epoxy - amazon s3 data … · impregnating and insulating copper coil windings in motors and...

EPOXY TECHNOLOGY Number of Components Two Frozen Syringe Mix Ratio By Weight 101 Specific Gravity 118 120degC 5 Minutes

Part A 120 100C 10 Minutes Part B 102 80degC 30 Minutes

P~Li~ s3Hoorn 2 Hours Shelf Life One year at 23degC Six months at -40C Note Container(s) should be kept closed when not in use middotPlease see Applications Note available on our website -TOTAL MASS SHOULD NOT EXCEED 25 GRAMSshy-IF PARTA CRYSTALIZES IN STORAGE PLACE CONTAINER IN A WARM OVEN UNTIL CRYSTALIZATION DISAPPEARS ALLOWTO COOL TO ROOM TEMPERA TURE BEFORE MIXING WITH THE PART B HARDENER middotPlease refer to Tech Tip 7 on our website -shy

Minimum Bond Line Cure Schedule 150degC 1 Minute

Product Description EPO-TEK 353ND is a tWo component high temperature epoxy designed for semiconductor hybrid fiber optic and medical applications It is one

of the most popular EPO-TE~ brand products and is known throughout the world for its performance and reliability Also available in a single component frozen syringe

EPO-TEKreg 353ND Advantages amp Application Notes

bull Reasonable pot-life that allows for low temperature curing to be realized It has an amber color change upon cure

bull Passes NASA low outgassing standard ASTM E595 with proper cure - httpoutgassingnasagov

bull Semiconductor suggested applications wafer-wafer bonding of CSP fabrication of MEMs devices flip chip underfill

bull Hybrid suggested applications providing near hermetic seals and UHV seals in sensor devices resisting high temperature packaging o Down-Hole petrochemical fiber optic sensors resisting gt200middotC field conditions

bull Fiber optic adhesive designed to meet Telecordia 1221 - suggested applicetions o Sealing fiber into ferrules transmitting light in the optical pathway from 800- 1550 nm range o Fiber component packaging adhesive for active alignment of optics environmental seal of opto-package V-groove arrays

bull Medical suggested applications o Potting fiber optic bundles into ferrules for light guides and endoscopes capable of resisting several sterilization techniques including

ETa gamma ION beam H202 plasma and gt200 autoclave steam cycles excellent adhesion to surfaces including SST diamond titanium brass ceramics glass and most plastics

o Adhesive for catheter devices including stents and guide wires o Certified to USP Class VI and ISO 10993 biocompatibility standards for medical implants o Compatible with CIDEXreg OPA sterilization

bull Electronics Assembly suggested applications o Used as dielectric layer in the fabrication of capacitors laminating PZT ferroelectrics found in ultrasound or ink-jetting devices o Impregnating and insulating copper coil windings in motors and inductor coils Bonding ferrite cores and magnets o Structural grade epoxy found in hard-disk drive devices bonding of SST metals kapton and magnets

Typical Properties (To be used as a guide only not as a specification

Cure condition 150C11 hour iiiiiiii~iiiiiii~i~~~ij

Consistency liquid Viscosity (50 RPM23C) 3000 - 5000 cPs Thixotropic Index NA Glass Transition Temp(Tg) a 90C (Dynamic Cure

2Q-200middotC IIS0 25 Min Ramp -1Q-200middotC 20degClMin) Coefficient of Thermal Expansion (CTE)

Below Tg 54 x 10-6 ininrC Above Tg 206 x 106 ininre

Shore 0 Hardness 85 Lap Shear Strength 23C gt 2000 psi Die Shear Strength a 15 Kg 5100 psi

317

nm

200degC 022 250degC 039 300degC 087

Operating Temp Continuous 55degC to 250degC Intermittent - 55degC to 350middotC

Storage Modulus 23C 516912 psi Ions CI 329 ppm

nm

EPOXY TECHNOLOGY INC 14 Fortune Drive Billerica MA 01821-3972 Phone 9786673805 Fax 9786639782

wwwEPOTEKcom

Epoxies and Adhesives for Demanding Applicatlonstrade This information is based on data and tests believed to be accurate Epoxy Technology Inc makes no warranties

(expressed or implied) as to its accuracy and assumes no liability in connection with any use of this product n_bull VVII

Revision 1102CLP SAFETY DATA SHEET Date 30 August 2012

SECTION 1 IDENTIFICATION OF THE SUBSTANCEMIXTURE AND OF THE COMPANYUNDERTAKING

11 Product identifier EPO-TEK 353ND Part A GHS Product Identifier EPO-TEK 353ND Part A Chemical Name Not applicable Trade name EPO-TEK 353ND Part A EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available

