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EMMENNAR PHARMA PVT. LTD. (UNIT V) SY. NO.S 632 (PART), 633 (PART), 635, 636 (PART), 637 (PART), 638 (PART) AND 642 (PART), PEDDAPALLY VILLAGE, JADCHERLA MANDAL, MAHABUBNAGAR DISTRICT, TELANGANA FORM I Project No. 12172101 November 2017 Emmennar Pharma Pvt. Ltd. Plot no. A4, Industrial Estate, Opposite Sanathnagar Police Station, Sanathnagar, Hyderabad, Telangana Pin code500 018 Phone :+91 9703706737 Email: [email protected] ; [email protected] ; STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants B115117 & 509, Annapurna Block, Aditya Enclave, Ameerpet, Hyderabad500 038. Phone: 04023748 555/23748616, Telefax: 04023748666 SUBMITTED TO MINISTRY OF ENVIRONMENT, FORESTS AND CLIMATE CHANGE GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI

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Page 1: EMMENNAR PHARMA PVT. LTD. (UNIT V)environmentclearance.nic.in/writereaddata/Online/TOR/29_Nov_2017... · 2.2 Water (expected source & competing users) unit: KLD YES Total water required

EMMENNAR PHARMA PVT. LTD. (UNIT ‐ V) SY. NO.S 632 (PART), 633 (PART), 635, 636 (PART), 637 (PART), 

638 (PART) AND 642 (PART), PEDDAPALLY VILLAGE,  JADCHERLA MANDAL, MAHABUBNAGAR DISTRICT, 

TELANGANA       

  

FORM I          

  

  

      

 

Project No. 1217‐21‐01 November 2017 

 

Emmennar Pharma Pvt. Ltd. Plot no. A‐4, Industrial Estate, Opposite Sanathnagar Police Station, Sanathnagar, Hyderabad, Telangana  Pin code‐500 018 Phone :+91 9703706737 E‐mail: [email protected][email protected];  

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants B‐115‐117 & 509, Annapurna Block,  Aditya Enclave, Ameerpet,  Hyderabad‐500 038. Phone: 040‐23748 555/23748616, Telefax: 040‐23748666      

 

SUBMITTED TO MINISTRY OF ENVIRONMENT, FORESTS AND CLIMATE CHANGE 

GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI

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Form I        Page 1 

APPENDIX – I (See Paragraph – 6) 

FORM I I)  Basic Information S.No.  Item  Details 1  Name of the Project/s  Emmennar Pharma Pvt. Ltd. (Unit – V) 2  S. No in the Schedule   5 (f) –A category (Synthetic Organic Chemicals) 3  Proposed capacity/area/length/tonnage to 

be handled/command area/lease area/number of wells to be drilled 

1. API Capacity: 960 TPM 2. R&D and Validation Products: 50 Kg/day 3. Co‐Generation Power Plant :  5 MW 

Total Site Area: 45 acres Project Cost: 25 Crores 

4  New/Expansion/Modernization  New 5  Existing Capacity/Area etc.  Not Applicable 6  Category of Project i.e 'A' or 'B'  “A” 7  Does it attract the general condition? If yes, 

please specify No 

8  Does it attract the Specific condition? If yes, please specify. 

No 

9  Location       Plot/Survey/Khasra No.   Sy. No.s 632 (Part), 633 (Part), 635, 636 (Part), 637 

(Part), 638 (Part) and 642 (Part),     Village  Peddapally Village  Tehsil  Jadcherla Mandal     District  Mahabubnagar District   State  Telangana 

10  Nearest railway station/airport along with distance in km. 

Railway Station: Jadcherla – 5.33 Km Airport: Rajiv Gandhi International Airport – 59 Km  

11  Nearest Town, City, District Headquarters along with distance in kms. 

Jadcherla  –4.5 Km 

12  Village Panchayats, Zilla Parishad, Municipal Corporation, Local body (complete postal address with telephone nos. to be given) 

