Download - OIL & GREASE CLEANER MATERIAL SAFETY DATA SHEETbennettgroup.ca/MSDS/data/Cement and Concrete... · GROUPE PERMACON 8145 Bombardier Ville d'Anjou (Qc.) Canada H1J 1A5 GROUPE PERMACON

GROUPE PERMACON8145 Bombardier

Ville d'Anjou (Qc.) CanadaH1J 1A5

GROUPE PERMACON GROUPune compagnie Oldcastle® an Oldcastle® company

8145 Bombardier, Ville d’Anjou (Quebec) - H1J 1A5 - Tél.: (514) 351-2120 - Fax : (514) 352-9802 - www.permacon.ca

OIL&GREASECLEANER MSDSRevisionDate(dd/mm/yyyy):27/05/2014 Page1of7

MATERIALSAFETYDATASHEET

SECTION1:IDENTIFICATIONProductidentifier :OIL&GREASECLEANER

ProductUse :Concretecleaner-Degreaser.ChemicalFamily :Alkalinemixture.

Supplier’snameandaddress: Manufacturer’snameandaddress:GROUPEPERMACONGROUP. RefertoSupplier8145BombardierVilled’Anjou,Quebec,CanadaH1J1A5InformationTelephone# :(514)351-2120ou1-888-PERMACON(TollFree)

24Hr.EmergencyTel#: :Chemtrec1-800-424-9300(WithinContinentalU.S.);Chemtrec703-527-3887(OutsideU.S.).

SECTION2-HAZARDSIDENTIFICATION

Classification :WHMISclassification:ClassE(CorrosiveMaterial).

OSHA:ThismaterialisclassifiedashazardousunderOSHAregulations(29CFR1910.1200).Hazardousclassification: AcuteHealthHazard.

EmergencyOverview :Cleargreenliquid.DANGER!CorrosiveCauseseye,skinanddigestivetractburns.Harmfulifswallowed.Maybeharmfulifinhaled.Causesrespiratorytractirritation.Containsmaterialwhichcancausedamagetothebloodsystem,theliverandthekidneys.

POTENTIALHEALTHEFFECTS:

Signsandsymptomsofshort-term(acute)exposureInhalation :Maycausesevereirritationtothenose,throatandrespiratorytract.Couldresultinpulmonaryedema(fluid

accumulation).Symptomsofpulmonaryedema(chestpain,shortnessofbreath)maybedelayed.Skin :Causesskinburns.Eyes :Causesburns.Symptomsmayincludeseverepain,blurredvision,rednessandcorrosivedamage.Ingestion :Maycausesevereirritationandcorrosivedamageinthemouth,throatandstomach.Symptomsmayinclude

severeabdominalpain,nauseaandvomiting.Ingestionoflargeramountsmaycausedefectstothecentralnervoussystem(e.g.dizziness,headache).

Effectsoflong-term(chronic)exposure:Prolongedorrepeatedcontactmaycausedrying,crackinganddefattingoftheskin. Repeatedabsorptionmaycausedisorderofcentralnervoussystem,liver,kidneysandblood.

Carcinogenicstatus :SeeTOXICOLOGICALINFORMATION,Section11.

Additionalhealthhazards :SeeTOXICOLOGICALINFORMATION,Section11.:SeeECOLOGICALINFORMATION,Section12.

Potentialenvironmentaleffects :SeeECOLOGICALINFORMATION,Section12.

SECTION3-COMPOSITION/INFORMATIONONINGREDIENTS

Ingredients CAS# Wt.%Alkylpolyglycolether 78330-20-8 5.00-10.00










Sodiumsilicate 1344-09-8 1.00-5.00Sodiumhexametaphosphate 68915-31-1 1.00-5.00

potassiumhydroxide 1310-58-3 1.00-5.00

SECTION4-FIRSTAIDMEASURES

Inhalation :Immediately remove person to fresh air. If breathing is difficult, give oxygen by qualifiedmedicalpersonnelonly.Ifbreathinghasstopped,giveartificialrespiration.Seekimmediate medicalattention/advice.

Skincontact :Removecontaminatedclothing.Flushaffectedskinwithgentlyflowinglukewarmwaterforatleast 20 minutes. Cover wound with sterile dressing. Do not rub area of contact. Washcontaminatedclothingbeforere-use.Seekimmediatemedicalattention/advice.Leatherandshoesthathavebeencontaminatedwiththesolutionmayneedtobedestroyed.