12 Relevant identified uses of the substance or mixture and uses advised against Identified use(s) Uses advised against Users are recommended to seek further advice

13 Details of the supplier of the safety data sheet Company Identification Epoxy Technology Inc Address 14 Fortune Drive Billerica MA 01821 USA Telephone (978) 667-3805 E-Mail (competentperson)techservepotekcom

14 Emergency telephone number - Chemtellnc Emergency Phone No (800) 255--3924 (813) 248-0585

SECTION 2 HAZARDS IDENTIFICATION

21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 5 Skin irritation 2 Eye Damage 3 Skin Sensitizer 1 (3115

322 332 341 ) 212 Directive 67548EEC amp Directive 199945EC - HARMFUL IRRITANT 22 Label elements 221 Label elements According to Regulation (Ee) No 127212008 (CLP)

GHS Product Identifier (EU)

Hazard lttgt~ Signal word(s) WARNINGpictogram(s)

Hazard H303 May be harmful if swallowed statement(s) H315 Causes skin irritation

H317 May cause an allergiC skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer

Precautionary P202 Do not handle until all safety precautions have been read and understood statement( s) P2S0 Wear protective glovesprotective clothingeye protectionface protection

P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P33S IF IN EYE8 Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P30S + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to 8end to a licensed recycler reclaimer or incinerator

222 Label elements Uf)4UrtlL amp Directive 19991451EC

Hazard Symbol

Risk Phrases R22 Harmful if swallowed R363S Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms

Safety Phrases 82 Keep out of the reach of children 823 Do not breathe fumeslvapour 82425 Avoid contact with skin and eyes 826 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 83639 Wear suitable protective clothing and eyeface protection 845 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)

9 Expiration Date 30 August 2014

23

33

Revision 1102GLP SAFETY DATA SHEET Date 30 August 2012

EPOmiddotTEK 353ND Part A

Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Sensitizer (Skin) Irritant (Eyes Skin) HMIS Health-2 Flammability-1 Reactivity - 0

WHMIS Classification (Canada) Hazardous under WHMIS Class D2B - Material Causing Other Toxic Effects (Sensitizer Irritation)

24 Additional Information None

SECTION 3 COMPOSITIONINFORMATION ON INGREDIENTS

i

EC Classification No 12722008EC

Hazardous ingredient(~) I WIW REACH

CAS No ECNo Registration Hazard pictogram(s) and Hazard statement(s) No

3153212 341 3312

Ilttgt~Epoxy Phenol Novolac gt75 128064-14-4 None NA 412 H303 H315H317 H319 H411 EUH205

REACH Hazardous ingredient(s) WIW CAS No EC No Registration Hazard pictogram(s) and Risk (R) Phras(es)

No

Epoxy Phenol Novolac gt75 28064-14-4 None NA Xn Xi R22 3638 43 51

Additional Information - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product

SECTION 4 FIRST AID MEASURES

41 DeSCription of first aid measures

Inhalation

Skin Contact

Eye Contact

Ingestion

42 Most important symptoms and effects both acute and delayed

43 Indication of the immediate medical attention and special treatment needed

Remove patient from exposure Keep patient at rest and give oxygen if breathing difficult If symptoms develop obtain medical attention

Remove contaminated clothing immediately and drench affected skin with plenty of water If irritation (redness rash blistering) develops get medical attention

Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention

Ingestion may cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention

Acute Causes serious eye irritation Causes skin irritation Allergic contact dermatitis Ingestion may cause irritation of the gastrointestinal tract

Delayed and chronic effects Allergic eczema

Treat symptomatically

Page 219 Expiration Date 30 August 2014


EPO-TEK 353ND Part A

SECTION 5 FIRE-FIGHTING MEASURES

Combustible but not readily ignited Acrid smoke Flash Pointgt 933degC I 200degF

51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or waterspray Media Unsuitable Extinguishing None known Media

52 Special hazards arising A self contained breathing apparatus and suitable protective clothing should from the substance or be worn in fire conditions mixture

53 Advice for fire-fighters Extinguish preferably with dry chemical foam or waterspray

SECTION 6 ACCIDENTAL RELEASE MEASURES

61 Personal precautions protective equipment and emergency procedures

62 Environmental precautions 63 Methods and material for

containment and cleaning up 64 Reference to other sections 65 Additional Information

Ensure full personal protection (including respiratory protection) during removal of spillages

Ventilation recommended

Transfer to a lidded container for disposal or recovery See Also Section 7 8 13 None

