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Effects of Nutrient Management Practices on Water Quality: Nitrogen Issues and Concerns Kevin Masarik Center for Watershed Science and Education

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Page 1: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Effects of Nutrient

Management Practices on

Water Quality:

Nitrogen

Issues and ConcernsKevin Masarik

Center for Watershed Science and Education

Page 2: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Background

• 70% of WI

population relies on

groundwater

• 42% (2.25 million

people) rely on

private wells as their

primary water supply

• Estimated 900,000

private wells in WI0

5000

10000

15000

20000

25000

Nu

mb

er

of

wells

insta

lled

WI Well Construction

Page 3: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nitrate-Nitrogen

• Most widespread groundwater

contaminant in WI

• Health related contaminant –

routinely tested for

• Very mobile, good at

identifying areas of land-use

impacts

• Agriculture is the largest

contributor of nitrate to

groundwater 0

10

2

“NATURAL”

UNSAFE - for infants and

pregnant women;

everyone should avoid

long term consumption.

Impacted by local land

use activities but suitable

for drinking.

Page 4: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nitrate-impacted Municipal Wells

• Amherst

• Cambria

• Chippewa Falls

• Crivitz Utilities

• Embarrass

• Fitchburg

• Fontana

• Janesville Water Utility

• Mattoon

• Morrisonville

• Oconomowoc

• Orfordville

• Plover

• Rome

• Sauk City

• Strum Waterworks

• Valders

• Village of Arlington

• Village of Clinton

• Village of Dalton

• Village of Footville

• Village of Friesland

• Waunakee

• Waupaca

• Whiting

Data obtained from Laura Chern of WDNR

2005 Total of $24 million

Page 5: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nitrate Impacts to Private Wells

• Estimated 12% of private

wells exceed drinking water

standard for nitrate

– 270,000 people (~3,000 additional people per year)

– 108,000 wells (1,000-2,000 additional wells per year)

DATCP, 2008

Page 6: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Estimated cost reduce nitrate exposure

$1.42/gallon $3.99/gallon $1.57/gallon $1.89/gallon $1.38/gallon

# affected compensation

estimate

assumptions Total estimate

270,000 people + 3K

per year

$1.38/gallon Assuming 0.5 gal/person/d

= $252/person/yr

$68 million/year + $0.75 per year

108,000 wells + 1-2K

per year

$1,000/well requiring

treatment

Conservative estimate (device, installation, replacement

filters, energy, etc.)

$108 million + additional $1-2

million per year

Disclaimer: Not all wells that exceed the drinking water standard are treated. This analysis estimates the cost of providing

bottled water to all affected or installation of water treatment on all affected wells.

Page 7: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Low

Nutrient Management and Nitrogen Recommendations

High

Nitrogen Fertilizer Added (lb/acre)

Page 8: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Low High

Yield Optimum

Nutrient Management and Nitrogen Recommendations

Nitrogen Fertilizer Added (lb/acre)

Page 9: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Low

Nitrogen Fertilizer Added (lb/acre)High

160 lbs/ac

economic optimum

that maximizes

profitability

Nutrient Management and Nitrogen Recommendations

Page 10: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Low

Nitrogen Fertilizer Added (lb/acre)

High

What is the ability of nitrogen nutrient recommendations to meet groundwater

performance standards?

Nitrogen Leaching Loss

Page 11: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

7-year Nitrate Leaching Study

N

CP NT

CP

CP

CP NT

NT

NT

0180 180

kg N/ha

CP =

Chisel

Plow

NT =

No Till

Lysimeters

•26 year old restored prairie

Plano Silt Loam soil at Arlington

Research Station

Page 12: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Sub-

optimalOptimal

Optimal +

manure

----------kg N ha-1----------

1996-2002 10 190 -

2002 10 190 190+145*

2003 10 190 190+128*

Pelletized ammonium nitrate used as the inorganic fertilizer

*Based on estimated available nutrient credit in 1st year of application

Long-term Nitrate Leaching

Study

Page 13: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Chisel-plow No-till

No-tillNo-till

Chisel-plow No-till

Chisel-plow

Chisel-plow

Sub-optimal

Optimal Optimal

Long-term Nitrate Leaching

Study

Page 14: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Annual Cumulative Precipitation

