estimating renewable thermal drying potential of sewage sludge 16 estimati… · ·...
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ESTIMATING RENEWABLE THERMAL DRYING POTENTIAL OF SEWAGE SLUDGE
Julio Cezar Rietow1,2
*, Bruno Galvão Cavalieri1,2
, Charles Carneiro1,3
,
Anderson Cardoso Sakuma2, Gustavo Rafael Collere Possetti
1,3
1Water and Sanitation Company of Paraná State (Sanepar, Brazil) - Research and Development Consulting
2Pontifícia Universidade Católica do Paraná (PUCPR, Brazil) - Polytechnic School - Environmental Engineering
3Instituto Superior de Administração e Economia do Mercosul (ISAE, Brazil) - Professional Master’s Program in
Governance and Sustainability
ABSTRACT
The Brazilian government, through the National Sanitation Plan, intends to invest more than US$ 500
billion in the sanitation sector until the year 2033, especially in the areas of collection and treatment of
wastewater. Given this situation, sanitation companies tend to look for simplified technologies and
already established treatment, for example, the UASB reactors. A major advantage of these systems is
the production of biogas, a by-product of high energy potential that contains methane in its
composition. Additionally, these systems also produce sludge, a by-product that typically has high
moisture content and pathogenic microorganisms. So it is necessary to promote the dewatering and the
hygienization of the sludge before its proper disposal. Thus, this study aimed to evaluate the possibility
of using the biogas generated in the anaerobic reactors of a midsize domestic wastewater treatment
plant (WWTP) as a source of energy for drying and hygienization the sewage sludge produced in it.
The estimates were made from a mathematical model that took into account the conversion routes of
organic matter and losses of methane in the reactor. The biogas produced by the UASB reactors in
WWTP studied was estimated, on average, to be equal to (2,250.0 ± 330.1) Nm³.d-1
, with a potential
energy associated with this gas of (15,755.0 ± 102.3) kWh.d-1
, since the excess sludge production was
estimated on average to be equal to (11.50 ± 0.04) m³.d-1
. Using a study of thermal dryer patterns with
a yield of 80% biogas burning, it was estimated that the potential energy available for use in WWTP
2
during the study period was (4,374.5x103
± 27,996.8) kWh.year-1
. Meanwhile, the estimate of the
necessary energy demand for sludge drying to total solids (TS) content of 85% was
(3,710.7x103 ± 23,744.0) kWh.year
-1. Thus, the results show that the biogas generated by the UASB
reactors provide the full amount of energy required for the drying and thermal hygienization of the
sludge.
Keywords: biogas, thermal hygienization, sewage sludge, UASB reactor.
1 INTRODUCTION
The Brazilian government, through the National Sanitation Plan (PLANSAB), plans to invest more
than US$ 500 billion in the sanitation sector until the year 2033, especially in the areas of collection
and treatment of wastewater. Given this scenario, sanitation companies are looking for simplified
technologies and already established treatment methods from a sustainable perspective that consider
environmental, social and economic aspects.
Thus, anaerobic systems, especially those based on Upflow Anaerobic Sludge Blanket (UASB)
reactors, are widely used in Brazil. The financial resources required for their construction and operation
are typically less expensive than those required for systems with aerobic nature. Additionally, UASB
reactors enable the production of a by-product such as biogas, a compound that can be used for
renewable energy purposes within the same wastewater treatment system (CHERNICHARO, 2007).
Currently, most Brazilian sanitation companies that have UASB reactors technologies in their sewage
treatment systems do not use the produced biogas. Because it is composed mainly of methane (CH4),
one of the main drivers of greenhouse gases, the captured biogas is typically sent to an open flare
where it is then thermally destroyed with low efficiency. According to the data of the
3
Intergovernmental Panel on Climate Change (IPCC, 2013), CH4 has a global warming potential 25
times that of carbon dioxide (CO2).
However, when the biogas is destroyed in open flares, the methane chemical energy is wasted. Thus,
even if premature, tests and studies involving the use of biogas are being conducted by sanitation
companies in Brazil, especially regarding heat and electrical generation.