Peddapally  –Village Panchayat 

13  Name of the Applicant  K. Vamshidhar Reddy 14  Registered Address  Emmennar Pharma Pvt. Ltd. (Unit – V) 

Sy. No.s 632 (Part), 633 (Part), 635, 636 (Part), 637 (Part), 638 (Part) and 642 (Part), Peddapally Village, Jadcherla Mandal, Mahabubnagar District, Telangana ‐ 509385 

15  Address for Correspondence:     Name  K. Vamshidhar Reddy   Designation(Owner/Partner/CEO)  Director   Address  Plot no. A‐4, Industrial Estate, Opposite Sanathnagar 

Police Station, Sanathnagar, Hyderabad, Telangana   Pin Code  500 018   E‐mail  [email protected]

[email protected]  

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Form I        Page 2 

  Telephone Number  +91 9703706737   Fax No.  040‐23801966 

16  Details of alternative Sites examined, if any. Location of these sites should be shown on a topo sheet. 

No 

17  Interlinked Projects  Not applicable 18  Whether separate application of interlinked 

project has been submitted?  ‐NA‐ 

19  If yes, date of submission   ‐NA‐ 20  If no, reason    21  Whether the proposal involves 

approval/clearance under: if yes, details of the same and their status to be given.                (a) The Forest (Conservation) Act, 1980?           (b) The Wildlife (Protection) Act, 1972?             (c) The C.R.Z Notification, 1991? 

‐NA‐ 

22  Whether there is any Government Order/Policy relevant/relating to the site? 

 No 

23  Forest land involved (hectares)   No 24  Whether there is any location pending 

against the project and /or land in which the project is propose to be set up?                           (a) Name of the Court                                            (b) Case No                                                         (c) Orders/directions of the Court, if any and its relevance with the proposed project. 

 No 

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Form I        Page 3 

(II)  Activity  1.  Construction,  operation  or  decommissioning  of  the  Project  involving  actions,  which  will  cause  physical changes in the locality (topography, land use, changes in water bodies, etc.) S.No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate quantities /rates, 

wherever possible) with source of information data 1.1  Permanent or temporary change in 

land use, land cover or topography including increase in    intensity of land use (with respect to local     land use plan)   

NO  The proposal is for a green field project. The land area for  proposed  plant  is  45  acres.  The  land  is  plain  and does not involve much of leveling/excavation. 

1.2  Clearance  of  existing  land, vegetation and buildings? 

NO  The  land  is  plain  and  does  not  involve  much  of leveling/excavation.   

1.3  Creation of new land uses?  NO   1.4  Pre‐construction investigations e.g. 

bore houses, soil testing? YES  Soil  test  done  and  soil  load  bearing  capacity 

established 1.5  Construction works?      YES  Construction  activity  involves  creation  of  Production 

Blocks, Utilities and ZLD system. 1.6  Demolition works?  NO   1.7  Temporary  sites  used  for 

construction  works  or  housing  of construction workers? 

NO  Construction  labor  from  local  villages  shall  be employed. 

1.8  Above  ground  buildings,  structures or  earthworks  including  linear structures, cut and fill or excavations 

YES  Storage  facilities  shall be  constructed.     No major  cut and fill or excavation is anticipated. 

1.9  Underground works including mining or     tunneling? 

NO  No underground works like mining and tunneling.  

1.10  Reclamation works?  NO   1.11  Dredging?   NO   1.12  Offshore structures? NO1.13  Production  and  manufacturing 

processes? YES  Enclosed in Annexure – I 

1.14  Facilities for storage of goods or materials? 

NO  Raw  materials  and  solvents  shall  be  stored  with  in factory premises. Materials  in bags and drums will be stored in flame proof ware houses.  

1.15  Facilities for treatment or disposal of solid waste or liquid effluents? 

YES  High  TDS  and  low  TDS  effluents  are  treated  in  ZLD system. Organic  waste  is  sent  to  cement  plants  for  co‐ processing or to TSDF.  Details  of    waste  treatment  facilities    presented  in Annexure II   

1.16  Facilities for long term housing of operational workers? 

NO  Operational workers stay in surrounding villages. 

1.17   New road, rail or sea traffic during construction or operation? 

YES  Construction materials shall be transported to the site.  The  traffic  density  of  the  existing  connecting  road  is negligible. 

