experimental investigation of a kw scale absorption power
TRANSCRIPT
Paper ID: 018, Page 1
6th International Seminar on ORC Power Systems, October 11 - 13, 2021, Munich, Germany
EXPERIMENTAL INVESTIGATION OF A KW SCALE ABSORPTION POWER
CYCLE WITH LIBR SOLUTION
Vaclav Novotny1,2*, Jan Spale1,2, Jan Pavlicko1,2, David J. Szucs1, Michal Kolovratnik2
1Czech Technical University in Prague, University Centre for Energy Efficient Buildings,
Trinecka 1024, Bustehrad, 27343, Czech Republic
2Czech Technical University in Prague, Faculty of Mechanical Engineering, Technicka 4, Praha 6, 16607, Czech Republic
*Corresponding Author: [email protected]
ABSTRACT
Absorption cycles have been proposed not only for cooling but also for power generation. Most
common is then Kalina cycle utilizing water-ammonia mixture working fluid. Other working fluids
theoretically may provide thermodynamic benefits, have only rarely been examined experimentally.
This work reports on, to the authors’ knowledge, the world’s first absorption power cycle using salt
solution (here aqueous solution of LiBr), known so far only from absorption cooling. The system with
a design power output of around 300 W features solutions such as a nylon 3D printed turbine or
measurement of temperature glide during phase change in the heat exchangers.
This work is focused on an analysis of the experimental performance of the system. The measured
turbine efficiency reached 25% with a potential for much higher values with better design. Over the
range of explored conditions, if 65% expander performance was assumed, the maximal cycle efficiency
could be around 4.5% and utilization efficiency 0.5%.
1 INTRODUCTION Utilization of low temperature heat sources, especially of waste heat, efficiently has been a goal of many
research activities. The traditional method widely considered and applied for higher temperatures, ORC,
often doesn’t reach at such low temperatures sufficient efficiency for commercial application.
Moreover, the requirements for heat rejection rise significantly as the heat source temperature and
efficiency decreases, and thus the relative amount of rejected heat against power output rises. The ideal
cycle for utilization of low temperature is a trilateral cycle with a gradual increase of working fluid
temperature along with the heat input, minimizing the irreversibilities. (DiPippo, 2012; An et al., 2016;
Novotny and Kolovratnik, 2017) Several methods to approach the trilateral cycles have been proposed,
including the use of zeotropic working fluids with a temperature glide during phase change. Absorption
power cycles are one of these systems, where many works in the past suggested the use of water-
ammonia mixture and several plants were built (Kalina, 1985; Zhang, He and Zhang, 2012; Macwan,
2013).
Another possible working fluid is a water-LiBr solution which was found to have theoretical advantages
for very low temperatures and the prospect of the efficient unit for power outputs even down to kW
scale as a result of low system pressures. (Novotny et al., 2016; Novotny and Kolovratnik, 2017) The
proposed working fluid is commonly applied in absorption chillers (Herold, Radermacher and Klein,
1996), but no previous experimental report of use as a power cycle has been found until now.
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6th International Seminar on ORC Power Systems, October 11 - 13, 2021, Munich, Germany
2 TEST RIG In order to verify the real applicability of the proposed cycle with the LiBr solution, an experimental
system has been proposed. First experimental considerations (Novotny et al., 2017) and unsuccessful
trials of low pressure flow boiling with pure water (Novotny, Suchna and Kolovratnik, 2018) led to the
design of a proof of concept system of the cycle with a nominal power output in hundreds of watts. Its
design was in detail introduced in (Novotný et al., 2019). Here the design is briefly reviewed, followed
by details on instrumentation and operation.
2.1 Design
The experimental proof-of-concept APC system is illustratively shown on a simplified diagram in
Figure 1a and a Ts diagram for illustration of the processes is in Figure 1b. As it is suggested by the
first figure, it utilizes a shell & tube desorber (i.e. steam generator) as well as a shell & tube falling film
absorber (LiBr solution flown on the outer surface of helically wound tubes and steam is absorbed).
