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Page 1: ChemInform Abstract: Asymmetric Synthesis of (2R,3S)-2,3-Epoxyamides via Camphor-Derived Sulfonium Ylides

1999 oxirane derivatives

oxirane derivativesR 0030

22 - 108Asymmetric Synthesis of (2R,3S)-2,3-Epoxyamides via Camphor-Derived Sulfonium Ylides. — The interest in epoxide and chiralsulfonium chemistry leads to the development of an approach to chiralepoxyamides such as (III). The absolute configuration in one case is provenby an independent synthesis using the Sharpless asymmetric dihydroxylation.— (ZHOU, YONG-GUI; HOU, XUE-LONG; DAI, LI-XIN; XIA, LI-JUN;TANG, MING-HUA; J. Chem. Soc., Perkin Trans. 1 [old] (1999) 1, 77-80; Lab.Organomet. Chem., Shanghai Inst. Org. Chem., Acad. Sin., Shanghai 200032,Peop. Rep. China; EN)

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