f-area tank farm groundwater sampling and analysis plan (u) · ftf groundwater sampling and...

Prepared by: Savannah River Nuclear Solutions, LLC Savannah River Remediation, LLC Savannah River Site Aiken, SC 29808 Prepared for U.S. Department of Energy under Contract No. DE-AC09-08SR22470

United States Department of Energy Savannah River Site

F-Area Tank Farm Groundwater Sampling and Analysis Plan (U)

SRNS-RP-2012-00287 Revision 1 November 2012

DISCLAIMER

This document was prepared in conjunction with work accomplished under Contract No. DE-AC09-08SR22470 with the U.S. Department of Energy. This work was prepared under an agreement with and funded by the U.S. Government. Neither the U.S. Government or its employees, nor any of its contractors, subcontractors or their employees, makes any express or implied: 1. warranty or assumes any legal liability for the accuracy, completeness, or for the use or results of such use of any information, product, or process disclosed; or 2. representation that such use or results of such use would not infringe privately owned rights; or 3. endorsement or recommendation of any specifically identified commercial product, process, or service. Any views and opinions of authors expressed in this work do not necessarily state or reflect those of the United States Government, or its contractors, or subcontractors

Printed in the United States of America Prepared for

U. S. Department of Energy and

Savannah River Site Nuclear Solutions, LLC Aiken, South Carolina

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page i of v

TABLE OF CONTENTS Section Page

LIST OF FIGURES ....................................................................................................................... ii

LIST OF TABLES ........................................................................................................................ iii

LIST OF ACRONYMS AND ABBREVIATIONS .................................................................... iv

1.0 INTRODUCTION ............................................................................................................ 1 1.1 Sampling Unit Name and Purpose for Sampling ............................................................... 1 1.2 Sampling Unit Location ....................................................................................................... 2 1.3 Statement of Broad Objectives for the Sampling .............................................................. 2

2.0 SAMPLING UNIT BACKGROUND ............................................................................. 2 2.1 Sampling Area Physical and Geographical Description ................................................... 2

2.1.1 Physical Setting .............................................................................................................. 2 2.1.2 Climate ........................................................................................................................... 3 2.1.3 Hydrostratigraphy .......................................................................................................... 3

2.2 Operational History .............................................................................................................. 4 2.3 Previous Investigations/Regulatory Actions ....................................................................... 6

2.3.1 Tank 8 Release and Investigation .................................................................................. 7 2.3.2 F-Area Tank Farm Groundwater Monitoring ................................................................ 7 2.3.3 FFA Operable Unit Investigations ................................................................................. 8

2.4 Summary of Existing Data ................................................................................................... 9

3.0 PROJECT DATA QUALITY OBJECTIVES (DQOS) .............................................. 11 3.1 Groundwater at the F-Area Tank Farm ........................................................................... 11

3.1.1 State the Problem ......................................................................................................... 11 3.1.2 Identify Goals of the Study .......................................................................................... 12 3.1.3 Identify Information Inputs .......................................................................................... 12 3.1.4 Define the Boundaries of the Study ............................................................................. 13 3.1.5 Develop the Analytical Approach ................................................................................ 13 3.1.6 Specify Performance or Acceptance Criteria ............................................................... 15 3.1.7 Develop the Plan for Obtaining the Data (Project Quality Objectives) ....................... 16

4.0 SAMPLING DESIGN AND RATIONALE ................................................................. 17 4.1 Rationale for FTF Groundwater Sample and Analysis Plan .......................................... 18

4.1.1 Groundwater Sampling of Newly Installed and Existing Monitoring Wells ............... 18 4.1.2 Data Evaluation ............................................................................................................ 19 4.1.3 Reporting ...................................................................................................................... 19

5.0 ANALYTICAL PLAN ................................................................................................... 19 5.1 Data Quality Levels ............................................................................................................ 20 5.2 Field Analytical Sampling Quality Assurance/Quality Control ..................................... 20 5.3 Sample Matrix Table .......................................................................................................... 22 5.4 Sample Location Map ......................................................................................................... 22

6.0 FIELD IMPLEMENTATION ....................................................................................... 22 6.1 List of Sampling/Collection Equipment ............................................................................ 23 6.2 Investigation Derived Waste .............................................................................................. 23

7.0 REFERENCES ............................................................................................................... 24

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page ii of v

LIST OF FIGURES

FIGURE 1: LOCATION OF F AREA IN THE GENERAL SEPARATIONS AREA AT THE

SAVANNAH RIVER SITE ............................................................................... 29

FIGURE 2: LOCATION OF THE F-AREA TANK FARM AT F AREA, SRS .......................... 30

FIGURE 3: HYDROSTRATIGRAPHIC UNITS AT F AREA (MODIFIED FROM AADLAND ET

AL, 1995) ...................................................................................................... 31

FIGURE 4: POTENTIOMETRIC SURFACE AND GROUNDWATER FLOW DIRECTIONS AT

THE F-AREA TANK FARM ........................................................................... 32

FIGURE 5: SURFACE AND GROUNDWATER FLOW AT THE GENERAL SEPARATIONS AREA

(MODIFIED FROM SRR, 2011) ..................................................................... 33

FIGURE 6: LOCATION OF FFA OUS AND KEY FACILITIES AT THE F-AREA TANK FARM

...................................................................................................................... 34

FIGURE 7: HISTORICAL NONVOLATILE BETA AND TECHNETIUM-99 ACTIVITIES IN

MONITORING WELL FTF 28 ....................................................................... 35

FIGURE 8: LOCATION OF UAZ AND LAZ WELLS AT AND NEAR THE F-AREA TANK

FARM............................................................................................................ 36

FIGURE 9: LOCATION OF WELLS FOR THE F-AREA TANK FARM GROUNDWATER

MONITORING NETWORK ............................................................................. 37

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page iii of v

LIST OF TABLES

TABLE 1: DATA QUALITY OBJECTIVES WORKSHEET FOR GROUNDWATER AT THE F-AREA TANK FARM ....................................................................................... 39

TABLE 2: MONITORING PARAMETERS FOR THE F-AREA TANK FARM GROUNDWATER

MONITORING PLAN ..................................................................................... 40

TABLE 3: SAMPLING MATRIX TABLE ............................................................................. 41

TABLE 4: LABORATORY CONTRACT REQUIRED DETECTION LIMITS COMPARED TO

REGIONAL SCREENING LEVELS FOR SURFACE OR GROUNDWATER MEDIA

...................................................................................................................... 43

TABLE 5: MINIMUM DETECTED ACTIVITY COMPARED TO WATER RADIOLOGICAL

MCL/PRGS ................................................................................................. 44

TABLE 6: MINIMUM FIELD QUALITY CONTROL/QUALITY ASSURANCE SAMPLING

REQUIREMENTS ........................................................................................... 45

TABLE 7: LABORATORY ANALYTICAL SPECIFICATIONS TABLE FOR TAL/TCL

ANALYTES FOR GROUNDWATER MEDIA .................................................... 46

TABLE 8: LABORATORY ANALYTICAL SPECIFICATIONS TABLE FOR RADIOLOGICAL

ANALYTES IN SOIL, SEDIMENT, SURFACE, AND GROUNDWATER MEDIA .. 47

TABLE 9: PRESERVATIVES, HOLDING TIMES, AND SAMPLE CONTAINERS FOR

GROUNDWATER COLLECTED AT THE FTF................................................. 48

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page iv of v

LIST OF ACRONYMS AND ABBREVIATIONS

Acronym Meaning

CERCLA Comprehensive Environmental Response, Compensation and Liability Act Ci curies cm centimeter CRDL Contract Required Detection Limit CSM Conceptual Site Model DQD Decision Quality Data DQI Data Quality Indicator DQO Data Quality Objective ERDMS Environmental Restoration Data Management System FFA FIPSL

Federal Facility Agreement F-Area Inactive Process Sewer Line

ft3 cubic feet ft feet FTF F-Area Tank Farm GAU Gordon Aquifer Unit GCP General Closure Plan GWMP Groundwater Monitoring Plan GSA HTF

General Separations Area H-Area Tank Farm

IDW Investigation Derived Waste in inches km2 square kilometers L liters LAZ Lower Aquifer Zone LLC Limited Liability Company m meter MCL Maximum Contaminant Level MDA Minimum Detected Activity mi2 square miles mL milliliters OU Operable Unit PA Performance Assessment pCi pico curies PQO Project Quality Objective PRG Preliminary Remediation Goal PVC polyvinyl chloride QA Quality Assurance QAPP Quality Assurance Project Plan QC Quality Control RCRA Resource Conservation and Recovery Act RFI RCRA Facility Investigation