1.18   New  road,  rail,  air  waterborne  or other  transport  infrastructure 

NO   

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Form I        Page 4 

including new or altered  routes  and stations, ports, airports etc? 

1.19   Closure  or  diversion  of  existing transport  routes  or  infrastructure leading  to  changes  in  traffic movements? 

NO   

1.20  New or diverted  transmission  lines opipelines? 

NO   

1.21  Impoundment, damming,  culverting, realignment or other changes to the hydrology      of  watercourses  or aquifers? 

NO   

1.22  Stream crossings?  NO  All  raw  materials,  solvents  and  waste  streams  are pumped through pipe lines above ground level.  

1.23  Abstraction  or  transfers  of  water form ground or surface waters? 

YES  Total  water  required  shall  be  met  from  ground water/Supply from Mission Bhagiradha. Total water  required  shall  be  1363  KLD  out  of which 738 KLD shall be  fresh water and the balance shall be recycled water. 

1.24  Changes in water bodies or the land surface affecting drainage or run‐off?

NO   

1.25  Transport  of  personnel  or materials for  construction,  operation  or decommissioning? 

YES  The  construction material  shall  be  drawn  from  local sources  within  10  km.    There  is  no  transport  of personnel, as the construction workers shall be drawn from local villages. 

1.26  Long‐term dismantling or decommissioning or restoration works? 

NO   

1.27  Ongoing activity during decommissioning which could have an impact on the environment? 

NO   

1.28  Influx of people to an area in either temporarily or permanently? 

YES  The  proposed  project  shall  increase  the  employment potential.

1.29  Introduction of alien species?  NO   1.30  Loss of native species or genetic 

diversity? NO  There are no major losses of tree/shrub species. 

1.31  Any other actions?  NO   

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Form I        Page 5 

2.   Use  of Natural  resources  for  construction  or  operation  of  the  Project  (such  as  land, water, materials  or energy, especially any resources which are non‐renewable or in short supply): S.No.  Information/checklist 

confirmation Yes/No  Details thereof (with approximate quantities /rates, 

wherever possible) with source of information data 2.1  Land especially undeveloped or 

agricultural land (ha) YES  Land area: 45 acres 

 Sy. No.s 632 (Part), 633 (Part), 635, 636 (Part), 637 (Part), 638 (Part) and 642 (Part), Peddapally Village, Jadcherla Mandal, Mahabubnagar District, Telangana.   

2.2   Water (expected source & competing users) unit: KLD 

YES  Total water required shall be met from ground water/Supply from Mission Bhagiradha. Total water required shall be 1363 KLD out of which 738 KLD shall be fresh water and the balance shall be recycled water. (Water Balance Enclosed in Annexure III) 

2.3  Minerals (MT)  NA   2.4  Construction material – stone, 

aggregates, sand / soil (expected source – MT) 

YES  Shall be sourced from the local villages. 

2.5  Forests and timber (source – MT) 

NO   

2.6  Energy including electricity and fuels (source, competing users) Unit: fuel (T), energy (MW) 

YES  The  required energy shall be drawn  from Transco. Standby DG sets of 2 X 1010 kVA, 3 x 720 kVA and 2 x 320 kVA are proposed.  

It is proposed to establish coal fired boilers of capacity 1 x 30 TPH and 1 x 10 TPH. It is proposed to keep 1 x 10 TPH boiler as standby after establishment of 1 x 30 TPH boiler.  

It  is proposed  to establish 4  x 2  Lac. K.Cal of  thermic  fluid heater for process requirement. Coal will be used as fuel. 

Total fuel requirement will be around 150 TPD (coal).   2.7  Any other natural resources 

(use appropriate standard units) 

NA   

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Form I        Page 6 

3.   Use,  storage,  transport, handling or production of  substances       or materials, which  could be harmful  to human health or the environment or raise concerns about   actual or perceived risks to human health. S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 3.1  Use of substances or materials, which 

are hazardous (as per MSIHC rules) to human health or the environment (flora, fauna, and  water supplies) 

YES  Hazardous chemicals shall be used for manufacturing of  Synthetic  Organic  Chemicals  and  intermediates. MSIHC  rules  shall  be  followed  during  storage, transportation  and  handling  of  raw  materials. Hazardous chemicals and solvent shall be stored and handled in closed systems. 