SECTION 7 HANDLING AND STORAGE

Precautions for safe 71 handling

72 Conditions for safe storage including any incompatibilities Storage Temperature Storage Life Incompatible materials

73 Specific end use(s)

Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapours Keep away from oxidizing agents Keep away from fire sparks and heated surfaces- no smoking Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc

Ambient Not available Oxidizing agents

Consult the supplier

SECTION 8 EXPOSURE CONTROLSPERSONAL PROTECTION

81 Control parameters

811 Occupational Exposure Limits

I CAS No LTEL I LTEL STEL STEL

i

SUBSTANCE Note8 hr TWA ppm) (8 hr TWA mgm3) (ppm) (mgm3) I

NE NE NE NE PEL (OSHA)

Epoxy Phenol Novolac 28064-14-4 I

i i NE NE NE NE TLV (ACGIH)


Revision 1102CLP SAFETYDATA SHEET Date 30 August 2012


812 Biological limit value

I Limit value type (country of origin)

SUBSTANCE CAS No Biological limit

value Note

USA None None None None

813 PNECs and DNELs

I DNEL Oral Inhalation Dermal

i Industry - Long Term - Local effects NA NA NA

Industry - Long Term - Systemic effects NA NA NA

Industry - Short term - Local effects NA NA NA

Industry - Short term - Systemic effects NA NA NA

Professional- Long Term - Local effects NA NA NA

Professional- Long Term - Systemic effects NA NA NA

Professional - Short term - Local effects NA NA NA

i Professional - Short term - Systemic effects NA NA NA

Consumer - Long Term - Local effects NA NA NA

Consumer - Long Term - Systemic effects NA NA NA

Consumer - Short term - Local effects NA NA NA

Consumer - Short term - Systemic effects NA NA NA

PNEC

Aquatic Compartment Not available

ITerrestrial Compartment Not available

I Atmospheric Compartment Not available

822 Personal protection equipment

O[ Respirators IWear suitable respiratory protective equipment if exposure to levels bull above the occupational exposure limit is likely I

01 Eye Safety glasses Protection

I

Gloves Wear protective gloves

ill I

Body Wear suitable protective clothing and gloves Ie protection

Engineering Use adequate ventilation andor engineering controls in high Controls tem~erature processing to prevent ex~osure to vapors Other Remove contaminated saturated clothing immediately Contaminated

clothing should be thoroughly cleaned


Revision 1102ClP SAFETY DATA SHEET Date 30 August 2012


SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

91 Information on basic physical and chemical properties Appearance Clear liquid Colour Clear liquid Odor Mild I Slight Odor Threshold (ppm) Not available Melting Point (C) I

Not available Boiling pointboiling range (0C) Not available Freezing Point (C) Flash Point (C) gt 200F 193degC Explosive limit ranges Not available Auto Ignition

Not available Decomposition Temperature (0C) Not ~vailableTemperature eC) Explosive properties Not available Oxidizing properties Not available Flammability (solid

Not available pH (Value) Not available gas) Evaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) Not available Density (gml) Not available Solubility (Water) Practically insoluble Solubility (Other) Not available Partition Coefficient (n-

Not available Viscosity (mPas) Not available Octanollwater)

92 Other information Volatile Organic Chemical (VOC) Content - Not available

SECTION 10 STABILITY AND REACTIVITY

101 Reactivity Slight

102 Chemical stability Stable under normal conditions

103 Possibility of hazardous reactions Can react violently if in contact with - Oxidizing agents

104 Conditions to avoid Avoid contact with heat and ignition sources

105 Incompatible materials Bleaching products and comparable oxidizers

106 Hazardous Decomposition Carbon monoxide Carbon dioxide Product(s)

SECTION 11 TOXICOLOGICAL INFORMATION

I SUBSTANCE CAS No LDso Oral LCso (Inhalation LD50 (Dermal

Rat Rat Rat)