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page v of v

LIST OF ACRONYMS AND ABBREVIATIONS

Acronym Meaning

RI Remedial Investigation ROD Record of Decision RPD Relative Percent Difference RSL USEPA Regional Screening Level SAP Sampling and Analysis Plan SCDHEC South Carolina Department of Health and Environmental Control SRNS Savannah River Nuclear Solutions, LLC SRR SRS

Savannah River Remediation, LLC Savannah River Site

ssEQL Sample Specific Estimated Quantitation Limit mg milligrams TAL Target Analyte List TCL Target Compound List UAZ Upper Aquifer Zone UCL Upper Control Limit USDOE United States Department of Energy USEPA United States Environmental Protection Agency UTRA Upper Three Runs Aquifer VV Verified and Validated WSRC Westinghouse Savannah River Company, LLC prior to December 8, 2005;

Washington Savannah River Company, LLC after December 8, 2005

FTF Groundwater Sampling and Analysis Plan (U) SRNS-RP-2012-00287 Savannah River Site Revision 1 November 2012 Page 1 of 48

1.0 INTRODUCTION

This Sampling and Analysis Plan (SAP) for the F-Area Tank Farm (FTF) was prepared

using the approved template for Sampling and Analysis Plans. The SAP template was

prepared in accordance with the United States Environmental Protection Agency

(USEPA) Uniform Federal Policy for Quality Assurance Project Plans (USEPA et al

2005) and the Area Completion Projects Programmatic Quality Assurance Project Plan

for Environmental Data Collection and Management (SRNS 2012a). Project- or task-

specific information of the FTF is documented in the SAP and refers to the program level

Quality Assurance Program Plan (QAPP) (SRNS 2012a) for the program level quality

objectives, standard operating procedures, and quality assurance/quality control

procedures.

1.1 Sampling Unit Name and Purpose for Sampling

As required by the Industrial Wastewater General Closure Plan for F-Area Waste Tank

Systems (SRR 2011) (herein referred to as the General Closure Plan [GCP]) monitoring

of the groundwater beneath the FTF will continue as requested by South Carolina

Department of Health and Environmental Control (SCDHEC) in support of Construction

Permit # 17,424-IW. Groundwater monitoring will be conducted in accordance with the

an approved FTF Groundwater Monitoring Plan (GWMP) during the interim period from

the time the individual waste tanks and ancillary equipment are removed from service

through post-closure groundwater monitoring defined in a final Record of Decision

(ROD) for the FTF Operable Unit (OU). There are currently two monitoring programs in

place [i.e., FTF/H-Area Tank Farm (HTF) Groundwater Monitoring and General

Separations Area (GSA) Western Groundwater OU] that utilize data from wells at and

around the FTF to document current groundwater conditions.

The F-Area Tank Farm Groundwater Monitoring Plan, Revision 1, was submitted in

February 2012 and approved by both regulatory agencies (SRNS 2012b). The FTF

GWMP includes a description of the groundwater monitoring network, sampling


frequency, constituents and associated detection limits, reporting frequency, and triggers

for evaluation of corrective action. The Core Team agreed that the details of the

sampling plan, including the sampling design and data quality objectives process, could

be presented in a separate SAP in support of the approved GWMP.

1.2 Sampling Unit Location

F Area occupies 364 acres in the north-central portion of the Savannah River Site (SRS)

within an area commonly referred to as the GSA (Figure 1). The GSA is located atop a

ridge running southwest to northeast that forms the drainage divide between Upper Three

Runs Creek to the north, Fourmile Branch to the south, and McQueen Branch to the east

and encompasses approximately 39 km2 (15 mi2). The FTF is located in the southern part

of F Area and occupies 22 acres (Figure 2).

The FTF is an active facility and is heavily developed. The FTF site was chosen because

of its favorable terrain and its proximity to the F-Canyon Separations Facility (the major

waste generation source), which was located near the center of the site, away from the

SRS boundaries.

1.3 Statement of Broad Objectives for the Sampling

The primary objective of the SAP is to develop the sampling design and data quality

objectives in support of the detection monitoring program as outlined in the approved

FTF GWMP.

2.0 SAMPLING UNIT BACKGROUND

2.1 Sampling Area Physical and Geographical Description

2.1.1 Physical Setting

Surface elevations at the FTF range from approximately 85 to 91.5 m (280 to 300 ft)

above mean sea level. Ground cover at the FTF is predominantly asphalt paving with


little surface exposed to infiltration. Surface runoff is predominantly to the south, west,

and north to tributaries of Fourmile Branch and Upper Three Runs Creek.

2.1.2 Climate

Rainfall at the site tends to be evenly distributed throughout the year. The average annual

precipitation at SRS is 121.9 cm (48 in). The evaporation rate is approximately 76.2 cm

(30 in) per year. The most severe weather is limited to frequent thunderstorms and

infrequent tornadoes and hurricanes. Additional details concerning the climatology and

meteorology of SRS can be found in the Performance Assessment (PA) for the FTF (SRR

2010a).

2.1.3 Hydrostratigraphy

The SRS lies in the Atlantic Coastal Plain, a southeast-dipping wedge of unconsolidated

and semi-consolidated sediment, which extends from its contact with the Piedmont

Province at the Fall Line to the continental shelf edge. Sediments range in geologic age

from Late Cretaceous to Recent and include sands, clays, limestones, and gravels. This

sedimentary sequence ranges in thickness from essentially zero at the Fall Line to more

than 1,219 m (4,000 ft) at the Atlantic Coast. At SRS, coastal plain sediments thicken

from approximately 213 m (700 ft) at the northwestern boundary to approximately 430 m

(1,410 ft) at the southeastern boundary of the site and form a series of aquifers and

confining and semi-confining units. Aquifer systems include the Floridan, Dublin, and

Midville systems.

Groundwater within the Floridan Aquifer system flows toward streams and swamps and

into the Savannah River at rates ranging from inches to several hundred feet per year.

The depth to which nearby streams cut into sediments, the lithology of the sediments, and

the orientation of the sediment formations control the horizontal and vertical movement

of the groundwater. The valleys of smaller perennial streams, such as Fourmile Branch,

McQueen Branch, and Crouch Branch in the GSA, allow discharge from the shallow

saturated geologic formations. With the release of water to the streams, the hydraulic


head of the aquifer unit releasing the water can become less than that of the underlying

unit. If this occurs, groundwater has the potential to migrate upward from the lower unit

to the overlying unit.

The hydrogeology at the FTF resides on coastal plain sediments consisting of alternating

sequences of sands, silts, and clays. The Upper Three Runs Aquifer (UTRA) is the

shallowest aquifer beneath the GSA. A semi-continuous confining unit (i.e., commonly

referred to as the “tan clay” confining zone) divides the UTRA into the Upper Aquifer

Zone (UAZ) and Lower Aquifer Zone (LAZ). A more continuous aquitard, the Gordon

Confining Unit (commonly referred to as the “green clay”) underlies the LAZ and

confines the underlying Gordon Aquifer Unit (GAU). Figure 3 depicts the regional

lithologic units and their corresponding hydrostratigraphic units (i.e., aquifers and

confining units) at SRS (Aadland et al 1995).

Current water level data indicate depth to shallow groundwater varies from 15.2 to 22 m

(50 to 72 ft) below land surface. Because the FTF resides on a topographic high within

the GSA, shallow groundwater flow mirrors the topography and is radially outward

towards nearby streams and swamps which eventually flow to the Savannah River

(Figure 4). The rate of flow in the shallow groundwater varies from inches to several feet

per year.

The depth of which nearby streams cut in to sediments, the lithology of the sediments,

and the orientation of the sediment formations control the horizontal and vertical

movement of the groundwater. Figure 5 depicts a conceptual diagram of surface and

groundwater flow at the GSA.

2.2 Operational History

The FTF was constructed to receive waste generated by various SRS production,

processing, and laboratory facilities. The use of the FTF isolated these wastes from the

environment, SRS workers, and the public. Facilities are in place to pretreat the

accumulated sludge and salt solutions (supernate) to enable the management of these


wastes within other SRS facilities (i.e., Defense Waste Processing Facility and Saltstone

Production Facility). These treatment facilities convert the sludge and supernate to more

stable forms suitable for permanent disposal in a federal repository or the Saltstone

Disposal Facility, as appropriate.