3.2  Changes in occurrence of disease or affect disease vectors (e.g. insect or water borne diseases). 

NO   

3.3  Affect the welfare of people e.g. by changing living conditions? 

YES  Shall  increase  the  employment  potential  for  locals and affect the living conditions for betterment. 

3.4  Vulnerable groups of people who could be affected by the project e.g. hospital patients, children, the elderly etc., 

NO  No sensitive receptors are present  in the  immediate vicinity  of  the  site.  The  project  shall  not  have  any significant impact on vulnerable groups of people.  

3.5  Any other causes  NO    

4. Production of solid wastes during construction or operation or decommissioning (MT/month) S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 4.1  Spoil, overburden or mine wastes  NO   4.2  Municipal waste (domestic and or 

commercial        wastes) NO  Wastes  from  canteen,  other  commercial wastes  like 

paper, empty containers etc.   The canteen wastes and commercial wastes shall be in the range of 15 kg/day 

4.3  Hazardous wastes (as per Hazardous Waste  Management Rules) 

YES  Hazardous waste generation during construction shall be  limited  to waste  oils,  batteries  and  containers  of paints  etc.    The  quantity  of  hazardous  wastes generated  during  operation  contain  salts  from evaporators,  process  residue,  and  solvent  residues, ETP sludge and filtration media etc.   

4.4  Other industrial process wastes  YES  Enclosed at Annexure IV 4.5  Surplus product  NO   4.6  Sewage sludge or other sludge from 

effluent  treatment YES  Sludge from Effluent treatment plant and evaporation 

salts shall be sent to TSDF.  4.7  Construction or demolition wastes  NO  Construction  activities  involve  creation of Production 

Blocks, Utilities and ZLD system. 4.8  Redundant machinery or equipment  NO   4.9  Contaminated soils or other materials  NO  All pipe lines including pipe lines of waste streams are 

above ground  level to eliminate the possibility of any contamination  due  to  seepage  and  for  ease  of maintenance. 

4.10  Agricultural wastes  NO   4.11  Other solid wastes  YES    

 

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Form I        Page 7 

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr) S.No.  Information/Checklist confirmation  Yes/No Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data 5.1  Emissions from combustion of fossil 

fuels from stationary or mobile sourcesYES  Coal  Shall  be  used  as  fuel.  Emissions  details  are 

enclosed in Annexure V 5.2  Emissions from production processes  YES  Gaseous  emissions  from  process  are  HCl,  SO2,  are 

scrubbed  in  scrubber  and.  Hydrogen  gas  sent  to atmosphere through water column.   

5.3  Emissions from materials handling including storage or transport 

NO  Material  transfer  takes  place  in  closed  pipeline systems using pumps with mechanical seals.

5.4  Emissions from construction activities including plant and equipment 

YES  Dust  may  rise  during  transport  of  material  and construction  activity.    The  dust  emissions  shall  be mitigated by water  spraying on  the  roads within  the premises.  

5.5  Dust  or  odors  from  handling  of materials  including  construction materials, sewage and  waste 

NO  Domestic  wastewater  sent  to  zero  liquid  discharge system. 

5.6  Emissions from incineration of waste  NO  Organic waste  streams are sent  to cement plants  for co‐incineration. 

5.7  Emissions from burning of waste in open air (e.g. slash materials, construction debris) 

NO   

5.8  Emissions from any other sources  NO

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Form I        Page 8 

6. Generation of Noise and Vibration, and Emissions of Light and Heat: S.No.  Information/Checklist confirmation Yes/No  Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data with source of information data 

6.1  From operation of equipment e.g. engines, ventilation plant, crushers 

YES  Material transport and construction equipment shall be source  of  noise,  while  transfer  pumps,  vacuum systems,  DG  sets  are  the  sources  of  noise  during operation.   

6.2  From industrial or similar processes  YES  From Turbine and DG sets, and controlled by providing Acoustic Enclosures. 

6.3  From construction or demolition  YES  Noise during construction shall be due to construction equipment and emergency DG sets.    