Eyecontact :Immediatelyflusheyesthoroughlywithrunningwaterforatleast20to30minutes. Protectunharmedeye.Seekimmediatemedicalattention/advice.

Ingestion :Donotinducevomiting.Havevictimrinsemouthwithwater,thengiveonetotwoglassesofwatertodrink.Seekimmediatemedicalattention/advice.Nevergiveanythingbymouthtoan unconsciousperson.

NotesForPhysician :Treatsymptomatically.

SECTION5-FIREFIGHTINGMEASURES

Firehazards/conditionsofflammability :Notflammableundernormalconditionsofuse.However,mayigniteifexposedtoextremeheatandflame.Closedcontainersmayrupture ifexposed toexcessheatorflamedue toa build-upofinternalpressure.

Flammabilityclassification(OSHA29CFR1910.1200):CombustibleLiquidClassIIIB.

Oxidizingproperties :None.Explosiondata:Sensitivitytomechanicalimpact/staticdischarge

:Notexpectedtobesensitivetomechanicalimpactorstaticdischarge.Suitableextinguishingmedia :Usewaterfogorfinespray,foams,carbondioxideordrychemical.Donotusewater

jet,asthismayspreadburningmaterial.Specialfire-fightingprocedures/equipment

:Firefightersshouldwearproperprotectiveequipmentandself-containedbreathingapparatuswithfullfacepieceoperatedinpositivepressuremode.Movecontainersfromfireareaifsafe todoso.Waterspraymaybeusefulincoolingequipmentexposedtoheatandflame.

Hazardouscombustionproducts :Carbonoxides;nitrogenoxides(NOx);metaloxides;formaldehyde;Phosphoruscompounds;otherunidentifiedorganiccompounds.

NFPARating :0-Minimal 1-Slight 2-Moderate 3-Serious 4-Severe Health: 3 Flammability: 1 Instability: 0 Special Hazards: None

SECTION6-ACCIDENTALRELEASEMEASURES

Personalprecautions :Restrictaccesstoareauntilcompletionofclean-up.Ensureclean-upisconductedbytrainedpersonnelonly.Individualsinvolvedinthecleanupmustwearappropriatepersonalprotectiveequipment.RefertoSection8,EXPOSURECONTROLSANDPERSONALPROTECTION,foradditionalinformationonacceptablepersonalprotectiveequipment.

Environmentalprecautions :Ensurespilledproductdoesnotenterdrains,sewers,waterways,orconfinedspaces.Spillresponse/cleanup :Removeallsourcesofignition.Ventilateareaofrelease.Stopthespillatsourceifitissafe

todoso.Containandabsorbspilledliquidwithnon-combustible,inertabsorbentmaterial(e.g.sand),thenplaceabsorbentmaterialintoacontainerforlaterdisposal(seeSection13).Dilutealkaliwithwaterandneutralizewithaceticacid(vinegar).Flushanyresidueinthespillareawithwater.Donotflushintosurfacewaterorsanitarysewersystem.Notifytheappropriateauthoritiesasrequired.

Prohibitedmaterials :Noneknown.










Specialspillresponseprocedures :Incaseofatransportationaccident,intheUnitedStatescontactCHEMTRECat1-800-424-9300or International at 1-703-527-3887. If a spill/release in excess of theEPA reportablequantityismadeintotheenvironment,immediatelynotifythenationalresponsecenterintheUnitedStates(phone:1-800-424-8002).USCERCLAReportablequantity(RQ):Potassiumhydroxide(1000lbs/454kg).

SECTION7-HANDLINGANDSTORAGE

SafeHandlingprocedures :Useonlyinwell-ventilatedareas.Wearsuitableprotectiveequipmentduringhandling.Avoidbreathingvapourormist.Avoidcontactwithskin,eyesandclothing.Washthoroughlyafterhandling.Keepawayfromacidsandotherincompatibles.Keepawayfromheat,sparks,andopenflames.Keepcontainerstightlyclosedwhennotinuse.

Storagerequirements :Storeinacool,dry,well-ventilatedarea.Storeawayfromincompatiblematerials.Storageareashouldbeclearlyidentified,clearofobstructionandaccessibleonlytotrainedandauthorized personnel.Inspectperiodicallyfordamageorleaks.Nosmokinginthearea.