Page 15: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nitrate Concentrations

Chisel Plow

No Tillage

Prairie

No Till

Page 16: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Annual Cumulative Water Drainage

& Nitrate Leaching

1996 1997 1998 1999 2000 2001 2002

Year

0

200

400

600

0

200

400

600

Wa

ter

Dra

inage (

mm

)

No-Tillage

Chisel-Plow

Figure 2. Yearly cumulative water drainage measured using replicate automated equilibrium

tension lysimeters for restored prairie, no-tillage, and chisel-plowed ecosystems.

1996 1997 1998 1999 2000 2001 2002

Year

0

40

80

120

0

40

80

120

NO

3-N

Le

ach

ing L

oss (

kg h

a-1)

No-Tillage

Chisel-Plow

Figure 5. Yearly cumulative NO3-N leaching loss determined from water drainage and

NO3-N concentrations measured in leachate from 1996 through 2002 in the restored

prairie, no-tillage, and chisel-plowed ecosystems.

Page 17: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Seven Year Summary for Economic

Optimal Rates vs. Prairie

System

Chisel-

plow

No-tillage Prairie

Total precipitation (cm) 548 548 548

Total drainage (cm) 295 201 87

Precipitation lost to drainage (%) 54 37 16

Total NO3--N leaching loss (kg ha-1) 283 268 0.31

Amount N lost to leaching (%) 20 19 0.4

Flow weighted mean NO3-N Conc.

(mg L-1)*

9.6 13.3 0.04

Masarik, UW-Extension

*Maximum concentration measured greater than 40 mg/L.

Page 18: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

0 100 200 300 400N application rate (kg ha-1)

0

10

20

30

Flo

w-w

eig

hte

d N

O3

-N c

oncen

tra

tio

n

(mg

L-1)

CP

NT

CP

NT

Y = 1.3 + 0.0068X + 0.00015X2

R2 = 0.88

Y = 0.89 + 0.0046X + 0.00019X2

R2= 0.87

a)

Comparison of sub-optimal, optimal,

excess N for 2 years of data

Masarik, UW-Extension

Page 19: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Additional research investigating this topic -

Page 20: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 21: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nit

rate

Co

ncen

trati

on

Forest/

Prairie/

CRP

0

Generalized Nitrate Leaching

Potential

Alfalfa Soybean Corn Potato

Corn-

Soybean

Recommended Nitrogen Rates

Masarik, UW-Extension

Page 22: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nit

rate

Co

ncen

trati

on

Forest/

Prairie/

CRP

0

Generalized Nitrate Leaching

Potential

Alfalfa Soybean Corn Potato

Corn-

Soybean

Recommended Nitrogen Rates

Masarik, UW-Extension

Page 23: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

36% of crop acres in Fond du Lac County have nutrient management plans*

*According to DATCP data for 2011

Page 24: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 25: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 26: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Slide courtesy of Jim Vanden Brook, DATCP

Page 27: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Slide courtesy of Jim Vanden Brook, DATCP

Page 28: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Slide courtesy of Jim Vanden Brook, DATCP

Page 29: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Nit

rate

Co

ncen

trati

on

Forest/

Prairie/

CRP

0

Alfalfa Soybean Corn Potato

Corn-

Soybean

Recommended Nitrogen Rates

Masarik, UW-Extension

Nitrate = f(Crop N Requirements + Excess N + Soils/Geology)

Page 30: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Comparing Land-use Impacts

Corn1

(per acre)

Prairie1

(per acre)

