electronic and steric factors for elimination reactions in carbenium ions derived from...
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![Page 1: Electronic and steric factors for elimination reactions in carbenium ions derived from (17.beta.-ethynylestradiol)M2L6 complexes (M2L6 = Co2(CO)6, Mo2Cp2(CO)4. X-ray structure of [Mo2Cp2(CO)4(.mu.-CH.tplbond.CC19H25O)]+BF-4](https://reader031.vdocuments.site/reader031/viewer/2022030206/5750a3591a28abcf0ca20cc8/html5/thumbnails/1.jpg)
824 Organometallics, Vol. 10, No. 3, 1991 Additions and Corrections
Additions and Corrections Guochen Jia,* Devon W. Meek, and Judith C. Gallucci: Synthesis and Reactivity of Ruthenium Hydride Com- plexes Containing Chelating Triphosphines. 4. Reactions of Ruthenium Hydride Complexes Containing Tri- phosphines with Olefins. 1990,9, 2549.
The structure of pyridine in eq 2 on page 2554 should be replaced by that of 2-vinylpyridine:
0,” =CH2 (excess)
M. Gruselle,* C. Cordier, M. Salmain, H. El h o u r i , C. GuBrin, J. Vaiasermann, and G. Jaouen*: Electronic and Steric Factors for Elimination Reactions in Carbenium Ions Derived from ( 178-ethynylestradiol)Mz~ Complexes (M&6 = CO~(CO)~, MozCpZ(CO),). X-ray Structure of
In the last line of the title, the compound should appear as given above. In the abstract, 2a and 2b should be written as [MzL6(cc-CHWC18H2zO)]+BF4-, where CHE CCl8HZ20 represents 17a-ethynyl-3-hydroxyestradiol. 2a’ and 2b’ should be [MzL&-CHWClJ4,0)]+BF4-, where CH=CC1J4,0 = 17a-ethynyl-3-methoxyestradiol. In the Introduction, l a and lb should read [M&(p-RC= CC18HaOz)]. la’ and lb’ should read [M,L6(pRC= CC1&,Oz)]. The formula in the fourth and fifth lines of the Introduction should read [MzL8(p-RC=CC- (OH)RIR,)]. In the Experimental Section, the compounds la, la’, lb’, and 2b’ should be written with the correct formulas mentioned above. In the Results and in the Discussion, 2b’ should be [MozCpz(CO),(p-CH= CC19Hz40)]+BF,- and the molecular structure of this compound should be [ M O ~ C ~ ~ ( C O ) ~ ( C ~ ~ H ~ ~ O ) ] + .
[Mo~C~~(CO)~(~-CH=CC~~H~~O)]+BFI-. 1990, 9, 2993.