The FTF consists of approximately 45,000 ft (8.5 miles) of transfer lines, 22 liquid waste

storage tanks, two evaporator systems, transfer pipelines, six diversion boxes, one catch

tank, a concentrate transfer system tank, and three pump pits. There are three major waste

tank types in FTF that range in size from 750,000 gallons (Type I tanks) to 1.3 million

gallons (Type III and Type IV tanks) and have varying degrees of secondary containment

and intra-tank interference, such as cooling coils and columns. Each of the tank types

were constructed at different times during which design features were greatly improved

upon.

The waste tanks are designated new style or old style based on type of containment, type

of leak detection and/or leakage. The old style tanks do not meet current standards for

secondary containment and/or leak detection or have leaked. Even though the FTF is still

in the operational period, the USDOE is in the process of removing wastes from tanks to

achieve operational closures under the Savannah River Site’s Federal Facility Agreement

(FFA). As required by SCDHEC Regulation 61-67, Standards for Wastewater Facility

Construction and SCDHEC Regulation 61-82, Proper Closeout of Wastewater Treatment

Facilities and Construction Permit #17,424-IW a closure plan has been prepared to

support the removal from service of the FTF underground radioactive waste tanks and

ancillary equipment.

USDOE’s anticipated schedule for removal of the waste tank systems from service was

developed in accordance with federal and state agreements. The FFA provides dates for

bulk waste removal efforts and completion of operational closures of Type I, Type II and

Type IV tanks (i.e., waste tanks that do not meet the standards set forth in Appendix B of

the FFA). Type III and Type IIIA tanks will remain in service until there is no longer a

need for them to support waste treatment, as described in the Savannah River Site

approved Site Treatment Plan, 2010 Update (SRNS 2011a).


During the waste tank operational closure period, at-tank leak detection is conducted by

automatic surveillance of sump monitoring systems. Daily inspections are conducted with

monitoring of secondary containment piping, routine direct visual camera surveys in the

annular spaces and non-routine direct visual camera surveys in primary tanks through

opened access risers and/or inspection ports in the roof. The leak detection and tank

inspection program conducted in accordance with the annual HLW Tank Farm Inspection

Plan will continue until agreement is reached to cease waste removal operations. Results

of the inspection program are reported annually on or before July 01 of each year as

required by Section IX.A.2 of the FFA and C Permit 17,424-IW.

USDOE is in the process of removing the remaining FTF waste tanks and ancillary

structures from service in accordance with the FTF General Closure Plan (SRR 2011) and

tank system-specific closure modules. Additional details concerning the regulatory

framework related to waste tank closure and removal from service can be found in the

FTF GCP (SRR 2011).

2.3 Previous Investigations/Regulatory Actions

The tanks in the FTF have only showed evidence of minor leaks which were typically

contained within the tank annulus (SRR 2010b; WSRC 1991; WSRC 1994). Other minor

releases and spills have been noted due to equipment failure, corrosion or operator error

(WSRC 1991). These sites have been placed in the FFA’s Appendix C (Resource

Conservation and Recovery Act [RCRA]/Comprehensive Environmental Response,

Compensation and Liability Act [CERCLA] Units List) as part of the FTF OU for

evaluation and possible remediation (WSRC 1996).

To support ongoing operation and closure of the FTF waste tanks per the GCP,

groundwater is currently monitored at the FTF according to the FTF Groundwater

Monitoring Plan (SRNS 2012b).

The following sections provide a summary of operations investigative work completed or

ongoing at the FTF. Additionally, because the groundwater at the FTF is included within


a larger FFA OU (i.e., GSA Western Groundwater OU), a summary of other OU

groundwater investigations performed in the area is also provided to illustrate previous

conditions of the groundwater system.

2.3.1 Tank 8 Release and Investigation

In 1961, approximately 1,500 gallons of waste leaked into subsurface soil from Tank 8 as

a result of an overfill (Garvin et al 1975). Investigation of the area in 1975 and 1976

through soil borings and dry well monitoring with radiation detectors determined an area

approximately 1,000 – 1,500 ft3 of soil was contaminated to a depth of 3.7 to 7.9 m (12 to

26 ft) below grade (Odum 1976). It was estimated that approximately 5,000 Ci of

cesium-137 and lesser amounts of strontium-90 and plutonium-238/239 were also present

(Odum 1976).

Analysis of the data determined that based on the location of the zone of contamination

and ion exchange capabilities of the soil, it was estimated that it would be many years

before the contamination reached shallow groundwater (Garvin et al 1975). Subsequent

soil investigation conducted in 1986 concluded that the zone of contamination had not

moved laterally (Grant et al 1986). There have been no additional studies since that time.

However, groundwater monitoring has continued as described below.

2.3.2 F-Area Tank Farm Groundwater Monitoring

The FTF groundwater monitoring program is currently being conducted according to the

FTF Groundwater Monitoring Plan (SRNS 2012b). The FTF Groundwater Monitoring

program is designed to monitor groundwater quality associated with the tank systems and

to detect any future impacts to groundwater that may occur. The results are reported

annually which includes a discussion of any trends and/or changes in the groundwater

quality conditions.

Various historical spills and releases have been recorded at the FTF. To determine

potential impact, groundwater monitoring and data analysis were needed at the FTF.

Therefore, between 1972 and 1984, 27 monitoring wells with prefix FTF were installed


in the FTF in locations that surrounded tank groupings. These wells were all installed

near the top of the water table aquifer (approximately 21.3 to 30.5 m [70 to 100 ft] below

ground surface).

By the early 2000’s, 18 of the FTF wells inside the facility had become unusable due to

the accumulation of sand and silt resulting in reduced or no flow. Because most of these

wells were on the north side of the facility, new wells (FTF 28 and FTF 29) were added

in 2002 and installed in the deeper LAZ of the UTRA along likely flow paths leading

from the FTF to Upper Three Runs Creek. These wells were located outside the FTF

facility away from areas of contaminated soil and historical spill sites. The FTF

monitoring program presently uses eleven (11) of the FTF prefixed wells.

Samples are collected and analyzed for gross alpha, nonvolatile beta, tritium, and nitrate-

nitrite. Sodium and total chromium are also analyzed to monitor the cooling systems.

The current results are presented in the latest F/HTF groundwater report (SRNS 2012c).

2.3.3 FFA Operable Unit Investigations

USDOE currently has an active groundwater monitoring program for monitoring

groundwater impacts from historical releases and spills within F Area and the FTF

(including the waste tanks). These spill sites were previously listed on the FFA

Appendix G (Site Evaluation Areas) by USDOE at the time of FFA approval and have

subsequently been placed on Appendix C (RCRA/ CERCLA Units List) as part of the

FTF OU for evaluation and possible remediation.

Sources of contamination present in groundwater at the FTF are derived from historical

releases from these spill sites. The FFA spill sites as listed for the FTF OU are depicted

on Figure 6.

In an effort to adequately monitor groundwater at F Area due to multiple sources and the

industrial setting the F-Area Tank Farm Groundwater OU and the F-Area Canyon

Groundwater OU were created; these were later combined and the name was changed to

the GSA Western Groundwater OU (WSRC 2004). This combined OU encompasses the


FTF, F-Area Canyon, F-Area Burning/Rubble Pits, F-Area Inactive Process Sewer Lines

(FIPSL) and several basins. Monitoring of groundwater, seeplines, and surface water is

being performed at a predetermined sampling frequency and number of wells as well as

for specific analytes.

As cited in the RCRA Facility Investigation/Remedial Investigation (RFI/RI) Phase 1

Work Plan for the General Separations Area (GSA) Western Groundwater Operable Unit

(U), numerous wells have been installed and monitored. Depth discrete samples primarily

from the UAZ and LAZ of the UTRA have been collected since 1997. Primary

contaminants detected downgradient of the FTF include tritium, nitrate, gross alpha, and

nonvolatile beta. Most of the detected contaminants are found in the UTRA (WSRC

2004).

In 2010, nonvolatile beta was the most widespread contaminant detected at levels

exceeding 50 pCi/L (SRNS 2011b). There is an existing nonvolatile beta groundwater

plume downgradient of the FTF in the LAZ that may be attributed to the Tank 8 release

of 1961, but is most likely due to the nearby FIPSL, which is a common source of

nonvolatile beta activities in groundwater (WSRC 2001). However, currently there are

no nonvolatile beta activities greater than 50 pCi/L at the FTF. Figure 7 depicts

nonvolatile beta and technetium-99 activities in monitoring well FTF 28. Historically,

the highest concentrations have been detected in the area near well FTF 28 and

downgradient of this well and the FIPSL.

