for supply reorder number: 487-3487-1485-7files.oceusa.com/media/assets/pdfs/msds/pdf/oce...

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MSDS Number: OCE2114 Océ Imagistics Inc. Issued: Revised: July 15, 2010 Product Name: Black Toner 485-7 (Vendor Code V031) Page: 1 of 6 Material Safety Data Sheet For Supply Reorder Number: 485-7 SECTION I-PRODUCT IDENTIFICATION Product Name: Black Toner Item 485-7 (Also manufactred as TN-3230, TN-3280, TN-620, TN-650, Reorder Number: 485-7 (Vendor Code V031) Manufacturer: Océ Imagistics Inc. Address: 100 Oakview Drive City: Trumbull State: CT Zip: 06611-4724 For MSDS copies: (773) 714 -4807 Emergency/Chemtrec: 800-424-9300 Effective Date: July 15, 2010 Print Date: 07/15/10 SECTION II - HAZARDOUS INGREDIENTS Additional Information May Contain Non-Hazardous Ingredients: Styrene-acrylate copolymer, Fatty acid ester, Polymethyl methacrylate, Silicone dioxide (amorphous) SECTION III - HAZARD IDENTIFICATION Emergency Overview: Black powder with no odor. High concentrations of dust suspended in air may present a dust explosion hazard. Inhalation of dust may cause minor respiratory irritation. Prolonged inhalation overexposure may result in lung damage. Relevant Routes of Exposure: Skin, eyes, inhalation Signs and Symptoms of Acute Overexposure: May cause mild eye irritation. This product is not a skin irritant. Signs and Symptoms of Chronic Overexposure: Prolonged inhalation of dust in excess of the exposure limits (as with any nuisance dust) may result in lung damage. Overexposure to dust in the normal use of this product is not expected. Medical Conditions Generally Aggravated By Exposure: None known. Potential Health Effects: Eyes: May cause mild irritation. Skin: No adverse effects expected Ingestion: No adverse effects expected. This product is not acutely toxic by Chemical Name: Styrene-acrylate Toner (Mixture). Chemical Name CAS No. EC No. %W/W EU Hazard Symbols EU Risk Phrases Styrene-acrylate copolymer 25767-47-9 Not applicable. 84 - 87 Not classified. Not classified. Carbon Black (bound) 1333-86-4 215-609-9 5 - 7 Not classified. Not classified. Fatty Acid Ester Confidential Not applicable. 4 - 5 Not classified. Not classified. PMMA 9011-14-7 Not applicable. 1 - 3 Not classified. Not classified. Styrene-acrylic resin Confidential Not applicable. 1 - 2 Not classified. Not classified. Silicon Dioxide (amorphous) 844491-94-7 430-570-1 < 1 Not classified. Not classified. Silicon Dioxide (amorphous) 7631-86-9 231-545-4 < 1 Not classified. Not classified. TN-3250, TN-3290, TN-3235, TN-3285)

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Page 1: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page: 1 of 6

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7

SECTION I - PRODUCT IDENTIFICATIONProduct Name: Black Toner Item 485-7 (Also manufactred as TN-3230, TN-3280, TN-620, TN-650,

Reorder Number: 485-7 (Vendor Code V031)Manufacturer: Océ Imagistics Inc.Address: 100 Oakview DriveCity: TrumbullState: CTZip: 06611-4724For MSDS copies: (773) 714 -4807 Emergency/Chemtrec: 800-424-9300Effective Date: July 15, 2010Print Date: 07/15/10

SECTION II - HAZARDOUS INGREDIENTS

Additional InformationMay Contain Non-Hazardous Ingredients: Styrene-acrylate copolymer, Fatty acid ester, Polymethyl methacrylate,Silicone dioxide (amorphous)

SECTION III - HAZARD IDENTIFICATIONEmergency Overview: Black powder with no odor. High concentrations of dust suspended in air

may present a dust explosion hazard. Inhalation of dust may causeminor respiratory irritation. Prolonged inhalation overexposure mayresult in lung damage.

Relevant Routes of Exposure: Skin, eyes, inhalationSigns and Symptoms of AcuteOverexposure:

May cause mild eye irritation. This product is not a skin irritant.

Signs and Symptoms of ChronicOverexposure:

Prolonged inhalation of dust in excess of the exposure limits (as with anynuisance dust) may result in lung damage. Overexposure to dust in thenormal use of this product is not expected.

Medical Conditions GenerallyAggravated By Exposure:

None known.

