Mirasil ® Siliconesfor Personal Care
2
Index� Silicones in Bluestar Silicones
• Synthesis …… 3• 4 different chemistries …… 4• What are silicones? Structure, properties …… 5-8
� Personal care range: Mirasil Brand• Brand name & INCI …… 9• Mirasil CM 5 …… 10• Mirasil HMS …… 11• Mirasil DM 50 to DM 5000 …… 12• Mirasil DM 60 000 to DM 500 000 …… 13• Mirasil ADM 211 / ADM 403 …… 14• Mirasil ADMH 395 / ADMH 3900 …… 15• Mirasil ADMH B100 …… 16• Mirasil ADME-P …… 17• Mirasil ADM-E 235C / ADM-E 257C (In development) …… 18• Mirasil ADMH-E 125 …… 19• Mirasil DMCO …… 20• Mirasil C-DMP …… 21• Mirasil C-DM / C-DMB …… 22• Mirasil C-DML …… 23• Mirasil D-DML …… 24• Mirasil PTM …… 25• Mirasil C-DPDM / P-DPDM …… 26• Mirasil Bright …… 27• Mirasil Micropearl 40 …… 28
� Technical and documental support …… 29
3
� Si : silicon the highest concentration on earth after oxygen
2+SiO C Si
polymerization
+Si
CH3
CH3
Cl Cl H2O
3
siloxanes
Si O Si
CH3CH3
CHCH3high Mw
� Hydrolysis
3chlorosilanes
+Si ClCH3 Si
CH3
CH
Cl Cl
� Bluestar direct synthesis
Silicone Synthesis
4
Methylchlorosilanes (MCS)
Intermediates (Cyclics, gums, D5, DM... )
Performanceconcentrates
Emulsions RTV HCR/LSR
silicium
methanol
silica
HCl
Great intermediates
Fine Chemistry
Chemical Specialities &Formulations
Mix & FixCenters®
MeCl
Marketing & Taylor-made
solutions
4 different chemistries
5
What are Silicones?
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3109°°°°
140°°°°
CH3H3C
Inorganic siloxane backbone with methyl/organic pendant groups
-Si-O-Si-O- -CH3
Polydimethylsiloxane polymer “ DIMETHICONE ”
� Various chemical substitutions: phenyl, alkyl,amino, polyether functionalities
6
PROPERTIES
Thermal stability
Resistance to naturalageing
Lubricating and softeningproperties
Exceptionally harmless
Permeable to gas
Spredability
Dielectric properties
Modular hydrophobic andorganophobic properties
Good fire resistance
Modular from release toadhesion
Creativity of the World of Organics (O)
Strength of the Mineral (Si)Strength of the Mineral (Si)
What makes Silicones original
•
•
•
•
•
•
•
••
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High spreadingEasy wetting
Low intermolecular forces
HydrophobicityOrientates at surface
Low surface tension
Various viscosityWide range of Polymer length
Non occlusivity
Highly polar & strongintermolecular forces
Water resistance
Barrier effect
Spreads easily
Lubricates hair and skin
Low thermal sensitivity
Flexibility of polymer chain
Stability
Minimises pore clogging
Various effect intensity
Properties BenefitsStructure
A unique structure various benefits
Methyl groups
Siloxane chain
Mirasil ®
Product range
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Brand names & INCI
CM 5
ADME-P
DM 50 - 5000
DMCO
High purity products
Emulsions
Dimethicones
HMS
C-DMP
DM 60000 - 500000
MIRASIL PRODUCTS PRODUCT INCI
Dimethicones Copolyols
Cyclopentasiloxane
Water (and)amodimethicone (and) Trideceth-6
Dimethicone
PEG/PPG 22/24 Dimethicone
Hexametildisiloxane
Cyclopentasiloxane (and) PEG/PPG-18/18-Dimethicone
Dimethicone
C-DMC-DMB
PTM
Performance concentrates
C-DPDM
D-DMLD-DML LV & HV
Phenyl functional silicone
P-DPDM
Cyclopentasiloxane (and) Dimethicone Cyclopentasiloxane (and) Dimethiconol
Phenyl TrimethiconeCyclopentasiloxane (and) DiphenylDimethicone
Dimethicone (and) Dimethiconol
Phenyl Trimethicone (and) DiphenylDimethicone
C-DMLC-DML LV & HV
