enclosure: 1environmentclearance.nic.in/writereaddata/online/tor/12...14 aniline liquid drum ms 14.4...

Enclosure: 1 Product Detail

Sr. No. Products Quantity (MT/Month)

Existing Proposed Total

1

a. 2 Ethyl Pyridone (Carbamyal 2 pyridone) 7 93

100

b. Cyano 2 pyaridone

-- 100

c. sulpho 2 pyaridone d. Napthol As e. Napthol ASBS f. Napthol ASD g. Napthol ASE h. Napthol ASOL i. Napthol ASBO j. M.U.A

2 Magnesium Sulphate 100 200 300

3

a. M.N.A -- 20 20 OR b. Dispersing agent phenol base – liquid,

Dispersing agent phenol base – solid, Dispersing agent Napthlene base – liquid, Dispersing agent Napthlene base – solid

-- 200 200

By products : 1 Dilute spent acid H2SO4 (45%) -- 575 575

Enclosure: 2 Packing & Final Use of Product

Sr. No. Product Type of Packing Final Application of Product

1 2 Ethyl Pyridone (Carbamyal 2 pyridone) Bag Manufacturing of dyes

2 Cyano 2 pyaridone Bag Manufacturing of dyes 3 sulpho 2 pyaridone Bag Manufacturing of dyes

4 Napthol As Bag

For dyeing & printing as well as Manufacturing of pigment

5 Napthol ASBS Bag


6 Napthol ASD Bag


7 Napthol ASE Bag


8 Napthol ASOL Bag


9 Napthol ASBO Bag


10 M.U.A Bag


11 Magnesium Sulphate Bag For dyeing & printing as well as Manufacturing of

pigment

12 M.N.A Bag


13 Dispersing agent phenol base – liquid Drum Manufacturing of dyes 14 Dispersing agent phenol base – solid Bag Manufacturing of dyes

15 Dispersing agent Napthlene base – liquid Drum Manufacturing of dyes

16 Dispersing agent Napthlene base - solid Bag Manufacturing of dyes

Enclosure: 3 Detail of Raw Material with his Quantity

Sr. No. Name of product Capacity

MT/Month Name of Raw

Material Raw Material Consumption

MT /MT MT/ Month

1

2 Ethyl Pyridone (Carbamyal 2 pyridone)

100

Cyano 2 Pyridone 0.956 95.6 Sulphuric Acid 2.623 262.3

Cyano 2 pyaridone MCA 0.727 72.7 MEA 0.636 63.6 MAA 0.909 90.9

Sulpho 2 pyaridone

Sodium Bi Sulphite 0.385 38.5 Formaldehyde 0.111 11.1 Carbamyal 2 Pyrodine 0.725 72.5

Caustic 0.324 32.4 Salt 0.139 13.9 Spent Sulphuric Acid (45%) 0.648 64.8

Napthol As

BON Acid 0.750 75 Toluene 4.329 432.9 Caustic flakes 0.159 15.9 PCl3 0.216 21.6 Aniline 0.361 36.1 Soda Ash 0.027 2.7

Napthol ASBS

BON Acid 0.649 64.9 Toluene 3.745 374.5 Caustic flakes 0.137 13.7 PCl3 0.187 18.7 Meta nitro Aniline 0.400 40 Soda Ash 0.074 7.4

Napthol ASD

BON Acid 0.694 69.4 o-Toluene 4.004 400.4 Caustic flakes 0.141 14.1 PCl3 0.200 20 Meta nitro Aniline 0.380 38 Soda Ash 0.024 2.4

Napthol ASE

BON Acid 0.667 66.7 Toluene 3.846 384.6

Caustic flakes 0.137 13.7 PCl3 0.192 19.2 P Chloro Aniline 0.436 43.6 Soda Ash 0.024 2.4

Napthol ASOL

BON Acid 0.591 59.1 Toluene 3.546 354.6 Caustic flakes 0.118 11.8 PCl3 0.177 17.7 O-Anisidine 0.402 40.2 Soda Ash 0.022 2.2

Napthol ASBO

BON Acid 0.658 65.8 Toluene 3.871 387.1 Caustic flakes 0.142 14.2 PCl3 0.193 19.3 Meta Nitro Aniline 0.412 41.2 Soda Ash 0.023 2.3

M.U.A MPD 0.497 49.7 HCl 1.163 116.3 Sodium Cynate 0.327 32.7

2 Magnesium Sulphate 300

Mgo 0.272 81.6 Sulphuric acid (98%) 0.670 201

Spent Sulphuric Acid 2.516 754.8

3

a. M.N.A 20 MDNB 1.250 250 NaHS 2.375 475

b.