In addition to biogas, another by-product originating from the wastewater treatment in a UASB reactor
is the sludge. The sludge, which contains pathogens and is continuously produced in wastewater
treatment plants (WWTP), is one of the main problems of sanitation companies in Brazil. The costs of
handling, treatment, transportation and disposal may reach 20-60% of all operating costs of the
treatment plant (ANDREOLI et al, 2001).
Thus, one of the possible solutions to reduce costs involving sludge management is the thermal drying
energy from biogas utilization. Additionally, the use of this gas promotes the reduction of CH4
emissions to the atmosphere, contributing to environmental sustainability and supporting renewable
energy for WWTPs. However, to validate it an alternative, it is necessary to know the amount of biogas
available for use and, as a result, compare it to the amount required for a given sludge drying system.
In this context, this study aimed to investigate the possibility of energy biogas utilization to promote
both drying and thermal hygienization of the sludge produced in a Brazilian medium-sized WWTP.
The estimation of biogas production and its respective energy potential occurred using a model that
considers the mass balance of chemical oxygen demand (COD) and losses of methane within a UASB
reactor. A similar model was used to estimate the sludge production. The balance of energy in the
sludge dryer was based on experimental data recently obtained.
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2 BIOGAS PRODUCTION IN UASB REACTORS
The improved source of UASB reactors occurred in the Netherlands in the 1970’s after research
conducted by Wageningen University, headed by Professor Gatze Lettinga. The UASB reactor
technology quickly spread through tropical countries like Colombia, India and Brazil. In the latter, the
acceptance of UASB reactors was well-known, putting it in its current position as a worldwide leader
(JORDÃO and PESSÔA, 2011).
The operational principle inherent to wastewater treatment in a UASB reactor is shown in Figure 1.
The domestic wastewater in upflow sludge is mixed with a preformed blanket or inoculated, given its
richness in anaerobic microorganisms. The organic matter present in the sewage sticks to the sludge
blanket, which then is degraded and stabilized by means of the microbiological activity of the system,
becoming more stable products such as water, biogas, sludge and scum (CAMPOS, 2000).
Figure 1: Schematic representation of the operation of a UASB reactor filled with domestic sewage.
Source: Chernicharo, 2007.
According to Lettinga (2005), the use of UASB reactor can be understood as a treatment alternative for
sustainable development. Pointing towards self-sufficiency and resource saving, the UASB reactor
Collect the effluent Biogas output
Three-phase separator
Deflector gases
Gas bubbles
Influent
Decantation compartment
Opening for the decanter
Sludge particles
Digestion compartment
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generates by-products such as excess sludge for agriculture and biogas for bioenergy production, which
can be reused by sanitation companies.
The biogas originating from the UASB reactor consists mainly of CH4 (60 to 85% v/v), nitrogen (N2 -
10 to 25% v/v) and CO2 (5 to 15% v/v). In a smaller volume, biogas still has small amounts of
hydrogen (H2), hydrogen sulfide (H2S), ammonia (NH3) and other trace gases. The biogas energy
potential is largely related to the amount of CH4 present in its composition. Thus, the lower heating
value (LHV) of CH4 is around 8,580 kcal.m-3
, since biogas with a concentration of 60% CH4 has a
LHV of the order of 5,138 kcal.m-3
(LOBATO, 2011).
In addition, the thermal efficiency arising from the burning of biogas has been studied as an alternative
to the sludge drying process in thermal dryers. The thermal efficiency of the biogas combustion in
dryers is approximately 80% and is thus an energy efficient drying process (WELLINGER et al.,
2013). In addition, studies by Possetti et al. (2014), as part of an experimental investigation of a
thermal sludge drying pilot system powered by biogas, showed that the energy required to evaporate 1
kilogram (kg) of water present in the sludge is approximately 1.2 kWh.
Although decision-making intrinsic to the energy use of biogas should be guided by measurement
analysis, this is often not feasible. In these cases, decisions must be guided by mathematical model
estimates. Studies by Silva et al. (2014) in a large WWTP showed that the biogas estimation model in
UASB reactors proposed by Lobato (2011) presents the results with smaller deviations from those
measured. This must consider the model in question in its COD balance mass, as shown in Figure 2.
All possible routes conversion of organic matter in an UASB reactor and the loss of methane to liquid
medium for the gaseous medium and also related to the reduction of sulfate (SO4) can not be neglected.