PRODUCT INCI
ADMH-E 125 Water,propoxytetramethylpiperi-dinyldimethicone (and) Trideceth-6
ADM 211 Amodimethicone ADM 403 Amodimethicone
ADMH 395ADMH 3900
ADMH B100
Amino functional silicone
PropoxytetramethylpiperidinylDimethicone
C15-19 alkane (and) Propoxytetramethyl-piperidinyldimethicone
ADM-E 235CWater (and) amodimethicone (and) Trideceth-12 (and) Cetrimonium chloride
BRIGHT C15-19 alkane (and) DiphenylDimethicone
Powder resin Micropearl 40 Polymethylsilsesquioxane
Indevelopment
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INCI: Cyclopentasiloxane
Mirasil CM 5
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
Features CharacteristicsAdvantages in
formulationCosmetic benefits
Uselevels
����High purity ����Decamethylcyclopentasiloxane > 97.0%����Octamethylcyclotetrasiloxane < 0.9%����Decamethylcyclopentasiloxane + Dodecamethylcyclohexasiloxane >99.7%
����Medium volatile fluid
����Appearance……… .. Clear liquid
����Viscosity (mm 2/s) …………..... 3.9
����Specific gravity (kg/m 3) ……...950
����Refractive index ………… ... 1,395
����Flash point (ºC)……………… ... 80
����Surface tension (mN/m)…… .18,3
����Transient carrier for actives delivery
����Improves pigment distribution
����Excelent spreading properties
����Non comedogenic emolient
����Soft, dry skin feel
1%to
10%
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INCI: Hexamethyldisiloxane
Mirasil HMS
(CH3)3Si-O-Si(CH3)3
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
����Not greasy volatile carrier
����Appearance………… .. Clear liquid
����Viscosity (mm2/s) ………… .... 0.65
����Specific gravity (kg/m 3) ….…...760
����Refractive index ………… .. . 1,375
����Flash point (ºC)…………… .……- 5
����Surface tension (mN/m)…… ..15,3
����Improves spreading properties
����Improves pigment distribution
����Excellent spreading properties
����Leaves no residue
����Soft, dry skin feel
0,1%to8%
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INCI: Dimethicone
Mirasil DM 50 to DM 5 000
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
H3C CH3( )n
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Linear polydimethylsiloxane fluids with medium molecular weight
Viscosity: 50 to 1 000 mm 2/s
����Appearance………… .. Clear liquid
����Specific gravity (kg/m 3) ……....970
����Refractive index ………… .. . 1,403
����Flash point (ºC)…………… ...…300
����Surface tension (mN/m)……… ..21
Compatibility(with cosmetic ingredients)
���� Skin care: skin protection and softness
���� Sun care: water resistance
���� AP DEO: detackification
0,5%to
15%
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INCI: Dimethicone
Mirasil DM 60 000 to DM 500 000
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
H3C CH3( )n
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
High molecular weight linear polydimethylsiloxane
Visco: 60000-500000 mm 2/s
����Appearance………… .. Clear liquid
����Specific gravity (kg/m 3) ………978
����Refractive index ………… ... . 1,410
����Flash point (ºC)…………… ...…300
����Surface tension (mN/m)……… ..21
Compatibility(with cosmetic ingredients)
���� Skin care: smooth and silky feel
���� Sun care: water resistance
���� Hair care: high conditioning
1%to
15%
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INCI: Amodimethicone
Mirasil ADM 211 & ADM 403
A = -O-CH3
B =-(CH2)3-NH (CH2)2-NH2
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Two different offers