Incompatiblematerials :Acids;Reducingagents;Oxidizingagents;Metals;Alkalies.Specialpackagingmaterials :Alwayskeepincontainersmadeofthesamematerialsasthesupplycontainer.

SECTION8-EXPOSURECONTROLSANDPERSONALPROTECTION

ExposureLimitsACGIHTLV OSHAPEL

Ingredients TWA STEL PEL STELAlkylpolyglycolether N/Av N/Av N/Av N/Av

Sodiumsilicate N/Av N/Av N/Av N/AvSodiumhexametaphosphate N/Av N/Av N/Av N/Av

potassiumhydroxide 2mg/m³(Ceiling) N/Av 2mg/m³(Ceiling) N/Av(finalrulelimit)

Ventilationandengineeringmeasures:Usegeneralorlocalexhaustventilationtomaintainairconcentrationsbelowrecommended exposurelimits.Ensureadequateventilation,especiallyinconfinedareas.

Respiratoryprotection :RespiratoryprotectionisrequirediftheconcentrationsexceedtheTLV.NIOSH-approved respirators are recommended.Advice should be sought from respiratory protectionspecialists.

Skinprotection :Imperviousglovesmustbewornwhenusingthisproduct.Adviceshouldbesoughtfromglovesuppliers.

Eye/faceprotection :Chemicalsplashgogglesmustbewornwhenhandlingthismaterial.Afullfaceshieldmayalso benecessary.

Otherprotectiveequipment :Wearachemicallyresistantapronandlongsleeveswhendispensing,topreventskincontact.Aneyewashstationandsafetyshowershouldbemadeavailable in theimmediateworking area.

Generalhygieneconsiderations :Avoidbreathingvapourormist.Avoidcontactwithskin,eyesandclothing.Donoteat,drinkor smoke when using this product. Upon completion of work, wash hands before eating,drinking,smokingoruseoftoiletfacilities.Removesoiledclothingandwashitthoroughlybeforereuse.Contaminatedworkclothingshouldnotbeallowedoutoftheworkplace.Keepworkingclothesseparately.

SECTION9-PHYSICALANDCHEMICALPROPERTIES

Physicalstate :liquid Appearance : Cleargreenliquid.Odour :N/Av Odourthreshold :N/AvpH :13.5Boilingpoint :90°C(194°F) Specificgravity : 1.06










Melting/Freezingpoint :N/Av Coefficientofwater/oildistributionVapourpressure(mmHg@20°C/68°F) :N/Av

:N/Av Solubilityinwater :Partiallysoluble.Vapourdensity(Air=1) :N/Av Evaporationrate(n-Butylacetate=1)

:N/AvVolatileorganicCompounds(VOC’s) :N/Av Volatiles(%byweight) :N/AvFlashpoint:>93.3°C(199.9°F)FlashpointMethod :closedcup Auto-ignitiontemperature :N/AvLowerflammablelimit(%byvol.) Upperflammablelimit(%byvol.)

:N/Av :N/AvFlameProjectionLength :N/Ap Flashbackobserved :N/Ap

SECTION10:STABILITYANDREACTIVITY

Stabilityandreactivity :Stable under the recommended storage and handling conditions prescribed. Contact withmetalsmayreleasesmallamountsofflammablehydrogengas.

Hazardouspolymerization :Hazardouspolymerisationdoesnotoccur.Conditionstoavoid :Avoidheatandopenflame.Avoidcontactwithincompatiblematerials.MaterialsToAvoidAndIncompatibility :Incompatiblematerials(seeSection7).Hazardousdecompositionproducts :Noneknown,refertohazardouscombustionproductsinSection5.

SECTION11-TOXICOLOGICALINFORMATION

Targetorgans :Eyes,skin,respiratorysystemanddigestivesystem.Routesofexposure :Inhalation: YES Skin Absorption: NO Skin & Eyes: YES Ingestion: YESToxicologicaldata :Seebelowforindividualingredientacutetoxicitydata.