The working fluid in the desorber (steam generator in cooling cycle terminology) undergoes a partial
phase change, ideally with temperature glide for good temperature profile match with the heat source.
The produced pure water steam is due to the boiling point elevation in a superheated state (when
considered separately from the solution, with which it is at vapour liquid equilibrium) and is routed to
the expander and subsequently absorber. The rich solution leaves absorber at the saturated state is routed
to the absorber in a separate line via a recuperator. While concepts with counter-flow low volume heat
exchangers (as plate type) assume a separator downstream, our design follows a large volume exchanger
design which already serves as a separator, as found in common absorption chillers. Note an additional
pump in the rich solution line to overcome potentially excessive pressure losses in the line and nozzles
in the absorber. In the absorber, the steam is absorbed into a subcooled liquid solution film flowing on
a heat transfer surface where heat is removed into cooling water. In case of an insufficient absorption
rate additional solution, a recirculation circuit is considered here with the solution nozzles in the half of
the absorber’s height.
a) b)
Figure 1: APC experimental rig, (a) schematic diagram, (b) Ts diagram of the designed cycle
extended to saturation vapour and liquid lines of LiBr solution at high and low system pressure and of
water
Major design parameters are summarized in Table 1 and in detail are described in (Novotný et al.,
2019). The overall configuration of the system is shown in Figure 2. Note especially the very low
pressures of the turbine inlet and outlet. Also, as the device serves as the proof of concept, some
components, especially the absorber, are oversized, and the device is built on two floors so that every
part of the system is accessible for the commissioning.
The main phenomena to be verified by this system are at first of course for the overall operation, but
also actual temperature profile in the heat exchangers with temperature glide (both desorber and
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absorber have inserted multiple temperature probes along the flow direction) and last but not least
feasibility of plastic 3D printed turboexpanders.
a) b)
Figure 2: APC experimental rig, (a) 3D model of the system, (b) photograph of the system
TABLE 1. Main design parameters of the APC rig
Heat source & sink fluid water
Inlet temperature of the heat source Ths 90 °C
Heat input Qin 20 kW
Inlet temperature of the cooling water Tcw 30 °C
Working fluid LiBr+H2O 35% (LiBr wt., lean) / 50% (rich)
Lean LiBr solution mass flow ��𝑙𝑒𝑎𝑛 0.026 kg s-1
Vapour mass flow ��𝑣𝑎𝑝 0.008 kg s-1
Turbine inlet pressure PHP 13.38 kPa
Turbine outlet pressure pLP 5.99 kPa
Turbine isentropic power output Wis 840 W
Turbine design power output Wturb 370 W
Design parasitic load (incl. cooling water pump and fan) Wparas 116.2 W
Design cycle / system / utilization efficiency 𝜂𝑐/𝜂𝑠𝑦𝑠𝑡/ 𝜂𝑢 1.9 / 1.3 / 0.2 %
2.2 Instrumentation
In the APC rig, most of the measurements were taken and recorded via PLC system AS332T-A with
measuring cards for RTD temperature sensors, voltage and current input. Additional temperature
sensors for temperature glide were measured via Labview (cRio module). The turbine load was
controlled via an in-house built DC load (output current was rectified first) system, which included a
PID regulator to keep set rotational speed. This system also recorded the voltage and current along with
rotational speed based on produced AC current frequency. Some details about this method can be found,
for example, in (Spale et al., 2021).
A simplified PFID showing the overall layout along with the position and types of measurements within
the system is shown in Figure 3. It also shows design thermodynamic properties in respective streams.
The details of the sensors for the measured variables are summarized in Table 2.