2.4 Summary of Existing Data

Groundwater monitoring wells installed within and around the FTF are included in the

existing groundwater data and discussed in this summary. Wells interior to the FTF near

and around the waste tanks include those wells with the FTF prefix (Figure 8). These

wells have been monitored for a number of years and a subset of these wells is currently

monitored in support of the FTF annual groundwater report. Currently, there are a total

of 29 FTF wells and all but two of these wells monitor the UAZ. The other two wells

monitor downgradient groundwater quality in the LAZ. Approximately half of the FTF


well series were installed in 1972 and 1973 with most of the wells constructed of

polyvinyl chloride (PVC). Of the remaining half of wells, all but two were installed in

1984 and the remaining two were installed in 2002. These wells all are constructed of

PVC.

The older FTF wells (i.e., 1972/1973) in the tank farm interior were constructed to

standards that are currently recognized as insufficient for environmental monitoring (due

to for example the filter packs, seals, grouting, casing materials, pump components, etc.).

Because of this situation, the 2012 Core Team removed these wells from the FTF

monitoring network.

As described in Section 2.3, spills and releases have occurred at the FTF. Investigation

of these spills/releases have noted impact to subsurface soil and groundwater. However,

impact to groundwater has been limited in extent. Historical groundwater monitoring of

the UAZ within the FTF has been performed at the FTF well series. As described earlier,

the older wells are not constructed to current well standards and as such monitoring

conducted at these wells has been limited to various metals and radionuclides.

Based on prior Core Team agreement from previous scoping meetings associated with the

GSA Western Groundwater OU and current FTF GWMP, the principal groundwater

contaminants identified at the FTF are nitrate/nitrite, cadmium, chromium, manganese,

sodium, tritium, and technetium-99. The selection of these groundwater contaminants is

based on process knowledge of FTF operations, spills/releases, and groundwater data. In

addition, radionuclide indicators, gross alpha and nonvolatile beta, are also of interest

since these constituents provide necessary information in regards to the potential

presence of other radionuclides (natural and/or man-made).

A review of historical groundwater data associated with the constituents of concern from

those wells at the FTF (i.e., FTF well series) are summarized in the FTF Groundwater

Monitoring Plan (SRNS-RP-2011-00995), Section 5.0, FTF Groundwater Monitoring to

Date. .


3.0 PROJECT DATA QUALITY OBJECTIVES (DQOs)

The Data Quality Objective (DQO) process is a series of logical steps that guides

managers or staff to a plan for the resource-effective acquisition of environmental data.

It is both flexible and iterative, and applies to both decision-making (i.e.,

compliance/non-compliance with a standard) and estimation (i.e., ascertaining the mean

concentration level of a contaminant). The DQO process is used to establish performance

and acceptance criteria, which serve as the basis for designing a plan for collecting data

of sufficient quality and quantity to support the goals of the study. Use of the DQO

process leads to efficient and effective expenditure of resources; consensus on the type,

and quantity of data needed to meet the project goal; and the full documentation of

actions taken during the development of the project. The DQO process is a series of

seven planning steps based on the scientific method (Sections 3.1.1 to 3.1.7 below) and is

detailed in USEPA Guidance (USEPA 2006).

3.1 Groundwater at the F-Area Tank Farm

The intent of this document is to provide supporting information in regards to

groundwater monitoring in accordance with the FTF GWMP during the interim period

from the time the waste tanks and ancillary equipment are removed from service and final

closure of the FTF OU. It is not the intent of this document to address all known sources

to the groundwater or to address potential soil contamination areas from previous known

spills or releases. This will be addressed as part of the FTF OU and GSA Western

Groundwater OU investigations.

3.1.1 State the Problem

Pursuant to FTF GCP Section 8.0 - Maintenance and Monitoring, USDOE and

SCDHEC, in consultation with USEPA must agree to a monitoring plan. Specifically the

GCP states:

Groundwater monitoring will be continued as requested by SCDHEC in support

of Construction Permit #17,424-IW during the interim period from the time the


individual waste tanks and ancillary structures are removed from service up to

the final closure of the FTF OU in accordance with an FTF groundwater

monitoring plan.

This plan includes such elements as a groundwater monitoring network, sampling

frequency, constituents and associated detection limits, reporting frequency, data

evaluation, and triggers for evaluation of corrective action.

The analysis of groundwater samples will be performed by a laboratory certified

for applicable parameters in accordance with SCDHEC R.61-81, State

Environmental Laboratory Certification Program.

3.1.2 Identify Goals of the Study

The primary objective of the SAP is to develop the sampling design and data quality

objectives in support of the detection monitoring program outlined in the approved

GWMP. The FTF GWMP establishes a monitoring program to support evaluation of

groundwater conditions at the FTF during the interim period from the time the individual

waste tanks and ancillary equipment are removed from service and the final closure of the

FTF OU.

3.1.3 Identify Information Inputs

Historical groundwater data have been reviewed and summarized previously in this SAP

(see Section 2.4). The data are of sufficient quality to make decisions concerning

groundwater quality. Groundwater monitoring results collected from the monitoring

network as described in the FTF GWMP will be evaluated to determine groundwater

conditions at FTF. The FTF GWMP includes a network of thirteen (13) monitoring wells

consisting of seven (7) existing wells and six (6) newly installed wells (Figure 9); twice-

a-year collection of routine groundwater samples and analyses from the monitoring well

network around the FTF; and preparation and submittal of an annual groundwater report

that documents the current state of groundwater quality at the FTF.


3.1.4 Define the Boundaries of the Study

The study area is approximately 22 acres on which the FTF resides within F Area within

the GSA (Figure 2). The area being monitored is heavily industrialized with many

operational areas and FFA OUs.

The UAZ and LAZ of the UTRA are the primary hydrostratigraphic units that are to be

monitored as part of this SAP.

3.1.5 Develop the Analytical Approach

Consistent with the FTF GWMP (SRNS 2012b), implementation of the FTF SAP will be

guided by the following accepted SRS protocols/procedures:

Samples will be analyzed using laboratories certified for applicable parameters in

accordance with SCDHEC R.61-81, State Environmental Laboratory

Certification Program (SCDHEC 2002).

Wells will be installed in accordance with SCDHEC Well Standards and

Regulations and with SRS site wide procedures found in Manual 3Q1

Hydrogeologic Data Collection Procedures and Specifications (SRNS 2010).

Samples will be collected, packed and shipped in accordance with the site wide

procedures found in Manual 3Q1 Hydrogeologic Data Collection Procedures and

Specifications (SRNS 2010).

Data management for the FTF groundwater monitoring program will be

performed in accordance with the Environmental Restoration Data Management

System (ERDMS) Data Management Plan (Q-DMP-B-00001, Revision 3, June

2006 or most current version). ERDMS will be used for database management

including mobilization, field measurements and analytical data.

The Quality Assurance Program is described in Area Completion Projects

Programmatic Quality Assurance Project Plan for Environmental Data

Collection and Management, ERD-AG-2005-00001, Rev.5.


The decision rules associated with the data evaluation are defined below.

If screening for gross alpha or nonvolatile beta results exceeds trigger levels, then

the appropriate alpha, beta, and/or gamma spectroscopy analyses will be

performed. The trigger levels for groundwater are 15 pCi/L gross alpha and 50

pCi/L nonvolatile beta.

As outlined in the FTF GWMP, if analysis yields results at or above 15 pCi/L for

gross alpha, new samples will be collected and analyzed for specific radionuclides

to determine the cause of the elevated alpha results, and to distinguish USDOE

program-added radioactivity from natural background (such as radon-thoron). If

the primary FTF process alpha emitters, which include americium-241,

plutonium-238, plutonium-239/240, and uranium-238 are not detected, then

additional constituents will be evaluated, including any of those constituents listed

as contaminant migration constituents of concern in the FTF PA.

If analysis yields at or above 50 pCi/L for nonvolatile beta, new samples will be

collected and analyzed for specific radionuclides in order to determine the cause

of the elevated nonvolatile beta results. Mobile beta emitters (such as cesium-

137, cobalt-60, iodine-129, strontium-90, and technetium-99), present in the tank

inventories, will be evaluated first. If none of these radionuclides are detected,

samples will be analyzed for other constituents until the radionuclide responsible

for the elevated nonvolatile beta results is identified. It will then be added to the

monitoring list for that well.

As described in Sections 6.5 and 6.6 of the FTF GWMP, data will also be

evaluated and reported for comparison with risk-based thresholds and/or MCLs

and statistically evaluated to monitor for trends in contaminant concentrations. If

it is determined that there is a release occurring upgradient of the FTF, SRS will

report this situation promptly to EPA and SCDHEC. Data scoping meetings may

be called to review data findings with EPA and SCDHEC annually, or as needed.


