Page 53












Pyridine U 250 125 D038 5000





Phenol-d5 24.9 10 94














Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.131 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5



Page 54
















Mercury U 0.00200 0.00100 D009 0.2



Page 55







Sample #: L17051231-02 Client ID: 17-0751 OSG DISPOSAL PIT Matrix: Soil Collect Date: 05/19/2017 13:24



Sample #: L17051231-04 Client ID: 17-0751 IR MUD ORIGINAL Matrix: Soil Collect Date: 05/19/2017 15:00






Sample #: L17051231-08 Client ID: 17-0751 IR MUD GRID A3 NEW Matrix: Soil Collect Date: 05/19/2017 15:30



Sample #: L17051231-10 Client ID: 17-0751 WEST BOREHOLE RETURN M




Sample #: L17051231-12 Client ID: 17-0751 WEST RECLAIMER PIT Matrix: Soil Collect Date: 05/19/2017 16:30



Sample #: L17051231-14 Client ID: 17-0751 EAST RECLAIMER NEW MUD





Page 56




May 25, 2017


Page 57




Qualkey: STD_ND=U



*+<>AB

B1B3C

CGDLE

EDLEMPCF, SFL

FP1H1IJ



QNSRARES

SMISPTIC

TNTCU

U,H1UJWX

X, SYZ


Page 58




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-01

L17051231-02

L17051231-02

L17051231-03

L17051231-04

911918

911919

911920

911921

911922

Samplenum

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

Container ID

1

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

1

2

3

1

2

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:26

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

BRG

BNB

CLS

CLS

JDH

AC

BRG

BNB

CLS

Seq.

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

Purpose

From

From

From

From

From

To

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

Products

TC-EX

8260

8270

TC-EX

8260

pH

pH

pH

pH

pH

Page 61




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-04

L17051231-05

L17051231-06

L17051231-06

911923

911924

911925

911926

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

4

1

2

3

1

2

1

2

3

4

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:26

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:55

22-MAY-2017 14:59

22-MAY-2017 16:26

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

JDH

AC

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

From

From

From

From

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

8270

TC-EX

8260

8270

pH

pH

pH

pH

Page 62




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-07

L17051231-08

L17051231-08

L17051231-09

L17051231-10

911927

911928

911929

911930

911931

Samplenum

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

Container ID

1

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

1

2

3

1

2

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

BRG

BNB

CLS

CLS

JDH

AC

BRG

BNB

CLS

Seq.

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

Purpose

From

From

From

From

From

To

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

Products

TC-EX

8260

8270

TC-EX

8260

pH

pH

pH

pH

pH

Page 63




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-10

L17051231-11

L17051231-12

L17051231-12

911932

911933

911934

911935

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

4

1

2

3

1

2

1

2

3

4

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

JDH

AC

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

From

From

From

From

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

8270

TC-EX

8260

8270

pH

pH

pH

pH

Page 64




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-13

L17051231-14

L17051231-14

911936

911937

911938

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

1

1

1

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

From

From

From

To

To

To

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Products

Products

Products

TC-EX

8260

8270

pH

pH

pH

Page 65



Laboratory Report Number: L17051231








Page 1








There were no discrepancies.Discrepancy Resolution



0016980 I 2.0 X


# Question Result

1 Were shipping coolers sealed? NA

2 Were custody seals intact? NA




6 Were sample containers intact and match COC? Yes

7 Were sample labels intact and match COC? Yes


9 Were samples received within EPA hold times? Yes





www.microbac.com

Page 2










17-0751 IR MUD ORIGINAL L17051231-03 05/19/2017 15:00 05/19/2017 20:10

17-0751 IR MUD ORIGINAL L17051231-04 05/19/2017 15:00 05/19/2017 20:10

17-0751 IR MUD SILO L17051231-05 05/19/2017 14:45 05/19/2017 20:10

17-0751 IR MUD SILO L17051231-06 05/19/2017 14:45 05/19/2017 20:10

17-0751 IR MUD GRID A3 NEW L17051231-07 05/19/2017 15:30 05/19/2017 20:10

17-0751 IR MUD GRID A3 NEW L17051231-08 05/19/2017 15:30 05/19/2017 20:10


L17051231-09 05/19/2017 16:18 05/19/2017 20:10


L17051231-10 05/19/2017 16:18 05/19/2017 20:10




L17051231-13 05/19/2017 17:12 05/19/2017 20:10


L17051231-14 05/19/2017 17:12 05/19/2017 20:10


www.microbac.com

Page 3








Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:14






Acetone 67-64-1 U 19.4 9.68

Benzene 71-43-2 5.32 J 9.68 0.968

Bromobenzene 108-86-1 U 9.68 0.968



Bromoform 75-25-2 U 9.68 0.968


2-Butanone 78-93-3 U 19.4 4.84

n-Butylbenzene 104-51-8 20.0 9.68 0.968


tert-Butylbenzene 98-06-6 3.66 J 9.68 0.968







Chloroform 67-66-3 U 9.68 0.968


2-Chlorotoluene 95-49-8 U 9.68 0.968

4-Chlorotoluene 106-43-4 U 9.68 0.968


1,2-Dibromoethane 106-93-4 U 9.68 0.968












Page 4














Ethylbenzene 100-41-4 5.91 J 9.68 0.968

2-Hexanone 591-78-6 45.8 19.4 4.84






Naphthalene 91-20-3 11.0 J 19.4 0.968


Styrene 100-42-5 U 9.68 0.968




Toluene 108-88-3 16.3 9.68 0.968

1,2,3-Trichlorobenzene 87-61-6 15.7 9.68 0.968









Vinyl acetate 108-05-4 U 19.4 4.84


o-Xylene 95-47-6 29.2 9.68 0.968

m-,p-Xylene 179601-23-1 23.0 9.68 0.968




Toluene-d8 115 81 117




Page 5







Certificate of AnalysisJ The analyte was positively identified, but the quantitation was below the RL



Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 3546 Prep Date: 05/22/2017 11:48














2,4-Dinitrophenol 51-28-5 U 1750 875







2-Nitroaniline 88-74-4 U 1750 875

2-Nitrophenol 88-75-5 U 351 175


3-,4-Methylphenol 65794-96-9 U 351 175

3-Nitroaniline 99-09-2 U 1750 875






4-Nitroaniline 100-01-6 U 1750 875

4-Nitrophenol 100-02-7 U 1750 875



Anthracene 120-12-7 U 351 175


Page 6













Benzoic acid 65-85-0 U 10600 701







Chrysene 218-01-9 U 351 175








Fluorene 86-73-7 U 351 175






Isophorone 78-59-1 U 351 175

Diphenylamine/n-Nitrosodiphenylamine 86-30-6 755 351 175


Naphthalene 91-20-3 372 351 175



Phenanthrene 85-01-8 193 J 351 175

Phenol 108-95-2 U 351 175

Pyrene 129-00-0 U 351 175






Page 7







Certificate of AnalysisNitrobenzene-d5 86.7 23 120


Phenol-d5 69.3 24 113




Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:15






Acetone 67-64-1 23.9 22.1 11.1

Benzene 71-43-2 3.16 J 11.1 1.11

Bromobenzene 108-86-1 U 11.1 1.11



Bromoform 75-25-2 U 11.1 1.11


2-Butanone 78-93-3 U 22.1 5.53

n-Butylbenzene 104-51-8 1.44 J 11.1 1.11









Chloroform 67-66-3 U 11.1 1.11



4-Chlorotoluene 106-43-4 U 11.1 1.11


1,2-Dibromoethane 106-93-4 U 11.1 1.11






Page 8




















Ethylbenzene 100-41-4 2.42 J 11.1 1.11

2-Hexanone 591-78-6 U 22.1 5.53






Naphthalene 91-20-3 4.18 J 22.1 1.11


Styrene 100-42-5 U 11.1 1.11




Toluene 108-88-3 6.40 J 11.1 1.11










Vinyl acetate 108-05-4 U 22.1 5.53


o-Xylene 95-47-6 4.26 J 11.1 1.11

m-,p-Xylene 179601-23-1 7.99 J 11.1 1.11


Page 9







Certificate of AnalysisSurrogate Recovery Lower Limit Upper Limit Q



Toluene-d8 113 81 117






Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 3546 Prep Date: 05/22/2017 11:48














2,4-Dinitrophenol 51-28-5 U 1720 861







2-Nitroaniline 88-74-4 U 1720 861

2-Nitrophenol 88-75-5 U 345 172


3-,4-Methylphenol 65794-96-9 U 345 172

3-Nitroaniline 99-09-2 U 1720 861






Page 10









4-Nitroaniline 100-01-6 U 1720 861

4-Nitrophenol 100-02-7 U 1720 861



Anthracene 120-12-7 U 345 172






Benzoic acid 65-85-0 U 10500 690







Chrysene 218-01-9 U 345 172








Fluorene 86-73-7 U 345 172






Isophorone 78-59-1 U 345 172








Page 11








Phenol 108-95-2 U 345 172

Pyrene 129-00-0 U 345 172







Phenol-d5 67.6 24 113



Client ID: 17-0751 IR MUD SILO Prep Method: 5030B/5030C/5035A Prep Date: 05/23/2017 09:20






Acetone 67-64-1 88.2 20.5 10.2

Benzene 71-43-2 2.22 J 10.2 1.02

Bromobenzene 108-86-1 U 10.2 1.02



Bromoform 75-25-2 U 10.2 1.02


2-Butanone 78-93-3 19.9 J 20.5 5.12

n-Butylbenzene 104-51-8 14.5 10.2 1.02



Carbon disulfide 75-15-0 10.8 10.2 1.02






Chloroform 67-66-3 U 10.2 1.02



4-Chlorotoluene 106-43-4 U 10.2 1.02


Page 12









1,2-Dibromoethane 106-93-4 U 10.2 1.02

















Ethylbenzene 100-41-4 4.50 J 10.2 1.02

2-Hexanone 591-78-6 U 20.5 5.12






Naphthalene 91-20-3 10.8 J 20.5 1.02


Styrene 100-42-5 U 10.2 1.02




Toluene 108-88-3 9.84 J 10.2 1.02









Page 13










Vinyl acetate 108-05-4 U 20.5 5.12


o-Xylene 95-47-6 13.3 10.2 1.02

m-,p-Xylene 179601-23-1 15.5 10.2 1.02




Toluene-d8 108 81 117



















2,4-Dinitrophenol 51-28-5 U 1780 889







2-Nitroaniline 88-74-4 U 1780 889

2-Nitrophenol 88-75-5 U 356 178



Page 14








3-,4-Methylphenol 65794-96-9 U 356 178

3-Nitroaniline 99-09-2 U 1780 889






4-Nitroaniline 100-01-6 U 1780 889

4-Nitrophenol 100-02-7 U 1780 889



Anthracene 120-12-7 U 356 178






Benzoic acid 65-85-0 U 10800 712







Chrysene 218-01-9 U 356 178








Fluorene 86-73-7 U 356 178






Isophorone 78-59-1 U 356 178


Page 15










Naphthalene 91-20-3 466 356 178



Phenanthrene 85-01-8 263 J 356 178

Phenol 108-95-2 U 356 178

Pyrene 129-00-0 U 356 178







Phenol-d5 65.4 24 113











Acetone 67-64-1 64.1 37.4 18.7

Benzene 71-43-2 U 18.7 1.87

Bromobenzene 108-86-1 U 18.7 1.87



Bromoform 75-25-2 U 18.7 1.87


2-Butanone 78-93-3 U 37.4 9.36

n-Butylbenzene 104-51-8 6.81 J 18.7 1.87






Page 16












Chloroform 67-66-3 U 18.7 1.87



4-Chlorotoluene 106-43-4 U 18.7 1.87


1,2-Dibromoethane 106-93-4 U 18.7 1.87

















Ethylbenzene 100-41-4 4.07 J 18.7 1.87

2-Hexanone 591-78-6 U 37.4 9.36






Naphthalene 91-20-3 5.16 J 37.4 1.87


Styrene 100-42-5 U 18.7 1.87





Page 17








Toluene 108-88-3 7.46 J 18.7 1.87










Vinyl acetate 108-05-4 U 37.4 9.36


o-Xylene 95-47-6 6.89 J 18.7 1.87

m-,p-Xylene 179601-23-1 8.61 J 18.7 1.87




Toluene-d8 110 81 117




















2,4-Dinitrophenol 51-28-5 U 3330 1660


Page 18














2-Nitroaniline 88-74-4 U 3330 1660

2-Nitrophenol 88-75-5 U 666 333


3-,4-Methylphenol 65794-96-9 U 666 333

3-Nitroaniline 99-09-2 U 3330 1660






4-Nitroaniline 100-01-6 U 3330 1660

4-Nitrophenol 100-02-7 U 3330 1660



Anthracene 120-12-7 U 666 333






Benzoic acid 65-85-0 U 20200 1330







Chrysene 218-01-9 U 666 333







Page 19










Fluorene 86-73-7 U 666 333






Isophorone 78-59-1 U 666 333







Phenol 108-95-2 U 666 333

Pyrene 129-00-0 U 666 333







Phenol-d5 62.2 24 113











Acetone 67-64-1 U 23.2 11.6

Benzene 71-43-2 U 11.6 1.16

Bromobenzene 108-86-1 U 11.6 1.16



Page 20









Bromoform 75-25-2 U 11.6 1.16


2-Butanone 78-93-3 U 23.2 5.80

n-Butylbenzene 104-51-8 2.28 E 11.6 1.16









Chloroform 67-66-3 U 11.6 1.16



4-Chlorotoluene 106-43-4 U 11.6 1.16


1,2-Dibromoethane 106-93-4 U 11.6 1.16

















Ethylbenzene 100-41-4 1.46 J 11.6 1.16

2-Hexanone 591-78-6 U 23.2 5.80




Page 21











Naphthalene 91-20-3 2.93 E 23.2 1.16


Styrene 100-42-5 U 11.6 1.16




Toluene 108-88-3 2.31 J 11.6 1.16










Vinyl acetate 108-05-4 U 23.2 5.80


o-Xylene 95-47-6 2.08 J 11.6 1.16

m-,p-Xylene 179601-23-1 2.96 J 11.6 1.16




Toluene-d8 117 81 117



E Estimated concentration due to sample matrix interference




Page 22























2,4-Dinitrophenol 51-28-5 U 1800 900







2-Nitroaniline 88-74-4 U 1800 900

2-Nitrophenol 88-75-5 U 360 180


3-,4-Methylphenol 65794-96-9 U 360 180

3-Nitroaniline 99-09-2 U 1800 900






4-Nitroaniline 100-01-6 U 1800 900

4-Nitrophenol 100-02-7 U 1800 900



Anthracene 120-12-7 U 360 180




Page 23











Benzoic acid 65-85-0 U 10900 721







Chrysene 218-01-9 U 360 180








Fluorene 86-73-7 U 360 180






Isophorone 78-59-1 U 360 180



Naphthalene 91-20-3 197 J 360 180




Phenol 108-95-2 U 360 180

Pyrene 129-00-0 U 360 180








Page 24







Certificate of AnalysisPhenol-d5 43.6 24 113











Acetone 67-64-1 19.0 17.0 8.52

Benzene 71-43-2 U 8.52 0.852

Bromobenzene 108-86-1 U 8.52 0.852



Bromoform 75-25-2 U 8.52 0.852


2-Butanone 78-93-3 U 17.0 4.26

n-Butylbenzene 104-51-8 1.10 J 8.52 0.852









Chloroform 67-66-3 U 8.52 0.852


2-Chlorotoluene 95-49-8 U 8.52 0.852

4-Chlorotoluene 106-43-4 U 8.52 0.852


1,2-Dibromoethane 106-93-4 U 8.52 0.852







Page 25



















Ethylbenzene 100-41-4 U 8.52 0.852

2-Hexanone 591-78-6 U 17.0 4.26






Naphthalene 91-20-3 1.10 J 17.0 0.852


Styrene 100-42-5 U 8.52 0.852




Toluene 108-88-3 1.43 J 8.52 0.852










Vinyl acetate 108-05-4 U 17.0 4.26


o-Xylene 95-47-6 1.14 J 8.52 0.852

m-,p-Xylene 179601-23-1 1.34 J 8.52 0.852



Page 26







Certificate of AnalysisDibromofluoromethane 98.6 80 120


Toluene-d8 114 81 117





















2,4-Dinitrophenol 51-28-5 U 1510 752







2-Nitroaniline 88-74-4 U 1510 752

2-Nitrophenol 88-75-5 U 301 151


3-,4-Methylphenol 65794-96-9 U 301 151

3-Nitroaniline 99-09-2 U 1510 752






Page 27









4-Nitroaniline 100-01-6 U 1510 752

4-Nitrophenol 100-02-7 U 1510 752



Anthracene 120-12-7 U 301 151






Benzoic acid 65-85-0 U 9130 603







Chrysene 218-01-9 U 301 151




Dibenzofuran 132-64-9 358 301 151



Fluoranthene 206-44-0 175 J 301 151

Fluorene 86-73-7 U 301 151






Isophorone 78-59-1 U 301 151



Naphthalene 91-20-3 1310 301 151



Phenanthrene 85-01-8 789 301 151


Page 28








Phenol 108-95-2 U 301 151

Pyrene 129-00-0 194 J 301 151







Phenol-d5 59.8 24 113











Acetone 67-64-1 U 502 251

Benzene 71-43-2 U 251 25.1

Bromobenzene 108-86-1 U 251 25.1

Bromochloromethane 74-97-5 U 251 50.2

Bromodichloromethane 75-27-4 U 251 25.1

Bromoform 75-25-2 U 251 25.1

Bromomethane 74-83-9 U 502 50.2

2-Butanone 78-93-3 U 502 125

n-Butylbenzene 104-51-8 U 251 25.1

sec-Butylbenzene 135-98-8 U 251 25.1

tert-Butylbenzene 98-06-6 U 251 25.1

Carbon disulfide 75-15-0 U 251 25.1

Carbon tetrachloride 56-23-5 U 251 25.1

Chlorobenzene 108-90-7 U 251 25.1

Chlorodibromomethane 124-48-1 U 251 25.1

Chloroethane 75-00-3 U 502 50.2

2-Chloroethyl vinyl ether 110-75-8 U 502 100

Chloroform 67-66-3 U 251 25.1

Chloromethane 74-87-3 U 502 100


Page 29










1,2-Dibromo-3-chloropropane 96-12-8 U 251 100

1,2-Dibromoethane 106-93-4 U 251 25.1

Dibromomethane 74-95-3 U 251 25.1




Dichlorodifluoromethane 75-71-8 U 502 50.2



1,1-Dichloroethene 75-35-4 U 251 25.1

cis-1,2-Dichloroethene 156-59-2 U 251 25.1

trans-1,2-Dichloroethene 156-60-5 U 251 25.1




cis-1,3-Dichloropropene 10061-01-5 U 251 25.1

trans-1,3-Dichloropropene 10061-02-6 U 251 25.1

1,1-Dichloropropene 563-58-6 U 251 25.1

Ethylbenzene 100-41-4 U 251 25.1

2-Hexanone 591-78-6 U 502 125

Hexachlorobutadiene 87-68-3 U 251 25.1

Isopropylbenzene 98-82-8 U 251 25.1

p-Isopropyltoluene 99-87-6 U 251 25.1

4-Methyl-2-pentanone 108-10-1 U 502 125

Methylene chloride 75-09-2 U 251 50.2

Naphthalene 91-20-3 U 502 25.1

n-Propylbenzene 103-65-1 U 251 25.1

Styrene 100-42-5 U 251 25.1



Tetrachloroethene 127-18-4 62.4 J 251 25.1

Toluene 108-88-3 U 251 25.1





Trichloroethene 79-01-6 U 251 25.1


Page 30








Trichlorofluoromethane 75-69-4 U 502 50.2

1,2,3-Trichloropropane 96-18-4 U 251 50.2



Vinyl acetate 108-05-4 U 502 125

Vinyl chloride 75-01-4 U 502 50.2

o-Xylene 95-47-6 U 251 25.1

m-,p-Xylene 179601-23-1 U 251 25.1




Toluene-d8 106 81 117




















2,4-Dinitrophenol 51-28-5 U 48700 24300




2-Chlorophenol 95-57-8 U 9740 4870


2-Methylphenol 95-48-7 U 9740 4870


Page 31








2-Nitroaniline 88-74-4 U 48700 24300

2-Nitrophenol 88-75-5 U 9740 4870


3-,4-Methylphenol 65794-96-9 U 9740 4870

3-Nitroaniline 99-09-2 U 48700 24300




4-Chloroaniline 106-47-8 U 9740 4870


4-Nitroaniline 100-01-6 U 48700 24300

4-Nitrophenol 100-02-7 U 48700 24300



Anthracene 120-12-7 U 9740 4870


Benzo(a)pyrene 50-32-8 U 9740 4870




Benzoic acid 65-85-0 U 295000 19500







Chrysene 218-01-9 U 9740 4870




Dibenzofuran 132-64-9 U 9740 4870



Fluoranthene 206-44-0 U 9740 4870

Fluorene 86-73-7 U 9740 4870





Page 32










Isophorone 78-59-1 U 9740 4870



Naphthalene 91-20-3 U 9740 4870




Phenol 108-95-2 U 9740 4870

Pyrene 129-00-0 U 9740 4870







Phenol-d5 49.0 24 113



Page 33









Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 5030B/5030C/5035A Prep Date: N/A


Workgroup #: WG615405 Analyst: TMB Run Date: 05/24/2017 14:22




Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 107 88 110




Client ID: 17-0751 OSG DISPOSAL PIT Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000







Page 34











Pyridine U 250 125 D038 5000





Phenol-d5 29.6 10 94













Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.869 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5









Mercury U 0.00200 0.00100 D009 0.2


Page 35










Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 5030B/5030C/5035A Prep Date: N/A






Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 110 88 110




Client ID: 17-0751 IR MUD ORIGINAL Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000






Page 36












Pyridine U 250 125 D038 5000





Phenol-d5 22.6 10 94













Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.647 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5









Page 37









Mercury U 0.00200 0.00100 D009 0.2



Client ID: 17-0751 IR MUD SILO Prep Method: 5030B/5030C/5035A Prep Date: N/A






Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 113 88 110 *





Client ID: 17-0751 IR MUD SILO Prep Method: 3510C Prep Date: 05/23/2017 14:05






o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000



Page 38















Pyridine U 250 125 D038 5000





Phenol-d5 30.3 10 94













Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.712 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5



Page 39















Mercury U 0.00200 0.00100 D009 0.2










Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 111 88 110 *





Page 40
















o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 29.5 10 94














Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.391 0.100 0.0500 D005 100


Page 41









Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2










Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Page 42










Toluene-d8 111 88 110 *












o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 22.1 10 94







Page 43
















Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.512 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2










Benzene U 50.0 1.25 D018 500




Page 44









Chloroform U 50.0 1.25 D022 6000










Toluene-d8 108 88 110











o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000








Pyridine U 250 125 D038 5000





Phenol-d5 28.7 10 94




Page 45




















Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.441 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5










Mercury U 0.00200 0.00100 D009 0.2



Page 46
















Benzene U 50.0 1.25 D018 500



Chloroform U 50.0 1.25 D022 6000










Toluene-d8 108 88 110











o-Cresol U 50.0 25.0 D023 200000

m-,p-Cresol U 50.0 25.0 D025 200000






Page 47












Pyridine U 250 125 D038 5000





Phenol-d5 24.9 10 94














Arsenic, TCLP U 1.00 0.500 D004 5

Barium, TCLP 0.131 0.100 0.0500 D005 100

Cadmium, TCLP U 0.100 0.0500 D006 1


Lead, TCLP U 1.00 0.500 D008 5


Silver, TCLP U 0.100 0.0500 D011 5



Page 48
















Mercury U 0.00200 0.00100 D009 0.2



Page 49







Sample #: L17051231-02 Client ID: 17-0751 OSG DISPOSAL PIT Matrix: Soil Collect Date: 05/19/2017 13:24



Sample #: L17051231-04 Client ID: 17-0751 IR MUD ORIGINAL Matrix: Soil Collect Date: 05/19/2017 15:00






Sample #: L17051231-08 Client ID: 17-0751 IR MUD GRID A3 NEW Matrix: Soil Collect Date: 05/19/2017 15:30



Sample #: L17051231-10 Client ID: 17-0751 WEST BOREHOLE RETURN M




Sample #: L17051231-12 Client ID: 17-0751 WEST RECLAIMER PIT Matrix: Soil Collect Date: 05/19/2017 16:30



Sample #: L17051231-14 Client ID: 17-0751 EAST RECLAIMER NEW MUD





Page 50




Login Number: L17051231Department: VolatilesAnalyst: Anthony Canter

METHOD

Preparation SW-846 5030B/5030C/5035A

Analysis SW-846 8260B

HOLDING TIMES



PREPARATION


CALIBRATION


Alternate Source Standards: Chloromethane, Bromomethane, 4-Chlorotoluene, Dichlorodifluoromethane, n-Propylbenzene, Vinyl Acetate exceeded the upper limit, and Carbon Disulfide was below the lower limit in ICV WG615237-11 analyzed 05/23/2017 on HPMS9. Outliers were not detected above reporting limits in associated samples. All other acceptance criteria were met. Please see the applicable QC report for a detailed presentation of the failures.