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Figure 3: APC experimental rig simplified PFID
Table 2: Test rig sensors and transducers
Parameter Type Range Error
Pressure Ceramic capacitive DMP331 0-400 kPa
0-200 kPa
0.35% FS,
0.10% FS
Temperature Pt100 RTD (4 wire) -50 - 200°C 0.5% + 0.3°C
Volumetric flowrate
(LiBr solution)
Vortex LIQUI-VIEW Base LVB-06-A 0.5-10 l/min <1% FS
Volumetric flowrate
(hot/cold water)
Vortex LIQUI-VIEW Base LVB-20-A,
LVB-15-A
5-85 l/min
3.5-50 l/min
<1% FS
Generated voltage Voltage divider +Arduino A/D 0-60 V 2% + 0.03 V
Generated current Arduino A/D via U drop (1 block) 0-30 A 2% + 0.02 A
Turbine rotation speed Electrical frequency via Arduino A/D 2k-100k rpm ~20 rpm (@ 10k rpm)
2.3 Operation
Before each test, the system was evacuated, and after each test campaign, the rig was filled with nitrogen
to slightly above ambient pressure to prevent oxygen intrusion and potential corrosion. The tests were
performed for ranges of basic solution concentration of 54% (as purchased) and 50%, 45% and 40%
and additionally during commissioning with pure distilled water. During the experimental tests,
conditions of the cycle were set. The cycle operating with the turbine has two degrees of freedom, speed
of the main pump and of the rich solution pump. When the bypass valve was used instead of the turbine,
its opening simulated the turbine’s swallowing capacity and thus provided one another degree of
freedom.
The pumps were operated in a way that the recirculation pump was set to run at a certain constant speed,
while the lean solution pump was (manually) controlled to provide a constant liquid level in the
desorber. The opposite way of control has proven to be unreliable as at certain states; the liquid solution
stopped returning to the storage tank (suspected crystallization issues though there should have been a
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margin from the crystallization concentration. This phenomenon might deserve deeper focus in the
future. The control of the pump, together with the high time constant of the system, sometimes caused
large departures from steady-state liquid flows. At least partial correction for these discrepancies is
provided in the next chapter.
The heat source was heating water taken as part of the output of biomass-fired ORC units, either a
50 kWth version as described in (Mascuch et al., 2018) or its scaled up 120 kWth version. Due to the
unit’s settings and partly heat losses in the heat input pipes, the heat source temperature was most of
the time between 75 and 85°C, while it could be further decreased by a three-way valve mixing in the
return water. The spread of explored heat source temperature was 67-88°C. The heat sink was given by
cooling water which rejected the heat into the air in an air cooler, and temperature depends on ambient
conditions. The range of the explored cooling water temperatures was 11-46°C. The range of
temperature difference between heat source inlet and cooling water inlet was 38-71K, but bear in mind
that the mass flow rates differed as well, between 0.15-0.87 kg/s at the heat source side and 0.27-
0.47 kg/s at the cooling water. The experimental campaigns with LiBr solution were performed in total
in 9 days between June and November 2020. A sample of recording of the selected data from the
operation is in Figure 4, with a distinct period of turbine operation, while the bypass was operated at
the rest of the time. The selected operation data of the steady state periods are summing up for about 20
hours out of which the turbine was in operation for more than 6 hours.
Figure 4: Example of the record of selected parameters from the APC operation with an indication of
the selected steady-state periods with and without turbine operation (numbers correspond to the PFID)
3 DATA EVALUATION From the recorded data are selected time periods or rather a constant operation, evaluated primarily by
the steadiness of the pressure levels. For further evaluation, the average values from these selected time
periods were obtained, and each value was treated as an operational state.
The mass flow rate cannot be directly evaluated from the volumetric flow rate of the liquid streams.
The reason is that the density is a function of LiBr concentration, which is not directly measured.
Therefore mass and energy balance equation of the desorber is used with the inputs, outputs and
measuring point according to Figure 5a. The assumption taken is that the rich solution leaving the
absorber is at the saturated rich solution temperature, thus its concentration is given. As the solution is
boiling within the desorber, this assumption should be accurate. A slight difference in results is obtained
if mass balance is applied to both solution and each component or, e.g. energy balance of separation
(from calculated 2 phase fluid quality). Using the energy balance also helps to smoothen and to lower
the impact of transient effects affecting the flowrate during cycle control (rising or falling of desorber
liquid level) and from volumetric flowrate measurement inaccuracies.