6.4  From blasting or piling  NO   6.5  From construction or operational 

traffic NO  The increased traffic shall not have any significant 

impact.  6.6  From lighting or cooling systems  NO   6.7  From any other sources  NO

  7.Risks of contamination of land or water from releases of    pollutants into the ground or into sewers,   surface     waters, groundwater, coastal waters or the sea: S.No.  Information/Checklist confirmation Yes/No  Details thereof (with approximate quantities/rates, 

wherever possible) with source of information data7.1  From handling, storage, use or 

spillage of hazardous materials NO  All the hazardous materials will be stored in MS drums, 

in  a  covered  shed  and  no  contamination  of  soil  is expected.  Same  philosophy  will  be  followed  for  the after expansion 

7.2  From discharge of sewage or other effluents to water or the land (expected mode and place of discharge) 

NO  All  the  waste  from  domestic  operations  sent  to  ZLD system. 

7.3  By deposition of pollutants emitted to air into the land or into water 

NO  All  the  emissions  from  process  are  controlled  by providing control equipment like scrubbers, Bag filters. 

7.4  From any other sources  NO   7.5  Is there a risk of long term build up 

of pollutants in environment from these     sources? 

NO  

 

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Form I        Page 9 

8.Risk of  accidents during  construction or operation of  the Project, which  could  affect human health or  the environment 

S.No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate quantities/rates, wherever possible) with source of information data 

8.1  From explosions, spillages, fires etc from storage, handling, use or production of hazardous substances 

YES  All  Inbuilt  Safety  precautions  will  be adopted  and  there  will  not  be  any damage  to  environment  or  human health  

8.2  From any other causes  NA   8.3  Could the project be affected by natural disasters 

causing environmental damage (e.g.     Floods, earthquakes, landslides, cloudburst etc)? 

NO   

 9.Factors which should be considered (such as consequential development) which could lead to environmental effects or the potential for cumulative impacts  with  other existing or planned activities in the locality S. No.  Information/Checklist confirmation  Yes/No  Details thereof (with approximate 

quantities/rates, wherever possible) with source of information data 

9.1  Lead to development of supporting.   facilities, ancillary development or development stimulated by the project which could have impact on the environment e.g.: • Supporting infrastructure (roads, power supply, waste or waste water treatment, etc.) •      housing development •      extractive industries •      supply industries •      other 

YES  The  project  shall  enhance  the  socio economic  status  of  the  area  by increasing  the  demand  for  housing, improving the employment.  

9.2  Lead to after‐use of the site, which could haven impact on the environment 

NO   

9.3  Set a precedent for later developments  NO   

9.4  Have cumulative effects due to proximity to other existing or planned projects with similar    effects 

NO  The  baseline  environmental  status  of the  surrounding  areas  is  within  the prescribed  limits as observed  from the Secondary data. 

 

          

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Form I        Page 10 

 (III)  Environmental Sensitivity S.No.  Areas  Name/ 

Identity Aerial  distance  (within  15  km.) Proposed project location boundary 

1   Areas  protected  under  international  conventions,  national  or  local  legislation  for  their  ecological,  landscape, cultural or other related value 

NA   

2  Areas  which  are  important  or  sensitive  for ecological  reasons  ‐  Wetlands,  watercourses  or other  water  bodies,  coastal  zone,  biospheres, mountains, forests 

YES  Tigalapalli RF ‐  SW – 1.4 km Appannapalli RF ‐ SW – 1.6 km Dindi Rive Stream – NE – 9 km  

3  Areas  used  by  protected,  important  or  sensitive  species  of  flora  or  fauna  for  breeding,  nesting, foraging, resting, over wintering, migration 

NA     

4   Inland, coastal, marine or underground waters  NO   5   State, National boundaries  NO   6   Routes or facilities used by the public for access to 

recreation or other tourist, pilgrim areas NO   

7   Defense installations  NO   8   Densely populated or built‐up area  YES  Nearest  habitation  from  the  site  is 

Bandaminipalle village at a distance of 1.4 km in East direction 

9   Areas  occupied  by  sensitive man‐made  land  uses  (hospitals,  schools,  places  of  worship,  community facilities) 

