©francesc díaz. october 2004. fabrication and characterisation of new optical and photonic...

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©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

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Page 1: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

©Francesc Díaz. October 2004.

Fabrication and characterisation of new optical

and photonic crystalline materials

Francesc Diaz

Page 2: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Permanent staff:

Prof. Francesc Díaz

Prof. Magdalena Aguiló

Dra. Josefina Gavaldà

Dr. Jaume Massons

Dra. Rosa Solé

FiCMA members

Post-Docs:

Dr. Joan CarvajalDr. Xavier Mateos

PhD students:

Anna Aznar

Frank Güell

Isabel Parreu

Sandra Peña

Oscar Silvestre

Montse Galceran

Technicians: Agustí Montero

Nicolette Bakker (part time)

© Francesc Díaz. October 2004.

Ramon y Cajal Researcher:

Dra. M. Cinta Pujol

Page 3: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Active Projects in the field of nanomaterials

Design and fabrication of periodic micro and nanostructured materials for photonic processes . Applications to solid state laser and nanodevices.

MAT2002-04603-C05

Double tungstate crystals. Synthesis, characterisation and applications (DT-

CRYS).

STRP-505580-1.

Nanotechnologies, materials and processes (NMP-3). FP6 of EU.

© Francesc Díaz. October 2004.

Page 4: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Nd:YAGKTP

LASER Materials. Hosts and frecuency multipliers.

2pumping

Example of materials for doubling frecuency

Laser host Doubling frecuency Material.

© Francesc Díaz. October 2004.

Page 5: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Laser Radiation

Solid state laser

h STIMULATION

PHOTONh COLLECTION OF

COHERENT PHOTONS

© Francesc Díaz. October 2004.

Solid host

Active ion

Page 6: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

KGW:RE

KYW:RE

KYbW:RE

KErW:RE

KLuW:RE

LASER MATERIALS (Bulk single crystals)

KRE(WO4)2 family

Monoclinic phase

Space group, C2/c

© Francesc Díaz. October 2004.

P200100219 International patent of FiCMA recently transferred to two companies

Monoclinic phase of KRE(WO4)2

• Space group, C2/c

Page 7: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Epitaxial layer of KYW:Yb on (010) faces of KYW substrate

MICRO AND NANO SINGLE CRYSTAL LAYERS

© Francesc Díaz. October 2004.

P200302881 National patent of FiCMA

(110)

Page 8: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Thin disc laser.

pumping

Laser layer

© Francesc Díaz. October 2004.

Laser emissionsubstrate

Page 9: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Preparation of Nanopowders of KREW by Sol-Gel

Sol-Gel : Pechini Method

KGdW Monoclinic Phase

© Francesc Díaz. October 2004.

Page 10: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Studies

Effect of particle size on RE3+ doping

© Francesc Díaz. October 2004.

Effect of particle size on spectroscopy of RE3+ ions

6 Chem. Mat.

5 IEEE J. Quant. Elect.

3 Phys. Rev. B

2 APL

4 Opt. Mat.

1 JAP

1 J. Appl. Cryst.

1 Appl. Phys. B

2 Invited conferences

14 Oral presentations

in Int. Conferences

17 Posters

in Int. Conferences

Effect of layer thickness on RE3+ spectroscopy and lasing

2 Patents

Page 11: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

...EEEP 33

2210

IF SECOND ORDER:

...tSinEtSinEP 22020010

AS Sin2(t) = (1 - Cos(2t)) / 2, THEN IT RESULTS::

...22020010

2020 tCosEtSinEEP

• IF THE CAPACITY OF POLARISATION IS INTENSE, THE RELATION

BETWEEN ELECTRICAL FIELD AND THE POLARISATION IS POLINOMIAL

(HIGHER ORDER TERMS= NON LINEARS). THEREFORE, IT TAKES PLACE THE

NON-LINEAL OPTICS

Non lineal Optics.

© Francesc Díaz. October 2004.

Page 12: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

RTP

RTP:Nb

RTP:(Nb,Er)

RTP:(Nb,Yb)

NLO MATERIALS (Bulk single crystals)

© Francesc Díaz. October 2004.

RbTiOPO4 family. Orthorombic phase

Spacel group of simetry: Pna21

Orthorombic phase

Spacial group of simetry: Pna21

Page 13: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Fabrication of photonic crystals of the KTP family

1-D photonic crystals in PPRTP2-D photonic crystals in KTP

© Francesc Díaz. October 2004.

Page 14: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Studies

QPM Effect characterisation

© Francesc Díaz. October 2004.

3 Chem. Mat.

2 Phys. Rev. B

2 APL

1 Opt. Mat.

1 JAP

1 J. Appl. Cryst.

3 Oral presentations

in Int. Conferences

7 Posters

in Int. Conferences

Material fabrication processes

Page 15: ©Francesc Díaz. October 2004. Fabrication and characterisation of new optical and photonic crystalline materials Francesc Diaz

Thank you

for your attention.

Tarragona, october 2004