The resulting graph in Figure 5b shows the discrepancy between the values obtained from energy
balance and the difference from the two measured volumetric flow rates. In order to select data with
higher quality, values with relative difference smaller than 40% or absolute difference smaller than
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0.015 kg/s were selected. Fluid properties are evaluated using the REFPROP database for water and
using formulation (Kim and Ferreira, 2004) for the LiBr solution.
a) b)
Figure 5: Schematic diagram of desorber parameters used in the evaluation of steam mass flow rate
(a) and graph of steam mass flow rate obtained by the difference in measured volumetric flow and
from the energy balance (b)
The turbine efficiency is evaluated with respect to the isentropic power. The efficiency is evaluated
both for the produced electrical power output (electrical efficiency), but isentropic efficiency is from
the power output evaluated as well. As the measured power is in the form of electricity, obtaining
mechanical power output has been done by using generator efficiency evaluated for each operation
state. The generator efficiency is obtained from characteristics provided by an eCalc1 tool, which
includes performance parameters of a wide range of aeromodelling BLDC motors. This tool was used
to obtain torque–rotational speed–efficiency dependencies, which were then applied. Additionally, a
nearly constant voltage drop on the rectifier was taken into account.
For the system itself, the important parameter is not just cycle efficiency (specified in Equation (1)),
but also a utilization efficiency (with respect to heat source heat content). Reference for the utilization
efficiency was taken as cooling water inlet temperature Tcw,in as shown in Equation (2). Only the gross
efficiency (excluding all parasitic load) was evaluated at this point. The unit was in most of the time,
operated with the bypass valve, only simulating the turbine. In order to assess the potential of the cycle
in general, a hypothetically achievable expander efficiency ηturb of 65% has been assumed as safely
realistic for such small systems based on (Weiss et al., 2017; Weiß et al., 2019). The cycle parameters
are then calculated with this expander efficiency value.
When the turbine was in operation the system produced an actual power output. This DC (after
rectification) power output, i.e. including turbine isentropic efficiency, generator efficiency and rectifier
diode efficiency (voltage drop), is then used to evaluate actual system efficiency as shown in second
expressions in Equations (1) and (2). The number of operating points with turbine is lower with one
reason being the given turbine’s swallowing capacity.
𝜂𝑐 =��𝑡𝑢𝑟𝑏
��𝑖𝑛=
��𝑠𝑡𝑒𝑎𝑚⋅(ℎ𝑡𝑢𝑟𝑏,𝑖𝑛−ℎ𝑡𝑢𝑟𝑏,𝑜𝑢𝑡,𝑖𝑠)⋅ 𝜂𝑡𝑢𝑟𝑏
��𝑠𝑜𝑢𝑟𝑐𝑒⋅(ℎ𝑠𝑜𝑢𝑟𝑐𝑒,𝑖𝑛−ℎ𝑠𝑜𝑢𝑟𝑐𝑒,𝑜𝑢𝑡)│𝜂𝑡𝑢𝑟𝑏=65% 𝑂𝑅 𝜂𝑐 =
��𝑡𝑢𝑟𝑏,𝑒𝑙,𝑚𝑒𝑎𝑠𝑢𝑟𝑒𝑑
��𝑖𝑛 (1)
𝜂𝑢 =��𝑡𝑢𝑟𝑏
��𝑠𝑜𝑢𝑟𝑐𝑒=
��𝑠𝑡𝑒𝑎𝑚⋅(ℎ𝑡𝑢𝑟𝑏,𝑖𝑛−ℎ𝑡𝑢𝑟𝑏,𝑜𝑢𝑡,𝑖𝑠)⋅ 𝜂𝑡𝑢𝑟𝑏
��𝑠𝑜𝑢𝑟𝑐𝑒⋅(ℎ𝑠𝑜𝑢𝑟𝑐𝑒,𝑖𝑛−ℎ𝑠𝑜𝑢𝑟𝑐𝑒 (𝑇=𝑇𝑐𝑤,𝑖𝑛))│𝜂𝑡𝑢𝑟𝑏=65% 𝑂𝑅 𝜂𝑐 =
��𝑡𝑢𝑟𝑏,𝑒𝑙,𝑚𝑒𝑎𝑠𝑢𝑟𝑒𝑑
��𝑠𝑜𝑢𝑟𝑐𝑒 (2)
Uncertainty analysis of the systematic error was performed for the cycle parameters as well. Partial
derivatives of the resulting parameters were substituted by differences with a specified step from the
measured value. Since the measured temperature and pressure differences are rather small and the
method of obtaining turbine mass flow rate and solution concentration are not straight forward,
1 https://www.ecalc.ch/torquecalc.php
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evaluated uncertainties are in the order of often dozens percent of the reported value, with the median
of the uncertainty of the main parameters reported in Table 3 (including possible outliers). This
highlights the fact that the results need to be taken as the report of the first proof of concept operation
and for higher accuracy a different approach to the instrumentation can be taken in the future. Note the
specifically low value for rich solution concentration as the solution at the desorber outlet is saturated
and only one pressure and temperature affects the resulting value. Similarly the measured utilization
efficiency is calculated from higher temperature difference and from directly measured power output,
even though the overall values are low.