Dispersing agent phenol base – liquid

200

Sulphuric Acid (98%) 0.139 27.8

Phenol 0.178 35.6 Formaldehyde 0.217 43.4 EDTA 0.008 1.6 Caustic soda lye 0.155 31

Dispersing agent phenol base – solid

Phenol based dispersing agent(Liquid)

2.227 445.4

Dispersing agent Napthlene base – liquid

Oleum (23%) 0.144 28.8 Sulphuric Acid(98%) 0.052 10.4

Napthalene 0.196 39.2

Formaldehyde 0.118 23.6 Caustic lye 0.196 39.2

Dispersing agent napthlene base - solid

Naphthalene based dispersing agent(Liquid)

2.380 476

Overall List of Raw Material

Sr. No. Raw material Chemical Name CAS No. MT/Month

Existing Proposed Total 1 Cyano 2 Pyridone Cyano 2 Pyridone 28141-13-1 6.692 88.91 95.6 2 Sulphuric Acid Sulphuric Acid 7664-93-9 23.051 253.149 276.2 3 MCA Methyl Cyno Acetate 105-34-0 0 72.7 72.7 4 MEA Mono Ethyl Amine 75-04-7 0 63.6 63.6

5 MAA Methyl Aceto Acetate 105-45-3 0 90.9 90.9

6 Sodium Bi Sulphite Sodium Bi Sulphite 7631-90-5 0 38.5 38.5 7 Formaldehyde Formaldehyde 50-00-0 0 32.8 32.8

8 Carbamyal 2 Pyrodine

Carbamyal 2 Pyrodine 1121-60-4 0 72.5 72.5

9 Caustic flask Sodium Hydroxide 1310-73-2 0 48.3 48.3 10 Salt Sodium Chloride 7647-14-5 0 13.9 13.9 11 BON Acid B-Oxy napthaoic Acid 92-70-6 0 75 75 12 Toluene Toluene 108-88-3 0 432.9 432.9

13 PCl3 Phosphorous Tri Chloride 7719-12-2 0 21.6 21.6

14 Aniline Aniline 62-53-3 0 36.1 36.1 15 Soda Ash Sodium Carbonate 497-19-8 0 7.4 7.4 16 o- Anisidine o- Anisidine 90-04-0 0 41.23 41.23 17 o- Tolune o- Tolune 108-88-3 0 38.4 38.4 18 Meta nitro Aniline Meta nitro Aniline 100-01-6 0 41.2 41.2 19 Alfa Napthyl Amine Alfa Napthyl Amine 86-56-6 0 40.2 40.2 20 MPD m-Phenylenediamine 108-45-2 0 49.7 49.7

21 HCl Hydro Chloric Acid 7647-01-0 7732-18-5 0 116.3 116.3

22 Sodium Cynate Sodium Cynate 917-61-3 0 32.7 32.7 23 Mgo Magnesium Oxide 1309-48-4 1.904 79.67 81.6 24 MDNB 0 250 250

25 NaHS Sodium Hydro Sulphide 7775-14-6 0 475 475

26 Phenol Phenol 108-95-2 0 35.6 35.6 27 EDTA Ehylene dyamine 60-00-4 0 1.6 1.6

tetra acetic acid 28 P Chloro Aniline P Chloro Aniline 106-47-8 0 43.6 43.6

29 Oleum (23%) Fuming Sulphuric Acid

7664-93-9 7446-11-9 0 28.8 28.8

30 Napthalene Napthalene 91-20-3 0 39.2 39.2

Enclosure: 4 Chemical Name & Physical form of raw material with his storage facility