Potential Health Effects: Eyes: May cause mild irritation. Skin: No adverse effects expected Ingestion: No adverse effects expected. This product is not acutely toxic by

Chemical Name: Styrene-acrylate Toner (Mixture).

Chemical Name CAS No. EC No. %W/W EU Hazard Symbols EU Risk Phrases

Styrene-acrylate copolymer 25767-47-9 Not applicable. 84 - 87 Not classified. Not classified.Carbon Black (bound) 1333-86-4 215-609-9 5 - 7 Not classified. Not classified.Fatty Acid Ester Confidential Not applicable. 4 - 5 Not classified. Not classified.PMMA 9011-14-7 Not applicable. 1 - 3 Not classified. Not classified.Styrene-acrylic resin Confidential Not applicable. 1 - 2 Not classified. Not classified.Silicon Dioxide (amorphous) 844491-94-7 430-570-1 < 1 Not classified. Not classified.Silicon Dioxide (amorphous) 7631-86-9 231-545-4 < 1 Not classified. Not classified.

TN-3250, TN-3290, TN-3235, TN-3285)

Page 2: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

SECTION III - HAZARD IDENTIFICATIONingestion.

Inhalation: Could be a route of exposure, but unlikely under normal use. Inhalationof toner powder may cause mucous membrane and respiratory irritation.Prolonged and repeated overexposure may cause lung damage.

Carcinogenicity: NTP: No IARC: In 1996 IARC re-evaluated carbon black as a group 2B carcinogen

(possible human carcinogen). Carbon black is a minor component of thetotal toner mixture. We believe that IARC’s findings are not applicable tothe typical uses and levels of exposure to toners or developers by ourcustomers and service personnel.

OSHA: No ACGIH: No OTHER: No

SECTION IV - FIRST AID MEASURESEyes: Do not rub eyes. Immediately flush with plenty of running cool to

lukewarm water, holding eye lids open to assure thorough rinsing. Getmedical attention if irritation persists or for foreign body in the eyes.

Skin: Wash with soap and water.Ingestion: If swallowed, dilute with water. DO NOT induce vomiting. Never give

fluids or induce vomiting if the victim is unconscious or havingconvulsions. Get medical attention.

Inhalation: Remove person to fresh air. Wash nostrils, rinse mouth. If irritation orpulmonary symptoms develop, consult a physician.

SECTION V - FIRE FIGHTING PROCEDURESFlammable Limits in Air (% byVolume): Not determinedFlash Point: Not applicableAutoignition Temperature: Not determinedExtinguishing Media: Water fog, carbon dioxide, dry chemical, halon or foam.Fire Fighting Instructions: Wear self-contained breathing apparatus and protective clothing to

prevent contact with skin and eyes. Do not use methods that may createa dust cloud, such as high pressure water.

Unusual Fire and ExplosionHazards:

Toner powder can form explosive mixtures with air at highconcentrations.

Known or Anticipated HazardousProducts of Combustion:

Emits carbon dioxide, carbon monoxide, nitrogen and smoke under fireconditions.

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MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page:

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7

Page 3: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

3 of 6

SECTION VI - ACCIDENTAL RELEASE MEASURESAccidental Release Measures: Carefully sweep material onto paper, or vacuum taking care not to

generate airborne dust. Do not use vacuum if large amounts arereleased due to risk of dust explosion.

Personal Precautions: Avoid inhalation of dust.Environmental Precautions: It is recommended to keep away from drains, surface and ground water.Methods for Cleanup: Sweep material onto paper, or vacuum small amounts.Large Spill: Not sold in large quantities.Small Spill: Sweep material onto paper or vacuum small amounts. Avoid generating

airborne dust.

SECTION VII - HANDLING AND STORAGEHandling: Avoid inhalation of toner dust. Avoid direct contact with toner. Keep

container closed when not in use.Storage: Store in a cool, dry place. Keep container closed. Keep out of the reach

of children.Other Precautions: Not required under normal use.

SECTION VIII - EXPOSURE CONTROLS & PERSONAL PROTECTIONEngineering Controls: None required with normal use.Ventilation Requirements: General office ventilation.Personal Protective Equipment: Eye/Face Protection: Not required under normal use. Skin Protection: Not required under normal use. Respiratory Protection: Not required under normal use.

Other Protective Clothingor Equipment:

Not required under normal use.

