effective dates
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Hazard Communication 2013 Jonathan Roberts, MS, CSHO, GSP Oklahoma Department of Corrections Safety Administration Unit. Effective Dates. Benefits of understanding chemical hazards. Prevent injuries, deaths from: Violent chemical reactions, fires, explosions - PowerPoint PPT PresentationTRANSCRIPT
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Hazard Communication 2013
Jonathan Roberts, MS, CSHO, GSPOklahoma Department of CorrectionsSafety Administration Unit
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Effective DatesEffective
Completion Date Requirement(s) Who
December 1, 2013 Train employees on the new label elements and safety data sheet (SDS) format.
Employers
June 1, 2015
December 1, 2015
Compliance with all modified provisions of this final rule, except:
The Distributor shall not ship containers labeled by the chemical manufacturer or
importer unless it is a GHS label
Chemical manufacturers,
importers, distributors and employers
June 1, 2016 Update alternative workplace labeling and hazard communication program as necessary,
and provide additional employee training for newly identified physical or health hazards.
Employers
Transition Period to the effective
completion dates noted above
May comply with either 29 CFR 1910.1200 (the final standard), or the current standard, or
both
Chemical manufacturers,
importers, distributors, and employers
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Benefits of understanding chemical hazards
Prevent injuries, deaths from:• Violent chemical reactions, fires,
explosions• Burns, irritation, trouble breathing,
nausea, diseases
1a
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Benefits of understanding chemical hazards
Manufacturers, importers:•Classify chemical hazards•Provide labels, safety datasheets (SDSs)
1b
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Detecting hazardous chemicals in work areas
• Air monitoring equipment• Appearance, odor• Physical, chemical
characteristics • Unknown chemicals to be considered hazardous
2a
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Physical and health hazards
• Chemical manufacturers or importers must classify chemicals according to the physical and health hazards
• A chemical can have both physical and health hazards
3a
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Physical hazards:
1. Explosives2. Flammable gases3. Flammable aerosols4. Flammable liquids5. Flammable solids6. Oxidizing liquids7. Oxidizing solids8. Oxidizing gases9. Self-Reactive
substances
10.Pyrophoric liquids11.Pyrophoric solids12.Self-heating
substances13.Organic peroxides14.Corrosive to metals15.Gases under pressure16.Substances which, in
contact with water emit flammable gases
4a
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Physical hazards
• Pyrophoric gas - spontaneously ignites at 130°F or below
• Combustible dust - build-up can ignite if suspended in air in confined area• Grains, sugar• Charcoal, soot• Chemicals (sulfur)• Metals (magnesium, aluminum)• Plastics, resins
4b
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Health hazards
• Acutely toxicity• Skin corrosion or
irritation• Serious eye damage
or irritation• Respiratory or skin
sensitization• Germ cell mutagen
• Carcinogenicity• Reproductive toxin• Target organ
systemic toxin• Single exposure• Repeated exposure
• Aspiration hazard
5a
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Health hazards
Simple asphyxiant - displaces oxygen in the air to create an oxygen-deficient atmosphere that can lead to unconsciousness, death
5b
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Health hazards
Health effects:•Can occur rapidly after brief exposure (acute)•Long-term effects after prolonged, repeated exposure (chronic)
5c
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Protective control measures
• Engineering controls
• Administrative, work practice controls
7a
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Protective control measures
• Enclosing operations• Ventilation equipment• Substituting less hazardous
chemicals• Safer chemical handling
procedures
7b
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Personal protective equipment (PPE)• Used when hazards are not completely
controlled or eliminated by other control measures
• PPE selection based on hazard assessment and effectiveness of PPE
8a
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Personal protective equipment (PPE)• Chemical-resistant:
• Goggles• Face shields• Gloves• Boots• Coveralls• Aprons• Respirators
• Do not use damaged, malfunctioning PPE
8b
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First aid
• Read SDSs for first aid information before using chemical
• Report overexposures to any chemical
• Get prompt first aid, medical attention
10a
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First aid
Contact with corrosive, irritating chemicals:•Know locations of emergency eyewash, showers•Learn how to use eyewash, showers•Flush eyes/skin with water
10b
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First aid