Sr. No. Raw Material Physical form Type of Packing MOC Max. at a time

storage capacity MT 1 Cyano 2 Pyridone Solid Bag HDPE bag with liner 150 2 Sulphuric Acid Liquid Storage Tank MS 51.9 3 MCA Liquid Storage Tank MS 13.3 4 MEA Liquid Drum HDPE 8.6 5 MAA Liquid Drum MS 15.8 6 Sodium Bi Sulphite Solid Bag HDPE bag with liner 60 7 Formaldehyde Liquid Storage Tank HDPE 80 8 Carbamyal 2 Pyrodine Solid Bag HDPE bag with liner 150 9 Caustic flask Solid Bags HDPE bag with liner 6.3

10 Salt Solid Bag HDPE bag with liner 50 11 BON Acid Solid Bags HDPE bag with liner 30.0 12 Toluene Liquid Storage Tank MS 6.04 13 PCl3 Liquid Drum/ Storage Tank MS 8.64 14 Aniline Liquid Drum MS 14.4 15 Soda Ash Solid Bags HDPE bag with liner 1.04 16 o- Anisidine Liquid Drum MS 16.4 17 o- Tolune Liquid Drum MS 15.20 18 Meta nitro Aniline Solid Bags HDPE bag with liner 15.9 19 Alfa Napthyl Amine Solid Bag HDPE bag with liner 7.7 20 MPD Solid Drum MS 0.99 21 HCl Liquid Tank/drum HDPE 2.3 22 Sodium Cynate Solid Bag HDPE bag with liner 0.65 23 Mgo Solid Bag HDPE bag with liner 100 24 MDNB Solid Bag HDPE bag with liner 6.0

25 NaHS Solid Bag HDPE bag with liner 11.8 26 Phenol Liquid Storage Tank MS 17.8 27 EDTA Solid Bag HDPE bag with liner 0.7 28 P Chloro Aniline Solid Bag HDPE bag with liner 17.4 29 Oleum (23%) Liquid Storage Tank MS 72 30 Napthalene Solid Bag HDPE bag with liner 98

Enclosure: 5 Property of Raw Material

Sr. No

Product

Physical & Chemical Composition B.P. F.P. LEL

TLV LD50

mg/kg Sp.Gr.

(Water=1)at

V.D. at

(air=1)

Odor Threshold Solubility in

Water Chemical Formula State MW oC oC % ppm or

mg/nm3 ppm,

mg/Nm3

1 Sulphuric Acid H2SO4 Liquid 98.08 270 NA NA 3 320 1.84 3.4 NA Soluble

2 MCA C4H5NO2 99.09 204 NA NA NA NA NS NA NA Soluble

3 Sodium Bi Sulphite NaHSO3 Solid 104.7 NA NA NA 5 2000 1.48 NA NA Soluble

4 Formaldehyde HCHO Liquid 30.02 98 50 6 0.37 5628 1.08 1.03 NA Soluble

5 Caustic flask NAOH Liquid 40 1390 NA NA 2 NA 2.12 NA NA Soluble

6 Salt NaCl Solid 58.44 1413 NA NA NA 3000 2.165 NA NA Soluble

7 Toluene C6-H5-CH3 Liquid 92.14 110.6 16 1.1 50 14100 0.8636 3.1 1.6 Soluble

8 Aniline C6H5NH2 Liquid 93.13 184.1 70 1.3 7.6 820 1.0216 3.22 2.4 Soluble

9 Soda Ash Na2CO3 Solid 106 NA NA NA NA 4090 2.532 NA NA Soluble

10 HCl HCl Liquid 36 127 NA NA 7 900 1.19 1.267 0.25-10 Completely Soluble

11 Sodium Cynate CNNaO Powder 65.01 NA NA NA 1500 1.89 NA NA NA Soluble

12 Oleum (23%) H2SO4 + 20% SO3 Liquid 178.14 254.47 NA NA NA 2140 1.92 3.4 NA Soluble

13 Napthalene C10H8 Solid 128.19 218 88 0.9 15 305.2 1.162 4.4 0.038 Soluble

Enclosure: 6 Detail of Hazardous Chemicals

The Raw materials, which are termed as hazardous Chemicals as per the “Manufacturing, Storage and Import of Hazardous Chemicals (MSIHC) Rules, 1989” are as listed below Table

Sr. No.

