freestanding hierarchical porous carbon film derived from

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Nano Res. Electronic Supplementary Material Freestanding hierarchical porous carbon film derived from hybrid nanocellulose for high-power supercapacitors Zhi Li 1 ( ), Kaveh Ahadi 1 , Keren Jiang 1 , Behzad Ahvazi 2 , Peng Li 3 , Anthony O. Anyia 2,4 , Ken Cadien 1 , and Thomas Thundat 1 ( ) 1 Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4, Canada 2 Biomass Conversion & Processing Technologies InnoTech, Alberta Innovates-Technology Futures, Edmonton, Alberta T6N 1E4, Canada 3 nanoFAB, University of Alberta, Edmonton, Alberta T6G 2V4, Canada 4 National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario K1A 0R6, Canada Supporting information to DOI 10.1007/s12274-017-1573-8 Figure S1 The morphology of CNF/CNC film before carbonization. (a) and (b) HiM images and (c) and (d) the AFM tomography highlighting the hierarchical structure. Address correspondence to Zhi Li, [email protected]; Thomas Thundat, [email protected]

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Page 1: Freestanding hierarchical porous carbon film derived from

Nano Res.

Electronic Supplementary Material

Freestanding hierarchical porous carbon film derivedfrom hybrid nanocellulose for high-power supercapacitors

Zhi Li1(), Kaveh Ahadi1, Keren Jiang1, Behzad Ahvazi2, Peng Li3, Anthony O. Anyia2,4, Ken Cadien1, and

Thomas Thundat1 ()

1 Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta T6G 2V4, Canada 2 Biomass Conversion & Processing Technologies InnoTech, Alberta Innovates-Technology Futures, Edmonton, Alberta T6N 1E4, Canada 3 nanoFAB, University of Alberta, Edmonton, Alberta T6G 2V4, Canada 4 National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario K1A 0R6, Canada

Supporting information to DOI 10.1007/s12274-017-1573-8

Figure S1 The morphology of CNF/CNC film before carbonization. (a) and (b) HiM images and (c) and (d) the AFM tomography highlighting the hierarchical structure.

Address correspondence to Zhi Li, [email protected]; Thomas Thundat, [email protected]

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| www.editorialmanager.com/nare/default.asp

Nano Res.

Figure S2 Additional morphology characterizations of CNF/CNC-900 film. (a) A low magnification HiM image showing the uniform porous structures in a large area; (b) the large scale AFM in an area of 20 μm × 20 µm.

Figure S3 (a) The TEM images of CNF/CNC film with ALD coating. The inset shows partially crystalline structure of the Al2O3 layer; (b) shows the corresponding electron diffraction pattern.

Figure S4 The selected area electron diffraction patterns of CNF/CNC-900 film (a) before and (b) after removing ALD Al2O3 layer. The (002) and (101) rings of carbon are overlapped with the (012) and (113) rings of Al2O3.

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www.theNanoResearch.com∣www.Springer.com/journal/12274 | Nano Research

Nano Res.

Figure S5 The HiM images of CNF-900 film.

Figure S6 The XPS survey of CNF/CNC-900 porous carbon film.