feira e congresso internacionais. - performance...
TRANSCRIPT
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Performance MaterialsPolyurethane Systems
Tadeu Nicodemus Ribeiro07.11.2018
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BASF at a glance Biggest Chemical
Supplier for Automotive Industries.
Sales 2017: €64,475 million (12% growth)
Thereof Automotive Driven Sales:
€11,400 million
EBIT 2017: €8,522 million
Expenditures for R&D: €1,888 million
Thereof ~ €210 million with direct
automotive relevance
Number of research and
development employees:
10,110.
Over than 130,000 customers.
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.
Freeport
Geismar
Kuantan
Antwerp
Florham Park
São Paulo
Singapore
Hongkong
Ludwigshafen
Nanjing
Regional centers
Verbund sites
Selected production
sites
Most important
reseach sites
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Sales
€2.1bnEmployees
~3,833
12/11/2018
Brasil
Perfis
Fonte: MARIS, Visão consolidada GR
Interno
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BASF diverse portfolio contributes to sustainable future
Crop Protection
PerformanceProducts
Dispersions & Pigments
Care Chemicals
Nutrition & Health
Performance Chemicals
Functional Materials & Solutions
AgriculturalSolutions
Oil & Gas
Oil & Gas
Chemicals Functional Materials & Solutions
Catalysts
ConstructionChemicals
Coatings
Performance Materials
Petrochemicals
Monomers
Intermediates
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E&EPowertrain ChassisExteriorInterior
▪ Dispersions
▪ Engineering plastics
▪ Elastomers
▪ Foams
▪ Leather and textile chemicals
▪ Plastic additives
▪ Polyurethanes
▪ Coatings
▪ Chemicals for coatings
▪ Engineering plastics
▪ Pigments
▪ Polyurethanes
▪ Battery materials
▪ Brake fluids
▪ Catalysts
▪ Engine Coolants
▪ Engineering plastics
▪ Fuel additives
▪ Lubricants and oils
▪ Polyurethanes
▪ Composites
▪ Engineering plastics
▪ Metal treatment chemicals
▪ Engineering plastics
▪ Elastomers
▪ Polyurethanes
BASF Automotive Solutions
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We are a leading partner for future mobility
▪ Global market
leader
Mobile Emissions Automotive
Coatings
Cellasto® Performance
Materials
Fuel and Lubricant
Solutions
BASF Automotive Solutions
We offer a broad portfolio to meet main automotive trends, working in synergy with our customers to develop
more efficient vehicles, with technology, innovation, safety and quality.
▪ No 2 in automotive
OEM coatings
▪ Chemetall acquisition
▪ Global market
leader in NVH
solutions
▪ No 1 in plastic
solutions for
lightweight
▪ No 1 for coolants
since 1929
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Polyurethane SystemsAutomotive Application
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Cellasto®
Undercarpet
Headliner
Steering WheelsDashboard Seating and
Head rest
Door Panel
Trunk Floor and
Spare Wheel Cover
Back Passenger Shelf
Spoiler
Gear Knob
Engine Cover
Air Filter
Hoodliner
Cable
Encapsulation
Window
Encapsulation
Adhesives
Sun VisorElastoflex®
Elastofoam®
Elastolit®
Elastonat®
Elastoskin®
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Ultrasim®
Foaming simulator for
automotive interior
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Ultrasim®
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CAE Tool Helps to Optimize the Design of Plastic Parts
◼ Anisotropic◼ Nonlinear ◼ Strain-rate sensitive◼ Tension-compression
asymmetric ◼ Failure modeling
Material modelling -
Integrative Simulation
CAE Methods +
Mathematical
Optimization
ULTRASIM®
◼ Process simulation◼ Mechanical simulation◼ Mathematical optimization
(parameter, shape, topology)
Calculate the part right Calculate the right part
22
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Need
◼ Lightweight
◼ Meet or exceed safety standards
◼ Optimize manufacturing time
BASF Solution
◼ Design and simulation expertise using Ultrasim®
◼ Polyamide chemistry and processing expertise
The Results
◼ One of the world’s 1st front end carriers made entirely of plastic
◼ Lightweight, safe
◼ Reduces assembly time
Front end carrier for Golf 7
8
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PU foaming simulation identifies critical aspects at an early stage of a project
and therefore can increase production efficiency at our customers!
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Ultrasim®
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Honeycomb
Composite based on PUR
matrix.
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Low density composite
High Mechanical Properties
Low emission (VDA 278)
Sub-sequent adhesion
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Core layer: Paper Honeycomb
Reinforcing fiber: Glass Mat
Matrix: Polyurethane
Elastoflex E®
Honeycomb
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Honeycomb
Polyol Isocyanate
Honeycomb paper and fiber sandwichPUR
Spraying Moulding
Final Piece
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Honeycomb
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Honeycomb
◼ Core A-wave 90 g/m²
◼ Core thickness 10 mm
◼ Reinforcing fibre 450 g/m² glass
◼ Density [DIN EN ISO 845] 314 kg/m³
◼ Modulus of flexure longitudinal [DIN EN 310] 2650.0 N/mm²
◼ Impact strength longitudinal [DIN EN ISO 179-1/1fU] 27.90 kJ/m²
◼ Modulus of flexure transversal [DIN EN 310] 2018.3 N/mm²
◼ Impact strength transversal [DIN EN 179-1/1fU] 17.61 kJ/m²
The given properties are exemplarily measured from one part, the mechanical properties depends a lot on the used core
layer, type of reinforcement fibre and fibre area weight.
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HoneycombFeatures and Information
• Low density: 350kg/m³
• High productivity
• Anti dropping systems
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ELASTOSKIN®
Soft polyurethane elastomer
based on aromatic MDI
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Elastoskin ®
Application
Release agent - 15 Seg.