Name of Hazardous chemicals

Reference in MSIHC Threshold

Quantity (MT) Maximum

Storage Capacity (MT) Sc-2 Sc-3

1 Aniline Sr. No. 37 (Sch-1 of MSIHC, 1989) -- -- 14.4 2 Formaldehyde Sr. No. 285 (Sch-1 of MSIHC, 1989) -- 50 80 3 HCL Sr. No. 313 (Sch-1 of MSIHC, 1989) 25 25 2.3 4 Naphthalene Sr. No. 417 (Sch-1 of MSIHC, 1989) -- -- 98 5 o-toludine Sr. No. 441 (Sch-1 of MSIHC, 1989) -- -- 15.20

6 Phosphorous Tri Chloride Sr. No. 506 (Sch-1 of MSIHC, 1989) -- -- 8.64

7 Caustic Soda (Sodium Hydroxide)

Sr. No. 571 (Sch-1 of MSIHC, 1989) -- -- 6.3

8 Sulphuric acid Sr. No. 591 (Sch-1 of MSIHC, 1989) -- -- 51.9 9 Toluene Sr. No. 628 (Sch-1 of MSIHC, 1989) -- -- 6.04

Enclosure: 7 Manufacturing Process and Chemical Reaction and Mass Balance

1. 2 Ethyl Pyridone:

Cyano 2 pyridone & sulphuric acid are taken in reactor. Then mass is drown in water & filter nutch. Filtrate is collected as spent acid which is either use for manufacturing of magnesium sulphate, sulpho 2 pyridone or sell to actual user.

2. Cyano 2 pyridone:

MEA, MCA & MAA are taken in a reactor for condensation. After that; distillation is carried out. During distillation mixture of methanol & water are generated, which will be used as fuel in boiler. Reactor mass is dried and packed as final product.

3. Sulpho 2 Pyridone:

In vessel-1 carbamoly 2 pyridone solution is prepared by taking water, carbamoly 2 pyridone & caustic solution. Meanwhile Water, Sodium bi sulphite & formaldehyde are taken in vessel-2. After that carbamoly 2 pyridone solution & salt are added to vessel-2. Further the mass is reacting with spent acid. Then mass is drown in water& filter nutch. Filtrate is sent to ETP. Wet cake is packed as final product.

4. Magnesium sulphate:

Magnesium oxide is taken into reactor. Add spent acid and sulphuric acid. The mass is then filtred in filter press. Wet cake is collected and sends to TSDF. Filtrate is crystallized in a crystallizer. Crystals are filter in a filter nutch. Filtrate is collected and recycles in the next batch. Crystals are packed as final product. Chemical Reaction:

MgO + H2SO4 + H2O MgSO4.7H2O

Chemical reaction:

OH

COOH BON Acid

ONa

COOH

Sodium Salt of Bon Acid

+ H2O + NaOH

ONa

COOH


+ PCI3 + 3 H2N—

3

OH

C—NH—

Naphthol AS

3 + 3NaCI + H3PO3

O

5. Naphthol AS:

BON Acid, caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, aniline, water & soda ash. Toluene is distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

Chemical reaction:

O

OH

COOH BON Acid

ONa

COOH


+ H2O + NaOH

ONa

COOH


+ PCI3 + 3 H2N—

3

OH

C—NH—

Naphthol ASBS

3 + 3NaCI + H3PO3

NO2

NO2

m-Nitro aniline

6. Napthol ASBS:

BON Acid, Caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, Meta Nitro aniline, water & soda ash. Toluene is distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

Chemical reaction:

O

OH

COOH BON Acid

ONa

COOH


+ H2O + NaOH

ONa

COOH


+ PCI3 + 3 H2N—

3

OH

C—NH—

Naphthol ASD

3 + 3NaCI + H3PO3

o-Toluidine

H2C

H3C

7. Naphthol ASD :

BON Acid, Caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, O-toludine, water & soda ash. Toluene is distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