Continuing Calibration and Tune: Chloromethane (non-target system performance check compound) exceeded the upper limit in CCV WG615404-02 analyzed 05/24/2017 on HPMS8. SPCC criteria were met. All other acceptance criteria were met. Please see the applicable QC report for a detailed presentation of the failures.

BATCH QA/QC


Laboratory Control Sample: Bromomethane and Dichlorodifluoromethane exceeded the upper limit in LCS WG615352-02 analyzed 05/23/2017 on HPMS9. All other acceptance criteria were met. Please see the applicable QC report for a detailed presentation of the failures.


Page 51




WG615352-02 Bromomethane 2017-05-23 17:16:00 145 37 143 Recovery

WG615352-02 Dichlorodifluoromethane 2017-05-23 17:16:00 158 25 130 Recovery

Matrix Spikes: The MS/MSD results were not associated with this sample delivery group (SDG), due to insufficient volume of sample. The laboratory included an LCS and LCS duplicate in the preparation batch in lieu of the NELAC prescribed MS/MSD. Microbac Laboratories recommends site specific MS/MSD samples to avoid possible data qualifications.

SAMPLES

Internal Standards: Sample 10 yielded low recovery for 1,4-Dichlorobenzene-d4. Sample matrix interference was obvious due to hydrocarbon. Other samples with similar amounts of hydrocarbon also yielded recovery lower than expected, but within acceptance limits. All other acceptance criteria were met.

Surrogates: Recoveries out of range were observed for the following surrogates: 4-Bromofluorobenzene, Toluene-d8. Samples 02, 04, 05, 07, 09, 10, 12 had one surrogate outlier per sample. No reanalysis required. Please see the applicable QC report for a detailed presentation of the failures.


L17051231-04 4-Bromofluorobenzene 2017-05-23 17:46:00 127 74 121 Recovery


L17051231-05 Toluene-d8 2017-05-23 19:23:00 113 88 110 Recovery





Other: Samples 01, 03, 05, 07, 09, 11, 13 were run at a dilution due to TCLP matrix.


Reason #1: Data System Fails to Select Correct Peak. In some cases the chromatography system selects and integrates the 'wrong peak'. In this case the analyst must correct the selection and force the system to integrate the proper peak. Other times the system may miss the peak completely.

Reason #2: Data System Splits the Peak Incorrectly or Integrates a False Peak as a Rider Peak. This phenomena is common at low concentrations where the signal:noise ratio is low. A single compound (peak) is incorrectly split into multiple peaks or integrated as a main peak with one or more rider peaks resulting in low areacounts for the target compound.

Reason #3: Improperly Integrated Isomers and/or coeluting compounds. This system often fails to distinguish coeluting compounds and or isomers. The integration areas and concentrations are wrong, and they must be corrected by manual integration. Prime examples are benzo(k)fluoranthene and benzo(b)fluoranthene which are often unresolved and integrated improperly when both are present at low concentrations in standards or samples.

Reason #4: System Establishes Incorrect Baseline. There are numerous situations in chromatography where the system establishes the baseline incorrectly. Some baseline errors will be obvious to the analyst and should be corrected via manual procedures.


Page 52



Reason #5: Miscellaneous. Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be required.


Narrative ID: 125950Approved By: Franci Bolden


Page 53




Login Number: L17051231Department: SemivolatilesAnalyst: Mary Schilling

METHOD

Preparation 3510C/1311/3546

Analysis SW-846 8270C

HOLDING TIMES



PREPARATION


CALIBRATION




BATCH QA/QC

Method Blank: In the blank analyzed 5/23/17 on HPMS12, WG615091-01, benzoic acid was above the MDL, but below the RL. The samples were non-detect for benzoic acid. Please see the applicable QC report for a detailed presentation of the failures.


Matrix Spikes: The client did not specify an MS/MSD for this sample delivery group. The laboratory selected sample 02 for MS/MSD analysis and recoveries out of range were observed for benzoic acid and hexachlorocyclopentadiene. Please see the applicable QC report for a detailed presentation of the failures.


Page 54



SAMPLES


Internal Standards: All acceptance criteria were met.

Surrogates: All acceptance criteria were met.






Reason #5: Miscellaneous Other situations involving integration errors may require in-depth review and technical judgment. These cases should be brought to the attention of the laboratory management. If the form of manual integration is not clearly covered by these four cases, then review and approval by the Managing Director or the QAO will be required.


Narrative ID: 125853Approved By: Eric Lawson


Page 55




Login Number: L17051231Department: MetalsAnalyst: Kerri Buck

METHOD



HOLDING TIMES



PREPARATION


CALIBRATION






BATCH QA/QC





Page 56




SAMPLES




Page 57




Login Number: L17051231Department: Metals - AAAnalyst: Laura Jones

METHOD



HOLDING TIMES



PREPARATION


CALIBRATION






BATCH QA/QC





Page 58




SAMPLES




Page 59




May 30, 2017


Page 60




Qualkey: STD_ND=U



*+<>AB

B1B3C

CGDLE

EDLEMPCF, SFL

FP1H1IJ



QNSRARES

SMISPTIC

TNTCU

U,H1UJWX

X, SYZ


Page 61



Organic QA/QC

Page 62







14G67536

05/16/17 11:21

05/16/17 14:27

WG614544

WG614301-01

HP14

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8015CMethod:

LJHAnalyst:


LCS

LCS2


17-0751 IR MUD SILO




WG614301-02

WG614301-03

L17050904-03

L17050904-01

L17050904-04

L17050904-05

L17050904-02

14G67537

14G67538

14G67540

14G67541

14G67542

14G67543

14G67544

05/16/17 15:06

05/16/17 15:45

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41



01

01

01

01

01

01

01

Page 63







8M419871

05/24/17 12:57

05/24/17 12:57

WG615405

WG615405-01

HPMS8

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8260BMethod:

TMBAnalyst:


LCS

LCS2

17-0751 OSG DISPOSAL PIT

WG615405-02

WG615405-03

L17051231-01

8M419872

8M419873

8M419874

05/24/17 13:25

05/24/17 13:53

05/24/17 14:22



01

01

DL01

Page 64







8M419884

05/24/17 19:08

05/24/17 19:08

WG615405

WG615405-04

HPMS8

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8260BMethod:

TMBAnalyst:


LCS

LCS2


WG615405-02

WG615405-03

L17051231-01

8M419872

8M419873

8M419874

05/24/17 13:25

05/24/17 13:53

05/24/17 14:22



01

01

DL01

Page 65







9M980444

05/23/17 16:46

05/23/17 16:46

WG615352

WG615352-01

HPMS9

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8260BMethod:

ADCAnalyst:


LCS

17-0751 IR MUD ORIGINAL

17-0751 IR MUD SILO

17-0751 IR MUD GRID A3 NEW


17-0751 WEST RECLAIMER PIT



WG615352-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

L17051231-02

9M980445

9M980446

9M980447

9M980448

9M980449

9M980450

9M980451

9M980452

05/23/17 17:16

05/23/17 17:46

05/23/17 18:16

05/23/17 18:47

05/23/17 19:17

05/23/17 19:47

05/23/17 20:17

05/23/17 20:47



01

01

01

01

01

01

01

01

Page 66




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5309108

26-MAY-2017 14:28

Dibromofluoromethane

1,2-Dichloroethane-d4

Toluene-d8

4-Bromofluorobenzene

99.8

103

106

112


86

80

88

86

-

-

-

-

118

120

110

115

Qualifier

PASS

PASS

PASS

PASS


Benzene

Carbon tetrachloride

Chlorobenzene

Chloroform

1,2-Dichloroethane

1,1-Dichloroethene

Methyl Ethyl Ketone

Tetrachloroethene

Trichloroethene

Vinyl chloride

1

1

1

1

1

1

1

1

1

1

0.125

0.250

0.125

0.125

0.250

0.500

2.50

0.250

0.250

0.250

5.00

5.00

5.00

5.00

5.00

5.00

10.0

5.00

5.00

10.0

U

U

U

U

U

U

U

U

U

U

0.125

0.250

0.125

0.125

0.250

0.500

2.50

0.250

0.250

0.250



11M18567

WG615282

Instrument ID:HPMS11

File ID:

Prep Date:05/23/17 13:37

Run Date:05/23/17 13:37

Analyst:TMB/JDS

Workgroup (AAB#): ug/LUnits:

8260BMethod:

WaterMatrix:


16-MAY-17Cal ID:HPMS11-OT900917Contract #:

5030B/5030C/503Prep Method:

MDL RL

MDL

RL



Page 67




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5309108

26-MAY-2017 14:28



Toluene-d8


103

99.6

107

107


86

80

88

86

-

-

-

-

118

120

110

115

Qualifier

PASS

PASS

PASS

PASS


Benzene


Chlorobenzene

Chloroform

1,2-Dichloroethane

1,1-Dichloroethene

Methyl Ethyl Ketone

Tetrachloroethene

Trichloroethene

Vinyl chloride

1

1

1

1

1

1

1

1

1

1

0.125

0.250

0.125

0.125

0.250

0.500

2.50

0.250

0.250

0.250

5.00

5.00

5.00

5.00

5.00

5.00

10.0

5.00

5.00

10.0

U

U

U

U

U

U

U

U

U

U

0.125

0.250

0.125

0.125

0.250

0.500

2.50

0.250

0.250

0.250



8M419871

WG615405

Instrument ID:HPMS8

File ID:

Prep Date:05/24/17 12:57

Run Date:05/24/17 12:57

Analyst:TMB


8260BMethod:

WaterMatrix:


17-APR-17Cal ID: HPMS8-OT900917Contract #:


MDL RL

MDL

RL



Page 68





SURROGATE STANDARDS


L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

-

-

o-Terphenyl

Octacosane

8015Method:

HP14Instrument Id:




26.2 36.2

12.6 9.41

53.4 52.3

30.9 30.4

39.5 34.6

69.6 62.6

69.7 68.2

73.4 74.9

43

25

-

-

136

162





Page 69







Diesel Range (C10-C28) 1000000 1000000 51200 0.384


* Exceeds

%D

Criteria %D

RF

14G67535

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:09:32

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 70







Diesel Range (C10-C28) 1000000 1040000 53300 4.46


* Exceeds

%D

Criteria %D

RF

14G67546

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:20:59

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 71







Page 72



LCS - Modified 03/06/2008




9M980445

WG615352

Instrument ID:HPMS9

File ID:

Run Date:05/23/2017

Run Time:17:16

Analyst:ADC



SoilMatrix:


Analytes Expected Found LCS Limits Q% Rec



Toluene-d8


105

103

108

109


80

80

81

74

-

-

-

-

120

120

117

121

Qualifier

PASS

PASS

PASS

PASS

WG615352-02Sample ID:

23-MAY-17Cal ID: HPMS9-STDQC Key:

Hexachlorobutadiene

Isopropylbenzene

p-Isopropyltoluene

4-Methyl-2-pentanone

Methylene chloride

Naphthalene

n-Propylbenzene

Styrene

1,1,1,2-Tetrachloroethane


Tetrachloroethene

Toluene

1,2,3-Trichlorobenzene


1,1,1-Trichloroethane


Trichloroethene

Trichlorofluoromethane

1,2,3-Trichloropropane

1,2,4-Trimethylbenzene


Vinyl acetate

Vinyl chloride

o-Xylene

m-,p-Xylene

65

68

72

47

74

50

72

74

71

55

72

77

60

65

70

60

72

48

65

75

74

10

45

70

70

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

40.0

21.5

21.4

22.2

20.6

23.2

25.7

23.6

22.4

22.2

23.2

22.1

23.0

23.7

22.8

22.2

23.3

21.4

21.2

23.4

23.4

23.2

25.9

25.7

22.9

45.5

108

107

111

103

116

129

118

112

111

116

110

115

119

114

111

117

107

106

117

117

116

130

129

115

114

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

135

129

128

146

128

146

136

130

137

130

130

126

135

130

135

125

126

154

130

132

133

150

140

130

130

8260BMethod:


Lot#:STD81766

Page 73







1,1-Dichloroethene

1,2-Dichloroethane

Methyl Ethyl Ketone

Benzene


Chlorobenzene

Chloroform

Tetrachloroethene

Trichloroethene

Vinyl chloride

LCS LCS2

4.01

1.54

5.32

2.70

2.37

2.22

2.08

0.870

1.31

0.804

20.1 20.9

20.8 21.1

18.6 19.6

21.1 21.6

20.4 20.9

21.2 21.7

18.9 19.3

21.4 21.6

20.6 20.8

21.8 22.0

Analytes %RPD

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0


100 105

104 105

93.0 98.1

105 108

102 105

106 108

94.3 96.3

107 108

103 104

109 110

% REC % REC

20

20

20

20

20

20

20

20

20

20

RPDLmt

%RecLimits

80

80

10

80

65

80

80

80

80

50

132

129

170

121

140

120

125

124

122

170

-

-

-

-

-

-

-

-

-

-

Q

Sample ID:

Sample ID:

WG615282-02

WG615282-03

LCS

LCS2

11M18568

11M18569

File ID:

File ID:




Toluene-d8

LCS LCS2

105 107

101 106

106 106

107 108


Surrogate Limits

80

86

86

88

120

118

115

110

-

-

-

-

Qualifier

PASS

PASS

PASS

PASS

Run Date:

Run Date:

05/23/2017 14:06

05/23/2017 14:35

WG615282


Analyst:TMB/JDS


8260BMethod:TCLP LeachMatrix:

L17051231Login Number: 5030B/5030C/503Prep Method:


# EXCEEDS RPD LIMIT


Page 74







1,1-Dichloroethene

1,2-Dichloroethane

Methyl Ethyl Ketone

Benzene


Chlorobenzene

Chloroform

Tetrachloroethene

Trichloroethene

Vinyl chloride

LCS LCS2

1.45

0.755

4.37

0.537

2.71

0.343

0.881

2.05

3.30

2.69

21.9 22.2

20.1 20.2

15.8 16.5

21.8 21.7

22.5 21.9

19.5 19.4

19.3 19.5

21.1 20.6

21.7 21.0

26.0 25.3

Analytes %RPD

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0


109 111

100 101

79.2 82.7

109 108

113 110

97.3 97.0

96.5 97.4

105 103

108 105

130 126

% REC % REC

20

20

20

20

20

20

20

20

20

20

RPDLmt

%RecLimits

80

80

10

80

65

80

80

80

80

50

132

129

170

121

140

120

125

124

122

170

-

-

-

-

-

-

-

-

-

-

Q

Sample ID:

Sample ID:

WG615405-02

WG615405-03

LCS

LCS2

8M419872

8M419873

File ID:

File ID:




Toluene-d8

LCS LCS2

95.4 97.5

100 103

104 103

106 107


Surrogate Limits

80

86

86

88

120

118

115

110

-

-

-

-

Qualifier

PASS

PASS

PASS

PASS

Run Date:

Run Date:

05/24/2017 13:25

05/24/2017 13:53

WG615405

Instrument ID:HPMS8

Analyst:TMB





# EXCEEDS RPD LIMIT


Page 75





SURROGATE STANDARDS


L17051231-01

WG615405-01

WG615405-02

WG615405-03

WG615405-04

DL01

01

01

01

01

1 2 3 4Sample Number Dilution Tag

10.0

1.00

1.00

1.00

1.00

1

2

3

4

-

-

-

-




Toluene-d8

8260Method:

HPMS8Instrument Id:


TCLP LeachMatrix:WG615405Workgroup (AAB#):


96.9 101 106 107

99.6 103 107 107

95.4 100 104 106

97.5 103 103 107

96.2 100 107 108

80

86

86

88

-

-

-

-

120

118

115

110



HPMS8CAL ID: -17-APR-17


Page 76





SURROGATE STANDARDS


L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615282-01

WG615282-02

WG615282-03

WG615282-04

WG615282-05

DL01

DL01

DL01

DL01

DL01

DL01

01

01

01

02

02


10.0

10.0

10.0

10.0

10.0

10.0

1.00

1.00

1.00

1.00

1.00

1

2

3

4

-

-

-

-




Toluene-d8

8260Method:

HPMS11Instrument Id:


TCLP LeachMatrix:WG615282Workgroup (AAB#):


105 103 108 110

109 106 113 113

107 103 110 111

108 102 112 111

104 101 113 108

107 101 107 108

103 99.8 112 106

105 101 106 107

107 106 106 108

106 105 113 112

104 102 114 110

80

86

86

88

-

-

-

-

120

118

115

110



HPMS11CAL ID: -16-MAY-17


Page 77





SURROGATE STANDARDS


L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615352-01

WG615352-02

01

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

3

4

-

-

-

-




Toluene-d8

8260Method:

HPMS9Instrument Id:




99.1 100 150 115

100 102 127 113

96.0 99.2 118 108

93.4 100 117 110

96.5 99.9 135 117

97.4 98.6 122 114

92.8 97.4 111 106

101 101 108 104

103 105 109 108

80

80

74

81

-

-

-

-

120

120

121

117





Page 78







CCC Calibration Check CompoundsSPCC System Performance Check Compounds

1,2-Dichloropropane

Ethylbenzene

Toluene

Chloroform

1,1-Dichloroethene

Vinyl Chloride


1,1-Dichloroethane

Bromoform

Chloromethane

Chlorobenzene

Benzene

Carbon Tetrachloride

1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.3

50.7

50.2

44.2

48.3

49.4

49.5

48.2

43.4

42.2

48.8

48.1

51.7

47.2

43.9

51.9

48.1

0.341

0.584

1.54

0.491

0.478

0.427

0.712

0.590

0.265

0.467

1.02

1.06

0.401

0.426

0.129

0.328

0.281

0.611

1.40

0.480

11.7

3.46

1.17

0.938

3.68

13.3

15.6

2.34

3.78

3.46

5.66

12.2

3.84

3.72


* Exceeds

%D

Criteria %D

RF

11M18564

WG615282


File ID:

Run Date:05/23/2017

Run Time:12:27

Analyst:TMB

Workgroup (AAB#):

8260BMethod:


16-MAY-17HPMS11 -Cal ID:

UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

STDQC Key:

WATERMatrix:

Page 79








Analyte Expected Found Q* Exceeds

%D Criteria %D

RF

11M18566

WG615282


File ID:

Run Date:05/23/2017

Run Time:13:08

Analyst:TMB/JDS

Workgroup (AAB#):

8260BMethod:



UNITS UCL

STDQC Key:

WATERMatrix:

Page 80








1,2-Dichloropropane

Ethylbenzene

Toluene

Chloroform

1,1-Dichloroethene

Vinyl Chloride


1,1-Dichloroethane

Bromoform

Chloromethane

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

53.4

55.2

55.5

49.9

57.2

59.8

45.7

56.1

43.6

60.1

52.2

55.3

59.1

50.8

42.3

56.0

54.8

0.269

0.613

1.54

0.501

0.414

0.478

0.432

0.509

0.177

0.509

1.04

1.14

0.445

0.288

0.0467

0.327

0.318

*

6.72

10.5

10.9

0.218

14.5

19.7

8.51

12.2

12.9

20.2

4.49

10.6

18.3

1.53

15.3

12.0

9.51


* Exceeds

%D

Criteria %D

RF

8M419869

WG615405

Instrument ID:HPMS8

File ID:

Run Date:05/24/2017

Run Time:11:59

Analyst:TMB

Workgroup (AAB#):

8260BMethod:


17-APR-17HPMS8 -Cal ID:

UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

STDQC Key:

WATERMatrix:

Page 81







Page 82



Calibration Table Report

Method: A9FOOWTR.M

Title: Appendix IX (SOP:OVL MSV01) Water 050317 HPMS11

Last Calibration: Thu May 04 07:07:15 2017

Curve: WG612759

Calibration Files

5 20 50 100 200 300 400 500

11M18002.D 11M18003.D 11M18004.D 11M18005.D 11M18006.D 11M18007.D 11M18008.D 11M18009.D

Compound Avg %RSD Linear Quadratic

I Fluorobenzene ISTD

T Acetonitrile 0.028 0.032 0.033 0.032 0.034 0.033 0.034 0.035 0.033 6.933

T 3-Chloro-1-propene 0.480 0.493 0.499 0.481 0.462 0.420 0.394 0.364 0.449 11.191

T 2-Chloro-1,3-butadiene 0.439 0.462 0.480 0.471 0.458 0.418 0.395 0.364 0.436 9.323

T Methacrylonitrile 0.149 0.176 0.191 0.188 0.193 0.186 0.185 0.178 0.181 7.820

T Isobutyl Alcohol 0.009 0.012 0.011 0.012 0.013 0.014 0.014 0.012 13.767

T 1-Butanol 0.005 0.006 0.006 0.007 0.007 0.006 11.655

T Cyclohexanone 0.008 0.008 0.010 0.010 0.011 0.011 0.010 12.441

T 2-Nitropropane 0.066 0.071 0.076 0.078 0.081 0.080 0.075 7.608

T Ethyl Acetate 0.229 0.253 0.260 0.255 0.254 0.241 0.233 0.221 0.243 5.885

T Methyl methacrylate 0.186 0.234 0.248 0.249 0.251 0.240 0.233 0.220 0.233 9.226

I Chlorobenzene-d5 ISTD

I 1,4-Dichlorobenzene-d4 ISTD

Mon May 08 16:08:06 2017

Page 83




Method: 8260WT.M

Title: 8260B/624 (SOP: OVL MSV01) Water 051617 HPMS11

Last Calibration: Wed May 17 12:46:08 2017

Curve: WG614378

Calibration Files

0.3 0.4 1 2 5 20 50 100 200 30011M18431.D 11M18432.D 11M18433.D 11M18434.D 11M18435.D 11M18436.D 11M18437.D 11M18438.D 11M18439.D 11M18440.D


Fluorobenzene ISTD

Dichlorodifluoromethane 0.317 0.353 0.357 0.424 0.407 0.378 0.368 0.372 9.541

Chloromethane 0.560 0.639 0.584 0.630 0.536 0.486 0.439 0.553 13.227

Vinyl Chloride 0.498 0.417 0.470 0.439 0.478 0.442 0.375 0.336 0.432 12.564

1,3-Butadiene 0.343 0.282 0.295 0.228 0.162 0.153 0.130 0.227 36.032 1.002

Bromomethane 0.207 0.210 0.206 0.193 0.198 0.204 0.219 0.205 4.082

Chloroethane 0.219 0.239 0.241 0.249 0.245 0.237 0.248 0.240 4.259

Trichlorofluoromethane 0.441 0.417 0.471 0.462 0.480 0.472 0.439 0.448 0.454 4.729

Diethyl ether 0.273 0.297 0.290 0.286 0.284 0.278 0.284 0.285 2.761

Isoprene 0.305 0.365 0.389 0.401 0.441 0.443 0.441 0.439 0.403 12.220

Acrolein 0.029 0.040 0.038 0.039 0.040 0.042 0.042 0.039 11.129

1,1,2-Trichloro-1,2,2-Trifluoroethane 0.195 0.234 0.242 0.249 0.253 0.241 0.255 0.239 8.688