Epoxy Phenol Novolac 28064-14-4 Not established Not established Not established

I 111

1112

112

~~~k

Information on toxicological effects

Mixtures Acute toxicity Irritation

Corrosivity Sensitisation Repeated dose toxicity Carcinogenicity Mutagenicity Toxicity for reproduction

Other information

Page 59

May be harmful if swallowed Causes skin and eye irritation May cause transient irritation Notto be expected May cause sensitization by skin contact No data No data No data No data

None

Expiration Date 30 August 2014

Revision 1102CLP SAnETY DATA SHEET Date 30 August 2012


SECTION 12 INFORMATION

121 Toxicity Harmful to aquatic life Harmful to algae

122 Persistence and degradability Biodegradable Not persistent

123 Bioaccumulative potential The product has low potential for bioaccumulation

124 Mobility in soil The product has high mobility in soil

125 Results of PBT and vPvB No data assessment

126 Other adverse effects No data

SECTION 13 DISPOSAL CONSIDERATIONS

131 Waste treatment methods Disposal should be in accordance with local state or national legislation Containers must not be punctured or destroyed by burning even when empty


SECTION 14 TRANSPORT INFORMATION

Land transport (ADRIRID) (b)(c)(d) UN number UN3082

Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Hazard label(s) Miscellaneous Environmental hazards Marine Pollutant Special precautions for None user

Sea transport (IMDG) (b)(c) UN number UN3082 Proper Shipping Name - Environmentally Hazardous Substance Liquid nos Transport hazard class(es) 9 Packing Group III Marine Pollutant Yes Special precautions for None user

Land transport (Within USA) (c)(d) UN number

Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Hazard label(s) None Environmental hazards None Special precautions for None user

Air transport (ICAOIIATA) (c) (d) UN number Proper Shipping Name - Not classified as dangerous for transport Transport hazard class(es) None Packing Group None Environmental hazards None Special precautions for None user

(b)- Fullpropershipplngname Environmentally Hazardous Substance Liquid nOs (Epoxy Phenol Novolac)

(c)- Consult with transport provider (d)- Check relevant regulations for Special Provisions

Transport in bulk according to Annex of MARPOL7378 and the IBC Code

Page 69 Expiration Date 30 August 2014 EPOXY TECHNOUXW

Revision 1102CLP SAFETY DATASHEET Date 30 August 2012


SECTION 15 REGULATORY INFORMATION

151

1511

1512

152

153

Safety health and environmental regulationslegislation specific for the substance or mixture EU regulations

Authorisations andor restrictions Consult the supplier on use European Union None (EINECSELINCS) WGK number Not Applicable

National regulations

USA

TSCA (Toxic Substance Control Act)

SARA 311312 - Hazard Categories

SARA 302 - Extremely Hazardous Substances SARA 313 - Toxic Chemicals

CERCLA (Comprehensive Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990)

CWA (Clean Water Act)

State Right to Know Lists

Proposition 65 (California)

Canada

WHMIS Classification

Canada (DSLINDSL)

Canada Ingredient Disclosure List (CIDL)

Chemical Safety Assessment

Label elements (EU)

All chemicals listed

Acute Health

Listed - None

Contains None

Listed - None

Listed - None

Listed - None

Listed - CAS28064-14-4 NJ PA

Listed - None

Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Sensitizer

Irritation) Listed - DSL

Listed as required

Irritant (Skin Eye) (Skin Sensitizer Irritation)

Label as Harmful Irritant under 199945EC 19072006EC and 127212008EC See Section 2 for full label requirements


Revision 1102CLP SA~ETY DATA SHEET Date 30 August 2012


SECTION 16 OTHER INFORMATION

The following sections contain revisions or new statements 1-16

LEGEND

ACGIH American Conference of Governmental Industrial NA not applicable not available Hygienists

AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and Health

ANSI American National Standards Institute NO not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective equipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and

Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TDG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)

mL milliliter WHMIS Workplace Hazardous Material Information System

References RTECS CAS Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information

Risk Phrases and Safety Phrases R22 Harmful if swallowed R3638 Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms S2 Keep out of the reach of children S23 Do not breathe fumeslvapour S2425 Avoid contact with skin and eyes S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)




Hazard statement(s) and Precautionary statement(s)

H303 May be harmful if swallowed H315 Causes skin irritation H317 May cause an allergic skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer P202 Do not handle until all safety precautions have been read and understood P280 Wear protective glovesprotective clothingeye protectionface protection P30t+ P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P308 + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator

Training advice None

Additional Information None