If the monitoring well network is insufficient for monitoring groundwater

contamination in the UAZ and LAZ, additional permanent monitoring wells may

be installed. As described in Sections 6.5 and 6.6 of the FTF GWMP, data

evaluations will be performed to evaluate compliance with risk-based thresholds

and/or MCLs, trending of contaminant concentrations, and to evaluate upgradient

sources. If the data evaluation identifies a concern, subsequent meetings may be

arranged to review the data and determine a pathforward, and as needed,

additional wells may be identified to further enhance monitoring at the FTF.

3.1.6 Specify Performance or Acceptance Criteria

According to USEPA guidance (USEPA 2006), “The USEPA has developed the DQO

Process as the Agency’s recommended planning process when environmental data are

used to select between two or more alternatives or to derive an estimate of contamination.

The DQO process is a seven step method designed to ensure that the appropriate type,

quantity, and quality of environmental data are collected for the intended application.

SW-846 methods (USEPA) are analytical procedures for sample analyses and are

presented in the Analytical Plan, Section 5. Section 4 presents DQO worksheets

developed for each subunit and/or media and specifies the quantity, type, and quality, of

data as well as ensuring representative data is collected for each sampling population.

Total study error is the additive impact of two main sources of error: 1) sampling error

and 2) measurement error, with sampling error being responsible for the vast majority of

the total error. “As much as 90% or more of the uncertainty in environmental data sets is

due to sampling variability as a direct consequence of the heterogeneity of the

environmental matrices” (Crumbling et al 2001). The method best suited to reduce

sampling error is to gather representative samples (Crumbling et al 2001).

It is incorrect to assume that randomly collected, non-representative samples, plus perfect

analytical chemistry will always lead risk managers to correct risk management

decisions. In order to avoid incorrect risk management decisions, it is more important to

develop Decision Quality Data (DQD). DQD is defined as data of known quality that can


logically be demonstrated to be effective for making the specified decision because both

the sampling and analytical uncertainties are managed to the degree necessary to meet

clearly defined and stated data needs (Crumbling et al 2001). Therefore, it is more

important for the risk managers to use decision quality data, emphasizing representative

sampling with a specified percentage of definitive data, in order to make a correct

decision and should not be confused by emphasizing analytical data quality which does

not necessarily equate to a correct risk management decision.

The DQOs for the FTF represent the type and level of analytical quality needed for

groundwater monitoring at this area and can be found in Sections 4 and 5 of this SAP.

3.1.7 Develop the Plan for Obtaining the Data (Project Quality Objectives)

The monitoring approach uses a layered scheme that considers the results of the previous

groundwater sampling data. Activities under this SAP include continued groundwater

monitoring of existing, newly installed monitoring wells, and background wells as

described in the FTF GWMP (SRNS 2012b). Split samples collected in support of

continued groundwater monitoring will be performed by SRS Field or subcontractor

personnel.

Project quality objectives (PQOs) are qualitative and quantitative statements derived from

the DQO process and are used as the basis for establishing the quality and the quantity of

data needed to support decisions. The PQOs for the FTF include the following:

Relative percent difference (RPD) < 100% between regular groundwater samples

and field duplicates when the groundwater sample result >= MDL but < sample-

specific estimated quantitation limit (ssEQL) for the precision data quality

indicator (DQI).

RPD <100% when groundwater sample result >=method detection limit but

<ssEQL for the precision DQI.

Percent Recovery from Matrix Spike and Matrix Spike Duplicates are generally

>= 135% or < 30% for accuracy/bias data quality indicator. Matrix Spike


recovery windows may be tighter than those listed. Tables 12 and 28 of the

Quality Assurance Project Plan (QAPP) list the general and analyte/media

specific Matrix Spike and Matrix Spike Duplicate recovery limits for various

analytical classifications (i.e., VOCs, SVOCs, etc.) as well as the frequency of

sampling which is by reference to Area Completion Projects Standard Operating

Procedure Analytical Data Qualification (ER-SOP-033).

No target compound >=ssEQL for equipment blanks, field blanks, method blanks,

or instrument blanks for the accuracy DQI.

ssEQL <MCL, RSL, or PRG for the sensitivity DQI.

Split sample result will have an RPD = 100% for groundwater samples.

5% of the samples will be split samples for the comparability DQI.

95% of the samples sent to the laboratory will have useable (non-rejected) results

for the completeness DQI.

90% of the planned samples will be collected and their data will be useable for the

completeness DQI.

The objective for the representativeness DQI is qualitative and will be met by properly

documenting field and analytical protocols. In the event these procedures and methods

are not able to be implemented, the appropriate corrective action documentation should

encompass the impact on the representativeness of the information. When review of the

data and documentation determines the data to be non-representative, the information is

qualified for use or is not used by the project.

4.0 SAMPLING DESIGN AND RATIONALE

Implementation of this SAP to obtain decision quality data for groundwater is

documented in the remaining sections of this sampling and analysis plan. The following

section describes how the plan is implemented to collect the physical data to meet the

criteria developed during the DQO process. A DQO worksheet was developed for the


groundwater at the FTF which specifies the quantity, type, and quality of data and

ensures representative data are collected for each sampling population (Table 1).

4.1 Rationale for FTF Groundwater Sample and Analysis Plan

As described in the FTF GWMP, six (6) groundwater wells were installed at five (5)

locations around the FTF (Figure 9). One location is a new background well cluster

consisting of a two (2) well cluster with a well completed in the UAZ and LAZ. These

wells will serve to provide needed data on current and future potential releases from the

FTF or to determine potential upgradient groundwater releases that may impact

groundwater quality downgradient at the FTF.

Of the four (4) remaining wells, two (2) were completed in the UAZ to the northwest of

the FTF to monitor groundwater flow towards Upper Three Runs Creek. The remaining

two (2) wells were completed in the LAZ to the southwest of the FTF to monitor

groundwater flow towards Fourmile Branch. The LAZ wells are located further from the

FTF since contaminants would be more likely to be present in the LAZ after they had

traveled some distance. The downgradient wells are intended to monitor the quality of

groundwater exiting the tank farm.

The installation of these well clusters was based on the diverging flow paths in the UAZ

and LAZ due to the location of the FTF on the groundwater divide and insufficient

groundwater monitoring in these areas (Figure 4). Additionally, groundwater modeling

in support of the PA for the FTF has indicated groundwater flow in these directions in the

event contaminants were released from the FTF. The installation of these new wells

along with the existing monitoring wells around the FTF will provide sufficient coverage

to detect any releases that may occur at the FTF.

4.1.1 Groundwater Sampling of Newly Installed and Existing Monitoring Wells

As described in the FTF GWMP, a total of thirteen monitoring wells (8 UAZ and 5

LAZ), will be sampled twice-a-year for nitrate/nitrite, cadmium, chromium, manganese,

sodium, gross alpha, nonvolatile beta, and tritium (Figure 9 and Tables 2 and 3).


Additionally, technetium-99 will be sampled and analyzed in only four (4) wells (two [2]

background and two [2] downgradient), to provide downgradient quality on existing

technetium-99 activities and to establish background groundwater quality.

The analytes identified were chosen based on the most prominent chemical and

radiological species present in the FTF during operations, waste removal, and tank

closure activities.

The list of analytes, along with their contract-required detection limits (CRDLs), MCLs,

and RSLs, is shown in Tables 4 and 5.

4.1.2 Data Evaluation

Data collected as a result of this Sample and Analysis Plan will be evaluated as outlined

in the FTF GWMP.

4.1.3 Reporting

As provided in the FTF GWMP, monitoring results will be reported on a calendar year

basis in an Annual Groundwater Monitoring Report for the F- and H-Area Radioactive

Liquid Waste Tank Farms to be submitted by March 31 of each year beginning in

calendar year 2013.

5.0 ANALYTICAL PLAN

This section describes the data quality levels for each type of data being collected. All

data collected under this SAP will follow the Area Completion Projects Quality

Assurance Project Plan for Environmental Data Collection and Management (QAPP)

(SRNS 2012a). The data quality level is determined by the intended use of the data.

Groundwater data will be collected under this SAP.

Groundwater data are needed to continue groundwater monitoring at the FTF during the

interim period from the time the individual waste tanks and ancillary equipment are

removed from service and final closure of the FTF OU. Groundwater data collected


under this SAP will be compared to various risk-based screening criteria (i.e., MCLs,

radiological PRGs, and RSLs) and evaluated per the data evaluation process described in

the FTF GWMP.