IMC application - 60-75 sec.
Elastoskin application - 90-120 sec.
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Elastoskin ®
Application
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Elastoskin ®
Mechanical Properties
Hardness
Shore A
Tear strenght
(kN/m)Elongation (%)
Tensile
Strenght
(Mpa)
Elastoskin® Aromatic PUR 67 50 350 14
Cast PVC 77 40 250 13
Cast TPU 77 50 350 8
Vacuum Form TPO 75 25 330 10
Vacuum Form PVC/ABS 93 64 140 16
Aliphatic Spray PUR 80 25 120 6
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Elastoskin ®
Temperature stability
-60
-50
-40
-30
-20
-10
0
TPO CastPVC Cast TPU Elastoskin®
Glass Transition Temperature
Te
mp
era
ture
(ºC
)
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Elastoskin ®
Color stability
0
1
2
3
4
5
6
7
8
9
TPO CAST PVC CAST TPU Spray Skin
Arizona Sunlight Exposure - 200,000 Langleys(47,962KJ) @ 110°C
De
lta
E R
ete
ntio
n
(co
lor
an
d g
loss c
ha
ng
e)
9 = no change
Elastoskin®
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Elastoskin®
Technology comparison
PVC/ABS
Vacuum
molded
PVC
Rotomoulding
TPU aliphatic
Rotomoulding
PUR aliphatic
Spray
Elastoskin
PUR
Cost
Texture Definition
Fogging
Colored Flexibility
Color and gloss
maintenance
Abrasion Resistance
Soft Touch
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Elastoskin ®
Features and Information
• High quality texture.
• Low fogging.
• High abrasion and UV resistance.
• Large color and gloss range.
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Headliner and
Hoodliner
Semi rigid thermoformable
acoustic foam
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Low density foams (20 to 35kg/m³)
Acoustic Insulation
Thermoformable technology
Low emission
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Hoodliner and HeadlinerAcoustic Behavior
When the mechanical wave, represented by “W”,
reaches the surface, it is divided in
• R = Reflexed portion
• A = Absorbed portion
• T = Transferred portion
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Hoodliner and HeadlinerAcoustic Behavior
When the mechanical wave, represented by “W”,
reaches the surface, it is divided in
• R = Reflexed portion
• A = Absorbed portion
• T = Transferred portion
As higher is the absorbed portion, higher is the acoustic
absorption and comfort.
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Hoodliner and Headliner
How we increase the absorption:
• The bigger is the internal surface (porosity),
the better is the absorption
• The thicker is the skin, lower is the
percentage of the absorption
• Open and connected cell structure is the best
option to increase the absorption.
Close cell
Open cell
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Hoodliner and HeadlinerAnalysis
α-Cabin
• Big Machine
• Sound waves in random direction
• Big sample needed
Kundt`s Tube
• Small size machine
• Sound wave moves in normal direction
• Small sample needed
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Hoodliner and HeadlinerAnalysis
0
0,1
0,2
0,3
0,4
0,5
0,6
0,7
0,8
0,9
1
0 1000 2000 3000 4000 5000 6000 7000
Ab
so
rpti
on
Co
eff
icie
nt
f (Hz)
Normal Acoustic
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Hoodliner and HeadlinerProcess
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Hoodliner and HeadlinerProcess
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Headliner and HoodlinerFeatures and Information
• High acoustic properties.
• Low odor and VOC.
• Low density.
• High productivity.
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11.03.201641
Other Applications
Performance Materials for
Automotive Industry
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Other ApplicationsPerformance Materials for Automotive Industry
Automotive Filter – Elastofoam®
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Automotive filter
◼ Density [DIN EN ISO 845] 260 - 490kg/m³
◼ Demould time 120 sec.
◼ Elongation at tear After aging 21 days of aging in deionized water at 80 ºC 342,5%
◼ Compression stress at 40%, N/cm After aging 500 h at 110ºC 26,5%
The results were obtained from parts collected from our customers, and met all standards. Ex. TL 848 2017.
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Other ApplicationsPerformance Materials for Automotive Industry
Undercarpet – Elastoflex W®
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Other ApplicationsPerformance Materials for Automotive Industry
Cavity Filling – Elastoflex W®
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Other ApplicationsPerformance Materials for Automotive Industry
Cavity Filling – Elastoflex W®
Truck Bed Liner– Elastocoat®
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Other ApplicationsPerformance Materials for Automotive Industry
Cavity Filling – Elastoflex W®
Truck Bed Liner– Elastocoat®
Engine Cover– Elastoflex®
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Engine Cover for Volvo
Need
◼ Lightweight
◼ Safe
◼ High quality appearance
◼ Functional design
BASF Solution
◼ Material expertise (tailor made Elastofoam® for application)
◼ Design expertise
The Results
◼ One step production process
◼ Design integrates acoustic and mechanical properties
◼ Lightweight (< 2kg!)
◼ Complies with safety standards
7
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Other ApplicationsPerformance Materials for Automotive Industry
Cavity Filling – Elastoflex W®
Truck Bed Liner– Elastocoat®
Engine Cover– Elastoflex®
Ultramid® Deep Gloss - EP
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Other ApplicationsPerformance Materials for Automotive Industry
Cavity Filling – Elastoflex W®
Truck Bed Liner– Elastocoat®
Engine Cover– Elastoflex®
Ultramid® Deep Gloss - EP
Basotect® - Acoustic Insulation
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Thank You!
Performance Materials – Transportation
Tadeu N. Ribeiro 55 11 944573049
César L. Valério 55 11 998824009
Marcos Carreiro 55 11996364036
Luiz Roxo 55 11 996584536
Egídio Júnior 55 11996891582
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