Table 3: Median uncertainties of major cycle parameters
Parameter Uncertainty (%) Parameter Uncertainty (%)
Cycle efficiency (ηturb=65%) 17.8 Steam mass flow rate 35.9
Utilization efficiency (ηturb=65%) 39.9 Solution flowrate 25.9
Cycle efficiency (measured Wturb,el) 22.0 Rich solution concentration 1.3
Utilization efficiency (m. Wturb,el) 7.2 Lean solution concentration 6.3
Pressure ratio 20.4 Concentration change 34.6
4 EXPERIMENTAL RESULTS The experimental performance has been explored mainly from three points of view, regarding
parameters of the cycle, the performance of the plastic 3D printed turboexpander and obtained actual
temperature profiles during the phase change with the temperature glide.
4.1 Cycle parameters
The cycle and utilization efficiency for assumed expander efficiency of 65% (or rather efficiency
potential) is plotted for these states in Figure 6 as a function of cycle pressure ratio and distributed
according to the calculated concentration difference. The operation states recorded as more accurate are
highlighted with rich colour. The second graph shows the same parameters but for actual expander
electrical output. In these graphs are shown the uncertainties values (in Figure 6a only for the more
accurate states) for illustration that the results are mostly illustrational rather than highly precise.
a) b)
Figure 6: Cycle and utilization efficiencies (c and u) as a function of charged LiBr concentration (40-
54%) and cycle pressure ratio (PR). Values for hypothetical 65% expander efficiency with “more
accurate” states in bold (a) and actually measured parameters with a current plastic turbine (b)
Note that the operation points are, however, recorded over a range of heat source and heat sink
temperatures and mass flow rates. In order to generalize the data with respect to the temperature
potential, Figure 7a shows the same data points as a function of the temperature difference between the
heat source and heat sink inlets. It is not an exhaustive range of possible operation states, but the general
trend is seen that the maximum cycle efficiency is independent of the fluid charge concentration. The
highest utilization efficiency is a domain of the lowest explored concentration, where is the highest
potential for concentration change from lean to rich solution.
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Multiple values for the same temperature difference (e.g. around 67°C, c,40%) are partly caused by the
high uncertainty, partly the temperatures of heat source and sink can differ. Another cause is in different
ratio between the lean and rich solution flowrate (another degree of freedom for the APC control). This
fact suggests that the optimal control strategy is also not as straight forward as for simple cycles such
as ORC.
a) b)
Figure 7: Cycle and utilization efficiencies (c and u) as a function of charged LiBr concentration (40-
54%) and of the temperature difference ΔT between the heat source and heat sink (a) and of a
concentration change in the cycle (b), all for hypothetical 65% expander efficiency
The concentration change is furthermore used for plotting the data Figure 7b. Here we can see a
confirmation of the thermodynamic models that the highest cycle efficiency is associated with lower
values of concentration change (but not the very lowest, particular optimum exists). On the other hand,
the utilisation efficiency increases with the concentration change with a possible optimum at somewhat
higher values. Thus, a drop in utilisation efficiency might come with a further increase in the
concentration difference (if the operating conditions allow such a state).