Chemical reaction:

O

OH

COOH BON Acid

ONa

COOH


+ H2O + NaOH

ONa

COOH


+ PCI3 + 3 H2N—

3

OH

C—NH—

Naphthol ASE

3 + 3NaCI + H3PO3

P-Chloro aniline

CI

CI

8. Naphthol ASE:

BON Acid, Caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, P-chloro aniline, water & soda ash. Toluene is distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

Chemical reaction:

O

OH

COOH BON Acid

ONa

COOH


+ H2O + NaOH

ONa

COOH


3

OH

C—NH—

Naphthol ASBO

3 + 3NaCI + H3PO3

AlfaNaphthly amine

+ PCI3 + 3

NH2

9. Naphthol ASBO:

BON Acid, Caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, Alpha Napthyl amine, water & soda ash. Toluene is distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

Chemical reaction:

O

OH

COOH BON Acid

ONa

COOH


+ H2O + NaOH

ONa

COOH


+ PCI3 + 3 H2N—

3

OH

C—NH—

Naphthol ASOL

3 + 3NaCI + H3PO3

o-Anisidine

H3CO

H3CO

10. Naphthol ASOL:

BON Acid, Caustic flakes & toluene are taken into reactor for dehydration. Water is removed and taken to ETP. Then mass is further taken for Naphthol formulation. Add PCI3, O-Anisidine, water & soda ash. Toluene is6 distilled & recycled. During reaction HCI gas is generated which is scrubbed in alkali scrubber & effluent is taken to ETP. Wet cake is dried in dryer & packed as final product.

11. Meta Nitro Aniline:

MDNB is reduced with sodium hydro sulphite, add water, then filtered the mass. Filtrate is taken to ETP. Wet cake washed with water. Wash water is taken to ETP. Wet cake dried & packed as a finished product.

12. Meta Urido Aniline: MPD, Hydro chloric acid & sodium cyanate are taken into reactor. Add water inti it. Mass is then filtered. Filtrate is taken to ETP. Wet cake is packed as final product.

13. Dispersing Agent based on phenol (liquid):

Phenol is first reacted with sulphuric acid in a sulphonator rector. This is condensed with formaldehyde & water, mass solution is filled directly in drums as a final product. In this process there is no filtration or washing hence no generation of any process effluent.

14. Dispersing Agent based on phenol (Solid) : Dispersing agent based on phenol liquid mass is spray dried in spray dryer. Finally dry powder is packed as a final product. There is no generation of any process effluent.

15. Dispersing Agent based on Naphthalene (liquid):

Naphthalene is first reacted with oleum & sulphuric acid in a sulphonator reactor. This is condensed with formaldehyde & water. After completion of reaction mass is neutralized with caustic lye & add water. Finally the liquid mass solution is filled directly in drums as a final product. In this process there is no filtration or washing hence no generation of any process effluent.

16. Dispersing Agent based on Naphthalene (Solid): Dispersing agent based on naphthalene liquid mass is spray dried in spray dryer. Finally dry powder is packed as a final product. There is no generation of any effluent.

Drawning

Filter

Draying

Reaction

Spent acid (45%): 5639 Kg

Use for production of sulpho 2 pyridone & magnesium sulphate or sell to actual users

Water: 3060 kg

Cyano 2 pyridone : 956 kg

Sulphuric acid: 2623 kg

2 Ethyl Pyridine: 1000 kg

Mass Balance of the Products

1. 2 Ethyl Pyridone:

Distillation

Drying

Cyano2-pyridone: 1000 kg

Condensation

Distillate: methanol & water mixture: 1227 kg

Used as fuel in boiler

MCA: 727 kg

MEA: 636 kg

MAA: 909 Kg

Vapors loss 45 Kg

2. Cyano 2 pyridone:

Addition

Addition

Filter

Addition

Sulpho 2 pyridone: 1000 kg

Effluent: 3795 kg

Salt: 139 Kg

Spent sulphuric acid: 648 Kg

Water :417 kg

Pyridine Solution

Water: 185 kg

Caramyal 2 pyridone : 725 kg

Caustic : 324 kg

Water: 1861 kg

Sodium bi sulphite : 385 kg

Formaldehyde : 111 Kg

3. Sulpho 2 Pyridone:

Reactor: 119360

Product (MgSO4): 1000 kg

Filtration in Filer Press

Mgo: 272 Kg Sulfuric Acid (98%): 67000 Kg

Spent H2SO4: 25160 Kg

Filtrate: 115860

Crystallization

Crystal: 110000

Centrifuge: 110000

Filter in Filter Nutch Filtrate: 58

Filtrate: 2365 kg

Wet Cake: 35

TSDF

4. Magnesium sulphate:

WET CAKE

DRYING

Effluent to ETP: 2649 kg

NAPHTHOL

FORMATION

PCI3 : 216 kg Aniline : 361 kg

Soda ash : 27 kg Water : 2597 kg

DEHYDRATION BON Acid : 750 kg

Toluene: 4329 kg

Caustic flakes: 159 kg

Water: 69 kg to ETP

HCI: 50 kg

Solvent Loss: 210 kg

Distill Toluene Recycle: 4250

Water: 100 kg + 10 kg Caustic

Alakli scruber


Drying Loss: 211 kg

3-Hydroxy-2-Napthonilide: 1000

5. Naphthol AS:

WET CAKE

DRYING


DEHYDRATION

BON Acid : 520 kg

Toluene: 3745 kg

Caustic flakes: 137 kg Water: 60 kg to ETP

HCI Gas: 11 kg


Distill Toluene Recycle: 3614 kg


Water Scrubber


Drying Loss: 111 kg

3-Hydroxy-3-Napthonilide: 1000 Kg

NAPHTHOL

FORMATION

PCI3: 187 kg Meta Nitro Aniline: 400 kg

Soda ash: 74 kg Water: 2247 kg

6. Napthol ASBS:

DEHYDRATION

BON Acid: 694 kg o-

Toludine: 4004 kg


PCI3: 200 kg Meta Nitro Aniline: 380 kg

Soda ash: 24 kg Water: 2403kg

NAPHTHOL

FORMATION

WET CAKE

DRYING

3-Hydroxy 2-Naptho O-Toludine: 1000 Kg

Water: 65 kg to ETP

HCI Gas: 16 kg





Drying Loss: 119 kg


Water Scrubber

7. Naphthol ASD :

BON Acid: 667 kg

Toluene: 3846 kg


DEHYDRATION Water: 63 kg to ETP

PCI3 : 192 kg P Chloro Aniline : 436 kg

Soda ash : 24 kg Water : 2308 kg

NAPHTHOL

FORMATION

HCI Gas: 17 kg



WET CAKE

DRYING Drying Loss: 114 kg

4 Chloro 3-Hydroxy-2-Napthonilide: 1000 Kg



Water Scrubber


8. Naphthol ASE:

BON Acid: 500 kg

Toluene: 3546 kg


DEHYDRATION Water: 55 kg to ETP

PCI3: 177 kg Alfa Napthyl Amine: 402 kg


NAPHTHOL

FORMATION

HCI Gas: 14 kg



WET CAKE

DRYING Drying Loss: 105 kg

3-Hydroxy N-Napthyl 2 -Napthonilide: 1000 Kg



Water Scrubber


9. Naphthol ASBO:

PCI3: 193 kg o-Anisidine: 412 kg


WET CAKE

DRYING


DEHYDRATION BON Acid: 658 kg

Toluene: 3871 kg


Water: 62 kg to ETP

HCI Gas: 17 kg

Solvent Loss: 135 Distill Toluene Recycle: 3736

Water:100 kg + 10 kg

Water


Drying Loss: 115 kg

3-Hydroxy 2 Naptho O- Anisidine : 1000 Kg