In general, models of biogas estimates that do not take into account the mass balance of COD and
losses of methane in UASB reactors overestimate the production of biogas and the chemical energy
6
accumulated in it. Models such as the IPCC (2006) and the Framework Convention of the United
Nations on Climate Change (UNFCCC, 2013), may overestimate the production of biogas in UASB
reactors by up to seven times, putting out financially and economically unfeasible projects over the
energy use of this gas (SILVA et al., 2014).
Figure 2 – Schematic representation of the biogas estimation model in a UASB reactor based on COD balance and methane losses.
Source: Lobato, 2011.
2 METHODOLOGY
The methodology in this paper was applied at medium-sized WWTP located in Curitiba-Paraná, Brazil.
This WWTP has the capacity to treat up to 38,000 m³.d-1
of domestic sewage. Before being released
into the river, sewage is treated physically and biologically. For the biological sewage treatment, the
treatment plant has six UASB reactors and two aeration ponds. The biogas generated by UASB reactors
is captured by a pipe structure and delivered into open flares, where CH4 is partially destroyed. The
excess sludge removed from the UASB reactors is sent to a centrifuge mechanical dewatering system,
which induces a sludge total solids (TS) concentration of about 20% in the end the process.
The mathematical model proposed by Lobato (2011) estimated the potential energy generation
associated with biogas and sludge production from a WWTP. Responsible for COD mass balance in the
7
process, the model considered all the conversion modes of COD inside a UASB reactor, as well as
losses of methane in the gas and liquid phases.
Thus, to implement its model, it is important to highlight some parameters: the population served by
WWTP (Pop), the contribution rate per capita of COD (QPCCOD), the contribution rate per capita
sewage (QPC), COD removal efficiency in the reactors (ECOD = 60%), the SO4 concentration in raw
wastewater (CSO4 = 80 gSO4.m-3
), the efficiency to reduce SO4 into the reactors (ESO4 = 80%), the
operating temperature of the reactors (T = 25ºC), the percentage of CH4 present in biogas
(CCH4 = 70%), the sludge production rate in the system (Yobs = 0.213 kgCODsludge.kgCODremov-1
), the
total solids volatile (TSV) conversion factor into COD (KTSV-COD = 1.42 kgCODsludge.kgSTV-1
), the
percentage of TSV in the system (CTSV = 40%), the sludge density ( = 1,020 kg.m-3
), the COD factor
that is consumed in the SO4 reduction process (KDQO-SO4 = 0.667 kgCOD.kgSO4converted-1
), the
percentage loss of CH4 in the gas phase with the residual gas (pw = 7.5%) and the loss coefficient
related to CH4 dissolved in the liquid medium (pL = 25 mg.L-1
).
For a better understanding of the biogas and sludge produced at WWTP by UASB reactors based on
Lobato’s method (2011), a large amount of operational information during the year of 2013 was used.
Therefore, calculations of Pop, QPCCOD and QPC were made from the historical mean of discharge
data to treated sewage in UASB reactors (Qmed) and COD of the wastewater influent to the reactors
(CODinfluent). The mean standard deviation of the estimates were calculated and considered as standard
uncertainty. Then, this uncertainty was expanded for a confidence level of 95.5%.
To estimate the energy required for drying the sludge produced, the value proposed by Possetti et al.
(2014) was used, and then 1.2 kWh energy is required to remove 1 kg of water present in the sludge.
The estimate also took into account a final concentration of 85% of TS and a thermal efficiency of
biogas burning into the dryers of 80%.
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For a better understanding of the methodology used, Figure 3 shows the layout of the sludge drying
process using biogas as a source of renewable energy in a thermal dryer.
Figure 3 – Schematic representation of the thermal sludge drying process using biogas.
Source: Authors.
The estimated result of the potential energy generation available for use was then compared with the
power required to dry sludge in a thermal dryer; thus, self-sustainability energy of the thermal sludge
drying system could be evaluated.