4.2 Turboexpander performance
During the operation of the experiment, the expander was in operation between various pressure levels
with the summary of all experimental characteristics in Figure 8. During the operation, a resonance
frequency and related vibrations caused that the maximal turbine speed was around 8000-9000 rpm.
The results confirm that the generally expected trend of decreasing efficiency with increasing the
pressure ratio is valid. Even with the poor surface quality, the efficiency is mostly within boundaries
provided by different loss models. This shows a high prospect of the plastic 3D printed concept with
better engineering than was adopted for this proof of concept. Furthermore inspection after about a year
in the environment with LiBr and more than 6 hours of operation, nor the turbine, nor the generator
showed any signs of damage or corrosion.
Figure 8: Measured turbine characteristics from APC operation and comparison with design
max ηcycle
max ηutil
ηcycle
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There are several reasons behind the very low efficiency of the tested turbine. One is surely the poor
surface quality of the flow sections as for these first trials, no post-processing was applied and the
surface is in the as-printed state. Second reason is the low velocity ratio, as it can be seen already from
the design point at unreached 15 000 rpm and the theoretical optimum is around 30 000 rpm. Lastly,
design was performed with loss models adopted from large steam turbines and no CFD optimization of
the geometry has been performed. Altogether, there is clearly a potential for major improvement with
more advanced design engineering than was adopted for this first proof of concept.
4.3 Temperature glide measurements
One of the objectives of the rig was to evaluate the temperature glide across the non-isothermal phase
change during desorption and absorption, as high temperature change was suggested in the past for
waste heat recovery. This glide for several selected operation cases is shown for both desorber and
absorber in Figure 9. For the desorber, there is a measured temperature of the boiling solution as the
temperature probes are placed under the liquid level. The recorded glide is significantly lower than
theoretical yet still well measurable. A certain decrease of the glide was expected due to the large
volume shell & tube exchanger with a nearly quiescent pool of the boiling solution. Interestingly, the
glide doesn’t much differ between the operation states with various solution charge LiBr concentration.
Such a result is, however, in accord with results in Figure 7b, where no clear relation between
concentration difference and charge solution concentration has been found. The lowest absolute
absorber temperature values for some of the 40% concentration are caused only by the fact that ambient
conditions allowed to achieve lower temperatures at these tests.
a) b)
Figure 9: Measured temperature glide profiles in desorber (a) and absorber (both sections) (b)
In the case of the absorber, in most of the cases was operational only the upper half as the lower half
designed as a backup if the absorption rate is insufficient. The measured temperature corresponds
sometimes to the low pressure water vapour than to the liquid LiBr solution as the probes wetting by
the solution cannot be fully assured due to the nature of the process. The inlet temperature shown is the
turbine outlet vapour, while the first point of measurement is after a packing (for adiabatic absorption)
and a small portion of cooling coils. Heat released during the adiabatic absorption may explain the
temperature increase in some cases between the inlet and the first measurement. An increase in
temperature in the bottom part may be associated with lower wetting of a specific probe by the solution
when the steam has the higher temperature.
5 CONCLUSIONS A proof of concept absorption power cycle unit with LiBr solution working fluid has been built and
operated. To the authors’ knowledge, the unit is a first power cycle with a salt solution experimentally
operated. With the heat source temperature below 90°C, the maximum gross electrical cycle efficiency
reached 0.8% and about 150 W. However, with a state of the art turboexpander, there is potential for
maximal cycle efficiencies of almost 5% and heat source utilization efficiencies around 0.5%. A plastic
3D printed turboexpander has successfully applied. Current turbine efficiency limits of around 25% can
be easily improved with a mechanical design allowing higher rotational speed and with surface
polishing (the as-printed state was used for first tests). The temperature glide has been measured, even
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though lower than theoretical, which was partly expected with the chosen desorber design. Overall, the
experimental performance and results show the general feasibility of the concept.
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ACKNOWLEDGEMENT This work was supported by the Grant Agency of the Czech Technical University in Prague, grant No.
SGS18/128/OHK2/2T/12 and SGS21/111/OHK2/2T/12.