NA   

10  Areas  containing  important,  high  quality  or  scarce resources  (ground  water  resources,  surface resources,  forestry,  agriculture,  fisheries,  tourism, minerals) 

NO   

11  Areas  already  subjected  to  pollution  or  environmental  damage.  (those where  existing  legal environmental standards     are exceeded)

NO   

12   Areas  susceptible  to  natural  hazard  which  could  cause  the  project  to  present  environmental problems  (earthquakes,  subsidence,  landslides, erosion,  flooding  or  extreme  or  adverse  climatic conditions) 

NO       

          

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EMMENNAR PHARMA PVT. LTD. (UNIT ‐ V) SY. NO.S 632 (PART), 633 (PART), 635, 636 (PART), 637 (PART), 

638 (PART) AND 642 (PART), PEDDAPALLY VILLAGE,  JADCHERLA MANDAL, MAHABUBNAGAR DISTRICT, TELANGANA 

 

   

  

 ANNEXURES 

    

   

 

   

 

         

  

        

       

Project No. 1217‐21‐01 November 2017 

 

Emmennar Pharma Pvt. Ltd. Plot no. A‐4, Industrial Estate, Opposite Sanathnagar Police Station, Sanathnagar, Hyderabad, Telangana  Pin code‐500 018 Phone :+91 9703706737 E‐mail: [email protected][email protected]

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants B‐115‐117 & 509, Annapurna Block,  Aditya Enclave, Ameerpet,  Hyderabad‐500 038. Phone: 040‐23748 555/23748616, Telefax: 040‐23748666      

 

SUBMITTED TO MINISTRY OF ENVIRONMENT, FORESTS AND CLIMATE CHANGE 

GOVERNMENT OF INDIA INDIRA PARYAVARAN BHAWAN, JOR BAGH ROAD, NEW DELHI

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Form I Annexures

            Page 1

Fig

A.1

Loc

atio

n M

ap o

f Em

men

nar P

harm

a Pv

t. Lt

d. (U

nit –

V)

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Form I Annexures

            Page 2

M A IN G A T E

Fig A.2 Plant Layout of Emmennar Pharma Pvt. Ltd. (Unit – V)

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Form I Annexures

            Page 3

ANNEXURE - I

M/s. Emmennar Pharma Pvt. Ltd. (Unit – V) proposes to set up a Synthetic Organic

Chemicals (Bulk Drugs & Intermediates) Unit in an area of 45 acres in at Sy. No.s 632 (Part),

633 (Part), 635, 636 (Part), 637 (Part), 638 (Part) and 642 (Part), Peddapally Village, Jadcherla

Mandal, Mahabubnagar District, Telangana. The proposed list of products and

manufacturing capacity is presented in Table A-1 and By-products presented in Table A-2.

Table A-1 Manufacturing Capacity S.No Name of Product CAS No. Capacity

TPM TPD 1 Methyl Ester 556-61-6 210 7 2 (2-Nitro-1-(Methylamino)-1-(Methylthio) ethane

(NMSM) 61832-41-5 90 3

3 Cyclopropylamine 765-30-0 60 2 4 Levetiracetam 102767-28-2 120 4 5 Omeprazole 73590-58-6 60 2 6 Meta Chloroanisole 2845-89-8 210 7 7 Meta Chloro Nitrobenzene 121-73-3 210 7 Total 960 32 8 R&D and Validation Products 50 Kg/day 9 Co-Generation Power Plant 5 MW

Table A-2 List of By-Products S.No Name of By-Product Capacity

(TPM) 1 Sulfur 116 2 HCl (30%) 51.48 3 HCl (35%) 2.8 4 Soidum Hydroxide (48%) 123 5 P-Chloro Nitro Benzene 26.2 6 O-Chloro Nitro Benzene 26.2

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Form I Annexures

            Page 4

Process Description of 2-Nitro-1-(Methylamino)-1-(Methylthio) Ethane (NMSM):