���� ADM 211 v= 1 000 mm 2/s amine content= 12 - 17 meq/100g
���� ADM 403 v= 300 mm 2/s amine content= 25 - 35 meq/100g
����Appearance… .…. Yellowish liquid
����Specific gravity (kg/m 3) …...…..974
����Refractive index ………… ...... 1,405
����Flash point (ºC)…………… .….. 104
����Clear products
���� Easy to handle
���� Color and heat protection
���� Improves wet and dry combing
���� Great cosmetic feel
Hair care:
0,5%to3%
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INCI: Propoxytetramethylpiperidinyl Dimethicone
Mirasil ADMH 395 & ADMH 3900
�Patented Bluestar Silicones technology
HALStechnology
A = -CH3
B = HALS
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
(CH2)3 O NH
CH3
CH3
CH3
CH3
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
���� HALS structure
Two different viscosities ���� ADMH 395 (10 000 mPa.s) ���� ADMH 3900 (90 000 mPa.s)
����Appearance… .…. Yellowish liquid����Color (Hazen) …………… ...... < 125����Specific gravity (kg/m 3) …...…..975����Refractive index ………… ..... 1,395����Flash point (ºC)…………… .….. 104����Amine content (meq/100g)…17-21
����Clear products
���� No yellowing formulations
���� Color protection
���� Improves wet and dry combing
���� Great cosmetic feel
���� Protection against oxidative stress
Hair care:
0,5%to3%
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INCI: C15-19 alkane (and) PropoxytetramethylpiperidinylDimethicone
Mirasil ADMH B100
HALStechnology
A = -CH3
B = HALS
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
(CH2)3 O NH
CH3
CH3
CH3
CH3
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
���� Blend C15-C19 alkane & ADMH 3900 (50:50)
���� Viscosity = 2 000 mPa.s
����Appearance… .…. Yellowish liquid����Color (Hazen) …………… ........ < 50����Specific gravity (kg/m 3) …...…..883����Refractive index ………… ..... 1,428����Flash point (ºC)…………… .…...124����Amine content (meq/100g)..…8-11
���� Low volatility
���� Compatible with cosmetics ingredients
���� Anti-radical and antioxidant
���� Color protection
���� Silky and pleasant touch
���� Friendly product
Skin care:
1% - 5%
Hair care:
1% - 3%
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INCI: Water (and) Amodimethicone (and) Trideceth-6
Mirasil ADME-P
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
A = -O-CH3
B = -(CH2)3-NH-(CH2)2-NH2
Amodimethicone :
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Non ionic micro-emulsion(25 nm particle size)
Silicone content: 27%
����Appearance… .…. Colouless liquid
����Specific gravity (kg/m 3) …..…...995
����pH ………………………..…........ 6-8
����Amine content (meq/100g)...…9-12
����Clear products
���� Simple addition and mixing to water based formulations
���� Color protection
���� Improves wet and dry combing
���� Imparts soft feel
Hair care
2%to
10%
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INCI: Water (and) Amodimethicone(and) Trideceth-12 (and) Cetrimonium chloride
Mirasil ADM-E 235C
A = -O-CH3
B = T-(CH2)3-NH (CH2)2-NH2
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
Amodimethicone :
Features Advantages in formulation Cosmetic benefits Use levels
Cationic emulsion ofan amine-functional siliconepolymer.� MIRASIL ADM-E 235 C
(35% of silicone content)
Conditioner :
2% - 5 %
Styling:
0,5% - 5%
� Provide soft feel to dry hair
� Reduce combing time on wethair
� Very good conditioning additive
� Developed as a conditioningadditive for hair care.