Acetone 0.089 0.093 0.091 0.092 0.093 0.097 0.090 0.092 2.806

1,1-Dichloroethene 0.473 0.457 0.486 0.517 0.521 0.518 0.495 0.494 0.495 4.648

Tert-Butyl Alcohol 0.023 0.027 0.027 0.028 0.031 0.032 0.028 11.816

Dimethyl Sulfide 0.287 0.297 0.340 0.336 0.357 0.356 0.352 0.351 0.334 8.216

Iodomethane 0.013 0.079 0.141 0.251 0.276 0.290 0.298 0.192 59.519 0.998

Methyl acetate 0.215 0.241 0.249 0.254 0.256 0.266 0.247 7.124

Methylene Chloride 0.335 0.334 0.310 0.314 0.305 0.293 0.302 0.313 5.038

Carbon Disulfide 0.710 0.770 0.789 0.834 0.806 0.757 0.688 0.765 6.757

Acrylonitrile 0.094 0.114 0.118 0.119 0.129 0.131 0.126 0.119 10.729

Methyl Tert Butyl Ether 0.745 0.695 0.766 0.793 0.821 0.803 0.773 0.768 0.771 5.035

trans-1,2-Dichloroethene 0.246 0.236 0.270 0.276 0.288 0.287 0.276 0.287 0.271 7.185

n-Hexane 0.407 0.430 0.467 0.476 0.471 0.467 0.453 6.165

Diisopropyl ether 1.117 1.264 1.233 1.203 1.164 1.017 0.915 1.130 11.071

Vinyl Acetate 0.479 0.533 0.487 0.517 0.535 0.472 0.424 0.492 8.019

1,1-Dichloroethane 0.640 0.593 0.611 0.604 0.645 0.631 0.596 0.577 0.612 3.958

Ethyl-Tert-Butyl ether 0.964 1.097 1.071 1.046 1.027 0.914 0.834 0.993 9.488

2-Butanone 0.137 0.139 0.143 0.147 0.152 0.157 0.155 0.147 5.313

Propionitrile 0.034 0.041 0.043 0.044 0.045 0.047 0.050 0.043 11.768

2,2-Dichloropropane 0.423 0.369 0.405 0.392 0.420 0.417 0.395 0.398 0.402 4.470

cis-1,2-Dichloroethene 0.316 0.262 0.294 0.319 0.332 0.328 0.315 0.320 0.311 7.292

Chloroform 0.668 0.681 0.536 0.542 0.526 0.550 0.525 0.494 0.481 0.556 12.730

1-Bromopropane 0.040 0.054 0.061 0.060 0.058 0.061 0.059 0.056 13.246

Bromochloromethane 0.129 0.172 0.187 0.196 0.199 0.196 0.192 0.198 0.184 12.931

Tetrahydrofuran 0.158 0.115 0.106 0.104 0.106 0.106 0.108 0.115 16.890 0.999

Dibromofluoromethane 0.280 0.262 0.272 0.271 0.260 0.269 3.091

1,1,1-Trichloroethane 0.415 0.399 0.423 0.462 0.483 0.485 0.463 0.464 0.449 7.243

Cyclohexane 0.581 0.524 0.578 0.607 0.650 0.644 0.623 0.599 0.540 0.594 7.282

1,1-Dichloropropene 0.331 0.335 0.357 0.372 0.408 0.407 0.386 0.387 0.373 7.978

Carbon Tetrachloride 0.304 0.349 0.379 0.396 0.420 0.430 0.409 0.410 0.387 10.874

Tert-Amyl-Methyl ether 0.714 0.837 0.823 0.816 0.803 0.73 0.677 0.77142 8.15202

1,2-Dichloroethane-d4 0.363 0.317 0.338 0.335 0.317 0.33379 5.69157

1,2-Dichloroethane 0.442 0.419 0.47 0.476 0.478 0.468 0.436 0.423 0.45135 5.33453

Benzene 1.156 1.084 1.179 1.185 1.199 1.141 1.011 0.878 1.104 10.0158

Trichloroethene 0.226 0.251 0.301 0.301 0.325 0.317 0.301 0.309 0.29146 11.7841

Methylcyclohexane 0.477 0.383 0.443 0.467 0.507 0.501 0.477 0.464 0.423 0.46019 8.49006


1,4-Dioxane 0.002 0.003 0.003 0.003 0.003 0.003 0.00293 13.9596

Bromodichloromethane 0.343 0.298 0.345 0.37 0.408 0.403 0.393 0.389 0.36867 10.1709

Dibromomethane 0.12 0.153 0.171 0.163 0.188 0.182 0.176 0.183 0.16712 13.2633

2-Chloroethyl Vinyl Ether 0.14 0.162 0.18 0.202 0.21 0.215 0.22 0.208 0.19218 14.9182

4-Methyl-2-Pentanone 0.099 0.116 0.122 0.127 0.138 0.133 0.12257 11.2898

cis-1,3-Dichloropropene 0.334 0.303 0.37 0.402 0.455 0.472 0.45 0.443 0.40378 15.4416 0.999

Dimethyl Disulfide 0.147 0.173 0.237 0.271 0.28 0.288 0.269 0.23782 23.5484 0.999

Chlorobenzene-d5 ISTD

Toluene-d8 1.507 1.348 1.404 1.335 1.146 1.34813 9.77146

Toluene 2.389 1.827 1.753 1.819 1.767 1.658 1.41 1.80307 16.3818 0.991

Ethyl Methacrylate 0.303 0.369 0.419 0.482 0.512 0.503 0.484 0.461 0.44178 16.5839 0.998

trans-1,3-Dichloropropene 0.496 0.468 0.517 0.577 0.593 0.574 0.53 0.53644 8.70041


2-Hexanone 0.257 0.302 0.314 0.319 0.323 0.318 0.30532 8.13831


Tetrachloroethene 0.237 0.276 0.301 0.34 0.35 0.354 0.336 0.331 0.31574 13.0405

Dibromochloromethane 0.302 0.303 0.328 0.364 0.422 0.438 0.419 0.416 0.37379 15.2048 0.999

1,2-Dibromoethane 0.218 0.277 0.297 0.323 0.336 0.338 0.324 0.324 0.30457 13.3219

1-Chlorohexane 0.435 0.368 0.42 0.471 0.528 0.54 0.528 0.493 0.454 0.47077 12.2378

Chlorobenzene 1.06 1.029 1.093 1.095 1.14 1.091 0.982 0.852 1.04267 8.68375

1,1,1,2-Tetrachloroethane 0.333 0.343 0.376 0.375 0.422 0.428 0.418 0.412 0.38822 9.55907

Ethylbenzene 0.49 0.553 0.573 0.617 0.631 0.597 0.568 0.5756 8.15775

m-,p-Xylene 0.624 0.61 0.662 0.73 0.738 0.723 0.635 0.52 0.6552 11.3677

o-Xylene 0.611 0.542 0.601 0.714 0.734 0.742 0.699 0.654 0.66201 10.9201

Styrene 0.915 0.841 0.944 1.039 1.186 1.213 1.116 0.962 1.02697 13.0703

Bromoform 0.169 0.221 0.229 0.278 0.299 0.304 0.316 0.25955 20.9192 0.999

Isopropylbenzene 1.54 1.47 1.654 1.773 1.858 1.79 1.534 1.228 1.60558 12.8593

1,4-Dichlorobenzene-d4 ISTD


p-Bromofluorobenzene 0.94 0.932 0.941 0.959 0.874 0.92914 3.499

1,2,3-Trichloropropane 0.192 0.203 0.227 0.25 0.237 0.238 0.241 0.22684 9.47455

trans-1,4-Dichloro-2-Butene 0.145 0.197 0.252 0.276 0.273 0.283 0.283 0.259 0.24598 20.0146 0.998

R^2

Page 84



n-Propylbenzene 3.443 3.25 3.731 4.084 4.255 3.72 3.078 3.6516 11.7041

Bromobenzene 0.765 0.798 0.769 0.857 0.913 0.978 0.915 0.884 0.825 0.85586 8.52037

1,3,5-Trimethylbenzene 2.528 2.343 2.64 2.841 3.025 2.723 2.375 1.866 2.54273 14.0286

2-Chlorotoluene 2.677 2.489 2.82 2.937 3.017 2.639 2.322 1.813 2.58925 14.9669

4-Chlorotoluene 1.945 1.885 2.066 2.17 2.308 2.123 1.844 1.421 1.97015 13.7289

a-Methylstyrene 1.273 1.545 1.523 1.47 1.247 1.119 1.36309 12.7744

tert-Butylbenzene 0.452 0.537 0.622 0.676 0.646 0.63 0.606 0.59568 12.8233

1,2,4-Trimethylbenzene 2.375 2.721 2.996 3.128 2.834 2.449 2.75056 10.8088

sec-Butylbenzene 2.835 3.307 3.628 3.804 3.444 2.938 3.32593 11.4512

p-Isopropyltoluene 2.257 2.755 2.988 3.212 2.941 2.558 2.7853 12.2258

1,3-Dichlorobenzene 1.381 1.452 1.581 1.675 1.801 1.669 1.574 1.332 1.5582 10.2657


n-Butylbenzene 2.011 2.347 2.567 2.939 2.747 2.426 2.50625 12.9532

1,2-Dichlorobenzene 1.749 1.667 1.454 1.685 1.649 1.757 1.617 1.532 1.299 1.60101 9.3155

1,2-Dibromo-3-Chloropropane 0.092 0.133 0.151 0.154 0.157 0.168 0.14243 19.0803 0.999

1,2,4-Trichlorobenzene 0.9 0.961 1.064 1.102 1.251 1.175 1.143 1.07 1.08325 10.4409

Hexachlorobutadiene 0.336 0.503 0.513 0.584 0.642 0.617 0.623 0.616 0.55426 18.444 1

Naphthalene 2.035 1.958 2.204 2.525 2.772 2.535 2.227 1.831 2.26105 14.3669

1,2,3-Trichlorobenzene 0.922 0.878 0.94 1.027 1.136 1.237 1.159 1.103 1.065 1.05185 11.4386

Thu May 18 10:46:55 2017

Page 85




Method: A9FOOWT.M

Title: A9-FOO Water SOP:MSV01 04-12-17 HPMS8

Last Calibration: Thu Apr 13 16:40:13 2017

Curve: WG609829

Calibration Files

5 20 50 100 200 300 400 5008M418916.D 8M418917.D 8M418918.D 8M418919.D 8M418920.D 8M418921.D 8M418922.D 8M418923.D

Compound Avg %RSD

I Fluorobenzene ISTDT Acetonitrile 0.013 0.012 0.013 0.013 0.012 0.013 0.013 0.013 3.572T 3-Chloro-1-propene 0.312 0.315 0.327 0.337 0.346 0.341 0.344 0.341 0.333 3.984T 2-Chloro-1,3-butadiene 0.285 0.299 0.317 0.330 0.340 0.336 0.337 0.336 0.322 6.267T Ethyl Acetate 0.099 0.101 0.098 0.101 0.108 0.103 0.106 0.109 0.103 4.045T Methacrylonitrile 0.052 0.059 0.057 0.059 0.064 0.061 0.063 0.065 0.060 7.025T Isobutyl Alcohol 0.003 0.004 0.004 0.004 0.005 0.005 0.004 12.096T 1-Butanol 0.000 0.000T Methyl methacrylate 0.096 0.101 0.103 0.107 0.116 0.112 0.116 0.121 0.109 7.922T 2-Nitropropane 0.027 0.028 0.031 0.034 0.034 0.035 0.037 0.032 11.358I Chlorobenzene-d5 ISTDI 1,4-Dichlorobenzene-d4 ISTDT Cyclohexanone 0.006 0.006 0.007 0.008 0.007 0.008 0.009 0.007 13.841

Mon Apr 17 15:45:45 2017

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Calibration Table ReportMethod: 8260WT.MTitle: Method 8260B/624 WTR-SOP:OVLMSV01 04-17-17 HPMS8Last Calibration: Tue Apr 18 08:45:38 2017Curve: WG610410Calibration Files


Compound Avg %RSD Linear Quad

I Fluorobenzene ISTDT Dichlorodifluoromethane 0.313 0.289 0.277 0.384 0.370 0.362 0.373 0.338 13.019P Chloromethane 0.456 0.440 0.417 0.437 0.403 0.401 0.407 0.423 5.087C Vinyl Chloride 0.426 0.430 0.414 0.394 0.429 0.389 0.367 0.347 0.399 7.750T 1,3-Butadiene 0.273 0.246 0.164 0.130 0.118 0.112 0.174 39.828 1.000

T Bromomethane 0.064 0.068 0.074 0.124 0.149 0.181 0.110 44.154 1.001

T Chloroethane 0.162 0.163 0.173 0.171 0.183 0.177 0.180 0.186 0.174 5.074T Trichlorofluoromethane 0.393 0.462 0.411 0.420 0.452 0.436 0.437 0.459 0.434 5.614T Diethyl ether 0.159 0.160 0.163 0.158 0.160 0.167 0.176 0.163 3.861T Isoprene 0.316 0.325 0.346 0.353 0.353 0.366 0.343 5.533T Acrolein 0.022 0.023 0.021 0.022 0.024 0.024 0.023 4.706T 1,1,2-Trichloro-1,2,2-Trifluoroethane 0.251 0.228 0.237 0.253 0.250 0.252 0.261 0.247 4.440T Acetone 0.036 0.033 0.036 0.037 0.034 0.035 0.035 4.082C 1,1-Dichloroethene 0.331 0.366 0.344 0.349 0.377 0.371 0.376 0.383 0.362 5.154T Tert-Butyl Alcohol 0.010 0.012 0.011 0.011 0.011 0.013 0.011 10.980T Dimethyl Sulfide 0.232 0.226 0.240 0.246 0.249 0.255 0.241 4.476T Iodomethane 0.026 0.067 0.121 0.154 0.164 0.116 0.108 48.714 NO CALT Methyl acetate 0.099 0.091 0.097 0.098 0.093 0.100 0.096 3.655T Methylene Chloride 0.271 0.245 0.249 0.263 0.258 0.264 0.272 0.260 3.943T Carbon Disulfide 0.794 0.744 0.746 0.729 0.763 0.767 0.766 0.713 0.753 3.339T Acrylonitrile 0.043 0.045 0.049 0.049 0.053 0.054 0.049 0.049 8.214T Methyl Tert Butyl Ether 0.495 0.474 0.502 0.530 0.528 0.543 0.517 0.513 4.642T trans-1,2-Dichloroethene 0.342 0.345 0.349 0.334 0.360 0.353 0.363 0.373 0.352 3.537T n-Hexane 0.301 0.278 0.290 0.295 0.300 0.301 0.294 2.997T Diisopropyl ether 0.776 0.794 0.805 0.792 0.783 0.801 0.768 0.788 1.708T Vinyl Acetate 0.353 0.350 0.359 0.366 0.348 0.345 0.354 2.233P 1,1-Dichloroethane 0.405 0.460 0.437 0.441 0.474 0.462 0.473 0.476 0.453 5.418T Ethyl-Tert-Butyl ether 0.651 0.652 0.684 0.667 0.669 0.693 0.679 0.671 2.398T 2-Butanone 0.053 0.052 0.056 0.058 0.053 0.059 0.055 5.073T Propionitrile 0.015 0.016 0.018 0.017 0.017 0.018 0.019 0.017 7.523T 2,2-Dichloropropane 0.336 0.387 0.384 0.373 0.399 0.387 0.396 0.399 0.383 5.430T cis-1,2-Dichloroethene 0.263 0.287 0.282 0.286 0.300 0.296 0.305 0.311 0.291 5.182C Chloroform 0.619 0.539 0.514 0.499 0.459 0.479 0.467 0.473 0.471 0.502 10.092T 1-Bromopropane 0.057 0.053 0.055 0.056 0.057 0.059 0.061 0.061 0.057 5.096T Bromochloromethane 0.118 0.150 0.156 0.160 0.167 0.167 0.170 0.168 0.157 11.011T Tetrahydrofuran 0.039 0.035 0.038 0.036 0.038 0.040 0.039 0.038 4.497S Dibromofluoromethane 0.251 0.244 0.261 0.272 0.265 0.269 0.273 0.262 4.105T 1,1,1-Trichloroethane 0.337 0.406 0.380 0.394 0.426 0.420 0.431 0.450 0.405 8.684T Cyclohexane 0.371 0.358 0.372 0.358 0.379 0.389 0.403 0.391 0.377 4.255T 1,1-Dichloropropene 0.354 0.340 0.337 0.363 0.353 0.359 0.371 0.354 3.449T Tert-Amyl-Methyl ether 0.568 0.579 0.618 0.598 0.602 0.629 0.609 0.600 3.552T Carbon Tetrachloride 0.288 0.38 0.359 0.363 0.404 0.394 0.41 0.411 0.3759 10.8547S 1,2-Dichloroethane-d4 0.215 0.219 0.227 0.237 0.23 0.224 0.235 0.2267 3.56551T Heptane 0 0T 1,2-Dichloroethane 0.247 0.28 0.273 0.279 0.298 0.293 0.305 0.299 0.284 6.56007T Benzene 1.013 1.058 1.034 1.013 1.082 1.044 1.045 0.975 1.0328 3.16185T Trichloroethene 0.28 0.291 0.275 0.274 0.294 0.29 0.302 0.315 0.2901 4.79714T Methylcyclohexane 0.371 0.369 0.386 0.392 0.4 0.402 0.3867 3.65443C 1,2-Dichloropropane 0.235 0.244 0.249 0.243 0.257 0.256 0.264 0.269 0.2522 4.51345T Bromodichloromethane 0.273 0.313 0.319 0.319 0.35 0.347 0.359 0.361 0.3301 9.09766T 1,4-Dioxane 0.001 0.001 0.002 0.002 0.002 0.0014 8.93532T Dibromomethane 0.101 0.125 0.129 0.129 0.138 0.136 0.14 0.14 0.1298 9.96462T 2-Chloroethyl Vinyl Ether 0.091 0.101 0.106 0.114 0.116 0.114 0.122 0.1091 9.65313T 4-Methyl-2-Pentanone 0.042 0.045 0.05 0.051 0.049 0.055 0.0489 9.48763T cis-1,3-Dichloropropene 0.303 0.354 0.349 0.364 0.401 0.404 0.417 0.416 0.3759 10.7244

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T Dimethyl Disulfide 0.133 0.169 0.201 0.215 0.226 0.237 0.1968 19.8258 0.998

I Chlorobenzene-d5 ISTDS Toluene-d8 1.126 1.107 1.183 1.185 1.136 1.123 1.136 1.1423 2.63592C Toluene 1.276 1.435 1.421 1.416 1.507 1.432 1.412 1.234 1.3916 6.46773T Ethyl Methacrylate 0.208 0.222 0.252 0.262 0.287 0.29 0.277 0.303 0.2625 12.7656T Paraldehyde 0 0T trans-1,3-Dichloropropene 0.367 0.363 0.389 0.421 0.422 0.44 0.423 0.4036 7.59969T 1,1,2-Trichloroethane 0.21 0.235 0.224 0.228 0.239 0.229 0.237 0.23 0.2289 4.06629T 2-Hexanone 0.048 0.053 0.058 0.06 0.054 0.063 0.0562 9.63322T 1,3-Dichloropropane 0.353 0.405 0.372 0.373 0.41 0.397 0.403 0.383 0.387 5.15702T Tetrachloroethene 0.245 0.284 0.279 0.285 0.31 0.295 0.312 0.328 0.2923 8.65757T Dibromochloromethane 0.232 0.267 0.271 0.289 0.315 0.318 0.333 0.328 0.2942 12.052T 1,2-Dibromoethane 0.188 0.209 0.218 0.222 0.242 0.236 0.241 0.233 0.2236 8.21869T 1-Chlorohexane 0.385 0.44 0.423 0.428 0.44 0.451 0.457 0.466 0.472 0.4403 5.99946P Chlorobenzene 1.008 0.965 0.972 0.936 1.008 0.988 1.042 1.006 0.9906 3.29062T 1,1,1,2-Tetrachloroethane 0.303 0.316 0.32 0.335 0.379 0.385 0.423 0.3515 12.6454C Ethylbenzene 0.467 0.5 0.532 0.513 0.574 0.568 0.62 0.665 0.5548 11.7603T m-,p-Xylene 0.572 0.637 0.62 0.627 0.689 0.677 0.694 0.623 0.6425 6.46237T o-Xylene 0.611 0.592 0.623 0.665 0.648 0.68 0.703 0.6459 6.13337T Styrene 0.814 0.93 0.929 0.995 1.114 1.111 1.142 1.067 1.0127 11.3997P Bromoform 0.125 0.142 0.163 0.191 0.196 0.207 0.207 0.176 18.66 0.999

T Isopropylbenzene 1.463 1.551 1.54 1.592 1.678 1.613 1.576 1.361 1.5466 6.28276I 1,4-Dichlorobenzene-d4 ISTDP 1,1,2,2-Tetrachloroethane 0.385 0.493 0.455 0.465 0.508 0.494 0.502 0.472 0.4717 8.42371S p-Bromofluorobenzene 0.897 0.839 0.876 0.891 0.86 0.878 0.935 0.8823 3.42248T 1,2,3-Trichloropropane 0.117 0.127 0.131 0.143 0.144 0.146 0.138 0.1352 7.82469T trans-1,4-Dichloro-2-Butene 0.058 0.065 0.085 0.109 0.122 0.115 0.114 0.116 0.0978 25.7933 1.000

T n-Propylbenzene 3.478 3.723 3.692 3.608 3.807 3.577 3.383 2.726 3.4991 9.72861T Bromobenzene 0.752 0.696 0.839 0.81 0.813 0.857 0.845 0.872 0.896 0.8199 7.58093T 1,3,5-Trimethylbenzene 2.467 2.514 2.525 2.506 2.737 2.623 2.589 2.306 2.5336 4.94471T 2-Chlorotoluene 2.674 2.623 2.305 2.553 2.347 2.198 2.2 2.21 2.3888 8.30021T 4-Chlorotoluene 1.995 2.135 2.439 1.867 2.369 2.326 2.308 1.784 2.1528 11.4607T a-Methylstyrene 1.296 1.355 1.455 1.517 1.498 1.401 1.4204 6.02416T tert-Butylbenzene 0.52 0.555 0.528 0.588 0.571 0.601 0.653 0.5736 7.96677T 1,2,4-Trimethylbenzene 2.284 2.607 2.62 2.578 2.817 2.742 2.701 2.343 2.5866 7.19751T sec-Butylbenzene 3.278 3.292 3.183 3.429 3.252 3.145 2.633 3.1733 8.03336T p-Isopropyltoluene 2.64 2.605 2.626 2.913 2.796 2.737 2.387 2.6721 6.23483T 1,3-Dichlorobenzene 1.502 1.596 1.568 1.535 1.665 1.625 1.642 1.581 1.5891 3.4371T 1,4-Dichlorobenzene 1.772 1.622 1.643 1.594 1.517 1.637 1.592 1.618 1.545 1.6156 4.45875T n-Butylbenzene 2.426 2.337 2.245 2.632 2.542 2.483 2.184 2.407 6.69686T 1,2-Dichlorobenzene 1.368 1.185 1.488 1.397 1.379 1.46 1.438 1.454 1.396 1.396 6.36818T 1,2-Dibromo-3-Chloropropane 0.073 0.072 0.076 0.079 0.083 0.077 0.0768 5.09915T 1,2,4-Trichlorobenzene 0.864 0.92 0.882 0.852 0.952 0.983 1.022 1.044 0.9399 7.72424T Hexachlorobutadiene 0.405 0.427 0.426 0.402 0.449 0.44 0.456 0.493 0.4374 6.74711T Naphthalene 1.353 1.273 1.232 1.251 1.396 1.436 1.465 1.339 1.3431 6.41915T 1,2,3-Trichlorobenzene 0.796 0.766 0.75 0.705 0.691 0.802 0.821 0.847 0.847 0.7805 7.29917

Tue Apr 18 12:15:24 2017

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Method: A9FOOSL.M

Title: FOO/APPIX SOIL 02/20/2017 SOP: OVL MSV01

Last Calibration: Tue Feb 21 15:27:36 2017

Curve: WG603526

Calibration Files

5 20 50 100 200 300 400 500 R^29M978918.D 9M978919.D 9M978920.D 9M978921.D 9M978922.D 9M978923.D 9M978924.D 9M978925.D

Compound Avg %RSD Linear

Fluorobenzene ISTD

Acetonitrile 0.045 0.047 0.047 0.049 0.046 0.049 0.046 0.047 3.144

3-Chloro-1-propene 0.438 0.493 0.514 0.528 0.521 0.484 0.489 0.467 0.492 6.091

2-Chloro-1,3-butadiene 0.383 0.447 0.470 0.490 0.481 0.448 0.457 0.435 0.451 7.360