LC50(4hr) LD50

Ingredients inh,rat (Oral,rat) (Rabbit,dermal)Alkylpolyglycolether N/Av 2030mg/kg N/Av

Sodiumsilicate N/Av 1960mg/kg >4640mg/kgSodiumhexametaphosphate N/Av 3053mg/kg N/Av

potassiumhydroxide N/Av 205mg/kg >1260mg/kg

Carcinogenicstatus :NocomponentsarelistedascarcinogensbyACGIH,IARC,OSHAorNTP.Reproductiveeffects :Notexpectedtohaveotherreproductiveeffects.Teratogenicity :Notexpectedtobeateratogen.Mutagenicity :Notexpectedtobemutagenicinhumans.Epidemiology :Notavailable.Sensitizationtomaterial :Notexpectedtobeaskinorrespiratorysensitizer.Synergisticmaterials :Notavailable.Irritancy :Corrosive.Otherimportanthazards :Noneknown.Conditionsaggravatedbyoverexposure

:Pre-existingskin,eyeandrespiratorydisorders.

SECTION12-ECOLOGICALINFORMATION

Ecotoxicity :No data is available on the product itself. The product should not be allowed to enter drainsorwatercourses,orbedepositedwhereitcanaffectgroundorsurfacewaters.

Mobility :Nodataisavailableontheproductitself.










Persistence :Nodataisavailableontheproductitself.Bioaccumulationpotential :Nodataisavailableontheproductitself.OtherAdverseEnvironmentaleffects :Nodataisavailableontheproductitself.

SECTION13-DISPOSALCONSIDERATIONS

HandlingforDisposal :SeeSection7(HandlingandStorage)forfurtherdetails.MethodsofDisposal :Dispose in accordance with all applicable federal, state, provincial and local regulations.

Contactyourlocal,state,provincialorfederalenvironmentalagencyforspecificrules.RCRA :Ifthisproduct,assupplied,becomesawasteintheUnitedStates,itmaymeetthecriteriaof

ahazardouswasteasdefinedunderRCRA,Title40CFR261.Itistheresponsibilityofthewastegeneratortodeterminetheproperwasteidentificationanddisposalmethod.

SECTION14:TRANPORTINFORMATION

Regulatory UNNumber ShippingName Class Packing LabelInformation Group

TDG UN1760 CORROSIVELIQUID,N.O.S. 8 III(Potassiumhydroxide)

TDG MaybeshippedasaLimitedQuantitywhentransportedincontainersnolargerthan5.0L,incombinationpackagingsAdditional nolargerthan30kggrossmass.information

49CFR/DOT UN1760 CORROSIVELIQUID,N.O.S. 8 III(Potassiumhydroxide)

49CFR/DOT MaybeshippedasaLimitedQuantitywhentransportedincontainersnolargerthan5.0L,incombinationpackagingsAdditional nolargerthan30kggrossmass.information

SECTION15-REGULATORYINFORMATION

USFederalInformation:TSCA:AlllistedingredientsappearontheToxicSubstancesControlAct(TSCA)inventory.

CERCLAReportableQuantity(RQ)(40CFR117.302):Potassiumhydroxide(1000lbs/454kg).

SARATITLEIII:Sec.302,ExtremelyHazardousSubstances,40CFR355:NoExtremelyHazardousSubstancesarepresentinthismaterial.

SARATITLEIII:Sec.311and312,MSDSRequirements,40CFR370HazardClasses:Immediate(Acute)healthhazard;ChronicHealthHazard.UnderSARASections311and312, theEPAhasestablished thresholdquantities for thereportingofhazardouschemicals.Thecurrentthresholdsare500poundsforthethresholdplanningquantity(TPQ),whicheverislower,forextremelyhazardoussubstancesand10,000poundsforallotherhazardouschemicals.

SARATITLEIII:Sec.313,ToxicChemicalsNotification,40CFR372:ThismaterialisnotsubjecttoSARAnotificationrequirements,sinceitdoesnotcontainanyToxicChemicalconstituentsabovedeminimusconcentrations.USStateRighttoKnowLaws:CaliforniaProposition65:Tothebestofourknowledge,thisproductdoesnotcontainanychemicalsknowntotheStateofCaliforniatocausecancerorreproductiveharm.OtherU.S.State“RighttoKnow”Lists:ThefollowingchemicalsarespecificallylistedbyindividualStates:Potassiumhydroxide(CA,MA,MN,NJ,PA,RI).InternationalInformation:CanadianEnvironmentalProtectionAct(CEPA)information:AllingredientslistedappearontheDomesticSubstancesList(DSL).










