equilibrio so2 agua

8/18/2019 Equilibrio SO2 AGUA

1/28

T1(20 °C) T2 (30 °C) T1(20 °C) T2 (30 °C)

0.00E+00 0 0 0.000000 0.0000005.62E-05 0.5 0.6 0.000658 0.0007891.40E-04 1.2 1.7 0.001579 0.0022372.80E-04 3.2 4.7 0.004211 0.0061844.22E-04 5.8 8.1 0.007632 0.0106585.64E-04 8.5 11.8 0.011184 0.0155268.42E-04 14.1 19.7 0.018553 0.0259211.40E-03 26 36 0.034211 0.0473681.97E-03 39 52 0.051316 0.068421

XA PA (mm Hg) Y A (P T=1atm)


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2.79E-03 59 79 0.077632 0.1039474.20E-03 92 125 0.121053 0.1644746.98E-03 161 216 0.211842 0.2842111.39E-02 336 452 0.442105 0.5947372.06E-02 517 688 0.680263 0.9052632.73E-02 698 0.918421

T1(20 °C) T2 (30 °C) T1(20 °C) T2 (30 °C)

0.00E+00 0.000 0 0 0.000000 0.0000005.62E-05 0.006 0.5 0.6 0.000658 0.0007891.40E-04 0.014 1.2 1.7 0.001579 0.002237

2.80E-04 0.028 3.2 4.7 0.004211 0.0061844.22E-04 0.042 5.8 8.1 0.007632 0.0106585.64E-04 0.056 8.5 11.8 0.011184 0.0155268.42E-04 0.084 14.1 19.7 0.018553 0.0259211.40E-03 0.140 26 36 0.034211 0.0473681.97E-03 0.197 39 52 0.051316 0.0684212.79E-03 0.279 59 79 0.077632 0.1039474.20E-03 0.420 92 125 0.121053 0.1644746.98E-03 0.698 161 216 0.211842 0.2842111.39E-02 1.385 336 452 0.442105 0.594737

2.06E-02 2.060 517 688 0.680263 0.9052632.73E-02 2.730 698 0.918421'

(293,15 ) 11.230 1.002E-05 8535.086

(303,15 ) 16.043 -4.202E-05 12192.407

LEY HENRY-EQUILIBRIO T1(20 °C) T2 (30 °C) T1(20 °C) T2 (30 °C)

0.00E+00 0.008 -0.032 0.000 0.000 0.00E+005.62E-05 0.487 0.653 0.001 0.001 5.62E-051.40E-04 1.205 1.679 0.002 0.002 1.40E-042.80E-04 2.397 3.382 0.003 0.004 2.80E-044.22E-04 3.609 5.113 0.005 0.007 4.22E-045.64E-04 4.821 6.845 0.006 0.009 5.64E-048.42E-04 7.194 10.234 0.009 0.013 8.42E-041.40E-03 11.982 17.074 0.016 0.022 1.40E-03

XA XA (%) P A (mm Hg) Y A (P T=1atm)

(** ) 293,15 (** ) 303,15

XA PA (mm Hg) Y A (P T=1atm) X A


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1.97E-03 16.779 23.926 0.022 0.031 1.97E-032.79E-03 23.821 33.985 0.031 0.045 2.79E-034.20E-03 35.855 51.176 0.047 0.067 4.20E-036.98E-03 59.583 85.071 0.078 0.112 6.98E-031.39E-02 118.219 168.833 0.156 0.222 1.39E-022.06E-02 175.830 251.132 0.231 0.330 2.06E-02

2.73E-02 233.015 332.821 0.307 0.438 2.73E-02

0.00.00E+00

5.00E-03

1.00E-02

1.50E-02

2.00E-02

2.50E-02XA


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0.4000000.5000000.6000000.7000000.8000000.9000001.000000

f(x) = 43.9604275061x - 0.0105851845R² = 0.999202372f(x) = 33.5484558573x - 0.0099956532R² = 0.9992071153

YA vs XA (293,15 )

!"#$%& (YA vs XA(293,15 ))

YA vs XA(303,15 )

!"#$%& (YA vsXA(303,15 ))

YA


5/28

'

0.00762 (293,15 ) 11.230 (** ) 293,15

-0.03194 (303,15 ) 16.043 (** ) 303,15

ATOS EXPERIMENTALES-EQUILIBRIO T1(20 °C) T2 (30 °C) T1(20 °C) T2 (30 °C) T1(20 °C)

0 0 0.000000 0.000000 0.00E+00 0.0000.5 0.6 0.000658 0.000789 5.62E-05 2.5421.2 1.7 0.001579 0.002237 1.40E-04 0.4243.2 4.7 0.004211 0.006184 2.80E-04 25.0805.8 8.1 0.007632 0.010658 4.22E-04 37.7698.5 11.8 0.011184 0.015526 5.64E-04 43.278