Septic 2

System

Total Nitrogen Inputs (lb) 169 9 20-25

Nitrogen Leaching Loss (lb) 36 0.04 16-20

Amount N lost to leaching (%) 20 0.4 80-90

1 Data from Masarik, Economic Optimum Rate on a silt-loam soil, 2003

2 Data from Tri-State Water Quality Council, 2005 and EPA 625/R-00/008

Page 31: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

20 lbs

Comparing Land-use Impacts

36 lbs/ac x 20 acres = 720 lbs

16 mg/L

20 lbs/septic system x 1 septic systems = 20 lbs

1/36th the impact on water quality

0.44 mg/L

20 a

cre

s

20 a

cre

s

Assuming 10 inches of recharge -

Masarik, UW-Extension

Page 32: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Water table Stream

Water table Stream

36 lbs/ac x 20 acres = 720 lbs

20 lbs/septic system

Masarik, UW-Extension

Page 33: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

36 lbs 36 lbs 36 lbs 36 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

20 lbs 20 lbs 20 lbs 20 lbs

Using these numbers: 36 septic systems on 20 acres (0.55 acre lots) needed to

achieve same impact to water quality as 20 acres of corn

Comparing Land-use Impacts

36 lbs/ac x 20 acres = 720 lbs 20 lbs/septic system x 36 septic systems = 720 lbs

20 a

cre

s

20 a

cre

s

Masarik, UW-Extension

Page 34: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

720 lbsWater table S

tream

Water table Stream

720 lbs

36 lbs/ac x 20 acres = 720 lbs

20 lbs/septic system x 36 septic systems = 720 lbs

Masarik, UW-Extension

Page 35: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Impermeable bedrock

Runoff

Groundwater or Baseflow

Land-use effects on surface waters

Page 36: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 37: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 38: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

1/24/04

2/23/04

3/24/04

4/23/04

5/23/04

6/22/04

7/22/04

8/21/04

9/20/04

10/20/04

11/19/04

12/19/04

Date

0

4

8

12

16

Str

ea

mflo

w(c

fs)

0

0.4

0.8

1.2

1.6

2

Pre

cip

ita

tion

(i

n.)

Graph 1

Runoff

Baseflow

0

Fever River

Study

http://www4.uwsp.edu/cnr/watersheds/Reports_Publications/Reports/fever_07.pdf

Page 39: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

y = 0.5573x - 1092.8

R2 = 0.5154

0

5

10

15

20

25

1965.0 1970.0 1975.0 1980.0 1985.0 1990.0 1995.0

Year

Nit

rate

-N

Nitrate and age-dates of

groundwater discharge

features to Fever River

Page 40: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Impermeable bedrock

Groundwater flow

2 years

10 years

30 years

Masarik, UW-Extension

Groundwater Residence Time

Page 41: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 42: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 43: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years
Page 44: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

What UWEX Nutrient Guidelines

Do and Don’t Do:– Do save farmers money by ensuring

nitrogen is used efficiently

– Do allow farms to maximize profitability

while holding everyone accountable to some

standard

– Do prevent fields from being treated as

dumping grounds for manure and other bio-

solids

– Do help prevent excessively high

concentrations of nitrate in groundwater

– Don’t prevent nitrate from leaching into

groundwater

– Don’t ensure groundwater quality meets

drinking water standards

– Don’t ensure that groundwater quality in

areas that already apply at economic

optimum rates will get better over time

Page 45: Effects of Nutrient Management Practices on Water Quality• Nutrient management is a first step that allows us to stabilize nitrate concentrations in groundwater • May take years

Conclusions• Significant nitrate leaching can occur even

when nitrogen recommendations are

followed – no environmental optimum rate

• Better implementation of nutrient

management and crediting of N will help

reduce extreme nitrate concentrations in

groundwater

• Nutrient management is a first step that

allows us to stabilize nitrate concentrations

in groundwater

• May take years or decades for groundwater

quality to reflect changes in land-use

practices

• If the goal is safe drinking water, we would

need to go beyond nutrient management in

areas that are significantly degraded– Beyond nutrient management: Less nutrient

intensive crops, N reduction rotations, CRP,

perennial, grazing systems, slow-release

fertilizers?, cover crops?

Kevin MasarikCenter for Watershed Science and Education800 Reserve St.Stevens Point, WI [email protected]

Presentation can be found online at:www.uwsp.edu/cnr/watersheds