NAPHTHOL

FORMATION

10. Naphthol ASOL:

REDUCTION MDNB: 250 kg NaHS: 2375 kg

Water: 4000 kg

FILTERATION

WET CAKE WASHING

DRAYING

META NITRO ANILINE: 1000 Kg

Vapour loss: 1125 kg

Effluent: 6200 kg

Wash Water: 1700 kg

11. Meta Nitro Aniline:

12. Meta Urido Aniline:

REDUCTION

MPD: 497 kg HCI: 1163 kg

Water: 1576 kg Sodium Cyanate: 327 kg

FILTERATION

WET CAKE

META URIDO ANILINE: 1000 Kg

Effluent: 2563 kg

NEUTRALIZATION Up to 7pH

At room temperature (1 HRS)

6450

Product: 1000 kg

SULPHONATOR at180oc (10HRS)

2050

Vapor Loss: 2 kg

Vapor Loss: 5 kg

Carbon Adsorption

Scrubber

PAKING IN DRUM/TANKER

CONDENSATION at 110oc (20 HRS)

5540

Sulphuric Acid (98%): 900 kgs

Phenol :1150 kgs

Sulphuric Acid (98%): 139 kg

Phenol: 178 kg

Water: 310 kg

Formaldehyde: 217 kg

EDTA: 8 kg

Caustic Soda lye: 155 kg

13. Dispersing Agent based on phenol (liquid):

Product: 1000 Kg

Phenol based Dispersing Agent (liquid): 2227 kg

Water Evaporation: 1227 kg SPRAY DRAYING

14. Dispersing Agent based on phenol (Solid) :

NEUTRALIZATION At room temperature

(1 HRS)

PRODUCT: 1000 kg

SULPHONATOR at180oc (10HRS)

Vapor Loss: 19 kg

Vapor Loss: 10 kg

Scrubber

PAKING IN DRUM/TANKER

CONDENSATION at 110oc (15 HRS)

Sulphuric Acid (98%): 52 kg

Naphthalene: 196 kg

Water: 98 kg

Formaldehyde: 118 kg

Water: 225 kg

Caustic Soda lye: 196 kg

Oleum: 735 kg

Condenser Carbon

Absorber

15. Dispersing Agent based on Naphthalene (liquid):

Product: 1000 Kg

Naphthalene based (Liquid)

: 2380 kg

Water Evaporation: 1380 kg SPRAY DRAYING

16. Dispersing Agent based on Naphthalene (Solid):

Enclosure: 8 Detail of Water Consumption & Waste Water Generation

Total water consumption will be 37.5 KLPD. Domestic water consumption will be 4 KLPD & Industrial water consumption will be 33.5 KLPD.

Domestic effluent @ 4 KLPD will be disposed to soak pit system. Industrial effluent 24 KLPD will be treated in Effluent treatment Plant consisting primary & secondary units and 24 KLPD will be discharged to CETP, Vapi.

Water Consumption KL /Day

Effluent Generation KL /Day

Existing Proposed Total Existing Proposed Total Domestic 1 3 4 1 3 4 Industrial Process 4 19 23 2 19 21 Boiler 0.5 4.5 5 0.5 0.5 1 Cooling 1 1 2 0 0.5 0.5 Plant washing 1 0.5 1.5 1 0.5 1.5 Gardening 1 1 2 0 0 0 Total 8.5 29.5 37.5 5.5 22.5 28

Water Balance Diagram

All the Figures are in KL/Day

Water Consumption 37.5

Cooling 2

Boiler 5

Process 23

Effluent 21

Gardening 2

Domestic Effluent goes to septic tank

4

Domestic 4

Industrial 33.5

Blow Down 1

Effluent 0.5

Effluent Sand to ETP 24

CETP Vapi 24

Plant Washing 1.5

Washing Effluent

1.5

24

3

Enclosure: 9 Detail of Effluent Treatment Plant

Sr. No. Name of Unit Capacity

(m3)

Retention Time (hr)