5.1 Data Quality Levels

All (100%) of the off-site laboratory analyses for groundwater samples collected at the

FTF wells will be verified and validated (VV). In addition, 10% of the VV samples will

have supplemental validation to meet more stringent definitive data criteria. Definitive

data are analytical data that are suitable for final decision making, including data used for

human health risk assessments (Table 6). Table 7 lists the specific methods and detection

limits for analytical analysis in groundwater. Table 8 lists the method and quantitation

limits for radiological analysis. Table 9 lists hold times, preservatives, and sample

containers for analysis conducted on groundwater samples collected from wells at the

FTF.

Regardless of data usage, laboratory quality assurance/quality control (QA/QC) samples

will be performed as specified in ACP Standard Operating Procedure Analytical Data

Qualification (ER-SOP-033) and ACP Programmatic Quality Assurance Project Plan for

Environmental Data Collection and Management (ERD-AG-2005-00001). Sufficient

quantity of sample will be collected to ensure laboratory QA/QC samples are performed

and reported.

5.2 Field Analytical Sampling Quality Assurance/Quality Control

All field analytical sampling quality assurance/quality control (QA/QC) will be

maintained through the use of QA/QC samples consisting of field duplicates,

rinsate/equipment blanks, field blanks, trip blanks, and split samples. Field personnel

will ensure that QA/QC samples are collected at the correct frequency and methodology

as described below.

Field quality assurance/quality control will be maintained through the use of QA/QC

samples and methods as described below:


1. Field Duplicate (co-located) Samples: Two or more independent samples collected

from side-by-side locations at the same point in time and space so as to be considered

identical. These separate samples are intended to represent the same population and

are carried through all steps of the sampling and analytical procedures in an identical

manner. These samples are used to assess precision of the total method, including

sampling, analysis, and site heterogeneity. Field duplicate samples are planned at a

combined minimum rate of 5% according to Obtaining and Managing Data for Area

Completion Projects (ACP) (ER-SOP-043), or typically 1 per 20 samples and

analyzed for the same parameters as the associated samples.

2. Equipment Blank: A sample of water free of measurable contaminants poured over or

through decontaminated field sampling equipment that is considered ready to collect

or process an additional sample. The purpose of this blank is to assess the adequacy

of the decontamination process. Also called rinse blank or rinsate blank. Equipment

blanks are typically planned at a rate of 1 blank per 40 samples.

3. Field Blank: A blank used to provide information about contaminants that may be

introduced during sample collection, storage, and transport; also a clean sample

exposed to sampling conditions, transported to the laboratory, and treated as an

environmental sample. Field blanks are optional and may be collected when

contamination from external environmental sources is anticipated by the project team.

Typically field blanks, when used, are planned at a rate of 1 blank per 40 samples.

4. Trip Blank: A clean sample of water free of measurable contaminants that is taken to

the sampling site and transported to the laboratory for analysis without having been

exposed to sampling procedures. Trip blanks are analyzed to assess whether

contamination was introduced during sample shipment (typically analyzed for volatile

organic compounds only). A blank consists of distilled-deionized water provided by

the laboratory to be placed in every cooler with volatile organic compounds samples

typically at the rate of 1 trip blank per cooler.


5. Split Samples: Two or more representative portions from a sample in the field,

analyzed by at least two different laboratories and/or methods. Prior to splitting, a

sample is mixed (except volatiles, oil and grease, or when otherwise determined) to

minimize sample heterogeneity. These are quality control samples used to assess

precision, variability, and data comparability between laboratories. Split samples are

planned at a combined minimum rate of 5% or typically 1 per 20 samples and

analyzed for the same parameters as the associated samples.

5.3 Sample Matrix Table

Table 3 provides a sampling matrix table that includes the following information:

sample count,

station identifier,

aquifer,

sample type,

sample media

sample collection method,

analytical suites, and

coordinates*.

*Proposed coordinates may change as necessary due to field conditions.

5.4 Sample Location Map

A map showing the proposed groundwater monitoring well sample locations are shown

on Figure 9.

6.0 FIELD IMPLEMENTATION

The following sections outline the field implementation procedures and processes for the

FTF SAP. Additional implementing documents, such as the environmental checklist,

automated hazard analysis, safe work permits, radiological work instructions,

site-specific health and safety plan, and investigation derived waste (IDW) management


plans, are internal to SRS and detail day-to-day sampling operations and safety

requirements.

6.1 List of Sampling/Collection Equipment

The types of sampling/collection equipment needed to execute the field implementation

plan are as follows:

Portable/hand-held pH meter,

Portable/hand-held Conductivity meter,

Portable/hand-held Turbidity meter,

Portable/hand-held Water Level Indicator,

KIJ-5 Radio, cell phone, and/or pager,

Field vehicle,

Personal protective equipment,

Chain-of-custodies,

Sampling supplies,

Sample bottles with preservatives,

Coolers and frozen blue ice or equivalent for packing samples in the field.

Equipment needs will vary from day to day based on sampling requirements and field

conditions.

6.2 Investigation Derived Waste

IDW will be managed according to the site-specific IDW management plan developed for

the project.


7.0 REFERENCES

Aadland, R.K., J.A. Gellici, and P.A. Thayer, 1995. Hydrogeologic Framework of West-

Central South Carolina, Report 5, Water Resources Division, South Carolina Department

of Natural Resources, Columbia, SC

Crumbling, Deana M., C. Groenjes, B. Lesnik, K. Lynch, J. Shockley, J. Van Ee, R.

Howe, L. Keith, and J. McKenna, 2001. “Managing Uncertainty in Environmental

Decisions”, Environmental Science & Technology, 2001, American Chemical Society,

October 1, 2001, pages 405A-409A.

FFA, 1993. Federal Facility Agreement for the Savannah River Site, Administrative

Docket Number 89-05-FF (Effective Date: August 16, 1993)

Garvin, R.G., W.L. Poe, 1975. Soil Contamination Adjacent to Tank 8-F, DPSPU-75-11-

8, E.I. du Pont de Nemours & Company, Savannah River Plant, Aiken, SC.

Grant, M.W., P.W. Weimorts, 1986. Results of Tank 8 Plume Study, DPST-86-511, E.I.

du Pont de Nemours & Company, Savannah River Plant, Aiken, SC.

Odum, J.V., 1976. Soil Contamination Adjacent to Waste Tank 8, DPSPU-76-11-4, E.I.

du Pont de Nemours & Company, Savannah River Plant, Aiken, SC.

Rucker, G.G., 2001. Calculation of the Isotopic Activities of Naturally Occurring

Uranium in Drinking Water Equivalent to Uranium Maximum Contaminant Level, Q-

CLC-B-00019, Revision 1 and ERTEC-2001-0001, Westinghouse Savannah River

Company, Savannah River Site, Aiken, SC.

SCDHEC, 2002. R.61-71, Well Standards and Regulations (April 26)

SCDHEC, 2011. R61-81, State Environmental Laboratory Certification Program

(September 23)


SRNS, 2010. Manual 3Q1, Hydrogeologic Data Collection Procedures and

Specifications, Sections 3000 and 9000, latest revisions, Savannah River Nuclear

Solutions, LLC, Savannah River Site, Aiken, SC

SRNS, 2011a. Savannah River Site Approved Site Treatment Plan, 2011 Annual Update

(U), SRNS-TR-2008-00101, Revision 3, Savannah River Nuclear Solutions, LLC, Aiken,

SC.

SRNS, 2011b. Scoping Summary for the General Separations Area Western

Groundwater Operable Unit (U), ERD-EN-2005-0127, Savannah River Nuclear

Solutions, LLC, Savannah River Site, Aiken, SC, August 2011.

SRNS, 2012a. Area Completion Projects Programmatic Quality Assurance Project Plan

for Environmental Data Collection and Management, ERD-AG-2005-00001, Revision 5,

Savannah River Nuclear Solutions, LLC, Savannah River Site, Aiken, SC.

SRNS, 2012b. F-Area Tank Farm Groundwater Monitoring Plan (U), SRNS-RP-2011-

00995, Revision 1, Savannah River Nuclear Solutions, LLC, Savannah River Site, Aiken,

SC.

SRNS, 2012c. 2011 Annual Groundwater Monitoring Report for the F- and H-Area

Radioactive Liquid Waste Tank Farms (U), SRNS-RP-2012-00022, Revision 0, Savannah

River Nuclear Solutions, LLC, Savannah River Site, Aiken, SC.

SRR, 2010a. Performance Assessment for the F-Area Tank Farm at the Savannah River

Site, SRR-CWDA-2007-00002, Revision 1, Savannah River Remediation, LLC,

Savannah River Site, Aiken, SC.