� Simple addition and mixingto water based formulations
InDevelopment
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INCI: Water (and) Propoxytetramethylpiperidinyl Dimethicone(and) Trideceth-6
Mirasil ADMH-E 125
A = -CH3
�Patented Bluestar Silicones technology
B = HALS
A Si
CH3
CH3
O Si O A
CH3
CH3
SiO
B
CH3
Si
CH3
CH3 mn
(CH2)3 O NH
CH3
CH3
CH3
CH3
Propoxytetramethylpiperidinyldimethicone :
HALStechnology
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
���� HALS structure
Non ionic micro-emulsion(25 nm particle size)
Silicone content: 25%
����Appearance… .…. Yellowish liquid
����Specific gravity (kg/m 3) …...…..995
����pH ………………………….......... 5-7
����Amine content (meq/100g)….…5-7
����Clear products
����No yellowing formulations
���� Simple addition and mixing to water based formulations
���� Color protection
���� Improves wet and dry combing
���� Great cosmetic feel
���� Protection against oxidative stress
Hair care
2%to
10%
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INCI: PEG/PPG 22/24 Dimethicone (DMCO)
Mirasil DMCO
y
Si O
Me
Me
Si O
Me
(OE)e
(OP)p
Me3SiO SiMe3
x
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
����Water soluble or water dispersable silicone polyethers
����Appearance……… .... Limpid liquid����Viscosity (mm 2/s) ……………. 1800����Specific gravity (kg/m 3) …...…1036����Refractive index …………… ... 1,446����Flash point (ºC)……………… .... 180����pH, 10% in water……………… .. 5,5
����Inverse solubility above cloud point temperature
����Low surface tension may increase deposition of other conditioning agent
���� Shampoos: reduce eyes irritation
���� Allow to formulate clear product
0.5%to3%
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INCI: Cyclopentasiloxane (and) PEG/PPG 18/18 Dimethicone
Mirasil C-DMP
y
Si O
Me
Me
Si O
Me
(OE)e
(OP)p
Me3SiO SiMe3
x
10% PEG/PPG 18/18 Dimethicone dispersed in D5
Inverse emulsifier Water in D5
Features Characteristics Advantages in formulation Cos metic benefits
����Delivery system for emolients, moisterizers, sunscreens, antiperspirant actives and pigments
����Gives stable water in silicone formulations
����Appearance… Slightly grey liquid
����Viscosity (mm 2/s) …………….< 100
����Specific gravity (kg/m 3) …,...… 956
����Non volatil content (%)……… . 10,5
����Flash point (ºC)……………… .... >77
����Allows formulation flexibility
����Clear W/S emulsion technology possible
���� Delivery system for both non polar (oil phase) and polar ingredients (water phase)
���� Wide range of Personal Care applications
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INCI: Cyclopentasiloxane (and) Dimethicone (C-DM / C-DMB)
Mirasil C-DM & Mirasil C-DMB
( )n
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
CH3 CH3Dimethicone:
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Solution of high molecular weight of dimethicone
Two different offers,
���� C-DM v= 3 500mPa.s , solid content = 30%
���� C-DMB v= 6 000mPa.s , solid content = 15%
����Appearance……… .…. Clear liquid
����Specific gravity (kg/m 3) …..…...960
����Refractive index ………… ..... 1,400
����Flash point (ºC)…………… .….. >77
����Surface tension (mN/m)……… .. 16
Easy to handle blend
���� Skin care: smooth dry feel on skin
���� Sun care: long lasting
���� Hair care: soft and silky feel
3%to
10%
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INCI: Cyclopentasiloxane (and) Dimethiconol
Mirasil C-DML
( )nSi
OSi
OSi
OSi
OSi
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
HO OHDimethiconol:
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Solution of high molecular weight of dimethiconol
Three different offers,
���� C-DML v= 6 000 mPa.s, solid content=15%
���� C-DML HV - C-DML LV v= 8 000mPa.s - v= 1 500 mPa,s
����Appearance……… .…. Clear liquid
����Specific gravity (kg/m 3) …..…...960
����Refractive index ………… ..... 1,400
����Flash point (ºC)…………… .….. >70
Easy to handle blend
���� Skin care: smooth dry feel on skin
���� Sun care: long lasting
���� Hair care: soft and silky feel
3%to
10%