Overexposure from breathing vapors, gases, aerosols, fumes, dust:•Move victim to safe area with fresh air•Get emergency medical assistance
10d
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First aid
Ingesting chemicals:• Call poison control center, emergency
medical responders• Have information from SDS available• Only induce vomiting or
give water if advised by a medical provider
10e
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Written HazCom program
OSHA’s HazCom standard includes requirements for:•Chemical classification•Safety data sheets (SDSs)•Labeling•Written HazCom program•Employee information, training•Provisions for trade secrets
11a
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Written HazCom program
Written HazCom program:•Labels, warnings•Safety data sheets (SDSs)•Employee information, training•List of hazardous chemicals•How employees learn hazards of non-routine tasks•Hazards of chemicals in unlabeled pipes
11b
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Labeling overview
• Labels warn of potential dangers
• Labels are not intended to be the sole source of information
• Labels serve as an immediate warning
• Containers need labels• Pipes, fuel tanks, engines are not
containers
12a
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Labeling overview
While HazCom 2012 is phased in, you will still see labels meeting previous rule:•Identity of hazardous chemical•Appropriate hazard warnings•Name and address of manufacturer, importer, or other responsible party
12d
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Labeling - shipped containers
• Product identifier (matches SDS and list)• Signal word (Danger = severe hazard;
Warning = less severe)• Hazard statement (based on hazard class
and category)• Pictogram (symbol to show hazard class)• Precautionary statement (safe use, storage)• Name, address, phone number of
manufacturer, importer, or responsible party to contact for emergency information
13a
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Labeling - shipped containers
13b
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Labeling - shipped containers
13c
Flame Over Circle
Flame
Flame Exploding Bomb
• Oxidizers • Flammables • Self-reactives • Pyrophorics • Self-heating • Emits flammable
gas • Organic peroxides
• Explosives • Self-reactives • Organic peroxides
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Labeling - shipped containers
13d
Skull and Crossbones Corrosion Gas Cylinder
• Acute toxicity(severe)
• Skin corrosion; burns
• Eye damage• Corrosive to
metals
• Gases under pressure
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Labeling - shipped containers
13e
Health Hazard Exclamation Mark Environmental
• Carcinogen • Respiratory
Sensitizer • Reproductive
Toxicity • Target organ
toxicity • Mutagenicity • Aspiration toxicity
• Irritant • Dermal sensitizer • Acute toxicity
(harmful) • Narcotic effects • Respiratory tract
irritation
• Environmentaltoxicity
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Labeling - shipped containers
OSHA-defined hazards - Simple asphyxiant: •No pictogram•Signal word = “WARNING”•Hazard statement = “May displace oxygen and cause rapid suffocation”
13f
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Labeling - shipped containers
OSHA-defined hazards - Combustible dust: •No pictogram•Signal word = “WARNING”•Hazard statement = “May form combustible dust concentrations in air”
13g
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Labeling - shipped containers
OSHA-defined hazards - Pyrophoric gas: •Flame pictogram•Signal word = “DANGER”•Hazard statement = “Catches fire spontaneously if exposed to air”
13h
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Labeling - in-house containers
• Rely on labels on shipped containers
• Re-label if label falls off• Re-label if label cannot be read
14a
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Labeling - in-house containers
Transferring hazardous chemicals to another container:•Must label container if another person will use it•Must label container if it is available during another shift
14b
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Labeling - in-house containers
Different system for in-house labels:•Product identifier•Words, pictures, symbols, or a combination of these, that provide at least general information on the hazards of the chemicals
14d
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Labeling - in-house containers
NFPA system identifies:•Health hazards - Blue•Flammability hazards - Red•Reactivity hazards - Yellow•Special hazards - White
Hazard severity (0 to 4):•0 = none•4 = severe
14e
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Labeling - in-house containers
HMIS system identifies:•Health hazards - Blue•Flammability hazards - Red•Physical hazards - Orange•Personal protection - WhiteHazard severity (0 to 4):•0 = minimal•1 = slight•2 = moderate•3 = serious•4 = severe
14f
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Safety data sheet (SDS)
• Chemical fact sheets• Provided by chemical
suppliers • Employer keeps them
up to date• Must be in English• Immediately available• Report missing SDSs
16a