Reaction Schemes

Methyl EsterCH3NCS

Mol. Wt. 73Nitromethane

CH3NO2Mol. Wt. 61

Dimethyl Sulfate(CH3O)2SO2Mol. Wt. 126

Potassium HydroxideMol. Wt. 56

KOH+ + +

NMSMC4H8O2N2S

Mol. Wt. 148

+

Potassium Methyl SulfateCH3KO4

Mol. Wt. 150

+

WaterMol. Wt. 18

H2O

DMSO

Process Description

Methyl Isothiocyanate is reacted with Nitiromethane and KOH in presence of DMSO

(Solvent) to get the salt, which is methylated with Dimethyl Sulphate. The mass is

quenched into water to separate NMSM and the mother liquor. Mother liquor is mixture of

DMSO, water and potassium methyl sulphate. DMSO is recovered and recycled. The

process flow diagram for NMSM is presented in Fig A.3 and material balance is presented

in Table A.3.

Fig A.3 Process Flow Diagram of NMSM

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Form I Annexures

            Page 5

Table A-3 Material Balance of NMSM Input Quantity

(TPD) Output Quantity

(TPD) Remarks

Methyl Ester 2.1 2-Nitro-1-(Methylamino)-1-(Methylthio) Ethane (NMSM)

3 Final Product

Potassium Hydroxide 1.61 Potassium Methylsufate 3.04 Inorganic Residue Nitromethane 1.76 DMSO Recovered 14.48 Recovered & reused Dimethyl Sulfate 3.63 DMSO Loss 0.06 Fugitive Loss Water 18 DMSO in Wastewater 0.09 To Wastewater Dimethyl Sulfoxide (DMSO)

15 DMSO in Residue 0.38 Solvent in residue

Methyl Ester 0.62 Organic Residue Nitromethane 0.52 Organic Residue Dimethyl Sulfate 1.07 To Wastewater Potassium Hydroxide 0.48 To Wastewater Wastewater 18.36 To Wastewater Total Input 42.1 Total Output 42.1

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Form I Annexures

            Page 6

ANNEXURE – II: Wastewater Treatment Facilities

The main sources of effluent generation from the plant are from process, floor washings,

blowing downs from boiler and cooling tower, and domestic effluents. The effluents

generated in the process, separation techniques and during purification contain organic

residues of raw materials, solvents, and products. Some of the raw materials used in the

process are also inorganic in nature. Hence the effluents contain both organics and in-

organics in various quantities leading to high COD and TDS levels respectively. The

quantity of effluents generated and mode of treatment is presented in Table A-4.

Table A-4 Quantity of Effluent Generated and Mode of Treatment

Description Quantity (KLD)

Mode of Treatment

HTDS Effluents Process 410 Sent to Stripper followed by MEE and ATFD.

Stripper Condensate sent to Cement Plants for Co-Incineration. MEE and ATFD Condensate sent to Biological treatment plant followed by RO. RO rejects sent to MEE and permeate reused in cooling towers make-up.

Washings 20 Scrubber Effluent 15 RO/DM rejects 28

Total - I 473 LTDS Effluents

Boiler Blow downs 27 Sent to Biological Treatment System followed by RO. RO permeate reused for cooling tower makeup. RO rejects sent to MEE.

Cooling Tower Blow downs 165 Domestic 18

Total - II 210 Grand Total (I+II) 683

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Form I Annexures

            Page 7

ANNEXURE – III: Water Balance

Water is required for process, scrubbers, washing, cooling tower makeup, steam

generation and domestic purposes. The required water shall be drawn from ground water

sources/supply from Mission Bhagiradha in addition to reuse of treated wastewater. The

total water requirement is in the order of 1363 KLD consisting of 738 KLD fresh water and

the remaining of recycled water. Total water balance is presented in Table A-5.

Table A-5 Total Water Balance (Tentative)

Purpose INPUT (KLD) OUTPUT (KLD) Fresh Water Recycled Water Loss Effluent

Process 385 410* Washings 20 20 Scrubber 15 15 Boiler Feed 110 59 27 Cooling Tower 150 625 610 165 RO/DM Plant 28 28 Domestic 20 2 18 Gardening 10 10 Gross Total 738 625 666 683 Total 1363 1388 * Process effluents contain soluble raw materials, byproducts, solvents etc.