SRR, 2010b. Annual Radioactive Waste Tank Inspection Program - 2009, SRR-STI-

2010-00283, Savannah River Remediation, LLC, Savannah River Site, Aiken, SC, June

2010.


SRR, 2011. Industrial Wastewater General Closure Plan for F-Area Waste Tank

Systems, LWO-RIP-2009-00009, Revision 2, Savannah River Remediation, LLC,

Savannah River Site, Aiken, SC.

USEPA, USDOD, USDOE, 2005. Uniform Federal Policy for Quality Assurance

Project Plans, EPA:-505-B-04-900A, Version 1 Final, March 2005.

USEPA, 2006. Guidance on Systematic Planning Using the Data Quality Objectives

Process, EPA QA/G-4, EPA/240/B-06/001, February 2006.

USEPA, 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities,

EPA 530/R-09-007, March 2009.

USEPA, 2011a. National Primary Drinking Water Regulations, Office of Groundwater

and Drinking Water, http://www.epa.gov/safewater/contaminants/index.html (August).

USEPA, 2011b. USEPA Preliminary Remediation Goals for Radionuclides, http://epa-

prg-ornl.gov/radionuclides/ (August).

USEPA, 2011c. USEPA Regional Screening Levels, http://epa.gov/reg3hwmd/risk/hu-

man/rbconcentration_table/ index.htm (June).

USEPA, Various Updates. Test Methods for Evaluating Solid Waste, Physical/Chemical

Methods, SW-846, Third Edition Basic Manual with Updates.

WSRC, 1991. Assessment Report Phase II for the F and H-Area High-Level Radioactive

Waste Tank Farms (U), WSRC-RP-93-549, Revision 0, Westinghouse Savannah River

Company, Savannah River Site, Aiken, SC, August, 1991.

WSRC, 1993, Assessment of Tritium in the Savannah River Site Environment, WSRC-

TR-93-214, Westinghouse Savannah River Company, Savannah River Site, Aiken, SC.


WSRC, 1994. Annual Radioactive Waste Tank Inspection Program – 1993 (U), WSRC-

TR-94-166, Westinghouse Savannah River Company, Savannah River Site, Aiken, SC,

May, 1994.

WSRC, 2001. Assessment Report: Groundwater Quality Near F- and H-Area Inactive

Process Sewer Lines (U), WSRC-RP-2001-4055, Revision 0, March 2001.

Westinghouse Savannah River Company, Savannah River Site, Aiken, SC.

WSRC, 2004. RCRA Facility Investigation/Remedial Investigation (RFI/RI) Phase 1

Work Plan for the General Separations Area (GSA) Western Groundwater Operable Unit

(U), WSRC-RP-2003-4147, Revision 1.1, November 2004. Westinghouse Savannah

River Company, Savannah River Site, Aiken, SC.


FIGURES


Figure 1: Location of F Area in the General Separations Area at the Savannah River Site


Figure 2: Location of the F-Area Tank Farm at F Area, SRS


Figure 3: Hydrostratigraphic Units at F Area (modified from Aadland et al, 1995)


Figure 4: Potentiometric Surface and Groundwater Flow Directions at the F-Area Tank Farm


Figure 5: Surface and Groundwater Flow at the General Separations Area (modified from SRR, 2011)


Figure 6: Location of FFA OUs and Key Facilities at the F-Area Tank Farm


Figure 7: Historical Nonvolatile Beta and Technetium-99 Activities in Monitoring Well FTF 28


Figure 8: Location of UAZ and LAZ Wells At and Near the F-Area Tank Farm


Figure 9: Location of Wells for the F-Area Tank Farm Groundwater Monitoring Network


TABLES


Table 1: Data Quality Objectives Worksheet for Groundwater at the F-Area Tank Farm

Pathway (Media)

Probable Conditions

Exposure Pathway and/or Release Mechanisms

Data Needs and DQOs Including

Engineering/Physical Processes

Field Activities Including Removal and

Characterization Parameters

Potential Remedial Action

Alternatives

Groundwater

Contamination of groundwater from leaching of secondary sources and spills from primary sources (i.e., waste tanks). Contaminated groundwater elevated above risk-based screening criteria exists. Known technetium-99 activities are present in a downgradient LAZ well. Varying shallow subsurface groundwater flow directions and rates result in multiple flow paths.

Ingestion or dermal contact with groundwater or inhalation of groundwater vapor.

Establish permanent monitoring locations in the UAZ and LAZ to monitor and evaluate groundwater contaminant concentration trends. Obtain groundwater data needed to adequately monitor possible contaminant release and movement in the groundwater. Establish and monitor background groundwater locations for data comparisons to upgradient groundwater quality at the FTF.

Sample monitoring wells in the UAZ and LAZ to monitor groundwater in the northwest and southwest vicinity of the FTF.

Nitrate/nitrite, cadmium, chromium, manganese, sodium, gross alpha, nonvolatile beta, and tritium. Technetium-99 for a select number of wells. Alpha, beta, and/or gamma speciation, if trigger levels exceeded for gross alpha (15 pCi/L) and/or nonvolatile beta (50 pCi/L), as required.

No remedial actions are warranted. Semi -annual sampling of groundwater monitoring wells and annual reporting will continue.


Table 2: Monitoring Parameters for the F-Area Tank Farm Groundwater Monitoring Plan Proposed Analytes for

Existing and New Wells (2 times/year)‡

Current Monitoring

Program Analytical Method

MCL/PRG (pCi/L,

pCi/mL, mg/L)

Action Level

CRDL/Typical MDA

Inorganics

Nitrate/Nitrite X EPA353.2 10 mg/L NA 0.01 mg/L (3)

Metals

Cadmium EPA6010C 0.005 mg/L NA 0.002 mg/L (3)

Chromium X EPA6010C 0.1 mg/L NA 0.002 mg/L (3)

Manganese EPA6010C NA NA 0.002 mg/L (3)

Sodium X EPA6010C NA NA 0.002 mg/L (3)

Radionuclide Indicators

Gross Alpha X EPA900.0MOD NA 15 pCi/L Sample Specific (2)

Nonvolatile Beta X EPA900.0MOD NA 4 mrem Sample Specific (2)

Radionuclides

Technetium-99 Beta Spectroscopy (1) 900 pCi/L NA 17.3 pCi/L (3)

Tritium X EPA906.0MOD 20 pCi/mL NA 0.5 pCi/mL (3)

Alpha Speciation (if gross alpha > 15 pCi/L)

X Alpha Spectroscopy (1) NA NA See Table 5 for selected isotopes

Beta Speciation (if nonvolatile beta > 50 pCi/L)

X Beta Spectroscopy (1) NA NA See Table 5 for selected isotopes

Gamma Speciation (if nonvolatile beta > 50 pCi/L)

X Gamma Spectroscopy (1) NA NA See Table 5 for selected isotopes

Proposed Field Parameters (1) No nationally recognized standardized methods, except Ra-226 and Ra-288 (EPA903.0MOD). (2) All minimum detected activities (MDAs) are on a sample specific basis, typical MDA for selected isotopes are provided in Tables 7 and 8, limits are not always attainable. (3) Contract Required Detection Limits (CRDL) are not always attainable. ‡The Analyte List includes radionuclides for information only.

Depth to Water X

pH X

specific conductance X

temperature X

turbidity X


Table 3: Sampling Matrix Table

Sample Coordinates

SampleCount

Station ID Aquifer Sample

Type Sample Media

Collection Method

Analyte Suite East North

1 FBG001Ca‡ LAZ REG Groundwater pump 1, 2, 3, 4, 5, 6 437085.697 3682792.647

2 FBG001Ca‡ LAZ SPL Groundwater pump 1, 2, 3, 4, 5, 6 437085.697 3682792.647

3 FBG001Da‡ UAZ REG Groundwater pump 1, 2, 3, 4, 6 437080.544 3682795.76

4 FTF 9Ra UAZ REG Groundwater pump 1, 2, 3, 4, 6 436707.182 3682662.677

5 FTF 12Ra UAZ REG Groundwater pump 1, 2, 3, 4, 6 436784.44 3682609.82

6 FTF 19 UAZ REG Groundwater bail 1, 2, 3, 4, 6 436869.32 3682598.5




10 FTF 28 LAZ REG Groundwater pump 1, 2, 3, 4, 5, 6 436731.599 3682536.215

11 FTF 28 LAZ FD Groundwater pump 1, 2, 3, 4, 5, 6 436731.599 3682536.215

12 FTF 29 LAZ REG Groundwater pump 1, 2, 3, 4, 6 436637.736 3682655.337

13 FTF 30a LAZ REG Groundwater pump 1, 2, 3, 4, 5, 6 436819.72 3682464.84

14 FTF 30D UAZ REG Groundwater pump 1, 2, 3, 4, 6 436820.59 3682467.06

15 FTF 31a LAZ REG Groundwater pump 1, 2, 3, 4, 6 436977.29 3682429.94

‡Background Well

aNew well installed per the FTF GWMP.

