Download - Pvc formulation perstorp_eng 2014
Plasticizers for today and for the future
Perstorp contributes to a better more sustainable world by delivering innovative chemical solutions
PVC Formulation 2014, Düsselsdorf
Table of ContentsIntroduction of the companyPerstorp in PVC industryPlasticizers
– Investment– Emoltene™ 100 (DPHP, C10)– Pevalen™ (Polyolester plasticizer)
Summary
Perstorp in briefWorld leader in several sectors of the specialty chemicals market
Pioneer in formalin chemistry, plastics and surface materials
Perstorp was formed in 1881, over 130 years of winning formulas
Since December 2005 controlled by PAI partners,a leading European private equity company
Annual turnover of more than 10 billion SEK in 2012
About 1,500 employees in 22 countries
Production plants in Europe, Asia and North America
Sales offices in all major markets
Perstorp in the PVC industryFully integrated plasticizer producer based on the west coast of Sweden since 1980’sPerstorp exited the DOP business in 2012Storage facilities in UK, Belgium, Germany and Portugal to serve entire EuropeFocus on European market and sustainable growthMember of ECPI, VinylPlus and founding member of PlasticiserPlus
Perstorp believes in plasticizers Perstorp is making its largest investment in historyBased on our own technology and backwardly integrated in raw materialsIt will be on stream in Q1 2015Two plasticizers in the product tree, EmolteneTM 100 and PevalenTM
This investment will increase the production by 150,000 MT
EmolteneTM 100 PevalenTMInvestment for a moresustainable future
Established C10 (DPHP) GP plasticizer
Excellent versatility and flexibility
Expands lifespan of end products
High technical performance, with good outdoor properties
High performancepolyol ester plasticizer
Highly efficient in providing softness
Easy to process and use
Low volatility ensuring no VOC and consistent properties
New capacity for Valeraldehyde andits derivatives
Strengthen ourproduction platform
Fully integrated andsecure supply chain
Ability to offercompetitive and safe products
Innovativeplasticizer for sensitive applications
Flexible, versatile & safe
Versatile generalPVS plasticizer
Emoltene™ 100 and Pevalen™ focus on different markets
Emoltene™ 100 – Durable applications
Wire and cablesFilms & sheets e.g. roofing membranes, swimming pool liners, automotive foilsCoated fabrics; e.g. tarpaulinsAutomotive interiors
Pevalen™ – Sensitive applications
Coated fabrics; e.g. table cloths, protective clothingFilms & sheets; e.g. office materials, furniture foilsFlooringPlastisols; e.g. wallpaper, toysMoulded parts; e.g. grips
Key segments where Emoltene™ 100 is preferable
Cables & wires
Low volatility and high UV resistance with C10 plasticizer Well accepted for PVC cables at all major users
Automotive interior
Low volatility/migration of C10 plasticizers secures long life span required Plasticized PVC not easy substituted for this industry due to the advantage PVC has vs. other polymers
Film and sheets
Low volatility of C10 plasticizers secures long life span required Plasticized PVC good UV stability and outdoor resistance
Volatility
-25
-20
-15
-10
-5
0DPHP DINP DOP
Wei
ght
Cha
nge,
%
Emoltene™ 100 (DPHP) has low volatilityEmoltene™ 100 (DPHP) makes the product durable
Fogging
Emoltene™ 100 (DPHP) has lower foggingEmoltene™ 100 (DPHP) is suitable for car interiors
0
0,5
1
1,5
2
2,5
3
3,5
4
DPHP DINP DOP
mg
Migration to plasticsABS PC PS Acrylic
TOTM Polymeric Polymeric Polymeric
DPHP TOTM TOTM TOTM
DOTP DPHP DOTP DPHP
DEHP DINP DINP DINCH
DINCH DINCH DPHP DINP
DINP DOTP DEHP DOTP
Polymeric DEHP DINCH DEHP
DOA ATBC DOA DOA
ATBC DOA ATBC ATBC
Benzoate Benzoate Benzoate Benzoate
Source: www.filmandsheet.com, www2.teknorapex.com/PVC-Plasticizer-Migration
Emoltene™ 100 (DPHP) has low migration Emoltene™ 100 (DPHP) contributes with high permanency
Water absorption
0,29
0,3
0,31
0,32
0,33
0,34
0,35
0,36
DPHP DINP DOP
Wei
ght
Cha
nge,
%
Emoltene™ 100 (DPHP) has low water absorptionEmoltene™ 100 (DPHP) suitable for outdoor applications
Pevalen™A versatile general purpose plasticizer that is equal to or in some cases better than standard phthalate plasticizers.
Perstorp is increasing capacity and will meet customer demand. Perstorp will by 2015 be fully integrated in raw materials.
At this time, Pevalen™ will be commercially competitive to other high volume plasticizers.
The chemistry is well established and proven.
Process for food contact approval underway.
Easy storage
Pevalen™ has low viscosity even at temperatures below 0°CPevalen™ does not need to be heated during storage
0
0,5
1
1,5
2
2,5
-20 0 20 40 60 80
Vis
cosi
ty P
as
Temperature °C
Viscosity
Emoltene 100
DOTP
DOP
DINP
Dinch
Pevalen™
DINCH
Processing – top of the class
Pevalen™ has short dry blend timePevalen™ gives fast processing
h:01
h:01
h:01
h:01
h:01
h:01
DINCH DINP DOP DOTP Pevalen™
Tim
e (
mm
/ss)
Dry blend time
Unique product performance
79
80
81
82
83
84
85
86
87
88
0 5 10 15 20 25
Har
dnes
s (S
hore
A)
Volatility (% lost)
Effciency
DINCH
DINP
DOP
DOTP
Pevalen™
Pevalen™ has a unique combination of low volatility and high plasticizing efficiency
Migration to rubber
-022
-020
-018
-016
-014
-012
-010DINCH DINP DOP DOTP Pevalen™
(%)
Migration to rubber, 28 days
Pevalen™ has lower or equal migration to rubber
Migration to plastics
Pevalen™ has comparable migration to plastics Pevalen™ high compatibility to PVC is also shown here it has a tendency to migrate more to non-plasticized PVC
-020
-018
-016
-014
-012
-010
-008
-006
-004
-002
000PVC PC PS PMMA
Migration to plastics, 28 days
Pevalen™
DINCH
DOTP
Durability
Pevalen™ has very good resistance to chemicalsPevalen™ has same performance as other plasticizers on oil
-0.5
0.0
0.5
1.0
1.5
2.0
2.5
3.0
Heptane Hexane Olive Oil
Wei
ght
loss
%
Extraction chemicals and oil
DINCH
DINP
DOP
Pevalen™
DOTP
Durability
Pevalen™ has same or better resistance to water solution as other plasticizers
-0.1
-0.1
0.0
0.0
0.0
0.0
0.01 %Soap 1% NaOH
Wei
ght
loss
%
Extraction water solutions
DINCH
DINP
DOP
Pevalen™
DOTP
Summary PlasticizersEmoltene™ 100 – well-established HMW phthalate plasticizer
Available in high volumesHighly competitive production platformValued for low water absorption, low volatility and migrationReflected in improved durability, good outdoor resistance and long life span
Pevalen™ – an innovative polyol ester plasticizerHigh performance polyol ester plasticizerHighly efficient in providing softnessEasy to process and useLow volatility and migration ensuring no VOC and consistent properties
Thank You for your attention!Anders MagnussonApplication Specialist
For more information please contact:
Inna ScholzSales ManagerPhone: +48 22 405 1527Mobile: +48 69 504 8386e-mail: [email protected]