Information contained in this publication or as otherwise supplied to Users is believed to be accurate and is given in good faith but it is for the Users to satisfy themselves of the suitability of the product for their own particular purpose Epoxy Technology Inc gives no warranty as to the fitness of the product for any particular purpose and any implied warranty or condition (statutory or otherwise) is excluded except to the extent that exclusion is prevented by law Epoxy Technology Inc accepts no liability for loss or damage (other than that arising from death or personal injury caused by defective product if proved) resulting from reliance on this information Freedom under Patents Copyright and Designs cannot be assumed




11 Product identifier EPO-TEK 353ND Part B GHS Product Identifier EPO-TEK 353ND Part B Chemical Name Not applicable Trade name EPO-TEK 353ND Part B EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available



14 Emergency telephone number - Chemtel Inc Emergency Phone No (800) 255-3924 (813) 248-0585


21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 4 Skin Corrosion 2 Eye Damage 1 (314322

331 383) 212 Directive 67548EEC amp Directive 199945EC - CORROSIVE HARMFUL 22 Label elements 221 Label elements According to Regulation (EC) No 127212008 (CLP)


~i~~~~am(s) Hazard statement(s)

Precautionary statement(s)

222 Label elements

Hazard Symbol

Risk Phrases

Safety Phrases

ltgt~~ Signal word(s) DANGER

H302 Harmful if swallowed H314 Causes severe skin bums and eye damage H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child P280 Wear protective glovesprotective clothingeye protectionlface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemovelTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinSing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator

According to OirtivA 67A54l1fEEC amp Directive 19991451EC

R22 Harmful if swallowed R34 Causes burns R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) S56 Dispose of this material and its container to hazardous or special waste collection


~--------~----~--- -~ - ---shy

Revision 1102CLP MATERIAL SAF5TY DATA SHEET Date 30 August 2012

EPO-TEK 353ND Part B

point

23 Other hazards GHS Classification (USA) Hazardous under OSHA Hazard Communication Standard - Corrosive (EyesSkin) Reproductive Harm HMIS Health-2 Flammability-1 Reactivity-1

WHMIS Classification (Canada) Hazardous under WHMIS (f)sectClass D2B - Material Causing Other Toxic Effects (Irritation) itT Class D2A - Material Causing Other Toxic Effects (Corrosive Irritation Reproductive Harm) Class E - Corrosive Material


SECTION 3 COMPOSITIONIINFORMATION ON INGREDIENTS

EC Classification No 1272200BEC I iHazardous ingredient(s)

I

WIW CAS No ECNo REACH

Registration No

Hazard pictogram(s) and Hazard statement(s)

Imidazole Blend 50-80 Proprietary Proprietary NA ~lttgt 314 3212 331 383 H302 H315

H318 H335

Imidazole 25-50 288-32-4 206-019-2 NA ~~lttgt 314 3211 B

3313711 B H302 H314 H361D

EC Classification No 6754BEEC

ingredient(s) WIW CAS No ECNo REACH

Registration No

Hazard pictogram(s) and Risk (R) Phras(es)

Imidazole Blend 50-80 j Proprietary Proprietary NA Xi R22 R371 R38 R41

Imidazole 25-50 288-32-4 206-019-2 NA C Xn R22 R34 R63

33 Additionallnfonnation - For full text of H phrases see section 16 For full text of R phrases see section 16 Non-Hazardous ingredients are not listed and make up the balance of the product


41 Description of first aid measures

Inhalation

Skin Contact

Eye Contact

Ingestion

42 Most important symptoms and

May cause irritation to the respiratory system Remove patient from exposure Keep patient at rest and give oxygen if breathing is difficult If symptoms develop obtain medical attention

Causes burns Remove contaminated clothing immediately and drench affected skin with plenty of water then wash with soap and water If irritation (redness rash blistering) develops get medical attention

May cause corneal injury May cause corneal damage Remove any contact lenses Irrigate with eyewash solution or clean water holding the eyelids apart for at least 15 minutes Obtain immediate medical attention

Ingestion will cause irritation of the gastrointestinal tract If swallowed seek medical advice immediately and show this container or label Do not induce vomiting Make victim drink plenty of water Get immediate medical attention

Acute Causes burns to skin and eyes Causes serious eye irritation Causes skin irritation Ingestion will cause irritation of the gastrOintestinal tract


Revision 1102CLP MATERIAL SAFETY DATA SHEET Date 30 August 2012


43

effects both acute and delayed

Indication of the immediate medical attention and special treatment needed

Delayed and chronic effects May cause comeal damage




51 Extinguishing media Suitable Extinguishing Extinguish preferably with dry chemical foam or water spray Media Unsuitable Extinguishing None known Media

52 Special hazards arising Combustion causes toxic fumes A self contained breathing apparatus and from the substance or suitable protective clothing should be worn in fire conditions mixture

53 Advice for fire-fighters Extinguish preferably with dry chemical foam or water spray Launder contaminated protective devices


61 Personal precautions Ensure full personal protection (including respiratory protection) during protective equipment and removal of spillages Avoid breathing fumes Evacuate if necessary emergency procedures