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Safety data sheet (SDS)
Use:•Verify label information•PPE recommendations•Symptoms, health effects•First aid•Emergency procedures
16b
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Safety data sheet (SDS)
SDSs contain all Sections in orderSection 1 - Identification:•Product ID•Manufacturer name, address, phone number•Emergency phone•Recommended use•Restrictions on use
Section 2 - Hazard identification:•All hazards•Required label elements
17a
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Safety data sheet (SDS)
Section 3 - Composition:•Chemical name, synonyms•CAS number•Percentage of ingredients•Trade secret claims
Section 4 - First aid:•Required treatment for each route of exposure•Acute (immediate) symptoms, effects•Immediate, special treatments
17b
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Safety data sheet (SDS)
Section 5 - Fire fighting:•Extinguishing techniques•Extinguishing equipment•Hazardous combustion products
•Equipment, precautions for firefighters Section 6 - Accidental release:•Personal precautions•Protective equipment•Emergency procedures•Containment and cleanup methods
17c
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Safety data sheet (SDS)
Section 7 - Handling, storage:•Safe handling•Safe storage
•Incompatible materials Section 8 - Exposure control, Personal protection:•Permissible exposure limits (PELs)•Threshold limit values (TLVs), other exposure limits•Engineering controls•Personal protective equipment (PPE)
17d
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Safety data sheet (SDS)
Section 9 - Physical, chemical properties:•Chemical appearance•Odor, odor threshold•Physical properties (pH, flash point, flammability limits, vapor pressure and density, auto-ignition temp., decomposition temp., viscosity, etc.)
Section 10 - Stability, reactivity•Conditions to avoid•Incompatible materials•Hazardous decomposition products
17e
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Safety data sheet (SDS)
Section 11 - Toxicological information:•Routes of exposure•Immediate, chronic effects•Toxicity data•Carcinogenicity
Section 12 - Ecological information (non-mandatory):•Ecotoxicity•Biodegradability
17f
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Safety data sheet (SDS)
Section 13 - Disposal considerations (non-mandatory):•Waste description•Waste handling, disposal
Section 14 - Transport information (non-mandatory)•DOT shipping name, hazard class, packing group•UN number
17g
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Safety data sheet (SDS)
Section 15 - Regulatory information (non-mandatory):•Product-specific safety, health, environmental regulations
Section 16 - Other information:•Date of SDS’s preparation or last revision
SDS indicates if no relevant information is available within a Section
17h
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Material Safety Data Sheets (MSDS)
• Being replaced with SDSs
• MSDSs have no standardized format, but must include certain information
18a
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Use, Dispensing techniques
• Check label, SDS• Wear PPE• Operate ventilation• Take only what you need • Keep containers closed• Do not use near heat, sparks, open flames
19a
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Use, Dispensing techniques
• Mixing some chemicals can cause dangerous reactions
• Do not mix chemicals without instructions
• Do not re-use containers
19b
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Use, Dispensing techniquesChemical transfer precautions:•Wear PPE•Work in well-ventilated area•Use the proper container•Extra precautions for flammable liquids:
• Electrically ground and bond containers• Using non-sparking tools• Pump from vertical drum• Self-closing valve from horizontal drum
19c
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Chemical storage
• Prevent:• Spills• Chemical reactions • Fires
• Review SDS• Separate storage room, cabinet• Segregate incompatible
chemicals, compressed gas cylinders
20a
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Chemical disposal
• Regulated as hazardous waste• Collect and dispose of properly • Do not mix wastes without
instructions• Do not pour into a sewer, sink• Properly decontaminate tools
21a
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HazCom Summary
• Methods, observations to detect chemicals
• Information on physical, health, simple asphyxiation, combustible dust, pyrophoric gas, and other hazards not otherwise classified
• Safe work practices, emergency procedures, and PPE use
22a
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HazCom Summary
• Details of HazCom program:• Labels on shipped containers• Labeling used on in-house
containers• Safety Data Sheets and the
order of information
• Always ask for HazCom help if you have any questions
23a
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Contact Information
• Safety Administration Unit• Jonathan Roberts, MS, CSHO, GSP Phone: 405-425-7144
email: [email protected]
• Ronnie Aldridge Phone: 405-425-7143
email: [email protected]
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?QUESTIONS?