REG = Regular sample. FD = Field duplicate. SPL = Split sample.


Table 3: Sampling Matrix Table (Continued)

Regular and QA Sample

Summary for Monitoring

Wells

Comments

RegularSamples 13

FieldDuplicates 1 Collect at 1 per 20.

SplitSamples 1 Collect at 1 per 20.

RinsateSamples 0 None to be collected since sampling will be conducted using existing, dedicated downhole well pumps.

FieldBlank 0 Optional. None to be collected.

TripBlanks 0 None to be collected or shipped with samples since VOCs are not included in the analyte suite.

TotalSamples 15

QA = Quality assurance. Analytical Suites 1. Inorganics: Nitrate/Nitrite 2. Metals: Cadmium, Chromium, Managanese, Sodium 3. Radionuclide Indicators: Gross Alpha and Nonvolatile Beta

b 4. Radionuclides: Tritium 5. Radionuclides: Technetium-99 6. Field Parameters: Depth to Water, pH, specific conductance, temperature, and turbidity b If the gross alpha result exceeds 15 pCi/L, then an alpha spectroscopy will be performed to include americium-241, plutonium-

238, plutonium-239/240, and uranium-238. If the nonvolatile beta result exceeds 50 pCi/L, then a beta/gamma spectroscopy will be performed to include iodine-129, strontium-90, cesium-137, cobalt-60, and technetium-99.


Table 4: Laboratory Contract Required Detection Limits Compared to Regional Screening Levels for Surface or Groundwater Media

Tap Water RSL

MCL

CRDL

CRDL>

Analyte CAS (µg/L) (µg/L) (µg/L) MCL/RSL

Cadmium 7440-43-9 6.9E-03 5.0E00 2.0E+00 >RSL Chromium 7440-47-3 1.0E+02 2.0E+00 No Manganese 7439-96-5 8.8E+02 ! 2.0E+00 No Nitrate-Nitrite as Nitrogen NO3NO2 1.0E+04 1.0E+01 No Sodium 7440-23-5 2.0E+00 No

>RSL means CRDL is greater than the RSL


Table 5: Minimum Detected Activity Compared to Water Radiological MCL/PRGs

Analyte Typical MDA

MCL/PRG MDA>MCL/PRG

Proposed Analytes for Existing and

New Wells (2 times/year)

Alpha Spectroscopy (pCi/L)

Americium-241 0.4 15 No X

Americium-243 0.462 15 No

Curium-242 0.9 15 No

Neptunium-237 0.771 15 No

Plutonium-238 0.35 15 No X

Plutonium-239/240 0.353 15 No X

Plutonium-242 0.372 15 No

Thorium-228 0.445 15 No

Thorium-230 0.523 15 No

Thorium-232 0.45 15 No

Uranium-233/234 0.663 10 Noa

Uranium-235 0.684 0.47 Noa

Uranium-238 0.744 10 Noa X

Gamma Spectroscopy (pCi/L)

Actinium-228 25 26.6 No

Cesium-137 5 200 No X

Cobalt-60 10 100 No X

Lead-214 20 154 No

Potassium-40 75 2.14 Yes

Specific Analyses (pCi/L)

Carbon-14 10 2,000 No

Iodine-129 1 1 No X

Nickel-59 20 300 No

Nickel-63 10 50 No

Promethium-147 10 600 No

Radium-226 0.3 5 No

Radium-228 0.5 5 No

Strontium-90 0.852 8 No X

Technetium-99 17.3 900 No X

Tritium (pCi/mL) 0.5 20 No X aFrom Rucker 2001.

Note: All minimum detected activity (MDAs) are sample specific. The MDAs represented above are typical MDA as reported by the subcontract laboratories but are not always achievable.


Table 6: Minimum Field Quality Control/Quality Assurance Sampling Requirements

Data Quality Level

Field Quality Control/Quality

Assurance Samples

Frequency of Field Quality Control/

Quality Assurance Sample

VV

Co-located Field Duplicate Minimum 5% (1)

Trip Blank Minimum 1 per cooler

Equipment Blank 1 per 40 samples(2)

Field Blank Optional; 1 per 40 samples(3)

Split Sample Minimum 5%

D

Co-located Field Duplicate Minimum 5%(1)

Trip Blank 1 per cooler

Equipment Blank 1 per 40 samples(2)

Field Blank Optional; 1 per 40 samples(3)

Split Sample Minimum 5%

Data Quality Levels VV Data Verified and Validated Data (validated to automated criteria; equivalent to USEPA

Screening Level Data) D Data USEPA Definitive Level Data Footnotes: (1) Minimum frequency established per ER-SOP-043 (2) Typical frequency (3) Recommended based on project needs; typical frequency


Table 7: Laboratory Analytical Specifications Table for TAL/TCL Analytes for Groundwater Media

Analyte

Analyte ID

Preparation B Method

Analytical B Method

CRDL A

(µg/L)

Metals Cadmium 7440-43-9 3005A,3015A EPA6010C 2.0 Chromium 7440-47-3 3005A,3015A EPA6010C 2.0 Manganese 7439-96-5 3005A,3015A EPA6010C 2.0 Sodium 7440-23-5 3005A,3015A EPA6010C 2.0

Inorganics Nitrate-Nitrite as Nitrogen NO3NO2 EPA353.2 10.0

A) CRDL is the Contract Required Detection Limit and is not always attainable. B) Extraction and preparation methods differ depending upon media, concentration, instrument, laboratory, and analytical method. Preparation methods will also influence detection limits.


Table 8: Laboratory Analytical Specifications Table for Radiological Analytes in Soil, Sediment, Surface, and Groundwater Media

Radionuclides Typical Water

MDAsa Analytical

Method

Alpha Spectroscopy (pCi/L)

Americium-241 0.40 NNS Americium-243 0.462 NNS Curium-243/244 0.503 NNS Curium-245/246 0.458 NNS Neptunium-237 0.771 NNS Plutonium-238 0.35 NNS Plutonium-239/240 0.353 NNS Plutonium-242 0.372 NNS Thorium-228 0.445 NNS Thorium-230 0.523 NNS Thorium-232 0.45 NNS Uranium-233/234 0.663 NNS Uranium-235 0.684 NNS Uranium 238 0.744 NNS

Gamma Pulse Height Analyses (pCi/L)

Actinium-228 25.00 NNS Cesium-137 5.0 NNS Cobalt-60 10.00 NNS Lead-214 20.00 NNS Potassium-40 75.00 NNS

Radiological Indicators (pCi/L)

Gross Alpha 3 EPA900.0MOD Nonvolatile Beta 4 EPA900.0MOD

Individual Analyses (pCi/L) Carbon-14 10.00 NNS Iodine-129 1.00 NNS Nickel-59 20.00 NNS Nickel-63 10.00 NNS Promethium-147 10.00 NNS Radium-226 0.30 EPA903.0MOD Radium-228 0.50 EPA903.0MOD Strontium-90 0.852 NNS Technetium-99 17.3 NNS Tritium (pCi/mL) 0.00050 EPA906.0MOD

a All MDAs are sample-specific. The MDAs represented above are typical MDAs as reported by the subcontract laboratories but are not always achievable. MDA = Minimum detected activity. NNS = No national standard. USEPA = United States Environmental Protection Agency.


Table 9: Preservatives, Holding Times, and Sample Containers for Groundwater Collected at the FTF

Parameter Preservative Holding Time Container

Metals (except chromium [VI] and mercury)

HNO3 to pH <2 6 months 1-L HDPE

Miscellaneous

Nitrate-Nitrite Cool to 4○ C. H2SO4 to pH < 2. 28 days 250 mL HDPE

Radionuclides

Radiological Test Gross Alpha HNO3 to pH <2 6 months 2-L HDPE

Radiological Test Nonvolatile Beta HNO3 to pH <2 6 months 2-L HDPE

Radium Total HNO3 to pH <2 6 months 2-L HDPE

Tritium None, Cool 0 to 6°C 180 days 250-mL amber glass

°C = Degrees Celsius. H2SO4 = Sulfuric acid. HDPE = High-density polyethylene. HNO3 = Nitric acid.

f-area tank farm groundwater sampling and analysis plan (u) · ftf groundwater sampling and...

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