4 RESULTS AND DISCUSSIONS
During the evaluation period, sewage influent discharge to WWTP UASB reactors followed a variable
performance. The mean was equal to (26,000.0 ± 37.1) m³.d-1
, and sewage COD average was equal to
(733.4 ± 3.1) mg.L-1
. The variable performance of COD is probably related to the significant rain that
occurred during the study period, which is also responsible for higher dilution of organic matter in
sewage. By multiplying discharge and COD, the average value obtained from COD load applied to the
system was equal to (18,555.0 ± 77.2) kgCOD.d-1
.
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The chart in Figure 4 shows the mass balance of COD in UASB reactors studied. The COD removal
efficiency used was equal to 60%, so the percentage of COD solubilized with treated effluent was 40%.
About (13.0 ± 1.8)% of COD removed in the process was converted into sludge. The COD used to
reduce SO4 was on average (8.2 ± 3.0)%. Regarding COD converted into methane and dissolved in the
effluent, the value was equal to (16.4 ± 6.0)%. On the other hand, COD that was converted into
methane and lost from the gas phase was (3.9 ± 0.6)%. Lastly, COD that was converted into methane
and recovered from the biogas was equal to (19.0 ± 11.8)%.
Figure 4 - Chart of approximate values of COD mass balance within the UASB reactors.
Source: Authors.
The normalized production of biogas was on average equal to (2,250.0 ± 330.1) Nm³.d-1
. Assuming
that biogas is composed by 70% of CH4, the production normalized of CH4 in the system was
(1,575.0 ± 231.4) Nm³.d-1
. Thus, the WWTP produced about (781,165.1 ± 114,050.1) Nm³ of biogas
and (546,815.6 ± 79,834.9) Nm³ of CH4 in 2013.
The production of biogas associated with potential energy generation was on average equal to
(15,755.0 ± 102.3) kWh.d-1
. During the study period, the WWTP produced an estimated
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(5,468.1x106 ± 34,995.2) kWh.year
-1. Taking into account a yield of 80% from biogas burning in the
sludge thermal dryer, the potential of energy available for use was (12,604.7 ± 81.8) kWh.d-1
or
(4,374.5x103 ± 27,996.8) kWh.years
-1.
The sludge production estimation into UASB reactors is about (11.50 ± 0.04) m³.d-1
of this sub-
product. Considering 20% of TS after the mechanical dewatering step, it is estimated that the WWTP
has produced about (4,043.7 ± 16.4) m³ of sludge in 2013. To achieve a final sludge content of 85% TS
it would be necessary to remove, on average, (8,763.8 ± 36.3) kg.d-1
of water in this material. Thereby,
the energy required to dry the sludge through sludge thermal drying system was on average
(10,516.6 ± 43.6) kWh.d-1
or (3,710.7x103 ± 23,744.0) kWh.years
-1.
Therefore, comparing the potential energy available for use with the required energy of the sludge
thermal drying system, as shown in the Figure 5, it is clear that the energy potential associated as
biogas produced by the UASB reactors would achieve in full the necessary energy demand for sludge
drying.
0 50 100 150 200 250 300 3500
10.000
20.000
30.000
40.000
50.000
60.000
70.000
80.000
En
erg
y (
kW
h.d
ia-1)
Time (days)
Potential energy available for use
Required energy of the sludge thermal drying system
Figure 5 – Comparison between the potential of energy from biogas available for use and the energy demand from sludge drying system.
Source: Authors.
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5 CONCLUSIONS
The results reported in this study indicate that the biogas produced by the UASB reactors can be used
as a renewable energy source for the drying and hygienization of sewage sludge produced in the
WWTP evaluation. The estimates showed that the use of the energy potential of biogas would fully
support the heat required for sludge thermal drying until 85% of TS. It is important, however, to verify
the biogas quantities available in WWTP by mean of field measurements.
The energy use of biogas and contributions to environmental issues regarding the reduction of
greenhouse gases emissions stands out as a promising alternative to reduce the costs inherent to the
management of sewage sludge produced in WWTPs. With the investments to be made in the Brazilian
sanitation sector, the energy use of biogas should be fully explored, favoring not only the process of
thermal drying for sludge but also the generation of electricity and cogeneration of energy. Thus, the
issue of sanitation in Brazil will soon be viewed with new perspectives, moving toward a more
sustainable, socially just, environmentally friendly, safe and economically viable model.
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