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INCI:Dimethicone (and) Dimethiconol (D-DML)
Mirasil D-DML
( )nSi
OSi
OSi
OSi
OSi
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
HO OH
Dimethiconol:
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Solution of high molecular weight of dimethiconol
Three different offers,
���� D-DML v= 6000 mPa.s,
���� D-DML HV - D-DML LV v= 9 000mPa.s - 1 500 mPa.s,
����Appearance……….…. Clear liquid
����Specific gravity (kg/m 3) …..…...960
����Refractive index …………..... 1,400
����Flash point (ºC)……………..... >130
Easy to handle blend
���� Skin care: smooth dry feel on skin
���� Sun care: long lasting
���� Hair care: soft and silky feel
3%to
10%
25
INCI: Phenyl Trimethicone
Mirasil PTM
[(CH3)3Si-O]3-Si-C6H5
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
����Easily emulsified gloss agent ����Resistant to oxidation
����Appearance………… ... Clear liquid
����Viscosity (mm 2/s) ………….…… 22
����Specific gravity (kg/m 3) …...… 990
����Refractive index …………… . 1,459
����Flash point (ºC)…………… .… > 100
����Surface tension (mN/m)……… .. 21
����Easy to incorporate
����SPF booster in sun care formulations
���� gloss���� softness���� reduces tackiness
0,5%to5%
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INCI: Cyclopentasiloxane (and) Diphenyl Dimethicone (C-DPDM)Phenyl Trimethicone (and) Diphenyl Dimethicone (P-DPDM)
Mirasil C-DPDM & Mirasil P-DPDM
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
( )n( )p CH3H3C
C6H5
C6H5
Diphenyl Dimethicone
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
Blend of high molecular weight Diphenyl Dimethicone
Two differnt offers,
���� C-DPDM v = 2 000 mPa.s, solid content = 15%
���� P-DPDM v =12 000 mPa.s, diphenyldimethicone content = 18%
����Appearance………… ... Clear liquid
����Specific gravity (kg/m 3) …...… 960
����Refractive index …………… . 1,460
����Flash point (ºC)…………… ...… > 75
����Easy to incorporate
����Good compatibility with vegetable oils
���� Skin care: unique silky feel
���� Sun care: water resistant
���� Hair care: antistatic and gloss effects
2%to
10%
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INCI: C15-19 alkane (and) Diphenyl Dimethicone
Mirasil BRIGHT
SiO
SiO
SiO
SiO
Si
CH3 CH3 CH3 CH3 CH3
CH3 CH3 CH3 CH3 CH3
( )n( )p CH3H3C
C6H5
C6H5
Diphenyl Dimethicone
Features Characteristics Advantages in formulation Cos metic benefitsUse
levels
���� Blend of high molecular weight Diphenyl Dimethicone
���� High refractive index
Diphenyldimethicone content: 20%
����Appearance………… ... Clear liquid
����Viscosity (mm 2/s) ………….…1 500
����Specific gravity (kg/m 3) …...… 838
����Refractive index …………… . 1,442
����Flash point (ºC)…………… ...… 124
���� Compatible with cosmetic ingredients:pigments and SPF
���� Easy to use
���� Provide hair shine
���� Film barrier protection
���� Anti-humidity effect long lasting
���� Non sticky effect
0,5%to5%
28
INCI: Polymethylsilsesquioxane
Mirasil Micropearl 40
����Highly pure sphericalsilicone resin particles
����3 dimension network
Features Cosmetic benefitsAdvantages in formulationUse
levelsCharacteristics
����Physical form……… Spherical����Color ……………… ........ White����Specific gravity (kg/m3) ..1300����Refractive index ……… .. 1,43����Particle size (micra)…… ... 4����pH……………………….… 5 - 9
���� Easy and uniformdispersion in cosmeticformulations
� Water repellence� Excelent lubricity� Soft focus effect� Non greasy touch
0,2to5
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Technical and documental support
� Mirasil brochure
� TDS and MSDS available for all Mirasil references
� Attestation Ingredient status of Bluestar Silicones Cosmetic Raw Material for all the Mirasil references (ongoing)
� R&D organization • Design labs in St. Fons (France)
• Technology oriented labs • Projects for new silicones
• Technical service lab in Sta. Perpetua (Spain)• Market and application oriented lab • Support to the existing range
� Mirasil samples kits
� Bluestar Silicones for Personal Care: www.bluestarsilicones.com