Exposure Guidelines: See Section II

SECTION IX - PHYSICAL & CHEMICAL PROPERTIESAppearance: Fine black powder with no odorBoiling Point: Not applicableColor: BlackFreezing Point: No data availableMelting Point: 120°COctanol/Water PartitionCoefficient:

No data available

Odor: No odorOdor Threshold: No data availablePercent Volatile: Not applicable

MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page:

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7

Page 4: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

4 of 6

SECTION IX - PHYSICAL & CHEMICAL PROPERTIESpH Value: Not applicablepH Concentration: Not applicablePhysical State: PowderReactivity in Water: NoneSolubility in Water: NegligibleSpecific Gravity or Density(Water=1):

1.15

Vapor Density: Not applicableVapor Pressure: Not applicableVapor Pressure Temperature: Not applicableVolatile Organic Compounds: No data availableWater/Oil Distribution Coefficient: No data availableWeight Per Gallon: Not applicable

SECTION X - STABILITY AND REACTIVITYStability: Stable Conditions to Avoid: Avoid excessive heat and electrical discharge. Do not throw into fire.Incompatibility With OtherMaterials:

Strong oxidizing materials and reducing agents.

Hazardous DecompositionProducts:

Thermal decomposition may release carbon monoxide, carbon dioxide,nitrogen and smoke.

Hazardous Polymerization: Will not occur. Conditions to Avoid: Not applicable

SECTION XI - TOXICOLOGICAL INFORMATIONVALUE ANIMAL ROUTES COMPONENTS

LD50: >2,000 mg/kg* Rat Oral ProductLC50: >5 mg/l/1 hr. Rat Inhalation Product

Additional InformationNote: This product tested negative in the AMES test for mutagenicity.

SECTION XII - ECOLOGICAL INFORMATIONEcological Information: No data available

SECTION XIII - DISPOSAL CONSIDERATIONSDisposal Considerations: Dispose in accordance with local, state, and federal regulations.

SECTION XIV - TRANSPORT INFORMATIONU.S. DOT

MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page:

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7

Page 5: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

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SECTION XIV - TRANSPORT INFORMATIONProper Shipping Name: Not regulatedHazard Class: Not applicableID Number: Not applicablePacking Group: Not applicableLabels: NoneSpecial Provisions: NonePackaging Exceptions: Not applicableNon-Bulk Packaging: Not applicableBulk Packaging: Not applicableAir/Rail Limit: NoneAir Cargo Limit: NoneVessel Stowage: Not applicableOther Stowage: Not applicableReportable Quantity: None

AIR - ICAO OR IATAProper Shipping Name: Not regulatedHazard Class: Not applicableID Number: Not applicableRisk: Not applicablePacking Group: Not applicableHazard Labels: NonePacking Instructions: Not applicableAir Passenger/Cargo Limit PerPackage:

Not applicable

Packing Instruction - Cargo: Not applicableAir Cargo Limit Per Package: Not applicableSpecial Provisions Code: None

WATER - IMDGProper Shipping Name: Not regulatedHazard Class: Not applicableID Number: Not applicablePacking Group: Not applicableRisk: Not applicableEmergency Procedures Code: Not applicableMedical First Aid Guide Code: Not applicable

SECTION XV - REGULATORY INFORMATIONU.S. Federal Regulations: See belowState Regulations: This product contains no chemicals subject to California Proposition 65.International Regulations: EU: Not classified as a dangerous material.

Canada: Not a controlled product.

MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page:

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7

Page 6: For Supply Reorder Number: 487-3487-1485-7files.oceusa.com/media/Assets/PDFs/MSDS/PDF/OCE 2114.pdf · 2014. 6. 24. · 487-3487-1485-7 SECTION I- PRODUCT IDENTIFICATION Product Name:

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SECTION XV - REGULATORY INFORMATIONSARA Hazards:

Acute: NoChronic: NoReactive: NoFire: NoPressure: No

Additional InformationThis product does not contain chemical or chemical compounds listed in the following SARA Title III categories:Extremely Hazardous Substances (302), Toxic Chemical Release Reporting (313).All the components of this product are listed in the EPA TSCA Inventory.

SECTION XVI - OTHER INFORMATIONNFPA Codes:

Health: 1Flammability: 1Reactivity: 0Other: 0

HMIS Codes:Health: 1Flammability: 1Reactivity: 0Protection:

Other Information: Keep out of reach of children

MSDS Number: OCE2114Océ Imagistics Inc.

Issued:Revised:

July 15, 2010

Product Name: Black Toner 485-7 (Vendor Code V031) Page:

Material Safety Data SheetFor Supply Reorder Number:

487-3

Material Safety Data SheetFor Supply Reorder Number:

487-1

Material Safety Data SheetFor Supply Reorder Number:

485-7