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    Dual Water Model

    Intellectual Property

    This presentation is sole the property

    of the INDONESIA TRAININGCENTRE.

    It is not to be duplicated or used byanyone other than the individual for

    personal use who has attended thecourse.

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    Dual Water Model

    Dual Water Model

    Schlumber er 1999

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    Dual Water Model

    Shale and Saturation

    The Archie equation has to be changed to takeaccount of the shale effect.

    The shale looks like low resistivity so anotherterm is added to the equations.

    The result is an equation which will can be usedto compute water saturation in shaly sands.

    All these equations return to Archies equation ifthere is no shale present.

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    Dual Water Model

    Saturation Equations

    Indonesia Equation

    Nigeria Equation

    Waxman-Smits Equation

    Dual Water Equation

    1

    Rt=

    Sw2

    F*Rw

    + BQvSw

    F*

    Ct = tmSwtn

    aCw +

    Swb

    SwtCwb Cw( )

    Sw = 1

    Vcl

    1Vcl2

    Rcl

    + eR

    w

    * 1

    Rt

    1

    Rt=

    Vcl1.4

    Rcl+

    em

    2

    aRw

    2

    Swn

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    Dual Water Model

    Saturation equations 2

    One of the difficulties is the number ofequations available for shaly sands.

    They are often country oriented, Nigeria,Venuzeula..

    The choice of equation was (is) dictated bylocal practice.

    Waxman-Smits (WS) and Dual Water(DW) approach the problem fromexperiments on the clay properties and are

    thus more realistic and universal.

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    Dual Water Model

    Dual water

    The Dual Water Model takes the basic work ofWaxman Smits and expands it for use with loggedinformation

    It divides the formation into solids and fluids.

    It splits the clay into dry clay and its associated

    water, called bound water

    The standard definitions for porosity andsaturation to describe the fractions of fluids in theformation are expanded to include the new model.

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    Dual Water Model

    Dual water model definitions

    hydrocarbon

    far

    water

    bound

    water

    dry

    clay

    clean

    matrix

    fluids

    solids

    unitvolume

    Vcl

    wet clayVdcl

    wb

    wf

    hyeffectiveporosity

    etotal

    porosity

    t

    = wf+ hy

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    Dual Water Model

    Clean to Shale

    t

    t

    t

    t

    Matrix

    Matrix

    Matrix

    Dry Colloid

    Dry Colloid

    Bound water

    Far Water

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    Dual Water Model

    Dual Water definitions 2

    the porosities are combined to give the saturations of thefluids present

    Swb = wb

    t

    Swf =

    wf

    t

    Shy =hy

    t

    wt = wf + wb

    t =e + wb = t1 Swb( )+ tSwb

    wt + hy =1

    Vcl = Vdcl + t wb

    saturation of bound water

    saturation of far water (this is Sw)

    Hydrocarbon saturation

    Total water saturation is the sum

    of the saturations of the two waters

    total water saturation plushydrocarbon saturation must beone

    wet clay volume includes the volume

    of bound water

    The total porosity is given by

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    Dual Water Model

    Simplified DWM

    Swt2

    =Rf

    t2Rt

    Archie Equation can be generalized into the following form;

    where;

    Swt - total water saturation

    ft - total porosity

    Rt - true formation resistivity

    Rf - resistivity of the water(s)

    The equation can be solved if Rf is known.

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    Dual Water Model

    Simplified DWM 2

    1) Clean water bearing zone

    Swt = 1

    t2Rt = Rf

    This is Rwf, the resistivity of Far water

    2) Clean 100% shale zone

    Swt = 1

    t2Rt = Rf

    This is Rwb, the resistivity of Bound water

    These are the two end points. To give a universalsolution they are combined linearly using thevolume of shale.

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    Dual Water Model

    Practical DWM 2

    Ct=

    t

    mSwt

    n

    aC

    wf+

    Swb

    Swt

    Cwb

    Cwf

    ( )

    The standard equation for the water saturationis expressed in terms of the conductivity, as it islinear.

    This equation is in terms of measured quantities,porosity and resistivity and parameters that canbe found, the far and bound water conductivities.

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    Dual Water Model

    DWM Saturation solution

    Swt =x + x2

    +CtF0

    Cw

    x = Swb Cw Cwb( )2Cw

    Fo = a m

    The solution to the equation is

    where

    and

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    Dual Water Model

    Practical outputs

    The equations give total water saturation Swtand total porosity t. These have to betransformed into effective saturation, Sw andeffective porosity, wf (or e)

    Sw = Swt Swb

    1 Swb

    wf = t Swt Swb( )

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    Dual Water Model

    Dual water equation solution

    This derivation of the Dual Water equations isvalid for any rock with any mixture of fluids

    It is possible to use the Dual Water Model tomake a manual computation of a shaly zone.

    However computer programs are bestequipped to handle the calculations.

    The selection of key parameters is essential toobtain the correct answers,

    Cwf - free water conductivity

    Cwb - bound water conductivity

    Swb - bound water saturation

    t - total porosity

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    Dual Water Model

    Rwa-GR crossplot

    10.00

    3.16

    1.00

    .32

    .10

    .03

    Hydrocarbon Sands

    FREQUENCY PLOT

    Shales

    Water Sands

    Gamma Ray API

    1500 30 60 90 120

    Rwb

    Rw

    R =wa

    tm

    aR

    t

    in clean zones R = Rwa w

    in shale zones R = Rwa wb

    Rwa

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    Dual Water Model

    Appendix

    This appendix contains a brief introduction to thebehaviour of clays in the formation.

    Full details are available in the relevant technicalpapers.

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    Dual Water Model

    Clays

    Clays are usually present as sheet like particles

    with very large surface areas compared to theirvolume

    There is an excess negative charge inside thesheet due to atoms with 3 units of positivecharge (e.g. Al) being substituted by atoms

    with 2 (e.g. Mg)The system is balanced by positive counterionson the surface of the clay sheets

    This is measured by the Cation ExchangeCapacity - CEC

    the units are milli-ion equivalent per 100gr ofdry clay material

    It is different for each clay type

    Montmorillonite - 1.00 meq/gr

    Illite - 0.20 meq/gr

    Kaolinite - 0.05 meq/gr

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    Dual Water Model

    Clay charge

    When the clays are immersed in water (as in areservoir)

    - the force keeping the counterions on the claysurface are reduced by the dielectric propertiesof the water

    - the counterions leave the clay surface- they move in a layer of water close to thesurface

    - they contribute to the electrical conductivityof the rock

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    Dual Water Model

    Diffuse layer

    The sodium ions (Na+) from the salt water areat a high concentration close to the clay surface

    This decreases until far away they reachequilibrium with the chlorine

    The negative chlorine (Cl-) behaves in theopposite sense

    The thickness of the layer where the positiveions are at a higher concentration is governedby the Gouy model and depends on the salinityof the water

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    Dual Water Model

    Exclusion Layer

    The simple situation is complicated by the finitesize of the molecules involved.

    There is a layer of water molecules adsorbed onthe clay surface and a shell around the sodiumion

    This gives a minimum thickness of the layer atthe Outer Helmholtz Plane of xH

    This distance at standard temperatures andpressures is 6.18 angstroms ()

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    Dual Water Model

    Diffuse layer thickness

    The diffuse layer thickness, xd has its minimumof xH at a water resistivity, Rw of 0.245 ohm-m(at standard temperature and pressure)

    Above this resistivity

    xd = xHwhere depends on the resistivity (salinity),i.e.

    = 1= , if Rw < 0.245 ohm-mxd

    xH