14.1 19.7 0.018553 0.025921 8.42E-04 48.97826 36 0.034211 0.047368 1.40E-03 53.914

PA (mm Hg) Y A (P T=1atm) X A PA (m

0.00E+00 1.00E-02 2.00E-02 3.00E-020.0000000.1000000.2000000.300000

XA

0.00E+00 5.00E-05 1.00E-04 1.50E-040.000000

0.000500

0.001000

0.001500

0.002000

0.002500

f(x) = 16.0426407533x - 0.000042021R² = 0.9970983227

f(x) = 11.2303763325x + 1.00243853065631E-005R² = 0.9996621613

YA XA (293,15-!"#$%& (YA XA (29

E RY))C *# !"#$%& (C *# )

XA

YA


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39 52 0.051316 0.068421 1.97E-03 56.97759 79 0.077632 0.103947 2.79E-03 59.62692 125 0.121053 0.164474 4.20E-03 61.027

161 216 0.211842 0.284211 6.98E-03 62.992336 452 0.442105 0.594737 1.39E-02 64.816517 688 0.680263 0.905263 2.06E-02 65.990

698 0.918421 2.73E-02 66.617

0 10.00020.00030.00040.00050.00060.00070.000

$sv"% "/# XA (20°C) $sv"% "/# XA (30°C)

% DESVIACI N


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400

500

600

700

800f(x) = 33409.9249046412x - 8.0447402075R² = 0.999202372f(x) = 25496.8264515811x - 7.596696464R² = 0.9992071153

A vs XA (293,15 )

!"#$%& ( A vs XA(293,15 ))

A vs XA(303,15 )

!"#$%& ( A vsXA(303,15 ))

PA(mm Hg)


8/28

8535.086

12192.407

DESVIACI N T2 (30 °C) T1(20 °C) T2 (30 °C)

0.000 0.000 0.0008.880 2.542 8.8801.255 0.424 1.255

28.044 25.080 28.04436.873 37.769 36.87341.995 43.278 41.99548.050 48.978 48.05052.572 53.914 52.572

Hg) Y A (P T=1atm)

0.00E+00 1.00E-02 2.00E-02 3.00E-020

100

200

300

XA

RY)3,15-

0.00E+00 5.00E-05 1.00E-04 1.50E-040

0.2

0.4

0.6

0.8

1

1.2

1.4

1.6

1.8

f(x) = 12192.4069724763x - 0.03193599R² = 0.9970983227

f(x) = 8535.0860127279x + 0.0076185328R² = 0.9996621613

A XA (293!"#$%& ( A

E RY))A XA (303!"#$%& ( A

E RY))

XA

PA(mm Hg)


9/28


10/28


11/28

15- E RY)A (293,15-

15- E RY)A (303,15-


12/28


13/28

DATOS EQUILIBRIO T1(20 °C) T2 (30 °C) T1(20 °C) T2 (30 °C)

0.000000 0 0 0.000000 0.0000000.000056 0.5 0.6 0.000658 0.0007890.000140 1.2 1.7 0.001579 0.002237

0.000280 3.2 4.7 0.004211 0.0061840.000422 5.8 8.1 0.007632 0.0106580.000564 8.5 11.8 0.011184 0.0155260.000842 14.1 19.7 0.018553 0.0259210.001403 26 36 0.034211 0.0473680.001965 39 52 0.051316 0.0684210.002790 59 79 0.077632 0.1039470.004200 92 125 0.121053 0.1644740.006980 161 216 0.211842 0.284211

n=3 Y#+1 (#=3) X0 ! ( * :;*2) 333.33

0.2 0 ( * :;*2) 5.17 #+1( * :

# Y#+1 (s < #$) Y1 C X#0 0.009 0.009 0 0.000001 0.1 0.009 0.0015832 0.001582 0.15 0.009 0.0025974 0.002593 0.2 0.009 0.0037384 0.003724

LINEA OPERACIÓN

# Y#+1 X#0 0.009 0.000001 0.1 0.001582 0.15 0.002593 0.2 0.00372

XA PA (mm Hg) Y A (P T=1atm)


14/28

6.4655172414

!#( * :;*2) 1( * :;* #+1( * :;*2)333.33 5.2194 5.2194333.86 5.2194 5.7471334.20 5.2194 6.0852334.58 5.2194 6.4655

0.000000 0.0010000.000000

0.050000

0.100000

0.150000

0.200000

0.250000

f(x) = 51.431R² = 0.99582

f(x) = 621.7R² = 0.9994

Ya


15/28

0.002000 0.003000 0.004000 0.005000 0.006000 0.007000 0.008000

029333x + 0.0132266136035

42738136x 2 + 26.4641526346x - 0.002540715237313

C &v% >$ E? "