Ethyl Acetate 0.305 0.314 0.329 0.323 0.306 0.316 0.305 0.314 3.020

Methacrylonitrile 0.103 0.111 0.116 0.121 0.122 0.117 0.122 0.117 0.116 5.609

Isobutyl Alcohol 0.019 0.019 0.017 0.020 0.021 0.020 0.022 0.023 0.020 8.963

1-Butanol 0.006 0.009 0.010 0.010 0.012 0.012 0.010 22.774 0.992

Methyl methacrylate 0.228 0.257 0.284 0.299 0.296 0.281 0.286 0.275 0.276 8.390

2-Nitropropane 0.057 0.060 0.077 0.086 0.089 0.087 0.094 0.092 0.080 17.823 0.998


Cyclohexanone 0.018 0.022 0.025 0.028 0.026 0.029 0.027 0.025 15.974 0.997


Tue Feb 21 15:37:39 2017

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Method: 8260SL.M

Title: 8260(B) SOP: OVL MSV01 SOIL 05/23/17 HPMS9

Last Calibration: Tue May 23 15:17:14 2017

Curve: WG615237

Calibration Files

0.5 1 2 5 20 50 100 200 3009M980432.D 9M980433.D 9M980434.D 9M980435.D 9M980436.D 9M980437.D 9M980438.D 9M980439.D 9M980440.D


Fluorobenzene ISTD


Chloromethane 0.378 0.340 0.282 0.300 0.359 0.338 0.333 10.813

Vinyl Chloride 0.184 0.241 0.260 0.207 0.215 0.228 0.201 0.219 11.773

1,3-Butadiene 0.145 0.162 0.144 0.114 0.113 0.102 0.107 0.127 18.242 0.996

Bromomethane 0.232 0.222 0.174 0.165 0.178 0.154 0.188 16.940 0.995

Chloroethane 0.185 0.193 0.175 0.169 0.199 0.170 0.182 6.849

Trichlorofluoromethane 0.335 0.409 0.412 0.383 0.388 0.445 0.404 0.397 8.572

Diethyl ether 0.294 0.286 0.249 0.243 0.296 0.291 0.277 8.617

Isoprene 0.338 0.363 0.334 0.344 0.391 0.360 0.355 5.983

Acrolein 0.049 0.059 0.059 0.053 0.057 0.065 0.067 0.058 11.013

1,1,2-Trichloro-1,2,2-Trifluoroethane 0.226 0.240 0.220 0.222 0.256 0.232 0.233 5.829

Acetone 0.222 0.159 0.143 0.150 0.133 0.140 0.158 20.777 0.998

1,1-Dichloroethene 0.349 0.408 0.425 0.400 0.410 0.465 0.424 0.412 8.467

Tert-Butyl Alcohol 0.058 0.054 0.051 0.050 0.067 0.056 12.119

Dimethyl Sulfide 0.217 0.268 0.292 0.265 0.274 0.320 0.284 0.274 11.429

Iodomethane 0.119 0.127 0.174 0.242 0.231 0.265 0.193 32.107 0.998

Methyl acetate 0.316 0.368 0.364 0.328 0.328 0.361 0.331 0.342 6.193

Methylene Chloride 0.299 0.280 0.244 0.246 0.286 0.253 0.268 8.765


Acrylonitrile 0.128 0.153 0.154 0.138 0.147 0.168 0.184 0.153 12.173

Methyl Tert Butyl Ether 0.597 0.772 0.788 0.711 0.725 0.839 0.743 0.739 10.283

trans-1,2-Dichloroethene 0.326 0.410 0.414 0.385 0.393 0.448 0.404 0.397 9.398

n-Hexane 0.429 0.487 0.464 0.460 0.527 0.478 0.474 6.906

Diisopropyl ether 1.261 1.248 1.050 1.028 1.240 1.196 1.170 8.911

Vinyl Acetate 0.439 0.514 0.599 0.692 0.630 0.675 0.592 16.497 0.998

1,1-Dichloroethane 0.443 0.517 0.523 0.477 0.481 0.552 0.491 0.498 7.221

Ethyl-Tert-Butyl ether 1.052 1.028 0.886 0.866 1.051 1.034 0.986 8.735

2-Butanone 0.175 0.185 0.185 0.219 0.198 0.223 0.197 10.014

Propionitrile 0.051 0.059 0.057 0.056 0.070 0.074 0.061 14.877

2,2-Dichloropropane 0.300 0.356 0.366 0.344 0.351 0.411 0.375 0.357 9.436

cis-1,2-Dichloroethene 0.203 0.265 0.282 0.253 0.258 0.306 0.273 0.263 12.141

Chloroform 0.380 0.445 0.465 0.413 0.419 0.486 0.430 0.434 8.101

1-Bromopropane 0.039 0.047 0.045 0.046 0.055 0.050 0.054 0.048 11.120

Bromochloromethane 0.133 0.160 0.171 0.163 0.168 0.190 0.174 0.165 10.435

Tetrahydrofuran 0.164 0.151 0.137 0.136 0.147 0.157 0.149 7.460


1,1,1-Trichloroethane 0.280 0.354 0.393 0.365 0.373 0.434 0.392 0.370 12.824

Cyclohexane 0.414 0.527 0.573 0.506 0.524 0.599 0.538 0.526 11.115

1,1-Dichloropropene 0.313 0.334 0.307 0.321 0.364 0.330 0.328 6.203

Tert-Amyl-Methyl ether 0.820 0.791 0.683 0.671 0.821 0.813 0.766 9.180

Carbon Tetrachloride 0.29289 0.31699 0.31213 0.33031 0.38971 0.3567 0.33312 10.4727


Heptane 0 0

1,2-Dichloroethane 0.33803 0.39852 0.40195 0.37996 0.38536 0.43986 0.39241 0.39087 7.76385

Benzene 0.80698 1.02836 1.02298 0.90895 0.92283 1.05233 0.90638 0.94983 9.29021

Trichloroethene 0.2249 0.28315 0.26996 0.2542 0.25942 0.29412 0.26134 0.26387 8.4207

Methylcyclohexane 0.43492 0.43679 0.42091 0.42381 0.48719 0.43852 0.44036 5.46016


1,4-Dioxane 0.00375 0.00403 0.00433 0.00452 0.00613 0.00633 0.00485 22.7665 0.998

Bromodichloromethane 0.28256 0.30468 0.30429 0.32033 0.38465 0.34655 0.32384 11.286

Dibromomethane 0.12277 0.1591 0.17751 0.16793 0.17202 0.2019 0.18104 0.1689 14.3914

2-Chloroethyl Vinyl Ether 0.13982 0.15845 0.17486 0.20617 0.18595 0.17305 14.6866

4-Methyl-2-Pentanone 0.10503 0.12528 0.13869 0.165 0.15182 0.17334 0.14319 17.8216 0.995

cis-1,3-Dichloropropene 0.32308 0.35447 0.35942 0.37785 0.44285 0.40028 0.37632 11.0204



Toluene-d8 1.32931 1.24766 1.36447 1.35272 1.18812 1.29646 5.8473

Toluene 1.12084 1.40035 1.54236 1.39327 1.362 1.55253 1.28612 1.37964 10.7922

Ethyl Methacrylate 0.34883 0.42389 0.44038 0.53408 0.48562 0.44656 15.5504 0.996


1,1,2-Trichloroethane 0.22386 0.31286 0.33003 0.30784 0.31162 0.35655 0.31582 0.30837 13.2509

2-Hexanone 0.17065 0.33435 0.37135 0.48319 0.44361 0.50745 0.3851 32.1752 0.994


Tetrachloroethene 0.24255 0.30066 0.32772 0.29019 0.2877 0.3347 0.29646 0.29714 10.1676

Dibromochloromethane 0.32723 0.33426 0.35311 0.36651 0.44137 0.39798 0.37008 11.6417

1,2-Dibromoethane 0.27496 0.3186 0.30635 0.32155 0.3685 0.33173 0.32028 9.5817

1-Chlorohexane 0.41418 0.46131 0.43155 0.43453 0.50377 0.45558 0.45015 6.9634

Chlorobenzene 0.88602 1.00258 1.08815 0.91569 0.9081 1.03953 0.87681 0.95956 8.67873

1,1,1,2-Tetrachloroethane 0.28684 0.33494 0.35481 0.3426 0.33769 0.39976 0.35625 0.3447 9.74074

Ethylbenzene 0.42796 0.52747 0.55239 0.49735 0.48604 0.56148 0.48774 0.50578 9.056

m-,p-Xylene 0.57238 0.52979 0.63877 0.69325 0.60511 0.59691 0.67843 0.56858 0.6104 9.22583

o-Xylene 0.48537 0.60436 0.64412 0.58265 0.5869 0.68063 0.5883 0.59605 10.184

Styrene 0.88222 1.01973 0.98335 0.99506 1.17911 1.00088 1.01006 9.50003

Bromoform 0.2468 0.26527 0.28042 0.351 0.32651 0.294 14.7714

Isopropylbenzene 1.35585 1.64249 1.67087 1.53129 1.51217 1.74054 1.4314 1.55494 8.81943


1,1,2,2-Tetrachloroethane 0.6242 0.81549 0.91406 0.90654 0.91148 1.02423 0.91847 0.8735 14.3627


1,2,3-Trichloropropane 0.26603 0.276 0.28125 0.27356 0.30345 0.28176 0.28034 4.52994

R^2

Page 90



trans-1,4-Dichloro-2-Butene 0.28278 0.3263 0.32882 0.39115 0.36223 0.33826 12.0828

n-Propylbenzene 3.03086 3.79165 4.03741 3.8251 3.52438 3.54164 2.91559 3.5238 11.8124

Bromobenzene 0.66226 0.8893 0.96298 0.8797 0.82324 0.87194 0.80221 0.84166 11.2124

1,3,5-Trimethylbenzene 2.17574 2.63707 2.86163 2.71343 2.49525 2.60622 2.26692 2.53661 9.60965

2-Chlorotoluene 2.13547 2.53777 2.80859 2.53254 2.4266 2.44126 2.17898 2.43732 9.40052

4-Chlorotoluene 2.00505 2.43818 2.37165 2.14992 1.838 2.01616 1.7285 2.07821 12.5789

a-Methylstyrene 1.35882 1.33081 1.30477 1.46901 1.32745 1.35817 4.77603

tert-Butylbenzene 0.66487 0.59944 0.55648 0.59297 0.54628 0.59201 7.88621

1,2,4-Trimethylbenzene 2.04957 2.86539 3.02888 2.79016 2.54896 2.71197 2.31826 2.61617 12.9265

sec-Butylbenzene 3.23905 3.62962 3.74038 3.55307 3.25781 3.38054 2.83017 3.37581 9.04278

p-Isopropyltoluene 2.509 3.10151 2.99414 2.91784 2.72192 2.92459 2.46968 2.80552 8.70289

1,3-Dichlorobenzene 1.50758 1.78058 1.84751 1.67405 1.56993 1.76979 1.53827 1.66967 8.01523


n-Butylbenzene 2.22913 2.79862 2.89925 2.71706 2.59446 2.88759 2.4027 2.64697 9.58809


1,2-Dibromo-3-Chloropropane 0.21621 0.23382 0.26844 0.30963 0.25254 0.25613 13.9658

1,2,4-Trichlorobenzene 1.06977 1.26451 1.30441 1.14806 1.24191 1.44339 1.13132 1.22905 10.2124

Hexachlorobutadiene 0.50283 0.59177 0.66688 0.60293 0.6322 0.77368 0.60822 0.6255 13.1682

Naphthalene 2.7944 3.32504 3.44532 3.28651 3.60003 3.81264 2.70881 3.28182 12.2994

1,2,3-Trichlorobenzene 1.10949 1.32469 1.31658 1.15583 1.28929 1.43286 1.11821 1.24956 9.85405

Wed May 24 12:57:24 2017

Page 91





5309110PDF File ID:




Analyte Expected Found* Exceeds

%D Limit %D

RF

11M18011

WG612759


File ID:

Run Date:05/04/2017

Run Time:00:00

Analyst:FJB

ICal Workgroup:

8260BMethod:



QUCLUnits

QC Key:STD

Page 92





5309110PDF File ID:




Chloroform

1,1-Dichloroethene

Vinyl Chloride

Chloromethane


1,1-Dichloroethane

Bromoform

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

18.3

18.4

21.6

22.3

19.6

19.1

16.5

20.9

20.5

20.2

19.6

19.4

21.4

21.9

0.508

0.455

0.467

0.617

0.704

0.586

0.246

1.09

1.13

0.392

0.443

0.143

0.338

0.319

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

8.60

8.00

8.20

11.5

2.10

4.30

17.6

4.40

2.30

1.20

1.90

2.80

6.90

9.30


* Exceeds

%D

Limit %D

RF

11M18442

WG614378


File ID:

Run Date:05/16/2017

Run Time:18:14

Analyst:ADC

ICal Workgroup:

8260BMethod:



QUCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 93





5309110PDF File ID:





%D Limit %D

RF

8M418926

WG609829

Instrument ID:HPMS8

File ID:

Run Date:04/12/2017

Run Time:16:10

Analyst:TMB

ICal Workgroup:

8260BMethod:



QUCLUnits

QC Key:STD

Page 94





5309110PDF File ID:




Chloroform

1,1-Dichloroethene

Vinyl Chloride

Bromoform

1,1-Dichloroethane


Chloromethane

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

44.7

47.0

45.4

42.9

47.6

45.7

48.6

47.2

47.6

50.2

47.2

43.5

50.6

47.5

0.449

0.340

0.363

0.175

0.432

0.431

0.411

0.934

0.983

0.377

0.268

0.0479

0.296

0.276

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

10.6

6.00

9.20

14.2

4.80

8.60

2.80

5.70

4.90

0.300

5.50

13.1

1.20

5.00


* Exceeds

%D

Limit %D

RF

8M419014

WG610410

Instrument ID:HPMS8

File ID:

Run Date:04/17/2017

Run Time:19:53

Analyst:TMB

ICal Workgroup:

8260BMethod:



QUCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 95





5308759PDF File ID:





%D Limit %D

RF

9M978927

WG603526

Instrument ID:HPMS9

File ID:

Run Date:02/21/2017

Run Time:01:23

Analyst:ADC

ICal Workgroup:

8260BMethod:


21-FEB-17HPMS9 -Cal ID:

QUCLUnits

QC Key:STD

Page 96





5308759PDF File ID:



Chloroform

1,1-Dichloroethene

1,2-Dichloropropane

Ethylbenzene

Toluene

Vinyl Chloride

Bromoform

Chlorobenzene

Chloromethane

1,1-Dichloroethane


Acetone

Benzene

Bromobenzene

Bromochloromethane

Bromodichloromethane

Bromomethane

2-Butanone

n-Butylbenzene

sec-Butylbenzene

tert-Butylbenzene

Carbon Disulfide


Dibromochloromethane

Chloroethane

2-Chloroethyl Vinyl Ether

2-Chlorotoluene

4-Chlorotoluene

1,2-Dibromo-3-Chloropropane

1,2-Dibromoethane

Dibromomethane

1,2-Dichlorobenzene

1,3-Dichlorobenzene

1,4-Dichlorobenzene

Dichlorodifluoromethane

1,2-Dichloroethane

cis-1,2-Dichloroethene

trans-1,2-Dichloroethene

1,3-Dichloropropane

2,2-Dichloropropane

cis-1,3-Dichloropropene

trans-1,3-Dichloropropene

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

21.3

21.5

21.3

22.0

22.4

22.6

17.7

21.7

24.9

20.6

21.4

17.9

21.9

22.6

21.3

20.3

28.6

19.4

23.4

23.0

23.1

15.6

21.5

19.4

22.2

20.6

20.1

26.2

18.9

21.5

21.1

22.1

22.3

22.2

32.8

21.2

21.9

21.6

22.5

21.6

22.7

20.0

0.463

0.442

0.298

0.556

1.54

0.247

0.261

1.04

0.414

0.512

0.934

0.144

1.04

0.949

0.176

0.329

0.240

0.191

3.09

3.88

0.684

0.593

0.358

0.359

0.202

0.178

2.45

2.72

0.242

0.344

0.178

1.82

1.86

1.94

0.455

0.414

0.288

0.428

0.578

0.387

0.428

0.510

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

6.60

7.50

6.70

9.90

11.8

12.8

11.3

8.40

24.4

2.80

6.90

10.5

9.40

12.8

6.40

1.60

43.0

3.20

16.8

14.9

15.5

22.0

7.40

3.10

11.1

3.00

0.400

31.0

5.40

7.30

5.60

10.6

11.5

11.2

63.9

5.80

9.50

7.80

12.3

8.20

13.7

0

Analyte Expected Found %DRF

9M980442

WG615237

Instrument ID:HPMS9

File ID:

Run Date:05/23/2017

Run Time:15:46

Analyst:ADC

ICal Workgroup:

8260BMethod:



Q

*

*

*

*

*

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 97





5308759PDF File ID:




1,1-Dichloropropene

2-Hexanone

Hexachlorobutadiene

Isopropylbenzene

p-Isopropyltoluene

4-Methyl-2-Pentanone

Methylene Chloride

Naphthalene

n-Propylbenzene

Styrene


Tetrachloroethene





Trichloroethene





Vinyl Acetate

o-Xylene

m-,p-Xylene

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

40.0

22.1

17.0

21.8

21.6

23.1

19.4

21.6

22.9

24.3

21.9

21.4

22.5

22.4

22.9

22.9

21.5

21.9

21.3

21.4

23.9

23.4

24.6

22.8

45.3

0.362

0.309

0.681

1.68

3.25

0.137

0.289

3.75

4.28

1.10

0.368

0.335

1.40

1.41

0.424

0.332

0.289

0.422

0.301

3.13

2.97

0.740

0.680

0.691

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

10.3

14.9

8.80

7.90

15.7

3.00

8.00

14.4

21.3

9.40

6.80

12.7

11.8

14.7

14.5

7.60

9.30

6.30

7.20

19.7

17.0

22.8

14.0

13.1


* Exceeds

%D

Limit %D

RF

9M980442

WG615237

Instrument ID:HPMS9

File ID:

Run Date:05/23/2017

Run Time:15:46

Analyst:ADC

ICal Workgroup:

8260BMethod:



Q

*

*

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 98



INTERNAL STANDARD AREA SUMMARY(COMPARED TO CCV)

INTERNAL_STD - Modified 03/06/2008



L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615095-01

WG615282-01

WG615282-02

WG615282-03

DL01

DL01

DL01

DL01

DL01

DL01

DL01

01

01

01

1 2 3

120312 229454 333775

117025 219558 318324

111321 213585 310490

111638 216952 314074

110236 217936 316529

112674 216605 311211

108085 213852 304757

119737 245509 352411

138533 255705 360756

141367 254883 357421

164010 287882 396075WG615277-02

328020 575764 792150

82005 143941 198038

Upper Limit

Lower Limit

Sample Number Dilution Tag

10.0

10.0

10.0

10.0

10.0

10.0

10.0

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-

1,4-Dichlorobenzene-d4

Chlorobenzene-d5

Fluorobenzene

WG615277-02CCV Number:

HPMS11Instrument ID:


TCLPMatrix:WG615282Workgroup (AAB#):

Underline = Response outside limits

HPMS11CAL ID:

IS- IS- IS-

IS-

IS-

IS-

-16-MAY-17

Page 99







L17051231-01

WG615278-01

WG615405-01

WG615405-02

WG615405-03

WG615405-04

DL01

DL01

01

01

01

01

1 2 3

290931 588362 720960

225844 459348 566858

275456 564667 695797

307106 595987 732592

318801 615097 750399

238600 496486 615842

318339 604742 745295WG615404-02

636678 1209484 1490590

159170 302371 372648

Upper Limit

Lower Limit


10.0

10.0

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene


HPMS8Instrument ID:




HPMS8CAL ID:

IS- IS- IS-

IS-

IS-

IS-

-17-APR-17

Page 100







L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615221-02

WG615221-03

WG615352-01

WG615352-02

01

01

01

01

01

01

01

01

01

01

01

1 2 3

183633 522816 830438

196549 494619 765999

210820 493003 732999

227405 560554 846320

149494 443488 726347

172098 449942 708037

294074 601340 861697

200812 483425 735399

217876 531450 816934

312747 634941 887685

280863 553971 778891

299797 575431 784465WG615237-07

599594 1150862 1568930

149899 287716 392233

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene


HPMS9Instrument ID:


SOLIDMatrix:WG615352Workgroup (AAB#):


HPMS9CAL ID:

IS- IS- IS-

IS-

IS-

IS-

-23-MAY-17

Page 101



INTERNAL STANDARD RETENTION TIME SUMMARY(COMPARED TO CCV)

INTERNAL_STD_RT - Modified 03/06/2008



L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615095-01

WG615282-01

WG615282-02

WG615282-03

DL01

DL01

DL01

DL01

DL01

DL01

DL01

01

01

01

1 2 3

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49

16.94 14.12 10.49WG615277-02

17.44 14.62 10.99

16.44 13.62 9.99

Upper Limit

Lower Limit


10.0

10.0

10.0

10.0

10.0

10.0

10.0

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene






IS- IS- IS-

IS-

IS-

IS-


Page 102







L17051231-01

WG615278-01

WG615405-01

WG615405-02

WG615405-03

WG615405-04

DL01

DL01

01

01

01

01

1 2 3

17.82 14.79 10.91

17.82 14.79 10.92

17.82 14.79 10.91

17.82 14.79 10.92

17.81 14.79 10.92

17.82 14.79 10.91

17.82 14.79 10.92WG615404-02

18.32 15.29 11.42

17.32 14.29 10.42

Upper Limit

Lower Limit


10.0

10.0

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene


HPMS8Instrument ID:




IS- IS- IS-

IS-

IS-

IS-


Page 103







L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615221-02

WG615221-03

WG615352-01

WG615352-02

01

01

01

01

01

01

01

01

01

01

01

1 2 3

17.63 14.6 10.73

17.64 14.61 10.73

17.64 14.61 10.73

17.64 14.61 10.73

17.63 14.6 10.74

17.63 14.61 10.73

17.63 14.6 10.73

17.64 14.61 10.73

17.63 14.61 10.73

17.64 14.61 10.73

17.64 14.61 10.73

17.63 14.61 10.73WG615237-07

18.13 15.11 11.23

17.13 14.11 10.23

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene


HPMS9Instrument ID:




IS- IS- IS-

IS-

IS-

IS-


Page 104



Instrument Run Log

Run Log ID:80588

Page: 1

Approved: February 24, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS9

ADC

8260

022017

NA

MSV01 24

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD80448

STD80322

STD80112

STD80191 STD80191

WG603477, WG603526

Column 1 ID: Column 2 ID:RTX502.2 NA

Method: SOP: Rev:5035/ 5030B/ 5030C PAT01 19

9M978905

9M978906

9M978907

9M978908

9M978909

9M978910

9M978911

9M978912

9M978913

9M978914

9M978915

9M978916

9M978917

9M978918

9M978919

9M978920

9M978921

9M978922

9M978923

9M978924

9M978925

9M978926

9M978927

9M978928

WG603477-01 BFB 50ng 8260

RINSE

WG603477-02 0.5ug/L STD 8260

WG603477-03 1.0ug/L STD 8260

WG603477-04 2.0ug/L STD 8260

WG603477-05 5.0ug/L STD 8260

WG603477-06 20.0ug/L STD 8260

WG603477-07 50.0ug/L STD 8260

WG603477-08 100.0ug/L STD 8260

WG603477-09 200.0ug/L STD 8260

WG603477-10 300.0ug/L STD 8260

RINSE

WG603477-11 50.0ug/L STD 8260

WG603526-01 5ug/kg A9FOO



WG603526-04 100ug/kg A9FOO

WG603526-05 200ug/kg A9FOO

WG603526-06 300ug/kg A9FOO

WG603526-07 400ug/kg A9FOO

WG603526-08 500ug/kg A9FOO

RINSE

WG603526-09 100ug/kg A9FOO ALT SRC

mix 2 check

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD79950

STD80322

STD80322

STD80322

STD80322

STD80322

STD80322

STD80322

STD80322

STD80322

STD80191

STD80557

STD80557

STD80557

STD80557

STD80557

STD80557

STD80557

STD80557

STD80470

STD80470

02/20/17 14:09

02/20/17 14:34

02/20/17 15:05

02/20/17 15:36

02/20/17 16:07

02/20/17 16:38

02/20/17 17:10

02/20/17 17:41

02/20/17 18:12

02/20/17 18:44

02/20/17 19:15

02/20/17 19:46

02/20/17 20:17

02/20/17 20:48

02/20/17 21:19

02/20/17 21:50

02/20/17 22:21

02/20/17 22:51

02/20/17 23:21

02/20/17 23:52

02/21/17 00:22

02/21/17 00:53

02/21/17 01:23

02/21/17 12:39

File ID Sample Information Dil Reference Date/TimeMat

7

1

7

7

7

7

7

7

7

7

7

1

7

7

7

7

7

7

7

7

7

7

7

7

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Comments:

Maintenance Log ID:

Page 105



Instrument Run Log

Run Log ID:81580

Page: 1

Approved: April 18, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS8

TMB

8260B

041217

NA

MSV01/OVAP MSV01 24/0

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81235

STD81397

STD81235

STD81404 NA

WG609829


Method: SOP: Rev:5030B/5030C/5035A PAT01/OVAP PAT01 18/1

Method: SOP: Rev:624 MSV10 15

8M418914

8M418915

8M418916

8M418917

8M418918

8M418919

8M418920

8M418921

8M418922

8M418923

8M418924

8M418925

8M418926

8M418927

8M418928

WG609829-01 50ng BFB STD 8260

RINSE

WG609829-02 5ug/L STD A9/FOO








RINSE

RINSE

WG609829-10 100ug/L ALT SRC STD A9/FO

WG609948-01 50ug/L CCV STD 8260

RINSE

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD80989

STD80989

STD81397

STD81397

STD81397

STD81397

STD81397

STD81397

STD81397

STD81397

STD81404

STD81377

04/12/17 10:17

04/12/17 10:42

04/12/17 11:11

04/12/17 11:40

04/12/17 12:10

04/12/17 12:41

04/12/17 13:10

04/12/17 13:40

04/12/17 14:10

04/12/17 14:39

04/12/17 15:09

04/12/17 15:39

04/12/17 16:10

04/12/17 16:39

04/12/17 17:09


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Comments:

Maintenance Log ID: 54128

Page 106



Instrument Run Log

Run Log ID:81593

Page: 1

Approved: April 20, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS8

TMB

8260B

041717

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81235

STD81447

STD81235

STD81461 NA

WG610410

2

3

4

X

X

Comments



Method: SOP: Rev:5030B/5030C/5035A PAT01 18/1


8M418996

8M418997

8M418998

8M418999

8M419000

8M419001

8M419002

8M419003

8M419004

8M419005

8M419006

8M419007

8M419008

8M419009

8M419010

8M419011

8M419012

8M419013

8M419014

8M419015

WG610373-01 50ng BFB STD 8260

WG610373-02 50ug/L CCV STD 8260

WG610373-02 50ug/L CCV STD 8260

WG000000-01 100ug/L A9 CCV STD 8260

WG610410-01 50ng BFB STD 8260

RINSE

WG610410-02 0.3ug/L STD 8260

WG610410-03 0.4ug/L STD 8260

WG610410-04 1ug/L STD 8260

WG610410-05 2ug/L STD 8260

WG610410-06 5ug/L STD 8260

WG610410-07 20ug/L STD 8260

WG610410-08 50ug/L STD 8260

WG610410-09 100ug/L STD 8260

WG610410-10 200ug/L STD 8260

WG610410-11 300ug/L STD 8260

RINSE

RINSE

WG610410-12 50ug/L ALT SRC STD 8260

RINSE

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD80989

STD81375

STD81375

STD81397

STD80989

STD81447

STD81447

STD81447

STD81447

STD81447

STD81447

STD81447

STD81447

STD81447

STD81447

STD81461

04/17/17 09:44

04/17/17 10:10

04/17/17 10:42

04/17/17 11:13

04/17/17 12:58

04/17/17 13:21

04/17/17 13:51

04/17/17 14:25

04/17/17 14:55

04/17/17 15:25

04/17/17 15:54

04/17/17 16:24

04/17/17 16:54

04/17/17 17:23

04/17/17 17:54

04/17/17 18:24

04/17/17 18:53

04/17/17 19:23

04/17/17 19:53

04/17/17 20:23


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Bromomethane was low, DNR.

Bromomethane and iodomethane were low, DNR.

Not needed, DNR.

Comments:

8M418997

8M418998

8M418999

File ID:

File ID:

File ID:


Page 107



Instrument Run Log

Run Log ID:81984

Page: 1

Approved: May 09, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS11

ADC

8260

050317

NA

MSV01, OVAP MSV01 24,0

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81442

STD81698/STD81708

STD81441

STD81656/STD81640 NA

WG612363 WG612759

14 X

Comments



Method: SOP: Rev:5035/ 5030B/ 5030C PAT01, OVAP PAT01 18,1


11M17986

11M17987

11M17988

11M17989

11M17990

11M17991

11M17992

11M17993

11M17994

11M17995

11M17996

11M17997

11M17998

11M17999

11M18000

11M18001

11M18002

11M18003

11M18004

11M18005

11M18006

11M18007

11M18008

11M18009

11M18010

11M18011

WG612363-01 50ng BFB STD 8260

RINSE

WG612363-02 .3ug/L CCV ICAL 8260

WG612363-03 .4ug/L CCV ICAL 8260

WG612363-04 1ug/L CCV ICAL 8260

WG612363-05 2ug/L CCV ICAL 8260

WG612363-06 5ug/L CCV ICAL 8260

WG612363-07 20ug/L CCV ICAL 8260

WG612363-08 50ug/L CCV ICAL 8260

WG612363-09 100ug/L CCV ICAL 8260

WG612363-10 200ug/L CCV ICAL 8260

WG612363-11 300ug/L CCV ICAL 8260

RINSE

WG612363-12 50ug/L ICV 8260

WG612363-12 20ug/L ICV 8260

WG612759-01 BFB 50ng A9FOO

WG612759-02 5ug/L STD A9FOO








RINSE


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD81491

STD81698

STD81698

STD81698

STD81698

STD81698

STD81698

STD81698

STD81698

STD81698

STD81698

STD81656

STD81656

STD81491

STD81708

STD81708

STD81708

STD81708

STD81708

STD81708

STD81708

STD81708

STD81640

05/03/17 10:28

05/03/17 10:52

05/03/17 11:21

05/03/17 11:50

05/03/17 12:19

05/03/17 12:48

05/03/17 13:17

05/03/17 13:46

05/03/17 14:15

05/03/17 14:44

05/03/17 15:13

05/03/17 15:42

05/03/17 16:11

05/03/17 16:40

05/03/17 17:47

05/03/17 19:14

05/03/17 19:42

05/03/17 20:10

05/03/17 20:39

05/03/17 21:08

05/03/17 21:36

05/03/17 22:05

05/03/17 22:34

05/03/17 23:02

05/03/17 23:31

05/04/17 00:00


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

WG612363-12 ICV had multiple failures. RR at 20ppb.

Comments:

11M17999File ID:

Maintenance Log ID:

Page 108



Instrument Run Log

Run Log ID:82278

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS11

ADC

8260B

051617

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81876

STD81698

STD81877

STD81861 STD81861

WG614378 (ICAL)




11M18429

11M18430

11M18431

11M18432

11M18433

11M18434

11M18435

11M18436

11M18437

11M18438

11M18439

11M18440

11M18441

11M18442

WG614378-01 BFB 50ng 8260

RINSE

WG614378-02 0.3ug/L CCV 8260

WG614378-03 0.4ug/L CCV 8260

WG614378-04 1.0ug/L CCV 8260

WG614378-05 2.0ug/L CCV 8260

WG614378-06 5.0ug/L CCV 8260

WG614378-07 20.0ug/L CCV 8260

WG614378-08 50.0ug/L CCV 8260

WG614378-09 100.0ug/L CCV 8260

WG614378-10 200.0ug/L CCV 8260

WG614378-11 300.0ug/L CCV 8260

RINSE

WG614378-12 20.0ug/L ALT 8260

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD81491

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81881

05/16/17 12:01

05/16/17 12:25

05/16/17 12:54

05/16/17 13:23

05/16/17 13:52

05/16/17 14:21

05/16/17 14:50

05/16/17 15:20

05/16/17 15:49

05/16/17 16:18

05/16/17 16:47

05/16/17 17:16

05/16/17 17:45

05/16/17 18:14


1

1

1

1

1

1

1

1

1

1

1

1

1

1

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Comments:

Maintenance Log ID:

Page 109



Instrument Run Log

Run Log ID:82377

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS9

ADC

8260

052317

NA

MSV01,OVAP MSV01 24,0

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81876

STD81880

STD81877

STD81881 STD81881

WG615352

20

Comments



Method: SOP: Rev:5035/ 5030B/ 5030C PAT01, OVAP PAT01 19, 0

9M980430

9M980431

9M980432

9M980433

9M980434

9M980435

9M980436

9M980437

9M980438

9M980439

9M980440

9M980441

9M980442

9M980443

9M980444

9M980445

9M980446

9M980447

9M980448

9M980449

9M980450

9M980451

9M980452

9M980453

9M980454

9M980455

9M980456

9M980457

WG615237-01 50ng BFB

RINSE

WG615237-02 0.5ug/kg STD8260

WG615237-03 1.0ug/kg STD8260

WG615237-04 2.0ug/kg STD8260

WG615237-05 5.0ug/kg STD8260

WG615237-06 20.0ug/kg STD8260

WG615237-07 50.0ug/kg STD8260

WG615237-08 100.0ug/kg STD8260

WG615237-09 200.0ug/kg STD8260

WG615237-10 300.0ug/kg STD8260

RINSE

WG615237-11 20.0ug/kg ALT8260

RINSE

WG615352-01 BLK 8260

WG615352-02 20ug/kg LCS 8260

L17051231-04 A 826-SPE

L17051231-06 A 826-SPE

L17051231-08 A 826-SPE

L17051231-10 A 826-SPE

L17051231-12 A 826-SPE

L17051231-14 A 826-SPE

WG615221-01 L17051231-02 A 826-SPE

WG615221-02 MS A 826-SPE

WG615221-03 MSD A 826-SPE

RINSE

RINSE

TEST CCV

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD81491

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81880

STD81881

STD81881

STD81881

STD81881

STD81881

STD81881

05/23/17 09:48

05/23/17 10:17

05/23/17 10:46

05/23/17 11:16

05/23/17 11:46

05/23/17 12:17

05/23/17 12:47

05/23/17 13:16

05/23/17 13:47

05/23/17 14:16

05/23/17 14:46

05/23/17 15:16

05/23/17 15:46

05/23/17 16:16

05/23/17 16:46

05/23/17 17:16

05/23/17 17:46

05/23/17 18:16

05/23/17 18:47

05/23/17 19:17

05/23/17 19:47

05/23/17 20:17

05/23/17 20:47

05/23/17 21:17

05/23/17 21:47

05/23/17 22:17

05/23/17 22:47

05/24/17 08:46


7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

7

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

NA

pH

Comments:

9M980449File ID:

Maintenance Log ID:

Page 110



Instrument Run Log

Run Log ID:82377

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS9

ADC

8260

052317

NA

MSV01,OVAP MSV01 24,0

Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81876

STD81880

STD81877

STD81881 STD81881

WG615352

Comments



Method: SOP: Rev:5035/ 5030B/ 5030C PAT01, OVAP PAT01 19, 0

L17051231-10 ISTD and SSTD failure are obvious SMI as is evident in lower ISTD response in other samples with similar HC.

Comments:

Maintenance Log ID:

Page 111



Instrument Run Log

Run Log ID:82361

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS11

TMB

8260

052317

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD82876

STD81983, STD81708

STD82877

STD82009, STD81742 STD82009

WG615282, WEG615296



Method: SOP: Rev:5035, 5030B, 5030C PAT01, OVAP PAT01 19,0

11M18562

11M18563

11M18564

11M18566

11M18567

11M18568

11M18569

11M18570

11M18571

11M18572

11M18575

11M18576

11M18577

11M18578

11M18579

11M18580

11M18581

11M18582

11M18583

11M18584

11M18585

11M18586

11M18587

11M18588

11M18589

11M18590

11M18591

11M18592

11M18593

11M18594

11M18595

11M18596

11M18597

11M18598

WG615277-01 50ng BFB STD 8260

WG615277-01 50ng BFB STD 8260

WG615277-02 50ug/L CCV STD 8260

WG615279-01 100ug/L CCV 826-A9

WG615282-01 BLANK 8260

WG615282-02 20ug/L LCS 8260

WG615282-03 20ug/L LCS2 8260

WG615282-04 20ug/L LCS A9 8260

WG615282-05 20ug/L LCS2 A9 8260

L17051074-01 C 00 2X 826-SPE

L17051074-03 C 00 5X 826-SPE

L17051074-01 C 00 2X 826-SPE

L17051074-05 C 00 2X 826-SPE

L17051231-01 10X AF 826-TC

L17051231-03 10X AF 826-TC

L17051231-05 10X AF 826-TC

L17051231-07 10X AF 826-TC

L17051231-09 10X AF 826-TC

L17051231-11 10X AF 826-TC

L17051231-13 10X AF 826-TC

L17051242-01 A TB 826-A9-SPE

L17051179-03 B A1 826-A9-SPE

L17050625-02 B 826-VAP2

L17051242-02 A 826-A9-SPE

L17051242-03 A 826-A9-SPE

L17051242-05 A ER 826-A9-SPE

RINSE

WG615296-01 20ug/L LCS 624

WG615296-02 20ug/L LCS 624

RINSE

WG615296-03 BLANK 624

L17051246-01 A 624-SPE

L17051272-01 A 624

L17051272-02 A 624

1

1

1

1

1

1

1

1

1

2

5

2

2

10

10

10

10

10

10

10

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD81972

STD81972

STD81983

STD81708

STD82009

STD82009

STD81742

STD81742

STD82009

STD82009

05/23/17 11:51

05/23/17 12:03

05/23/17 12:27

05/23/17 13:08

05/23/17 13:37

05/23/17 14:06

05/23/17 14:35

05/23/17 15:04

05/23/17 15:33

05/23/17 16:02

05/23/17 16:35

05/23/17 17:27

05/23/17 17:56

05/23/17 18:25

05/23/17 18:54

05/23/17 19:23

05/23/17 19:52

05/23/17 20:20

05/23/17 20:49

05/23/17 21:18

05/23/17 21:47

05/23/17 22:16

05/23/17 22:45

05/23/17 23:14

05/23/17 23:43

05/24/17 00:12

05/24/17 00:41

05/24/17 01:10

05/24/17 01:39

05/24/17 02:08

05/24/17 02:37

05/24/17 03:06

05/24/17 03:34

05/24/17 04:03


1

1

1

1

1

1

1

1

1

1

1

1

1

17

17

17

17

17

17

17

1

1

1

1

1

1

1

2

2

2

2

2

2

2

NA

NA

NA

NA

NA

NA

NA

NA

NA

<2

<2

<2

<2

NA

NA

NA

NA

NA

NA

NA

<2

<2

<2

<2

<2

<2

NA

NA

NA

NA

NA

<2

6

5

pH

Comments:

Maintenance Log ID:

Page 112



Instrument Run Log

Run Log ID:82361

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS11

TMB

8260

052317

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD82876

STD81983, STD81708

STD82877

STD82009, STD81742 STD82009

WG615282, WEG615296

10

23

26 X

Comments

Seq. Rerun Dil. Analytes

Missed Tune

Reason



Method: SOP: Rev:5035, 5030B, 5030C PAT01, OVAP PAT01 19,0

11M18599

11M18600

11M18601

11M18602

11M18603

11M18604

RINSE

L17051151-01 B 00 2X 624-SPE

CCV

RINSE

RINSE

WG615095-01 FBLK 10X AF 826-TC

1

2

1

1

1

10

05/24/17 04:32

05/24/17 05:02

05/24/17 05:31

05/24/17 06:01

05/24/17 06:30

05/24/17 06:59


2

2

1

1

1

17

NA

<2

NA

NA

NA

NA

pH

L17051074-01 SOFTWARE ERROR, RERUN VIAL IMMEDIATELY.

L17050625-02 NOT NEEDED DNR.

L17051242-05 DNR

Comments:

11M18572

11M18587

11M18590

File ID:

File ID:

File ID:

Maintenance Log ID:

Page 113



Instrument Run Log

Run Log ID:82387

Page: 1



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS8

TMB

8260B

052417

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81815

STD81983

STD81815

STD82009 STD82009

WG615405

Comments





8M419868

8M419869

8M419870

8M419871

8M419872

8M419873

8M419874

8M419875

8M419876

8M419877

8M419878

8M419879

8M419880

8M419881

8M419882

8M419883

8M419884

8M419885

8M419886

8M419887

8M419888

8M419889

8M419890

8M419891

8M419892

8M419893

8M419894

8M419895

8M419896

8M419897

WG615404-01 50ng BFB STD 8260

WG615404-02 50ug/L CCV STD 8260

WG000000-01 100ug/L A9 CCV STD 8260

WG615405-01 VBLK0524 BLANK STD 826

WG615405-02 20ug/L LCS STD 8260

WG615405-03 20ug/L LCS2 STD 8260

L17051231-01 B 10X 826-TC

L17051257-01 A 10X 826-TC

L17051257-02 A 10X 826-TC

L17051284-10 A 826-LOW

L17051284-11 A 826-LOW

L17051307-01 A 10X 826-TC

L17051310-03 A TB 826-BETX

L17051310-01 A 826-BETX

L17051311-01 A 826-BETX

L17051312-01 A 826-BETX

WG615405-04 VBLK0524 BLANK STD 624

L17051284-01 B 624-SPE

L17051284-02 B 624-SPE

L17051284-03 B 624-SPE

L17051284-04 B 624-SPE

L17051284-05 B 624-SPE

L17051284-06 B 624-SPE

L17051284-07 B 624-SPE

L17051284-08 B 624-SPE

L17051284-09 B 624-SPE

WG615278-01 A FBLK 10X 826-TC

WG615405-06 A MS 1257-01 10X 826-TC

CCV

RINSE

1

1

1

1

1

1

10

10

10

1

1

10

1

1

1

1

1

1

1

1

1

1

1

1

1

1

10

10

1

1

STD81972

STD81983

STD81708

STD82009

STD82009

STD82009

05/24/17 11:36

05/24/17 11:59

05/24/17 12:28

05/24/17 12:57

05/24/17 13:25

05/24/17 13:53

05/24/17 14:22

05/24/17 14:50

05/24/17 15:19

05/24/17 15:49

05/24/17 16:17

05/24/17 16:46

05/24/17 17:14

05/24/17 17:42

05/24/17 18:11

05/24/17 18:39

05/24/17 19:08

05/24/17 19:36

05/24/17 20:05

05/24/17 20:33

05/24/17 21:02

05/24/17 21:30

05/24/17 21:59

05/24/17 22:29

05/24/17 22:57

05/24/17 23:26

05/24/17 23:54

05/25/17 00:23

05/25/17 00:51

05/25/17 01:21


1

1

1

1

1

1

17

1

17

2

2

17

1

1

1

1

2

2

2

2

2

2

2

2

2

2

17

17

1

1

NA

NA

NA

NA

NA

NA

5

5

5

<2

<2

5

<2

<2

<2

<2

NA

<2

<2

<2

<2

<2

<2

<2

<2

<2

4

NA

NA

NA

pH

Comments:


Page 114



Instrument Run Log

Run Log ID:82387

Page: 2



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS8

TMB

8260B

052417

NA


Internal Standard:

CCV:

Surrogate Standard:

LCS: MS/MSD:

Workgroups:

STD81815

STD81983

STD81815

STD82009 STD82009

WG615405

3

Comments





Not needed, DNR.

Comments:

8M419870File ID:


Page 115



VOA Preparation/Preservation/Extraction Log

VOA_EXT - Modified 05/22/2008 PDF ID:Report generated: 05/23/2017 09:29


5305888

WG615221

Run Date:05/23/2017 09:14

Analyst:JSTBatch #:

L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615221-01

WG615221-02

WG615221-03

SAMPLE # Fraction

A

A

A

A

A

A

A

A

A

A

Preserved

5.16

5.00

4.98

5.04

5.18

5.17

5.07

5.16

5.17

5.06

50.0

45.2

49.0

26.5

41.6

56.8

1.96

50.0

50.0

50.0

Sample Wt Water

5

5

5

5

5

5

5

5

5

5

Method:5030B/5030C/5035

PCT-S Tare Wt Total Wt

05/23/17 09:14

05/23/17 09:15

05/23/17 09:20

05/23/17 09:22

05/23/17 09:23

05/23/17 09:25

05/23/17 09:28

05/23/17 09:15

05/23/17 09:15

05/23/17 09:16

Collected

05/19/17 13:24

05/19/17 15:00

05/19/17 14:45

05/19/17 15:30

05/19/17 16:18

05/19/17 16:30

05/19/17 17:12

MeOH CommentsVt

5

5

5

5

5

5

5

5

5

5

Comments:1 = improperly sealed cap2 = preserved out of hold

3 = effervesced4 = preserved with NaHSO4

5 = preserved by freezing6 = preserved in field

Analyst:

COA19469

COA18552

Purge and trap methanol

Purified Lab Sand Lot #

Product:8260

Page 116







14G67536

05/16/17 11:21

05/16/17 14:27

WG614544

WG614301-01

HP14

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8015CMethod:

LJHAnalyst:


LCS

LCS2


17-0751 IR MUD SILO




WG614301-02

WG614301-03

L17050904-03

L17050904-01

L17050904-04

L17050904-05

L17050904-02

14G67537

14G67538

14G67540

14G67541

14G67542

14G67543

14G67544

05/16/17 15:06

05/16/17 15:45

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41



01

01

01

01

01

01

01

Page 119




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5297723

17-MAY-2017 10:07

o-Terphenyl

Octacosane

69.6

62.6


43

25

-

-

136

162

Qualifier

PASS

PASS


Diesel Range (C10-C28) 12500 10000 J3900



14G67536

WG614544

Instrument ID:HP14

File ID:

Prep Date:05/16/17 11:21

Run Date:05/16/17 14:27

Analyst:LJH


8015CMethod:

SoilMatrix:



3546Prep Method:

MDL RL

MDL

RL



Page 120








LCS LCS2

4.13137000 143000

Analytes %RPD

250000 250000


54.9 57.2

% REC % REC

26

RPDLmt

%RecLimits

35 120-

Q

Sample ID:

Sample ID:

WG614301-02

WG614301-03

LCS

LCS2

14G67537

14G67538

File ID:

File ID:

o-Terphenyl

Octacosane

LCS LCS2

69.7 73.4

68.2 74.9


Surrogate Limits

43

25

136

162

-

-

Qualifier

PASS

PASS

Run Date:

Run Date:

05/16/2017 15:06

05/16/2017 15:45

WG614544

Instrument ID:HP14

Analyst:LJH





# EXCEEDS RPD LIMIT


Page 121





SURROGATE STANDARDS


L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

-

-

o-Terphenyl

Octacosane

8015Method:

HP14Instrument Id:




26.2 36.2

12.6 9.41

53.4 52.3

30.9 30.4

39.5 34.6

69.6 62.6

69.7 68.2

73.4 74.9

43

25

-

-

136

162





Page 122




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5308023

25-MAY-2017 09:27

2,4,6-Tribromophenol

2-Fluorobiphenyl

2-Fluorophenol

Nitrobenzene-d5

p-Terphenyl-d14

Phenol-d5

105

85.6

72.2

88.2

97.5

74.0


19

30

25

23

18

24

-

-

-

-

-

-

122

115

121

120

137

113

Qualifier

PASS

PASS

PASS

PASS

PASS

PASS


Chrysene

Di-N-Butylphthalate

Di-n-octylphthalate

Dibenzo(a,h)Anthracene

Dibenzofuran

Diethylphthalate

Dimethylphthalate

Fluoranthene

Fluorene

Hexachlorobenzene

Hexachlorobutadiene

Hexachlorocyclopentadiene

Hexachloroethane

Indeno(1,2,3-cd)pyrene

Isophorone

Diphenylamine/n-Nitrosodiphenylamine

N-Nitrosodipropylamine

Naphthalene

Nitrobenzene

Pentachlorophenol

Phenanthrene

Phenol

Pyrene

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

375

82.5

82.5

82.5

82.5

82.5

82.5

82.5

412

82.5

82.5

82.5

165

165

165

165

165

165

165

165

165

165

165

750

165

165

165

165

165

165

165

825

165

165

165

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

U

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

82.5

375

82.5

82.5

82.5

82.5

82.5

82.5

82.5

412

82.5

82.5

82.5



12M62299

WG615227


File ID:

Prep Date:05/22/17 11:48

Run Date:05/23/17 11:25

Analyst:SCB


8270CMethod:

SoilMatrix:


10-APR-17Cal ID:HPMS12-OT900917Contract #:

3546Prep Method:

MDL RL

MDL

RL



Page 123







Diesel Range (C10-C28) 1000000 1040000 53300 4.46


* Exceeds

%D

Criteria %D

RF

14G67546

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:20:59

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 124







Page 125



LCS - Modified 03/06/2008




9M980445

WG615352

Instrument ID:HPMS9

File ID:

Run Date:05/23/2017

Run Time:17:16

Analyst:ADC



SoilMatrix:


Analytes Expected Found LCS Limits Q% Rec



Toluene-d8


105

103

108

109


80

80

81

74

-

-

-

-

120

120

117

121

Qualifier

PASS

PASS

PASS

PASS

WG615352-02Sample ID:

23-MAY-17Cal ID: HPMS9-STDQC Key:

Hexachlorobutadiene

Isopropylbenzene

p-Isopropyltoluene

4-Methyl-2-pentanone

Methylene chloride

Naphthalene

n-Propylbenzene

Styrene



Tetrachloroethene

Toluene





Trichloroethene





Vinyl acetate

Vinyl chloride

o-Xylene

m-,p-Xylene

65

68

72

47

74

50

72

74

71

55

72

77

60

65

70

60

72

48

65

75

74

10

45

70

70

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

40.0

21.5

21.4

22.2

20.6

23.2

25.7

23.6

22.4

22.2

23.2

22.1

23.0

23.7

22.8

22.2

23.3

21.4

21.2

23.4

23.4

23.2

25.9

25.7

22.9

45.5

108

107

111

103

116

129

118

112

111

116

110

115

119

114

111

117

107

106

117

117

116

130

129

115

114

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

-

135

129

128

146

128

146

136

130

137

130

130

126

135

130

135

125

126

154

130

132

133

150

140

130

130

8260BMethod:


Lot#:STD81766

Page 126







1,1-Dichloroethene

1,2-Dichloroethane

Methyl Ethyl Ketone

Benzene


Chlorobenzene

Chloroform

Tetrachloroethene

Trichloroethene

Vinyl chloride

LCS LCS2

4.01

1.54

5.32

2.70

2.37

2.22

2.08

0.870

1.31

0.804

20.1 20.9

20.8 21.1

18.6 19.6

21.1 21.6

20.4 20.9

21.2 21.7

18.9 19.3

21.4 21.6

20.6 20.8

21.8 22.0

Analytes %RPD

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0


100 105

104 105

93.0 98.1

105 108

102 105

106 108

94.3 96.3

107 108

103 104

109 110

% REC % REC

20

20

20

20

20

20

20

20

20

20

RPDLmt

%RecLimits

80

80

10

80

65

80

80

80

80

50

132

129

170

121

140

120

125

124

122

170

-

-

-

-

-

-

-

-

-

-

Q

Sample ID:

Sample ID:

WG615282-02

WG615282-03

LCS

LCS2

11M18568

11M18569

File ID:

File ID:




Toluene-d8

LCS LCS2

105 107

101 106

106 106

107 108


Surrogate Limits

80

86

86

88

120

118

115

110

-

-

-

-

Qualifier

PASS

PASS

PASS

PASS

Run Date:

Run Date:

05/23/2017 14:06

05/23/2017 14:35

WG615282


Analyst:TMB/JDS





# EXCEEDS RPD LIMIT


Page 127





SURROGATE STANDARDS


L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615091-01

WG615091-02

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6Sample Number Dilution Tag

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

3

4

5

6

-

-

-

-

-

-


2-Fluorobiphenyl

2-Fluorophenol

Nitrobenzene-d5

p-Terphenyl-d14

Phenol-d5

8270Method:





101 77.8 67.6 86.7 92.1 69.3

85.5 84.2 69.3 89.2 80.3 67.6

91.0 83.7 66.8 86.5 76.4 65.4

83.4 81.7 62.9 84.5 75.9 62.2

70.9 57.1 45.1 60.2 79.1 43.6

87.9 82.1 62.5 88.7 77.3 59.8

54.9 64.3 46.1 72.5 68.3 49.0

105 85.6 72.2 88.2 97.5 74.0

84.5 79.7 68.6 81.7 80.9 67.7

19

30

25

23

18

24

-

-

-

-

-

-

122

115

121

120

137

113





Page 128








2,4-Dichlorophenol

2-Nitrophenol

4-Chloro-3-Methylphenol

Acenaphthene

Benzo[a]pyrene

Di-n-Octyl Phthalate

Fluoranthene


Phenol

1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol

2,4,6-Trichlorophenol

2,4-Dinitrophenol

4-Nitrophenol


n-Nitrosodipropylamine

2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

51100

52000

53200

48200

50200

47200

50600

48100

48100

48000

57600

49000

49200

61500

51500

64100

43500

44100

47100

50900

52100

47000

52200

46100

48700

0.280

0.204

0.316

1.25

1.10

1.62

1.15

0.653

1.60

1.47

0.166

0.126

0.386

0.180

0.446

0.279

0.634

0.939

1.35

0.455

0.209

0.555

0.357

1.54

0.391

2.11

3.91

6.32

3.66

0.347

5.63

1.11

3.89

3.76

4.04

15.2

1.94

1.57

22.9

3.04

28.3

13.1

11.9

5.72

1.80

4.28

6.00

4.46

7.73

2.50


* Exceeds

%D

Criteria %D

RF

12M62316

WG615400


File ID:

Run Date:05/24/2017

Run Time:10:05

Analyst:MES

Workgroup (AAB#):

8270CMethod:



UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 129







1,4-Dichlorobenzene


2,4-Dichlorophenol

2-Nitrophenol


Acenaphthene

Benzo[a]pyrene


Fluoranthene

Hexachlorobutadiene


Pentachlorophenol

Phenol

2,4-Dinitrophenol

4-Nitrophenol




1,2-Dichlorobenzene

1,3-Dichlorobenzene


2,4-Dimethylphenol

2,4-Dinitrotoluene

2,6-Dinitrotoluene

2-Chloronaphthalene

2-Chlorophenol

2-Methylnaphthalene

2-Methylphenol

2-Nitroaniline

3,3'-Dichlorobenzidine

3-,4-Methylphenol

3-Nitroaniline

4,6-Dinitro-2-Methylphenol

4-Bromophenyl Phenyl Ether

4-Chloroaniline

4-Chlorophenyl Phenyl Ether

4-Nitroaniline

Acenaphthylene

Anthracene

Benzo[a]anthracene

Benzo[b]fluoranthene

Benzo[ghi]perylene

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49200

50300

49800

50900

53300

47200

51300

47400

50400

56800

48800

50400

48700

64700

53700

59200

40200

50900

47900

50100

49000

47300

50200

49000

47700

50800

50700

45900

53000

51000

50300

47900

59500

52200

53300

49900

48500

46800

48800

48600

48800

52200

1.51

0.395

0.273

0.200

0.316

1.23

1.12

1.63

1.15

0.164

0.663

0.130

1.62

0.190

0.465

0.257

0.595

0.305

1.36

1.56

0.393

0.325

0.448

0.341

1.25

1.54

0.714

0.978

0.377

0.421

1.44

0.411

0.130

0.204

0.115

0.630

0.388

2.00

1.14

1.19

1.22

1.02

1.65

0.588

0.389

1.71

6.53

5.67

2.55

5.26

0.827

13.6

2.39

0.738

2.53

29.4

7.31

18.3

19.7

1.88

4.18

0.244

2.07

5.33

0.306

1.94

4.58

1.59

1.48

8.13

5.97

1.92

0.606

4.17

19.0

4.43

6.68

0.224

2.99

6.49

2.32

2.76

2.39

4.35

Analyte Expected Found Q%DRF

12M62298

WG615227


File ID:

Run Date:05/23/2017

Run Time:10:50

Analyst:SCB

Workgroup (AAB#):

8270CMethod:



UNITS

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 130








Benzo[k]fluoranthene

Benzoic Acid

Benzyl Alcohol

bis(2-Chloroethoxy)methane

bis(2-Chloroethyl)ether

bis(2-Chloroisopropyl)ether

bis(2-Ethylhexyl)phthalate

Butyl Benzyl Phthalate

Chrysene

Di-n-Butyl Phthalate

Dibenz[ah]anthracene

Dibenzofuran

Diethylphthalate

Dimethylphthalate

Fluorene

Hexachlorobenzene

Hexachloroethane

Indeno[1,2,3-cd]pyrene

Isophorone

Naphthalene

Nitrobenzene

Phenanthrene

Pyrene

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

45400

33100

49600

40700

45700

49600

47400

43200

48400

49000

55200

47600

49000

49200

49200

53800

51400

53400

48400

49100

49700

48700

47300

0.991

0.151

0.948

0.392

0.843

1.47

0.920

0.585

1.07

1.38

1.05

1.70

1.48

1.42

1.35

0.216

0.607

1.24

0.606

1.07

0.340

1.10

1.28

9.13

33.7

0.830

18.6

8.51

0.722

5.24

13.6

3.26

2.05

10.3

4.72

1.97

1.63

1.58

7.50

2.75

6.90

3.26

1.86

0.625

2.56

5.31


* Exceeds

%D

Criteria %D

RF

12M62298

WG615227


File ID:

Run Date:05/23/2017

Run Time:10:50

Analyst:SCB

Workgroup (AAB#):

8270CMethod:



UNITS

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

UCL40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 131





5309621PDF File ID:




1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol


2,4-Dinitrophenol


4-Nitrophenol


2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49900

55900

63000

50800

59200

61400

53000

57900

50400

51600

52500

49400

49500

53400

53400

49200

1.53

0.161

0.162

0.398

0.172

0.267

0.459

0.790

1.07

1.47

0.469

0.198

0.585

0.366

1.78

0.395

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

0.300

11.9

26.1

1.60

18.4

22.8

6.00

15.7

0.900

3.20

4.90

1.30

1.00

6.90

6.80

1.60


* Exceeds

%D

Limit %D

RF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

40

30

40

40

40

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 132





5308029PDF File ID:



1,4-Dichlorobenzene


2,4-Dichlorophenol

2-Nitrophenol


Acenaphthene

Benzo[a]pyrene


Fluoranthene

Hexachlorobutadiene


Pentachlorophenol

Phenol

2,4-Dinitrophenol

4-Nitrophenol




1,2-Dichlorobenzene

1,3-Dichlorobenzene


2,4-Dimethylphenol

2,4-Dinitrotoluene

2,6-Dinitrotoluene

2-Chloronaphthalene

2-Chlorophenol

2-Methylnaphthalene

2-Methylphenol

2-Nitroaniline

3-,4-Methylphenol

3-Nitroaniline



4-Chloroaniline


4-Nitroaniline

Acenaphthylene

Anthracene

Benzo[a]anthracene


Benzo[ghi]perylene


CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49900

50800

50900

51800

49900

54800

50100

52800

49600

55900

50600

63000

54300

59200

53000

61400

57900

48700

50300

51600

49200

51000

52500

52000

57000

52600

48200

50400

54800

51600

51900

55500

50600

50700

51300

51400

49800

48500

48600

48600

50700

49700

1.53

0.398

0.279

0.204

0.296

1.42

1.10

1.82

1.13

0.161

0.687

0.162

1.81

0.172

0.459

0.267

0.790

0.291

1.43

1.60

0.395

0.350

0.469

0.361

1.49

1.59

0.678

1.07

0.389

1.47

0.445

0.121

0.197

0.110

0.648

0.410

2.13

1.13

1.19

1.21

0.993

1.09

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

0.300

1.60

1.90

3.70

0.300

9.50

0.300

5.70

0.800

11.9

1.10

26.1

8.50

18.4

6.00

22.8

15.7

2.60

0.600

3.30

1.60

2.00

4.90

3.90

13.9

5.20

3.70

0.900

9.50

3.20

3.90

11.0

1.20

1.40

2.50

2.70

0.400

3.00

2.80

2.80

1.50

0.500

Analyte Expected Found %DRF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 133





5308029PDF File ID:




Benzoic Acid

Benzyl Alcohol






Chrysene



Dibenzofuran

Diethylphthalate

Dimethylphthalate

Fluorene

Hexachlorobenzene

Hexachloroethane


Isophorone

Naphthalene

Nitrobenzene

Phenanthrene

Pyrene

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

47200

51300

51400

52000

50800

54000

51000

50600

52700

49900

50600

52800

52300

52600

49400

49500

49100

51400

50000

53400

48700

48200

0.232

0.981

0.474

0.957

1.51

1.05

0.690

1.12

1.49

0.953

1.80

1.59

1.51

1.44

0.198

0.585

1.14

0.644

1.09

0.366

1.10

1.31

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

5.70

2.50

2.70

3.90

1.50

7.90

2.00

1.10

5.40

0.200

1.30

5.50

4.60

5.20

1.30

1.00

1.70

2.80

0

6.90

2.60

3.60


* Exceeds

%D

Limit %D

RF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 134





5308029PDF File ID:




3,3'-Dichlorobenzidine 50000 53400 0.441ug/L 6.80


* Exceeds

%D

Limit %D

RF

12M61779

WG609563


File ID:

Run Date:04/10/2017

Run Time:22:36

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

Units

QC Key:STD

Page 135







L17051231-01

L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615097-01

WG615097-02

WG615216-01

WG615216-02

01

01

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6

99379 185096 299893 368338 292656 314410

100414 164426 305392 369646 284088 312476

101237 168295 299488 337884 291478 326419

101050 166928 314177 333596 287340 315427

103302 187260 301163 382759 293979 345239

102788 170112 319126 371740 291431 323009

102941 185878 301302 380841 289977 343511

104843 191921 310692 390373 303833 358289

104813 174002 318860 344942 304969 324813

108833 187407 315435 396011 322065 359979

102537 181219 295395 362752 299904 327491

118542 206426 354369 405282 359204 380634WG615388-02

237084 412852 708738 810564 718408 761268

59271 103213 177185 202641 179602 190317

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

4

5

6

-

-

-

-

-

-


Acenaphthene-d10

Chrysene-d12

Naphthalene-d8

Perylene-d12

Phenanthrene-d10






HPMS12CAL ID:

IS- IS- IS- IS- IS- IS-

IS-

IS-

IS-

IS-

IS-

IS-

-10-APR-17

Page 136







L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615091-01

WG615091-02

WG615091-04

WG615091-05

01

01

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6

101407 186165 298269 383844 304512 342200

104196 189493 325826 387870 310151 352205

98204 186958 311427 380478 308097 338839

105419 188682 309876 387587 322218 339647

106267 192777 326550 393519 323697 324841

104638 188174 311919 384487 304487 335235

101947 185256 300791 377915 298286 340457

102238 186655 302139 380370 297124 339873

102517 186096 303270 377713 309601 347719

99388 174511 287191 351610 278235 323738

99333 161886 295386 363889 275328 308800

162142 316083 529986 633707 530132 578472WG615240-02

324284 632166 1059972 1267414 1060264 1156944

81071 158042 264993 316854 265066 289236

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

4

5

6

-

-

-

-

-

-


Acenaphthene-d10

Chrysene-d12

Naphthalene-D8

Perylene-d12

Phenanthrene-d10






HPMS12CAL ID:


IS-

IS-

IS-

IS-

IS-

IS-

-10-APR-17

Page 137







L17051231-01

L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615097-01

WG615097-02

WG615216-01

WG615216-02

01

01

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.829 10.932 16.243 9.121 19.085 12.546

7.823 10.927 16.243 9.116 19.085 12.546

7.82 10.93 16.24 9.12 19.08 12.55WG615388-02

8.32 11.43 16.74 9.62 19.58 13.05

7.32 10.43 15.74 8.62 18.58 12.05

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

4

5

6

-

-

-

-

-

-


Acenaphthene-d10

Chrysene-d12

Naphthalene-d8

Perylene-d12

Phenanthrene-d10







IS-

IS-

IS-

IS-

IS-

IS-


Page 138







L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615091-01

WG615091-02

WG615091-04

WG615091-05

01

01

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.074 12.54

7.823 10.927 16.232 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.232 9.116 19.074 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.237 9.116 19.079 12.54

7.823 10.927 16.242 9.116 19.079 12.54

7.823 10.927 16.243 9.116 19.079 12.54

7.83 10.93 16.25 9.12 19.09 12.55WG615240-02

8.33 11.43 16.75 9.62 19.59 13.05

7.33 10.43 15.75 8.62 18.59 12.05

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

4

5

6

-

-

-

-

-

-


Acenaphthene-d10

Chrysene-d12

Naphthalene-D8

Perylene-d12

Phenanthrene-d10







IS-

IS-

IS-

IS-

IS-

IS-


Page 139



Instrument Run Log

Run Log ID:81488

Page: 1 Approved: 12-APR-17


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS12

SCB

8270C/D

041017

NA

MSS01 28

Column 1 ID: Column 2 ID:RXI-5MS NA

Method: SOP: Rev:OVAP MSS01 0

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

12M61763

12M61764

12M61765

12M61766

12M61767

12M61768

12M61769

12M61770

12M61771

12M61772

12M61773

12M61774

12M61775

12M61776

12M61777

12M61778

12M61779

12M61780

12M61781

12M61782

12M61783

12M61784

12M61785

12M61786

12M61787

12M61788

RINSE W/IS

WG609563-01 50PPM DFTPP STD

WG609563-02 50PPM 8270 STD



WG609563-02 50PPM 8270 STD

WG609563-03 1PPM 8270 STD

WG609563-04 3PPM 8270 STD

WG609563-05 10PPM 8270 STD

WG609563-06 15PPM 8270 STD

WG609563-07 25PPM 8270 STD

WG609563-08 80PPM 8270 STD

WG609563-09 100PPM 8270 STD

WG609563-10 120PPM 8270 STD

WG609563-11 50PPM 8270 ALT SRC

WG609563-12 50PPM 1,4-DIOX ALT SRC

WG609563-13 50PPM MP,A9,BEN ALT SRC

WG609604-01 50PPM TCL/A-TERP STD







WG609604-08 50PPM TCL/A-TERP ALT SRC

BAKE OUT

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD80383

STD79533

STD80383

STD80383

STD79533

STD79533

STD79533

STD79533

STD79533

STD79533

STD79533

STD79533

STD79533

STD81294

STD79236

STD79746

STD81291

STD81291

STD81291

STD81291

STD81291

STD81291

STD81291

STD81289

04/10/17 13:58

04/10/17 14:32

04/10/17 14:51

04/10/17 15:33

04/10/17 16:14

04/10/17 16:33

04/10/17 17:06

04/10/17 17:39

04/10/17 18:12

04/10/17 18:46

04/10/17 19:19

04/10/17 19:52

04/10/17 20:25

04/10/17 20:59

04/10/17 21:31

04/10/17 22:04

04/10/17 22:36

04/10/17 23:09

04/10/17 23:42

04/11/17 00:14

04/11/17 00:47

04/11/17 01:20

04/11/17 01:52

04/11/17 02:25

04/11/17 02:57

04/11/17 03:30


1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

COA19575Internal STD: Surrogate STD: NA

Comments:

WG609563, WG609604Workgroups:

2

3

WG609563-01 50PPM DFTPP STD DNR

WG609563-02 50PPM 8270 STD raised the voltage by 50, DNR

Comments


Maintenance Log ID:

Calibration STD


STD79533, 81291CCV STD: LCS STD: MS/MSD STD:

Eluent ID#:

Page 140



Instrument Run Log

Run Log ID:81488

Page: 2 Approved: 12-APR-17


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS12

SCB

8270C/D

041017

NA

MSS01 28




WG609563, WG609604Workgroups:

4

WG609563-01 50PPM DFTPP STD has an ion failure, DNR

Comments


Maintenance Log ID: Syringe Filter Lot#:

STD79533, 81291CCV STD: LCS STD:

Eluent ID#:

Page 141



Instrument Run Log

Run Log ID:82369



Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

HPMS12

SCB

8270C/D

052317

MES

MSS01 28



1

2

3

4

5

6

7

8

9

10

11

19

13

14

15

16

17

18

12M62296

12M62297

12M62298

12M62299

12M62300

12M62301

12M62302

12M62303

12M62304

12M62305

12M62306

12M62307

12M62308

12M62309

12M62310

12M62311

12M62312

12M62313



WG615240-02 50PPM 8270 STD

WG615091-01 BLANK 5/22

WG615091-02 LCS 5/22

L17051231-14

L17051231-04

L17051231-08

L17051231-06

L17051231-10

L17051231-12

L17051231-02 REF

WG615091-04 MS

WG615091-05 MSD

BAKE OUT

BAKE OUT

BAKE OUT

BAKE OUT

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

STD80383

STD80383

STD79533

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

SOIL

05/23/17 10:01

05/23/17 10:32

05/23/17 10:50

05/23/17 11:25

05/23/17 11:58

05/23/17 12:31

05/23/17 13:03

05/23/17 13:36

05/23/17 14:10

05/23/17 14:43

05/23/17 15:16

05/23/17 15:49

05/23/17 16:22

05/23/17 16:55

05/23/17 17:28

05/23/17 18:01

05/23/17 18:34

05/23/17 19:07


1

1

1

7

7

7

7

7

7

7

7

7

7

7

1

1

1

1


Comments:

WG615227Workgroups:

1

4

13

14

X

DFTPP, ion ratio failed.

WG615091-01 BLANK 5/22 benzoic acid is >MDL, but <RL. The associated samples are non-detect for this analyte.

WG615091-04 MS: 2 analytes failed low.

WG615091-05 MSD: 2 analytes failed low.