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Form I Annexures

            Page 8

ANNEXURE – IV: Solid Waste

Solid wastes are generated from the process shall be sent to TSDF/ Cement Industries for Co-

incineration. The inorganic residue, evaporation salts from MEE and ATFD and ETP Sludge

shall be sent to TSDF. Total solid waste generated and mode of disposal is presented in Table

A-6.

Table A-6 Total Solid Waste Generated and Mode of Disposal (Tentative)

S.No Description Units Quantity Mode of Disposal 1 Ash from Boiler TPD 37.5 Sold to Brick manufactures 2 Process Organic residue TPD 33.4 Sent to TSDF/Cement Industries 3 Process Inorganic residue TPD 16.1 Sent to TSDF 3 Solvent Residue TPD 10.2 Sent to TSDF/Cement Industries 4 Stripper Distillate KLD 8 Sent to TSDF/Cement Industries 5 Spent Carbon Kg/day 250 Sent to TSDF/Cement Industries 6 Mixed Solvents KLD 95 Sent to authorized recovery

units/Cement plants for co-incineration

7 Spent Solvents KLD 320 Recovered within the plant premises.

8 Evaporation Salts TPD 18.5 Sent to TSDF 9 ETP Sludge Kg/day 250 Sent to TSDF

10 Detoxified containers No.s/year 2500 After detoxification sent to Authorized agencies

11 Waste Oil Kl/Annum 5 Sent to Authorized Recyclers 12 Used batteries No.s/year 60 Sent to Authorized Recyclers

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Form I Annexures

            Page 9

ANNEXURE – V: Stack Emissions Details

It is proposed to establish coal fired boilers of capacity 1 x 30 TPH and 1 x 10 TPH. It is

proposed to keep 1 x 10 TPH boiler as standby after establishment of 1 x 30 TPH boilers. It is

proposed to establish 4 x 2 Lac. K.Cal of thermic fluid heater for process requirement. DG sets

of 2 X 1010 kVA, 3 x 720 kVA and 2 x 320 kVA are proposed for emergency power

requirement during load shut down period only. The proposed air pollution control

equipment for coal fired boiler is Bag filters. DG sets shall be provided with stack heights

based on the CPCB formula for effective stack height.

Table A-7. Stack Emission Details

S. No

Stack Connected to Stack Ht (m)

Dia of stack at top(m)

Temp. of exhaust

gases (0C)

Exit Velocity (m/sec)

Pollutant Emission Rate (g/sec)

PM SO2 NOx 1 1 x 30 TPH Coal

Fired Boiler 40 1.2 170 15 0.9 1.3 1.8

2 1 x 10 TPH Coal Fired Boiler

30 0.9 150 6.5 0.22 0.5 0.8

3 4 x 2 Lakh Kcal Thermic Fluid Heaters

15.2 0.4 180 6.5 0.04 0.08 0.12

4 2 X 1010 kVA DG set#

10 0.4 170 10 0.04 0.025 0.18

5 3x 720 kVA DG set#

6 0.3 150 8 0.01 0.015 0.12

6 2 x 320 kVA DG Set#

4 0.2 140 6.2 0.01 0.01 0.08

#DG sets will be used during load shut down by Transco. Note: 1 x 10 TPH fired boiler shall be kept as standby after establishment of 30 TPH boiler.

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EMMENNAR PHARMA PVT. LTD. (UNIT ‐ V) SY. NO.S 632 (PART), 633 (PART), 635, 636 (PART), 637 (PART), 

638 (PART) AND 642 (PART), PEDDAPALLY VILLAGE,  JADCHERLA MANDAL, MAHABUBNAGAR DISTRICT, TELANGANA 

  

  

    

    

  

       

  

 

 

  

 

 

 

STUDIES AND DOCUMENTATION BY TEAM Labs and Consultants   QCI: MoE&F OM, List A‐1, S.No.25.   (An ISO 9001:2008, ISO 14001:2004 &  OHSAS 18001:2007 Certified Organization) B‐115, Annapurna Block, Aditya Enclave Ameerpet, Hyderabad‐500 038. Phone: 040‐23748 555/616, Telefax: 040‐23748666 Email: [email protected]