MOC

1 Collection tank 10 4 RCC

2 Neutralization cum Flocculator tank 3 1 RCC

3 Settling tank 25 9 MS

4 Aeration tank with built in secondary clarifier 15 5.5 RCC

5 Sand Filter 1.5 0.5 MS 6 Carbon Filter 1.5 0.5 MS 7 Sludge Drying Bed 1 m2 --- Brick masonry

1 2 6 4 5 3

7

Effluent Inlet

Treated Effluent to

CETP

ETP Diagram

Enclosure: 10 Detail of Flue Gas Emission & Process Gas Emission with APCM System

Type of Flue Gas Emission:

No. Stack attached To Stack

Height (Meter)

APC Measures

Pollutants

SPM Mg/NM3

SO2 ppm

NOX ppm Existing Proposed

1. Boiler 600

kg/hour --- 11 ---

< 150

mg/NM3

< 100 ppm

< 50 ppm

2 D.G. Set 125 KVA

---

11 ---

< 150

mg/NM3

< 100 ppm

< 50 ppm

3 ---

Steam Boiler

800 kg/hr

11 Wet scrubber

< 150

mg/NM3

< 100 ppm

< 50 ppm

4 ---

HAG 400

kg/Hour

11 --- -- < 100 ppm --

Type of Process Gas Emission:

No. Stack attached To Stack Height (Meter) APC Measures Pollutants and their

limits

1. Napthol Reactor 11 Alkali Scrubber HCl< 20 mg/Nm3

2 Oleum Storage Tank and Sulphonator 11 Alkali Scrubber SO2< 40 mg/Nm3

3 HCHO Reactor 11 Carbon

Adsorption System

Formaldehyde Vapors< 10 mg/Nm3

Details of Fuels

Methanol + water mixer generates from manufacturing of cyano 2 Pyridone which will be used as fuel in our boiler. We will use methanol+ water mixer as a fuel in our proposed boiler (800 Kg/Hr). And in case of unavability of methanol + water mixer in case of zero production of cyano 2 pyridone, we will use Bio Coal/Coal as optional fuel.

We have decided to put our existing boiler (600 Kg/Hr) on standby. We will also use methanol + water mixer in stand by boiler. And in case of unavability of that fuel we will use PNG as optional fuel in standby boiler.

We will use Bio Coal/Coal as a Fuel in HAG.

Sr. No Name of Fuel Quantity


1 Diesel 10 Liter/Day -- 10 Liter/Day

2 Natural gas 55 SCM/Hr -- 55 SCM/Hr

3 Methanol + water Mixer -- 5 MT/Day 5 MT/Day

4 Bio Coal/Coal -- 1.60 MT/Day 1.60 MT/Day

Enclosure: 11 Detail of Hazardous Waste Management

Sr.

No.

Type of

Waste Category

Quantity Management


1 ETP Waste

Cat. No.: 35.3 3.6 MT/Year

196.4 MT/Year

200 MT/Year

Collection, Storage, Transportation, Disposal to TSDF site

2 Process Waste

Cat. No.: 34.3 42

MT/Year 84

MT/Year 126

MT/Year

Collection, Storage, Transportation, Disposal to TSDF

3 Used oil

Cat. No.: 5.1 0 0.012 KL/Year

0.012 KL/Year

Collection, Storage, Transportation, sell to authorize recycler.

4 Discarded

Containers/ Bags

Cat. No.: 33.1 2 MT/Year

430 MT/Year

432 MT/Year

Used for packing of ETP waste or return back to raw material supplier.

Enclosure: 12 Name & Address of Partner

Sr. No. Name of Partners

Residential Address

1 Mr. Nareshbhai N. Patel Flat No. A-1/102, Jalaram Co Operative Housing So. Ltd, Chharvada Road, GIDC Vapi, Pardi, Valsad

2 Mr. Mohanbhai N. Patel Village: Laloda, Ta: Idar, Dist: Sabarkantha

Enclosure: 13 Land Supporting Document

Enclosure: 14 Site Plan & Layout Plan

Enclosure: 15 CA Certificate

Enclosure: 16 Membership Certificates

Enclosure: 17 SSI Certificate

Enclosure: 18 Existing Consent Order Copy

enclosure: 1environmentclearance.nic.in/writereaddata/online/tor/12...14 aniline liquid drum ms 14.4...

Documents