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Page 1: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Chapter 9 Notes – Part III

Mr Nelson 2010

Page 2: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Polarity

• But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar.

Page 3: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Polarity

• There are two ways to tell if a molecule is nonpolar:– Symmetry – perfect symmetry

= nonpolar

– Dipoles moments – if the dipoles ‘cancel out’ the molecule is nonpolar

Page 4: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Examples

• Draw the Lewis Dot Structure for:– HCl

– CCl4

Page 5: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar
Page 6: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Bonding & Lone Pairs

• Electron pairs that are shared are called bonding pairs

• Electron pairs that are not bonded or shared are called lone or unshared pairs

Page 7: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Steric Number• The total electron pairs

around the central atom is the steric number.

• Double or triple bonds count as one steric number (electron domain).

• The central atom has a steric number of four.

Page 8: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

Determining the shape of molecules

Page 9: Chapter 9 Notes – Part III Mr Nelson 2010. Polarity But just because a molecule possesses polar bonds does not mean the molecule as a whole will be polar

VSEPR (not the Bond girl Vesper)

• VSEPR: Valence Shell Electron Pair Repulsion

– Electron pairs will arrange so they are as far apart as possible. ALL HAVE NEGATIVE CHARGES

– ALL e- pairs determine the shape, bonded or not, but ONLY bonded pairs determine the name of the shape.


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