Comments


Maintenance Log ID:

Calibration STD



Eluent ID#:

Page 142





5309110PDF File ID:




Chloroform

1,1-Dichloroethene

Vinyl Chloride

Chloromethane


1,1-Dichloroethane

Bromoform

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

18.3

18.4

21.6

22.3

19.6

19.1

16.5

20.9

20.5

20.2

19.6

19.4

21.4

21.9

0.508

0.455

0.467

0.617

0.704

0.586

0.246

1.09

1.13

0.392

0.443

0.143

0.338

0.319

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

8.60

8.00

8.20

11.5

2.10

4.30

17.6

4.40

2.30

1.20

1.90

2.80

6.90

9.30


* Exceeds

%D

Limit %D

RF

11M18442

WG614378


File ID:

Run Date:05/16/2017

Run Time:18:14

Analyst:ADC

ICal Workgroup:

8260BMethod:



QUCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 143





5308759PDF File ID:




1,1-Dichloropropene

2-Hexanone

Hexachlorobutadiene

Isopropylbenzene

p-Isopropyltoluene

4-Methyl-2-Pentanone

Methylene Chloride

Naphthalene

n-Propylbenzene

Styrene


Tetrachloroethene





Trichloroethene





Vinyl Acetate

o-Xylene

m-,p-Xylene

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

20.0

40.0

22.1

17.0

21.8

21.6

23.1

19.4

21.6

22.9

24.3

21.9

21.4

22.5

22.4

22.9

22.9

21.5

21.9

21.3

21.4

23.9

23.4

24.6

22.8

45.3

0.362

0.309

0.681

1.68

3.25

0.137

0.289

3.75

4.28

1.10

0.368

0.335

1.40

1.41

0.424

0.332

0.289

0.422

0.301

3.13

2.97

0.740

0.680

0.691

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

10.3

14.9

8.80

7.90

15.7

3.00

8.00

14.4

21.3

9.40

6.80

12.7

11.8

14.7

14.5

7.60

9.30

6.30

7.20

19.7

17.0

22.8

14.0

13.1


* Exceeds

%D

Limit %D

RF

9M980442

WG615237

Instrument ID:HPMS9

File ID:

Run Date:05/23/2017

Run Time:15:46

Analyst:ADC

ICal Workgroup:

8260BMethod:



Q

*

*

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

Units

QC Key:STD

Page 145







L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615095-01

WG615282-01

WG615282-02

WG615282-03

DL01

DL01

DL01

DL01

DL01

DL01

DL01

01

01

01

1 2 3

120312 229454 333775

117025 219558 318324

111321 213585 310490

111638 216952 314074

110236 217936 316529

112674 216605 311211

108085 213852 304757

119737 245509 352411

138533 255705 360756

141367 254883 357421

164010 287882 396075WG615277-02

328020 575764 792150

82005 143941 198038

Upper Limit

Lower Limit


10.0

10.0

10.0

10.0

10.0

10.0

10.0

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

-

-

-


Chlorobenzene-d5

Fluorobenzene






HPMS11CAL ID:

IS- IS- IS-

IS-

IS-

IS-

-16-MAY-17

Page 146



Inorganic QA/QC

Page 147







14G67536

05/16/17 11:21

05/16/17 14:27

WG614544

WG614301-01

HP14

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8015CMethod:

LJHAnalyst:


LCS

LCS2


17-0751 IR MUD SILO




WG614301-02

WG614301-03

L17050904-03

L17050904-01

L17050904-04

L17050904-05

L17050904-02

14G67537

14G67538

14G67540

14G67541

14G67542

14G67543

14G67544

05/16/17 15:06

05/16/17 15:45

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41



01

01

01

01

01

01

01

Page 148




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5297723

17-MAY-2017 10:07

o-Terphenyl

Octacosane

69.6

62.6


43

25

-

-

136

162

Qualifier

PASS

PASS


Diesel Range (C10-C28) 12500 10000 J3900



14G67536

WG614544

Instrument ID:HP14

File ID:

Prep Date:05/16/17 11:21

Run Date:05/16/17 14:27

Analyst:LJH


8015CMethod:

SoilMatrix:



3546Prep Method:

MDL RL

MDL

RL



Page 149








LCS LCS2

4.13137000 143000

Analytes %RPD

250000 250000


54.9 57.2

% REC % REC

26

RPDLmt

%RecLimits

35 120-

Q

Sample ID:

Sample ID:

WG614301-02

WG614301-03

LCS

LCS2

14G67537

14G67538

File ID:

File ID:

o-Terphenyl

Octacosane

LCS LCS2

69.7 73.4

68.2 74.9


Surrogate Limits

43

25

136

162

-

-

Qualifier

PASS

PASS

Run Date:

Run Date:

05/16/2017 15:06

05/16/2017 15:45

WG614544

Instrument ID:HP14

Analyst:LJH





# EXCEEDS RPD LIMIT


Page 150





SURROGATE STANDARDS


L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

-

-

o-Terphenyl

Octacosane

8015Method:

HP14Instrument Id:




26.2 36.2

12.6 9.41

53.4 52.3

30.9 30.4

39.5 34.6

69.6 62.6

69.7 68.2

73.4 74.9

43

25

-

-

136

162





Page 151







Diesel Range (C10-C28) 1000000 1000000 51200 0.384


* Exceeds

%D

Criteria %D

RF

14G67535

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:09:32

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 152







Diesel Range (C10-C28) 1000000 1040000 53300 4.46


* Exceeds

%D

Criteria %D

RF

14G67546

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:20:59

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 153







Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.400

1.00

0.0500

0.500

0.500

0.400

0.400

0.398

1.01

0.0503

0.506

0.504

0.407

0.405

99.5

101

101

101

101

102

101

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110


* Exceeds

LIMITS

Criteria LIMITS

%REC

T4.052317.165324

WG615308

Instrument ID:ICP-THERMO4

File ID:

Run Date:05/23/2017

Run Time:16:53

Analyst:KKB

Workgroup (AAB#):

6010BMethod:


23-MAY-17ICP-TH -Cal ID:

UNITS

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

STDQC Key:

WATERMatrix:

Page 154







Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.400

1.00

0.0500

0.500

0.500

0.400

0.400

0.397

1.01

0.0508

0.506

0.511

0.402

0.402

99.2

101

102

101

102

100

100

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110


* Exceeds

LIMITS

Criteria LIMITS

%REC

T4.052317.171908

WG615308


File ID:

Run Date:05/23/2017

Run Time:17:19

Analyst:KKB

Workgroup (AAB#):

6010BMethod:



UNITS

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

STDQC Key:

WATERMatrix:

Page 155



CCB - Modified 03/05/2008


CONTINUING CALIBRATION BLANK (CCB)


Analytes MDL RDL Concentration Qualifier

Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

0.100

0.0100

0.0100

0.0200

0.100

0.0800

0.0100

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

T4.052317.144628

WG615308


File ID:

Run Date:05/23/2017

Run Time:14:46

Analyst:KKB

Workgroup (AAB#):

mg/LUnits:

6010BMethod:


U

U

U

U

U

U

U

U = Result is less than MDL.F = Result is between MDL and RL.


* = Result is above RL.

WATERMatrix: QAPP:STD

Page 156








Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

0.100

0.0100

0.0100

0.0200

0.100

0.0800

0.0100

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

T4.052317.161307

WG615308


File ID:

Run Date:05/23/2017

Run Time:16:13

Analyst:KKB

Workgroup (AAB#):

mg/LUnits:

6010BMethod:


U

U

U

U

U

U

U





Page 157





5297726PDF File ID:





* Exceeds

%D

Limit %D

RF

14G67518

WG613451

Instrument ID:HP14

File ID:

Run Date:05/09/2017

Run Time:14:09

Analyst:LJH

ICal Workgroup:

8015CMethod:



QUCL20

Units

QC Key:STD

Page 158







1,1-Dichloroethene

1,2-Dichloroethane

Methyl Ethyl Ketone

Benzene


Chlorobenzene

Chloroform

Tetrachloroethene

Trichloroethene

Vinyl chloride

LCS LCS2

4.01

1.54

5.32

2.70

2.37

2.22

2.08

0.870

1.31

0.804

20.1 20.9

20.8 21.1

18.6 19.6

21.1 21.6

20.4 20.9

21.2 21.7

18.9 19.3

21.4 21.6

20.6 20.8

21.8 22.0

Analytes %RPD

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0


100 105

104 105

93.0 98.1

105 108

102 105

106 108

94.3 96.3

107 108

103 104

109 110

% REC % REC

20

20

20

20

20

20

20

20

20

20

RPDLmt

%RecLimits

80

80

10

80

65

80

80

80

80

50

132

129

170

121

140

120

125

124

122

170

-

-

-

-

-

-

-

-

-

-

Q

Sample ID:

Sample ID:

WG615282-02

WG615282-03

LCS

LCS2

11M18568

11M18569

File ID:

File ID:




Toluene-d8

LCS LCS2

105 107

101 106

106 106

107 108


Surrogate Limits

80

86

86

88

120

118

115

110

-

-

-

-

Qualifier

PASS

PASS

PASS

PASS

Run Date:

Run Date:

05/23/2017 14:06

05/23/2017 14:35

WG615282


Analyst:TMB/JDS





# EXCEEDS RPD LIMIT


Page 159





SURROGATE STANDARDS


L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615091-01

WG615091-02

01

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

3

4

5

6

-

-

-

-

-

-


2-Fluorobiphenyl

2-Fluorophenol

Nitrobenzene-d5

p-Terphenyl-d14

Phenol-d5

8270Method:





101 77.8 67.6 86.7 92.1 69.3

85.5 84.2 69.3 89.2 80.3 67.6

91.0 83.7 66.8 86.5 76.4 65.4

83.4 81.7 62.9 84.5 75.9 62.2

70.9 57.1 45.1 60.2 79.1 43.6

87.9 82.1 62.5 88.7 77.3 59.8

54.9 64.3 46.1 72.5 68.3 49.0

105 85.6 72.2 88.2 97.5 74.0

84.5 79.7 68.6 81.7 80.9 67.7

19

30

25

23

18

24

-

-

-

-

-

-

122

115

121

120

137

113





Page 160








2,4-Dichlorophenol

2-Nitrophenol


Acenaphthene

Benzo[a]pyrene


Fluoranthene


Phenol

1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol


2,4-Dinitrophenol

4-Nitrophenol



2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

51100

52000

53200

48200

50200

47200

50600

48100

48100

48000

57600

49000

49200

61500

51500

64100

43500

44100

47100

50900

52100

47000

52200

46100

48700

0.280

0.204

0.316

1.25

1.10

1.62

1.15

0.653

1.60

1.47

0.166

0.126

0.386

0.180

0.446

0.279

0.634

0.939

1.35

0.455

0.209

0.555

0.357

1.54

0.391

2.11

3.91

6.32

3.66

0.347

5.63

1.11

3.89

3.76

4.04

15.2

1.94

1.57

22.9

3.04

28.3

13.1

11.9

5.72

1.80

4.28

6.00

4.46

7.73

2.50


* Exceeds

%D

Criteria %D

RF

12M62316

WG615400


File ID:

Run Date:05/24/2017

Run Time:10:05

Analyst:MES

Workgroup (AAB#):

8270CMethod:



UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 161







1,4-Dichlorobenzene


2,4-Dichlorophenol

2-Nitrophenol


Acenaphthene

Benzo[a]pyrene


Fluoranthene

Hexachlorobutadiene


Pentachlorophenol

Phenol

2,4-Dinitrophenol

4-Nitrophenol




1,2-Dichlorobenzene

1,3-Dichlorobenzene


2,4-Dimethylphenol

2,4-Dinitrotoluene

2,6-Dinitrotoluene

2-Chloronaphthalene

2-Chlorophenol

2-Methylnaphthalene

2-Methylphenol

2-Nitroaniline

3,3'-Dichlorobenzidine

3-,4-Methylphenol

3-Nitroaniline



4-Chloroaniline


4-Nitroaniline

Acenaphthylene

Anthracene

Benzo[a]anthracene


Benzo[ghi]perylene

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49200

50300

49800

50900

53300

47200

51300

47400

50400

56800

48800

50400

48700

64700

53700

59200

40200

50900

47900

50100

49000

47300

50200

49000

47700

50800

50700

45900

53000

51000

50300

47900

59500

52200

53300

49900

48500

46800

48800

48600

48800

52200

1.51

0.395

0.273

0.200

0.316

1.23

1.12

1.63

1.15

0.164

0.663

0.130

1.62

0.190

0.465

0.257

0.595

0.305

1.36

1.56

0.393

0.325

0.448

0.341

1.25

1.54

0.714

0.978

0.377

0.421

1.44

0.411

0.130

0.204

0.115

0.630

0.388

2.00

1.14

1.19

1.22

1.02

1.65

0.588

0.389

1.71

6.53

5.67

2.55

5.26

0.827

13.6

2.39

0.738

2.53

29.4

7.31

18.3

19.7

1.88

4.18

0.244

2.07

5.33

0.306

1.94

4.58

1.59

1.48

8.13

5.97

1.92

0.606

4.17

19.0

4.43

6.68

0.224

2.99

6.49

2.32

2.76

2.39

4.35

Analyte Expected Found Q%DRF

12M62298

WG615227


File ID:

Run Date:05/23/2017

Run Time:10:50

Analyst:SCB

Workgroup (AAB#):

8270CMethod:



UNITS

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 162









Benzoic Acid

Benzyl Alcohol






Chrysene



Dibenzofuran

Diethylphthalate

Dimethylphthalate

Fluorene

Hexachlorobenzene

Hexachloroethane


Isophorone

Naphthalene

Nitrobenzene

Phenanthrene

Pyrene

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

45400

33100

49600

40700

45700

49600

47400

43200

48400

49000

55200

47600

49000

49200

49200

53800

51400

53400

48400

49100

49700

48700

47300

0.991

0.151

0.948

0.392

0.843

1.47

0.920

0.585

1.07

1.38

1.05

1.70

1.48

1.42

1.35

0.216

0.607

1.24

0.606

1.07

0.340

1.10

1.28

9.13

33.7

0.830

18.6

8.51

0.722

5.24

13.6

3.26

2.05

10.3

4.72

1.97

1.63

1.58

7.50

2.75

6.90

3.26

1.86

0.625

2.56

5.31


* Exceeds

%D

Criteria %D

RF

12M62298

WG615227


File ID:

Run Date:05/23/2017

Run Time:10:50

Analyst:SCB

Workgroup (AAB#):

8270CMethod:



UNITS

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

ug/kg

UCL40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 163








1,2-Dichloropropane

Ethylbenzene

Toluene

Chloroform

1,1-Dichloroethene

Vinyl Chloride


1,1-Dichloroethane

Bromoform

Chloromethane

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.3

50.7

50.2

44.2

48.3

49.4

49.5

48.2

43.4

42.2

48.8

48.1

51.7

47.2

43.9

51.9

48.1

0.341

0.584

1.54

0.491

0.478

0.427

0.712

0.590

0.265

0.467

1.02

1.06

0.401

0.426

0.129

0.328

0.281

0.611

1.40

0.480

11.7

3.46

1.17

0.938

3.68

13.3

15.6

2.34

3.78

3.46

5.66

12.2

3.84

3.72


* Exceeds

%D

Criteria %D

RF

11M18564

WG615282


File ID:

Run Date:05/23/2017

Run Time:12:27

Analyst:TMB

Workgroup (AAB#):

8260BMethod:



UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

STDQC Key:

WATERMatrix:

Page 164








Analyte Expected Found Q* Exceeds

%D Criteria %D

RF

11M18566

WG615282


File ID:

Run Date:05/23/2017

Run Time:13:08

Analyst:TMB/JDS

Workgroup (AAB#):

8260BMethod:



UNITS UCL

STDQC Key:

WATERMatrix:

Page 165








1,2-Dichloropropane

Ethylbenzene

Toluene

Chloroform

1,1-Dichloroethene

Vinyl Chloride


1,1-Dichloroethane

Bromoform

Chloromethane

Chlorobenzene

Benzene


1,2-Dichloroethane

2-Butanone

Tetrachloroethene

Trichloroethene

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

SPCC

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

50.0

53.4

55.2

55.5

49.9

57.2

59.8

45.7

56.1

43.6

60.1

52.2

55.3

59.1

50.8

42.3

56.0

54.8

0.269

0.613

1.54

0.501

0.414

0.478

0.432

0.509

0.177

0.509

1.04

1.14

0.445

0.288

0.0467

0.327

0.318

*

6.72

10.5

10.9

0.218

14.5

19.7

8.51

12.2

12.9

20.2

4.49

10.6

18.3

1.53

15.3

12.0

9.51


* Exceeds

%D

Criteria %D

RF

8M419869

WG615405

Instrument ID:HPMS8

File ID:

Run Date:05/24/2017

Run Time:11:59

Analyst:TMB

Workgroup (AAB#):

8260BMethod:



UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

20

STDQC Key:

WATERMatrix:

Page 166





5309621PDF File ID:




1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol


2,4-Dinitrophenol


4-Nitrophenol


2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49900

55900

63000

50800

59200

61400

53000

57900

50400

51600

52500

49400

49500

53400

53400

49200

1.53

0.161

0.162

0.398

0.172

0.267

0.459

0.790

1.07

1.47

0.469

0.198

0.585

0.366

1.78

0.395

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

0.300

11.9

26.1

1.60

18.4

22.8

6.00

15.7

0.900

3.20

4.90

1.30

1.00

6.90

6.80

1.60


* Exceeds

%D

Limit %D

RF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

40

30

40

40

40

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 167



CORR_FACTORS - Modified 03/05/2008


INTERELEMENT CORRECTION FACTORS (ANNUALLY)


ALUMINUM

ANTIMONY

ARSENIC

BARIUM

BERYLLIUM

BORON

CADMIUM

CALCIUM

CHROMIUM

COBALT

COPPER

IRON

LEAD

LITHIUM

MAGNESIUM

MANGANESE

MOLYBDENUM

NICKEL

PHOSPHORUS

POTASSIUM

SELENIUM

SILICON

SILVER

SODIUM

STRONTIUM

THALLIUM

TIN

TITANIUM

VANADIUM

ZINC

ZIRCONIUM

Analyte

308.20

206.80

189.00

455.40

313.10

249.60

228.80

422.60

267.70

228.60

224.70

261.10

220.30

670.70

279.10

257.60

202.00

231.60

214.90

766.40

196.10

212.40

328.10

589.50

407.70

190.80

189.90

337.20

292.40

206.20

339.10

Wave Length

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

0

ZR

Insturment ID:

Date:

Method:ICP-THERMO4

01/04/2017

6010B

Login Number:L17051231

Page 168





5308029PDF File ID:




Benzoic Acid

Benzyl Alcohol






Chrysene



Dibenzofuran

Diethylphthalate

Dimethylphthalate

Fluorene

Hexachlorobenzene

Hexachloroethane


Isophorone

Naphthalene

Nitrobenzene

Phenanthrene

Pyrene

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

47200

51300

51400

52000

50800

54000

51000

50600

52700

49900

50600

52800

52300

52600

49400

49500

49100

51400

50000

53400

48700

48200

0.232

0.981

0.474

0.957

1.51

1.05

0.690

1.12

1.49

0.953

1.80

1.59

1.51

1.44

0.198

0.585

1.14

0.644

1.09

0.366

1.10

1.31

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

5.70

2.50

2.70

3.90

1.50

7.90

2.00

1.10

5.40

0.200

1.30

5.50

4.60

5.20

1.30

1.00

1.70

2.80

0

6.90

2.60

3.60


* Exceeds

%D

Limit %D

RF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 169



Instrument Run Log

Run Log ID: 82374

Page: 1 Approved: May 24, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

ICP-THERMO4

KKB

200.7/6010B/6010C

052317T4.1R.TXT

N/A

ME600G 8

Calibration Std:

ICSA:

ICV Std:

ICSAB:

Post Spike:

Workgroups:

STD81957

STD81649

STD81979

STD81939

STD81528

615308,615115,615271,615275

1

2

3

4

5

6

7

8

9

10

11

12

13

14

15

16

17

18

19

20

21

22

23

24

25

26

27

28

29

30

31

32

33

34

T4.052317.141017

T4.052317.141400

T4.052317.141743

T4.052317.142128

T4.052317.142455

T4.052317.142822

T4.052317.143152

T4.052317.143535

T4.052317.143920

T4.052317.144300

T4.052317.144628

T4.052317.153305

T4.052317.153648

T4.052317.154016

T4.052317.154400

T4.052317.154743

T4.052317.155127

T4.052317.155507

T4.052317.155847

T4.052317.160229

T4.052317.160557

T4.052317.160939

T4.052317.161307

T4.052317.161653

T4.052317.162035

T4.052317.162415

T4.052317.162755

T4.052317.163134

T4.052317.163503

T4.052317.163831

T4.052317.164215

T4.052317.164558

T4.052317.164940

T4.052317.165324

WG615438-01

WG615438-02

WG615438-03

WG615438-04

WG615438-05

WG615438-06

WG615438-07

WG615438-08

WG615438-09

WG615438-10

WG615438-11

WG615215-02

WG615215-03

WG615014-01

WG615014-02

WG615014-03

L17051122-01

L17051160-01

L17051161-01

WG615308-01

WG615308-02

WG615438-12

WG615438-13

L17051162-01

L17051167-01

L17051167-02

WG615215-01

WG615215-04

WG615215-05

L17051170-01

L17051170-02

L17051231-01

L17051231-03

WG615438-14

Calibration Point

Calibration Point

Calibration Point

Calibration Point

Calibration Point

Initial Calibration Verification

Initial Calib Blank

Interference Check

Interference Check

CCV

CCB

Method/Prep Blank

Laboratory Control S

Fluid Blank 1

Fluid Blank 1

Fluid Blank 2

\#1 CELLAR DIRT

AWV 10 BAGS

SAPA 7 BAGS

Post Digestion Spike

Serial Dilution

CCV

CCB

KAISER 9 BAGS

WPAFB-SA-101

WPAFB-SA-102

Reference Sample

Matrix Spike

Matrix Spike Duplica

5/8 WASTE DRUM \#1

5/8 WASTE DRUM \#2

17-0751 OSG DISPOSAL PI


CCV

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

5/50

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

1

5

1

1

1

1

1

1

1

1

1

1

1

1

1

L17051161-01

L17051161-01

L17051167-03

L17051167-03

L17051167-03

05/23/17 14:10

05/23/17 14:14

05/23/17 14:17

05/23/17 14:21

05/23/17 14:24

05/23/17 14:28

05/23/17 14:31

05/23/17 14:35

05/23/17 14:39

05/23/17 14:43

05/23/17 14:46

05/23/17 15:33

05/23/17 15:36

05/23/17 15:40

05/23/17 15:44

05/23/17 15:47

05/23/17 15:51

05/23/17 15:55

05/23/17 15:58

05/23/17 16:02

05/23/17 16:05

05/23/17 16:09

05/23/17 16:13

05/23/17 16:16

05/23/17 16:20

05/23/17 16:24

05/23/17 16:27

05/23/17 16:31

05/23/17 16:35

05/23/17 16:38

05/23/17 16:42

05/23/17 16:45

05/23/17 16:49

05/23/17 16:53

Seq. File ID Sample ID Prep Dil Reference Date/Time

Comments:

Maintenance Log ID:

Int. Std: RGT39282

CCV: STD81717 COA19158LLCCV: Tuning Sol :

Stannous : Hydroxylamine :

Page 170







L17051231-01

L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615097-01

WG615097-02

WG615216-01

WG615216-02

01

01

01

01

01

01

01

01

01

01

01

1 2 3 4 5 6

99379 185096 299893 368338 292656 314410

100414 164426 305392 369646 284088 312476

101237 168295 299488 337884 291478 326419

101050 166928 314177 333596 287340 315427

103302 187260 301163 382759 293979 345239

102788 170112 319126 371740 291431 323009

102941 185878 301302 380841 289977 343511

104843 191921 310692 390373 303833 358289

104813 174002 318860 344942 304969 324813

108833 187407 315435 396011 322065 359979

102537 181219 295395 362752 299904 327491

118542 206426 354369 405282 359204 380634WG615388-02

237084 412852 708738 810564 718408 761268

59271 103213 177185 202641 179602 190317

Upper Limit

Lower Limit


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

NA

NA

NA

NA

NA

NA

1

2

3

4

5

6

-

-

-

-

-

-


Acenaphthene-d10

Chrysene-d12

Naphthalene-d8

Perylene-d12

Phenanthrene-d10






HPMS12CAL ID:


IS-

IS-

IS-

IS-

IS-

IS-

-10-APR-17

Page 171




Method: 8260WT.M

Title: 8260B/624 (SOP: OVL MSV01) Water 051617 HPMS11

Last Calibration: Wed May 17 12:46:08 2017

Curve: WG614378

Calibration Files



Fluorobenzene ISTD


Chloromethane 0.560 0.639 0.584 0.630 0.536 0.486 0.439 0.553 13.227

Vinyl Chloride 0.498 0.417 0.470 0.439 0.478 0.442 0.375 0.336 0.432 12.564

1,3-Butadiene 0.343 0.282 0.295 0.228 0.162 0.153 0.130 0.227 36.032 1.002

Bromomethane 0.207 0.210 0.206 0.193 0.198 0.204 0.219 0.205 4.082

Chloroethane 0.219 0.239 0.241 0.249 0.245 0.237 0.248 0.240 4.259

Trichlorofluoromethane 0.441 0.417 0.471 0.462 0.480 0.472 0.439 0.448 0.454 4.729

Diethyl ether 0.273 0.297 0.290 0.286 0.284 0.278 0.284 0.285 2.761

Isoprene 0.305 0.365 0.389 0.401 0.441 0.443 0.441 0.439 0.403 12.220

Acrolein 0.029 0.040 0.038 0.039 0.040 0.042 0.042 0.039 11.129

1,1,2-Trichloro-1,2,2-Trifluoroethane 0.195 0.234 0.242 0.249 0.253 0.241 0.255 0.239 8.688

Acetone 0.089 0.093 0.091 0.092 0.093 0.097 0.090 0.092 2.806

1,1-Dichloroethene 0.473 0.457 0.486 0.517 0.521 0.518 0.495 0.494 0.495 4.648

Tert-Butyl Alcohol 0.023 0.027 0.027 0.028 0.031 0.032 0.028 11.816

Dimethyl Sulfide 0.287 0.297 0.340 0.336 0.357 0.356 0.352 0.351 0.334 8.216

Iodomethane 0.013 0.079 0.141 0.251 0.276 0.290 0.298 0.192 59.519 0.998

Methyl acetate 0.215 0.241 0.249 0.254 0.256 0.266 0.247 7.124

Methylene Chloride 0.335 0.334 0.310 0.314 0.305 0.293 0.302 0.313 5.038


Acrylonitrile 0.094 0.114 0.118 0.119 0.129 0.131 0.126 0.119 10.729

Methyl Tert Butyl Ether 0.745 0.695 0.766 0.793 0.821 0.803 0.773 0.768 0.771 5.035

trans-1,2-Dichloroethene 0.246 0.236 0.270 0.276 0.288 0.287 0.276 0.287 0.271 7.185

n-Hexane 0.407 0.430 0.467 0.476 0.471 0.467 0.453 6.165

Diisopropyl ether 1.117 1.264 1.233 1.203 1.164 1.017 0.915 1.130 11.071

Vinyl Acetate 0.479 0.533 0.487 0.517 0.535 0.472 0.424 0.492 8.019

1,1-Dichloroethane 0.640 0.593 0.611 0.604 0.645 0.631 0.596 0.577 0.612 3.958

Ethyl-Tert-Butyl ether 0.964 1.097 1.071 1.046 1.027 0.914 0.834 0.993 9.488

2-Butanone 0.137 0.139 0.143 0.147 0.152 0.157 0.155 0.147 5.313

Propionitrile 0.034 0.041 0.043 0.044 0.045 0.047 0.050 0.043 11.768


cis-1,2-Dichloroethene 0.316 0.262 0.294 0.319 0.332 0.328 0.315 0.320 0.311 7.292