This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the information required by the CPR.

SECTION16-OTHERINFORMATION

HMISRating :*-Chronichazard0-Minimal1-Slight2-Moderate3-Serious4-SevereHealth: *3 Flammability: 1 Reactivity: 0

Legend :ACGIH:AmericanConferenceofGovernmentalIndustrialHygienistsCA:CaliforniaCAS:ChemicalAbstractServicesCERCLA:ComprehensiveEnvironmentalResponse,Compensation,andLiabilityActof1980CFR:CodeofFederalRegulationsDOT:DepartmentofTransportationEPA:EnvironmentalProtectionAgencyEST:EasternStandardTimeHMIS:HazardousMaterialsIdentificationSystemHSDB:HazardousSubstancesDataBankIARC:InternationalAgencyforResearchonCancerInh:InhalationMA:MassachusettsMN:MinnesotaMSHA:MineSafetyandHealthAdministrationN/Ap:NotApplicableN/Av:NotAvailableNFPA:NationalFireProtectionAssociationNIOSH:NationalInstituteofOccupationalSafetyandHealthNTP:NationalToxicologyProgramOSHA:OccupationalSafetyandHealthAdministrationPA:PennsylvaniaPEL:PermissibleexposurelimitRCRA:ResourceConservationandRecoveryActRI:RhodeIslandRTECS:RegistryofToxicEffectsofChemicalSubstancesSARA:SuperfundAmendmentsandReauthorizationActSTEL:ShortTermExposureLimitTDG:CanadianTransportationofDangerousGoodsAct&RegulationsTLV:ThresholdLimitValuesTSCA:ToxicSubstanceControlActTWA:TimeWeightedAverageWHMIS:WorkplaceHazardousMaterialsIdentificationSystem

References :1.ACGIH,ThresholdLimitValuesandBiologicalExposureIndicesfor2009.2. InternationalAgencyforResearchonCancerMonographs,searched2009.3. CanadianCentreforOccupationalHealthandSafety,CCInfoWebdatabases,2009(Chempendium,HSDBandRTECs).4. MaterialSafetyDataSheetfrommanufacturer.5. CaliforniaProposition65List-September11,2009version.









OIL&GREASECLEANERMSDSRevisionDate(dd/mm/yyyy):27/05/2014 Page7of7

Preparedfor:GROUPEPERMACONGROUP8145Bombardier,Villed’Anjou,Quebec,CanadaH1J1A5Phone.:(514)351-2120ou1-888-PERMACON(TollFree)PleasedirectallinquiriestoGroupePermaconGroup.

Preparedby:ICCTheComplianceCenterInc.Canada: 1-888-977-4834USA: 1-888-442-9628http://www.thecompliancecenter.com

DISCLAIMEROFLIABILITYThisMateiralSafetyDataSheet(MSDS)waspreparedbyICCTheComplianceCenterInc.usinginformationprovidedbyGroupePermaconGroupandCCOHS’Web InformationService.The information in theMaterialSafetyDataSheet isoffered foryourconsiderationandguidancewhenexposedtothisproduct.ICCTheComplianceCenterIncandGroupePermaconGroupexpresslydisclaimallexpressedorimpliedwarrantiesandassumenoresponsibilitiesfortheaccuracyorcompletenessofthedatacontainedherein.ThedatainthisMSDSdoesnotapplytousewithanyotherproductorinanyotherprocess.

ThisMaterialSafetyDataSheetmaynotbechanged,oralteredinanywaywithouttheexpressedknowledgeandpermissionofICCTheComplianceCenterInc.andGroupePermaconGroup.MSDSPreparationDate(dd/mm/yyyy)

:04/01/2011MSDSReviewedDate(dd/mm/yyyy)

:27/05/2014RevisionNo. :4

RevisionInformation :Sections2and3,switched. (M)SDSsectionsupdated:

2. HAZARDSIDENTIFICATION;3. COMPOSITION/INFORMATIONONINGREDIENTS;5. FIRE-FIGHTINGMEASURES;8. EXPOSURECONTROLS/PERSONALPROTECTION;9. PHYSICALANDCHEMICALPROPERTIES;11. TOXICOLOGICALINFORMATION;12. ECOLOGICALINFORMATION;15. REGULATORYINFORMATION.

ENDOFDOCUMENT





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