62 Environmental Precautions Ventilation recommended Avoid release to the environment 63 Methods and material for

containment and cleaning up Transfer to a lidded container for disposal or recovery Consult an accredited waste disposal contractor or the local authority for advice

64 Reference to other sections See Also Section 7 8 13 65 Additional Information None



72 Conditions for safe storage including any incompatibilities

Storage Temperature Storage Life Incompatible materials


Avoid ingestion Use only in well-ventilated areas Avoid inhalation of high concentrations of vapors Keep away from oxidizing agents Keep away from fire sparks and heated surfaces - no smoking

Protect from sunlight Store in a well-ventilated place Do not use or store near heat or open flame Do not store and transport with oxidizers etc

Ambient Not available Oxidizing agents Can react violently if in contact with acids alkalis reducing agents and heavy metals






Revision 1102CLP MATERIAL SAFIiTY DATA SHEET Date 30 August 2012


SUBSTANCE I

CAS No i LTEL (8 hrTWA I LTEL (8 hrTWA STEL ppm) mgm) (ppm)

STEL (mgm3) Note

No occupational exposure limits for this product or listed components have been established

OEls are not available for non-listed components


Limit value type (country of origin) SUBSTANCE CAS No Biological limit

value Note


813 PNECs and DNELs


Industry - Long Term - Local effects NA NA NA

i Industry - Long Term - Systemic effects NA NA NA


Industry - Short term Systemic effects NA NA NA

i Professional - Long Term - Local effects NA NA NA

I Professional- Long Term - Systemic effects NA NA NA

I Professional Short term - Local effects NA NA NA

Professional- Short term - Systemic effects NA NA NA

I Consumer - Long Term - Local effects NA NA NA

Consumer Long Term Systemic effects NA NA NA



PNEC


Terrestrial Compartment Not available

Atmospheric Compartment Not available


0 Respirators Wear suitable respiratory protective equipment if exposure to levels above the occupational exposure limit is likely

Eye Safety glasses


Body Wear suitable protective clothing and gloves protection

Engineering Controls

Protection


C


EPamiddotTEK 353ND Part B

Other Remove contaminated saturated clothing immediately Contaminated clothing should be thoroughly cleaned


91 Information on basic physical and chemical properties Appearance Liquid Color Amber Odor Mild I Slight Odor Threshold ppm Not available Melting Point CC) I Not available Boiling pointboiling range (0G) Not availableFreezing Point (OC) Flash Point (0G) gt 200F I 93C Explosive limit ranges Not available Auto Ignition Not available Decomposition Temperature (0G) Not availableTemperature CC) Explosive properties Not available Oxidizing properties Not available Flammability (solid Not available pH (Value) gt 10gas) EVaporation rate lt Butyl Acetate Vapor Pressure (mm Hg) Not available Vapor Density (Air=1) gt1 Density (gml) 102 Solubility (Water) Partially soluble Solubility (Other) Not available Partition CoeffiCient (n- Not available Viscosity (mPas) Not availableOctanollwater)



101 Reactivity

102 Chemical stability

103 Possibility of hazardous reactions

104 Conditions to avoid

105 Incompatible materials

106 Hazardous Decomposition Product(s)

Slight

Stable under normal conditions

Can react violently if in contact with - Oxidizing agents Can react violently if in contact with acids alkalis and reducing agents

Heat and direct sunlight Avoid contact with heat and ignition sources Bleaching products and comparable oxidizers Can react violently if in contact with acids alkalis and reducing agents

Carbon monoxide Carbon dioxide Nitrogen oxides Hydrogen cyanide Thermal decomposition will evolve toxic irritant and flammable vapors

c-middot SECTION 11 TOXICOLOGICAL INFORMATION

I I LD50 I LC50 LD50 Ir----S_U--B-S~T_A-_N_C_E__--+--c-C_A_S--N_O_middot---r-i---(1IOra=IcR=a=tL--)-+_ l(I=n=ha=l=atio-n-c~R=at2t)-+~ (Dermal Rat) I Imidazole Blend Proprietary I Not established I Not established Not established I -1_lm~id_a-zole______ -_2_88_middot3-2-4_-I__2_2_0_m_~L-I----N_ot es--tab_li_sh_e-d____N_ot_esta_b_lis-h_e_d--l1

111 Information on toxicological effects

1112 Mixtures Acute toxicity Harmful if swallowed Ingestion may cause irritation of the

gastrOintestinal tract

Irritation May cause bums to skin and eyes

Corrosivity May cause burns to skin and eyes

Repeated dose toxicity Expected to be similar to single exposures

Carcinogenicity No data

EPOXYTECHNOIDGY Page 59 Expiration Date 30 August 2014


EPO-TEK 353NO Part B

Mutagenicity No data

Toxicity for reproduction Suspected of damaging fertility or the unborn child

112 Other information None

SECTION 12 ECOLOGICAL INFORMATION


122 Persistence and degradability Moderatelypartially biodegradable

123 Bioaccumulative potential Moderatelypartially biodegradable

124 Mobility in soil The product has moderate mobility in soil







Land transport (AORlRIO) (c) (d) Land transport (Within USA) (c)(d) UN number 3267 UN number 3267

Corrosive Liquid basic Corrosive Liquid basic organic Proper Shipping Name Proper Shipping Name

organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Hazard label(s) CORROSIVE Hazard label(s) CORROSIVE Environmental hazards None Environmental hazards None Special precautions for user None Special precautions for user None

Sea transport (IMOG) (c)(d) Air transport (ICAOIATA) (c) (d) UN number 3267 UN number 3267

Corrosive Liquid basic Corrosive Liquid basic organiC Proper Shipping Name Proper Shipping Name

organic nos (Imidazole) noS (Imidazole) Transport hazard class(es) 8 Transport hazard class(es) 8 Packing Group III Packing Group III Marine Pollutant None Environmental hazards None Special precautions for user None Special precautions for user None

(c)- Consult with transPort provider (d)- Check relevant regulations for Special Provisions

Transport in bulk according to Annex II of MARPOL7378 and the IBC Code


151

1511


Authorisations andor restrictions on use





European Union (EINECSELINCS) All chemicals listed

German WGK number 2

1512 National regulations

USA

TSCA (Toxic Substance Control Act) All chemicals listed

SARA 3111312 - Hazard Categories Acute Health

SARA 302 - Extremely Hazardous Listed - None Substances SARA 313 - Toxic Chemicals Listed - None

CERCLA (Comprehensive Listed - None Environmental Response Compensation and Liability Act) CM (Clean Air Act 1990) Listed - None

CWA (Clean Water Act) Listed - None

State Right to Know Lists Listed as required

Proposition 65 (California) - This product contains the following substances) known to the state of California to cause cancer andor reproductive harm Acrylonitrile CAS 107-13-1 lt005

Canada

WHMIS Classification Class D Division 2 Subdivision B Material Causing Other Toxic Effects (Irritation) Class D Division 2 Subdivision A Material Causing Other Toxic Effect (Corrosive Irritation Reproductive Harm) Class E Corrosive Material

Canada (DSUNDSL) Listed - DSL

Canada Ingredient Disclosure List (CIDL) Listed as required

Japan

Deleterious Substance Law Regulated

152 Chemical Safety Assessment Harmful Corrosive (Skin Eye) Irritant (Respiratory system) Reproductive Toxicity

153 Label elements (EU)

Label as Corrosive Harmful Human Health under 12722008EC and 19972006EC and Harmful Corrosive under 199945EC See Section 2 for full label requirements

Page 79 E)(piration Date 30 August 2014

------------------ ~~~~ --------------- --- _--shy~ ---~-


EPO-TEK 353N D Part B


The following sections contain revisions or new statements 116

LEGEND ACGIH American Conference of Governrnentallndustrial NA not applicable not available

Hygienists AICS Australian Inventory of Chemical Substances NIOSH National Institute for Occupational Safety and

Health ANSI American National Standards Institute ND not determined atm atmosphere (pressure unit) NFPA National Fire Prevention Association BOD biological oxygen demand NTP National Toxicology Program CAS Chemical Abstracts Service OC open cup CC closed cup OSHA Occupational Safety and Health Administration CDTA Chemical Drug and Trafficking Act Part partition COC Cleveland Open Cup PEL permissible exposure limits COD chemical oxygen demand ppb parts per billion coeff coefficient PPE personal protective ~uipment CFR Code of Federal Regulations ppm parts per million CPR cardio-pulmonary resuscitation psi pounds per square inch DEA Drug Enforcement Agency RCRA Resource Conservation and Recovery Act DOT Department of Transportation RQ Reportable quantity DSCL Dangerous Substances Classification and Labeling RTK Right to Know EEC European Economic Community SARA Superfund Amendments and Reauthorization Act FDA Food and Drug Administration STEL short-term exposure limit HMIS Hazardous Materials Information System SUSDP Standard for the Uniform Scheduling of Drugs and

Poisons (Australia) IARC International Agency for Research on Cancer TCC Tagliabue Closed Cup IDLH immediate danger to life or health TOG Transportation of Dangerous Goods kg kilogram TPQ threshold planning quantity L liter TQ threshold quantity LC50 median lethal concentration TSCA Toxic Substances Control Act LD50 median lethal dose TWA time-weighted average LEL lower explosive limit UEL upper explosive limit mg milligram WES Workplace Exposure Standard (New Zealand)


References RTECS CA9 Registry EINECSESIS Casarett amp Doulls Toxicology Goldfrankss Toxicological Emergencies Manufacturer Information

Risk Phrases and Safety Phrases R22 Harmful if swallowed R34 Causes burns R3738 Irritating to respiratory system and skin R41 Risk of serious damage to eyes R63 Possible risk of harm to the unborn child S2 Keep out of the reach of children S26 In case of contact with eyes rinse immediately with plenty of water and seek medical advice S28 After contact with skin wash immediately with plenty of soap and water S3639 Wear suitable protective clothing and eyeface protection S45 In case of accident or if you feel unwell seek medical advice immediately (show the label wherePQssible) S56 Dispose of this material and its container to hazardous or special waste collection point

Hazard statement(s) and Precautionary statement(s) H302 Harmful if swallowed H314 Causes severe skin burns and eye damage H315 Causes skin irritation H318 Causes serious eye damage H335 May cause respiratory irritation H361 D Suspected of damaging fertility or the unborn child


Revision 1102CLP MATERIALSAFETY DATA SHEET Date 30 August 2012