Chloroform 0.668 0.681 0.536 0.542 0.526 0.550 0.525 0.494 0.481 0.556 12.730

1-Bromopropane 0.040 0.054 0.061 0.060 0.058 0.061 0.059 0.056 13.246

Bromochloromethane 0.129 0.172 0.187 0.196 0.199 0.196 0.192 0.198 0.184 12.931

Tetrahydrofuran 0.158 0.115 0.106 0.104 0.106 0.106 0.108 0.115 16.890 0.999



Cyclohexane 0.581 0.524 0.578 0.607 0.650 0.644 0.623 0.599 0.540 0.594 7.282

1,1-Dichloropropene 0.331 0.335 0.357 0.372 0.408 0.407 0.386 0.387 0.373 7.978

Carbon Tetrachloride 0.304 0.349 0.379 0.396 0.420 0.430 0.409 0.410 0.387 10.874

Tert-Amyl-Methyl ether 0.714 0.837 0.823 0.816 0.803 0.73 0.677 0.77142 8.15202


1,2-Dichloroethane 0.442 0.419 0.47 0.476 0.478 0.468 0.436 0.423 0.45135 5.33453

Benzene 1.156 1.084 1.179 1.185 1.199 1.141 1.011 0.878 1.104 10.0158

Trichloroethene 0.226 0.251 0.301 0.301 0.325 0.317 0.301 0.309 0.29146 11.7841

Methylcyclohexane 0.477 0.383 0.443 0.467 0.507 0.501 0.477 0.464 0.423 0.46019 8.49006


1,4-Dioxane 0.002 0.003 0.003 0.003 0.003 0.003 0.00293 13.9596

Bromodichloromethane 0.343 0.298 0.345 0.37 0.408 0.403 0.393 0.389 0.36867 10.1709

Dibromomethane 0.12 0.153 0.171 0.163 0.188 0.182 0.176 0.183 0.16712 13.2633

2-Chloroethyl Vinyl Ether 0.14 0.162 0.18 0.202 0.21 0.215 0.22 0.208 0.19218 14.9182

4-Methyl-2-Pentanone 0.099 0.116 0.122 0.127 0.138 0.133 0.12257 11.2898

cis-1,3-Dichloropropene 0.334 0.303 0.37 0.402 0.455 0.472 0.45 0.443 0.40378 15.4416 0.999



Toluene-d8 1.507 1.348 1.404 1.335 1.146 1.34813 9.77146

Toluene 2.389 1.827 1.753 1.819 1.767 1.658 1.41 1.80307 16.3818 0.991

Ethyl Methacrylate 0.303 0.369 0.419 0.482 0.512 0.503 0.484 0.461 0.44178 16.5839 0.998



2-Hexanone 0.257 0.302 0.314 0.319 0.323 0.318 0.30532 8.13831


Tetrachloroethene 0.237 0.276 0.301 0.34 0.35 0.354 0.336 0.331 0.31574 13.0405

Dibromochloromethane 0.302 0.303 0.328 0.364 0.422 0.438 0.419 0.416 0.37379 15.2048 0.999

1,2-Dibromoethane 0.218 0.277 0.297 0.323 0.336 0.338 0.324 0.324 0.30457 13.3219

1-Chlorohexane 0.435 0.368 0.42 0.471 0.528 0.54 0.528 0.493 0.454 0.47077 12.2378

Chlorobenzene 1.06 1.029 1.093 1.095 1.14 1.091 0.982 0.852 1.04267 8.68375


Ethylbenzene 0.49 0.553 0.573 0.617 0.631 0.597 0.568 0.5756 8.15775

m-,p-Xylene 0.624 0.61 0.662 0.73 0.738 0.723 0.635 0.52 0.6552 11.3677

o-Xylene 0.611 0.542 0.601 0.714 0.734 0.742 0.699 0.654 0.66201 10.9201

Styrene 0.915 0.841 0.944 1.039 1.186 1.213 1.116 0.962 1.02697 13.0703

Bromoform 0.169 0.221 0.229 0.278 0.299 0.304 0.316 0.25955 20.9192 0.999

Isopropylbenzene 1.54 1.47 1.654 1.773 1.858 1.79 1.534 1.228 1.60558 12.8593




1,2,3-Trichloropropane 0.192 0.203 0.227 0.25 0.237 0.238 0.241 0.22684 9.47455

trans-1,4-Dichloro-2-Butene 0.145 0.197 0.252 0.276 0.273 0.283 0.283 0.259 0.24598 20.0146 0.998

R^2

Page 172



n-Propylbenzene 3.443 3.25 3.731 4.084 4.255 3.72 3.078 3.6516 11.7041

Bromobenzene 0.765 0.798 0.769 0.857 0.913 0.978 0.915 0.884 0.825 0.85586 8.52037

1,3,5-Trimethylbenzene 2.528 2.343 2.64 2.841 3.025 2.723 2.375 1.866 2.54273 14.0286

2-Chlorotoluene 2.677 2.489 2.82 2.937 3.017 2.639 2.322 1.813 2.58925 14.9669

4-Chlorotoluene 1.945 1.885 2.066 2.17 2.308 2.123 1.844 1.421 1.97015 13.7289

a-Methylstyrene 1.273 1.545 1.523 1.47 1.247 1.119 1.36309 12.7744

tert-Butylbenzene 0.452 0.537 0.622 0.676 0.646 0.63 0.606 0.59568 12.8233

1,2,4-Trimethylbenzene 2.375 2.721 2.996 3.128 2.834 2.449 2.75056 10.8088

sec-Butylbenzene 2.835 3.307 3.628 3.804 3.444 2.938 3.32593 11.4512

p-Isopropyltoluene 2.257 2.755 2.988 3.212 2.941 2.558 2.7853 12.2258



n-Butylbenzene 2.011 2.347 2.567 2.939 2.747 2.426 2.50625 12.9532

1,2-Dichlorobenzene 1.749 1.667 1.454 1.685 1.649 1.757 1.617 1.532 1.299 1.60101 9.3155

1,2-Dibromo-3-Chloropropane 0.092 0.133 0.151 0.154 0.157 0.168 0.14243 19.0803 0.999

1,2,4-Trichlorobenzene 0.9 0.961 1.064 1.102 1.251 1.175 1.143 1.07 1.08325 10.4409

Hexachlorobutadiene 0.336 0.503 0.513 0.584 0.642 0.617 0.623 0.616 0.55426 18.444 1

Naphthalene 2.035 1.958 2.204 2.525 2.772 2.535 2.227 1.831 2.26105 14.3669

1,2,3-Trichlorobenzene 0.922 0.878 0.94 1.027 1.136 1.237 1.159 1.103 1.065 1.05185 11.4386

Thu May 18 10:46:55 2017

Page 173




Method: A9FOOWT.M

Title: A9-FOO Water SOP:MSV01 04-12-17 HPMS8

Last Calibration: Thu Apr 13 16:40:13 2017

Curve: WG609829

Calibration Files

5 20 50 100 200 300 400 5008M418916.D 8M418917.D 8M418918.D 8M418919.D 8M418920.D 8M418921.D 8M418922.D 8M418923.D

Compound Avg %RSD

I Fluorobenzene ISTDT Acetonitrile 0.013 0.012 0.013 0.013 0.012 0.013 0.013 0.013 3.572T 3-Chloro-1-propene 0.312 0.315 0.327 0.337 0.346 0.341 0.344 0.341 0.333 3.984T 2-Chloro-1,3-butadiene 0.285 0.299 0.317 0.330 0.340 0.336 0.337 0.336 0.322 6.267T Ethyl Acetate 0.099 0.101 0.098 0.101 0.108 0.103 0.106 0.109 0.103 4.045T Methacrylonitrile 0.052 0.059 0.057 0.059 0.064 0.061 0.063 0.065 0.060 7.025T Isobutyl Alcohol 0.003 0.004 0.004 0.004 0.005 0.005 0.004 12.096T 1-Butanol 0.000 0.000T Methyl methacrylate 0.096 0.101 0.103 0.107 0.116 0.112 0.116 0.121 0.109 7.922T 2-Nitropropane 0.027 0.028 0.031 0.034 0.034 0.035 0.037 0.032 11.358I Chlorobenzene-d5 ISTDI 1,4-Dichlorobenzene-d4 ISTDT Cyclohexanone 0.006 0.006 0.007 0.008 0.007 0.008 0.009 0.007 13.841

Mon Apr 17 15:45:45 2017

Page 174







14G67536

05/16/17 11:21

05/16/17 14:27

WG614544

WG614301-01

HP14

Blank File ID:

Prep Date:

Analyzed Date:

Work Group:

Blank Sample ID:

Instrument ID:

8015CMethod:

LJHAnalyst:


LCS

LCS2


17-0751 IR MUD SILO




WG614301-02

WG614301-03

L17050904-03

L17050904-01

L17050904-04

L17050904-05

L17050904-02

14G67537

14G67538

14G67540

14G67541

14G67542

14G67543

14G67544

05/16/17 15:06

05/16/17 15:45

05/16/17 17:04

05/16/17 17:43

05/16/17 18:22

05/16/17 19:02

05/16/17 19:41



01

01

01

01

01

01

01

Page 176




METHOD BLANK REPORT

Report Name:BLANK

PDF ID: 5297723

17-MAY-2017 10:07

o-Terphenyl

Octacosane

69.6

62.6


43

25

-

-

136

162

Qualifier

PASS

PASS


Diesel Range (C10-C28) 12500 10000 J3900



14G67536

WG614544

Instrument ID:HP14

File ID:

Prep Date:05/16/17 11:21

Run Date:05/16/17 14:27

Analyst:LJH


8015CMethod:

SoilMatrix:



3546Prep Method:

MDL RL

MDL

RL



Page 177








LCS LCS2

4.13137000 143000

Analytes %RPD

250000 250000


54.9 57.2

% REC % REC

26

RPDLmt

%RecLimits

35 120-

Q

Sample ID:

Sample ID:

WG614301-02

WG614301-03

LCS

LCS2

14G67537

14G67538

File ID:

File ID:

o-Terphenyl

Octacosane

LCS LCS2

69.7 73.4

68.2 74.9


Surrogate Limits

43

25

136

162

-

-

Qualifier

PASS

PASS

Run Date:

Run Date:

05/16/2017 15:06

05/16/2017 15:45

WG614544

Instrument ID:HP14

Analyst:LJH





# EXCEEDS RPD LIMIT


Page 178





SURROGATE STANDARDS


L17050904-01

L17050904-02

L17050904-03

L17050904-04

L17050904-05

WG614301-01

WG614301-02

WG614301-03

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

-

-

o-Terphenyl

Octacosane

8015Method:

HP14Instrument Id:




26.2 36.2

12.6 9.41

53.4 52.3

30.9 30.4

39.5 34.6

69.6 62.6

69.7 68.2

73.4 74.9

43

25

-

-

136

162





Page 179







Diesel Range (C10-C28) 1000000 1000000 51200 0.384


* Exceeds

%D

Criteria %D

RF

14G67535

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:09:32

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 180







Diesel Range (C10-C28) 1000000 1040000 53300 4.46


* Exceeds

%D

Criteria %D

RF

14G67546

WG614544

Instrument ID:HP14

File ID:

Run Date:05/16/2017

Run Time:20:59

Analyst:LJH

Workgroup (AAB#):

8015CMethod:



UNITS

ug/kg

UCL20

STDQC Key:

WATERMatrix:

Page 181







Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.400

1.00

0.0500

0.500

0.500

0.400

0.400

0.398

1.01

0.0503

0.506

0.504

0.407

0.405

99.5

101

101

101

101

102

101

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110


* Exceeds

LIMITS

Criteria LIMITS

%REC

T4.052317.165324

WG615308


File ID:

Run Date:05/23/2017

Run Time:16:53

Analyst:KKB

Workgroup (AAB#):

6010BMethod:



UNITS

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

STDQC Key:

WATERMatrix:

Page 182







Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.400

1.00

0.0500

0.500

0.500

0.400

0.400

0.397

1.01

0.0508

0.506

0.511

0.402

0.402

99.2

101

102

101

102

100

100

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110

90 - 110


* Exceeds

LIMITS

Criteria LIMITS

%REC

T4.052317.171908

WG615308


File ID:

Run Date:05/23/2017

Run Time:17:19

Analyst:KKB

Workgroup (AAB#):

6010BMethod:



UNITS

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

mg/L

STDQC Key:

WATERMatrix:

Page 183








Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

0.100

0.0100

0.0100

0.0200

0.100

0.0800

0.0100

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

T4.052317.144628

WG615308


File ID:

Run Date:05/23/2017

Run Time:14:46

Analyst:KKB

Workgroup (AAB#):

mg/LUnits:

6010BMethod:


U

U

U

U

U

U

U





Page 184








Arsenic

Barium

Cadmium

Chromium

Lead

Selenium

Silver

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

0.100

0.0100

0.0100

0.0200

0.100

0.0800

0.0100

0.0500

0.00500

0.00500

0.0100

0.0500

0.0400

0.00500

T4.052317.161307

WG615308


File ID:

Run Date:05/23/2017

Run Time:16:13

Analyst:KKB

Workgroup (AAB#):

mg/LUnits:

6010BMethod:


U

U

U

U

U

U

U





Page 185





5297726PDF File ID:





* Exceeds

%D

Limit %D

RF

14G67518

WG613451

Instrument ID:HP14

File ID:

Run Date:05/09/2017

Run Time:14:09

Analyst:LJH

ICal Workgroup:

8015CMethod:



QUCL20

Units

QC Key:STD

Page 186







1,1-Dichloroethene

1,2-Dichloroethane

Methyl Ethyl Ketone

Benzene


Chlorobenzene

Chloroform

Tetrachloroethene

Trichloroethene

Vinyl chloride

LCS LCS2

4.01

1.54

5.32

2.70

2.37

2.22

2.08

0.870

1.31

0.804

20.1 20.9

20.8 21.1

18.6 19.6

21.1 21.6

20.4 20.9

21.2 21.7

18.9 19.3

21.4 21.6

20.6 20.8

21.8 22.0

Analytes %RPD

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0

20.0 20.0


100 105

104 105

93.0 98.1

105 108

102 105

106 108

94.3 96.3

107 108

103 104

109 110

% REC % REC

20

20

20

20

20

20

20

20

20

20

RPDLmt

%RecLimits

80

80

10

80

65

80

80

80

80

50

132

129

170

121

140

120

125

124

122

170

-

-

-

-

-

-

-

-

-

-

Q

Sample ID:

Sample ID:

WG615282-02

WG615282-03

LCS

LCS2

11M18568

11M18569

File ID:

File ID:




Toluene-d8

LCS LCS2

105 107

101 106

106 106

107 108


Surrogate Limits

80

86

86

88

120

118

115

110

-

-

-

-

Qualifier

PASS

PASS

PASS

PASS

Run Date:

Run Date:

05/23/2017 14:06

05/23/2017 14:35

WG615282


Analyst:TMB/JDS





# EXCEEDS RPD LIMIT


Page 187





SURROGATE STANDARDS


L17051231-02

L17051231-04

L17051231-06

L17051231-08

L17051231-10

L17051231-12

L17051231-14

WG615091-01

WG615091-02

01

01

01

01

01

01

01

01

01


1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1.00

1

2

3

4

5

6

-

-

-

-

-

-


2-Fluorobiphenyl

2-Fluorophenol

Nitrobenzene-d5

p-Terphenyl-d14

Phenol-d5

8270Method:





101 77.8 67.6 86.7 92.1 69.3

85.5 84.2 69.3 89.2 80.3 67.6

91.0 83.7 66.8 86.5 76.4 65.4

83.4 81.7 62.9 84.5 75.9 62.2

70.9 57.1 45.1 60.2 79.1 43.6

87.9 82.1 62.5 88.7 77.3 59.8

54.9 64.3 46.1 72.5 68.3 49.0

105 85.6 72.2 88.2 97.5 74.0

84.5 79.7 68.6 81.7 80.9 67.7

19

30

25

23

18

24

-

-

-

-

-

-

122

115

121

120

137

113





Page 188








2,4-Dichlorophenol

2-Nitrophenol


Acenaphthene

Benzo[a]pyrene


Fluoranthene


Phenol

1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol


2,4-Dinitrophenol

4-Nitrophenol



2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

51100

52000

53200

48200

50200

47200

50600

48100

48100

48000

57600

49000

49200

61500

51500

64100

43500

44100

47100

50900

52100

47000

52200

46100

48700

0.280

0.204

0.316

1.25

1.10

1.62

1.15

0.653

1.60

1.47

0.166

0.126

0.386

0.180

0.446

0.279

0.634

0.939

1.35

0.455

0.209

0.555

0.357

1.54

0.391

2.11

3.91

6.32

3.66

0.347

5.63

1.11

3.89

3.76

4.04

15.2

1.94

1.57

22.9

3.04

28.3

13.1

11.9

5.72

1.80

4.28

6.00

4.46

7.73

2.50


* Exceeds

%D

Criteria %D

RF

12M62316

WG615400


File ID:

Run Date:05/24/2017

Run Time:10:05

Analyst:MES

Workgroup (AAB#):

8270CMethod:



UNITS

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

UCL20

20

20

20

20

20

20

20

20

20

20

20

20

40

40

40

40

40

40

40

40

40

40

40

40

STDQC Key:

WATERMatrix:

Page 189



Instrument Run Log

Run Log ID: 82367

Page: 2 Approved: May 24, 2017


Instrument:

Analyst1:

Method:

Dataset:

Analyst2:

SOP: Rev:

CVAA1

LSJ

7470A/245.1

052317C.CSV

N/A

404 17

Calibration Std:

ICSA:

ICV Std:

ICSAB:

Post Spike:

Workgroups:

STD82023

N/A

STD82017

N/A

STD82023

615228

35

36

37

38

39

40

41

42

M7.052317.155351

M7.052317.155624

M7.052317.155857

M7.052317.160130

M7.052317.160401

M7.052317.160631

M7.052317.160904

M7.052317.161135

L17051231-03

L17051231-05

L17051231-07

L17051231-09

L17051231-11

L17051231-13

WG615387-15

WG615387-16


17-0751 IR MUD SILO

17-0751 IR MUD GRID A3 NE

17-0751 WEST BOREHOLE

17-0751 WEST RECLAIMER

17-0751 EAST RECLAIMER

CCV

CCB

4/40

4/40

4/40

4/40

4/40

4/40

1

1

1

1

1

1

1

1

05/23/17 15:53

05/23/17 15:56

05/23/17 15:58

05/23/17 16:01

05/23/17 16:04

05/23/17 16:06

05/23/17 16:09

05/23/17 16:11

Seq. File ID Sample ID Prep Dil Reference Date/Time

Comments:

Maintenance Log ID:

Int. Std:

CCV: LLCCV: Tuning Sol :

RGT39471 Stannous : RGT39469Hydroxylamine :

Page 190





5309621PDF File ID:




1,4-Dichlorobenzene

Hexachlorobutadiene

Pentachlorophenol


2,4-Dinitrophenol


4-Nitrophenol


2-Methylphenol

3-,4-Methylphenol

2,4-Dinitrotoluene

Hexachlorobenzene

Hexachloroethane

Nitrobenzene

Pyridine


CCC

CCC

CCC

CCC

SPCC

SPCC

SPCC

SPCC

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

50000

49900

55900

63000

50800

59200

61400

53000

57900

50400

51600

52500

49400

49500

53400

53400

49200

1.53

0.161

0.162

0.398

0.172

0.267

0.459

0.790

1.07

1.47

0.469

0.198

0.585

0.366

1.78

0.395

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

ug/L

0.300

11.9

26.1

1.60

18.4

22.8

6.00

15.7

0.900

3.20

4.90

1.30

1.00

6.90

6.80

1.60


* Exceeds

%D

Limit %D

RF

12M61777

WG609563


File ID:

Run Date:04/10/2017

Run Time:21:31

Analyst:SCB

ICal Workgroup:

8270CMethod:



QUCL30

30

40

30

40

40

40

30

30

30

30

30

30

30

30

30

Units

QC Key:STD

Page 192




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-01

L17051231-02

L17051231-02

L17051231-03

L17051231-04

911918

911919

911920

911921

911922

Samplenum

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

Container ID

1

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

1

2

3

1

2

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:26

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

BRG

BNB

CLS

CLS

JDH

AC

BRG

BNB

CLS

Seq.

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

Purpose

From

From

From

From

From

To

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

Products

TC-EX

8260

8270

TC-EX

8260

pH

pH

pH

pH

pH

Page 195




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-04

L17051231-05

L17051231-06

L17051231-06

911923

911924

911925

911926

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

4

1

2

3

1

2

1

2

3

4

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:26

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:55

22-MAY-2017 14:59

22-MAY-2017 16:26

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

JDH

AC

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

From

From

From

From

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

8270

TC-EX

8260

8270

pH

pH

pH

pH

Page 196




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-07

L17051231-08

L17051231-08

L17051231-09

L17051231-10

911927

911928

911929

911930

911931

Samplenum

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

Container ID

1

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

1

2

3

1

2

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

BRG

BNB

CLS

CLS

JDH

AC

BRG

BNB

CLS

Seq.

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

Purpose

From

From

From

From

From

To

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

Products

TC-EX

8260

8270

TC-EX

8260

pH

pH

pH

pH

pH

Page 197




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-10

L17051231-11

L17051231-12

L17051231-12

911932

911933

911934

911935

Samplenum

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

Container ID

1

1

1

1

Bottle:

Bottle:

Bottle:

Bottle:

1

2

3

4

1

2

3

1

2

1

2

3

4

LOGIN

PREP

PREP

STORE

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

EXT

DIG

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

EXT

DIG

A2

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:42

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

CLS

CPD

ZTB

CLS

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

CLS

JDH

AC

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

Purpose

From

From

From

From

To

To

To

To

Date/Time

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Relinquish

Products

Products

Products

Products

8270

TC-EX

8260

8270

pH

pH

pH

pH

Page 198




Login:

Account:

Project:

Samples:

Due Date:

L17051231

2755

2755.044

14

24-MAY-2017



L17051231-13

L17051231-14

L17051231-14

911936

911937

911938

Samplenum

Samplenum

Samplenum

Container ID

Container ID

Container ID

1

1

1

Bottle:

Bottle:

Bottle:

1

2

3

1

2

1

2

3

4

LOGIN

PREP

STORE

LOGIN

ANALYZ

LOGIN

PREP

PREP

STORE

COOLER

W1

TCL

COOLER

V1

COOLER

W1

EXT

DIG

W1

TCL

A2

V1

ORG4

W1

EXT

DIG

A2

22-MAY-2017 10:46

22-MAY-2017 11:26

22-MAY-2017 15:43

22-MAY-2017 10:46

22-MAY-2017 10:57

22-MAY-2017 10:46

22-MAY-2017 11:53

22-MAY-2017 14:59

22-MAY-2017 16:25

CLS

BNB

BRG

CLS

JDS

CLS

CPD

ZTB

CLS

BRG

BNB

CLS

CLS

JDH

AC

Seq.

Seq.

Seq.

Purpose

Purpose

Purpose

From

From

From

To

To

To

Date/Time

Date/Time

Date/Time

Accept

Accept

Accept

Relinquish

Relinquish

Relinquish

Products

Products

Products

TC-EX

8260

8270

pH

pH

pH

Page 199



Document Content(s)

EPAemail.DOCX.........................................................1-2

DRO Results.PDF.......................................................3-29

Totals and TCLP Results prelim.PDF....................................30-94

Totals and TCLP Results Final.PDF.....................................95-293


from: [email protected] [mailto:[email protected]] … · 2018-04-07 · from:...

Documents