! %&"@:*" (C &

# *"% (C &v

!"#$% >$ B


16/28

% >$ E? ")

>$ E? ")

#


17/28

ATB E D ! FR BX% Y%

0 00.01260.01670.0208 0.0158

0.0258 0.01970.0309 0.02390.0405 0.03280.0503 0.04160.0737 0.0657

0.096 0.09150.137 0.150.175 0.218

0.21 0.2980.241 0.392

0.297 0.618

Y#+1 (#=3) X0 ! ( * :;*2) 10.44 #+1( * :;*2)0.06 0 ( * :;*2) 4.41 !%-#( * :;*2)

!#( * :;*2)# X# Y#+1

0 0 6.00E-041 0.05 1.15E-012 0.01 2.34E-023 0.02 4.63E-02

# 0.02601 6.00E-02


18/28

0.00063834.696 X# 0.026010.279 Y1 6.379E-04

10.723 1( * :;* 4.417

0

0.02

0.04

0.06

0.08

0.1

0.12

0.14

Ya


19/28

0 0.01 0.02 0.03 0.04 0.05 0.06 0.0

f(x) = 2.2837402778x + 0.0006R² = 1

f(x) = 2.6281148962x 2 + 0.6971739937x + 2.18427186819347E-005R² = 0.9999519183


20/28

0.08

C &v% E? " "'&"# *"% (C &v% E? " "'&" )# *"% (C &v% E? " "'&" )# *"% (C &v% E? " "'&" )

!"#$% B<!"#$%& (!"#$% B


21/28

#+1( * :) 100 C &v% >$ $? " "'&" Y% #+1 0.022 Y%=0,68X%X% 0 0 X% Y%

0 0!% # ( * A :) 1.98 0.005 0.0034

%1 ( * A :) 0.22 0.01 0.0068

( * A :) 97.8 0.015 0.01021 ( * A :) 98.02 0.02 0.0136

Y %1 0.00224444 0.025 0.0170.03 0.0204

C!"#$ $!"&' m " Y% #+1 X# 0 0.00224444

0.022 0.03235294 0.03235294 0.022

Y %1 X0

0.0022444399 0

X" (m ") ! ( * :) 88.83! # ( * :) 61.2 ! # ( * :) 90.81! ( * :) 59.22 X# 0.02180377


22/28

C!"#$ $!"&' &a*&' x0 0.00224444 0 0.00224444

0.02180377 0.022 0.015 0.01582150.02180377 0.022

0 0.005 0.01 0.015 0.02 0.0250

0.005

0.01

0.015

0.02

0.025

f(x) = 0.9060618241x + 0.0022444399

R² = 1

f(x) = 0.6106264028x + 0.0022444399

R² = 1f(x) = 0.68x - 1.31132768882862E-018R² = 1

Ya


23/28

.03 0.035

C &v% >$ E? " "'&"

!"#$%& (C &v% >$ E? " "'&" )

!"#$% B


24/28

DATOS EQUILIBRIOxA A

0 00.0126 0.01510.0167 0.02010.0208 0.0254

0.0258 0.03210.0309 0.0390.0405 0.05270.0503 0.06710.0737 0.105

0.096 0.1450.137 0.2350.175 0.342

x1 0.101 1 0.25

0.01 0.0340.05 0.14x2 0.005 2 0.02


25/28

0 0.02 0.04 0.06 00

0.05

0.1

0.15

0.2

0.25

0.3

0.35

0.4

f(x) = - 5.3331121738xR² = 0.9999974019

f(x) = 5.3790598098x 2R² = 0.9997247171

Ya


26/28

.08 0.1 0.12 0.14 0.16 0.18 0.2

2 + 2.9632214863x + 0.0051269325

+ 0.9869527384x + 0.0023123814

C &v% >$ E? " "'&"# *"% (C &v% >$ E? " "'&" )

! %&"@:*" (C &v% >$ E? " "'&" )!"#$% B<

# *"% (!"#$% B


27/28

C &v% >$ $? " "'&" Y%=25X%

X% Y%0 0

0.005 0.1250.01 0.25

0.015 0.3750.02 0.5

0.025 0.6250.03 0.75

0.035 0.8750.04 1

0.045 1.1250.05 1.25

X Y

0.002 00.008 0.13150.021 0.3243

0.03 0.41430.04 0.5

0 0.010

0.2

0.4

0.6

0.8

1

1.2

1.4

f(x) = -R² = 0.9

f(x) = 25xR² = 1

Ya


28/28

0.02 0.03 0.04 0.05 0.06

98.2365712712x 2 + 21.2062182717x - 0.035046840586722715

+ 1.33897934774369E-016C &v% >$ E? " "'&"!"#$%& (C &v% >$ E? " "'&" )!"#$% B<

# *"% (!"#$% B

equilibrio so2 agua

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