P280 Wear protective glovesprotective clothingeye protectionface protection P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P301 + P310 IF SWALLOWED Immediately call a POISON CENTER or doctorphysician P303 + P361 + P353 IF ON SKIN (or hair) RemoveTake off immediately all contaminated clothing Rinse skin with watershower P305 + P351 + P338 IF IN EYES Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P305 IF IN EYES Get immediate medical attention P501 Dispose of contentscontainer to Send to a licensed recycler reclaimer or incinerator




EPOXY Page 99 Expiration Date 30 August 2014 TECHNOLClGY



11 Product identifier EPO-TEK 353ND Part A GHS Product Identifier EPO-TEK 353ND Part A Chemical Name Not applicable Trade name EPO-TEK 353ND Part A EPOXYCAS No Mixture EINECS No Mixture TECHNOLOGY REACH Registration No Not available



14 Emergency telephone number - Chemtellnc Emergency Phone No (800) 255--3924 (813) 248-0585


21 Classification of the substance or mixture 211 Regulation (EC) No 127212008 (CLP) - Acute toxicity 5 Skin irritation 2 Eye Damage 3 Skin Sensitizer 1 (3115

322 332 341 ) 212 Directive 67548EEC amp Directive 199945EC - HARMFUL IRRITANT 22 Label elements 221 Label elements According to Regulation (Ee) No 127212008 (CLP)


Hazard lttgt~ Signal word(s) WARNINGpictogram(s)

Hazard H303 May be harmful if swallowed statement(s) H315 Causes skin irritation

H317 May cause an allergiC skin reaction H319 Causes serious eye irritation H411 Toxic to aquatic life with long lasting effects EUH205 Contains epoxy constituents See information supplied by the manufacturer

Precautionary P202 Do not handle until all safety precautions have been read and understood statement( s) P2S0 Wear protective glovesprotective clothingeye protectionface protection

P301 + P330 + P331 IF SWALLOWED rinse mouth Do NOT induce vomiting P302 + P352 IF ON SKIN Wash with plenty of soap and water P305 + P351 + P33S IF IN EYE8 Rinse cautiously with water for several minutes Remove contact lenses if present and easy to do Continue rinsing P30S + P313 If exposed or concerned Get medical adviceattention P501 Dispose of contentscontainer to 8end to a licensed recycler reclaimer or incinerator

222 Label elements Uf)4UrtlL amp Directive 19991451EC

Hazard Symbol

Risk Phrases R22 Harmful if swallowed R363S Irritating to eyes and skin R43 May cause sensitization by skin contact R51 Toxic to aquatic organisms

Safety Phrases 82 Keep out of the reach of children 823 Do not breathe fumeslvapour 82425 Avoid contact with skin and eyes 826 In case of contact with eyes rinse immediately with plenty of water and seek medical advice 83639 Wear suitable protective clothing and eyeface protection 845 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)


23

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Page 59


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151

1511

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152

153




USA








Canada


Canada (DSLINDSL)



Label elements (EU)


Acute Health

Listed - None

Contains None

Listed - None

Listed - None

Listed - None


Listed - None



Listed as required








LEGEND





























222 Label elements

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151

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23

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Page 59


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151

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151

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Page 59


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151

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153




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Contains None

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Listed - None


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151

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9


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151

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153




USA








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Page 59


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9 Expiration Date 30 August 2014 EPOXY TECHNOUXW




151

1511

1512

152

153




USA








Canada


Canada (DSLINDSL)



Label elements (EU)


Acute Health

Listed - None

Contains None

Listed - None

Listed - None

Listed - None


Listed - None



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LEGEND





























222 Label elements

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151

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151

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153




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151

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151

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151

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151

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151

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151

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------------------ ~~~~ --------------- --- _--shy~ ---~-





















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